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At least 631 records · Page 35Linked to original sources

Stable Carbon Isotopes of HCO3 in the Aquia Aquifer, Maryland: Evidence for an Isotopically Heavy Source of CO2

Concentrations of HCO 3 and δ 13 C values of dissolved inorganic carbon change along the hydrologic gradient of the Aquia aquifer. In the outcrop area, meteoric recharge rapidly dissolves carbonate shell material (δ 13 C ∼ 0.0 per mil) in the presence of soil-gas CO 2 (δ 13 C∼–26 per mil). HCO 3 concentrations in this area range from 150-200 mg/1 and δ 13 C values of dissolved HCO 3 are approximately –13.0 per mil. Concentrations of HCO 3 decrease gradually (to about 130 mg/1) and δ 13 C values become slightly heavier (to about –11.4 per mil) as water flows away from the outcrop area. These trends reflect progressive dissolution of metastable carbonate shell material and subsequent precipitation of secondary calcite cement. At about 40 miles downgradient in the flow system, HCO 3 concentrations increase sharply (to about 400 mg/1), and δ 13 C values become significantly heavier (δ 13 C ∼–6.2 per mil). The observed 1:1 molar ratio of Na + to HCO - 3 in this downgradient water shows that dissolution of isotopically heavy carbonate shell material cannot by itself explain the observed δ 13 C trend. Rather, the Na:HCO - 3 ratio demonstrates that shell material dissolution must take place in the presence of CO 2 . Because the aquifer in this area is closed to both soil-gas and atmospheric CC>2, an aquifer-generated source of isotopically heavy (δ 13 C ∼–5.3 per mil) CO 2 is implied. Possible sources of aquifer-generated CO 2 include bacterially-mediated fermentation of lignitic aquifer materials and bacterially-mediated methanogenesis.

Ground Water↗

Correcting for diffusion in carbon-14 dating of ground water

It has generally been recognized that molecular diffusion can be a significant process affecting the transport of carbon-14 in the subsurface when occurring either from a permeable aquifer into a confining layer or from a fracture into a rock matrix. An analytical solution that is valid for steady-state radionuclide transport through fractured rock is shown to be applicable to many multilayered aquifer systems. By plotting the ratio of the rate of diffusion to the rate of decay of carbon-14 over the length scales representative of several common hydrogeologic settings, it is demonstrated that diffusion of carbon-14 should often be not only a significant process, but a dominant one relative to decay. An age-correction formula is developed and applied to the Bangkok Basin of Thailand, where a mean carbon-14-based age of 21,000 years was adjusted to 11,000 years to account for diffusion. This formula and its graphical representation should prove useful for many studies, for they can be used first to estimate the potential role of diffusion and then to make a simple first-order age correction if necessary.

Groundwater↗

Potentially bioavailable natural organic carbon and hydrolyzable amino acids in aquifer sediments

This study evaluated the relationship between concentrations of operationally defined potentially bioavailable organic -carbon (PBOC) and hydrolyzable amino acids (HAAs) in sediments collected from a diverse range of chloroethene--contaminated sites. Concentrations of PBOC and HAA were measured using aquifer sediment samples collected at six selected study sites. Average concentrations of total HAA and PBOC ranged from 1.96 ± 1.53 to 20.1 ± 25.6 mg/kg and 4.72 ± 0.72 to 443 ± 65.4 mg/kg, respectively. Results demonstrated a statistically significant positive relationship between concentrations of PBOC and total HAA present in the aquifer sediment (p < 0.05). Higher levels of HAA were consistently observed at sites with greater levels of PBOC and first-order decay rates. Because amino acids are known to be readily biodegradable carbon compounds, this relationship suggests that the sequential chemical extraction procedure used to measure PBOC is a useful indicator of bioavailable carbon in aquifer sediments. This, in turn, is consistent with the interpretation that PBOC measurements can be used for estimating the amount of natural organic carbon available for driving the reductive dechlorination of chloroethenes in groundwater systems.

Ground Water Monitoring and Remediation↗

Nonstructural leaf carbohydrates dynamics of Pinus edulis during drought-induced tree mortality reveal role for carbon metabolism in mortality mechanism

* Vegetation change is expected with global climate change, potentially altering ecosystem function and climate feedbacks. However, causes of plant mortality, which are central to vegetation change, are understudied, and physiological mechanisms remain unclear, particularly the roles of carbon metabolism and xylem function. * We report analysis of foliar nonstructural carbohydrates (NSCs) and associated physiology from a previous experiment where earlier drought-induced mortality of Pinus edulis at elevated temperatures was associated with greater cumulative respiration. Here, we predicted faster NSC decline for warmed trees than for ambient-temperature trees. * Foliar NSC in droughted trees declined by 30% through mortality and was lower than in watered controls. NSC decline resulted primarily from decreased sugar concentrations. Starch initially declined, and then increased above pre-drought concentrations before mortality. Although temperature did not affect NSC and sugar, starch concentrations ceased declining and increased earlier with higher temperatures. * Reduced foliar NSC during lethal drought indicates a carbon metabolism role in mortality mechanism. Although carbohydrates were not completely exhausted at mortality, temperature differences in starch accumulation timing suggest that carbon metabolism changes are associated with time to death. Drought mortality appears to be related to temperature-dependent carbon dynamics concurrent with increasing hydraulic stress in P. edulis and potentially other similar species.

New Phytologist↗

Groundwater residence time estimates obscured by anthropogenic carbonate

Groundwater is an important source of drinking and irrigation water. Dating groundwater informs its vulnerability to contamination and aids in calibrating flow models. Here, we report measurements of multiple age tracers ( 14 C, 3 H, 39 Ar, and 85 Kr) and parameters relevant to dissolved inorganic carbon (DIC) from 17 wells in California’s San Joaquin Valley (SJV), an agricultural region that is heavily reliant on groundwater. We find evidence for a major mid-20th century shift in groundwater DIC input from mostly closed- to mostly open-system carbonate dissolution, which we suggest is driven by input of anthropogenic carbonate soil amendments. Crucially, enhanced open-system dissolution, in which DIC equilibrates with soil CO 2 , fundamentally affects the initial 14 C activity of recently recharged groundwater. Conventional 14 C dating of deeper SJV groundwater, assuming an open system, substantially overestimates residence time and thereby underestimates susceptibility to modern contamination. Because carbonate soil amendments are ubiquitous, other groundwater-reliant agricultural regions may be similarly affected.

California↗

Methane-derived marine carbonates of pleistocene age

In some calcium carbonate-bearing sandstones from the edge of the continental shelf off the northeast United States, the δC 13 range is from -30 and -60 per mil for both aragonite and high-magnesium calcite. The δC 13 of co-existing shells of Modiolus sp. is normal (+ 1.7 to -2.7 per mil). The δO 18 values of around + 3.5 per mil in all samples suggest deposition at temperatures around 0°C. Quaternary methane oxidized either chemically or microbiologically to carbon dioxide is the probable source of carbon in these carbonates.

Science↗

Sensitivity of boreal forest carbon balance to soil thaw

We used eddy covariance; gas-exchange chambers; radiocarbon analysis; wood, moss, and soil inventories; and laboratory incubations to measure the carbon balance of a 120-year-old black spruce forest in Manitoba, Canada. The site lost 0.3 ?? 0.5 metric ton of carbon per hectare per year (ton C ha-1 year-1) from 1994 to 1997, with a gain of 0.6 ?? 0.2 ton C ha-1 year-1 in moss and wood offset by a loss of 0.8 ?? 0.5 ton C ha-1 year-1 from the soil. The soil remained frozen most of the year, and the decomposition of organic matter in the soil increased 10-fold upon thawing. The stability of the soil carbon pool (~150 tons C ha-1) appears sensitive to the depth and duration of thaw, and climatic changes that promote thaw are likely to cause a net efflux of carbon dioxide from the site.

Science↗

Contribution of increasing CO2 and climate to carbon storage by ecosystems in the United States

The effects of increasing carbon dioxide (CO2) and climate on net carbon storage in terrestrial ecosystems of the conterminous United States for the period 1895-1993 were modeled with new, detailed historical climate information. For the period 1980-1993, results from an ensemble of three models agree within 25%, simulating a land carbon sink from CO2 and climate effects of 0.08 gigaton of carbon per year. The best estimates of the total sink from inventory data are about three times larger, suggesting that processes such as regrowth on abandoned agricultural land or in forests harvested before 1980 have effects as large as or larger than the direct effects of CO2 and climate. The modeled sink varies by about 100% from year to year as a result of climate variability.

Science↗

Krumholzibacteriota and Deltaproteobacteria contain rare genetic potential to liberate carbon from monoaromatic compounds in subsurface coal seams

Biogenic methane in subsurface coal seam environments is produced by diverse consortia of microbes. Although this methane is useful for global energy security, it remains unclear which microbes can liberate carbon from the coal. Most of this carbon is relatively resistant to biodegradation, as it is contained within aromatic rings. Thus, to explore for coal-degrading taxa in the subsurface, this study reconstructed relevant metagenome-assembled genomes (MAGs) from coal seams by using a key genomic marker for the anaerobic degradation of monoaromatic compounds as a guide: the benzoyl-CoA reductase gene ( bcrABCD ). Three MAGs were identified with this genetic potential. The first represented a novel taxon from the Krumholzibacteriota phylum, which this study is the first to describe. This Krumholzibacteriota MAG contained a full set of genes for benzoyl-CoA dearomatization, in addition to other genes for anaerobic catabolism of monoaromatics. Analysis of Krumholzibacteriota MAGs from other environments revealed that this genetic potential may be common, and thus, Krumholzibacteriota may be important organisms for the liberation of recalcitrant carbon in a broad range of environments. Moreover, the assembly and characterization of two Syntrophorhabdus aromaticivorans MAGs from different continents and a Syntrophaceae sp. MAG implicate the Deltaproteobacteria class in coal seam monoaromatic degradation. Each of these taxa are potential rate-limiting organisms for subsurface coal-to-methane biodegradation. Their description here provides some understanding of their function within the coal seam microbiome and will help inform future efforts in coal bed methane stimulation, anoxic bioremediation of organic pollutants, and assessments of anoxic, subsurface carbon cycling and emissions.

mBio↗

Correlation of basinal carbonate cycles to nearshore parasequences in the Late Cretaceous Greenhorn seaway, Western Interior U.S.A.

Upper Cretaceous limestone-shale couplets developed within the late transgressive stage of the Greenhorn cyclothem may be correlated from carbonate-dominated (basinal) sequences in central Kansas and Colorado westward to clastic cycles in southern Utah. Six such basinal couplets have been traced to corresponding upward-coarsening progradational cycles developed on the western margin of the Western Interior basin. In the central basin in Colorado and Kansas, these sedimentary cycles are represented by limestone-shale and marlstone-shale couplets ∼0.5-1.0 m in thickness. More calcareous parts of these couplets may be correlated westward into condensed, fossiliferous concretion and shell beds in proximal offshore lithofacies of Arizona and Utah. These concretion and shell beds are physically traceable farther landward (westward) into bioturbated, fossil-rich, transgressive lag deposits that bound 10- to 20-m-thick coarsening-upward progradational strand-plain deposits (parasequences) in southwestern Utah. Thus, the progra-dational phase of parasequence deposition correlates with accumulation of clay-rich sediment in the central basin, and the transgressive phase is characterized by reduced terrigenous input and deposition of carbonate-rich sediment. We consider Milankovitch-style orbital forcing of climate and tectonically induced fluctuations in rates of foredeep basin subsidence as possible forcing mechanisms for these basinwide events. Based on the widespread distribution of the limestone-shale couplets, as well as on estimated sedimentation rates and geochronology, it has been widely speculated that these carbonate cycles reflect Milankovitch cycles with periodicities on the order of 20 k.y. to 100 k.y. If so, then stratigraphic data suggest that orbital forcing of climate affected eustasy and/or sediment input and biogenic production in the Western Interior basin. Alternatively, thrusting events in the Sevier orogenic belt may have produced episodic changes in the rates of foredeep basin subsidence and consequent changes in base level, which could have controlled the deposition of the Greenhorn parasequences and carbonate cycles. In either case, correlation of these units demonstrates a consistent basinwide sedimentary response to high-frequency base level or sediment input changes in the Western Interior epicontinental basin.

Arizona, Colorado, Kansas, Utah↗

Rhythmic bedding in Upper Cretaceous pelagic carbonate sequences: Varying sedimentary response to climatic forcing

Rhythmic bedding is a prominent feature of North American and European Upper Cretaceous pelagic carbonate sequences deposited in epicontinental and continental-edge settings. Such bedding rhythms can result from variations in carbonate productivity, terrigenous dilution, redox conditions, or bottom currents. Each type of bedding cycle is expressed differently in the stratigraphic record but probably was caused by climatic cycles that are linked to variations in the Earth's orbital characteristics (Milankovitch cycles). Thus, pelagic carbonates of Cretaceous age acted as particularly sensitive recorders of orbitally induced changes in climate. Documentation of these bedding rhythms will permit detailed chronostratigraphic and lithostratigraphic correlations and will further illuminate depositional processes in Upper Cretaceous carbonate sequences.

Geology↗

Cambrian–Ordovician of the central Appalachians:Correlations and event stratigraphy of carbonate platform andadjacent deep-water deposits

This trip seeks to illustrate the succession of Cambrian and Ordovician facies deposited within the Pennsylvania and Maryland portion of the Great American Carbonate Bank. From the Early Cambrian (Dyeran) through Late Ordovician (Turinan), the Laurentian paleocontinent was rimmed by an extensive carbonate platform. During this protracted period of time, a succession of carbonate rock, more than two miles thick, was deposited in Maryland and Pennsylvania. These strata are now exposed in the Nittany arch of central Pennsylvania; the Great Valley of Pennsylvania, Maryland, and Virginia; and the Conestoga and Frederick Valleys of eastern Pennsylvania and Maryland. This fi eld trip will visit key outcrops that illustrate the varied depositional styles and environmental settings that prevailed at different times within the Pennsylvania reentrant portion of the Great American Carbonate Bank. In particular, we will contrast the timing and pattern of sedimentation in off-shelf (Frederick Valley), outer-shelf (Great Valley), and inner-shelf (Nittany arch) deposits. The deposition was controlled primarily by eustasy through the Cambrian and Early Ordovician (within the Sauk megasequence), but was strongly infl uenced later by the onset of Taconic orogenesis during deposition of the Tippecanoe megasequence.

Pennsylvania, Maryland↗

Advances in carbonate exploration and reservoir analysis

The development of innovative techniques and concepts, and the emergence of new plays in carbonate rocks are creating a resurgence of oil and gas discoveries worldwide. The maturity of a basin and the application of exploration concepts have a fundamental influence on exploration strategies. Exploration success often occurs in underexplored basins by applying existing established geological concepts. This approach is commonly undertaken when new basins &lsquo;open up&rsquo; owing to previous political upheavals. The strategy of using new techniques in a proven mature area is particularly appropriate when dealing with unconventional resources (heavy oil, bitumen, stranded gas), while the application of new play concepts (such as lacustrine carbonates) to new areas (i.e. ultra-deep South Atlantic basins) epitomizes frontier exploration. Many low-matrix-porosity hydrocarbon reservoirs are productive because permeability is controlled by fractures and faults. Understanding basic fracture properties is critical in reducing geological risk and therefore reducing well costs and increasing well recovery. The advent of resource plays in carbonate rocks, and the long-standing recognition of naturally fractured carbonate reservoirs means that new fracture and fault analysis and prediction techniques and concepts are essential.

Geological Society Special Publication↗

Near-surface, marine seismic-reflection data defines potential hydrogeologic confinement bypass in a tertiary carbonate aquifer, southeastern Florida

Approximately 210 km of near-surface, high-frequency, marine seismic-reflection data were acquired on the southeastern part of the Florida Platform between 2007 and 2011. Many high-resolution, seismic-reflection profiles, interpretable to a depth of about 730 m, were collected on the shallow-marine shelf of southeastern Florida in water as shallow as 1 m. Landward of the present-day shelf-margin slope, these data image middle Eocene to Pleistocene strata and Paleocene to Pleistocene strata on the Miami Terrace. This high-resolution data set provides an opportunity to evaluate geologic structures that cut across confining units of the Paleocene to Oligocene-age carbonate rocks that form the Floridan aquifer system.Seismic profiles image two structural systems, tectonic faults and karst collapse structures, which breach confining beds in the Floridan aquifer system. Both structural systems may serve as pathways for vertical groundwater flow across relatively low-permeability carbonate strata that separate zones of regionally extensive high-permeability rocks in the Floridan aquifer system. The tectonic faults occur as normal and reverse faults, and collapse-related faults have normal throw. The most common fault occurrence delineated on the reflection profiles is associated with karst collapse structures. These high-frequency seismic data are providing high quality structural analogs to unprecedented depths on the southeastern Florida Platform. The analogs can be used for assessment of confinement of other carbonate aquifers and the sealing potential of deeper carbonate rocks associated with reservoirs around the world.

Florida↗

Interplay of late Cenozoic siliciclastic supply and carbonate response on the southeast Florida platform

High-resolution seismic-reflection data collected along the length of the Caloosahatchee River in southwestern Florida have been correlated to nannofossil biostratigraphy and strontium-isotope chemostratigraphy at six continuously cored boreholes. These data are interpreted to show a major Late Miocene(?) to Early Pliocene fluvial-deltaic depositional system that prograded southward across the carbonate Florida Platform , interrupting nearly continuous carbonate deposition since early in the Cretaceous. Connection of the platform top to a continental source of siliciclastics and significant paleotopography combined to focus accumulation of an immense supply of siliciclastics on the southeastern part of the Florida Platform . The remarkably thick (> 100 m), sand-rich depositional system, which is characterized by clinoformal progradation, filled in deep accommodation, while antecedent paleotopography directed deltaic progradation southward within the middle of the present-day Florida Peninsula. The deltaic depositional system may have prograded about 200 km southward to the middle and upper Florida Keys, where Late Miocene to Pliocene siliciclastic form the foundation of the Quaternary carbonate shelf and shelf margin of the Florida Keys. These far-traveled siliciclastic deposits filled accommodation on the southeastern part of the Florida Platform so that paleobathymetry was sufficiently shallow to allow Quaternary recovery of carbonate sedimentation in the area of southern peninsular Florida and the Florida Keys.

Florida↗

Sequential development of platform to off-platform facies of the great American carbonate bank in the central Appalachians

In the central Appalachians, carbonate deposition of the great American carbonate bank began during the Early Cambrian with the creation of initial ramp facies of the Vintage Formation and lower members of the Tomstown Formation. Vertical stacking of bioturbated subtidal ramp deposits (Bolivar Heights Member) and dolomitized microbial boundtsone (Fort Duncan Member) preceded the initiation of platform sedimentation and creation of sand shoal facies (Benevola Member) that was followed by the development of peritidal cyclicity (Daragan Member). Initiation of peritidal deposition coincided with the development of a rimmed platform that would persist throughout much of the Cambrian and Early Odrovician. At the end of deposition of the Waynesboro Formation, the platform became subaerially exposed because of the Hawke Bay regression, bringing the Sauk I supersequence to and end. In the Conestoga Valley of eastern Pennsylvania, Early Cambrian ramp deposition was succeeded by deposition of platform-margin and periplatfrom facies of the Kinzers Formation. The basal Sauk II transgression during the early Middle Cambrian submerged the platform and reinitiated the pertidal cyclicity that had characterized the pre-Hawke Bay deposition, This thick stack of meter-scale cycles is preserved as the Pleasant Hill and Warrior Formations of the Nittany arch, the Elbrook Formation of the Great Valley, and the Zooks Corner Formations of the Conestoga Valley. Deposition of peritidal cycles was interrupted during deposition of the Glossopleura and Bathuriscus-Elrathina Biozones by third-order deepening episodes that submerged the platform with subtidal facies. Regressive facies of the Sauk II supersequence produced platform-wide restrictions and the deposition of the lower sandy member of the Gatesburg Formation, the Big Spring Station Member of the Conococheague Formation, and the Snitz Creek Formation. Submergence of the platform was initiated during the late Steptoean ( Elvinia Zone) with the epansion of extensive subtidal thrombotic boundstone facies. Vertical stacking of no fewer than four of these thrombolite-dominated intervals records third-order deepening episodes separated by intervening shallowing episodes that produced peritidal ribbony and laminated mudcracked dolostone. The maximum deepening of the Sauk III transgression produced the Stonehenge Formation in two separate and distinct third-order submergences. Circulation restriction during the Sauk III regression produced a thick stack of meter-scale cycles of the Rockdale Run Formation, and the lower Bellefonte Dolomite of the Nittany arch (central Pennsylvania). This regressive phase was interrupted by a third-order deepening event that produced the oolitic member of the lower Rockdale Run and the Woodsboro Member of the Grove Formation in the Frederick Valley. Restricted circulation continued into the Whiterockian, with deposition of the upper Rockdale Run and the Pinesberg Station Dolomite in the Great Valley and the missile and upper parts of the Bellefonte Dolomore and the Nittany Arch region. This deposition was continuous from the Ibexian into the Whiterockian; the succession lacks significant unconformities and there are no missing biozones through this interval, the top of which marks the end of the Sauk megasequence. During deposition of the Tippecanoe megasequence, the peritidal shelf cycles were reestablished during deposition of the St. Paul Group. The vertical stacking of lithologies in the Row Park and New Market Limestones represents transgressive and regressice facies of a third-order deepening event. This submergence reached its maximum deepening within the lower Row Park Limestone and extended with the Nittany arch region with deposition of equivalent Loysburg Formation.. Shallow tidal-flat deposits were bordered to the south and east by deep-water ramp deposits of the Lincolnshire Formation. The St. Paul Group is succeeded upsection by ramp facies of the Chamersberg and the Edinburg Formations in the Great Valley, whereas shallow-shelf sedimentation continued in the Nittany-arch area with the depostion of the Hatter Limestoen and the Snyder and Linden Hall Formations. Carbonate deposition on the great American carbonate bank was brought to an end when it was buried beneath clastic flysch deposits of the Martinsberg Formation. Foundering of the bamk was diachronus, and the flysch seidments prograded from east to west.

Maryland, Pennsylvania, Virginia, West Virginia↗

Empirical relation between carbonate porosity and thermal maturity: An approach to regional porosity prediction

Data indicate that porosity loss in subsurface carbonate rocks can be empirically represented by the power function, ^Thgr = a (TTI) b , where ^Thgr is regional porosity, TTI is Lopatin's time-temperature index of thermal maturity, the exponent, b, equals approximately -0.372, and the multiplier, a, is constant for a given data population but varies by an order of magnitude overall. Implications include the following. 1. The decrease of carbonate porosity by burial diagenesis is a maturation process depending exponentially on temperature and linearly on time. 2. The exponent, b, is essentially independent of the rock matrix, and may reflect rate-limiting processes of diffusive transport. 3. The multiplying coefficient, a, incorporates the net effect on porosity of all depositional and diagenetic parameters. Within constraints, carbonate-porosity prediction appears possible on a regional measurement scale as a function of thermal maturity. Estimation of carbonate porosity at the time of hydrocarbon generation, migration, or trapping also appears possible.

American Association of Petroleum Geologists Bulle↗

A comprehensive assessment of mangrove species and carbon stock on Pohnpei, Micronesia

Mangrove forests are the most important ecosystems on Pohnpei Island, Federated States of Micronesia, as the island communities of the central Pacific rely on the forests for many essential services including protection from sea-level rise that is occurring at a greater pace than the global average. As part of a multi-component assessment to evaluate vulnerabilities of mangrove forests on Pohnpei, mangrove forests were mapped at two points in time: 1983 and 2018. In 2018, the island had 6,426 ha of mangrove forest. Change analysis indicated a slight (0.76%) increase of mangrove area between 1983 and 2018, contrasting with global mangrove area declines. Forest structure and aboveground carbon (AGC) stocks were inventoried using a systematic sampling of field survey plots and extrapolated to the island using k-nearest neighbor and random forest species models. A gridded or wall to wall approach is suggested when possible for defining carbon stocks of a large area due to high variability seen in our data. The k-nearest neighbor model performed better than random forest models to map species dominance in these forests. Mean AGC was 167 ± 11 MgC ha -1 , which is greater than the global average of mangroves (115 ± 7 MgC ha -1 ) but within their global range (37–255 MgC ha -1 ) Kauffman et al. (2020). In 2018, Pohnpei mangroves contained over 1.07 million MgC in AGC pools. By assigning the mean AGC stock per species per area to the map, carbon stock distributions were visualized spatially, allowing future conservation efforts to be directed to carbon dense stands.

Pohnpei Island↗