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At least 613 records · Page 34Linked to original sources

Testing models of Laramide orogenic initiation by investigation of Late Cretaceous magmatic-tectonic evolution of the central Mojave sector of the California arc

The Mojave Desert region is in a critical position for assessing models of Laramide orogenesis, which is hypothesized to have initiated as one or more seamounts subducted beneath the Cretaceous continental margin. Geochronological and geochemical characteristics of Late Cretaceous magmatic products provide the opportunity to test the validity of Laramide orogenic models. Laramide-aged plutons are exposed along a transect across the Cordilleran Mesozoic magmatic system from Joshua Tree National Park in the Eastern Transverse Ranges eastward into the central Mojave Desert. A transect at latitude ∼33.5°N to 34.5°N includes: (1) the large upper-crustal Late Cretaceous Cadiz Valley batholith, (2) a thick section of Proterozoic to Jurassic host rocks, (3) Late Cretaceous stock to pluton-sized bodies at mesozonal depths, and (4) a Jurassic to Late Cretaceous midcrustal sheeted complex emplaced at ∼20 km depth that transitions into a migmatite complex truncated along the San Andreas fault. This magmatic section is structurally correlative with the Big Bear Lake intrusive suite in the San Bernardino Mountains and similar sheeted rocks recovered in the Cajon Pass Deep Scientific Drillhole. Zircon U-Pb geochronology of 12 samples via secondary ionization mass spectrometry (SIMS) (six from the Cadiz Valley batholith and six from the Cajon Pass Deep Scientific Drillhole) indicates that all Cretaceous igneous units investigated were intruded between 83 and 74 Ma, and Cajon Pass samples include a Jurassic age component. A compilation of new and published SIMS geochronological data demonstrates that voluminous magmatism in the Eastern Transverse Ranges and central Mojave Desert was continuous throughout the period suggested for the intersection and flat-slab subduction of the Shatsky Rise conjugate deep into the interior of western North America. Whole-rock major-element, trace-element, and isotope geochemistry data from samples from a suite of 106 igneous rocks represent the breadth of Late Cretaceous units in the transect. Geochemistry indicates an origin in a subduction environment and intrusion into a crust thick enough to generate residual garnet. The lack of significant deflections of compositional characteristics and isotopic ratios in igneous products through space and time argues against a delamination event prior to 74 Ma. We argue that Late Cretaceous plutonism from the Eastern Transverse Ranges to the central Mojave Desert represents subduction zone arc magmatism that persisted until ca. 74 Ma. This interpretation is inconsistent with the proposed timing of the docking of the Shatsky Rise conjugate with the margin of western North America, particularly models in which the leading edge of the Shatsky Rise was beneath Wyoming at 74 Ma. Alternatively, the timing of cessation of plutonism precedes the timing of the passage of the Hess Rise conjugate beneath western North America at ca. 70–65 Ma. The presence, geochemical composition, and age of arc products in the Eastern Transverse Ranges and central Mojave Desert region must be accounted for in any tectonic model of the transition from Sevier to Laramide orogenesis.

California↗

Analysis of magnetotelluric profile data from the Ruby Mountains metamorphic core complex and southern Carlin Trend region, Nevada

We have collected about 150 magnetotelluric (MT) soundings in northeastern Nevada in the region of the Ruby Mountains metamorphic core complex uplift and southern Carlin mineral trend, in an effort to illuminate controls on core complex evolution and deposition of world-class gold deposits. The region has experienced a broad range of tectonic events including several periods of compressional and extensional deformation, which have contributed to the total expression of electrical resistivity. Most of the soundings are in three east-west profiles across increasing degrees of core uplift to the north (Bald Mountain, Harrison Pass and Secret Pass latitudes). Two shorter lines cross a prominent east-west structure to the north of the northern profile. MT impedance tensor and vertical magnetic field rotations imply a N-NNE average regional geoelectric strike, similar to surface geologic trends. Model resistivity cross sections were derived using a 2-D inversion algorithm, which damps departures of model parameters from an a priori structure, emphasizing the transverse magnetic (TM) mode and vertical magnetic field data. Geological interpretation of the resistivity combines previous seismic, potential field and isotope models, structural and petrological models for regional compression and extension, and detailed structural/stratigraphic interpretations incorporating drilling for petroleum and mineral exploration. To first order, the resistivity structure is one of a moderately conductive, Phanerozoic sedimentary section fundamentally disrupted by intrusion and uplift of resistive crystalline rocks. Late Devonian and early Mississippian shales of the Pilot and Chainman Formations together form an important conductive marker sequence in the stratigraphy and show pronounced increases in conductance (conductivity-thickness product) from east to west. These increases in conductance are attributed to graphitization caused by Elko-Sevier era compressional shear deformation and possibly by intrusive heating. The resistive crystalline central massifs adjoin the host stratigraphy across crustal-scale, subvertical fault zones. These zones provide electric current pathways to the lower crust for heterogeneous, upper crustal induced current flow. Resistive core complex crust may be steeply bounded under the middle of the neighboring grabens and not deepen at a shallow angle to arbitrary distances to the west. The numerous crustal breaks imaged with MT may contribute to the low effective elastic thickness estimated regionally for the Great Basin and exemplify the mid-crustal, steeply dipping slip zones in which major earthquakes nucleate. An east-west oriented conductor in the crystalline upper crust spans the East Humboldt Range and northern Ruby Mountains. The conductor may be related to an inferred ArcheanProterozoic suture or nearby graphitic metasediments, with possible alteration by middle Tertiary magmatic activity. Lower crustal resistivity everywhere under the profiles is low and appears quasi one-dimensional. It is consistent with a low rock porosity (

Open-File Report↗

Summary of the San Juan structural basin regional aquifer-system analysis, New Mexico, Colorado, Arizona, and Utah

Ground-water resources are the only source of water in most of the San Juan structural basin and are mainly used for municipal, industrial, domestic, and stock purposes. Industrial use increased dramatically during the late 1970's and early 1980's because of increased exploration and development of uranium and coal resources. The San Juan structural basin is a northwest-trending, asymmetric structural depression at the eastern edge of the Colorado Plateau. The basin contains as much as 14,000 feet of sedimentary rocks overlying a Precambrian basement complex. The sedimentary rocks dip basinward from the basin margins toward the troughlike structural center, or deepest part of the basin. Rocks of Triassic age were selected as the lower boundary for the study. The basin is well defined by structural boundaries in many places with structural relief of as much as 20,000 feet reported. Faulting is prevalent in parts of the basin with displacement of several thousand feet along major faults. The regional aquifers in the basin generally are coincident with the geologic units that have been mapped. Data on the hydrologic properties of the regional aquifers are minimal. Most data were collected on those aquifers associated with uranium and coal resource production. These data are summarized in table format in the report. The regional flow system throughout most of the basin has been affected by the production of oil or gas and subsequent disposal of produced brine. To date more than 26,000 oil- or gas- test holes have been drilled in the basin, the majority penetrating no deeper than the bottom of the Cretaceous rocks. The general water chemistry of the regional aquifers is based on available data. The depositional environments are the major factor controlling the quality of water in the units. The dominant ions are generally sodium, bicarbonate, and sulfate. A detailed geochemical study of three sandstone aquifers--Morrison, Dakota, and Gallup--was undertaken in the northwestern part of the study area. Results of this study indicate that water chemistry changed in individual wells over short periods of time, not expected in a regional flow system. The chemistry of the water is affected by mixing of recharge, ion filtrate, or very dilute ancient water, and by leakage of saline water. The entire system of ground-water flow and its controlling factors has been defined as the conceptual model. A steady-state, three-dimensional ground-water flow model was constructed to simulate modern predevelopment flow in the post-Jurassic rocks of the regional flow system. In the ground-water flow model, 14 geologic units or combinations of geologic units were considered to be regional aquifers, and 5 geologic units or combinations of geologic units were considered to be regional confining units. The model simulated flow in 12 layers (hydrostratigraphic units) and used harmonic-mean vertical leakance to indirectly simulate aquifer connection across 3 other hydrostratigraphic confining units in addition to coupling the 12 units.

Water-Resources Investigations Report↗

Data from geologic investigations in the Yemen Arab Republic during 1976

The results of semiquantitative spectrographic analyses for 31 elements in 126 specimens of rocks from the Yemen Arab Republic, collected mainly during February 1976 from the Precambrian area in the southeastern part of the country, provide background data for use in geochemical evaluation of areas potentially favorable for mineral deposits. Gold and thorium were undetected; the lower limits of determination are 10 parts per million (ppm) and 20 ppm, respectively. For the other elements, the abundances follow geochemical norms for crustal distribution: (1) Fe, Nb, and Zr in Holocene weathering products; (2) Ca and Sr in Pliocene limestone; (3) Mo in Pliocene(?) or Miocene(?) dikes; (4) Be, La, and Sn in Miocene(?) alkalic granite; (5) As, Be, and La in Tertiary and/or Cretaceous felsic tuff; (6) V in Tertiary and/or Cretaceous carbonaceous sedimentary rocks interbedded with volcanic rocks; (7) Be, La, Sn, and Zr in Tertiary and/or Cretaceous undivided volcanics; (8) Sn and W in Precambrian felsite and pegmatite; (9) Co, Cr, Ni, and Ti in Precambrian mafic rocks; (10) Mg and Sr in Precambrian marble and calcsilicate rocks; (11) Y in Precambrilan schist; (12) B and Sc dispersed in rocks of many ages; and (13) Ag, Ba, Bi, Cd, Cu, Mn, Pb, Sb, Sn, and Zn in a hydrothermal replacement deposit in Precambrian sediment. None of the rocks contained as much as 205 ppm equivalent uranium. The highest values for Ag, Cu, Pb, Zn, and Cd were obtained on a sample of hydrothermally altered siltstone not personally collected by the writers. It was said to have come from the Ma'rib area in the eastern part of the Yemen Arab Republic. The source must be studied, because this single sample is high-grade base-metal ore. Among the samples collected by the writers, the economically most significant are altered tuffs, ignimbrites, and felsites exposed between Jibal Hufash and Manakhah on the road from Hudaydah to San'a'. They are strongly anomalous for As and weakly anomalous, variously, for Hg, Mo, and Pb, which elements may constitute an epigenetic dispersion pattern from hidden sulfide deposits. Inasmuch as chalcopyrite and native copper have been reported in the vicinity of Jabal Haraz in the Manakhah area, the rocks of the Yemen Volcanics in this region should be explored for base-metal sulfide deposits. The first results of paleontologic examinations of fossils collected during 1975 and 1976 are presented, as are a list of Landsat images covering the Yemen Arab Republic, and a selected bibliography of reports on geology and the allied sciences relating to the Yemen Arab Republic.

Open-File Report↗

Petroleum geology and resources of the middle Caspian Basin, Former Soviet Union

The Middle Caspian basin occupies a large area between the Great Caucasus foldbelt and the southern edge of the Precambrian Russian craton. The basin also includes the central part of the Caspian Sea and the South Mangyshlak subbasin east of the sea. The basin was formed on the Hercynian accreted terrane during Late Permian?Triassic through Quaternary time. Structurally, the basin consists of the fold-and-thrust zone of the northern Caucasus foothills, the foredeep and foreland slope, the Stavropol-Prikumsk uplift and East Manych trough to the north of the slope, and the South Mangyshlak subbasin and slope of the Karabogaz arch east of the Caspian Sea. All these major structures extend offshore. Four total petroleum systems (TPS) have been identified in the basin. The South Mangyshlak TPS contains more than 40 discovered fields. The principal reserves are in Lower?Middle Jurassic sandstone reservoirs in structural traps. Source rocks are poorly known, but geologic data indicate that they are in the Triassic taphrogenic sequence. Migration of oil and gas significantly postdated maturation of source rocks and was related to faulting and fracturing during middle Miocene to present time. A single assessment unit covers the entire TPS. Largest undiscovered resources of this assessment unit are expected in the largely undrilled offshore portion of the TPS, especially on the western plunge of the Mangyshlak meganticline. The Terek-Caspian TPS occupies the fold-and-thrust belt, foredeep, and adjoining foreland slope. About 50 hydrocarbon fields, primarily oil, have been discovered in the TPS. Almost all hydrocarbon reserves are in faulted structural traps related to thrusting of the foldbelt, and most traps are in frontal edges of the thrust sheets. The traps are further complicated by plastic deformation of Upper Jurassic salt and Maykop series (Oligocene? lower Miocene) shale. Principal reservoirs are fractured Upper Cretaceous carbonates and middle Miocene sandstones. Principal source rocks are organic-rich shales in the lower part of the Maykop series. Source rocks may also be present in the Eocene, Upper Jurassic, and Middle Jurassic sections, but their contribution to discovered reserves is probably small. Three assessment units are delineated in the TPS. One of them encompasses the thrust-and-fold belt of northern Caucasus foothills. This assessment unit contains most of the undiscovered oil resources. The second assessment unit occupies the foredeep and largely undeformed foreland slope. Undiscovered resources of this unit are relatively small and primarily related to stratigraphic traps. The third unit is identified in almost untested subsalt Jurassic rocks occurring at great depths and is speculative. The unit may contain significant amounts of gas under the Upper Jurassic salt seal. The Stavropol-Prikumsk TPS lies north of the Terek-Caspian TPS and extends offshore into the central Caspian Sea where geologic data are scarce. More than one hundred oil and gas fields have been found onshore. Offshore, only one well was recently drilled, and this well discovered a large oil and gas field. Almost the entire sedimentary section of the TPS is productive; however, the principal oil reserves are in Lower Cretaceous clastic reservoirs in structural traps of the Prikumsk uplift. Most original gas reserves are in Paleogene reservoirs of the Stavropol arch and these reservoirs are largely depleted. At least three source rock formations, in the Lower Triassic, Middle Jurassic, and Oligocene?lower Miocene (Maykop series), are present in the TPS. Geochemical data are inadequate to correlate oils and gases in most reservoirs with particular source rocks, and widespread mixing of hydrocarbons apparently took place. Three assessment units encompassing the onshore area of the TPS, the offshore continuation of the Prikumsk uplift, and the central Caspian area, are identified. The

Bulletin↗

Overview of the Microscopic Imager Investigation during Spirit's first 450 sols in Gusev crater

The Microscopic Imager (MI) on the Mars Exploration Rover Spirit has returned images of Mars with higher resolution than any previous camera system, allowing detailed petrographic and sedimentological studies of the rocks and soils at the Gusev landing site. Designed to simulate a geologist's hand lens, the MI is mounted on Spirit's instrument arm and can resolve objects 0.1 mm in size or larger. This paper provides an overview of MI operations, data calibration, processing, and analysis of MI data returned during the first 450 sols (Mars days) of the Spirit landed mission. The primary goal of this paper is to facilitate further analyses of MI data by summarizing the methods used to acquire and process the data, the radiometric and geometric accuracy of MI data products, and the availability of archival products. In addition, scientific results of the MI investigation are summarized. MI observations show that poorly sorted soils are common in Gusev crater, although aeolian bedforms have well‐sorted coarse sand grains on their surfaces. Abraded surfaces of plains rocks show igneous textures, light‐toned veins or fracture‐filling minerals, and discrete coatings. The rocks in the Columbia Hills have a wide variety of granular textures, consistent with volcaniclastic or impact origins. Case hardening and submillimeter veins observed in the rocks as well as soil crusts and cemented clods imply episodic subsurface aqueous fluid movement, which has altered multiple geologic units in the Columbia Hills. The MI also monitored Spirit's solar panels and the magnets on the rover's deck.

Journal of Geophysical Research E: Planets↗

High-resolution delineation of chlorinated volatile organic compounds in a dipping, fractured mudstone: depth- and strata-dependent spatial variability from rock-core sampling

Synthesis of rock-core sampling and chlorinated volatile organic compound (CVOC) analysis at five coreholes, with hydraulic and water-quality monitoring and a detailed hydrogeologic framework, was used to characterize the fine-scale distribution of CVOCs in dipping, fractured mudstones of the Lockatong Formation of Triassic age, of the Newark Basin in West Trenton, New Jersey. From these results, a refined conceptual model for more than 55 years of migration of CVOCs and depth- and strata-dependent rock-matrix contamination was developed. Industrial use of trichloroethene (TCE) at the former Naval Air Warfare Center (NAWC) from 1953 to 1995 resulted in dense non-aqueous phase liquid (DNAPL) TCE and dissolved TCE and related breakdown products, including other CVOCs, in underlying mudstones. Shallow highly weathered and fractured strata overlie unweathered, gently dipping, fractured strata that become progressively less fractured with depth. The unweathered lithology includes black highly fractured (fissile) carbon-rich strata, gray mildly fractured thinly layered (laminated) strata, and light-gray weakly fractured massive strata. CVOC concentrations in water samples pumped from the shallow weathered and highly fractured strata remain elevated near residual DNAPL TCE, but dilution by uncontaminated recharge, and other natural and engineered attenuation processes, have substantially reduced concentrations along flow paths removed from sources and residual DNAPL. CVOCs also were detected in most rock-core samples in source areas in shallow wells. In many locations, lower aqueous concentrations, compared to rock core concentrations, suggest that CVOCs are presently back-diffusing from the rock matrix. Below the weathered and highly fractured strata, and to depths of at least 50 meters (m), groundwater flow and contaminant transport is primarily in bedding-plane-oriented fractures in thin fissile high-carbon strata, and in fractured, laminated strata of the gently dipping mudstones. Despite more than 18 years of pump and treat (P&T) remediation, and natural attenuation processes, CVOC concentrations in aqueous samples pumped from these deeper strata remain elevated in isolated intervals. DNAPL was detected in one borehole during coring at a depth of 27 m. In contrast to core samples from the weathered zone, concentrations in core samples from deeper unweathered and unfractured strata are typically below detection. However, high CVOC concentrations were found in isolated samples from fissile black carbon-rich strata and fractured gray laminated strata. Aqueous-phase concentrations were correspondingly high in samples pumped from these strata via short-interval wells or packer-isolated zones in long boreholes. A refined conceptual site model considers that prior to P&T remediation groundwater flow was primarily subhorizontal in the higher-permeability near surface strata, and the bulk of contaminant mass was shallow. CVOCs diffused into these fractured and weathered mudstones. DNAPL and high concentrations of CVOCs migrated slowly down in deeper unweathered strata, primarily along isolated dipping bedding-plane fractures. After P&T began in 1995, using wells open to both shallow and deep strata, downward transport of dissolved CVOCs accelerated. Diffusion of TCE and other CVOCs from deeper fractures penetrated only a few centimeters into the unweathered rock matrix, likely due to sorption of CVOCs on rock organic carbon. Remediation in the deep, unweathered strata may benefit from the relatively limited migration of CVOCs into the rock matrix. Synthesis of rock core sampling from closely spaced boreholes with geophysical logging and hydraulic testing improves understanding of the controls on CVOC delineation and informs remediation design and monitoring.

New Jersey, New York, Pennsylvania↗

Water-quality parameters and benthic algal communities at selected streams in Minnesota, August 2000 - Study design, methods and data

Water-quality measurements and benthic algal samples were measured or collected from select Minnesota streams as part of a multiagency (Minnesota Pollution Control Agency, Minnesota Department of Natural Resources, U.S. Environmental Protection Agency, and U.S. Geological Survey) study. The goal of the multiagency study was to identify quantifiable thresholds of water-quality impairment and establish quantifiable indicators of nutrient enrichment for medium to high-order streams. This report describes the study design, sampling methods, and summarizes the physical, chemical, and benthic algal data for a component of the multiagency study that was designed to document diurnal water-quality measurements (specific conductance, pH, water temperature, and dissolved oxygen), benthic algal community composition and chlorophyll-a content, and primary productivity at 12 stream sites on 6 streams in Minnesota during August 2000. Specific conductance, pH, water temperature, dissolved oxygen concentrations and percent dissolved oxygen saturation measurements were made with submersible data recorders at 30 minute intervals for a period of 3-6 days during August 2000. Benthic algae collected from wood and rock substrate were identified and enumerated. Biovolume (volume of algal cells per unit area), density (number of cells per unit area), and chlorophyll-a content from benthic algae were determined. These data can be used as part of the multiagency study to develop an understanding of the relations among nutrient concentrations, algal abundance, algal community composition, and primary production and respiration processes in rivers of differing ecoregions in Minnesota.

Minnesota↗

Novel insights about petroleum systems from source and reservoir rock characterization, Cretaceous Deposits, Babouri-Figuil Basin, Northern Cameroon

The Babouri-Figuil Basin (BFB) is a frontier basin for petroleum in Cameroon. It belongs to the series of Cretaceous rift basins of the West and Central Rift System (WCARS), the origin of which is related to the opening of the South Atlantic. Within the same rift system, commercial hydrocarbon accumulations have been discovered in Chad, Sudan, Niger and, more recently, in Nigeria (Gongola Basin). The study of the geology of the BFB just recently received considerable attention, mainly because of its presumed hydrocarbon potential. In the pursuit of researching possible petroleum systems in the BFB, the current study provides a first look into the characterization of source and reservoir rock and its integration into a 2D lithostratigraphic model. The study was solely based on outcrop samples. Black shale and massive claystone are good to excellent hydrocarbon source rocks [e.g., up to 38 wt% total organic carbon (TOC), up to 943 mg/g hydrogen index, up to 85 m thickness, up to 20–30 km lateral extension], with moderate to high values of extractable organic matter (e.g., >10,000 ppm). Calcareous claystone, on the other hand, are poor source rocks [e.g., <0.20 wt% TOC]. The samples are thermally immature, except for those located close to volcanic intrusion at Golombe that have reached the threshold for oil generation (Tmax >435 °C, production index >0.1). The petrographic analysis of sandstone revealed that they are fine-grained to coarse-grained, poorly to moderately sorted, texturally and compositionally immature to submature, subarkosic to arkosic arenites. The main diagenetic processes that affected sandstones are as follows: moderate to intense compaction characterized by the development of long, concavo-convex, and sutured contacts between grains; cementation through calcite, iron oxide, and quartz cements; alteration of mica and feldspar grains; partial to complete dissolution of feldspar, mica, amphibole grains, and calcite cement; and the replacement of feldspar and mica grains by clay minerals. Alteration and dissolution increase the porosity of sandstone through the creation of secondary pores. However, mechanical compaction through the development of a pseudomatrix and cementation as pore-filling materials have significantly reduced the quality of sandstone beds as conventional petroleum reservoirs. Hence, the best reservoir-quality sandstones in the basin are generally located in the upper portion of the basin in terms of its lithostratigraphic model. They are the cleanest sandstones with the smallest amount of cement and the lowest ductile grain content (pseudomatrix), with a thickness that varies from 3 m to 120 m and a lateral extension of 20 km. The lithostratigraphic model of the basin is characterized by an extensive lacustrine environment that provided a thick sequence of organic-rich formations; sand deposited as extensive reservoirs sandwiched between shale/claystone beds; the development of stratigraphic traps through lateral facies change; and the widespread deposition of lacustrine and floodplain claystone that provide regional seals. The similarities between the Babouri-Figuil Basin and proven petroleum systems in other WCARS rift basins suggest that the basin may host at least one petroleum system where actively generating source rocks are present.

Babouri-Figuil Basin↗

Magmatic infiltration and melting in the lower crust and upper mantle beneath the Cima volcanic field, California

Xenoliths of lower crustal and upper mantle rocks from the Cima volcanic field (CVF) commonly contain glass pockets, veins, and planar trains of glass and/or fluid inclusions in primary minerals. Glass pockets occupy spaces formerly occupied by primary minerals of the host rocks, but there is a general lack of correspondence between the composition of the glass and that of the replaced primary minerals. The melting is considered to have been induced by infiltration of basaltic magma and differentiates of basaltic magma from complex conduits formed by hydraulic fracturing of the mantle and crustal rocks, and to have occurred during the episode of CVF magmatism between ∼7.5 Ma and present. Variable compositions of quenched melts resulted from mixing of introduced melts and products of melting of primary minerals, reaction with primary minerals, partial crystallization, and fractionation resulting from melt and volatile expulsion upon entrainment of the xenoliths. High silica melts ( >∼60% SiO 2 ) may result by mixing introduced melts with siliceous melts produced by reaction of orthopyroxene. Other quenched melt compositions range from those comparable to the host basalts to those with intermediate Si compositions and elevated Al, alkalis, Ti, P, and S; groundmass compositions of CVF basalts are consistent with infiltration of fractionates of those basalts, but near-solidus melting may also contribute to formation of glass with intermediate silica contents with infiltration only of volatile constituents.

California↗

Miocene phosphatization of rocks from the summit of Rio Grande Rise, Southwest Atlantic Ocean

Marine phosphorites are an important part of the oceanic phosphorus cycle and are related to the effects of long-term global climate changes. We use petrography, mineralogy, rare earth elements contents, and 87 Sr/ 86 Sr-determined carbonate fluorapatite (CFA) and calcite ages to investigate the paragenesis and history of phosphatization of carbonate sediments, limestones, ferromanganese crusts, and ironstones from the summit of Rio Grande Rise (RGR), Southwest Atlantic Ocean. Phosphatization of all the rock types occurred throughout the Miocene from 20.2 to 6.8 million years ago (Ma), and occasionally during the Quaternary, mainly through the cementation of carbonate sediments by cryptocrystalline CFA, likely involving the dissolution of the smaller size fraction of foraminifera-nannofossil ooze. Porosity/permeability and abundance of fine calcite material were important factors determining the intensity of phosphatization of the various rock types. Phosphatization was initiated during a transition to a more dynamic circulation system in the South Atlantic Ocean, which remobilized phosphorus from deeper waters and increased primary productivity that culminated with the middle-Miocene Climatic Optimum between ∼17 and 14.8 Ma. The relatively shallow-water depth of RGR summit during the Miocene provided proximity to the oxygen minimum zone, a reservoir for reactive phosphorus, especially during periods of enhanced phosphorus cycling spurred by surface primary productivity. The cessation of phosphatization at RGR resulted from a rapidly cooling and dry climate that characterized the Miocene-Pliocene transition. Our results support previous observations that periods of broadly intensified ocean circulation and local hydrodynamic changes were the key paleoceanographic links to phosphorite formation.

Paleoceanography and Paleoclimatology↗

Legacy of the California Gold Rush: Environmental geochemistry of arsenic in the southern Mother Lode Gold District

Gold mining activity in the Sierra Nevada foothills, both recently and during the California Gold Rush, has exposed arsenic-rich pyritic rocks to weathering and erosion. This study describes arsenic concentration and speciation in three hydrogeologic settings in the southern Mother Lode Gold District: mineralized outcrops and mine waste rock (overburden); mill tailings submerged in a water reservoir; and lake waters in this monomictic reservoir and in a monomictic lake developing within a recent open-pit mine. These environments are characterized by distinct modes of rock-water interaction that influence the local transport and fate of arsenic. Arsenic in outcrops and waste rock occurs in arsenian pyrite containing an average of 2 wt% arsenic. Arsenic is concentrated up to 1300 ppm in fine-grained, friable, iron-rich weathering products of the arsenian pyrite (goethite, jarosite, copiapite), which develop as efflorescences and crusts on weathering outcrops. Arsenic is sorbed as a bidentate complex on goethite, and substitutes for sulfate in jarosite. Submerged mill tailings obtained by gravity core at Don Pedro Reservoir contain arsenic up to 300 ppm in coarse sand layers. Overlying surface muds have less arsenic in the solid fraction but higher concentrations in porewaters (up to 500 μg/L) than the sands. Fine quartz tailings also contain up to 3.5 ppm mercury related to the ore processing. The pH values in sediment porewaters range from 3.7 in buried gypsum-bearing sands and tailings to 7 in the overlying lake sediments. Reservoir waters immediately above the cores contain up to 3.5 μg/L arsenic; lake waters away from the submerged tailings typically contain less than 1 μg/L arsenic. Dewatering during excavation of the Harvard open-pit mine produced a hydrologic cone of depression that has been recovering toward the pre-mining groundwater configuration since mining ended in 1994. Aqueous arsenic concentrations in the 80 m deep pit lake are up to 1000 μg/L. Redistribution of the arsenic occurs during summer stratification, with highest concentrations at middle depths. The total mass of arsenic in the pit lake increases coinciding with early winter rains that erode, partially dissolve, and transport arsenic-bearing salts into the pit lake. Arsenic concentration, speciation, and distribution in the Sierra Nevada foothills depend on many factors, including the lithologic sources of arsenic, climatic influences on weathering of host minerals, and geochemical characteristics of waters with which source and secondary minerals react. Oxidation of arsenian pyrite to goethite, jarosite, and copiapite causes temporary attenuation of arsenic during summer, when these secondary minerals accumulate; subsequent rapid dissemination of arsenic into the aqueous environment is caused by annual winter storms. As the population of the Mother Lode area grows, it is increasingly important to consider these effects during planning and development of land and groundwater resources.

California↗

Environmental processes that affect mineral deposits in the eastern United States

A thorough understanding of the environmental processes that affect mineral deposits and mine wastes has become increasingly important as the Nation wrestles with how to meet our current demand for metals without compromising the environment and how to mitigate the damage caused by the mining practices of previous generations. Regulatory requirements are dominated by empirical approaches to environmental problems associated with mining, but mitigation and reclamation can be enhanced greatly by a theoretical and conceptual understanding of the processes that affect the availability, transport, and fixation of metals and the generation of acidic waters. U.S. Geological Survey (USGS) research efforts in the Eastern United States are concentrating on environmental processes that affect a class of mineral deposits known as massive sulfide deposits. These occurrences were valued historically for their sulfur content and recently for their metals. This deposit type is a research priority because of its economic significance and high potential for adverse environmental impact due to its high sulfide content and the low acid-buffering capacity of host rocks. Numerous examples of these deposits are found in the East, including reclaimed mine sites, abandoned mines, active mines, and sites currently in the permitting process for future production. Published studies of mine drainage chemistry from the Iron Mountain massive sulfide deposit in California have documented extreme conditions of very low pH and high heavy-metal concentrations. These extreme conditions are attributed to the unique hydrologic and climatic settings of the deposit and probably are independent of the mineral deposit type. Areas currently under study include Bald Mountain, Maine, the Great Smoky Mountains National Park, the Vermont copper belt, Contrary Creek, Virginia, and Prince William Forest Park, Virginia (fig.1). Goals of the research are (1) to give land-use planners and the mining industry a better empirical framework from which to assess potential environmental impacts of mining, particularly under eastern climatic conditions, and (2) to provide a better theoretical and conceptual framework from which to design more effective and cost efficient mitigation and reclamation programs.

Information Handout↗

Evolving magma storage conditions beneath Mount St. Helens inferred from chemical variations in melt inclusions from the 1980-1986 and current (2004-2006) eruptions

Major element, trace element, and volatile concentrations in 187 glassy melt inclusions and 25 groundmass glasses from the 1980-86 eruption of Mount St. Helens are presented, together with 103 analyses of touching FE-Ti oxide pairs from the same samples. These data are used to evaluate the temporal evolution of the magmatic plumbing system beneath the volcano during 1980-86 and so provide a framework in which to interpret analyses of melt inclusions from the current (2004-2006) eruption. Major and trace element concentrations of all melt inclusions lie at the high SiO 2 end of the data array defined by eruptive products of the late Quaternary age from Mount St. Helens. For several major and trace elements, the glasses define a trend that is oblique to the whole-rock trend, indicating that different mineral assemblages were responsible for the two trends. The whole-rock trend can be ascribed to differentiation of hydrous basaltic parents in a deep-seated magma reservoir, probably at depths great enough to stabilize garnet. In contrast, the glass trends were generated by closed-system crystallization of the phenocryst and microlite mineral assemblages at low pressures. The dissolved H 2 O content of the melt inclusions from 1980-86, as measured by the ion microprobe, ranges from 0 to 6.7 wt. percent, with the highest values obtained from the plinian phase of May 18, 1980. Water contents decrease with increasing SiO 2 , consistent with decompression-driven crystallization. Preliminary data for dissolved CO 2 in melt inclusions from the May 18 plinian phase from August 7, 1980, indicate that X H 2 O in a vapor phase was approximately constant at 0.80, irrespective of H 2 O content, suggestive of closed-system degassing with a high bubble fraction or gas streaming through the subvolcanic system. Temperature and f O 2 estimates for touching Fe-Ti oxides show evidence for heating during crystallization owing to release of latent heat. Consequently, magmas with the highest microlite crystallinities record the highest temperatures. Magmas also become progressively reduced during ascent and degassing, probably as a result of redox equilibria between exsolving S-bearing gases and magmas. The lowest temperature oxides have f O 2 &asymp; NNO, similar to high-temperature fumarole gases from the volcano. The temperature and f O 2 of the magma tapped by the plinian phase of May 18, 1980, are 870-875&deg;C and NNO+0.8, respectively. The dissolved volatile contents of the melt inclusions have been used to calculate sealing pressures; that is, the pressure at which chemical exchange between inclusion and matrix melt ceased. These are greatest for the May 18 plinian magma (120 to 320 MPa); lower pressures are recorded by samples of the preplinian cryptodome and by all post-May 18 magmas. Magma crystallinity, calculated from melt-inclusion Rb contents, is negatively correlated with sealing pressure, consistent with decompression crystallization. Elevated contents of Li in melt inclusions from the cryptodome and post-May 18 samples are consistent with transfer of Li in a magmatic vapor phase from deeper parts of the magma system to magma stored at shallower levels. The Li enrichment attains its maximum extent at ~150 MPa, which is ascribed to separation of a single vapor phase into H 2 O-rich gas and dense Li-rich brine at the top of the magma column. There are striking correlations between melt-inclusion chemistry and monitoring data for the 1980-86 eruption. Dissolved SO 2 contents of melt inclusions from any given event, multiplied by the mass of magma erupted during that event, correlate with the measured flux of SO 2 at the surface, suggesting that magma degassing and melt-inclusion sealing are closely related in time and space. Textural and chemical evidence indicates that melt inclusions became effectively sealed (physically or kinetically) shortly before eruption. Thus by converting pressure to depth using a density model and edifice-loading algorithm for the volcano, changing depths of magma extraction with time can be tracked and compared to the seismic record. The plinian eruption of May 18, 1980, involved magma stored 5-11 km below sea level; this is inferred to be the subvolcanic magma chamber. The preceding eruptions, including the May 18, 1980, blast, involved magma withdrawal from the cryptodome and conduit down to 5 km below sea level. Subsequent 1980 eruptions tapped magma down to depths of &le;10 km below sea level. Tapping of magma stored deeper than 2 km below sea level stopped abruptly at the end of 1980, coincident with the onset of extensive shallow seismicity and a change from explosive to effusive eruption style from 1981 to 1986. Overall, the 1980-86 eruption is consistent with the evisceration of a thin, vertically extensive body of magma extending from 5 to at least 11 km below sea level and connected to the surface by a thin conduit. In the absence of sustained high magma-supply rates from depth, decompression crystallization of magma ascending through the system leads eventually to plugging of the conduit. The current eruption of Mount St. Helens shares some similarities with the 1981-86 dome-building phase of the previous eruption, in that there is extensive shallow seismicity and extrusion of highly crystalline material in the form of a sequence of flows and spines. Melt inclusions from the current eruption have low H 2 O contents, consistent with magma extraction from shallow depths. Highly enriched Li in melt inclusions suggests that vapor transport of Li is a characteristic feature of Mount St. Helens. Melt inclusions from the current eruption have subtly different trace-element chemistry from all but one of the 1980-86 melt inclusions, with steeper rareearth-element (REE) patterns and low U, Th, and high-fieldstrength elements (HFSE), indicating addition of a new melt component to the magma system. It is anticipated that increasing involvement of the new melt component will be evident as the current eruption proceeds.

Washington↗

Influence of stretching and density contrasts on the chemical evolution of continental magmas: An example from the Ivrea-Verbano Zone

The southern Ivrea-Verbano Zone of the Italian Western Alps contains a huge mafic complex that intruded high-grade metamorphic rocks while they were resident in the lower crust. Geologic mapping and chemical variations of the igneous body were used to study the evolution of underplated crust. Slivers of crustal rocks (septa) interlayered with igneous mafic rocks are concentrated in a narrow zone deep in the complex (Paragneiss-bearing Belt) and show evidence of advanced degrees of partial melting. Variations of rare-earth-element patterns and Sr isotope composition of the igneous rocks across the sequence are consistent with increasing crustal contamination approaching the septa. Therefore, the Paragneiss-bearing Belt is considered representative of an “assimilation region” where in-situ interaction between mantle- and crust-derived magmas resulted in production of hybrid melts. Buoyancy caused upwards migration of the hybrid melts that incorporated the last septa and were stored at higher levels, feeding the Upper Mafic Complex. Synmagmatic stretching of the assimilation region facilitated mixing and homogenization of melts. Chemical variations of granitoids extracted from the septa show that deep septa are more depleted than shallow ones. This suggests that the first incorporated septa were denser than the later ones, as required by the high density of the first-injected mafic magmas. It is inferred that density contrasts between mafic melts and crustal rocks play a crucial role for the processes of contamination of continental magmas. In thick under plated crust, the extraction of early felsic/hybrid melts from the lower crust may be required to increase the density of the lower crust and to allow the later mafic magmas to penetrate higher crustal levels.

Contributions to Mineralogy and Petrology↗

Response of benthic invertebrate assemblages to metal exposure and bioaccumulation associated with hard-rock mining in northwestern streams, USA

Benthic macroinvertebrate assemblages, environmental variables, and associated mine density were evaluated during the summer of 2000 at 18 reference and test sites in the Coeur d'Alene and St. Regis River basins, northwestern USA as part of the US Geological Survey's National Water-Quality Assessment Program. Concentrations of Cd, Pb, and Zn in water and (or) streambed sediment at test sites in basins where production mine density was ???0.2 mines/km2 (in a 500-m stream buffer) were significantly higher than concentrations at reference sites. Zn and Pb were identified as the primary contaminants in water and streambed sediment, respectively. These metal concentrations often exceeded acute Ambient Water Quality Criteria for aquatic life and the National Oceanic and Atmospheric Administration Probable Effect Level for streambed sediment. Regression analysis identified significant correlations between production mine density in each basin and Zn concentrations in water and Pb in streambed sediment (r2 = 0.69 and 0.65, p < 0.01). Metal concentrations in caddisfly tissue, used to verify site-specific exposures of benthos, also were highest at sites downstream from intensive mining. Benthic invertebrate taxa richness and densities were lower at sites downstream than upstream of areas of intensive hard-rock mining and associated metal enrichment. Benthic invertebrate metrics that were most effective in discriminating changes in assemblage structure between reference and mining sites were total number of taxa, number of Ephemeroptera, Plecoptera, and Trichoptera (EPT) taxa, and densities of total individuals, EPT individuals, and metal-sensitive Ephemeroptera individuals.

Journal of the North American Benthological Societ↗

Yields of bedrock wells in Massachusetts

Six to seven percent of the population of Massachusetts obtains its water from domestic bedrock wells. Additional public, commercial, industrial, and domestic supplies from bedrock will be needed in the future. Information about the factors that are related to large well yields is needed. The factors associated with well yields were identified by use of statistical analysis of reported data from 4,218 bedrock wells. The median reported yield of all bedrock wells was 7 gallons per minute, and the median depth was 170 feet. Wells in valleys and lowlands had the largest median yield--I0 gallons per minute. The median well yield on hilltops and slopes was 6 gallons per minute. In valleys and lowlands, significant increases in well yields corresponded to increasing thickness of overburden. On hilltops and slopes, only small increases in well yield corresponded to increases in overburden thickness. Increases in well diameter corresponded to significant increases in well yields for all well locations, depths, and use categories. The common assumptions that fractured crystalline rocks generally yield only small quantities of water to wells and that the fractures that yield water to wells pinch out or are closed because of lithostatic pressure at depths greater than 300 to 400 feet may be in error. Analysis of well data indicates that the median yield of all bedrock wells decreased as well depth increased to 400 feet and increased slightly with well depths greater than 600 feet. The median yield of bedrock wells located in valleys and lowlands reached 50 gallons per minute at depths of 600 to 700 feet. The median yield of wells located on hilltops and slopes reached 15 gallons per minute at depths of 600 to 700 feet. Carbonate bedrock, with a median well yield of 25 gallons per minute, seemed to be the most productive bedrock type. A reported yield of 1,700 gallons per minute from an industrial well completed in carbonate bedrock is the largest reported yield from a bedrock well in Massachusetts. Yield of wells in sedimentary rocks of the Connecticut Valley increased significantly at depths greater than 400 feet, indicating that this bedrock type may have some primary permeability. Commercial or industrial wells had a median yield of 30 gallons per minute. These wells appear to be preferentially sited, large in diameter, and deeper than average to maximize potential well yields. The median reported bedrock well yield and depth have changed over time. The median yield of about 20 gallons per minute for 1920-40 decreased to 6 gallons per minute for 1970-80. Well depth increased from 128 feet for 1950- 60 to 250 feet for 1980-90. The period during which well depths began to increase coincides with a change in bedrock-well drilling methods from cable tool to air rotary with percussion. Four methods of testing the yield of domestic bedrock wells were evaluated: air injection, evacuation and recovery, constant-discharge, and instantaneous discharge or recharge. A constant-discharge test best satisfied the criteria established to evaluate the testing methods. Further data collection and evaluation are needed for the systematic characterization and appraisal of the bedrock aquifers of Massachusetts. Specific elements include (1) improved and expanded collection and storage of well data, (2) detailed hydrogeologic evaluations of apparent high yield bedrock areas, (3) an evaluation of the relation between the vertical distribution of hydraulic properties measured during well drilling to actual hydraulic properties, (4) an evaluation of the effect of well diameter on well yield, and (5) areal evaluations to characterize the quality of water in bedrock.

Water-Resources Investigations Report↗

Strategic and critical metals in produced geothermal fluids from Nevada and Utah

Herein we summarize the results of an investigation dealing with the concentrations and inventories of strategic, critical and valuable materials (SCVM) in produced fluids from geothermal and hydrocarbon reservoirs (50-250° C) in Nevada and Utah. Water samples were collected from thirty-four production wells across eight geothermal fields, the Uinta Basin oil/gas province in northeast Utah, and the Covenant oil field in southwestern Utah; additional water samples were collected from six hot springs in the Sevier Thermal Belt in southwestern Utah. Most SCVM concentrations in produced waters range from <0.1 to 100 µg/kg; the main exception is lithium, which has concentrations that range from <1000 to 25,000 ug/kg. Relatively high concentrations of gallium, germanium, scandium, selenium, and tellurium are measured too. Geothermal waters contain very low concentrations of REEs, below analytical detections limits (0.01 µg/kg), but the concentrations of lanthanum, cerium, and europium range from 0.05 to 5 µg/kg in Uinta basin waters. Among the geothermal fields, the Roosevelt Hot Spring reservoir appears to have the largest inventories of germanium and lithium, and Patua appears to have the largest inventories of gallium, scandium, selenium, and tellurium. By comparison, the Uinta basin has larger inventories of gallium. The concentrations of gallium, germanium, lithium, scandium, selenium, and tellurium in produced waters appear to be partly related to reservoir temperature and concentrations of total dissolved salts. The relatively high concentration and large inventory of lithium occurring at Roosevelt Hot Springs may be related to granitic-gneissic crystalline rocks, which host the reservoir. Analyses of calcite scales from Dixie Valley indicate enrichments in cobalt, gallium, gold, palladium, selenium and tellurium, and these metals appear to be depositing at deep levels in production wells due to boiling. Comparisons with SCVM mineral deposits suggest that brines in sedimentary basins, or derived from lacustrine evaporites, enable aqueous transport of gallium, germanium, and lithium.

Conference Paper↗