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At least 631 records · Page 35Linked to original sources

USGS2019

India National Gas Hydrate Program Expedition 02 summary of scientiﬁc results: Numerical simulation of reservoir response to depressurization

The India National Gas Hydrate Program Expedition 02 (NGHP-02) discovered gas hydrate at high saturation in sand reservoirs at several sites in the deepwater Bay of Bengal. To assess the potential response of those deposits to scientific depressurization experiments, comprehensive geologic models were constructed to enable numerical simulation for two sites. Both sites (NGHP-02-09 and NGHP-02-16) feature thick sequences of thinly-interbedded reservoir and non-reservoir facies at sub-seafloor depths of less than 300 m and sub-sea depths of 2,400 m or more. These settings pose significant challenges to current modeling capabilities. First, the thinly-bedded reservoir architecture complicates the determination of basic reservoir parameters from both log and core data due to measurement resolution issues. Secondly, the fine-scale variation in sediment properties imparts great contrasts in key parameters over very short distances, creating high gradients at multiple scales and varying orientations that necessitate careful design of high-definition simulation grids. Thirdly, the deposits include internal sources of water, as well as a range of complex boundary conditions, including variable permeability within the overlying mud-rich “seals”, that complicate reservoir depressurization. Lastly, because of the unique combination of great water depth and relatively shallow sub-seafloor depth, models designed to maximize the dissociation rate impose large pressure drawdowns on relatively low-strength sediments. This condition renders the proper evaluation and integration of the geomechanical response to hydrate dissociation critical. In this report, we review the history of gas hydrate reservoir simulation, discuss methods for creating geologic input models, and summarize the key findings and implications of the collaborative NGHP-02 numerical simulation effort. Together, the studies confirm the viability of the modeled accumulations for scientific testing and identify key challenges related to the selection of specific test sites and the design of test wells.

Journal of Marine and Petroleum Geology↗

USGS2019

National Gas Hydrate Program expedition 02: Identification of gas hydrate prospects in the Krishna-Godavari Basin, offshore India

After completing the first expedition of India's National Gas Hydrate Program (NGHP-01) in 2006, it was concluded that for the next expedition (National Gas Hydrate Program 02; NGHP-02), a new drill site review effort should focus on identifying potential deep-water offshore gas hydrate accumulations in sand dominated depositional environments. Therefore, geological and geophysical data analysis and 3D seismic data interpretation along with associated seismic modeling were carried out in three areas of the Krishna-Godavari Basin: Areas B, C, and E. Conventional petroleum exploration approaches of seismic amplitude evaluation were adapted to prospect for potential sand-rich depositional systems within the gas hydrate stability zone. Subsequently, these prospective areas were further assessed through the geological and geophysical evaluation of depositional setting, gas sources, and gas migration pathways. In Area B, prospecting focused on a large anticlinal structure with a prominent bottom-simulating reflector and several key horizons that indicated evidence for potential sand-hosted hydrate occurrences. In Area C, the prospects were distributed throughout various settings within a very large deep-water channel-levee-fan system with complex indications of potential gas hydrate occurrence in sand-prone seismic facies. In Area E, prospects were associated with high amplitude events within inferred channel-levee sequences. Based on the pre-expedition/onboard drill-site evaluation, the 22 most promising sites in the Krishna-Godavari Basin were identified and prioritized to investigate and delineate a total of 17 identified gas hydrate prospects. This paper describes the geo-scientific studies carried out prior to NGHP-02 for site identification, evaluation and prioritization. An important outcome of this study is the identification of two potentially producible gas hydrate systems inferred to host significant quantity of gas hydrate in stratigraphic-structural traps.

Journal of Marine and Petroleum Geology↗

USGS2022

Geochemical characterization of natural gases in the pre-salt section of the Santos Basin (Brazil) focused on hydrocarbons and volatile organic sulfur compounds

The objective of this work is to characterize the geochemistry of a suite of natural gas samples from five fields in order to improve the understanding of the lacustrine petroleum system of the pre-salt section from the Santos Basin (Brazil). Additionally, the distribution of volatile organic sulfur compounds (VOSC) in petroleum reservoirs was examined to investigate possible applications to petroleum systems assessments. The hydrocarbon gases were generated by thermogenic processes associated with the oil window. The 13 C-enriched values for C 1 (>−40‰) were interpreted as an organic source signature rather than an indication of thermal maturity, except for the oil occurrence (Field B), where a different fluid charge mainly composed of methane and CO 2 from a minor external kitchen area in the Santos Basin was identified. The molecular composition and the carbon and hydrogen isotopic data of the hydrocarbon gases, when combined with the VOSC molecular compositional data, allow the identification of four gas families associated with different kitchens and/or migrations pathways. The total VOSC concentrations range from 0.7 to 23.9 ppm by volume (ppmV). The organic sulfides are mainly composed of carbonyl sulfide (COS) and diethyl sulfide. The main thiol compound is ethanethiol. The cyclic VOSC are primarily composed of thiophene, with a negligible amount of branched thiophenes (<0.1 ppmV). H2S showed a strong positive Pearson's correlation with COS and methanethiol (MeSH) concentrations (r = 0.943 and 0.807, respectively). This suggests that COS and MeSH formation was linked to H 2 S generation and/or post-catagenetic interactions between hydrocarbons and H 2 S, mainly related to thermochemical sulfate reduction (TSR). In contrast, the distribution of higher molecular weight VOSC seems to be controlled by source rock facies, rather than H 2 S concentration. Principal component analysis of the VOSC compositional data identified some subgroups within the gas families mainly associated with TSR. The results presented in this work reveal that VOSC can be an important auxiliary tool in petroleum system studies.

Atlantic Ocean, Santos Basin↗

USGS2017

Re-Os systematics and geochemistry of cobaltite (CoAsS) in the Idaho cobalt belt, Belt-Purcell Basin, USA: Evidence for middle Mesoproterozoic sediment-hosted Co-Cu sulfide mineralization with Grenvillian and Cretaceous remobilization

We report the first study of the Re-Os systematics of cobaltite (CoAsS) using disseminated grains and massive sulfides from samples of two breccia-type and two stratabound deposits in the Co-Cu-Au Idaho cobalt belt (ICB), Lemhi subbasin to the Belt-Purcell Basin, Idaho, USA. Using a 185 Re + 190 Os spike solution, magnetic and non-magnetic fractions of cobaltite mineral separates give reproducible Re-Os analytical data for aliquot sizes of 150 to 200 mg. Cobaltite from the ICB has highly radiogenic 187 Os/ 188 Os ratios (17–45) and high 187 Re/ 188 Os ratios (600–1800) but low Re and total Os contents (ca. 0.4–4 ppb and 14–64 ppt, respectively). Containing 30 to 74% radiogenic 187 Os, cobaltite from the ICB is amenable to Re-Os age determination using the isochron regression approach. Re-Os data for disseminated cobaltite mineralization in a quartz-tourmaline breccia from the Haynes-Stellite deposit yield a Model 1 isochron age of 1349 ± 76 Ma (2σ, n = 4, mean squared weighted deviation MSWD = 2.1, initial 187 Os/ 188 Os ratio = 4.7 ± 2.2). This middle Mesoproterozoic age is preserved despite a possible metamorphic overprint or a pulse of metamorphic-hydrothermal remobilization of pre-existing cobaltite that formed along fold cleavages during the ca. 1190–1006 Ma Grenvillian orogeny. This phase of remobilization is tentatively identified by a Model 3 isochron age of 1132 ± 240 Ma (2σ, n = 7, MSWD = 9.3, initial 187 Os/ 188 Os ratio of 9.0 ± 2.9) for cobaltite in the quartz-tourmaline breccia from the Idaho zone in the Blackbird mine. All Mesoproterozoic cobaltite mineralization in the district was affected by greenschist- to lower amphibolite-facies (garnet zone) metamorphism during the Late Jurassic to Late Cretaceous Cordilleran orogeny. However, the fine- to coarse-grained massive cobaltite mineralization from the shear zone-hosted Chicago zone, Blackbird mine, is the only studied deposit that has severely disturbed Re-Os systematics with evidence for a linear trend of mixing with (metamorphic?) fluids. The new Re-Os ages and extremely high initial 187 Os/ 188 Os ratios of cobaltite reported here favor a magmatic-hydrothermal genetic model for a multi-stage REE-Y-Co-Cu-Au mineralization occurring at ca. 1370 to 1349 Ma, and related to the emplacement of the Big Deer Creek granite pluton at ca. 1377 Ma. In our model, deposition of paragenetically early xenotime and gadolinite was followed by an influx of Mesoproterozoic evaporitic brines and magmatic-hydrothermal fluids containing metals and reduced sulfur derived from mafic and oceanic island-arc Archean to Paleoproterozoic rocks in the Laurentian basement. Cobaltite mineralization occurred upon cooling of these fluids at an inferred temperature of 300 °C or below.

Idaho↗

USGS2009

Comparison of natural gases accumulated in Oligocene strata with hydrous pyrolysis gases from Menilite Shales of the Polish Outer Carpathians

This study examined the molecular and isotopic compositions of gases generated from different kerogen types (i.e., Types I/II, II, IIS and III) in Menilite Shales by sequential hydrous pyrolysis experiments. The experiments were designed to simulate gas generation from source rocks at pre-oil-cracking thermal maturities. Initially, rock samples were heated in the presence of liquid water at 330 ??C for 72 h to simulate early gas generation dominated by the overall reaction of kerogen decomposition to bitumen. Generated gas and oil were quantitatively collected at the completion of the experiments and the reactor with its rock and water was resealed and heated at 355 ??C for 72 h. This condition simulates late petroleum generation in which the dominant overall reaction is bitumen decomposition to oil. This final heating equates to a cumulative thermal maturity of 1.6% R r , which represents pre-oil-cracking conditions. In addition to the generated gases from these two experiments being characterized individually, they are also summed to characterize a cumulative gas product. These results are compared with natural gases produced from sandstone reservoirs within or directly overlying the Menilite Shales. The experimentally generated gases show no molecular compositions that are distinct for the different kerogen types, but on a total organic carbon (TOC) basis, oil prone kerogens (i.e., Types I/II, II and IIS) generate more hydrocarbon gas than gas prone Type III kerogen. Although the proportionality of methane to ethane in the experimental gases is lower than that observed in the natural gases, the proportionality of ethane to propane and i-butane to n-butane are similar to those observed for the natural gases. ?? 13 C values of the experimentally generated methane, ethane and propane show distinctions among the kerogen types. This distinction is related to the ?? 13 C of the original kerogen, with 13 C enriched kerogen generating more 13 C enriched hydrocarbon gases than kerogen less enriched in 13 C. The typically assumed linear trend for ?? 13 C of methane, ethane and propane versus their reciprocal carbon number for a single sourced natural gas is not observed in the experimental gases. Instead, the so-called "dogleg" trend, exemplified by relatively 13 C depleted methane and enriched propane as compared to ethane, is observed for all the kerogen types and at both experimental conditions. Three of the natural gases from the same thrust unit had similar "dogleg" trends indicative of Menilite source rocks with Type III kerogen. These natural gases also contained varying amounts of a microbial gas component that was approximated using the ???? 13 C for methane and propane determined from the experiments. These approximations gave microbial methane components that ranged from 13-84%. The high input of microbial gas was reflected in the higher gas:oil ratios for Outer Carpathian production (115-1568 Nm 3 /t) compared with those determined from the experiments (65-302 Nm 3 /t). Two natural gas samples in the far western part of the study area had more linear trends that suggest a different organic facies of the Menilite Shales or a completely different source. This situation emphasizes the importance of conducting hydrous pyrolysis on samples representing the complete stratigraphic and lateral extent of potential source rocks in determining specific genetic gas correlations. ?? 2009 Elsevier Ltd.

Organic Geochemistry↗

USGS2019

Geochemistry of a thermally immature Eagle Ford Group drill core in central Texas

The Upper Cretaceous Eagle Ford Group displays significant lateral and vertical geochemical variability. Much of the work on the Eagle Ford Group has been focused southwest of the San Marcos arch. To more fully characterize the Eagle Ford across the entire region, a thermally immature drill core was acquired north of the San Marcos arch that recovered the Pepper Shale and the Eagle Ford Group. Molecular and isotopic analyses of rock extracts were combined with bulk organic and inorganic geochemistry and mineralogy to track the variability in organic matter source and depositional environment, as well as to identify drivers of organic enrichment. The Pepper Shale received significant terrigenous organic matter in its distal deltaic or prodeltaic setting compared to the more distally deposited Eagle Ford Group that primarily hosts marine organic matter. The upper Eagle Ford contains two chemofacies. The older upper Eagle Ford chemofacies has similar mineralogy and organic matter to the underlying lower Eagle Ford, and both intervals display good to excellent source rock potential. In contrast, the younger upper Eagle Ford chemofacies has a different sterane assemblage, a larger terrigenous component, and a higher clay mineral abundance. However, anoxic to euxinic depositional conditions distinguish the lower Eagle Ford from the upper Eagle Ford, which was deposited under oxic to dysoxic conditions. Redox chemistry and organic matter source are two important variables that determine source rock quality, but they did not change in parallel during Eagle Ford deposition. Differences in organic facies explain the Tmax variability, and depositional redox conditions governed organic-richness in the Eagle Ford Group in central Texas.

Texas↗

USGS2007

Holocene sea-level oscillations and environmental changes on the Eastern Black Sea shelf

A multi-proxy study of four sediment cores from the Eastern (Caucasian) Black Sea shelf revealed five transgressive-regressive cycles overprinted on the general trend of glacioeustatic sea-level rise during the last 11,000??14C yr. These cycles are well represented in micro-and macrofossil assemblages, sedimentation rates, and grain size variations. The oldest recovered sediments were deposited in the Neoeuxinian semi-freshwater basin (??? 10,500-9000??14C yr BP) and contain a Caspian-type mollusk fauna dominated by Dreissena rostriformis. Low ??18O and ??13C values are measured on this species. The first appearance of marine mollusks and ostracodes from the Mediterranean is established in this part of the Black Sea at ??? 8200??14C yr BP, i.e., about 1000-2000??yr later than the appearance of marine microfossils in the deeper part of the sea. The Early Holocene (Bugazian to Vityazevian) condensed section of shell and shelly mud sediments with at least two hiatuses represent a high-energy shelf-edge facies. It contains a transitional assemblage representing a mixture of Caspian and Mediterranean fauna. This pattern suggests a dual-flow regime via the Bosphorus after 8200??14C yr BP. Caspian species disappear and oligohaline species decrease in abundance during the Vityazevian-Prekalamitian cycle. Later, during the Middle to Late Holocene, low sea-level stands are characterized by shell layers, whereas silty mud with various mollusk and ostracode assemblages rapidly accumulated during transgressions. Restricted mud accumulation, as well as benthic faunal composition and abundance, suggest high-energy and well-ventilated bottom water during low sea-level stands. A trend of 18O enrichment in mollusk shells points to an increase in bottom-water salinity during the Vityazevian to Kalamitian transgressions (??? 7000 to 5700??14C yr BP) due to a more open connection with the Mediterranean, while a pronounced increase in polyhaline species abundance is established during the Kalamitian to Djemetean transgressions (??? 6400 to 2700??14C yr BP). However, the composition of the faunal assemblage indicates that bottom-water salinity never exceeded modern values of 18-20??psu. ?? 2006 Elsevier B.V. All rights reserved.

Palaeogeography, Palaeoclimatology, Palaeoecology↗

USGS2015

Uranium-series ages of fossil corals from Mallorca, Spain: The "Neotyrrhenian" high stand of the Mediterranean Sea revisited

The emergent marine deposits of the Mediterranean basin have been recognized as an important record of Quaternary sea level history for more than a century. Previous workers identified what have been interpreted to be two separate high stands of sea in the late Quaternary, namely the “Eutyrrhenian” (thought to be ~ 120 ka) and the “Neotyrrhenian” (thought to be either ~ 100 ka or ~ 80 ka). On Mallorca, Spain, both of these named deposits lie close to present sea level, implying paleo-sea levels slightly above present during both marine isotope stages (MIS) 5.5/5e and either 5.3/5c or 5.1/5a. If these interpretations are correct, they conflict, at least in part, with sea level records from far-field localities. We analyzed corals from the Neotyrrhenian beds on Mallorca, which gave U-series ages from ~ 126 ka to ~ 118 ka. These ages are consistent with previously published amino acid data that show that the Neotyrrhenian and Eutyrrhenian deposits are not significantly different in age. A fossil molluscan fauna from the Neotyrrhenian deposits on Mallorca has a warm-water paleozoogeographic aspect, with nine southward-ranging species and four extralimital southern species. When compared with sea surface temperatures obtained from planktonic foraminifera and alkenones from ODP core 977 in the nearby Alboran Sea, the only time period that shows comparable warmth is MIS 5.5/5e, consistent with the U-series ages of corals from the Neotyrrhenian deposits. We propose that the Neotyrrhenian deposits are a beachrock facies of the same age as the Eutyrrhenian deposits. This interpretation is consistent with the differences in physical sedimentology of the two deposits, explains the U-series and amino acid data indicating the same age, is consistent with the very slight elevation difference of the Neotyrrhenian and Eutyrrhenian beds, and explains the similar, though not identical paleozoogeographic aspects of their fossil faunas.

Mallorca↗

USGS2019

Paleoclimate of the subtropical Andes during the latest Miocene, Lauca Basin, Chile

Uplift of the Andean Cordillera during the Miocene and Pliocene produced large-scale changes in regional atmospheric circulation that impacted local ecosystems. The Lauca Basin (northern Chilean Altiplano) contains variably fluvial and lacustrine sedimentary sequences spanning the interval from 8.7 to 2.3 Ma. Field samples were collected from paleo-lacustrine sediments in the basin. Sediments were dated using detrital zircon geochronology on volcanic tuffs, yielding an age range between ~5.57 and 5.44 Ma. These new age constraints provided an opportunity to evaluate changes in the Lauca Basin ecosystem across this dynamic Miocene-Pliocene transition. We employed multiple proxies (lithofacies analysis, diatoms, pollen, and oxygen stable isotopes of authigenic carbonates) to interpret ancient lacustrine and terrestrial paleoenvironments. Alternations among mudstone, carbonate, and evaporitic facies indicate lake-level variability through time. The diatom assemblage is characterized by meso- to hypersaline and alkaline-tolerant taxa typical of shallow lakes. The δ 18 O values ranged from −8.96 to −2.22‰ indicating fluctuations in water balance. Pollen taxa in the outcrop are typical of a transitional stage between seasonal cloud forest and open grassland. Together, these proxies indicate that the Lauca paleolake sediments were deposited under a wetter-than-modern climate with high temporal variability. Our results refine previous studies in the Lauca Basin and are consistent with other regional studies suggesting that the South American summer monsoon at the Miocene-Pliocene transition was more intense than it is at present.

Palaeogeography, Palaeoclimatology, Palaeoecology↗

USGS2005

U-Pb zircon geochronology of Mesoproterozoic postorogenic rocks and implications for post-Ottawan magmatism and metallogenesis, New Jersey Highlands and contiguous areas, USA

Postorogenic rocks are widespread in Grenville terranes of the north-central Appalachians where they form small, discordant, largely pegmatitic felsic intrusive bodies, veins, and dikes, and also metasomatic calcic skarns that are unfoliated and postdate the regional 1090 to 1030 Ma upper amphibolite- to granulite-facies metamorphism related to the Grenville (Ottawan) Orogeny. Zircons from magmatic and nonmagmatic rocks from northern New Jersey and southern New York were dated to provide information on the regional tectonomagmatic and metallogenic history following Ottawan orogenesis. We obtained U-Th-Pb zircon ages of 1004 ?? 3 Ma for pegmatite associated with the 1020 ?? 4 Ma Mount Eve Granite near Big Island, New York, 986 ?? 4 Ma for unfoliated, discordant pegmatite that intrudes supracrustal marble at the Buckwheat open cut, Franklin, New Jersey, ???990 Ma for a silicate-borate skarn layer in the Franklin Marble at Rudeville, New Jersey, and 940 ?? 2 Ma for a calc-silicate skarn layer at Lower Twin Lake, New York. This new data, together with previously published ages of 1020 ?? 4 to 965 ?? 10 Ma for postorogenic rocks from New Jersey and southern New York, provide evidence of magmatic activity that lasted for up to 60 Ma past the peak of high-grade metamorphism. Postorogenic magmatism was almost exclusively felsic and involved relatively small volumes of metaluminous to mildly peraluminous melt that fractionated from an A-type granite parent source. Field relationships suggest the melts were emplaced along lithosphere-scale fault zones in the Highlands that were undergoing extension and that emplacement followed orogenic collapse by least 30 Ma. Postorogenic felsic intrusions correspond to the niobium-yttrium-fluorine (NYF) class of pegmatites of C??erny?? (1992a). Geochronologic data provide a temporal constraint on late-stage hydrothermal activity and a metallogenic event in New Jersey at ???990 to 940 Ma that mineralized pegmatites with subeconomic to economic deposits of magnetite ?? U ?? Th ?? rare earth element (REE) and formed metasomatic calcic skarn bodies in marble and reactive carbonate rocks. Mineralization associated with this event overlaps the timing of pegmatite emplacement, suggesting a petrogenetic relationship. Coeval metallogeny at 975 to 950 Ma in the New York Hudson Highlands and 980 to 937 Ma in the Canadian Grenville Province implies that this event was widespread following the Ottawan phase of the Grenville Orogeny. ?? 2005 Elsevier B.V. All rights reserved.

Precambrian Research↗

USGS2021

New interpretations of the ages and origins of the Hawkeye Granite Gneiss and Lyon Mountain Granite Gneiss, Adirondack Mountains, NY: Implications for the nature and timing of Mesoproterozoic plutonism, metamorphism, and deformation

The Hawkeye Granite Gneiss and Lyon Mountain Granite Gneiss are widespread Mesoproterozoic plutonic rocks that occur in the amphibolite- to granulite-facies Adirondack Highlands of northern New York, USA. The strongly deformed Hawkeye Granite Gneiss, previously dated by zircon multi-grain thermal ionization mass spectrometry (TIMS) U-Pb analyses at about 1100 Ma, was intruded by the weakly deformed Lyon Mountain Granite Gneiss. Previous sensitive high resolution ion microprobe (SHRIMP) analyses of Lyon Mountain Granite Gneiss zircon rims were considered to record the time of igneous emplacement at about 1.05 Ga, whereas the ages of zircon cores (~1.15 Ga) were interpreted as being inherited from nearby metaigneous country rocks. This interpretation has formed the basis of numerous models for the Mesoproterozoic structural and tectonic evolution of the Adirondacks Highlands. New U-Pb spot analyses (~15-20 µm diameter) by SHRIMP from four samples of Hawkeye Granite Gneiss and eight samples of Lyon Mountain Granite Gneiss challenge the historically accepted ages of the rocks. Using a combination of high-resolution CL imagery of oscillatory zoned cores and weakly zoned to unzoned rims, SHRIMP U-Pb geochronology, SHRIMP trace element geochemistry, and SEM petrography, we conclude that: (1) the Hawkeye Granite Gneiss was emplaced at about 1160 to 1155 Ma; (2) the vast majority of Lyon Mountain Granite Gneiss zircon cores yield ages of 1150 to 1145 Ma and are mainly primary, not inherited; and (3) the Hawkeye Granite Gneiss and Lyon Mountain Granite Gneiss zircon rims (~1080 to 1000 Ma) are metamorphic in origin, not igneous. Thus, both the Hawkeye Granite Gneiss and Lyon Mountain Granite Gneiss are considered herein to be late members of the mangerite-charnockite-granite (MCG) plutonic suite, emplaced during the waning stages of the Shawinigan orogeny. Zircon cores from two small plutons of largely undeformed fayalite granite of the Lyon Mountain Granite Gneiss are about 1142 Ma, providing a minimum age constraint for the termination of the Shawinigan. Zircon rim ages can be deconvoluted into multiple metamorphic events of the Ottawan and Rigolet tectonothermal events. These new interpretations have profound implications for structural, tectonic, and ore deposit models of the Adirondacks Highlands.

New York↗

USGS2014

Pluvial lakes in the Great Basin of the western United States: a view from the outcrop

Paleo-lakes in the western United States provide geomorphic and hydrologic records of climate and drainage-basin change at multiple time scales extending back to the Miocene. Recent reviews and studies of paleo-lake records have focused on interpretations of proxies in lake sediment cores from the northern and central parts of the Great Basin. In this review, emphasis is placed on equally important studies of lake history during the past ∼30 years that were derived from outcrop exposures and geomorphology, in some cases combined with cores. Outcrop and core records have different strengths and weaknesses that must be recognized and exploited in the interpretation of paleohydrology and paleoclimate. Outcrops and landforms can yield direct evidence of lake level, facies changes that record details of lake-level fluctuations, and geologic events such as catastrophic floods, drainage-basin changes, and isostatic rebound. Cores can potentially yield continuous records when sampled in stable parts of lake basins and can provide proxies for changes in lake level, water temperature and chemistry, and ecological conditions in the surrounding landscape. However, proxies such as stable isotopes may be influenced by several competing factors the relative effects of which may be difficult to assess, and interpretations may be confounded by geologic events within the drainage basin that were unrecorded or not recognized in a core. The best evidence for documenting absolute lake-level changes lies within the shore, nearshore, and deltaic sediments that were deposited across piedmonts and at the mouths of streams as lake level rose and fell. We review the different shorezone environments and resulting deposits used in such reconstructions and discuss potential estimation errors. Lake-level studies based on deposits and landforms have provided paleohydrologic records ranging from general changes during the past million years to centennial-scale details of fluctuations during the late Pleistocene and Holocene. Outcrop studies have documented the integration histories of several important drainage basins, including the Humboldt, Amargosa, Owens, and Mojave river systems, that have evolved since the Miocene within the active tectonic setting of the Great Basin; these histories have influenced lake levels in terminal basins. Many pre-late Pleistocene lakes in the western Great Basin were significantly larger and record wetter conditions than the youngest lakes. Outcrop-based lake-level data provide important checks on core-based proxy interpretations; we discuss four such comparisons. In some cases, such as for Lakes Owens and Manix, outcrop and core data synthesis yields stronger and more complete records; in other cases, such as for Bonneville and Lahontan, conflicts point toward reconsideration of confounding factors in interpretation of core-based proxies.

Great Basin↗

USGS2020

Late Quaternary evolution and stratigraphic framework influence on coastal systems along the north-central Gulf of Mexico, USA

Coastal systems in the Gulf of Mexico are threatened by reduced sediment supply, storm impacts and relative sea-level rise (RSLR). The geologic record provides insight into geomorphic evolution thresholds to these forcing mechanisms to help predict future barrier evolution in response to climate change. This study synthesizes ∼2100 km of geophysical data, 700 + sediment cores, and 62 radiocarbon dates to regionally map two lowstand sequence boundaries, multiple ravinement surfaces and fourteen depositional facies demonstrating stratigraphic and antecedent topographic influences on coastal evolution. The Mississippi-Alabama (MSAL) barriers are anchored by a marine isotope stage (MIS) 5e section of Dauphin Island coupled with an MIS 2 surface gradient change. Sand for the modern MSAL barriers were largely sourced through Holocene transgressive ravinement of relict valley fill deposits, providing up to 300 × 106 m3 of sand. Mud-filled MIS 2 tributaries correspond to areas of repeated storm breaching or tidal inlets. A Holocene geomorphic evolutionary model was created for Petit Bois and Dauphin Islands, highlighting RSLR rates, changes in sediment supply and the antecedent geologic framework. As the MIS 2 surface was flooded, tidal/wave scour supplied sand to migrating marine shoals. These transgressing shoals converted drowned paleovalleys to estuaries ∼9ka BP. Islands formed in their modern positions ∼6ka BP, when sediment supply was high and RSLR rates were 2 mm/yr. Between ∼4ka-1750 CE, islands prograded from reduced RSLR rates of 1-0.4 mm/yr and sufficient sand supply from alongshore/inner shelf sources. Currently, the islands experience 3.74 mm/yr of RSLR and reduced sediment supply, resulting in barrier degradation.

Alabama, Mississippi↗

USGS2025

Reconstructing late Pleistocene relative sea levels on transgressed shelves: An example from central California

Although prevalent for the late Holocene, relative sea level (RSL) constraints during and immediately after the Last Glacial Maximum (LGM) are sparse. This scarcity of data is particularly pronounced along mid-latitude shelves such as central California, which lack post LGM RSL constraints older than 12 ka. In this study we collected 7 sediment cores and high-resolution seismic data from Estero Bay to constrain RSLs across the central California shelf between ∼9 and ∼16 ka. We reconstructed these RSLs using two sea-level indicators found within our sediment cores: the wave ravinement shell hash burial surface (WRSHBS) and the sedimentary contact between offshore mud facies and ripple cross-laminated sands. To determine the indicative meaning of these two sea-level indicators, we examined the relationship between the local wave regime, modern bathymetric profiles, and the depth of preservation of each sea-level indicator. After correcting for tectonic uplift, we estimated sea levels in central California to have been ∼39 ± 7.5 and 49 ± 7.5 m below present sea level between 9 and 12 ka, in agreement with previous RSL reconstructions along this coast. Between 13.8 and 15.9 ka, we estimate sea levels to have reached ∼86 ± 8–99 ± 8 m below present sea level. Our findings offer a Late Pleistocene RSL reconstruction for central California and develop new methodologies for estimating past RSLs on similar mid-latitude shelves.

California↗

USGS2004

Late Quaternary glaciation of the Upper Soca River Region (Southern Julian Alps, NW Slovenia)

Extent of Late Quaternary glaciers in the Upper Soc??a River Region (Southern Julian Alps, SE Europe) has been analyzed using a combination of geological mapping, glaciological modeling, and sediment dating (radiocarbon, U/Th series and Infrared Stimulated Luminescence-IRSL). Field investigations focused mainly on relatively well preserved Quaternary sequences in the Bovec Basin, an intramontane basin located SW of the Mediterranean/Black Sea divide and surrounded by mountain peaks reaching from approximately 2100 up to 2587 m a.s.l. Within the Basin we recognized two Late Quaternary sedimentary assemblages, which consist of the same facies association of diamictons, laminated lacustrine deposits and sorted fluvial sediments. Radiocarbon dating of the upper part of the lake sediments sequence (between 12790??85 and 5885??60 14C years b.p.) indicates that the younger sedimentary assemblage was deposited during the last glacial maximum and through early Holocene (Marine Isotope Stage 21, MIS 2-1). Sediment ages obtained for the older assemblage with U/Th and IRSL techniques (between 154.74??22.88 and 129.93??7.90 ka b.p. for selected samples) have large errors but both methods yield results consistent with deposition during the penultimate glacial-interglacial transition (MIS 6-5). Based on analyses of field data combined with glaciological modeling, we argue that both sediment complexes formed due to high sediment productivity spurred by paraglacial conditions with glaciers present in the uplands around the Bovec Basin but not extending down to the basin floor. Our study shows that the extent and intensity of direct glacial sedimentation by Late Quaternary glaciers in the region was previously significantly overestimated. ?? 2004 Elsevier B.V. All rights reserved.

Sedimentary Geology↗

USGS2005

Unexpected trend in the compositional maturity of second-cycle sand

It is generally accepted that recycling of sandstone generates relatively more mature sand than its parent sandstone. Such maturity is accomplished mainly through chemical weathering as the chemically unstable minerals are eliminated. Because chemical weathering is ubiquitous on the Earth's surface, maturity due to recycling is expected in most geological settings. However, contrary to one's expectation, second-cycle Holocene sand, exclusively derived from sandy facies of the first-cycle Pennsylvanian-Permian Cutler Formation, is actually less mature than its first-cycle parent near Gateway, Colorado. Both the Cutler sandstone and Holocene sand were the products of similar geological processes that controlled their respective composition. In spite of such similarities, a significant difference in composition is observed. We propose that the unexpected immaturity in second-cycle Holocene sand may be due to mechanical disintegration of coarse-grained feldspar and feldspar-rich rock fragments into relatively smaller fractions. Results presented in this paper are the first quantitative estimation of recycling of parent sandstone into daughter sand, and the first observed reverse maturity trend in second-cycle sand. These unexpected results suggest the need for further research to quantitatively understand the recycling process. ?? 2005 Elsevier B.V. All rights reserved.

Sedimentary Geology↗

USGS2017

Rapid Holocene coastal change revealed by high-resolution micropaleontological analysis, Pamlico Sound, North Carolina, USA

Foraminiferal analyses of 404 contiguous samples, supported by diatom, lithologic, geochronologic and seismic data, reveal both rapid and gradual Holocene paleoenvironmental changes in an 8.21-m vibracore taken from southern Pamlico Sound, North Carolina. Data record initial flooding of a latest Pleistocene river drainage and the formation of an estuary 9000. yr ago. Estuarine conditions were punctuated by two intervals of marine influence from approximately 4100 to 3700 and 1150 to 500. cal. yr BP. Foraminiferal assemblages in the muddy sand facies that accumulated during these intervals contain many well-preserved benthic foraminiferal species, which occur today in open marine settings as deep as the mid shelf, and significant numbers of well-preserved planktonic foraminifera, some typical of Gulf Stream waters. We postulate that these marine-influenced units resulted from temporary destruction of the southern Outer Banks barrier islands by hurricanes. The second increase in marine influence is coeval with increased rate of sea-level rise and a peak in Atlantic tropical cyclone activity during the Medieval Climate Anomaly. This high-resolution analysis demonstrates the range of environmental variability and the rapidity of coastal change that can result from the interplay of changing climate, sea level and geomorphology in an estuarine setting. ?? 2011 University of Washington.

North Carolina↗

USGS1998

Rare earth element metasomatism in hydrothermal systems: The Willsboro-Lewis wollastonite ores, New York, USA

Wollastonite ores and garnet-pyroxene skarns in the Willsboro-Lewis district, New York, USA were formed in a complex hydrothermal system associated with the emplacement of a large anorthosite pluton. Contact-metamorphic marbles were replaced by wollastonite, garnet, and clinopyroxene during infiltration metasomatism involving large volumes of water of chiefly meteoric origin. Rare earth elements (REE) in these rocks show large departures from the protolith REE distribution, indicative of substantial REE mobility. Three types of chondrite-normalized REE distribution patterns are present. The most common, found in ores and skarns containing andradite-rich garnet, is convex-up in the light REE (LREE) with a maximum at Pr and a positive Eu anomaly. Europium anomalies and Pr/Yb ratios are correlated with X(Ad) in garnet. This pattern (type C) results from uptake of REE from hydrothermal fluids by growing crystals of calcsilicate minerals, principally andradite, with amounts of LREE controlled by the difference in ionic radius between Ca++ and REE3+ in garnet X sites. The Eu anomaly results either from prior interaction of the fluids with plagioclase-rich, Eu-positive anorthositic rocks in and near the ore zone, or by enrichment of divalent Eu on growth surfaces of garnet followed by entrapment, or both. Relative enrichment in heavy REE (type H) occurs in ores and skarn where calcsilicates, including grossularitic garnet, in contact-metamorphic marble have been concentrated by dissolution of calcite. In most cases a negative Eu anomaly is inherited from the marble protolith. Skarns containing titanite and apatite exhibit high total REE, relative light REE enrichment, and negative Eu anomalies (type L). These appear to be intrusive igneous rocks (ferrodiorites or anorthositic gabbros) that have been converted to skarn by Ca metasomatism. REE, sequestered in titanite, apatite, and garnet, preserve the approximate REE distribution pattern of the igneous protolith. Post-ore granulite facies metamorphism homogenized zoned mineral grains without causing complete intergranular reequilibration and does not appear to have significantly affected the whole-rock REE distributions. These results demonstrate that extensive REE metasomatism can occur in hydrothermal systems at shallow to intermediate depths and that REE geochemistry may be useful in discerning the origin of skarns and skarn-related ore deposits.

Geochimica et Cosmochimica Acta↗