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Compositional changes in sediments of subalpine lakes, Uinta Mountains (Utah): Evidence for the effects of human activity on atmospheric dust inputs

Sediments in Marshall and Hidden Lakes in the Uinta Mountains of northeastern Utah contain records of atmospheric mineral-dust deposition as revealed by differences in mineralogy and geochemistry of lake sediments relative to Precambrian clastic rocks in the watersheds. In cores spanning more than a thousand years, the largest changes in composition occurred within the past approximately 140 years. Many elements associated with ore deposits (Ag, As, Bi, Cd, Cu, In, Mo, Pb, S, Sb, Sn, and Te) increase in the lake sediments above depths that correspond to about AD 1870. Sources of these metals from mining districts to the west of the Uinta Mountains are suggested by (1) the absence of mining and smelting of these metals in the Uinta Mountains, and (2) lower concentrations of most of these elements in post-settlement sediments of Hidden Lake than in those of Marshall Lake, which is closer to areas of mining and the densely urbanized part of north-central Utah that is termed the Wasatch Front, and (3) correspondence of Pb isotopic compositions in the sediments with isotopic composition of ores likely to have been smelted in the Wasatch Front. A major source of Cu in lake sediments may have been the Bingham Canyon open-pit mine 110 km west of Marshall Lake. Numerous other sources of metals beyond the Wasatch Front are likely, on the basis of the widespread increases of industrial activities in western United States since about AD 1900. In sediment deposited since ca. AD 1945, as estimated using 239+240 Pu activities, increases in concentrations of Mn, Fe, S, and some other redox-sensitive metals may result partly from diagenesis related to changes in redox. However, our results indicate that these elemental increases are also related to atmospheric inputs on the basis of their large increases that are nearly coincident with abrupt increases in silt-sized, titanium-bearing detrital magnetite. Such magnetite is interpreted as a component of atmospheric dust, because it is absent in catchment bedrock. Enrichment of P in sediments deposited after ca. AD 1950 appears to be caused largely by atmospheric inputs, perhaps from agricultural fertilizer along with magnetite-bearing soil.

Utah↗

International strategic minerals inventory summary report; tin

The International Strategic Minerals Inventory tin inventory contains records for 56 major tin deposits and districts in 21 countries. These countries accounted for 98 percent of the 10 million metric tons of tin produced in the period 1934-87. Tin is a good alloying metal and is generally nontoxic, and its chief uses are as tinplate for tin cans and as solder in electronics. The 56 locations consist of 39 lode deposits and 17 placers and contain almost 7.5 million metric tons of tin in identified economic resources (R1E) and another 1.5 million metric tons of tin in other resource categories. Most of these resources are in major deposits that have been known for over a hundred years. Lode deposits account for 44 percent of the R1E and 87 percent of the resources in other categories. Placer deposits make up the remainder. Low-income and middle-income countries, including Bolivia and Brazil and countries along the Southeast Asian Tin Belt such as Malaysia, Thailand, and Indonesia account for 91 percent of the R1E resources of tin and for 61 percent of resources in other categories. The United States has less than 0.05 percent of the world's tin R1E in major deposits. Available data suggest that the Soviet Union may have about 4 percent of resources in this category. The industrial market economy countries of the United States, Japan, Federal Republic of Germany, and the United Kingdom are major consumers of tin, whereas the major tin-producing countries generally consume little tin. The Soviet Union and China are both major producers and consumers of tin. At the end of World War II, the four largest tin-producing countries (Bolivia, the Belgian Congo (Zaire), Nigeria, and Malaysia) produced over 80 percent of the world's tin. In 1986, the portion of production from the four largest producers (Malaysia, Brazil, Soviet Union, Indonesia) declined to about 55 percent, while the price of tin rose from about $1,500 to $18,000 per metric ton. In response to tin shortages during World War II, the United States began stockpiling refined tin metal from approximately 1946 to 1953 to ensure a strategic supply in the event of another war. Since World War II, there have been six International Tin Agreements to maintain price and supply stability between tin producers and consumers. Artificially high prices set by the tin-producing members and a tin glut brought on by independent producers like Brazil caused the collapse of the world tin market in late 1985; the International Tin Council exhausted its credit to support the market price. By the year 2025, Bolivia's underground lode mines will likely have insignificant production, as will those in the United Kingdom. Tin mines in the Southeast Asian Tin Belt will still be active. Brazil, which has risen from the eighth-ranked tin-producing country in 1982 to the largest producer in 1988, will likely be a major influence on world tin production well into the 21st century. The future mining activity of deposits presently inactive in Australia is impossible to predict.

Circular↗

Undiscovered phosphate resources in the Caribbean region and their potential value for agricultural development

The countries of the world's humid tropical regions lack the soil fertility necessary for high agricultural productivity. A recently developed agricultural technology that increases soil fertility can make tropical agriculture highly productive, but the technique requires large inputs into the soil of phosphorus and other fertilizers and soil amendments. Use of fertilizers derived from phosphate rock is increasing greatly throughout the world, and fertilizer raw materials are being produced more and more frequently from phosphate rock deposits close to the areas of use. An increased understanding of the origin of phosphate rock in ancient oceans has enabled exploration geologists to target areas of potential mineral resource value and to search directly for deposits. However, because of the difficulty of prospecting for mineral deposits in forested tropical regions, phosphate rock deposits are not being explored for in the countries of the humid tropics, including most countries of the Caribbean region. As a result, the countries of the Caribbean must import phosphate rock or phosphorus fertilizer products. In the present trade market, imports of phosphate are too low for the initiation of new agricultural technology in the Caribbean and Central American region. A newly proposed program of discovery and development of undiscovered phosphate rock deposits revolves around reconnaissance studies, prospecting by core drilling, and analysis of bulk samples. The program should increase the chance of discovering economic phosphate rock deposits. The search for and evaluation of phosphate rock resources in the countries of the Caribbean region would take about 5 years and cost an average of $15 million per country. The program is designed to begin with high risk-low cost steps and end with low risk-high cost steps. A successful program could improve the foreign exchange positions of countries in the Caribbean region by adding earnings from agricultural product exports and by substituting domestically produced phosphate rock and fertilizer products for imported phosphate fertilizers. A successful program also could provide enough domestically produced phosphorus fertilizer products to allow initiation of new agricultural technology in the region and thus increase domestic food production. Finally, a new phosphorus fertilizer industry would create new jobs in the mining, chemical, and transportation industries of the Caribbean region.

Circular↗

U.S. Geological Survey Science for the Wyoming Landscape Conservation Initiative - 2008 Annual Report

The Wyoming Landscape Conservation Initiative (WLCI) was launched in 2007 in response to concerns about threats to the State's world class wildlife resources, especially the threat posed by rapidly increasing energy development in southwest Wyoming. The overriding purpose of the WLCI is to assess and enhance aquatic and terrestrial habitats at a landscape scale, while facilitating responsible energy and other types of development. The WLCI includes partners from Federal, State, and local agencies, with participation from public and private entities, industry, and landowners. As a principal WLCI partner, the U.S. Geological Survey (USGS) provides multidisciplinary scientific and technical support to inform decisionmaking in the WLCI. To address WLCI management needs, USGS has designed and implemented five integrated work activities: (1) Baseline Synthesis, (2) Targeted Monitoring and Research, (3) Integration and Coordination, (4) Data and Information Management, and (5) Decisionmaking and Evaluation. Ongoing information management of data and products acquired or generated through the integrated work activities will ensure that crucial scientific information is available to partners and stakeholders in a readily accessible and useable format for decisionmaking and evaluation. Significant progress towards WLCI goals has been achieved in many Science and Technical Assistance tasks of the work activities. Available data were identified, acquired, compiled, and integrated into a comprehensive database for use by WLCI partners and to support USGS science activities. A Web-based platform for sharing these data and products has been developed and is already in use. Numerous map products have been completed and made available to WLCI partners, and other products are in progress. Initial conceptual, habitat, and climate change models have been developed or refined. Monitoring designs for terrestrial and aquatic indicators have been completed, pilot data have been collected for terrestrial indicators, and evaluations of alternative monitoring designs are underway. Initial models and map products have been developed for assessing vegetation, surface disturbance, oil and gas resources, mineral resources, surficial geology, invasive species, aspen treatments, ungulate migration corridors, greater sage-grouse (Centrocercus urophasianus), pygmy rabbits (Brachylagus idahoensis), and songbirds, and data were collected or compiled to validate and refine the models. Coordination and collaboration among partners has led to the production of several documents addressing WLCI objectives, strategies, and guiding principles, and has facilitated implementation of on-the-ground habitat treatments.

Open-File Report↗

Geologic studies in Alaska by the U.S. Geological Survey, 1997

The eight papers that follow continue the series of U.S. Geological Survey (USGS) reports on investigations in the geologic sciences in Alaska. The series presents new and sometimes preliminary findings that are of interest to earth scientists in academia, government, and industry; to land and resource managers; and to the general public. Reports presented in Geologic Studies in Alaska cover a broad spectrum of topics from all parts of the State (fig. 1), which serves to emphasize the diversity of USGS efforts to meet the Nation's needs for earth-science information in Alaska. The papers in this volume are organized under the topics Resources, Geologic Framework, and Environment and Climate. Such an organization is intended to reflect the scope and objectives of USGS programs currently active in Alaska. Resource papers include one that presents detailed observations from a Mississippian Zn-Pb-Cu-Ag occurrence in the Brooks Range (Werdon). Mineralogic, chemical, and isotopic data provide the basis for a proposed relationship between this vein-breccia deposit and the shale-hosted massive sulfide deposit type, which includes the active Red Dog mine in the western Brooks Range. Also included under the topic of Resources is a paper that presents geochemical and isotopic data from the Greens Creek and Woewodski Island volcanogenic massive sulfide deposits in southeastern Alaska (Newberry and Brew). The depositional environment and sedimentological setting of Tertiary coal beds in the Matanuska and Susitna Valleys is the focus of a third paper under the topic of Resources (Flores and others). Geologic Framework studies provide background information that is the scientific basis for present and future studies of the environment, mineral and energy resources, paleoclimate, and hazards in Alaska. One paper presents the results of sedimentologic and paleontologic comparisons of lower Paleozoic, deep-water-facies rock units in central Alaska (Dumoulin and others). The authors show which of these units are likely to correlate with one another, suggest likely source regions, and provide a structural restoration of units that have been fragmented by large fault motions. A second framework paper provides a map, rock descriptions, and chemical compositions of volcanic rocks in a newly recognized, geologically young volcanic center in the Aleutian volcanic arc (Hildreth and others). A third paper presents an interesting summary of gravity changes that occurred in south-central Alaska during the great earthquake of 1964 and for the following 25 years (Barnes). Gravity changes correlate with land-elevation changes in some cases, but not in others, which means that different processes are responsible for the gravity changes.

Alaska↗

Gold-bearing skarns

In recent years, a significant proportion of the mining industry's interest has been centered on discovery of gold deposits; this includes discovery of additional deposits where gold occurs in skarn, such as at Fortitude, Nevada, and at Red Dome, Australia. Under the classification of Au-bearing skarns, we have modeled these and similar gold-rich deposits that have a gold grade of at least 1 g/t and exhibit distinctive skarn mineralogy. Two subtypes, Au-skarns and byproduct Au-skarns, can be recognized on the basis of gold, silver, and base-metal grades, although many other geological factors apparently are still undistinguishable largely because of a lack of detailed studies of the Au-skarns. Median grades and tonnage for 40 Au-skarn deposits are 8.6 g/t Au, 5.0 g/t Ag, and 213,000 t. Median grades and tonnage for 50 byproduct and Au-skarn deposits are 3.7 g/t Au, 37 g/t Ag, and 330,000 t. Gold-bearing skarns are generally calcic exoskarns associated with intense retrograde hydrosilicate alteration. These skarns may contain economic amounts of numerous other commodities (Cu, Fe, Pb, Zn, As, Bi, W, Sb, Co, Cd, and S) as well as gold and silver. Most Au-bearing skarns are found in Paleozoic and Cenozoic orogenic-belt and island-arc settings and are associated with felsic to intermediate intrusive rocks of Paleozoic to Tertiary age. Native gold, electru, pyrite, pyrrhotite, chalcopyrite, arsenopyrite, sphalerite, galena, bismuth minerals, and magnetite or hematite are the most common opaque minerals. Gangue minerals typically include garnet (andradite-grossular), pyroxene (diopside-hedenbergite), wollastonite, chlorite, epidote, quartz, actinolite-tremolite, and (or) calcite.

Bulletin↗

Water Withdrawals, Use, and Trends in Florida, 2005

In 2005, the total amount of water withdrawals in Florida was estimated at 18,359 million gallons per day (Mgal/d). Saline water accounted for 11,486 Mgal/d (63 percent), and freshwater accounted for 6,873 Mgal/d (37 percent). Groundwater accounted for 4,247 Mgal/d (62 percent) of freshwater withdrawals, and surface water accounted for the remaining 2,626 Mgal/d (38 percent). Surface water accounted for nearly all (99.9 percent) saline-water withdrawals. An additional 660 Mgal/d of reclaimed wastewater was used in Florida during 2005. The largest amount of freshwater was withdrawn from Palm Beach County, and the largest amount of saline water was withdrawn from Pasco County. Fresh groundwater provided drinking water (public supplied and self-supplied) for 16.19 million people (90 percent of Florida's population), and fresh surface water provided drinking water for 1.73 million people (10 percent). The majority of groundwater withdrawals (nearly 60 percent) in 2005 was obtained from the Floridan aquifer system which is present throughout the entire State. The majority of fresh surface-water withdrawals (59 percent) came from the southern Florida hydrologic unit subregion and is associated with Lake Okeechobee and the canals in the Everglades Agricultural Area of Glades, Hendry, and Palm Beach Counties, as well as the Caloosahatchee River and its tributaries in the agricultural areas of Collier, Glades, Hendry, and Lee Counties. Overall, agricultural irrigation accounted for 40 percent of the total freshwater withdrawals (ground and surface), followed by public supply with 37 percent. Public supply accounted for 52 percent of groundwater withdrawals, followed by agricultural self-supplied (31 percent), ommercial-industrial-mining self-supplied (8.5 percent), recreational irrigation and domestic self-supplied (4 percent each), and power generation (0.5 percent). Agricultural self-supplied accounted for 56 percent of fresh surface-water withdrawals, followed by power generation (20.5 percent), public supply (13 percent), recreational irrigation (6 percent), and commercial-industrial self-supplied (4.5 percent). Power generation accounted for nearly all (99.9 percent) saline-water withdrawals. Of the 17.92 million people who resided in Florida during 2005, 41 percent (7.36 million people) resided in the South Florida Water Management District (SFWMD), followed by the St. Johns River Water Management District (SJRWMD) and the Southwest Florida Water Management District (SWFWMD) with 25 percent each (4.46 and 4.44 million people, respectively), the Northwest Florida Water Management District (NWFWMD) with 7.5 percent (1.34 million people), and the Suwannee River Water Management District (SRWMD) with 1.5 percent (0.32 million people). The largest amount of freshwater withdrawals was from the SFWMD, which was one-half (50 percent) of the State's total freshwater withdrawals, followed by the SJRWMD (19 percent), SWFWMD (16 percent), NWFWMD (10 percent), and SRWMD (5 percent). Between 1950 and 2005, the population of Florida increased by 15.15 million (550 percent), and the total water withdrawals (fresh and saline) increased 15,700 Mgal/d (600 percent). More recently, total withdrawals decreased 1,790 Mgal/d (9 percent) between 2000 and 2005, but the total population increased by 1.94 million (12 percent). Between 1990 and 2005, saline-water withdrawals increased 1,120 Mgal/d (11 percent), whereas between 2000 and 2005, saline-water withdrawals decreased 470 Mgal/d (4 percent). Between 1990 and 2005, freshwater withdrawals decreased 710 Mgal/d (9 percent), whereas between 2000 and 2005, freshwater withdrawals decreased 1,320 Mgal/d (16 percent). The use of highly mineralized groundwater as a source of supply, primarily for public supply, also has increased in Florida. This water, referred as nonpotable water, increased from just less than 2 Mgal/d in 1970, to 142 Mgal/d in 2005. Nonpotable water is treated to meet drin

Scientific Investigations Report↗

Vertical gradients in water chemistry in the central High Plains aquifer, southwestern Kansas and Oklahoma panhandle, 1999

The central High Plains aquifer is the primary source of water for domestic, industrial, and irrigation uses in parts of Colorado, Kansas, New Mexico, Oklahoma, and Texas. Water-level declines of more than 100 feet in some areas of the aquifer have increased the demand for water deeper in the aquifer. The maximum saturated thickness of the aquifer ranged from 500 to 600 feet in 1999. As the demand for deeper water increases, it becomes increasingly important for resource managers to understand how the quality of water in the aquifer changes with depth. In 1998?99, 18 monitoring wells at nine sites in southwestern Kansas and the Oklahoma Panhandle were completed at various depths in the central High Plains aquifer, and one monitoring well was completed in sediments of Permian age underlying the aquifer. Water samples were collected once from each well in 1999 to measure vertical gradients in water chemistry in the aquifer. Tritium concentrations measured in ground water indicate that water samples collected in the upper 30 feet of the aquifer were generally recharged within the last 50 years, whereas all of the water samples collected at depths more than 30 feet below the water table were recharged more than 50 years ago. Dissolved oxygen was present throughout the aquifer, with concentrations ranging from 1.7 to 8.4 mg/L. Water in the central High Plains aquifer was predominantly a calcium-bicarbonate type that exhibited little variability in concentrations of dissolved solids with depth (290 to 642 mg/L). Exceptions occurred in some areas where there had been upward movement of mineralized water from underlying sediments of Permian age and areas where there had been downward movement of mineralized Arkansas River water to the aquifer. Calcium-sulfate and sodium-chloride waters dominated and concentrations of dissolved solids were elevated (862 to 4,030 mg/L) near the base of the aquifer in the areas of upward leakage. Dissolution of gypsum or anhydrite and halite in sediments of Permian age by ground water was the likely source of calcium, sulfate, sodium, and chloride in those waters. Calcium-sodium-sulfate waters dominated, and concentrations of dissolved solids were as large as 4,916 mg/L near the water table in the area of downward leakage. Dissolution of minerals in sedimentary deposits of marine origin in upstream areas of the Arkansas River drainage were the likely sources of calcium, sodium, and sulfate in those waters. Nitrate was detected throughout the aquifer and the background concentration was estimated to be 2.45 mg/L as N. The largest nitrate concentrations (8.28, 22, and 54.4 mg/L as N) occurred in recently recharged water collected adjacent to irrigated fields. Three pesticides (atrazine, metolachlor, simazine) and five pesticide degradation products (alachlor ethanesulfonic acid, alachlor oxanilic acid, deethylatrazine, metolachlor ethanesulfonic acid, metolachlor oxanilic acid) were detected in recently recharged water from six water-table wells. Five of the six wells were adjacent to irrigated fields. These data indicate that concentrations of nitrate and pesticides increased over time in some areas of the aquifer as a result of agricultural activities. Results from this study indicate that vertical gradients in water chemistry existed in the central High Plains aquifer. The chemical gradients resulted from chemical inputs to the aquifer from underlying sediments of Permian age, from the Arkansas River, and from agricultural activities. In areas where those chemical inputs occurred, water quality in the aquifer was impaired and may not have been suitable for some intended uses.

Water-Resources Investigations Report↗

Hydrogeologic and water-quality characteristics of the Prairie du Chien-Jordan aquifer, Southeast Minnesota

Quality of water in the Prairie du Chien-Jordan aquifer is generally good, except for some localized contamination, Coal-tar derivatives that contaminate the aquifer in St. Louis Park, a western suburb in the Twin Cities Metropolitan Area, pose the most serious threat to water quality. High hardness and iron concentration limit suitability for municipal and industrial use in parts of extreme southeast Minnesota. Confining beds of bedrock and drift, however, protect most of the aquifer from surface pollutants. The Prairie du Chien-Jordan aquifer is part of a sequence of sedimentary bedrock units in southeast Minnesota. The Jordan Sandstone is a white to yellow, fine- to coarse-grained sandstone. The Prairie du Chien Group comprises two dolomitic formations that are vuggy and fractured and interbedded with thin layers of shale. The aquifer formations were deposited in Paleozoic seas that occupied the Hollandale embayment. The aquifer dips toward the interior of the embayment where it is as deep as 750 feet below land surface and as thick as 500 feet. Permeability is secondary in the Prairie du Chien Group because of solution cavities and fractures, and intergranular in the Jordan Sandstone. Water in the aquifer is confined except in the eastern part. Water generally flows to the north and east into the Minnesota and Mississippi Rivers. A ground-water divide separates part of the flow southward into Iowa. This aquifer supplies more water than any other bedrock one in the State. Calcium magnesium bicarbonate type water is most common in the aquifer. Calcium and sulfate and, to a lesser degree sodium and magnesium, increase in concentration toward the southwestern part of the study area. Bicarbonate concentration, on the other hand, decreases toward the southwestern corner of the study area. Leakage from overlying Cretaceous deposits is the source of much of the sulfate and other minerals in the southwest. This report is one of a series on the hydrogeology and water quality of the 14 principal aquifers in Minnesota prepared by the U. S. Geological Survey. The U. S. Environmental Protection Agency requested these studies because of the need for information to develop its Underground Injection Control Program.

Minnesota↗

Barite (Barium)

Barite (barium sulfate, BaSO 4 ) is vital to the oil and gas industry because it is a key constituent of the mud used to drill oil and gas wells. Elemental barium is an additive in optical glass, ceramic glazes, and other products. Within the United States, barite is produced mainly from mines in Nevada. Imports in 2011 (the latest year for which complete data were available) accounted for 78 percent of domestic consumption and came mostly from China. Barite deposits can be divided into the following four main types: bedded-sedimentary; bedded-volcanic; vein, cavity-fill, and metasomatic; and residual. Bedded-sedimentary deposits, which are found in sedimentary rocks with characteristics of high biological productivity during sediment accumulation, are the major sources of barite production and account for the majority of reserves, both in the United States and worldwide. In 2013, China and India were the leading producers of barite, and they have large identified resources that position them to be significant producers for the foreseeable future. The potential for undiscovered barite resources in the United States and in many other countries is considerable, however. The expected tight supply and rising costs in the coming years will likely be met by increased production from such countries as Kazakhstan, Mexico, Morocco, and Vietnam. Barium has limited mobility in the environment and exposed barium in the vicinity of barite mines poses minimal risk to human or ecosystem health. Of greater concern is the potential for acidic metal-bearing drainage at sites where the barite ores or waste rocks contain abundant sulfide minerals. This risk is lessened naturally if the host rocks at the site are acid-neutralizing, and the risk can also be lessened by engineering measures.

Professional Paper↗

Design approaches in quarrying and pit-mining reclamation

Reclaimed mine sites have been evaluated so that the public, industry, and land planners may recognize there are innovative designs available for consideration and use. People tend to see cropland, range, and road cuts as a necessary part of their everyday life, not as disturbed areas despite their high visibility. Mining also generates a disturbed landscape, unfortunately one that many consider waste until reclaimed by human beings. The development of mining provides an economic base and use of a natural resource to improve the quality of human life. Equally important is a sensitivity to the geologic origin and natural pattern of the land. Wisely shaping out environment requires a design plan and product that responds to a site's physiography, ecology, function, artistic form, and publication perception. An examination of selected sites for their landscape design suggested nine approaches for mining reclamation. The oldest design approach around is nature itself. Humans may sometimes do more damage going to an area in the attempt to repair it. Given enough geologic time, a small-site area, and stable adjacent ecosystems, disturbed areas recover without mankind's input. Visual screens and buffer zones conceal the facility in a camouflage approach. Typically, earth berms, fences, and plantings are used to disguise the mining facility. Restoration targets social or economic benefits by reusing the site for public amenities, most often in urban centers with large populations. A mitigation approach attempts to protect the environment and return mined areas to use with scientific input. The reuse of cement, building rubble, macadam meets only about 10% of the demand from aggregate. Recognizing the limited supply of mineral resources and encouraging recycling efforts are steps are steps in a renewable resource approach. An educative design approach effectively communicates mining information through outreach, land stewardship, and community service. Mine sites used for art show a celebration of beauty and experience -- abstract geology. The last design approach combines art and science in a human-nature ecosystem termed integration. With environmental concerns, an operating or reclaimed mine site can no longer be considered isolated from its surroundings. Site analysis of mine works needs to go beyond site-specific information and relate to the regional context of the greater landscape. Understanding design approach can turn undesirable features (mines and pits) into something perceived as desirable by the public.

Book↗

Weight of Production of Emeralds, Rubies, Sapphires, and Tanzanite from 1995 Through 2005

U.S. Geological Survey (USGS) historically has not attempted to report comprehensive world production of gemstones on a country basis. This was because estimation of gemstone production is inherently difficult due to the fragmentary nature of the industry, the lack of governmental oversight or reporting in many countries where colored gemstones are mined, and the wide variation in quality between individual gemstones. Unlike diamonds, which, with the exception of the alluvial stones of West Africa, are mainly produced by large international mining companies and evaluated, cut, and marketed through a highly developed pricing structure and complex commercial arrangements, colored gemstones are mainly mined by individuals or small companies and have less developed evaluation and marketing arrangements. The trading centers for colored gems are smaller and less well known than the diamond centers. Colored gemstones, like alluvial diamonds, have the potential to be used to fund civil conflicts and other illegal activities, and because trade in colored gemstones is less organized than that of diamonds, they offer less opportunity for effective regulation of their trade. And, like diamond, until the recent advent of the Kimberley Process no generally accepted estimates of colored gemstone production globally or by producing country have existed. The present paper is a first attempt to develop production statistics for the three precious gems - emeralds , rubies , and sapphires - and tanzanite tanzanite, a semi-precious gem. The data consist of the weight of production of each of the gemstones from 1995 through 2005. Preliminary data on the weights of gemstone production were presented as a poster session at the Gemological Institute of America's Gemological Research Conference in San Diego, CA, in 2006, and as a published abstract (Yager, 2006) in an attempt to gather response to the estimates. The USGS continues to welcome information and suggestions that would improve the data presented here. Information used to make the production estimates presented in this paper include annual USGS Mineral Questionnaires completed by producing countries, data on exports from producing countries, reports from the literature, and company reports. Comparisons of the weight and the value of production of a type of gemstone between countries may differ considerably. Whereas east African countries dominate the weight production of rubies, Burma (Myanmar) is widely thought to have the highest value of ruby production. Data on the value of gemstone production are even more difficult to estimate than is the weight of production. Value of production is dependent upon both the quality and the sizes of the stones produced. Such data are not readily available and are difficult to estimate; therefore this report does not present tables of values of production. Instead, the report briefly discusses the forms in which gemstones are sold, the systems used to value the gemstones, and selected data that illustrate the variability of value of gemstones of a particular type.

Open-File Report↗

Summary appraisals of the nation's ground-water resources – Upper Colorado region

The Upper Colorado Region covers about 113,500 square miles (293,965 km 2 ) in parts of Arizona, Colorado, New Mexico, Utah, and Wyoming. Drainage from about 97 percent of the region is to the Colorado River. About 60 percent of the land is owned or administered by the Federal Government, and another 15 percent is in Indian trust. The predominantly arid to semiarid region is sparsely populated (averaging about three persons per square mile, or about two and one-half persons per km 2 ) and is used chiefly for grazing, recreation, and mineral development. The water supply for the region comes from precipitation within the region, which averages about 95 million acre-feet (117,182.5 hm 3 ) per year. Development of the region's water supply has been limited almost entirely to surface water. Only about 2 percent of the total estimated volume of water withdrawn (about 5.7 million acre-ft, or 7,030.9 hm 3 ) and consumed (about 3.6 million acre-ft, or 4,440.6 hm 3 ) in the region in 1970 came directly from ground-water sources. By the year 2020 consumptive use of water within the region and water exports to adjacent regions are expected to total more than 6.5 million acre-feet (8,017.8 hm 3 ) per year. Use of the ground-water resources of the Upper Colorado Region in water-resources management can help to meet these water needs. A tremendous amount of water is stored in the rocks (ground-water reservoirs) of the Upper Colorado Region. Recoverable water in just the upper 100 feet (30.5 m) of saturated rocks is estimated to be as much as 115 million acre-feet (141,852.5 hm 3 ). That amount is nearly four times the total active storage capacity of all surface-water reservoirs in the region. The average annual replenishable supply of the ground-water reservoir is about 4 million acre-feet (4,934 hm 3 ). This amount of water could irrigate about 1.3 million acres (526,1,10 ha) of crops having an annual water requirement of 3 feet per acre (0.9 m/ha), or it could provide about 3,600 million gallons (13,627,440 m 3 ) per day for industrial use. Most of the ground water is in consolidated rocks, which generally yield water to wells slowly. Much of the ground water is saline and, in some places, occurs at great depths. Nevertheless, the ground water is more uniformly distributed than is surface water, both areally and with time; therefore, it can be used advantageously in overall waterresources management. Recent advancements in the field of demineralization and in evaluation and development of ground water make this possible. Options available for use of ground water in water-resources management·in the·region include conjunctive use with surface water or development of ground water as an independent supply. The latter option could be for & perennial supply or for a time-limited supply (mining ground water), depending on the need and the existing ground-water conditions. All options can be carried out so as to meet the requirements of the Colorado River Compact. The options could be implemented to optimally develop the Upper Colorado River Basin's allocation of Colorado River water while meeting the Compact commitments to the Lower Basin.

Arizona, Colorado, New Mexico, Utah, Wyoming↗

Vertical gradients in water chemistry and age in the Northern High Plains Aquifer, Nebraska, 2003

The northern High Plains aquifer is the primary source of water used for domestic, industrial, and irrigation purposes in parts of Colorado, Kansas, Nebraska, South Dakota, and Wyoming. Despite the aquifer’s importance to the regional economy, fundamental ground-water characteristics, such as vertical gradients in water chemistry and age, remain poorly defined. As part of the U.S. Geological Survey’s National Water-Quality Assessment Program, water samples from nested, short-screen monitoring wells installed in the northern High Plains aquifer were analyzed for major ions, nutrients, trace elements, dissolved organic carbon, pesticides, stable and radioactive isotopes, dissolved gases, and other parameters to evaluate vertical gradients in water chemistry and age in the aquifer. Chemical data and tritium and radiocarbon ages show that water in the aquifer was chemically and temporally stratified in the study area, with a relatively thin zone of recently recharged water (less than 50 years) near the water table overlying a thicker zone of older water (1,800 to 15,600 radiocarbon years). In areas where irrigated agriculture was an important land use, the recently recharged ground water was characterized by elevated concentrations of major ions and nitrate and the detection of pesticide compounds. Below the zone of agricultural influence, major-ion concentrations exhibited small increases with depth and distance along flow paths because of rock/water interactions. The concentration increases were accounted for primarily by dissolved calcium, sodium, bicarbonate, sulfate, and silica. In general, the chemistry of ground water throughout the aquifer was of high quality. None of the approximately 90 chemical constituents analyzed in each sample exceeded primary drinking-water standards. Mass-balance models indicate that changes in groundwater chemistry along flow paths in the aquifer can be accounted for by small amounts of feldspar and calcite dissolution; goethite and clay-mineral precipitation; organic-carbon and pyrite oxidation; oxygen reduction and denitrification; and cation exchange. Mixing with surface water affected the chemistry of ground water in alluvial sediments of the Platte River Valley. Radiocarbon ages in the aquifer, adjusted for carbon mass transfers, ranged from 1,800 to 15,600 14C years before present. These results have important implications with respect to development of ground-water resources in the Sand Hills. Most of the water in the aquifer predates modern anthropogenic activity so excessive removal of water by pumping is not likely to be replenished by natural recharge in a meaningful timeframe. Vertical gradients in ground-water age were used to estimate long-term average recharge rates in the aquifer. In most areas, the recharge rates ranged from 0.02 to 0.05 foot per year. The recharge rate was 0.2 foot per year in one part of the aquifer characterized by large downward hydraulic gradients. Nitrite plus nitrate concentrations at the water table were 0.13 to 3.13 milligrams per liter as nitrogen, and concentrations substantially decreased with depth in the aquifer. Dissolved-gas and nitrogen-isotope data indicate that denitrification in the aquifer removed 0 to 97 percent (average = 50 percent) of the nitrate originally present in recharge. The average amount of nitrate removed by denitrification in the aquifer north of the Platte River (Sand Hills) was substantially greater than the amount removed south of the river (66 as opposed to 0 percent), and the extent of nitrate removal appears to be related to the presence of thick deposits of sediment on top of the Ogallala Group in the Sand Hills that contained electron donors, such as organic carbon and pyrite, to support denitrification. Apparent rates of dissolved-oxygen reduction and denitrification were estimated on the basis of decreases in dissolved-oxygen concentrations and increases in concentrations of excess nitrogen gas and ground-water ages along flow paths from the water table to deeper wells. Median rates of dissolved-oxygen reduction and denitrification south of the Platte River were at least 10 times smaller than the median rates north of the river in the Sand Hills. The relatively large denitrification rates in the Sand Hills indicate that the aquifer in that area may have a greater capacity to attenuate nitrate contamination than the aquifer south of the river, depending on rates of ground-water movement in the two areas. Small denitrification rates south of the river indicate that nitrate contamination in that part of the aquifer would likely persist for a longer period of time.

Nebraska↗

An open-water electrical geophysical tool for mapping sub-seafloor heavy placer minerals in 3D and migrating hydrocarbon plumes in 4D

A towed-streamer technology has been developed for mapping placer heavy minerals and dispersed hydrocarbon plumes in the open ocean. The approach uses induced polarization (IP), an electrical measurement that encompasses several different surface-reactive capacitive and electrochemical phenomena, and thus is ideally suited for mapping dispersed or disseminated targets. The application is operated at sea by towing active electrical geophysical streamers behind a ship; a wide area can be covered in three dimensions by folding tow-paths over each other in lawn-mower fashion. This technology has already been proven in laboratory and ocean settings to detect IP-reactive titanium- and rare-earth (REE) minerals such as ilmenite and monazite. By extension, minerals that weather and accumulate/concentrate by a similar mechanism, including gold, platinum, and diamonds, may be rapidly detected and mapped indirectly- even when dispersed and covered with thick, inert sediment. IP is also highly reactive to metal structures such as pipelines and cables. Currently, the only means for mapping an oil-spill plume is to park a large ship in the ocean and drop a sampling string over the side, requiring hours of time per sampling point. The samples must then be chemically analyzed, adding additional time and expense. We believe that an extension of the marine IP technology could also apply to rapidly mapping both seafloor- blanket and disseminated hydrocarbon plumes in the open ocean, as hydrocarbon droplets in conductive seawater are topologically equivalent to a metal-plates-and-dielectric capacitor. Because the effective capacitance would be frequency-dependent on droplet size, the approach we advocate holds the potential to not only map, but also to characterize the evolution and degradation of such a plume over time. In areas where offshore oil field development has been practiced for extended periods, making IP measurements from a towed streamer may be useful for locating buried - nd exposed pipelines, as well as pipeline leaks. We believe this technique will be a more cost-effective method than drop-sampling to map and monitor hydrocarbon plumes in open ocean settings. A marine induced polarization system was used successfully to map a 15 km × 45 km swath of the ocean floor off eastern South Africa with 3-meter sampling along 200-meter-separated profiles. The survey detected titanium-bearing sands up to 15 meters below the seafloor. From preliminary laboratory work it is apparent that we can extend this technology to monitor significant environmental problems including anthropogenic and industrial waste washed into sensitive estuaries and sounds during storm-water runoff episodes, and also to map and characterize dispersed oil plumes in the seawater column in three dimensions, as well as movement and dispersal of both over time.

Conference Paper↗

Ground-water resources and geology of Colquitt County, Georgia

Limestone beds of Eocene, Oligocene, and lower Miocene age, called the principal artesian aquifer, are the chief source of ground water for Colquitt County. Because streams are small, undependable and relatively inaccessible to most users, ground water is the most important source for increased industrial and agricultural water use. Southeast of Moultrie the principal artesian aquifer is very productive, and has transmissivity in excess of 145,000 feet squared per day (13,500 meters squared per day). A structural or paleogeographic feature called the Suwannee strait traverses the county from near the southwest corner to the northeast corner. In this strait, limestone in the principal artesian aquifer is partly replaced by fine-grained clastic sediment, impairing transmissivity and making wells hard to construct. Transmissivity is much lower northwest of the strait than it is southeast, probably because of facies changes in the aquifer. In the belt of the hypothesized Ochlockonee fault, water containing greater-than-usual concentrations of dissolved solids is produced. This anomaly could be the result of the fault having acted as a conduit when the vertical hydraulic gradient was upward from a deeper aquifer, or be the result of the movement of ground water from a sulfate-rich source in the sediments of the Suwannee strait. In south-central Colquitt County, clay-capped permeable beds extending above potentiometric surfaces create conditions favorable for breathing wells. Predominantly clastic beds of Miocene age overlie the Suwannee Limestone. These beds have a transmissivity of about 2,280 feet squared per day (215 meters squared per day), but they are of comparatively little importance because larger yields can be obtained from the underlying principal artesian aquifer. Moreover, wells are difficult to construct in the poorly consolidated clastic sediments, and water from these shallow beds is likely to be depleted during droughts. The ground water is generally hard, but is otherwise of good quality. One exception is near the hypothesized Ochlockonee fault where water contains higher-than-usual concentrations of various ions, especially sulfate. Another exception occurs along the axis of the Suwannee strait where clay minerals in the channel facies may soften the water by ion exchange.

Georgia↗

Water resources inventory of Connecticut Part 10: Lower Connecticut River basin

The lower Connecticut River basin study area in south-central Connecticut includes 639 square miles and is drained principally by the Connecticut River and by seven smaller streams that flow directly to Long Island Sound between the West River on the west and the Connecticut River on the east. The population in 1979 was estimated to be 210,380. Much of the industrial development and population centers are in the Mattabesset River basin in the northwestern part, and the largest water use is also in the Mattabesset River basin. Precipitation averages 47 inches per year and provides an abundant supply of water. About 20 inches returns to the atmosphere as evapotranspiration, and the remainder either flows directly to streams or percolates to the water table, eventually discharging to Long Island Sound. Small quantities of water are exported from the basin by the New Haven and Meridan Water Departments, and small quantities are imported by the New Britain Water Department and Metropolitan Direct Commission. Precipitation during 1931-60 resulted in an average annual runoff of 302 billion gallons. In inflow from the Connecticut River is added to the average annual runoff, the 4,370 billion gallon s per year is potentially available for water ue. The domestic, institutional, commercial, and industrial (other than cooling water) water use for 1970 was 7 billion gallons, which is only 3 percent of the total water used, whereas 97 percent of the total is cooling water for power plants. Approximately 60 percent of the 7 billion gallons is treated before being discharged back to the streams. The total amount of fresh water used during 1970 was estimated to be 256,000 million gallons (Mgal), of which 247,000 Mgal was used for cooling water at stream electric-generating plants. The quantity for domestic, commercial, industrial, and agricultural used was 9,000 Mgal, which was approximately 120 gallons a day per person. Public water systems providing 70 percent of these requirement and all the systems supplying water met the drinking water standards of the Connecticut General Assembly (1975). Till is widespread and generally provides only small amounts of water. Wells in till normally yield only a few hundred gallons of water daily and may be inadequate during dry periods. The thickness of of till ranges from 0 to 15 feet; a median thickness of 26 feet is estimated from information provided in drillers' logs of 467 wells penetrating underlying bedrock. The till is generally used only as an emergency or secondary source of water. Bedrock aquifers underlie the entire area and include sedimentary and crystalline (igneous and metamorphic) rock types. These aquifers supply small and usually reliable quantities of water to wells and are the chief source of water for many rural homes and farms., About 90 percent of the wells tapping bedrock yield at least 2 gal/min. The median yields from wells tapping aquifers in sedimentary, igneous, and metamorphic rocks are 11, 8, and 6.5 gal/min, respectively. The quantity of water potentially available from stratified drift was estimated on the basis of hydraulic characteristics of the aquifers, mathematical modeling of the aquifer system, and evaluation of natural and induced recharge. Long-term yields estimated or ten areas underlain by significant thickness of stratified drift range from 0.4 to 4.4 million gallons per day (Mgal/d). A change in well spacing or numbering could increase the long-term yields, but detailed modeling verification studies are needed to confirm optimal well locations. The chemical and physical (turbidity, color, taste, and sediment load) quality of water is good. The water if generally low in dissolved solids and is classified as soft to hard. Surface water is less mineralized than ground water, especially during high flow, when it is primarily derived from surface runoff rather than groundwater runoff. A median dissolved-solids concentration of 42 milligrams per liter (mg/L) and median hardness of 18 mg/L were determined from water samples collected from 26 streams during the high-flow period. During the low-flow period, median dissolved-solids concentration of 61 mg/L and median hardness of 27 mg/L were determined from sample from the same streams. The quality of water in stratified-drift and crystalline-rock aquifers is generally better than that in the sedimentary-rock aquifers. Water from 32 wells tapping stratified drift had median dissolved-solids concentrations of 116 mg/L; and 33 wells tapping stratified drift and 42 tapping crystalline rock had median hardness of 73 mg/L and 68 mg/L, respectively. Water from 32 wells tapping sedimentary rock had median dissolved concentrations of 231 and 156 mg/L, respectively. Sedimentary rock generally yields the hardest water. Iron and manganese occur objectionable concentrations in places, particularly in water from streams draining swamps and in water from aquifers either rich in iron and manganese-nearing minerals or where the reducing environment for solution of these minerals is favorable. Concentrations of iron in excess of 0.3 mg/L were found in 35 percent of the high streamflow samples, and in 45 percent of the ground-water samples. Most of the high iron and manganese concentration in streams and aquifers are found east of the Connecticut River. Human activities and tidal influence along the coast have modified the quality of water in much f the study area. The greatest influence from human activities has been in the northwestern part, in the Mattabesset River basin. There, the quality of water has been affected by domestic and animal wastes, which cause high dissolved-solids concentrations, high nitrate and phosphate loads and high bacterial counts. In the entire area, high nitrate in groundwater occur only locally, and its presence in an individual water supply is chiefly a function of its proximity to sources of contamination, of well construction, and of thickness of overburden. Thirty public-supply wells did have water that had high sodium concentrations or objectionable iron and manganese concentrations, but these are not considered health hazards in the concentrations found in the water samples. Streams, wetlands, and some aquifers along the sough boundary of the basin contain salty water because of tidal movement or extensive ground-water withdrawals. High sediment concentrations also occur as a result of tidal influence in this area.

Connecticut↗

Diel biogeochemical processes in terrestrial waters

Many biogeochemical processes in rivers and lakes respond to the solar photocycle and produce persistent patterns of measureable phenomena that exhibit a day–night, or 24-h, cycle. Despite a large body of recent literature, the mechanisms responsible for these diel fluctuations are widely debated, with a growing consensus that combinations of physical, chemical, and biological processes are involved. These processes include streamflow variation, photosynthesis and respiration, plant assimilation, and reactions involving photochemistry, adsorption and desorption, and mineral precipitation and dissolution. Diel changes in streamflow and water properties such as temperature, pH, and dissolved oxygen concentration have been widely recognized, and recently, diel studies have focused more widely by considering other constituents such as dissolved and particulate trace metals, metalloids, rare earth elements, mercury, organic matter, dissolved inorganic carbon (DIC), and nutrients. The details of many diel processes are being studied using stable isotopes, which also can exhibit diel cycles in response to microbial metabolism, photosynthesis and respiration, or changes in phase, speciation, or redox state. In addition, secondary effects that diel cycles might have, for example, on biota or in the hyporheic zone are beginning to be considered. This special issue is composed primarily of papers presented at the topical session “Diurnal Biogeochemical Processes in Rivers, Lakes, and Shallow Groundwater” held at the annual meeting of the Geological Society of America in October 2009 in Portland, Oregon. This session was organized because many of the growing number of diel studies have addressed just a small part of the full range of diel cycling phenomena found in rivers and lakes. This limited focus is understandable because (1) fundamental aspects of many diel processes are poorly understood and require detailed study, (2) the interests and expertise of individual scientists typically do not encompass the wide diversity and range of processes that produce diel cycles, and (3) the logistics of making field measurements for 24-h periods has limited recognition and understanding of these important cycles. Thus, the topical session brought together hydrologists, biologists, geochemists, and ecologists to discuss field studies, laboratory experiments, theoretical modeling, and measurement techniques related to diel cycling. Hopefully with the cross-disciplinary synergy developed at the session as well as by this special issue, a more comprehensive understanding of the interrelationships between the diel processes will be developed. Needless to say, understanding diel processes is critical for regulatory agencies and the greater scientific community. And perhaps more importantly, expanded knowledge of biogeochemical cycling may lead to better predictions of how aquatic ecosystems might react to changing conditions of contaminant loading, eutrophication, climate change, drought, industrialization, development, and other variables.

Chemical Geology↗