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At least 649 records · Page 36Linked to original sources
USGS1999

Diagenesis of lower Cretaceous pelagic carbonates, North Atlantic: Paleoceanographic signals obscured

The stable isotope and minor element geochemistry of Neocomian (Lower Cretaceous) pelagic carbonates of the North Atlantic Basin (Deep Sea Drilling Project Sites 105, 367, 387, 391, and 603) was examined to develop a diagenetic model for pelagic limestones. In particular, we hoped to test the fidelity of whole-rock geochemical records as paleoceanographic indicators for pelagic deposits of pre-Aptian age, in which individual microfossils are not available for analysis. Data indicate that in addition to depth of burial, rhythmic variations in primary carbonate content have strongly controlled diagenetic patterns and associated geochemical signatures in these Neocomian sequences. Samples become increasingly depleted in Sr and 18O with increasing CaCO3 content. Within individual sedimentary sections, substantial decreases in Sr/Ca ratios and ??18O values are evident over a range of 4 to 98% CaCO3. However, even over a relatively narrow range of 50 to 98% CaCO3 a 2.5%c variation in ??18O values and a change of a factor of 1.7 in Sr/Ca ratios are observed. Carbon isotope compositions do not vary as extensively with CaCO3 content, but carbonate-rich intervals tend to be relatively depleted in 13C. Petrographic analysis reveals that these geochemical patterns are related to the transfer of CaCO3 from carbonate-poor intervals (calcareous shales and marlstones) to adjacent carbonate-rich intervals (limestones) during burial compaction and pressure solution. This process results in the addition of diagenetic cement to carbonate-rich intervals to produce a bulk composition that is relatively depleted in Sr and 18O and, at the same time, enables the retention of more-or-less primary carbonate that is relatively enriched in Sr and 18O in adjacent carbonate-poor intervals. Thus, although cyclic variations in CaCO3 content are primary in the Neocomian sequences examined, measured variations in Sr/Ca ratios and ??18O values are not and, as such, do not provide reliable proxies for past variations in climate, oceanographic conditions, or global ice volume.

Journal of Foraminiferal Research↗
USGS1995

The influence of Hurricane Andrew on sediment distribution in Louisiana coastal marshes

The areal extent and temporal patterns of sediment deposition in delta marshes and shallow water bodies of Louisiana associated with the passage of Hurricane Andrew were determined from sediment traps, marker horizons, and benchmarks deployed for other studies. Data were collected over different time scales from 11 sites representing salt, brackish, and intermediate marshes, shallow water substrates, and regularly-flooded and partially impounded marshes located in Terrebonne, Barataria, and Pontchartrain basins. Storm tide data were collected at 6 hydrograph stations located in the vicinity of the sediment sampling sites. Significant sediment deposition and surface elevation changes were associated with the occurrence of storm tides both near and far (up to 130 km away) from the track of the storm. Short-term sediment deposition indicated an increase of up to 1–3 orders of magnitude compared to pre-storm rates. This increased rate remained high for up to 12 weeks, suggesting that material brought in by the storm was available for resuspension and deposition. But short-term sediment deposition decreased precipitously after passage of the first major cold front across Louisiana, suggesting that the sediment made available by the storm was removed or consolidated. The storm-associated sediments were characteristically coarser with lower organic matter content than the pre-storm marsh soils. Marsh vertical accretion and surface elevation change were enhanced on both semi-annual and annual time scales for all sites we studied. This single storm generated 2–6 cm more vertical accretion than occurred in either the year before or after the storm. Sediment was both introduced from outside the coastal marsh system and redistributed as the marsh substrate eroded. At shallow water sites, elevation increases were greater and were maintained near wave barriers constructed to baffle water movement while unprotected areas had smaller increases and quickly lost whatever gains had occurred. These findings indicate the potential importance of hurricanes in providing a pulse of sediment on a broad geographic scale to balance the effects of subsidence in this rapidly subsiding delta. These results further suggest that hurricanes play a large role in coastal marsh survival, particularly for marshes remote or isolated (i.e., impounded) from a riverine source of sediment.

Louisiana↗
USGS2012

Magnetic fabric, flow directions, and source area of the Lower Miocene Peach Springs Tuff in Arizona, California, and Nevada

We have used anisotropy of magnetic susceptibility (AMS) to define the flow fabric and possible source area of the Peach Springs Tuff, a widespread rhyolitic ash flow tuff in the Mojave Desert and Great Basin of California, Arizona, and Nevada. The tuff is an important stratigraphic marker from the Colorado Plateau to Barstow, California, a distance of 350 km; however, the location of its source caldera is unknown. Dated at 18.5 Ma by 40 Ar/ 39 Ar, the tuff erupted during the early stages of Miocene extension along the lower Colorado River. The thicker accumulations (>100 m) occur at Kingman, Arizona, and in the Piute Mountains, California, on opposite sides of the Colorado River extensional corridor. Our AMS studies produced well-defined magnetic lineations in 30 of 42 sites distributed throughout the tuff. Typical ratios of the principal AMS axes are 1.01 for the magnetic lineation ( k max / k int ) and 1.02 for the foliation ( k int / k min ); the bulk magnetic susceptibility of the Peach Springs Tuff averages 2.0×10 −3 in the SI unit system. The subhorizontal lineations, which presumably parallel the flow directions, form a pattern radiating outward from the approximate center of the outcrop area. Magnetic foliations define an imbrication that generally dips away from the distal margins and toward the center of the outcrop of the tuff. The lineation and imbrication indicate a source region near the southern tip of Nevada. Defining the best intersection of the AMS lineations required restoration of major extension, strike-slip faulting, and associated tectonic rotation in the disrupted tuff. The optimum intersection of magnetic lineations lies in the southern Black Mountains of Arizona on the eastern side of the Colorado River extensional corridor. No caldera structures are known from that area, but the area contains thick sections of the Peach Springs Tuff above a silicic volcanic center. The caldera may be buried under younger deposits in the Mohave Valley of Arizona. Tertiary granite in the Newberry Mountains may represent a deeper level of the Peach Springs Tuff vent that has been exhumed by detachment faulting.

Journal of Geophysical Research↗
USGS2012

Relation of peralkaline magmatism to heterogeneous extension during the Middle Miocene, southeastern Nevada

Volcanism migrated southward in the northern Basin and Range province in the Oligocene and early Miocene to produce voluminous calcalkaline silicic ash flow tuffs. Alkaline volcanism became dominant by middle Miocene (17–14 Ma) as smaller volumes of rhyolite-trachyte-basalt suites were erupted from the relatively small Kane Springs Wash caldera complex including the Narrow Canyon, Boulder Canyon, and Kane Springs Wash calderas in southeastern Nevada. Only minor extension affected the Kane Wash area before the end of calcalkaline activity, but extension expressed by rate of progressive stratal tilt peaked (15–13.5 Ma) with peralkaline magmatism (14.7–14.4 Ma). Variations in distribution, degree, style, and timing of deformation demonstrate heterogeneous extension in the Kane Wash area. Only minor extension and tilting persisted post-middle Miocene (<12 Ma). All major eruptive sources overlap domains of rapid extension. Most of the eruptive volumes from the two oldest calderas of the complex apparently pooled within their calderas, creating outflow deficits. Denudation faulting associated with magmatic tumescence may have followed preexisting active extensional fault systems to unload magma chambers, thus triggering eruptions into structural depressions. Evolution of alkaline magmas is demonstrated by progressive increases in peralkalinity and high field strength elements such as Zr, Y, and Nb. Nd, Pb, and Sr isotopic compositions provide evidence that significantly less crustal interaction affected middle Miocene peralkaline magmas than pre-middle Miocene calcalkaline magmas. ε Nd values are −5 to −7 for peralkaline magmas and −7 to −11 for calcalkaline magmas; 208 Pb/ 204 Pb ratios are 38.2–38.6 for peralkaline magmas and 38.5–38.9 for calcalkaline magmas. Regional cooling, short duration of magmatism, small volumes of magma, and local extension caused less crustal interaction in peralkaline Kane Wash magmas than in earlier magmas. North of the Kane Wash area, older more voluminous calcalkaline magmas intruded hotter crust for a longer period and thus interacted with the crust to a greater degree in spite of synvolcanic extension.

Journal of Geophysical Research↗
USGS1985

Effects of contaminants on toxicity of the lampricides TFM and Bayer 73 to three species of fish

Waters in the Great Lakes basin contain more than 400 contaminant chemicals that potentially affect fishery resources, commerce, and human inhabitants. We determined in the laboratory the effects of selected contaminants on the toxicity of the widely used lampricides TFM (3-trifluoromethyl-4-nitrophenol) and Bayer 73 (2′,5-dichloro-4′-nitrosalicylanilide) to three species of fish—rainbow trout ( Salmo gairdneri ), white sucker ( Catostomus commersoni ), and fathead minnow ( Pimephales promelas ). The fish were exposed to paired mixtures of lampricides and selected contaminants in standardized, acute static toxicity tests to determine the resulting type of response—less than additive, additive, or greater than additive (synergistic). As expected, the toxicities of combinations of lampricides with organic pesticides, metal, industrial or municipal pollutants, and tannic acid were mostly additive. However, the toxicity of a combination of TFM, Delnav, and malathion was synergistic, and extremely small quantities of each chemical became lethal when mixed. The concentration that produced 50% mortality was 1.64 mg/L for TFM alone but only 0.041 mg/L for TFM with the pesticides. Toxicities of the pesticides in the combination also increased commensurately. The triple combination of chemicals produced extraordinary synergism and effectively demonstrated the hazards that may result if certain chemical combinations occur in the aquatic environment. However, synergism is not the only kind of toxic action that produces hazards to aquatic organisms. All three types of toxic action are of concern because toxic units produced by contaminant chemicals add to the toxic units of applied management chemicals. Since the toxicity of the majority of chemical combinations is simply additive, this cumulative toxic action contributes more total units to aquatic environments than the extreme actions of less than additive and synergism. The toxicity of the lampricide TFM, as well as other management chemicals, is reinforced by the presence of any contaminant that contributes additional units of toxicity. Therefore, all types of cumulative toxic action should be of concern to people and agencies involved with protecting the environment.

Journal of Great Lakes Research↗
USGS2004

The Late Cambrian SPICE (δ13C) event and the Sauk II-Sauk III regression: new evidence from Laurentian basins in Utah, Iowa, and Newfoundland

Carbon isotope data from Upper Cambrian sections in three Laurentian basins in northern Utah, central Iowa, and western Newfoundland record a large positive ??13C excursion (SPICE event) of up to + 5???. Peak ??13C ratios are well dated by trilobite collections to the middle of the Steptoean Stage (Dunderbergia Zone) and occur during maximum regression associated with formation of the Sauk II-Sauk III subsequence boundary on the North American craton. Maximum regression was marked by an influx of quartz sand into carbonate-platform settings in all three widely separated basins. In northern Utah, this quartz sand formed a thick sequence known as the Worm Creek Quartzite, which marks a conspicuous interruption of carbonate deposition during the Middle to Late Cambrian in the region. In western Newfoundland, the thickness of the quartz sand unit is much reduced but still marks a brief shutdown of the carbonate factory that is unique to the Cambrian shelf succession of the area. In the central Iowa area of the cratonic interior, an upward-shallowing carbonate succession culminates in cross-stratified trilobite grainstones at the peak of the SPICE in Dunderbergia Zone time, and the lowest point on the relative-sea-level curve is associated with the occurrence of coarse quartz sand derived from the encroaching shoreface. Although it is difficult to determine precisely the departure from baseline ??13C that marks the beginning of the SPICE excursion in the stratigraphic successions analyzed, our results are consistent with a rise and subsequent fall in ??13C tracking a major regressive-transgressive event recorded across northern Laurentia. The correlation of a major ??13C excursion with regression is similar to that described for the Late Ordovician, for which the pattern has been attributed to either increased carbonate relative to terrigenous weathering rates as ice sheets covered up organic-matter-containing silicates at high latitudes or high productivity and organic-carbon burial driven by oceanic overturn. The lack of known Steptoean-age ice sheets that could have affected the ratio of carbonate to silicate weathering rates suggests that organic-carbon burial was the likely cause of the SPICE event. We suggest that increased weathering and erosion rates during relative sea-level fall (Sauk II-III) increased the burial fraction of organic carbon in an expanded region of fine-grained siliciclastic deposits in shelf and upper slope environments during the Steptoean. ?? 2004, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research↗
USGS2020

Fluorescence spectroscopy of ancient sedimentary organic matter via confocal laser scanning microscopy (CLSM)

Fluorescence spectroscopy via confocal laser scanning microscopy (CLSM) was used to analyze ancient sedimentary organic matter, including Tasmanites microfossils in Devonian shale and Gloecapsomorpha prisca ( G. prisca ) in Ordovician kukersite from North American basins. We examined fluorescence emission as a function of excitation laser wavelength, sample orientation, and with respect to location within individual organic entities and in transects across bedded organic matter. Results from spectral scans of the same field of view in Tasmanites with different laser lines showed progressive red-shift in emission maxima with longer excitation wavelengths. This result indicates steady-state Tasmanites fluorescence emission is an overlapping combination of emission from multiple fluorophore functions. Stokes shift decreased with increasing excitation wavelength, further suggesting the presence of multiple fluorophore functions with different S 1 → S 0 transition energies. This observation also indicates that at longer excitation wavelengths, less absorbed light energy is dissipated via collisional transfer than at shorter excitation wavelengths and may suggest fewer polar functions are preferentially absorbing. Confirming earlier results, emission spectra observed from high fluorescence intensity regions (fold apices) in individual Tasmanites are blue-shifted relative to emission from other locations in the same microfossil. We suggest high intensity emission is from photoselective alignment of polarized excitation with the fluorophore absorption and emission transition moment. The blue shift observed in regions of high intensity emission may be due to relative absence or realignment of polar species, e.g., bridging ether or ester functions, although variations in O abundance could not be confirmed with preliminary time-of-flight secondary ion mass spectrometry (TOF-SIMS) analysis. Tasmanites occurring in consolidated sediments are flattened from original spherical morphology and, in optical microscopy, this burial deformation results in generally parallel extinction (strain-influenced) and positive elongation. The deformation also induces fluorescence anisotropy observed as variations in emission wavelength when individual Tasmanites are measured from their long axis parallel to bedding, whereas this effect is absent in bedding-normal view. Transects from G. prisca -rich source layers into adjacent reservoir layers show decrease in fluorescence intensity and spectral red-shift (increase in full-width half-maximum with increasing red portion of the half-width). These results may suggest an increase in fluorescence quenching across the source-to-reservoir transition zone, consistent with an increase in aromaticity following petroleum expulsion and migration. These observations are supported by increasing reflectance values measured across similar micro-scale transects. Our results highlight the applicability of CLSM as a broad and under-utilized approach for the characterization of sedimentary organic matter and are discussed with perspective toward petroleum processes and thermal indices research.

International Journal of Coal Geology↗
USGS2009

Identification of hydrated silicate minerals on Mars using MRO-CRISM: Geologic context near Nili Fossae and implications for aqueous alteration

[1] The Noachian terrain west of the Isidis basin hosts a diverse collection of alteration minerals in rocks comprising varied geomorphic units within a 100,000 km 2 region in and near the Nili Fossae. Prior investigations in this region by the Observatoire pour l'Minéralogie, l'Eau, les Glaces, et l'Activité (OMEGA) instrument on Mars Express revealed large exposures of both mafic minerals and iron magnesium phyllosilicates in stratigraphic context. Expanding on the discoveries of OMEGA, the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) aboard the Mars Reconnaissance Orbiter (MRO) has found more spatially widespread and mineralogically diverse alteration minerals than previously realized, which represent multiple aqueous environments. Using CRISM near-infrared spectral data, we detail the basis for identification of iron and magnesium smectites (including both nontronite and more Mg-rich varieties), chlorite, prehnite, serpentine, kaolinite, potassium mica (illite or muscovite), hydrated (opaline) silica, the sodium zeolite analcime, and magnesium carbonate. The detection of serpentine and analcime on Mars is reported here for the first time. We detail the geomorphic context of these minerals using data from high-resolution imagers onboard MRO in conjunction with CRISM. We find that the distribution of alteration minerals is not homogeneous; rather, they occur in provinces with distinctive assemblages of alteration minerals. Key findings are (1) a distinctive stratigraphy, in and around the Nili Fossae, of kaolinite and magnesium carbonate in bedrock units always overlying Fe/Mg smectites and (2) evidence for mineral phases and assemblages indicative of low-grade metamorphic or hydrothermal aqueous alteration in cratered terrains. The alteration minerals around the Nili Fossae are more typical of those resulting from neutral to alkaline conditions rather than acidic conditions, which appear to have dominated much of Mars. Moreover, the mineralogic diversity and geologic context of alteration minerals found in the region around the Nili Fossae indicates several episodes of aqueous activity in multiple distinct environments.

Journal of Geophysical Research E: Planets↗
USGS2003

Aeolian processes in Proctor Crater on Mars: Sedimentary history as analyzed from multiple data sets

Proctor Crater is a 150 km diameter crater in Noachis Terra, within the southern highlands of Mars. The analysis leading to the sedimentary history incorporates several data sets including imagery, elevation, composition, and thermal inertia, mostly from the Mars Global Surveyor mission. The resulting stratigraphy reveals that the sedimentary history of Proctor Crater has involved a complex interaction of accumulating and eroding sedimentation. Aeolian features spanning much of the history of the crater interior dominate its surface, including large erosional pits, stratified beds of aeolian sediment, sand dunes, erosional and depositional streaks, dust devil tracks, and small bright bed forms that are probably granule ripples. Long ago, up to 450 m of layered sediment filled the crater basin, now exposed in eroded pits on the crater floor. These sediments are probably part of an ancient deposit of aeolian volcaniclastic material. Since then, some quantity of this material has been eroded from the top layers of the strata. Small, bright dune forms lie stratigraphically beneath the large dark dune field. Relative to the large dark dunes, the bright bed forms are immobile, although in places, their orientations are clearly influenced by the presence of the larger dunes. Their prevalence in the crater and their lack of compositional and thermal distinctiveness relative to the crater floor suggests that these features were produced locally from the eroding basin fill. Dust devil tracks form during the spring and summer, following a west-southwesterly wind. Early in the spring the dust devils are largely restricted to dark patches of sand. As the summer approaches, dust devil tracks become more plentiful and spread to the rest of the crater floor, indicating that the entire region acquires an annual deposit of dust that is revealed by seasonal dust devils. The dark dunes contain few dust devil tracks, suggesting that accumulated dust is swept away directly by saltation, rather than by the passage of dust devils. Spectral deconvolution indicates that the dark dunes have infrared spectra consistent with basalt-like materials. The average thermal inertia calculated from Thermal Emission Spectrometer bolometric temperatures is 277 ?? 17 J m-2 s-0.5 K-1, leading to an effective grain size of 740 ?? 170 ??m, which is consistent with coarse sand and within the range expected for Martian sand. The coarse sand that composes the large dune field may have originated from outside the crater, saltating in from the southwest. Most of the transport pathway that delivered this sand to the dune field has since been eroded away or buried. The sand was transported to the east center of the crater floor, where beneath the present-day dunes a 50 m high mound of sand has accumulated. Dune slip faces indicate a wind regime consisting of three opposing winds. Some of these wind directions are correlated with the orientations of dust devil tracks and bright bed forms. The combination of a tall mound of sand and three opposing winds is consistent with a convergent wind regime, which produces the large reversing transverse and star dunes that dominate the dune field. The dark dunes have both active slip faces and seemingly inactive slip faces, suggesting that the dunes vary spatially in their relative activity. Nevertheless, the aeolian activity that has dominated the history of Proctor Crater still continues today. Copyright 2003 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗
USGS1972

Factors of ecologic succession in oligotrophic fish communities of the Laurentian Great Lakes

Oligotrophic fish communities of the Great Lakes have undergone successive disruptions since the mid-1800s. Major contributing factors have been intensive selective fisheries, extreme modification of the drainage, invasion of marine species, and progressive physical&ndash;chemical changes of the lake environments. Lake Ontario was the first to be affected as its basin was settled and industrialized earliest, and it was the first to be connected by canals to the mid-Atlantic where the alewife ( Alosa pseudoharengus ) and sea lamprey ( Petromyzon marinus ) which ultimately became established in the Great Lakes were abundant. Oligotrophic fish communities were successively disrupted in Lakes Erie, Huron, Michigan, and Superior as the affects of population growth, industrialization, and marine invaders spread upward in the Laurentian drainage.The degree and sequence of response of families offish and species within families differed for each factor, but the sequence of change among families and species has been the same in response to each factor as it affected various lakes at different times. The ultimate result of the disruption of fish communities has been a reduction of productivity of oligotrophic species that ranges from extreme in Lake Ontario to moderate in Lake Superior, and which has reached a state of instability and rapid change in the upper three Great Lakes by the rnid-1900s similar to the situation in Lake Ontario in the mid-1800s. Since oligotrophic species (primarily salmonines, coregonines, and deepwater cottids) are the only kinds of fish that fully occupied the entire volume of the deepwater Great Lakes (Ontario, Huron, Michigan, and Superior), the fish biomass of these lakes has been reduced as various species declined or disappeared. In Lake Erie, which is shallow, and in the shallow bays of the deep lakes, oligotrophic species were replaced by mesotrophic species, primarily percids, which have successively increased and declined. All oligotrophic species are greatly reduced or extinct in lakes Ontario and Erie, and are in various stages of decline in lakes Huron, Michigan, and Superior, from greatest to least, respectively. The percids appear to be near the end of their sequence of succession in lakes Erie, Ontario, and Huron (primarily Saginaw Bay) where only the yellow perch ( Perca flavescens ) remains abundant. The yellow perch appears to be on the brink of decline in Lake Erie, which has been more severely influenced by water quality change than the other lakes.

Journal of the Fisheries Research Board of Canada↗
USGS2012

Active tectonic and magmatic processes beneath Long Valley Caldera, eastern California: An overview

Geological, chronological, and structural studies of the Long Valley-Mono/Inyo Craters area document a long history of related volcanic eruptions and earthquakes controlled by regional extensional tectonics of the Basin and Range province. This activity has persisted for hundreds of thousands of years and is likely to continue. The Long Valley magma chamber had a volume approaching 3000 km 3 prior to its climatic caldera-forming eruption 0.7 m.y. ago but has been reduced to less than a third of this volume by cooling, eruption, and crystallization. Seismic evidence indicates that the main mass of the present Long Valley magma chamber is about 10 km in diameter and that its roof is 8–10 km deep with smaller cupolas as shallow as 4–5 km. Although a chamber of this size is probably capable of producing an eruption approaching 30 km 3 of lava, the record over the past 0.5 m.y. suggests that eruptions of 1 km 3 or less are far more likely. Models proposed for the current ground uplift and seismicity within the caldera require inflation of 0.1–0.2 km 3 by additional magma since mid-1979, and some models suggest that inflation was accompanied by injection of a thin dike or dikes (probably of silicic magma) into the ring fracture zone beneath the south moat. Several of the M 5.8–6.2 earthquakes that occurred in the region beginning in 1978 had non-double-couple focal mechanisms. Whether these unusual mechanisms indicate injection of mafic (low-viscosity) magma at midcrustal depths in the Sierra Nevada block south of the caldera remains debatable. Studies of calderas of various ages throughout the world indicate that episodes of unrest are relatively common and do not invariably culminate in eruptions. Although current unrest is concentrated in the south moat of Long Valley caldera, the Inyo/Mono Craters probably hold a greater potential for producing an eruption in the foreseeable future. The Inyo/Mono Craters have erupted at 500-year intervals over the past 2000–3000 years, whereas the Long Valley magma chamber has erupted at about 200,000-year intervals over the past 700,000 years. In either case, a major earthquake near the caldera could strongly influence the course of volcanic activity.

Journal of Geophysical Research Solid Earth↗
USGS2001

Sedimentary Carbon, Sulfur, and Iron Relationships in Modern and Ancient Diagenetic Environments of the Eel River Basin (U.S.A.)

Depositional and diagenetic controls on the distributions of carbon, sulfur, and iron (C-S-Fe) in modern sediments and upper Pleistocene mudrocks of the Eel River Basin (ERB), northern California continental margin, were investigated using a combination of geochemical, radioisotopic, and sedimentological methods. A mass balance based on down-core profiles of porewater and solid-phase constituents and diagenetic modeling suggests that only 12-30% of the pyrite-S produced via SO 4 -2 reduction during burial is retained in modern shelf and upper slope deposits of the ERB. Bioturbational reoxidation of initially reduced S is inferred to be the major control on S preservation, on the basis of an observed inverse relationship between pyrite-S retention and biological mixing intensity, estimated from profiles of excess 234 Th. Importantly, these findings argue that massive depositional episodes on the shelf following floods of the Eel River have a negligible long-term impact on bioturbating macrofauna and the potential to affect geochemical properties of the sediments. Down-core profiles of reactive Fe 3+ and Py-Fe(II) for the modern deposits suggest that highly reactive Fe phases are sulfidized well within ∼ 500-2000 years of burial, thereby limiting later pyritization, which could occur through sulfidation of less reactive phases. This result explains the low (≤ 0.4) degree of pyritization (DOP) values exhibited by both modern and ancient deposits of the ERB and lends support to the notion that pyritization in aerobic continental-margin sediments is largely associated with highly reactive detrital Fe oxides. Comparable mean C/S weight ratios for modern sediments (5.4 ± 3.3, 1σ) and mudrocks (6.9 ± 4.5) of the ERB suggest that the upper Pleistocene strata reflect a geochemical environment analogous to that of the modern margin. Specifically, the C-S-Fe signatures shared by the modern and ancient deposits are a consequence of similar detrital Fe mineralogies, initial organic-matter content (C org ≤ 1%) and composition (C/N = 13 to 17, δ 13 C org = -22 to -25‰), burial rate, and importantly, bioturbation intensity. The findings of this study have important implications for the use of C-S-Fe signatures as indicators of diagenetic processes in dynamic, continental-margin environments.

California↗
USGS2002

The oligocene Lund Tuff, Great Basin, USA: A very large volume monotonous intermediate

Unusual monotonous intermediate ignimbrites consist of phenocryst-rich dacite that occurs as very large volume (> 1000 km3) deposits that lack systematic compositional zonation, comagmatic rhyolite precursors, and underlying plinian beds. They are distinct from countless, usually smaller volume, zoned rhyolite-dacite-andesite deposits that are conventionally believed to have erupted from magma chambers in which thermal and compositional gradients were established because of sidewall crystallization and associated convective fractionation. Despite their great volume, or because of it, monotonous intermediates have received little attention. Documentation of the stratigraphy, composition, and geologic setting of the Lund Tuff - one of four monotonous intermediate tuffs in the middle-Tertiary Great Basin ignimbrite province - provides insight into its unusual origin and, by implication, the origin of other similar monotonous intermediates. The Lund Tuff is a single cooling unit with normal magnetic polarity whose volume likely exceeded 3000 km3. It was emplaced 29.02 ?? 0.04 Ma in and around the coeval White Rock caldera which has an unextended north-south diameter of about 50 km. The tuff is monotonous in that its phenocryst assemblage is virtually uniform throughout the deposit: plagioclase > quartz ??? hornblende > biotite > Fe-Ti oxides ??? sanidine > titanite, zircon, and apatite. However, ratios of phenocrysts vary by as much as an order of magnitude in a manner consistent with progressive crystallization in the pre-eruption chamber. A significant range in whole-rock chemical composition (e.g., 63-71 wt% SiO2) is poorly correlated with phenocryst abundance. These compositional attributes cannot have been caused wholly by winnowing of glass from phenocrysts during eruption, as has been suggested for the monotonous intermediate Fish Canyon Tuff. Pumice fragments are also crystal-rich, and chemically and mineralogically indistinguishable from bulk tuff. We postulate that convective mixing in a sill-like magma chamber precluded development of a zoned chamber with a rhyolitic top or of a zoned pyroclastic deposit. Chemical variations in the Lund Tuff are consistent with equilibrium crystallization of a parental dacitic magma followed by eruptive mixing of compositionally diverse crystals and high-silica rhyolite vitroclasts during evacuation and emplacement. This model contrasts with the more systematic withdrawal from a bottle-shaped chamber in which sidewall crystallization creates a marked vertical compositional gradient and a substantial volume of capping-evolved rhyolite magma. Eruption at exceptionally high discharge rates precluded development of an underlying plinian deposit. The generation of the monotonous intermediate Lund magma and others like it in the middle Tertiary of the western USA reflects an unusually high flux of mantle-derived mafic magma into unusually thick and warm crust above a subducting slab of oceanic lithosphere. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Volcanology and Geothermal Research↗
USGS2012

Seismicity and shear strain in the southern Great Basin of Nevada and California

This study examines the relationship between the distribution of small earthquakes (M L ≤4.3) and mechanisms of strain accumulation and relaxation in an area with long repeat times between large events, the Southern Great Basin Seismic Network (SGBSN) region. The Great Basin is a unique continental extensional province characterized by normal and strike-slip faulting, high heat flow, crust of thin to normal thickness, and high elevations. The SGBSN is operated to provide data to address suitability issues pertaining to Yucca Mountain, Nevada which is being evaluated as a potential site for a national mined geologic nuclear waste repository. Suitability issues include estimation of the probability of occurrence of future damaging earthquakes, the characterization of the mechanisms that drive hydrologic flow, and the identification of fractures (faults) that might act as flow conduits or barriers. This study attempts to explain the distribution of small earthquakes in terms of spatial variations in the shear strain field; where strain concentrates there should be a greater number of small earthquakes. Strain field models are constructed under the assumption that long term fault behavior perturbs an otherwise uniform strain field. These strain field models are then interpreted with regard to the regional tectonics and site suitability issues. Modeling results provide one possible explanation of why earthquake clusters cover regions much larger than the surface projections of any of mapped major faults; clusters in a wide band along and extending northeast of the northern half of the Furnace Creek fault may correspond to elevated shear strains along the fault and a broad cluster in the Pahranagat Shear Zone may be associated with shear strain arising from a distribution of smaller localized faults. The relatively large number of small earthquakes in the southern and eastern portions of the Nevada Test Site is consistent with the strain field models. A minimum in shear strain at Yucca Mountain is predicted by all models consistent with an almost total lack of earthquakes observed there. The region to the west of the Death Valley/Furnace Creek fault system, the portion of the study area with the most active deformation but few small earthquakes, is an area of low shear strain. A possible reason for this is that the fault configuration in the area is optimal for accommodating regional deformation via large earthquakes or creep. While there is also a relative lack of earthquakes at Yucca Mountain, this may be indicative of a lack of accumulating strain energy and thus, a lower potential for a large earthquake.

Journal of Geophysical Research↗
USGS2006

Classification tree and minimum-volume ellipsoid analyses of the distribution of ponderosa pine in the western USA

Aim? Ponderosa pine (Pinus ponderosa Douglas ex Lawson & C. Lawson) is an economically and ecologically important conifer that has a wide geographic range in the western USA, but is mostly absent from the geographic centre of its distribution - the Great Basin and adjoining mountain ranges. Much of its modern range was achieved by migration of geographically distinct Sierra Nevada (P. ponderosa var. ponderosa) and Rocky Mountain (P. ponderosa var. scopulorum) varieties in the last 10,000 years. Previous research has confirmed genetic differences between the two varieties, and measurable genetic exchange occurs where their ranges now overlap in western Montana. A variety of approaches in bioclimatic modelling is required to explore the ecological differences between these varieties and their implications for historical biogeography and impending changes in western landscapes. Location? Western USA. Methods? We used a classification tree analysis and a minimum-volume ellipsoid as models to explain the broad patterns of distribution of ponderosa pine in modern environments using climatic and edaphic variables. Most biogeographical modelling assumes that the target group represents a single, ecologically uniform taxonomic population. Classification tree analysis does not require this assumption because it allows the creation of pathways that predict multiple positive and negative outcomes. Thus, classification tree analysis can be used to test the ecological uniformity of the species. In addition, a multidimensional ellipsoid was constructed to describe the niche of each variety of ponderosa pine, and distances from the niche were calculated and mapped on a 4-km grid for each ecological variable. Results? The resulting classification tree identified three dominant pathways predicting ponderosa pine presence. Two of these three pathways correspond roughly to the distribution of var. ponderosa, and the third pathway generally corresponds to the distribution of var. scopulorum. The classification tree and minimum-volume ellipsoid model show that both varieties have very similar temperature limitations, although var. ponderosa is more limited by the temperature extremes of the continental interior. The precipitation limitations of the two varieties are seasonally different, with var. ponderosa requiring significant winter moisture and var. scopulorum requiring significant summer moisture. Great Basin mountain ranges are too cold at higher elevations to support either variety of ponderosa pine, and at lower elevations are too dry in summer for var. scopulorum and too dry in winter for var. ponderosa. Main conclusions? The classification tree analysis indicates that var. ponderosa is ecologically as well as genetically distinct from var. scopulorum. Ecological differences may maintain genetic separation in spite of a limited zone of introgression between the two varieties in western Montana. Two hypotheses about past and future movements of ponderosa pine emerge from our analyses. The first hypothesis is that, during the last glacial period, colder and/or drier summers truncated most of the range of var. scopulorum in the central Rockies, but had less dramatic effects on the more maritime and winter-wet distribution of var. ponderosa. The second hypothesis is that, all other factors held constant, increasing summer temperatures in the future should produce changes in the distribution of var. scopulorum that are likely to involve range expansions in the central Rockies with the warming of mountain ranges currently too cold but sufficiently wet in summer for var. scopulorum. Finally, our results underscore the growing need to focus on genotypes in biogeographical modelling and ecological forecasting.

Journal of Biogeography↗
USGS2019

Interferometric synthetic aperture radar study of recent eruptive activity at Shrub mud volcano, Alaska

Shrub mud volcano is one of three large mud volcanoes that comprise the Klawasi Group in the Copper River Basin of southcentral Alaska. Except for minor discharges in the mid-1950s when the group was first described, Shrub was dormant prior to its reactivation in summer 1996. From 1997 to 1999, Shrub vigorously erupted more than 5 x 105 cubic meters of saline mud and carbon dioxide-rich gas at temperatures as high as 54 degrees C. Thereafter, activity waned but continued at least through 2015. We analyzed 192 interferograms derived from 106 synthetic aperture radar (SAR) images acquired by the JERS-1 (L-band), ERS-1/2 (C-band), RADARSAT-1 (C-band), and ALOS PALSAR (L-band) satellites to characterize ground deformation at Shrub before, during, and after its reactivation. Collectively, the interferograms span 1992–2000 and 2006–2011. We fit the observations with two deformation sources: a deflating, steeply dipping, pipe-like body under the summit area and an inflating, shallow-dipping, sill-like body under the southwest flank. Both sources are shallow, with centroids less than 1 km beneath the summit. Prior to reactivation, the flank source inflated ~0.35 x 105 cubic meters per year from July 1992 to May 1996. During eruptive activity, the summit source deflated at higher rates that peaked at ~8.71 x 105 cubic meters per year during May–November 1997 and continued at ~0.95 x 105 cubic meters per year during the 2006–2011 observation window. Cumulative source-volume loss is comparable to the volume of mud erupted. We interpret the summit source as the volcano’s feeder conduit that pressurized prior to the first SAR observation in 1992. Also before 1992, the conduit ruptured to feed a lateral intrusion of mud under the southwest flank, perhaps along a bedding plane in underlying glaciolacustrine deposits. The growing sill caused the southwest flank to inflate while it accommodated the mud supply from depth, which explains why we observed pre-eruptive inflation of the flank but not the summit. The summit began deflating when the conduit ruptured to the surface at the onset of eruptive activity. The flank source did not deflate concurrently because the weight of the thin overburden was insufficient to collapse the sill. There is a suggestion in the modern topography that lateral intrusions under Shrub’s southwest flank are a common feature of activity there.

Alaska↗
USGS2003

Oceans on Mars: An assessment of the observational evidence and possible fate

If the large Late Hesperian outflow channels were eroded by extensive floods, as appears likely, then large bodies of water must have once occupied the northern plains during that period. Previous estimates of the sizes of bodies of water in the northern lowlands range up to 3 ?? 108 km3. Several contacts have been previously mapped around the edges of the northern plains and interpreted to be shorelines remaining from these former standing bodies of water. We examine the elevations and geologic relations along these contacts in detail and find little support for their interpretation as shorelines. Some contacts are clearly of volcanic origin, and all have significant variations in elevation. Better support for the former presence of water over large parts of the northern plains is provided by the Vastitas Borealis Formation (VBF). Most of the post-Noachian fill within the northern basin is ridged plains of Lower Hesperian age, interpreted to be volcanic in origin. Overlying the ridged plains is the VBF, a thin veneer of material of Upper Hesperian age. The VBF may have been deposited from large floods. Support for this interpretation is the similarity in age between the outflow channels and the VBF, the presence of the VBF at the lower ends of the outflow channels, and identification of numerous features in the outcrop areas of the VBF that are suggestive of basal melting of an ice sheet. To cover all the area over which the VBF is exposed would require ???2.3 ?? 107 km3 of water. Spread over the entire surface of Mars, this volume is equal to a global layer (global equivalent layer, or GEL) ???156 m deep. We find no support for the larger estimates of ocean volumes that range up to 3 ?? 108 km3 and which imply comparable amounts of water per unit area as are currently present on the surface of the Earth. Under present climatic conditions on Mars an ocean would freeze in a geologically short time period (???104 years), then would sublimate away at rates strongly dependent on the presence or absence of debris on the ice surface. The present VBF is interpreted as a sublimation residue from the ponded outflow channel effluents. The fate of a volume of water thought to have been emplaced by the outflow channels (???2.3 ?? 107 km3) is largely accounted for by the presence of other existing reservoirs on the planet. An approximately 20-30 m GEL of water is estimated to be in the present polar caps, and a 50 m GEL may have escaped to space since the Hesperian, leaving ???80 m GEL unaccounted for. This amount may be partly trapped in other volatile-rich deposits on the surface, and a significant amount could have reentered the groundwater system by south polar basal melting and been progressively cold-trapped at the base of a growing cryosphere. On the basis of our assessment of the Hesperian-aged deposits, we predict that testing of the Clifford and Parker [2001] hypothesis that a Noachian-aged ocean covered up to one third of the surface of Mars will be made very difficult by the enhanced degradation rates in the Noachian and subsequent geological events in the northern lowlands.

Journal of Geophysical Research E: Planets↗
USGS2012

Lithology and evolution of the crust-mantle boundary region in the southwestern Basin and Range Province

Mantle and crustal xenoliths from volcanic rocks in the southwestern Basin and Range province and Colorado Plateau Transition Zone reveal histories of episodic magmatism and deformation that have profoundly influenced the crustal structure of this region. Seismic transects in this area show a strongly reflective Moho of generally low relief, which, in the area of modern transects, consists of a thin zone (<2 km thick) of short reflectors. The upper mantle is transparent and has a P n of 7.8–8.0 km/s similar to much of the western United States. A lower crustal zone, 2–13 km thick, has variable internal reflectivity and a relatively low velocity of 6.6–6.8 km/s. Upper mantle peridotite xenoliths show both ductile and brittle deformational features and have structures and compositions affected by magmatic intrusion; intrusions form complex dike systems and extensive zones of grain boundary infiltration in peridotite xenoliths. Whereas melt infiltration preceded and followed ductile deformation, brittle deformation, represented by closely spaced joint systems and faults, followed ductile deformation and is related to the youngest magmatic episodes. These structural characteristics and high uppermost mantle temperature (∼1000°C) may combine to explain the relatively low P n . Alternating layers of ductily deformed and undeformed peridotites, with or without igneous intrusions, may contribute to the reflectivity of the Moho. Lower crustal xenoliths are dominantly igneous-textured pyroxenites and mafic to intermediate gabbros identical to the dikes in peridotite xenoliths. The crustal xenoliths also commonly are jointed, and in addition many show partial melting and have abundant cavities that probably were filled with CO 2 -rich fluids. These rocks are interpreted as products of underplated magmas that were fed through the mantle dike systems and may represent the lowest crustal unit identified in the seismic records. The mafic compositions and high densities of the crustal xenoliths indicate that the low velocity of the lower crust may be caused in part by fracture systems, partial melts, and high temperatures. Garnet granulite xenoliths from a locality with no mantle peridotite xenoliths probably represent crust of the region before late Miocene extension. Felsic granulite xenoliths from two localities have velocities like those of the two lower crustal units identified seismically and could be present in the modern crust as unequilibrated remnants of old crust. The preferred model for the evolution of the lower lithosphere is one in which extension affects the upper mantle as well as the crust and is overlapped in time by multiple magmatic episodes. The earliest magmatic events preceded extension, and later events accompanied and followed extension.

Arizona, California, Nevada↗