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Diamond-drill exploration of the Rousseau talc prospect, Cambridge, Vermont, and the Barnes Hill prospect, Waterbury, Vermont

The Geological Survey carried out a program of diamond-drilling at two localities in Vermont during the period July-September 1950. The deposits chosen for drilling were two of the more promising talc deposits associated with ultramafic rocks of several that had been mapped earlier by the Geological Survey, but could not be evaluated accurately because critical data were lacking that could be obtained only by sub-surface exploration. The Rousseau talc prospect is in Cambridge township, Lamoille County, Vermont. Surface rights are owned by L. and N. N. Porter; mineral rights are owned by Eastern Magnesia Talc Co. Three drill holes encountered no talc; the other five penetrated from 2 to 110 feet of talc ore. The deposit lies on the west limb of the Green Mountain anticlinorium. The country rock consists of quartz-chlorite-sericite schist and chlorite-albite schist. The schistosity strikes slightly west of north and dips 20° - 40° to the west. The talc deposit is roughly lenticular, and although generally concordant in detail with the schistosity of the country rock, is slightly cross-cutting in overall relationship. The entire deposit is composed of Tit (talc-carbonate rock) and steatite, out is presumably derived from ultramafic igneous rooks which were first serpentinized. The dimensions of the lens are about 700 feet by 500 feet by 130 feet. The talc is of good quality and is suitable, either as a mine run product or as a flotation concentrate, for most industrial uses other than industrial steatite. No pencil stock was encountered. The Barnes hill talc prospect is in Waterbury township, Washington County, Vermont. Surface rights are divided among Donald P. and Glenola Brown, John Barnes, and Eastern Magnesia Talc Co. One drill hole at Barnes hill was barren. The other six penetrated about 20 to 140 feet of talc ore. The deposit lies on the east limb of the Green Mountain anticlinorium. The country rock outside of the ultramafic rock body consists of quartz-chlorite-sericite schist, chlorite-albite schist; and chlorite amphibolite, which strike generally about N, 20° E. and dip steeply to the east. The ultramafic body is elliptical in plan, about 1,600 feet long and 360 feet wide. The vertical dimension is unknown. The original ultramafic rock has been almost completely serpentinized and is extensively altered to grit and steatite. The talc ore is somewhat irregularly distributed throughout the ultramafic body, but it is possible to delineate with considerable confidence portions of the body that consist predominantly of ore. The largest ore bodies are in the eastern and northern parts of the ultramafic body. The ore contains more or less admixed serpentine, and so is only of intermediate to fairly good color (whiteness). It is suitable for many industrial uses in which purity and high whiteness are not necessary. No pencil stock was seen.

Vermont↗

Impacts of petroleum production on ground and surface waters: Results from the Osage-Skiatook Petroleum Environmental Research A site, Osage County Oklahoma

Kharaka has been a research hydrogeochemist with the U.S. Geological Survey since1975. His current research covers the fields of water-rock-gas interactions, CO 2 sequestration, contamination from agricultural drainage and petroleum produced water, and fluid-fault interactions. Kharaka has authored more than 100 scientific papers and book chapters and has delivered about 200 presentations. He received his Ph.D. from the University of California, Berkeley, in 1971. Thordsen is a geologist, employed with the U.S. Geological Survey since 1981 and presently working in the project team Hydrogeochemistry of Fine Grained Sediments, in the Water Resources Division, National Research Program. His recent research covers water-rock interactions and geochemical modeling in geothermal systems, fault-fluid systems, and petroleum produced water brine impacts. He received his M.S. in geology from the Ohio State University in 1988. Kakouros has been a hydrogeologist in the U.S. Geological Survey Water Resources Division in Menlo Park, California, since 1999. His current research covers the fields of Se contamination from agricultural drainage, CO 2 sequestration, and contamination from petroleum and petroleum-produced water. Kakouros received his M.Sc. from the San Jose State University in 2001. Herkelrath is a physicist in the U.S. Geological Survey's Water Resources Division National Research Program in Menlo Park, California. Herkelrath received his Ph.D. in physics from the University of Wisconsin at Madison. His recent research interests include multiphase flow and solute transport modeling in shallow ground-water systems where oil or brine is present.

Oklahoma↗

Chapter 5. Assessment of undiscovered conventional oil and gas resources-Lower Cretaceous Travis Peak and Hosston formations, Jurassic Smackover interior salt basins total petroleum system, in the East Texas basin and Louisiana-Mississippi salt basins provinces

The Lower Cretaceous Travis Peak Formation of east Texas and southern Arkansas (and the correlative Hosston Formation of Louisiana and Mississippi) is a basinward-thickening wedge of terrigenous clastic sedimentary rocks that underlies the northern Gulf of Mexico Basin from east Texas across northern Louisiana to southern Mississippi. Clastic detritus was derived from two main fluvial-deltaic depocenters, one in northeastern Texas and the other extending from southeastern Mississippi northwestward into northeastern Louisiana. Across the main hydrocarbon-productive trend in east Texas and northern Louisiana, the Travis Peak and Hosston Formations are about 2,000 ft thick. The most likely sources for hydrocarbons in Travis Peak and Hosston reservoirs are two stratigraphically lower units, lime mudstones of the Upper Jurassic Smackover Formation and organic-rich shales of the Upper Jurassic Bossier Shale of the Cotton Valley Group. As a result of the absence of proximal source rocks and a lack of effective migration pathways from stratigraphically or geographically distant source rocks, hydrocarbon charge is sufficient for development of conventional gas accumulations but insufficient for development of basin-centered gas. The petroleum assessment of the Travis Peak and Hosston Formations was conducted by using a total petroleum system model. A total petroleum system includes all of the important elements of a hydrocarbon fluid system needed to develop oil and gas accumulations, including source and reservoir rocks, hydrocarbon generation, migration, traps and seals, and undiscovered accumulations. A total petroleum system is mappable and may include one or more assessment units. For each assessment unit, reservoir rocks contain similar geology, exploration characteristics, and risk. The Jurassic Smackover Interior Salt Basins Total Petroleum System is defined for this assessment to include (1) Upper Jurassic Smackover carbonates and calcareous shales and organic-rich shales of the Upper Jurassic Bossier Shale of the Cotton Valley Group and (2) Lower Cretaceous Travis Peak and Hosston Formations. The Jurassic Smackover Interior Salt Basins Total Petroleum System includes three conventional Travis Peak-Hosston assessment units: Travis Peak-Hosston Gas and Oil (AU 50490205), Travis Peak-Hosston Updip Oil (AU 50490206), and Travis Peak-Hosston Hypothetical Updip Oil (AU 50490207). A fourth assessment unit, the Hosston Hypothetical Slope-Basin Gas Assessment Unit, was named and numbered (AU 50490208) but not geologically defined or quantitatively assessed owing to a lack of data. Together, assessment units 50490205 to 50490207 are estimated to contain a mean undiscovered conventional resource of 29 million barrels of oil, 1,136 billion cubic feet of gas, and 22 million barrels of natural gas liquids.

Alabama, Arkansas. Florida, Georgia, Louisiana, Mi↗

Aquifers of Arkansas: protection, management, and hydrologic and geochemical characteristics of groundwater resources in Arkansas

Sixteen aquifers in Arkansas that currently serve or have served as sources of water supply are described with respect to existing groundwater protection and management programs, geology, hydrologic characteristics, water use, water levels, deductive analysis, projections of hydrologic conditions, and water quality. State and Federal protection and management programs are described according to regulatory oversight, management strategies, and ambient groundwater-monitoring programs that currently (2013) are in place for assessing and protecting groundwater resources throughout the State. Physical attributes, groundwater geochemistry, and groundwater quality are described for each of the 16 aquifers of the State. Information in regard to the hydrology and geochemistry of each of the aquifers is summarized from about 550 historical and recent publications. Additionally, more than 8,000 sites with groundwater-quality data were obtained from the U.S. Geological Survey National Water Information System and the Arkansas Department of Environmental Quality databases and entered into a spatial database to investigate distribution and trends in chemical constituents for each of the aquifers. The 16 aquifers of the State were divided into two major physiographic regions of the State: the Coastal Plain Province (referred to as Coastal Plain) of eastern and southern Arkansas, which includes 11 of the 16 aquifers, and the Interior Highlands Division (referred to as Interior Highlands) of western Arkansas, which includes the remaining 5 aquifers. The 11 aquifers in the Coastal Plain consist of various geologic units that are Cenozoic in age and consist primarily of Cretaceous, Tertiary, and Quaternary sands, gravels, silts, and clays. Groundwater in the Coastal Plain represents one of the most valuable natural resources in the State, driving the economic engines of agriculture, while also supplying abundant water for commercial, industrial, and public-supply use. In terms of age from youngest to oldest, the aquifers of the Coastal Plain include Quaternary alluvial aquifers, including the Mississippi River Valley alluvial aquifer (the most important aquifer in Arkansas in terms of volume of use and economic benefits), the Jackson Group (a regional confining unit that served for decades as an important source of domestic supply), and the Cockfield, Sparta, Cane River, Carrizo, Wilcox, Nacatoch, Ozan, Tokio, and Trinity aquifers. The Mississippi River Valley alluvial aquifer accounts for approximately 94 percent of all groundwater used in the State, and the aquifer is used primarily for irrigation purposes. The Sparta aquifer is the second most important aquifer in terms of use, and the aquifer was used in the past dominantly as a source of public and industrial supply, although increasing irrigation use is occurring because of critically declining water levels in the Mississippi River Valley alluvial aquifer. Other aquifers of the Coastal Plain generally are used as important local sources of domestic, industrial, and public supply, in addition to other minor uses. Water quality generally is good for all aquifers of the Coastal Plain, except for elevated iron concentrations and localized areas of high salinity. The high salinity results from intrusion from underlying formations, evapotranspiration processes in areas of low recharge, and inadequate flushing in downgradient areas of residual salinity from deposition in marine environments. Trends in the spatial distribution of individual chemical constituents are related to position along the flow path for most aquifers of the Coastal Plain. These trends include elevated iron and nitrate concentrations with lower pH values and dissolved solids in groundwater from the outcrop areas, transitioning to lower iron and nitrate (related to changes in redox) and higher pH and dissolved solids (dominantly from the dissolution of carbonate minerals) in groundwater downgradient from outcrop areas. Groundwater generally trended from a calcium- to a sodium-bicarbonate water type with increasing cation exchange along the flow path. The Interior Highlands of western Arkansas has less reported groundwater use than other areas of the State, reflecting a combination of factors. These factors include prevalent and increasing use of surface water, less intensive agricultural uses, lower population and industry densities, lesser potential yield of the resource, and lack of detailed reporting. The overall low yields of aquifers of the Interior Highlands result in domestic supply as the dominant use, with minor industrial, public, and commercial-supply use. Where greater volumes are required for growth of population and industry, surface water is the greatest supplier of water needs in the Interior Highlands. The various aquifers of the Interior Highlands generally occur in shallow, fractured, well-indurated, structurally modified bedrock of this mountainous region of the State, as compared to the relatively flat-lying, unconsolidated sediments of the Coastal Plain. In terms of age from youngest to oldest, the aquifers of the Interior Highlands include: the Arkansas River Valley alluvial aquifer, the Ouachita Mountains aquifer, the Western Interior Plains confining system, the Springfield Plateau aquifer, and the Ozark aquifer. Spatial trends in groundwater geochemistry in the Interior Highlands differ greatly from trends noted for aquifers of the Coastal Plain. In the Coastal Plain, the prevalence of long regional flow paths results in regionally predictable and mappable geochemical changes along the flow paths. In the Interior Highlands, short, topographically controlled flow paths (from hilltops to valleys) within small watersheds represent the predominant groundwater-flow system. As such, dense data coverage from numerous wells would be required to effectively characterize these groundwater basins and define small-scale geochemical changes along any given flow path for aquifers of the Interior Highlands. Changes in geochemistry generally were related to rock type and residence time along individual flow paths. Dominant changes in geochemistry for the Ouachita Mountains aquifer and the Western Interior Plains confining system are attributed to rock/water interaction and changes in redox zonation along the flow path. In these areas, groundwater evolves along flow paths from a calcium- to a sodium-bicarbonate water type with increasing reducing conditions resulting in denitrification, elevated iron and manganese concentrations, and production of methane in the more geochemically evolved and strongest reducing conditions. In the Ozark and Springfield Plateau aquifers, rapid influx of surface-derived contaminants, especially nitrogen, coupled with few to no attenuation processes was attributed to the karst landscape developed on Mississippian- and Ordovician-age carbonate rocks of the Ozark Plateaus. Increasing nitrate concentrations are related to increasing agricultural land use, and areas of mature karst development result in higher nitrate concentrations than areas with less karst features.

Arkasas↗

Geology of the Mount St. Helens area: Record of discontinuous volcanic and plutonic activity in the Cascade Arc of southern Washington

The Quaternary edifice of Mount St. Helens volcano was built upon a deeply eroded terrane of gently folded and altered volcanic and plutonic rocks that represent the core of the Tertiary Cascade magmatic arc. These rocks constitute an east dipping homoclinal sequence, several kilometers thick, of subaerially erupted mafic to silicic flows and volcaniclastic strata; K‐Ar ages from this section range from about 28 to 23 Ma (late Oligocene and earliest Miocene), which corresponds to an apparent lull in Cascade volcanism to the north of Mount Rainier. Volcanism was essentially continuous during this period of time, and neither a well‐defined base nor top of the section is exposed within the mapped area. Basalt and basaltic andesite dominate the lower part of the mid‐Tertiary section, whereas andesitic and dacitic rocks comprise most of the upper part. This section was intruded by numerous mafic to silicic dikes, sills, and irregular plutonic bodies, most no more than a few million years younger than their host rocks, and subjected to pervasive burial metamorphism and widespread hydrothermal alteration. Large areas of hornfelsed rock surrounding even relatively small intrusions indicate that the proportion of plutonic rock becomes significantly greater at shallow depth beneath the existing erosion surface. A large granitic pluton intruded the mid‐Tertiary section north of Spirit Lake at about 21 Ma. The Earl porphyry copper deposit occurs within the pluton but appears too young (17 Ma) to be genetically related to it. In contrast to the rather continuous and voluminous Oligocene to early Miocene activity, volcanism since then in the Mount St. Helens area has been localized and Volumetrically minor. Products of three younger eruptive periods have been recognized: a sequence of 15 m.y. old pyroxene andesite flows resting unconformably on mid‐Tertiary strata south of Mount St. Helens, widespread shallow dikes and sills of pyroxene andesite between 10 and 8 m.y. old, and compositionally diverse rocks erupted during the past 3 m.y. The Quaternary lavas are more potassic than the Tertiary lavas and typically contain phenocrysts of hornblende and biotite, which are absent from the older rocks. A number of Tertiary structures define a broad NNE trending zone that may reflect a deep‐seated lithospheric flaw that has controlled the locus of Cascade magmatism in southern Washington for the past 25 m.y. Mount St. Helens lies within this zone at the intersection of the NNW striking St. Helens seismic zone (SHZ) and an ENE trending alignment of Pleistocene silicic plug‐domes. No surface breakage has been detected along the SHZ, which is apparently very young. The linear zone of silicic vents is probably controlled by a fault that has been interpreted from seismic records to occur directly beneath the volcano. This zone parallels the directions of regional maximum horizontal compressive stress and North America/Juan de Fuca plate convergence. Mount St. Helens is an example of a low‐volume tectonically controlled magmatic system in an early stage of development.

Washington↗

Manganese

Manganese is an essential element for modern industrial societies. Its principal use is in steelmaking, where it serves as a purifying agent in iron-ore refining and as an alloy that converts iron into steel. Although the amount of manganese consumed to make a ton of steel is small, ranging from 6 to 9 kilograms, it is an irreplaceable component in the production of this fundamental material. The United States has been totally reliant on imports of manganese for many decades and will continue to be so for at least the near future. There are no domestic reserves, and although some large low-grade resources are known, they are far inferior to manganese ores readily available on the international market. World reserves of manganese are about 630 million metric tons, and annual global consumption is about 16 million metric tons. Current reserves are adequate to meet global demand for several decades. Global resources in traditional land-based deposits, including both reserves and rocks sufficiently enriched in manganese to be ores in the future, are much larger, at about 17 billion metric tons. Manganese resources in seabed deposits of ferromanganese nodules and crusts are larger than those on land and have not been fully quantified. No production from seabed deposits has yet been done, but current research and development activities are substantial and may bring parts of these seabed resources into production in the future. The advent of economically successful seabed mining could substantially alter the current scenario of manganese supply by providing a large new source of manganese in addition to traditional land-based deposits. From a purely geologic perspective, there is no global shortage of proven ores and potential new ores that could be developed from the vast tonnage of identified resources. Reserves and resources are very unevenly distributed, however. The Kalahari manganese district in South Africa contains 70 percent of the world’s identified resources and about 25 percent of its reserves. South Africa, Brazil, and Ukraine together accounted for nearly 65 percent of reserves in 2013. The combination of total import reliance for manganese, the mineral commodity’s essential uses in our industrialized society, and the potential for supply disruptions because of the limited sources of the ore makes manganese among the most critical minerals for the United States. Manganese is the 12th most abundant element in Earth’s crust. Its concentration varies among common types of rocks, mostly in the range of from 0.1 to 0.2 percent. The highest quality manganese ores contain from 40 to 45 percent manganese. The formation of these ores requires specialized geologic conditions that concentrate manganese at several hundred times its average crustal abundance. The dominant processes in forming the world’s principal deposits take place in the oceans. As a result, most important manganese deposits occur in ancient marine sedimentary rocks that are now exposed on continents as a result of subsequent tectonic uplift and erosion. In many cases, other processes have further enriched these manganiferous sedimentary rocks to form some of today’s highest grade ores. Modern seabed resources of ferromanganese nodules cover vast areas of the present ocean floor and are still forming by complex interactions of marine microorganisms, manganese dissolved in seawater, and chemical processes on the seabed. Manganese is ubiquitous in soil, water, and air. It occurs most often in solid form but can become soluble under acidic conditions. Manganese mining, like any activity that disturbs large areas of Earth’s surface, has the potential to produce increases in manganese concentrations that could be harmful to humans or the environment if not properly controlled. Although manganese is an essential nutrient for humans and most other organisms, overexposure can lead to neurotoxicity in humans. Workers at manganese mining and processing facilities have the greatest potential to inhale manganese-rich dust. Without proper protective equipment, these workers may develop a permanent neurological disorder known as manganism. Each manganese mine is unique and presents its own suite of potential hazards and preventative measures. Likewise, various nations have their own sets of standards to ensure safe mining, isolation of mine waste, treatment of mine waters, and mine closure and restoration. Interest in mining trace metals contained in ferromanganese nodules and crusts on the seabed has increased rapidly in the past decade. Prime areas for future research include overcoming the technological challenges presented by mining as deep as 6,500 meters below sea level and understanding and mitigating the potential impacts of seabed mining on marine ecosystems.

Professional Paper↗

Monitoring, forecasting collapse events, and mapping pyroclastic deposits at Sinabung volcano with satellite imagery

During the ongoing (2013–present) eruption of Sinabung volcano, north Sumatra, we have routinely used a variety of satellite remote sensing data to observe and forecast lava dome and lava flow collapse events, to map the resulting pyroclastic deposits, and to estimate effusion rates. In this paper, we focus on the first two years of the current eruption (September 2013–December 2015), and we summarize major events in 2016. We divide the eruption into 5 major phases: 1) phreatomagmatic (July 2013–18 December 2013), 2) first dome growth and collapse (18 December 2013–10 January 2014), 3) lava-flow (10 January 2014–mid-September 2014), 4) second lava dome and collapse (mid-September 2014–July 2015), 5) lava dome collapse and ash explosion phase (August 2015–present). Throughout the eruption, remotely sensed information has been instrumental in assessing the stability of the lava dome and flow and to forecast collapse events that produce pyroclastic density currents (PDCs: block-and-ash flows, co-ignimbrite surges, and blasts). Forecasts based on remote sensing data in combination with seismic, geodetic and gas-monitoring data have also helped inform decisions related to alert levels and evacuations. Relatively unusual aspects of the Sinabung eruption include the transition from dome to flow morphology (phase 2 to phase 3 transition) and the frequent occurrence during phase 3 of collapses from the lava flow-front and flow-margins—collapses that produced extensive pyroclastic density currents. By analogy to the well-known “Merapi type” collapses and pyroclastic deposits, we propose that lava flow-front and flow-margin collapses with associated PDCs be known as “Sinabung type.” Although detailed study of deposits has not been possible due to continuing hazards, our observations suggest that the transition from lava dome to lava flow and the occurrence of flow-front and flow-margin collapses reflect a particular combination of lava viscosity and steepness of slope. Our observations also show clear evidence of at least one slope-parallel high-velocity and dilute PDC (a “blast”) that emanated from a lava-margin collapse site 500 m downslope from the vent. This 1 February 2014 blast downed and singed a forest out to at least 3.9 km from the collapse site and killed 16 people. We also use a combination of field and remotely sensed data to map the distribution of Sinabung deposits. We estimate eruptive volumes and extrusion rates by combining sequential measurements of lava surface and pyroclastic flow areas with thickness estimates derived from simple geometric assumptions, oblique photographs and Digital Elevation Models (DEMs) derived from remotely sensed data. Our estimates of short-term effusion rates vary widely on a daily to weekly basis, from <1 to >20 m 3 s −1 . In a few cases, periods of increased extrusion precede lava flow-front collapses by a few days to a week, suggesting delays in transmittance of effusion pulses as lava moves from vent to flow front. We find that, as of 1 January 2016, the total area of deposits is 10 7 m 2 , and their approximate deposit volume is about 0.3 km 3 , equivalent to 0.2 km 3 Dense Rock Equivalent (DRE). We anticipate that our deposit maps will be valuable in the future as a framework for the study of the magmatic and textural evolution of eruptive products through time.

Sinabung volcano↗

Petrologic, tectonic, and metallogenic evolution of the southern segment of the ancestral Cascades magmatic arc, California and Nevada

Ongoing arc magmatism along western North America was preceded by ancestral arc magmatism that began ca. 45 Ma and evolved into modern arc volcanism. The southern ancestral arc segment, active from ca. 30 to 3 Ma, adjoins the northern segment in northern California across a proposed subducted slab tear. The east edge of the Walker Lane approximates the east edge of the southern arc whose products, mostly erupted from stratovolcanoes and lava dome complexes arrayed along the crest of the ancestral arc, extend down the west flank of the Sierra Nevada. Southern arc segment rocks include potassic, calc-alkaline intermediate- to silicic-composition lava flows, lava dome complexes, and associated volcaniclastic deposits. Northern and southern segment rocks are similar to other convergent-margin magmatic arc rocks but are compositionally distinct from each other. Southern segment rocks have lower TiO 2 , FeO*, CaO, and Na 2 O contents and higher K 2 O contents, and exhibit less compositional-temporal variation. Compositional distinctions between the northern and southern segment rocks reflect the composition and thickness of the crust beneath which the associated magma systems were sourced. Northern segment rock compositions are consistent with generation beneath thin, primitive crust, whereas southern segment rocks represent magmas generated and fractionated beneath thicker, more evolved crust. Although rocks in the two arc segments have similar metal abundances, they are metallogenically distinct. Small porphyry copper deposits are characteristic of the northern segment whereas significant epithermal precious metal deposits are most commonly associated with the southern segment. These metallogenic differences are also fundamentally linked to the tectonic settings and crustal regimes within which these two arc segments evolved.

California, Nevada↗

Undiscovered petroleum resources for the Woodford Shale and Thirteen Finger Limestone-Atoka Shale assessment units, Anadarko Basin

In 2010 the U.S. Geological Survey assessed undiscovered oil and gas resources for the Anadarko Basin Province of Colorado, Kansas, Oklahoma, and Texas. The assessment included three continuous (unconventional) assessment units (AU). Mean undiscovered resources for the (1) Devonian Woodford Shale Gas AU are about 16 trillion cubic feet of gas (TCFG) and 192 million barrels of natural gas liquids (MMBNGL), (2) Woodford Shale Oil AU are 393 million barrels of oil (MMBO), 2 TCFG, and 59 MMBNGL, and (3) Pennsylvanian Thirteen Finger Limestone-Atoka Shale Gas AU are 6.8 TCFG and 82 MMBNGL. The continuous gas AUs are mature for gas generation within the deep basin of Oklahoma and Texas. Gas generation from the Woodford Shale source rock started about 335 Ma, and from the Thirteen Finger Limestone-Atoka Shale AU about 300 Ma. Maturation results are based on vitrinite reflectance data, and on 1D and 4D petroleum system models that calculated vitrinite reflectance (R o ), and Rock-Eval and hydrous pyrolysis transformation (HP) ratios through time for petroleum source rocks. The Woodford Shale Gas AU boundary and sweet spot were defined mainly on (1) isopach thickness from well-log analysis and published sources; (2) estimated ultimate recoverable production from existing, mainly horizontal, wells; and (3) levels of thermal maturation. Measured and modeled Ro ranges from about 1.2% to 5% in the AU, which represents marginally mature to overmature for gas generation. The sweet spot included most of the Woodford that was deposited within eroded channels in the unconformably underlying Hunton Group. The Thirteen Finger Limestone-Atoka Shale Gas AU has no known production in the deep basin. This AU boundary is based primarily on the gas generation window, and on thickness and distribution of organic-rich facies from these mainly thin shale and limestone beds. Estimates of organic richness were based on well-log signatures and published data.

Open-File Report↗

Mineral resources of Du Noir Addition, Washakie Wilderness area, Fremont County, Wyoming

The Du Noir Addition to the Washakie Wilderness area consists of 34,200 acres (13,840 hectares) of scenic mountainous terrain that adjoins the Teton Wilderness and Washakie Wilderness areas. The area was studied in 1973 by the U.S. Geological Survey and U.S. Bureau of Mines to evaluate its mineral, fuel, and geothermal energy potential. This evaluation is based on a search of the geologic literature, claim and production records, and fieldwork including mapping, inspection of claims and prospects, interpretation of aeromagnetic maps, and analyses of bedrock and stream-sediment samples. Flat-lying Eocene volcaniclastic rocks of the Absaroka volcanic field are exposed in about two-thirds of the Du Noir Addition. These volcanics unconformably overlie the deeply eroded, northwest-trending Du Noir anticline in which Paleozoic marine strata of Devonian through Permian age are exposed. Of lesser importance are small deposits of Eocene non-volcanic conglomerate, and basaltic intrusive and extrusive rocks of late Pliocene and possibly younger age. The results of this study indicate that the mineral, fuel, and geothermal potential of the Du Noir Addition are minimal. Low-grade copper-molybdenum mineralization occurs outside the addition, associated with intrusive rocks, but no indications of alteration or mineralization were found within the study area. Anomalous, but not economically important, concentrations of molybdenum and uranium were found in Permian and Eocene carbonaceous shales. Phosphate rock in the Phosphoria Formation occurs in beds too thin to constitute a resource. Large amounts of very pure limestone are present in the Madison Limestone, but equally pure limestone, much closer to transportation facilities, is found throughout this part of Wyoming. That part of the Du Noir anticline in the addition is too deeply eroded to be a likely reservoir of oil and gas. Present data indicates a low potential for geothermal energy in or near the addition.

Wyoming↗

Cenozoic distributed volcanism of the Arabia Plate—A review

Cenozoic volcanic rocks of the Arabia Plate cover about 140,000 square kilometers across a distance of about 3,000 kilometers from southern Yemen to southeastern Turkey. The majority of volcanic products are alkali basalts that erupted in restricted areas, commonly over periods of a million or more years, building mafic lava fields, each known in Arabic as a “harrat.” Harrat volcanism commenced following the Oligocene flood-lava effusions that blanketed the (now) Ethiopian highlands, southern Sudan, and western Yemen, and overlapped the latest Oligocene to early Miocene initial riftings of the Red Sea and Gulf of Aden, but the majority of harrat volcanism has been since approximately 13–10 million years ago. Persistent harrat magmatism in restricted locations led to the development of intermediate and evolved magmas (hawaiites, mugearites, benmoreites, trachytes, comendites, and phonolites) mainly through intracrustal crystallization-differentiation. Most of these intermediate and evolved magmas erupt at sites of the greatest aggregate volcanic relief, reflecting sites of the greatest overall magmatic fluxes. Production of fractionated magmas at these sites negates “monogenetic” as an appropriate descriptor of harrat volcanism. This chapter summarizes the geologic, eruptive, and tectonic history and aspects of the petrogenesis of the Cenozoic Arabian alkalic province. Particular emphasis is placed on results of a joint study of Ḩarrat Rahat adjacent to the city of Al Madīnah al Munawwarah, Kingdom of Saudi Arabia, published as U.S. Geological Survey Professional Paper 1862 and Saudi Geological Survey Special Report SGS–SP–2021–1. A goal of this chapter is to provide an introduction to those unfamiliar with this vast, enigmatic, and fascinating region of distributed continental volcanism.

Arabia Plate↗

Geology and total petroleum systems of the Paradox Basin, Utah, Colorado, New Mexico, and Arizona

The geological model for the development of the Total Petroleum Systems (TPSs) within the Paradox Basin formed the foundation of the recent U.S. Geological Survey assessment of undiscovered, technically recoverable resources in the basin. Five TPSs were defined, of which three have known production and two are hypothetical. These TPSs are based on geologic elements of the basin and the potential development of Precambrian, Devonian, Pennsylvanian, Permian-Mississippian, and Cretaceous source rock intervals. The most studied source intervals are the Pennsylvanian black shales that were deposited during relative high stands in an otherwise evaporitic basin. These black shales are the source for most of the discovered hydrocarbons in the Paradox Basin. A second oil type can be traced to either a Mississippian or Permian source rock to the west, and therefore requires long-distance migration to explain its presence in the basin. Upper Cretaceous continental to nearshore-marine sandstones are interbedded with coal beds that have recognized coalbed methane potential. Precambrian and Devonian TPSs are considered hypothetical, as both are known to have organic-rich intervals, but no discovered hydrocarbons have been definitively typed back to either of these units.

Arizona, Colorado, New Mexico, Utah↗

Are the Columbia River Basalts, Columbia Plateau, Idaho, Oregon, and Washington, USA, a viable geothermal target? A preliminary analysis

The successful development of a geothermal electric power generation facility relies on (1) the identification of sufficiently high temperatures at an economically viable depth and (2) the existence of or potential to create and maintain a permeable zone (permeability >10 -14 m 2 ) of sufficient size to allow efficient long-term extraction of heat from the reservoir host rock. If both occur at depth under the Columbia Plateau, development of geothermal resources there has the potential to expand both the magnitude and spatial extent of geothermal energy production. However, a number of scientific and technical issues must be resolved in order to evaluate the likelihood that the Columbia River Basalts, or deeper geologic units under the Columbia Plateau, are viable geothermal targets. Recent research has demonstrated that heat flow beneath the Columbia Plateau Regional Aquifer System may be higher than previously measured in relatively shallow (<600 m depth) wells, indicating that sufficient temperatures for electricity generation occur at depths 5 km. The remaining consideration is evaluating the likelihood that naturally high permeability exists, or that it is possible to replicate the high average permeability (approximately 10 -14 to 10 -12 m 2 ) characteristic of natural hydrothermal reservoirs. From a hydraulic perspective, Columbia River Basalts are typically divided into dense, impermeable flow interiors and interflow zones comprising the top of one flow, the bottom of the overlying flow, and any sedimentary interbed. Interflow zones are highly variable in texture but, at depths <600 m, some of them form highly permeable regional aquifers with connectivity over many tens of kilometers. Below depths of ~600 m, permeability reduction occurs in many interflow zones, caused by the formation of low-temperature hydrothermal alteration minerals (corresponding to temperatures above ~35 °C). However, some high permeability (>10-14 m 2 ) interflows are documented at depths up to ~1,400 m. If the elevated permeability in these zones persists to greater depths, they may provide natural permeability of sufficient magnitude to allow their exploitation as conventional geothermal reservoirs. Alternatively, if the permeability in these interflow zones is less than 10-14 m 2 at depth, it may be possible to use hydraulic and thermal stimulation to enhance the permeability of both the interflow zones and the natural jointing within the low-permeability interior portions of individual basalt flows in order to develop Enhanced/Engineered Geothermal System (EGS) reservoirs. The key challenge for an improved Columbia Plateau geothermal assessment is acquiring and interpreting comprehensive field data that can provide quantitative constraints on the recovery of heat from the Columbia River Basalts at depths greater than those currently tested by deep boreholes.

Idaho, Oregon, Washington↗

Geology and undiscovered oil and gas resources in the Madison Group, Williston Basin, North Dakota and Montana

Two of the total petroleum systems (TPS) defined as part of the U.S. Geological Survey (USGS) assessment of the Williston Basin contain Mississippian Madison Group strata: 1) the Bakken-Lodgepole TPS, which includes the Lodgepole Formation; and 2) the Madison TPS, which includes the Mission Canyon, Charles, and Spearfish formations. The Bakken-Lodgepole TPS is defined as the area in which oil generated from the upper and lower shales of the Upper Devonian-Lower Mississippian Bakken Formation has accumulated in reservoirs in the Three Forks, Bakken, and Lodgepole formations. Two conventional assessment units (AU) have been identified within the Bakken-Lodgepole TPS, including one in the Bakken Formation and another in the Waulsortian mound reservoirs of the lower Lodgepole Formation. Lodgepole Formation Waulsortian mound oil production has been restricted to a small part of Stark County, North Dakota. Reservoirs are sealed by middle and upper Lodgepole Formation tight argillaceous limestones. Several nonproductive mounds and mound-like structures have also been identified in the Lodgepole Formation. Productivity correlates closely with the oil window of the Bakken Formation shales, and also indicates the likelihood of limited lateral migration of Bakken Formation oil into Lodgepole Formation reservoirs in North Dakota and Montana. Such considerations limit the estimated mean of undiscovered, technically recoverable resources to 8 million barrels of oil (MMBO) for the Lodgepole Formation conventional reservoirs. The Madison TPS is defined as the area where oil generated from Mission Canyon and Charles formation source rocks has accumulated in reservoirs of the Mission Canyon and Charles formations and in reservoirs within the Triassic Spearfish Formation. One continuous reservoir AU, the Mission Canyon-Charles AU, was defined within the Madison TPS; its boundary coincides with the TPS boundary. There is extensive conventional production throughout the AU on major structures and in stratigraphic-structural traps. The largest fields are on the Little Knife, Billings Nose, and Nesson anticlines. Recent studies show that Madison Group oils were generated from organic-rich Mission Canyon Formation and Ratcliffe Interval carbonates adjacent to the reservoirs. Seals were formed by overlying or lateral evaporites or tight carbonates. Based on available geologic and production data, the undiscovered oil resources for conventional reservoirs in the Mission Canyon-Charles AU were estimated to have a mean of 45 MMBO.

Mountain Geologist↗

A 15 000-year record of climate change in northern New Mexico, USA, inferred from isotopic and elemental contents of bog sediments

Elemental (C, N, Pb) and isotopic ( δ 13 C, δ 15 N) measurements of cored sediment from a small bog in northern New Mexico reveal changes in climate during the Late Pleistocene and Holocene. Abrupt increases in Pb concentration and δ 13 C values ca. 14 420 cal. YBP indicate significant runoff to the shallow lake that existed at that time. Weathering and transport of local volcanic rocks resulted in the delivery of Pb-bearing minerals to the basin, while a 13 C-enriched terrestrial vegetation source increased the δ 13 C values of the sedimentary material. Wet conditions developed over a 300 a period and lasted for a few hundred years. The Younger Dryas period (ca. 12 700–11 500 cal. YBP) caused a reduction in terrestrial productivity reflected in decreasing C/N values, δ 15 N values consistently greater than 0‰ and low organic content. By contrast, aquatic productivity increased during the second half of this period, evidenced by increasing δ 13 C values at the time of highest abundance of algae. Dry conditions ca. 8 000–6 000 cal. YBP were characterised by low organic carbon content and high Pb concentrations, the latter suggesting enhanced erosion and aeolian transport of volcanic rock. The range in δ 13 C, δ 15 N and C/N values in the sedimentary record fall within the range of modern plants, except during the periods of runoff and drought. The sedimentary record provides evidence of natural climate variability in northern New Mexico, including short- (multi-centennial) and long-(millennial) term episodes during the Late Pleistocene and Holocene.

Journal of Quaternary Science↗

Uranium in surface waters and sediments affected by historical mining in the Denver West 1:100,000 Quadrangle, Colorado

Geochemical sampling of 82 stream waters and 87 stream sediments within mountainous areas immediately west of Denver, Colorado, was conducted by the U.S. Geological Survey in October 1994. The primary purpose was to evaluate regionally the effects of geology and past mining on the concentration and distribution of uranium. The study area contains uranium- and thorium-rich bedrock, numerous noneconomic occurrences of uranium minerals, and several uranium deposits of variable size and production history. During the sampling period, local streams had low discharge and were more susceptible to uranium-bearing acid drainage originating from historical mines of base- and precious-metal sulfides. Results indicated that the spatial distribution of Precambrian granites and metamorphic rocks strongly influences the concentration of uranium in stream sediments. Within-stream transport increases the dispersion of uranium- and thorium rich mineral grains derived primarily from granitic source rocks. Dissolved uranium occurs predominantly as uranyl carbonate complexes, and concentrations ranged from less than 1 to 65 micrograms per liter. Most values were less than 5 micrograms per liter, which is less than the current drinking water standard of 30 micrograms per liter and much less than locally applied aquatic-life toxicity standards of several hundred micrograms per liter. In local streams that are affected by uranium-bearing acid mine drainage, dissolved uranium is moderated by dilution and sorptive uptake by stream sediments. Sorbents include mineral alteration products and chemical precipitates of iron- and aluminum-oxyhydroxides, which form where acid drainage enters streams and is neutralized. Suspended uranium is relatively abundant in some stream segments affected by nearby acid drainage, which likely represents mobilization of these chemical precipitates. The 234U/238U activity ratio of acid drainage (0.95-1.0) is distinct from that of local surface waters (more than 1.05), and this distinctive isotopic composition may be preserved in iron-oxyhydroxide precipitates of acid drainage origin. The study area includes a particularly large vein-type uranium deposit (Schwartzwalder mine) with past uranium production. Stream water and sediment collected downstream from the mine's surface operations have locally anomalous concentrations of uranium. Fine-grained sediments downstream from the mine contain rare minute particles (10-20 micrometers) of uraninite, which is unstable in a stream environment and thus probably of recent origin related to mining. Additional rare particles of very fine grained (less than 5 micrometer) barite likely entered the stream as discharge from settling ponds in which barite precipitation was formerly used to scavenge dissolved radium from mine effluent.

Colorado↗

Magnesite and brucite in the United States, exclusive of Alaska and Hawaii

The important deposits of magnesite (MgCO 3 ) and brucite (MgO.H 2 O) in the United States (exclusive of Alaska and Hawaii) are shown on the accompanying map. Single deposits and groups of deposits are shown by geometric symbols according to four size categories based on estimated production plus reserves. These categories are: less than 10,000 tons, 10,000 to 100,000 tons, 100,000 to 1,000,000 tons, and more than 1,000,000 tons. Occurrences of mineralogic interest only are not shown. All map locations are numbered consecutively in each State and keyed to the locality index. The geographical coordinates in the locality index represent the centers of the geometric symbols. Thus, the same coordinates are assigned to all deposits covered by a group symbol. The map was compiled from published reports and data in the files of the United States Geological Survey. The names, geographic coordinates, and geologic types of deposits are given in the locality index. The principal published reports used in compiling the map are listed in the selected references. The main types of commercial deposits of magnesite in the United States are: (1) replacement bodies in limestone and dolomite; (2) replacements and veins in serpentine; and (3) sedimentary beds. Other magnesite deposits of varied origin and less common occurrence include beds associated with talc, chlorite, and mica schists; and veins and lenses in altered tuffs. Brucite is a relatively rare mineral of secondary origin which usually accompanies other magnesian minerals, particularly magnesite and hydromagnesite, and is associated with carbonate rocks and serpentine. Magnesite was first mined in California in 1886, and the State was the only domestic producer until the development of the Washington deposits began in 1916. In recent years, the main production of magnesite has been from Stevens County, Washington, and Nye County, Nevada. Production in California has been intermittent since 1945. Magnesite deposits in Texas were mined during and immediately after World War II. At present (1961) the only brucite deposits being worked are those at Gabbs, Nye County, Nevada. They have been mined almost continuously since 1935.

Mineral Investigations Resource Map↗

International strategic minerals inventory summary report; niobium (columbium) and tantalum

Major world resources of niobium and tantalum are described in this summary report of information in the International Strategic Minerals Inventory (ISMI). ISMI is a cooperative data-collection effort of earth-science and mineral-resource agencies in Australia, Canada, the Federal Republic of Germany, the Republic of South Africa, the United Kingdom, and the United States of America. Part I of this report presents an overview of the resources and potential supply of niobium and tantalum based on inventory information; Part II contains tables of both geologic and mineral-resource information and includes production data collected by ISMI participants. Niobium is used principally as an alloying element in special steels and superalloys, and tantalum is used mainly in electronics. Minerals in the columbite-tantalite series are principal ore minerals of niobium and tantalum. Pyrochlore is a principal source of niobium. These minerals are found in carbonatite, certain rocks in alkaline igneous complexes, pegmatite, and placer deposits. ISMI estimates show that there are over 7 million metric tons of niobium and almost 0.5 million metric tons of tantalum in known deposits, outside of China and the former Soviet Union, for which reliable estimates have been made. Brazilian deposits, followed by Canadian deposits, contain by far the largest source of niobium. Tantalum production is spread widely among several countries, and Brazil and Canada are the most significant of these producers. Brazil's position is further strengthened by potential byproduct columbite from tin mining. Present economically exploitable resources of niobium appear to be sufficient for the near future, but Brazil will continue to be the predominant world supplier of ferrocolumbium. Tantalum, a byproduct of tin production, has been captive to the fluctuations of that market, but resources in pegmatite in Canada and Australia make it likely that future increases in the present modest demand will be met.

Circular↗