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Beryllium--important for national defense

Beryllium is one of the lightest and stiffest metals, but there was little industrial demand for it until the 1930s and 1940s when the aerospace, defense, and nuclear sectors began using beryllium and its compounds. Beryllium is now classified by the U.S. Department of Defense as a strategic and critical material because it is used in products that are vital to national security. The oxide form of beryllium was identified in 1797, and scientists first isolated metallic beryllium in 1828. The United States is the world's leading source of beryllium. A single mine at Spor Mountain, Utah, produced more than 85 percent of the beryllium mined worldwide in 2010. China produced most of the remainder, and less than 2 percent came from Mozambique and other countries. National stockpiles also provide significant amounts of beryllium for processing. To help predict where future beryllium supplies might be located, U.S.Geological Survey (USGS) scientists study how and where beryllium resources are concentrated in Earth's crust and use that knowledge to assess the likelihood that undiscovered beryllium resources may exist. Techniques to assess mineral resources have been developed by the USGS to support the stewardship of Federal lands and to better evaluate mineral resource availability in a global context. The USGS also compiles statistics and information on the worldwide supply of, demand for, and flow of beryllium. These data are used to inform U.S. national policymaking.

Fact Sheet↗

Fracture patterns and their origin in the upper Devonian Antrim Shale gas reservoir of the Michigan basin: A review

INTRODUCTION: Black shale members of the Upper Devonian Antrim Shale are both the source and reservoir for a regional gas accumulation that presently extends across parts of six counties in the northern part of the Michigan basin (fig. 1). Natural fractures are considered by most petroleum geologists and oil and gas operators who work the Michigan basin to be a necessary condition for commercial gas production in the Antrim Shale. Fractures provide the conduits for free gas and associated water to flow to the borehole through the black shale which, otherwise, has a low matrix permeability. Moreover, the fractures assist in the release of gas adsorbed on mineral and(or) organic matter in the shale (Curtis, 1992). Depths to the gas-producing intervals (Norwood and Lachine Members) generally range from 1,200 to 1,800 ft (Oil and Gas Journal, 1994). Locally, wells that produce gas from the accumulation are as deep as 2,200 (Oil and Gas Journal, 1994). Even though natural fractures are an important control on Antrim Shale gas production, most wells require stimulation by hydraulic fracturing to attain commercial production rates (Kelly, 1992). In the U.S. Geological Survey's National Assessment of United States oil and gas, Dolton (1995) estimates that, at a mean value, 4.45 trillion cubic feet (TCF) of gas are recoverable as additions to already discovered quantities from the Antrim Shale in the productive area of the northern Michigan trend. Dolton (1995) also suggests that undiscovered Antrim Shale gas accumulations exist in other parts of the Michigan basin. The character, distribution, and origin of natural fractures in the Antrim Shale gas accumulation have been studied recently by academia and industry. The intent of these investigations is to: 1) predict 'sweet spots', prior to drilling, in the existing gas-producing trend, 2) improve production practices in the existing trend, 3) predict analogous fracture-controlled gas accumulations in other parts of the Michigan basin, and 4) improve estimates of the recoverable gas in the Antrim Shale gas plays (Dolton, 1995). This review of published literature on the characteristics of Antrim Shale fractures, their origin, and their controls on gas production will help to define objectives and goals in future U.S. Geological Survey studies of Antrim Shale gas resources.

Michigan↗

Water budget and water quality of Ward Lake, flow and water-quality characteristics of the Braden River estuary, and the effects of Ward Lake on the hydrologic system, west-central Florida

The Braden River is the largest tributary to the Manatee River. The river was dammed in 1936 to provide the city of Bradenton a source of freshwater supply. The resulting impoundment was called Ward Lake and had a storage capacity of about 585 million gallons. Reconstruction in 1985 increased the size of the reservoir to about 1,400 million gallons. The lake has been renamed the Bill Evers Reservoir and drains about 59 square miles. The Braden River watershed can be subdivided into three hydrologic reaches. The upper reach consists of a naturally incised free-flowing channel. The middle reach consists of a meandering channel affected by backwater as a result of the dam. The lower reach is a tidal estuary. Water budgets were calculated for the 1993 through 1997 water years. Mean surface-water inflow to Ward Lake for the 5-year period was 1,645 inches per year (equivalent depth over the surface of the lake), or about 81.8 percent of total inflow. Mean ground-water inflow was 311 inches per year, or about 15.5 percent. A mean of 55 inches of rain fell directly on the lake and accounted for only 2.7 percent. Mean surface-water outflow was 1,736 inches, or about 86.4 percent of total water leaving the lake. There was no net ground-water outflow from the lake. Mean surface-water withdrawal for public supply was 229 inches per year, or about 11.4 percent. Mean evaporation was 45 inches and accounted for only 2.2 percent of the mean outflow. Change in lake storage on the budget was negligible. Most chemical constituents contained in water flowing to Ward Lake meet the standards specified by the Florida Department of Environmental Protection and the U.S. Environmental Protection Agency. Phosphorus is the exception, exceeding the U.S. Environmental Protection Agency limits of 0.10 milligram per liter in most samples. However, the source of the phosphorus is naturally occurring phosphate deposits underlying the watershed. Organic nitrogen and orthophosphate are the dominant species of nutrients in the streams and the lake. A major source of water to the streams is the surficial aquifer system. Mineralized water pumped from the intermediate aquifer system and the Upper Floridan aquifer for irrigation of agricultural areas or golf courses has influenced the chemical composition of the surficial aquifer and surface-water systems. The Braden River estuary receives freshwater inflow from Ward Lake and from three major streams discharging downstream from the dam. Salinity levels in the estuary are affected by freshwater flow from these sources and by antecedent conditions in the estuary prior to flow events. The lowest salinity levels are often measured at the confluence with Williams and Gap Creeks rather than at the outfall from the lake. The chemical composition of water flowing from the tributaries to the estuary is similar to the chemical composition of water in the tributaries flowing to Ward Lake and does not appear to be affected by brackish water from high tides. Nitrogen concentrations in water from Glen Creek were greater than in water from all other tributaries in the watershed. Fertilizer from orange groves and stormwater runoff from urban and industrial areas affect the water quality in Glen Creek. The effects of the reservoir on the hydrology of the watershed were to change the middle reach of the river from a brackish water estuary ecosystem to a freshwater lake ecosystem, raise water levels in the surficial aquifer system adjacent to the river, change water quality, and reduce freshwater flow to the estuary during periods of low flow. The lake acts as a sink for total organic carbon, dissolved solids, calcium, chloride, and sulfate, thereby decreasing loads of these constituents to the estuary.

Florida↗

Water resources of Indiana County, Pennsylvania

Indiana County, west-central Pennsylvania, is a major producer of coal and natural gas. Water managers and residents are concerned about the effects of mining and natural gas exploration on the surface- and ground-water resources of the county. This study assesses the quality and quantity of water in Indiana County. Ground- and surface-water sources are used for public supplies that serve 61 percent of the total population of the county. The remaining 39 percent of the population live in rural areas and rely on cisterns and wells and springs that tap shallow aquifers. Most of the county is underlain by rocks of Middle to Upper Pennsylvanian age. From oldest to youngest, they are the Allegheny Group, the Glenshaw Formation, the Casselman Formation, and the Monongahela Group. Almost all the coals mined are in the Allegheny Group and the Monongahela Group. Ground water in Indiana County flows through fractures in the rock. The size and extent of the fractures, which are controlled by lithology, topography, and structure, determine the sustained yield of wells. Topography has a significant control over the yields of wells sited in the Allegheny Group. Properly sited wells in the Glenshaw Formation may have yields adequate for municipal, commercial, or industrial uses. The Casselman Formation yields adequate amounts of water for domestic use. Yield of the Monongahela Group is small, and the water may not be of suitable quality for most uses. Yields of hilltop wells may be marginal, but valley wells may yield sufficient amounts for large-volume users. Data on the other rock units are sparse to nonexistent. Few wells in the county yield more than 40 gallons per minute. Most of the wells that do are in valleys where alluvial deposits are extensive enough to be mapable. Short-term water-level fluctuations are variable from well to well. Seasonal water-level fluctuations are controlled by time of year and amount of precipitation. The quality of water from the Casselman Formation, Glenshaw Formation, and Allegheny Group tends to be hard and may have concentrations of iron and manganese that exceed the U.S. Environmental Protection Agency Secondary Maximum Contaminant Levels of 0.3 milligrams per liter and 0.05 milligrams per liter, respectively. Ground water from the Glenshaw Formation is less mineralized than ground water from the Allegheny Group. Concentrations of minerals in water from the Casselman Formation are between those in water from the Glenshaw Formation and the Allegheny Group. Water from wells on hilltops has lower concentrations of dissolved solids than water from wells on hillsides. Water from valley wells is the most mineralized. Nearly half the springs tested yield water that is low in pH and dissolved solids; this combination makes the water chemically aggressive. The 7-day, 10-year low-flow frequencies for 26 unregulated surface-water sites ranged from 0.0 to 0.19 cubic feet per second per square mile. The presence of coal mines and variations in precipitation were probably the principal factors affecting flow duration on Blacklick Creek (site 28) during 1953-88. Sustained base flows of regulated streams such as Blacklick Creek generally were larger than those of unregulated streams as a result of low-flow augmentation. The annual water loss in streamflow as a result of evapotranspiration, diversion, seepage to mines, and seepage to the ground-water system was determined at four sites (sites 8, 9, 17, and 28) and ranged from 35 to 53 percent. The highest concentrations of dissolved solids, iron, manganese, aluminum, zinc, and sulfate were measured mostly in streams in central and southern Indiana County, where active and abandoned coal mines are the most numerous. Streamflow was measured during low flow in two small basins; one basin almost completely deep mined (Cherry Run) and one basin unmined (South Branch Plum Creek). The measurements showed a con

Pennsylvania↗

Aptian ‘Shale Gas’ Prospectivity in the Downdip Mississippi Interior Salt Basin, Gulf Coast, USA

This study evaluates regional ‘shale gas’ prospectivity of the Aptian section (primarily Pine Island Shale) in the downdip Mississippi Salt Basin (MSB). Previous work by the U.S. Geological Survey estimated a mean undiscovered gas resource of 8.8 trillion cubic feet (TCF) in the chronostratigraphic-equivalent Pearsall Formation in the Maverick Basin of south Texas, where industry has established a moderately successful horizontal gas and liquids play. Wells penetrating the downdip MSB Aptian section at depths of 12,000-15,000 ft were used to correlate formation tops in a 15-well cross-section extending about 200 miles (mi) east-southeastward from Adams Co. to Jackson Co. Legacy cuttings from these wells were analyzed for thermal maturity and source rock quality. Bitumen reflectance (n=53) increases with increasing present-day burial depth in the east-central study area from 1.0% to 1.7%. As the Aptian section shallows in Adams Co. to the west, bitumen Ro values are higher (1.7-2.0%), either from relatively greater heat flux or greater mid-Cenomanian uplift and erosion in this area. Total organic carbon (TOC) content ranges 0.01-1.21 and averages 0.5 wt.% (n=51); pyrolysis output (S2; n=51) averages 0.40 mg HC/g rock, indicating little present-day hydrocarbon-generative potential. Bitumen reflectance is preferred as a thermal maturity parameter as Tmax values are unreliable. Normalized X-ray diffraction (XRD) mineral analyses (n=26) indicate high average clay abundance (53 wt.%) relative to quartz (29%) and carbonate (18%). Mineral content shows a spatial relationship to an Appalachian orogen clastic sediment source, with proximal high clay and quartz and distal high carbonate content. Clastic influx from the Appalachian orogen is confirmed by detrital zircon U-Pb ages with dominant Grenville and Paleozoic components [105 ages from a Rodessa sandstone and 112 ages from a Paluxy (Albian) sandstone]. Preliminary information from fluid inclusion microthermometry (41 aqueous measurements from calcite cements in one argillaceous James Limestone sample) indicates homogenization temperatures (Th) of 120-135°C, consistent with present-day bottom-hole conditions and measured bitumen Ro values towards the western end of the MSB. Downdip in the central MSB, microthermometry (26 aqueous measurements from quartz dust rims in one Paluxy sandstone sample) and measured bitumen Ro values indicate maximum temperatures may have been significantly higher (~25°C) than present-day conditions. High inclusion salinities (15-25 wt.% salt) at both locations suggest interaction of pore fluids with evaporites. Mercury injection capillary pressure (MICP) analyses (n=3) indicate porosity ranges 1.3-2.1% and permeability 0.006-0.02 µD for Pine Island and Rodessa shales. Overall, results from this work indicate generally poor ‘shale gas’ prospectivity compared to other shale reservoirs based primarily on depth, low organic content, low porosity, and high clay content. However, thickness and thermal maturity are appropriate, moderate reservoir pressures are present, and petroleum systems modelling by others has indicated high undiscovered gas potential for the basin as a whole.

Conference Paper↗

Ocean floor manganese deposits

Much of the dissolved Mn delivered to the oceans is slowly oxidized and precipitated alongside varying amounts of Fe into Mn and ferromanganese (FeMn) mineral deposits that occur extensively in the deep ocean wherever sediment accumulation is low and substrate is available. FeMn crusts grow as pavements on rock outcrops throughout the global ocean whereas nodules form as individual FeMn-encrusted particles on the sediment-covered abyssal plains. Both crusts and nodules are composed predominantly of Fe and Mn oxide minerals that precipitate from seawater and for some nodules also from porewaters of deep-sea sediment. In contrast, hydrothermal oxide deposits consist predominantly of Mn or Fe oxide. FeMn crusts and nodules exhibit very high specific surface areas that allow them to scavenge abundant metals and other elements, recording the history of the source waters. Crusts especially serve as an important record of paleoceanographic conditions over the past 70 + million years. Critical metals essential to many computer, military, and green technologies are enriched in crust and nodule deposits to concentrations high enough to compare with, or exceed, typical terrestrial deposits, and they can be considered as potential resources for mining in the near future. Twenty-three contracts pertaining to exploration for nodules and crusts have been signed with the International Seabed Authority, and resource/reserve, baseline, and environmental impact assessments are underway. Many challenges remain to be addressed before full-scale mining of marine FeMn deposits will occur. However, their unique genesis and the growing worldwide need for rare and critical metals keep these deep-ocean deposits relevant to industry, scientists, and governments.

Book chapter↗

Water quality in the proposed Prosperity Reservoir area, Center Creek Basin, Missouri

Water in Center Creek basin, Mo., upstream from the proposed Prosperity Reservoir damsite is a calcium bicarbonate type that is moderately mineralized, hard, and slightly alkaline. Ammonia and organic nitrogen, phosphorus, total organic carbon, chemical oxygen demand, and bacteria increased considerably during storm runoff, probably due to livestock wastes. Nitrogen and phosphorus concentrations are probably high enough to cause the proposed lake to be eutrophic. Minor-element concentrations were at or near normal levels in Center and Jones Creeks. The only pesticides detected were 0.01 micrograms per liter of 2, 4, 5-T in one base-flow sample and 0.02 to 0.04 micrograms per liter of 2, 4, 5-T and 2, 4-D in all storm-runoff samples. Fecal coliform and fecal streptococcus densities ranged from 2 to 650 and 2 to 550 colonies per 100 milliliters, respectively, during base flow , but were 17,000 to 45,000 and 27,000 to 70,000 colonies per 100 milliliters, respectively, during storm runoff. Water in Center Creek about 2.5 miles downstream from the proposed damsite is similar in quality to that upstream from the damsite except for higher concentrations of sodium, sulfate, chloride, fluoride, nitrogen, and phosphorus. These higher concentrations are caused by fertilizer industry wastes that enter Center Creek about 1.0 mile downstream from the proposed damsite. (Woodard-USGS).

Missouri↗

Quality of water from freshwater aquifers and principal well fields in the Memphis Area, Tennessee

Water from the freshwater aquifers in the Memphis area is suitable for most uses. Freshwater aquifers are the alluvium and fluvial (terrace) deposits of Quaternary age, the Memphis Sand and Fort Pillow Sand of Tertiary age, and the Ripley Formation and McNairy Sand of Cretaceous age. About 180 million gallons/day (mgd) of freshwater are withdrawn from the Memphis Sand, primarily for municipal and industrial use; the Memphis Sand is the principal aquifer supplying the City of Memphis. The alluvium provides water for irrigation and some industrial uses, and the fluvial deposits provide water for domestic use in rural areas. The Fort Pillow Sand supplies water for some municipal and industrial uses. The Ripley-McNairy aquifer is not used as a source of water. Water from the alluvium, fluvial deposits, and Memphis Sand is a calcium bicarbonate type, and water from the Fort Pillow Sand and Ripley-McNairy aquifer is a sodium bicarbonate type. Dissolved solids concentrations are low in the Memphis Sand, with a median value of 83 mg/L, and are high in the Ripley-McNairy aquifer with a value of about 1,000 mg/L. Water is very soft in the Fort Pillow Sand with a median hardness value of 9 mg/L as CaCO3 and is very hard in the alluvium with a median value of 285 mg/L. Iron concentrations are low in the fluvial deposits with a median value of 50 micrograms/L and are high in the alluvium with a median value of 5,200 micrograms/L. Temperature of the water generally increases with depth, ranging from 16.0 C in the alluvium and fluvial deposits to about 32.0 C in the Ripley-McNairy aquifer. Water from the Memphis Sand at Memphis Light, Gas and Water Division well fields has very low mineralization. Median values are 79 mg/L dissolved solids concentrations, 56 mg/L alkalinity as CaCO3, 46 mg/L hardness as CaCO3, 4 mg/L chloride, 3.5 mg/L sulfate, and 600 micrograms/L iron.

Tennessee↗

One hundred years of cobalt production in the Democratic Republic of the Congo

Cobalt is an indispensable element for the manufacture of strategic technologies including advanced batteries, jet engines, rare-earth permanent magnets, petroleum catalysts, and tool parts that enable construction, manufacturing, and mining. Cobalt routinely scores high in mineral supply risk assessments due to the concentration of cobalt mine production in the Democratic Republic of the Congo (DRC). This stands in contrast to the fact that DRC cobalt mine production had a 20% compound annual growth rate from 1995 through 2020—in large part due to investments by Chinese firms beginning in the mid-2000s. Given this continuous growth, one may ask why this supply is perceived to be so risky. This analysis illuminates the causes of historic disruptions to DRC cobalt mine and refinery production by analyzing country-level production, historical reports, and cobalt prices back to 1924. The results indicate that the main causes of supply disruptions were damage to transportation routes, underinvestment in maintaining nationalized mining assets, and the disintegration of the DRC economy during the early 1990s. On the other hand, cobalt mine production increased 50% from 1977 to 1979 despite two secessionist conflicts in DRC's cobalt producing region and increased seven-fold from 1996 to 2003 despite two African wars over the DRC and its resources. These results indicate that—barring another economic disintegration or mining industry nationalization—DRC mine production will likely continue to be the dominant supplier of the world's growing demand for cobalt in lithium-ion batteries. These results also indicate that sustained development of transportation (and other) infrastructure in Africa, as well as support for good governance in the DRC may prove key to the continued stability of DRC cobalt mine supplies.

Resources Policy↗

Twenty-eighth annual report of the Director of the United States Geological Survey

The plan of operations for the last fiscal year, including an itemized statement of the appropriations, amounting to $1,758,720, with the allotments thereof, was approved by the Secretary of the Interior on July 10, 1906. The work of the various branches and divisions conformed to this plan, and a detailed statement of their operations may be found on later pages. On January 23 the former Director, Charles D. Walcott, was appointed to the position of Secretary of the Smithsonian Institution, and his resignation as Director was accepted by the President, becoming effective April 30, 1907. Mr. Walcott has been a member of the Survey since its organization, and the thirteen years of his service as the administrative head of the bureau cover the period of its greatest growth. At the beginning of his directorship Mr. Walcott disclaimed any desire to make radical changes in either the policy or the administration of the Survey as developed under his predecessors, King and Powell, but in his first report, the Director's sixteenth, he mentioned certain readjustments which he deemed desirable in order that the Survey might better meet the economic and educational needs of the country. It is noteworthy that, almost without exception, these improvements have been accomplished, and even more fully than as then outlined. Among these changes may be mentioned : The raising of the standard of the topographic maps, with the representation thereon of land subdivision lines, and the extension of exact leveling and primary triangulation; the placing of the entire topographic and geologic force within the classified service; the obtaining of authority from Congress to issue separates of the annual report in pamphlet form, thus permitting advance publication of chapters of the Mineral Resources report, as well as of papers on economic geology; the enlargement of the work of the divisions of hydrography, mineral resources, and geology, in the last case providing for reconnaissance surveys of regions of economic importance. Equally notable was the growth of the Survey under Mr. Walcott's administration, as shown by the increase in both the extent and the scope of its operations. The appropriations for the last fiscal year amounted to more than four times the total of those made thirteen years ago, and there was, of course, a corresponding increase in the amount of field and office work performed. The development of the relations between the Geological Survey and the public within the same period is measured by a more than fourfold increase in amount of official correspondence, nearly fourfold increase in number of printed pages in the various reports of the year, and a more than fivefold increase in copies of maps printed, while the total annual distribution of publications, books, and maps grew from less than 200,000 to nearly a million copies, the sales increasing from $2,100 to over $18,000. The extent to which the results of the work by this organization are now utilized by both the industrial world and the educational and scientific institutions furnishes the best index of the degree of success attained by Mr. Walcott and his colleagues.

Annual Report↗

Ground-water supplies of the Ypsilanti area, Michigan

As of the date of this report (August 1945), the major water users in the Ypsilanti area are: (1) the city of Ypsilanti, (2) the Willow Run bomber plant, built by the Federal Government and operated by the Ford Motor Co., and (3) the war housing project of the Federal Public Housing Authority, designated in this report the Willow Run Townsite. The city, bomber plant, and townsite have required large quantities of water for domestic and industrial uses, and the necessary water supplies have been developed from wells. The Federal Works Agency had the responsibility of deciding whether the existing water facilities were adequate to meet the expected demands and determining the character of any additional public water-supply facilities that might be constructed with Federal assistance. In order to appraise the ground-water resources of the area the Federal Works Agency requested the Geological Survey to investigate the adequacy of the existing supplies and the availability of additional water. The present report is the result of the investigation, which was made in cooperation with the Michigan Geological Survey Division. The water supplies of the three major users are obtained from wells penetrating glacial and associated sands and gravels. Supplies for the city of Ypsilanti and the Willow Run bomber plant are obtained from wells in the valley of the Huron River; the supply for the Willow Run Townsite is obtained from wells penetrating glacial gravels underlying the upland northeast of the valley. The bedrock formations of the area either yield little water to wells or yield water that is too highly mineralized for most uses. The water supply for the bomber plant is obtained from three closely spaced, highly productive wells at the northern edge of the Huron River, a little more than 3 miles southeast of Ypsilanti. The water receives complete treatment in a modern treatment plant. River water also can be treated and has been used occasionally in the winter and spring. The average daily pumpage during periods of maximum production at the bomber plant has been 4.5 to 4.75 million gallons. On June 30, 1945, production of bombers was suspended, and the plant went on a. maintenance basis. The water supply of the bomber-plant well field is replenished by recharge from precipitation and from the Huron River. The evidence shows that recharge from the river is one of the principal sources of water and gives assurance both of the adequacy of the present supply and of the availability of additional water if needed. The safe yield of the three existing wells is estimated to be not less than 6 million gallons per day. The Ypsilanti public water supply is obtained from three tubular wells drilled in 1943, which replaced a number of suction-pumped tubular wells and one large dug well. All the wells penetrate sand and gravel in the bend of the Huron River in the southeastern part of Ypsilanti. The water is treated in a modern treatment plant completed in 1939. The average daily pumpage in million gallons was about 1.68 in 1942, 1.70 in 1943, and 1.66 in 1944. Considerable water was furnished to the Willow Run bomber plant from the Ypsilanti public-supply system during the period from August 1941 through March 1943. The available information indicates that the water pumped from the Ypsilanti well field is replenished by ground-water flow from adjacent stretches of the Huron Valley and from the upland areas outside the valley, from precipitation on the valley in the vicinity of the well field, and possibly from the Huron River. It is believed that sufficient water can be obtained from the well field to meet the expected demand for a considerable time. The safe yield of the present wells is estimated to be not less than 3 million gallons per day, and detailed pumping tests might show that still larger supplies could be safely developed. The water supply of the Willow Run Townsite is obtained from four wells in two well fields about 2 miles apart, one well in the northwest or Prospect and Geddes Road field, and three wells in the southeast or Wiard Road field. The pumpage was originally expected to be 2 to 3 million gallons per day, but it averaged only about 450,000 gallons per day from March 1943 through June 1945. The evidence afforded by logs of wells and by pumping tests indicates that the water-bearing gravels at the townsite are covered by relatively impermeable materials and thus that the rate of recharge is low. However, only relatively small declines in water level have occurred during more than 2 years' operation of the wells, indicating that recharge may occur nearby. The safe yield of the present wells is estimated to be 1.0 to 1.5 million gallons per day, and detailed pumping tests might show it to be somewhat greater. The water supply of the Willow Run Townsite has the smallest potential capacity of the three major ground-water supplies in the area; however, the demand has been relatively small, and no difficulty should arise unless this demand increases greatly. The investigation involved the drilling of 13 test wells to locate additional ground-water supplies, on the assumption that the wartime demand for water in the Ypsilanti area might increase beyond the capacity of the present sources. All 13 wells were drilled at sites selected by the Geological Survey. Two wells on the Willow Run Townsite were drilled by the Federal Public Housing Authority and 11 at other sites by the Federal Works Agency. Records of the wells are given in the report and discussed with respect to the availability of water at the different sites; similarly, the results of the controlled pumping tests made on four of the test wells drilled by the Federal Works Agency are analyzed and discussed with respect to the availability of additional water. The combined results of the test drilling and the pumping tests show that emergency supplies of several million gallons per day can be developed at the sites of the test wells. The best site shown by the test drilling is on the south bank of the Huron River opposite the bomber-plant well field, where a Well with a capacity of several thousand gallons per minute could be constructed if necessary. Three wells in the outwash-filled valley now occupied by Fleming Creek, on two of which pumping tests were made, show that emergency supplies ranging from a few hundred thousand to a million gallons per day could be developed at these test-well sites if necessary. Smaller Supplies ranging from a gallon or two per minute to perhaps 100,000 or 200,000 gallons per day could be developed at the sites of the remaining test Wells. Pumping tests made on the supply wells of the three major water users by the consulting-engineering firms who designed the systems are analyzed and discussed briefly by the authors. The report includes maps and graphs showing the surficial geology of the area, the location of wells, and fluctuations of water level in selected wells. Alsp included are tables giving data on water levels and pumpage, chemical analyses of representative ground waters, and records of wells.

Michigan↗

Shallow geologic framework of the Mississippi Sound and the potential for sediment resources

The Mississippi Sound, an estuarine environment located between the mainland and barrier islands bordering the northern Gulf of America (formerly the Gulf of Mexico), serves as a vital ecosystem for the States of Mississippi and Alabama. Spanning approximately 100 kilometers from east to west and covering 1,400 square kilometers, the sound is home to marine industry and ports, and its shallow and brackish waters sustain a diverse array of marine life. Barrier islands along the southern edge of the sound separate the microtidal estuary from the Gulf of America. This protection from gulf wave action mediates current flow within the sound, resulting in predominantly fine-grained sediment deposition along the seafloor. This study, conducted by the U.S. Geological Survey in cooperation with the U.S. Army Corps of Engineers, provides insight on fluvial and tidal processes spanning the past 5,000 years. The report synthesizes existing research to provide a comprehensive overview of the sound geology, from Pleistocene origins to present-day morphology, and utilizes high-resolution single channel seismic profiles and sediment data to identify and map sedimentary deposits and morphologic features at and below the seafloor. Despite its ecological significance, the Mississippi Sound faces environmental challenges, including water-quality issues, habitat degradation, storm-induced erosion, and the ongoing threats of sea-level rise and environmental changes. This study uses the present-day understanding of the sound's geology to inform coastal management decisions, hazard assessment, and potential mineral resources.

Louisiana, Mississippi↗

Detailed description of oil shale organic and mineralogical heterogeneity via fourier transform infrared mircoscopy

Mineralogical and geochemical information on reservoir and source rocks is necessary to assess and produce from petroleum systems. The standard methods in the petroleum industry for obtaining these properties are bulk measurements on homogenized, generally crushed, and pulverized rock samples and can take from hours to days to perform. New methods using Fourier transform infrared (FTIR) spectroscopy have been developed to more rapidly obtain information on mineralogy and geochemistry. However, these methods are also typically performed on bulk, homogenized samples. We present a new approach to rock sample characterization incorporating multivariate analysis and FTIR microscopy to provide non-destructive, spatially resolved mineralogy and geochemistry on whole rock samples. We are able to predict bulk mineralogy and organic carbon content within the same margin of error as standard characterization techniques, including X-ray diffraction (XRD) and total organic carbon (TOC) analysis. Validation of the method was performed using two oil shale samples from the Green River Formation in the Piceance Basin with differing sedimentary structures. One sample represents laminated Green River oil shales, and the other is representative of oil shale breccia. The FTIR microscopy results on the oil shales agree with XRD and LECO TOC data from the homogenized samples but also give additional detail regarding sample heterogeneity by providing information on the distribution of mineral phases and organic content. While measurements for this study were performed on oil shales, the method could also be applied to other geological samples, such as other mudrocks, complex carbonates, and soils.

Energy & Fuels↗

Mineral resource of the month: Iron and steel

Iron is one of the most abundant elements on Earth, but it does not occur in nature in a useful metallic form. Although ancient people may have recovered some iron from meteorites, it wasn’t until smelting was invented that iron metal could be derived from iron oxides. After the beginning of the Iron Age in about 1200 B.C., knowledge of iron- and steelmaking spread from the ancient Middle East through Greece to the Roman Empire, then to Europe and, in the early 17th century, to North America. The first successful furnace in North America began operating in 1646 in what is now Saugus, Mass. Introduction of the Bessemer converter in the mid-19th century made the modern steel age possible. Pig iron is a high-carbon alloy made by smelting iron ore in a blast furnace with carbonaceous material, typically coke, as a reducing agent. Limestone is added to the iron ore-coke charge as a fluxing agent to remove impurities. Steel is produced from pig iron by removing some of the carbon in a basic oxygen converter and adding several alloying elements, such as manganese, chromium, copper, nickel, titanium, molybdenum, tungsten and vanadium. Steel is also made by recycling ferrous scrap in an electric arc furnace. There are many grades of steel, but the three major types of steel are carbon, alloy and stainless. About 93 percent of the steel made in the United States is carbon steel, which contains a maximum 2 percent carbon. Applications are found in appliances, construction, shipbuilding, containers and packaging, as well as in the automotive, machinery and equipment industries. Alloy steel, about 5 percent of annual production, contains as much as 4 percent alloying elements. Special applications for alloy steel include use in machined parts and tool fabrication. Stainless steel, which accounts for about 2 percent of annual steel production, is formed by adding chromium and usually nickel to steel to make it highly corrosion-resistant. Since 2008, steelmaking capacity has greatly exceeded apparent steel consumption, primarily as a result of China’s rapid economic expansion and rapidly increasing capacity. This has resulted in an influx of steel products into the United States and other steelmaking countries that already have excess capacity. Demand by China’s steelmakers has also driven unprecedented increases in the prices of iron ore and metallurgical coal. In the short term, steelmaking capacity, globally and especially in China, is expected to continue to exceed steel consumption, with steel prices and production costs remaining stable.

Earth↗

Oil spills, 1971-75, Gulf of Mexico outer continental shelf

Oil spillage connected with federally supervised drilling and production activities has been a matter of wide public concern. In its supervision of mineral-resource development on the Outer Continental Shelf (OCS), the U.S. Geological Survey is responsible for the day-to-day inspection and monitoring of OCS oil and gas operations. During these activities, the U.S. Geological Survey records and investigates hydrocarbon discharges resulting from such operations. Beginning in 1971, all spills have been recorded, and a computer file has been maintained on all spills of 1 barrel or more. The total Gulf of Mexico OCS oil spillage recorded during January 1, 1971-December 31, 1975, amounted to 51,421 barrels. Production during that period amounted to 35,219 barrels per barrel spilled. In all, 5,857 spills were recorded, but 85.5 percent of the total spill volume was contributed by just 5 incidents. The environmental effect of these incidents apparently was minimal and of short duration. No spills of more than 50 barrels resulted from drilling operations during the period. The only spillage resulting from blowouts was caused by nondrilling incidents, including completion, production, and workover. The amount of oil discharged from spills of less than 50 barrels decreased by more than half between 1971 and 1975. The improvement reflects changes in the operating philosophy of the offshore industry, tightening of U.S. Geological Survey operating orders, and substantial increases in the inspection force. Most production-platform spills involve failures in the sump system, the separator system, or other hydrocarbon-handling equipment; improved sump-system designs and better high-low-level controls have reduced both the number and the volume of spills. Pipeline and pump spills also declined significantly, although the decline appears less attributable to revisions in OCS operating requirements. No operator consistently contributed a disproportionate amount of spillage. Most of the platforms having production spills had only one spill during the period. Of the 304 platforms having incidents, 255 had 2 spills or less and 188 had only 1 spill. Comparison of the volume spilled with the volume produced for Gulf of Mexico OCS operations during 1971-75 results in a spillage rate of 0.0028 percent. Spillage from tankers is estimated to be greater. The OCS drilling and production spillage rate is not expected to increase during exploration and development of the frontier areas.

Circular↗

Mineral commodity profiles: Silver

Overview -- Silver is one of the eight precious, or noble, metals; the others are gold and the six platinum-group metals (PGM). World mine production in 2001 was 18,700 metric tons (t) and came from mines in 60 countries; the 10 leading producing countries accounted for 86 percent of the total. The largest producer was Mexico, followed by Peru, Australia, and the United States. About 25 percent of the silver mined in the world in 2001 came from silver ores; 15 percent, from gold ores and the remaining 60 percent, from copper, lead, and zinc ores. In the United States, 14 percent of the silver mined in 2001 came from silver ores; 39 percent, from gold ores; 10 percent, from copper and copper-molybdenum ores; and 37 percent, from lead, zinc, and lead-zinc ores. The precious metal ores (gold and silver) came from 30 lode mines and 10 placer mines; the base-metal ores (copper, lead, molybdenum, and zinc) came from 24 lode mines. Placer mines yielded less than 1 percent of the national silver production. Silver was mined in 12 States, of which Nevada was by far the largest producer; it accounted for nearly one-third of the national total. The production of silver at domestic mines generated employment for about 1,100 mine and mill workers. The value of mined domestic silver was estimated to be $290 million. Of the nearly 27,000 t of world silver that was fabricated in 2001, about one-third went into jewelry and silverware, one-fourth into the light-sensitive compounds used in photography, and nearly all the remainder went for industrial uses, of which there were 7 substantial uses and many other small-volume uses. By comparison, 85 percent of the silver used in the United States went to photography and industrial uses, 8 percent to jewelry and silverware, and 7 percent to coins and medals. The United States was the largest consumer of silver followed by India, Japan, and Italy; the 13 largest consuming countries accounted for nearly 90 percent of the world total. In the United States, about 30 companies accounted for more than 90 percent of the silver fabricated. The consumption of silver for all fabrication uses is expected to grow slowly through the decade ending in 2010 at about 1.3 percent per year for the world and 2.4 percent per year for the United States. World and U.S. reserves and reserve bases are more than adequate to satisfy the demand for newly mined silver through 2010. The other components of supply will be silver recovered from scrap, silver from industrial stocks, and silver bullion that is sold into the market from commodity exchange and private stocks.

Open-File Report↗

Quantifying anthropogenic contributions to century-scale groundwater salinity changes, San Joaquin Valley, California, USA

Total dissolved solids (TDS) concentrations in groundwater tapped for beneficial uses (drinking water, irrigation, freshwater industrial) have increased on average by about 100 mg/L over the last 100 years in the San Joaquin Valley, California (SJV). During this period land use in the SJV changed from natural vegetation and dryland agriculture to dominantly irrigated agriculture with growing urban areas. Century-scale salinity trends were evaluated by comparing TDS concentrations and major ion compositions of groundwater from wells sampled in 1910 (Historic) to data from wells sampled in 1993-2015 (Modern). TDS concentrations in subregions of the SJV, the southern (SSJV), western (WSJV), northeastern (NESJV), and southeastern (SESJV) were calculated using a cell-declustering method. TDS concentrations increased in all regions, with the greatest increases found in the SSJV and SESJV. Evaluation of the Modern data from the NESJV and SESJV found higher TDS concentrations in recently recharged (post-1950) groundwater from shallow (< 50 m) wells surrounded predominantly by agricultural land uses, while premodern (pre-1950) groundwater from deeper wells, and recently recharged groundwater from wells surrounded by mainly urban, natural, and mixed land uses had lower TDS concentrations, approaching the TDS concentrations in the Historic groundwater. For the NESJV and SESJV, inverse geochemical modeling with PHREEQC indicated that weathering of primary silicate minerals accounted for the majority of the increase in TDS concentrations, contributing more than nitrate from fertilizers and sulfate from soil amendments combined. Bicarbonate showed the greatest increase among major ions, resulting from enhanced silicate weathering due to recharge of irrigation water enriched in CO2 during the growing season. The results of this study demonstrate that large anthropogenic changes to the hydrologic regime, like massive development of irrigated agriculture in semi-arid areas like the SJV, can cause large changes in groundwater quality on a regional scale.

California↗

Mercury in stream water at five Czech catchments across a Hg and S deposition gradient

The Czech Republic was heavily industrialized in the second half of the 20th century but the associated emissions of Hg and S from coal burning were significantly reduced since the 1990s. We studied dissolved (filtered) stream water mercury (Hg) and dissolved organic carbon (DOC) concentrations at five catchments with contrasting Hg and S deposition histories in the Bohemian part of the Czech Republic. The median filtered Hg concentrations of stream water samples collected in hydrological years 2012 and 2013 from the five sites varied by an order of magnitude from 1.3 to 18.0 ng L &minus; 1 . The Hg concentrations at individual catchments were strongly correlated with DOC concentrations r from 0.64 to 0.93 and with discharge r from 0.48 to 0.75. Annual export fluxes of filtered Hg from individual catchments ranged from 0.11 to 13.3 &mu;g m &minus; 2 yr &minus; 1 and were highest at sites with the highest DOC export fluxes. However, the amount of Hg exported per unit DOC varied widely; the mean Hg/DOC ratio in stream water at the individual sites ranged from 0.28 to 0.90 ng mg &minus; 1 . The highest stream Hg/DOC ratios occurred at sites Pluhův Bor and Jezeř&iacute; which both are in the heavily polluted Black Triangle area. Stream Hg/DOC was inversely related to mineral and total soil pool Hg/C across the five sites. We explain this pattern by greater soil Hg retention due to inhibition of soil organic matter decomposition at the sites with low stream Hg/DOC and/or by precipitation of a metacinnabar (HgS) phase. Thus mobilization of Hg into streams from forest soils likely depends on combined effects of organic matter decomposition dynamics and HgS-like phase precipitation, which were both affected by Hg and S deposition histories.

Journal of Geochemical Exploration↗