Search USGS⌕ Search

SEARCH · Search USGS

Results for “Clays and Clay Minerals”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 613 records · Page 34Linked to original sources
USGS1993

Ground-water-quality assessment of the Central Oklahoma Aquifer, Oklahoma: Geochemical and geohydrologic investigations

The National Water-Quality Assessment pilot project for the Central Oklahoma aquifer examined the chemical and isotopic composition of ground water, the abundances and textures of minerals in core samples, and water levels and hydraulic properties in the flow system to identify geochemical reactions occurring in the aquifer and rates and directions of ground-water flow. The aquifer underlies 3,000 square miles of central Oklahoma and consists of Permian red beds, including parts of the Permian Garber Sandstone, Wellington Formation, and Chase, Council Grove, and Admire Groups, and Quaternary alluvium and terrace deposits. In the part of the Garber Sandstone and Wellington Formation that is not confined by the Permian Hennessey Group, calcium, magnesium, and bicarbonate are the dominant ions in ground water; in the confined part of the Garber Sandstone and Wellington Formation and in the Chase, Council Grove, and Admire Groups, sodium and bicarbonate are the dominant ions in ground water. Nearly all of the Central Oklahoma aquifer has an oxic or post-oxic environment as indicated by the large dissolved concentrations of oxygen, nitrate, arsenic(V), chromium(VI), selenium(VI), vanadium, and uranium. Sulfidic and methanic environments are virtually absent. Petrographic textures indicate dolomite, calcite, sodic plagioclase, potassium feldspars, chlorite, rock fragments, and micas are dissolving, and iron oxides, manganese oxides, kaolinite, and quartz are precipitating. Variations in the quantity of exchangeable sodium in clays indicate that cation exchange is occurring within the aquifer. Gypsum may dissolve locally within the aquifer, as indicated by ground water with large concentra-tions of sulfate, but gypsum was not observed in core samples. Rainwater is not a major source for most elements in ground water, but evapotranspiration could cause rainwater to be a significant source of potassium, sulfate, phosphate and nitrogen species. Brines derived from seawater are the most likely source of bromide and chloride in the aquifer. The dominant reaction in recharge is the uptake of carbon dioxide gas from the unsaturated zone (about 2.0 to 4.0 millimoles per liter) and the dissolution of dolomite (about 0.3 to 1.0 millimoles per liter). This reaction generates calcium, magnesium, and bicarbonate water composition. If dolomite does not dissolve to equilibrium, pH values range from 6.0 to 7.3; if dolomite dissolves to equilibrium, pH values are about 7.5. By the time recharge enters the deeper flow system, all ground water is saturated or supersaturated with dolomite and calcite. After carbonate-mineral equilibration has occurred, cation exchange of calcium and magnesium for sodium is the dominant geochemical reaction, which occurs to a substantial extent only in parts of the aquifer. Mass transfers of cation exchange greater than 2.0 millimoles per liter occur in the confined part of the Garber Sandstone and Wellington Formation and in parts of the Chase, Council Grove, and Admire Groups. Associated with cation exchange is dissolution of small quantities of dolomite, calcite, biotite, chlorite, plagioclase, or potassium feldspar, which produces pH values that range from 8.6 to 9.1. Large tritium concentrations indicate ground-water ages of less than about 40 years for most samples of recharge. Carbon-14 ages for samples from the unconfined aquifer generally are less than 10,000 years. Carbon-14 ages of ground water in the confined part of the aquifer range from about 10,000 to 30,000 years or older. These ages produce a time trend in deuterium values that qualitatively is consistent with the timing of the transition from the last glacial maximum to the present interglacial period. The most transmissive geologic units in the Central Oklahoma aquifer are the Garber Sandstone and Wellington Formation and the alluvium and terrace deposits; the Chase, Council Grove, and Admire Groups are less transmissive on the basis of available specific-capacity data. The transmissivities of the Permian geologic units depend largely on the percentage of sandstone; the percentage is greatest in the central part of the aquifer and decreases in all directions from this central part. Because of large mudstone and siltstone contents, the Hennessey Group and the Vanoss Formation are assumed to be confining units above and below the aquifer. The Cimarron and Canadian Rivers are defined to be the northern and southern extent of the aquifer because of decreases in transmissivity beyond the rivers and because there is no indication of ground-water underflow at these rivers. The eastern boundary of the aquifer is the limit of the outcrop of the Chase, Council Grove, and Admire Groups. The presence of brines in the western part of the study unit and below the aquifer indicate the extent of the freshwater flow system in these directions. Regional ground-water flow is west to east; the Deep Fork is a major discharge area for the regional flow system. Local flow systems are present within the unconfined part of the study unit. Most streams are gaining streams, and very few losing streams are evident. Median values of aquifer properties were estimated as follows: recharge to the saturated zone, 1.6 inches per year; evapotranspiration of water that never reaches the saturated zone, 25 to 30 inches per year; porosity, 0.22; storage coefficient, 0.0002; transmissivity, 260 to 450 feet squared per day; horizontal hydraulic conductivity, 4.5 feet per day; and the ratio of horizontal to vertical hydraulic conductivity, 10,000. Reported ground-water withdrawals peaked in 1985 at 13,900 million gallons but had decreased to 7,860 million gallons by 1989. Unreported domestic withdrawals were estimated to be 1,685 million gallons in 1980. The flow system in the aquifer can be considered to have three major components: (1) A shallow, local flow system in the unconfined part of the aquifer, (2) a deep, regional flow system in the unconfined part of the aquifer, and (3) a deep, regional flow system in the confined part of the aquifer. In the shallow, local flow system, water flows relatively quickly along short flowlines from the point of recharge to the point of discharge at the nearest stream. Many water samples from shallow wells contain large concentrations of tritium, which indicate ground-water ages of less than 40 years. In the deep, regional flow system in the unconfined part of the aquifer, water takes more time to flow along longer flowlines than in the shallow, local flow system. Much of the water in this flow system is recharged along ridges that correspond to ground-water divides between drainage basins. Transit times for water recharging the aquifer along ridges is greater than 5,000 years, computed using a numerical flow model in conjunction with a particle-tracking model. The deep, regional flow system in the confined part of the Garber Sandstone and Wellington Formation is recharged from a small part of the outcrop area of the Garber Sandstone. From the recharge area, water flows west under the confining unit to discharge to streams as far away as the Cimarron River. Flowpaths are relatively long, as much as 50 miles. The transit times in this flow system range from thousands to tens of thousands of years. The long-term hydrogeochemical process occurring in the Central Oklahoma aquifer is removal of unstable minerals, including dolomite, calcite, biotite, chlorite, and feldspars, and the replacement of exchangeable sodium on clays with calcium and magnesium. Over geologic time, the flux of water through the rapidly moving, local flow system has been sufficient to remove most of the dolomite, calcite, and exchangeable sodium. In places, chlorite and feldspars have been removed. In the deep, regional flow system of the unconfined part of the Garber Sandstone and Wellington Formation, the flux of water has been sufficient to remove most of the exchangeable sodium, but carbonate minerals remain sufficiently abundant to maintain dolomite and calcite equilibrium. In the confined part of the Garber Sandstone and Wellington Formation and in the less transmissive parts of the unconfined aquifer, including the Chase, Council Grove, and Admire Groups, ground-water flow is slowest, and the flux of water and extent of reaction have been insufficient to remove either the carbonate minerals or the exchangeable sodium on clays.

Oklahoma↗
USGS2016

Discharge, water temperature, and water quality of Warm Mineral Springs, Sarasota County, Florida: A retrospective analysis

Warm Mineral Springs, located in southern Sarasota County, Florida, is a warm, highly mineralized, inland spring. Since 1946, a bathing spa has been in operation at the spring, attracting vacationers and health enthusiasts. During the winter months, the warm water attracts manatees to the adjoining spring run and provides vital habitat for these mammals. Well-preserved late Pleistocene to early Holocene-age human and animal bones, artifacts, and plant remains have been found in and around the spring, and indicate the surrounding sinkhole formed more than 12,000 years ago. The spring is a multiuse resource of hydrologic importance, ecological and archeological significance, and economic value to the community. The pool of Warm Mineral Springs has a circular shape that reflects its origin as a sinkhole. The pool measures about 240 feet in diameter at the surface and has a maximum depth of about 205 feet. The sinkhole developed in the sand, clay, and dolostone of the Arcadia Formation of the Miocene-age to Oligocene-age Hawthorn Group. Underlying the Hawthorn Group are Oligocene-age to Eocene-age limestones and dolostones, including the Suwannee Limestone, Ocala Limestone, and Avon Park Formation. Mineralized groundwater, under artesian pressure in the underlying aquifers, fills the remnant sink, and the overflow discharges into Warm Mineral Springs Creek, to Salt Creek, and subsequently into the Myakka River. Aquifers described in the vicinity of Warm Mineral Springs include the surficial aquifer system, the intermediate aquifer system within the Hawthorn Group, and the Upper Floridan aquifer in the Suwannee Limestone, Ocala Limestone, and Avon Park Formation. The Hawthorn Group acts as an upper confining unit of the Upper Floridan aquifer. Groundwater flow paths are inferred from the configuration of the potentiometric surface of the Upper Floridan aquifer for September 2010. Groundwater flow models indicate the downward flow of water into the Upper Floridan aquifer in inland areas, and upward flow toward the surface in coastal areas, such as at Warm Mineral Springs. Warm Mineral Springs is located in a discharge area. Changes in water use in the region have affected the potentiometric surface of the Upper Floridan aquifer. Historical increase in groundwater withdrawals resulted in a 10- to 20-foot regional decline in the potentiometric surface of the Upper Floridan aquifer by May 1975 relative to predevelopment levels and remained at approximately that level in May 2007 in the area of Warm Mineral Springs. Discharge measurements at Warm Mineral Springs (1942–2014) decreased from about 11–12 cubic feet per second in the 1940s to about 6–9 cubic feet per second in the 1970s and remained at about that level for the remainder of the period of record. Similarity of changes in regional water use and discharge at Warm Mineral Springs indicates that basin-scale changes to the groundwater system have affected discharge at Warm Mineral Springs. Water temperature had no significant trend in temperature over the period of record, 1943–2015, and outliers were identified in the data that might indicate inconsistencies in measurement methods or locations. Within the regional groundwater basin, Warm Mineral Springs is influenced by deep Upper Floridan aquifer flow paths that discharge toward the coast. Associated with these flow paths, the groundwater temperatures increase with depth and toward the coast. Multiple lines of evidence indicate that a source of warm groundwater to Warm Mineral Springs is likely the permeable zone of the Avon Park Formation within the Upper Floridan aquifer at a depth of about 1,400 to 1,600 feet, or deeper sources. The permeable zone contains saline groundwater with water temperatures of at least 95 degrees Fahrenheit. The water quality of Warm Mineral Springs, when compared with other springs in Florida had the highest temperature and the greatest mineralized content. Warm Mineral Springs water is characterized by a slight-green color, with varying water clarity, low dissolved oxygen (indicative of deep groundwater), and a hydrogen sulfide odor. Water-quality samples detected ammonium-nitrogen and nitrates, but at low concentrations. The drinking water standard for nitrate adopted by the U.S. Environmental Protection Agency is 10 milligrams per liter, measured as nitrogen. Water samples collected at spring vents by divers on April 29, 2015, had concentrations of 0.9 milligram per liter nitrate-nitrogen at vent A and 0.04–0.05 milligram per liter at vents B, C, and D. Typically, the water clarity is highest in the morning (about 30 feet Secchi depth) and often decreases throughout the day. Analysis of existing data provided some insight into the hydrologic processes affecting Warm Mineral Springs; however, data have been sparsely and discontinuously collected since the 1940s. Continuous monitoring of hydrologic characteristics such as discharge, water temperature, specific conductance, and water-quality indicators, such as nitrate and turbidity (water clarity), would be valuable for monitoring and development of models of spring discharge and water quality. In addition, water samples could be analyzed for isotopic tracers, such as strontium, and the results used to identify and quantify the sources of groundwater that discharge at Warm Mineral Springs. Groundwater flow/transport models could be used to evaluate the sensitivity of the quality and quantity of water flowing from Warm Mineral Springs to changes in climate, aquifer levels, and water use.

Florida↗
USGS2015

Geotechnical aspects in the epicentral region of the 2011, M w 5.8 Mineral, Virginia earthquake

A reconnaissance team documented the geotechnical and geological aspects in the epicentral region of the M w (moment magnitude) 5.8 Mineral, Virginia (USA), earthquake of 23 August 2011. Tectonically and seismically induced ground deformations, evidence of liquefaction, rock slides, river bank slumps, ground subsidence, performance of earthen dams, damage to public infrastructure and lifelines, and other effects of the earthquake were documented. This moderate earthquake provided the rare opportunity to collect data to help assess current geoengineering practices in the region, as well as to assess seismic performance of the aging infrastructure in the region. Ground failures included two marginal liquefaction sites, a river bank slump, four minor rockfalls, and a ~4-m-wide, ~12-m-long, ~0.3-m-deep subsidence on a residential property. Damage to lifelines included subsidence of the approaches for a bridge and a water main break to a heavily corroded, 5-cm-diameter valve in Mineral, Virginia. Observed damage to dams, landfills, and public-use properties included a small, shallow slide in the temporary (“working”) clay cap of the county landfill, damage to two earthen dams (one in the epicentral region and one further away near Bedford, Virginia), and substantial structural damage to two public school buildings.

Virginia↗
USGS1988

Genetic interpretations of elemental and chemical differences in a soil chronosequence, California

Soils developed on fluvial terraces in central California have similar parent materials, climatic settings, vegetation cover and slopes but range in age from 40,000 to 3,000,000 years. The soils have chemical compositions that change systematically with increasing age. Such chemical differentiation is most likely the result of long-term weathering and mineralogical transformations that occurred since deposition of terrace fills and stabilization of the geomorphic surfaces. The changes in composition with time closely mimic other studies on mineral weathering, in which alkali and alkali-earth elements are lost more rapidly than transitional elements. The relative rates of element loss were determined by changes in element ratios over time. Net losses and gains of elements in different size fractions were monitored by their concentrations relative to Zr, the most stable constituent. Both sand and finer size fractions have lost considerable amounts of Ca, Mg, Na and K. Aluminum appears to have been lost from the sand fraction and gained in the fine fraction over a 3-million-year-time-span. Although there is no evidence for losses of Fe and Ti from sands, there is a net influx of Fe and Ti into finer fractions, probably gained from undetectable yet significant weathering of sand grains. Etching of sand grains, clay mineralogy, and microprobe analyses also indicate that the soils have undergone these chemical transformations during their formation. Mineralogical analyses also mimic other studies on mineral weathering, in which the pyroxenes weather more rapidly than hornblende, which weathers more rapidly than sphene or zircon.

California↗
USGS2005

High-resolution seismic-reflection image of the Chesapeake Bay impact structure, NASA Langley Research Center, Hampton, Virginia

A 1-kilometer-long (0.62-mile-long) seismic reflection and refraction profile collected at the National Aeronautics and Space Administration (NASA) Langley Research Center, Hampton, Va., provides a detailed image of part of the annular trough of the buried, 35-million-year-old Chesapeake Bay impact structure. This profile passes within 5 meters (m; 16.4 feet (ft)) of a 635.1-m-deep (2,083.8-ft-deep), continuously cored and geophysically logged test hole at the Langley Center (the USGS-NASA Langley corehole). High-resolution seismic reflection images (having a common-depth-point spacing of 2.5 m (8.2 ft)) of the upper 1,000 m (3,281 ft) along the seismic profile were generated by using refraction velocities and corehole sonic velocities to convert from time sections to depth sections. Time-distance, unmigrated depth-distance, and migrated depth-distance images show lateral variations in the geologic units observed in the USGS-NASA Langley corehole. A high-amplitude reflection at 630 to 625 m (2,067 to 2,051 ft) depth on the migrated depth image correlates with the top of weathered granite (the Langley Granite) at 626.3 m (2,054.7 ft) in the Langley core. Additional high-amplitude reflections below that depth likely represent a weathering profile developed in the upper part of the granite. Diffractions on the unmigrated images suggest that the granite contains numerous inhomogeneities that may consist of mineral veins and mineralized faults and fractures, as seen in the granite cores. Above the granite, crater unit A (minimally to moderately disturbed sands and clays of the Cretaceous Potomac Formation) is characterized by semicontinuous, horizontal and moderately inclined reflections that are broken by pervasive, subvertical, small-offset faults. Sediments of the lower beds of crater unit A below 558.1 m (1,831.0 ft) in the core have horizontal bedding and are nearly pristine. Above that depth, the upper beds of crater unit A contain thick fluidized sand intervals and fractured clay-silt beds. The contact between the granite and crater unit A is essentially horizontal on the migrated depth profile and shows minor relief produced by a few steeply dipping faults. Above crater unit A, the lower beds of crater unit B are lithologically similar to the upper beds of crater unit A and display similar impact-generated deformation. In the migrated depth image, crater unit A and the lower beds of crater unit B are combined into one unit. A thin zone (0.3 m (1.0 ft) thick) of injected glauconitic sediment at the base of the lower beds (at 442.5 m (1,451.7 ft) depth) is the only occurrence of exotic material in the lower beds of crater unit B in the core. The upper beds of crater unit B (above 427.7 m (1,403.3 ft) depth) are represented by discontinuous, locally weak, isolated, or inclined reflections on the migrated depth image. In the core, the upper beds of crater unit B are divided into megablocks and megablock zones that consist of fragmented sediments of the Potomac Formation. The megablocks are separated by matrix zones that consist of smaller blocks of sediments of the Potomac Formation suspended in a matrix of native disaggregated sediments of the Potomac Formation and injected, exotic disaggregated, glauconitic Upper Cretaceous and lower Tertiary marine sediments. Angular relationships and offsets of reflections across the high-relief contact between the upper beds of crater unit B and the underlying combined crater unit A and the lower beds of crater unit B suggest that the contact is a dip-slip fault locally. Above a contact with crater unit B at a depth of 269.4 m (884.0 ft), the Exmore beds are represented by strong, continuous and discontinuous, overstepping reflections that suggest division of the Exmore into four laterally discontinuous depositional subunits. Two of these subunits are present near the Langley corehole on the seismic images and are recognized in the core (Gohn and others, this volume, chap. C). In the Langley core, the Exmore beds consist of clasts of Cretaceous and Tertiary preimpact sediments and cataclastic, shocked, pre-Mesozoic igneous rocks suspended in a matrix of calcareous, muddy, quartz-glauconite sand and granules that contains shocked quartz. The dipping, truncated, and disrupted reflections within crater units A and B are interpreted to represent a 550-m-wide (1,805-ft-wide), stratabound collapse structure. This structure does not affect the underlying basement granite or the lower beds of crater unit A, nor does it affect the base of the Exmore beds above crater unit B. The collapse structure is not bounded laterally by major normal faults. Instead, structural displace ments appear to be distributed among abundant short, smalloffset faults and intervals of fluidized sediment. Fluidized sands above 558 m (1,831 ft) depth in crater unit A are interpreted as a low-strength zone that accommodated the widespread, latestage, gravitational collapse of the impact structure. The pro posed Langley collapse structure may be analogous to stratabound grabens in the outer zone of the Silverpit crater (North Sea). The Exmore beds are interpreted as impact-generated, ocean-resurge deposits. The upper contact of the Exmore section is a wavy, semicontinuous reflection that may represent large bedforms produced by resurge currents or returning impact-generated tsunamis, or it may represent the unmodified blocky or hummocky top of the final Exmore debris flow. Typically continuous, nearly horizontal reflections characterize the upper Eocene to Pleistocene postimpact section of dominantly marine sediments.

Virginia↗
USGS2023

Beyond conductive targets: Characterizing lithium-prospective lacustrine evaporite mineral systems of North America’s Basin and Range Province with regional-scale AEM

The Basin and Range province of North America hosts substantial lacustrine evaporite mineral systems prospective for lithium, a critical mineral currently listed for mineral resource assessment by the U.S. Geological Survey. Airborne electromagnetic (AEM) surveys are being conducted to support these assessments by identifying shallow clays and brines, as well as through improving the shallow subsurface geologic framework of the regional fluid flow system. In 2022-2023, three focus areas with proven lithium resources or considered highly prospective for lithium are being surveyed. Results from this effort can help to improve our understanding of the geologic conditions and geophysical signatures associated with known resource regions and benefit future lithium resource assessments by identifying regions with similar geophysical and geologic characteristics.

Arizona, California, Idaho, Nevada, Oregon, Utah↗
USGS2020

Impacts of mineralogical variation on CO2 behavior in small pores from producing intervals of the Marcellus Shale: Results from neutron scattering

The Near and InterMediate Range Order Diffractometer (NIMROD) was used to examine the potential impact of shale mineralogy on CO 2 behavior within micropores. Two samples with varying mineral compositions were obtained from producing intervals in the dry gas window in the Middle Devonian Marcellus Shale. One of the samples contained relatively high amounts of quartz and clay and low carbonate, the other contained relatively equal amounts of quartz, carbonate, and clay. The samples were probed with CO 2 at subcritical pressures (20–50 bar) and temperature (22 °C) and characterized over a neutron scattering vector ( Q ) range of 0.02 < Q < 50 Å –1 . This Q range provides information from the atomistic length-scale up to pore radii of 10 nm. Mineralogy variations between the samples did not affect scattering ratios over the entire Q range accessible with the NIMROD. Q values for the minimum scattering ratios of both samples at similar pressures are remarkably similar, particularly for Q < ∼0.09 Å –1 , and maximum scattering ratios are similar in both samples suggesting that mineral pores are so uncommon in the pore sizes examined that they cannot be resolved due to the overwhelming amounts of organic pores in these samples. Overall, these findings suggest that mineralogical variations have little effect on CO 2 behavior within organic matter-hosted shale micropores at high thermal maturities and they lend support to the assertion that CO 2 cannot be stored in the vast surface areas of micropores in organic material in shale formations. In addition, CO 2 enhanced oil recovery (EOR) is unlikely to displace petroleum from some of the smaller mesopores (2.5 to ∼3.5 nm) and all of the micropores because they are effectively closed to CO 2 . amples were probed with CO2 at subcritical pressures (20 50 bar) and temperature (22 oC) and characterized over a neutron scattering vector (Q) range of 0.02 < Q < 50 -1. This Q range provides information on nominal pore size radii of around 10 0.5 nm. Mineralogy variations between the samples did not affect scattering ratios over the entire Q range accessible with the NIMROD. Q values for the minimum scattering ratios of both samples at similar pressures are statistically indistinguishable and maximum scattering ratios are similar in both samples suggesting that mineral pores are either absent or are so uncommon that they cannot be resolved due to the overwhelming amounts of organic pores in these samples. Overall, these findings suggest that mineralogical variations have little effect on CO2 behavior within organic matter-hosted shale micropores at high thermal maturities and they lend support to the assertion that CO2 cannot be stored in the vast surface areas of micropores (<2.5 nm) in shale formations. In addition, CO2 enhanced oil recovery (EOR) is unlikely to displace petroleum from some of the smaller mesopores (2.5 10 nm) and all of the micropores because they are effectively closed to CO2.

Energy & Fuels↗
USGS1886

The gabbros and associated hornblende rocks occurring in the neighborhood of Baltimore, Maryland

Considerable attention has been devoted during late years to the metamorphism of igneous rocks, and it can now be regarded as placed beyond reasonable doubt that such rocks may be changed to more or less schistose masses, which often closely resemble crystallized sediments. This possibility has heretofore been largely ignored, owing doubtless to the extensive obliteration of those characteristics which are generally regarded as most typical of eruptive rocks. Schistose or banded structure, however, can now hardly be considered as necessarily an indication of sedimentary origin. The minerals which are most characteristic of the so-called crystalline schists have been repeatedly shown to be derived from the alteration of igneous as well as of aqueous formations. These minerals only represent the final and most stable combination of certain elements under certain conditions, and are quite independent of the earlier combinations in which these elements may have existed. A lava bed and a clay bank, if the two may be supposed to have originally had the same chemical composition, might, under the influence of the same metamorphic agencies, ultimately give rise to the same rock in spite of original differences in structure or mineralogical composition. Stratification may be obliterated by metamorphism, while foliation, or even a banded structure, may, by the same means, be secondarily induced. Neither structure nor mineral composition can be taken as an infallible guide in determining the origin or the age of rocks. The present paper is intended as a contribution to our knowledge of a particular phase of metamorphism in eruptive rocks, i. e., that one which is dependent on the secondary development of hornblende by the paramorphism or pseudomorphism of pyroxene. This is a change the frequency of which renders it of fundamental geological importance. It has already received considerable attention from many eminent geologists, but no locality heretofore studied seems to have afforded opportunities for tracing out every stage in the process of alteration superior to those offered by the area of massive rocks west and northwest of the city of Baltimore. Here, covering a district of over fifty square miles, the unchanged pyroxene rock and its resultant hornblendic equivalent occur in the most intimate relations. Exposures of both rocks in situ are numerous, and the opportunity of following out the gradual transition of one into the other is proportionately great.

Maryland↗
USGS1995

Mineral and energy resources of the Roswell Resource Area, East-Central New Mexico

The sedimentary formations of the Roswell Resource Area have significant mineral and energy resources. Some of the pre-Pennsylvanian sequences in the Northwestern Shelf of the Permian Basin are oil and gas reservoirs, and Pennsylvanian rocks in Tucumcari Basin are reservoirs of oil and gas as well as source rocks for oil and gas in Triassic rocks. Pre-Permian rocks also contain minor deposits of uranium and vanadium, limestone, and gases. Hydrocarbon reservoirs in Permian rocks include associated gases such as carbon dioxide, helium, and nitrogen. Permian rocks are mineralized adjacent to the Lincoln County porphyry belt, and include deposits of copper, uranium, manganese, iron, polymetallic veins, and Mississippi-Valley-type lead-zinc. Industrial minerals in Permian rocks include fluorite, barite, potash, halite, polyhalite, gypsum, anhydrite, sulfur, limestone, dolomite, brine deposits (iodine and bromine), aggregate (sand), and dimension stone. Doubly terminated quartz crystals, called 'Pecos diamonds' and collected as mineral specimens, occur in Permian rocks along the Pecos River. Mesozoic sedimentary rocks are hosts for copper, uranium, and small quantities of gold-silver-tellurium veins, as well as significant deposits of oil and gas, carbon dioxide, asphalt, coal, and dimension stone. Mesozoic rocks contain limited amounts of limestone, gypsum, petrified wood, and clay. Tertiary rocks host ore deposits commonly associated with intrusive rocks, including platinum-group elements, iron skarns, manganese, uranium and vanadium, molybdenum, polymetallic vein deposits, gold-silver-tellurium veins, and thorium-rare-earth veins. Museum-quality quartz crystals are associated with Tertiary intrusive rocks. Industrial minerals in Tertiary rocks include fluorite, vein- and bedded-barite, caliche, limestone, and aggregate. Tertiary and Quaternary sediments host important placer deposits of gold and titanium, and occurrences of silver and uranium. Important industrial commodities include caliche, limestone and dolomite, and aggregate. Quaternary basalt contains sub-ore-grade uranium, scoria, and clay deposits.

New Mexico↗
USGS2006

State summaries: Indiana

In 2005, the Indiana industrial minerals industry generated $789 million, a record high for the state and an increase of 2.2% from 2004. Among all states, Indiana ranked 24th. Mineral commodities produced in the state included crushed limestone and dolomite, construction sand and gravel, industrial sand, dimension limestone, dimension sandstone, gypsum, common clay and shale, freshwater pearls, peat, lime, and masonry and portland cement.

Mining Engineering↗
USGS1982

Mineral resource potential map of the Troublesome Roadless Area, McCreary County, Kentucky

A geologic and geochemical investigation and a survey of existing mines and prospects have been conducted to determine the mineral resource potential of the Troublesome Roadless Area, McCreary County, Ky. The study area comprises six tracts totaling about 2,943 acres in the Daniel Boone National Forest. It is in the Cumberland Plateau section of the Appalachian Plateaus Province. All surface and mineral rights are federally owned. Limestone and shale units of Mississippian age and overlying sandstone, shale, and coal beds of Pennsylvanian age comprise the bedrock exposed in the Troublesome Roadless Area. Coal, sandstone, and shale are the principal mineral resources in the study area. Coal has been mined near the roadless area from at least two coal beds. Available data indicate that coal reserves do not underlie the area. Coal resources totalling 7 4 7,000 short tons in the Stearns No. 1112 (?) coal bed and 166,000 short tons in the Barren Fork(?) coal bed are contained in the Troublesome Roadless Area. Possible uses for sandstone units include silica sand, construction sand, and dimension stone. Shale may be suitable for structural clay products. Commercial quantities of oil and gas may be present at shallow depth in rocks of Mississippian age. A stream-sediment geochemical survey failed to recognize anomalies that would suggest mineralization, and the metallic mineral potential of the study area appears limited.

Kentucky↗
USGS1992

Ground water chemistry and geochemical modeling of water-rock interactions at the Osamu Utsumi mine and the Morro do Ferro analogue study sites, Poços de Caldas, Minas Gerais, Brazil

Surface and ground waters, collected over a period of three years from the Osamu Utsumi uranium mine and the Morro do Ferro thorium/rare-earth element (Th/REE) deposits, were analyzed and interpreted to identify the major hydrogeochemical processes. These results provided information on the current geochemical evolution of ground waters for two study sites within the Po&ccedil;os de Caldas Natural Analogue Project. The ground waters are a K&ndash;Fe&ndash;SO 4 &ndash;F type, a highly unusual composition related to intense weathering of a hydrothermally altered and mineralized complex of phonolites. Tritium and stable isotope data indicate that ground waters are of meteoric origin and are not affected significantly by evaporation or water&ndash;rock interactions. Recharging ground waters at both study sites demonstrate water of less than about 35 years in age, whereas deeper, more evolved ground waters are below 1 TU but still contain in most cases detectable tritium. These deeper ground waters may be interpreted as being of 35 to 60 or more years in age, resulting mainly from an admixture of younger with older ground waters and/or indicating the influence of subsurface produced tritium. Geochemical processes involving water&ndash;rock&ndash;gas interactions have been modeled using ground water compositions, mineralogic data, ion plots and computations of speciation, non-thermodynamic mass balance and thermodynamic mass transfer. The geochemical reaction models can reproduce the water chemistry and mineral occurrences and they were validated by comparing the results of thermodynamic mass transfer calculations (using the PHREEQE program, Parkhurst et al., 1980). The results from the geochemical reaction models reveal that the dominant processes are production of CO 2 in the soil zone through aerobic decay of organic matter, dissolution of fluorite, calcite, K-feldspar, albite, chlorite and manganese oxides, oxidation of pyrite and sphalerite, and precipitation of ferric oxides, silica and kaolinite. Gibbsite precipitation can be modeled for the shallow (recharge) water chemistry at Morro do Ferro, consistent with known mineralogy. Recharge waters are undersaturated with respect to barite and discharging waters and deeper ground waters are saturated to supersaturated with respect to barite demonstrating a strong solubility control. Strontium isotope data demonstrate that sources other than calcium-bearing minerals are required to account for the dissolved strontium in the ground waters. These may include K-feldspar, smectite&ndash;chlorite mixed-layer clays and goyazite [SrAl 3 (PO 4 ) 2 (OH) 5 &bull; H 2 O]. 1992.

Journal of Geochemical Exploration↗
USGS1974

Geology and mineral resources of the Lehighton and Palmerton quadrangles, Carbon and Northampton Counties, Pennsylvania

The Lehighton and Palmerton 73 1/2-minute quadrangles cover an area of about 112 square miles of diversified terrain in the folded Appalachian Mountain and Great Valley sections of the Valley and Ridge physiographic province in Carbon, Lehigh, and Northampton Counties, Pennsylvania. The Lehigh River and Blue Mountain are the prominent features of the topography. Rock units defined and mapped in the area are the lithified sediments that were deposited in a variety of offshore marine, marine shelf, marginal marine, and fluvial environments associated with two phases of basin filling. The rocks are separated into four lithotectonic units, each deformed semi-independently of adjacent lithotectonic units. Decollements presumably separate the lithotectonic units. Lithotectonic unit 1 consists of about 12,000 feet of slate and graywacke of the Middle and Upper Ordovician Martinsburg Formation. This unit contains mainly asymmetric, similar, and nearly isoclinal folds, with wave lengths of 1,000 to 3,000 feet and amplitudes of 400 to 2,000 feet, formed mainly by passive flow and slip. Lithotectonic unit 2 includes about 3,100 feet of sandstone, siltstone, shale, and conglomerate of the Shawangunk Formation (Ordovician(?) and Silurian), Bloomsburg Red Beds (Silurian), and the lower part of the Poxono Island Formation (Silurian). This unit contains mainly asymmetric and concentric folds, with wavelengths of about one mile and amplitudes of 1,500 to 5,000 feet, formed by flexural slip with minor passive slip and flow. Lithotectonic unit 3 contains about 750 feet of limestone, shale, siltstone, sandstone, and dolomite of the upper part of the Poxono Island Formation, Bossardville Limestone, and Decker Formation (all Silurian), the Coeymans and New Scotland Formations, Shriver Chert, and Ridgeley Formation of the Oriskany Group and the Schoharie-Esopus Formation (all Lower Devonian), and the Palmerton Formation and Buttermilk Falls Limestone (both Middle Devonian). This unit has asymmetric, concentric, similar, and flap folds, with wavelengths of 1,000 to 1,500 feet and amplitudes of about 1,550 feet, formed by flexural slip and flow and passive slip and flow. Lithotectonic unit 4 consists of more than 13,000 feet of sandstone, conglomerate, siltstone, and shale of the Middle Devonian Marcellus and Mahantango Formations, the Upper Devonian Trimmers Rock and Catskill Formations, the Devonian-Mississippian Spechty Kopf Forma tion, the Mississippian Pocono and Mauch Chunk Formations, and the Pennsylvanian Pottsville Formation. This unit contains nearly symmetric, concentric flexural-slip folds with wavelengths of more than five miles and amplitudes of about one mile. Surficial deposits occur throughout the mapped area and include: Pleistocene pre-lllinoian(?) till and outwash(?), lllinoian(?) till and outwash, Wisconsinan outwash, shale-chip rubble, boulder fields, and colluvium; and Holocene alluvium, landslide deposits, and man-made dumps. The rocks of the mapped area, except for the deeply weathered lime stones, generally have good slope stability and foundation support strength, moderate to low primary infiltration capacity and aquifer potential but moderate to high secondary values for these properties, moderate resistance to weathering, and are moderately difficult to difficult to excavate. All of these properties are strongly influenced by the abundant bedding, cleavage, and joint partings of the rocks. Similar evaluations for the surficial deposits indicate less desirable values except for the ease of excavation of most of the unconsolidated materials. Currently active and potential mineral resources are numerous in the Lehighton and Palmerton quadrangles and include slate, sand, paint ore, building stone, crushed rock, lightweight aggregate, clinker residue, clay, hydraulic cement, and roofing granules.

Pennsylvania↗
USGS1982

Mineral resource potential map of the Savannah Roadless Area, Liberty County, Florida

The Savannah Roadless Area is underlain by sedimentary rocks having low potential for oil and gas and minerals. The low potential for oil or gas notwithstanding, the possibilities for discovery cannot be ruled out because the area and nearby lands have not been thoroughly explored. No minerals have been mined within the Savannah Roadless Area, and the only production nearby has been the digging of clayey sand used in stabilizing U.S. Forest Service roads. Fuller's earth, quartz sand and gravel, clayey sand, and common clay presently are produced elsewhere in the region, and limestone and peat have been produced in the past. No clay suitable for structural clay products or fuller's earth is present in the roadless area; however, a bed of quartz sand and gravel of excellent quality was penetrated at a depth interval of 37-50 ft by one drill hole. Although this bed is coarser grained-and therefore is more suitable for many uses-than the sand deposits worked elsewhere in the Big Bend region, its mineral resource potential is reduced by the thickness of overburden above it and by its distance from markets in population centers. The Apalachicola National Forest has been explored for phosphate and reconnoitered for heavy minerals, but no valuable deposits of either have been found.

Florida↗
USGS1978

Geochemical maps showing the distribution and abundance of gold in stream sediments and of gold and silver in heavy-mineral concentrates in the Seward and Blying Sound quadrangles, Alaska

Reconnaissance geochemical and mineralogical sampling was done in the Seward and Blying Sound quadrangles during 1975 and 1976 as part of the Alaska Mineral Resources Assessment Program (AMRAP). These maps show the distribution and abundance of gold and silver in heavy-mineral concentrates. Stream-sediment and heavy-mineral concentrate samples were collected from active stream channels and locally, from the interface of streambeds with intermediate- to low-tide beaches. Most of the stream sediment is fine- to coarse-grained sand, with a clay-silt fraction in streams discharging from glaciers. Stream sediment samples were air dried and sieved through a 80-mesh (0.2 mm) sieve, and the minus-80 mesh fraction was saved for analysis. A split of each sample was analyzed for gold by a 10 gram atomic-absorption method (Ward and others, 1969). Another split was analyzed for 16 elements by a semiquantitative spectrographic method (Grimes and Marranzino, 1968). The heavy-mineral concentrates were obtained by panning stream sediments in the field to remove most of the light minerals. The panned samples were sieved though a 20-mesh (0.8 mm) screen in the laboratory, and the minus-20 mesh fraction was further separated with bromoform (specific gravity: 2.86) to remove any remaining light-mineral grains. Magnetite and other strongly magnetic heavy minerals were removed from the heavy-mineral fraction by use of a hand magnet. The remaining sample was passed through a Frantz Isodynamic Separator 1 and a nonmagnetic fraction was obtained at a setting of 0.6 amperes. A split of this fraction was pulverized and analyzed for 16 elements including gold and silver by semiquantitative spectrographic method used for analyzing the stream sediment. The remaining split of the nonmagnetic fraction was examined for its mineralogic composition using a binocular microscope and X-ray diffraction. The nonmagnetic concentrates primarily contain muscovite, sphene, zircon, apatite, rutile, and anatase. Ore minerals such as gold, scheelite, minium, and most sulfides are also found in this fraction. Sample sites and gold and silver values (in parts per million) are indicated by symbols as defined in the histograms. The maps show two populations for gold in stream sediments and for gold and silver heavy mineral concentrates. One population consists of generally higher gold and silver values found in samples collected in the sedimentary terrane in the western half of the area. The other population consists of generally lower gold and silver values found in samples collected in areas of sheeted basalt dikes, pillow basalts, and sedimentary terrane in the eastern half of the area. The anomalous silver values found on Knight Island and Latouche Island are associated with chalcopyright- and pyrite-bearing rocks. 1 The use of trade names is for descriptive purposes only and does not constitute endorsement of those products by the U.S. Geological Survey.

Alaska↗
USGS1994

Euramerican tonsteins: Overview, magmatic origin, and depositional-tectonic implications

Carboniferous tonsteins (kaolinized volcanic-ash beds) of wide geographic distribution are known in both Europe and North America. Relict volcanic minerals common in these Euramerican tonsteins are volcanic quartz (including beta-quartz paramorphs), zircon and ilmenite; less common are magnetite, fayalite, rutile, monazite, xenotime, apatite and sanidine. Data for two relatively thick (3-13 cm) and widespread (>400 km) European tonsteins (Erda and Sub-Worsley Four-foot) indicate an increase in detrital quartz near the top of the beds which indicates mixing with normal clastic sediments, including the introduction of heavy detrital minerals (e.g., tourmaline and garnet). These thick tonsteins show multiple horizontal bedding, normal graded bedding, disturbed bedding, and centimeter-scale scour surfaces. The Fire Clay tonstein in North America represents from one to five separate volcanic air-fall ash deposits as determined by normal graded bedding and mineralogical analysis. These features indicate several episodes of volcanic-ash deposition and very localized subsequent erosion and bioturbation. Electron microprobe data from glass inclusions in volcanic quartz in Euramerican tonsteins indicate a rhyolitic origin for these tonsteins and reveal chemical "fingerprints" valuable for intra- and inter-basinal correlations. However, the tectonic framework for European and North American tonsteins was quite different. In Europe, volcanic-ash beds were associated with Variscan collisional tectonics, whereas in North America, volcanic ash was associated with Ouachita tectonic activity, explosive volcanism from the Yucatan block, collision between the South American and North American plates, and the formation of Pangea.

Palaeogeography, Palaeoclimatology, Palaeoecology↗
USGS1981

Lithology, reservoir properties, and burial history of portion of Gammon Shale (Cretaceous), southwestern North Dakota

In the northern Great Plains, large quantities of biogenic methane are contained at shallow depths in Cretaceous marine mudstones. The Gammon Shale and equivalents of the Milk River Formation in Canada, which comprise most sediments deposited offshore during the Eagle-Telegraph Creek regression, are typical of such gas-bearing rocks. At Little Missouri field, southwestern North Dakota, Gammon reservoirs consist of discontinuous lenses and laminae of siltstone, less than 10 mm thick, enclosed by silty clay shale. Large amounts of allogenic clay, including highly expansible mixed-layer illite-smectite cause great water sensitivity and high measured and calculated water-saturation values. Reconstructed burial depths, clay mineralogy, and organic matter maturation studies show that the Gammon has not undergone thermal conditions sufficient for oil or thermal gas generation. Scarce authigenic minerals such as pyrite, siderite, and calcite probably formed as a result of bacterial metabolism early in the burial history. The scarcity of authigenic silicates suggests that diagenesis has been inhibited during much of the burial history by the presence of free methane. Shale layers are practically impermeable whereas siltstone microlenses are porous (30 to 40%) and have permeabilities on the order of 3 to 30 md. Reservoir continuity between siltstone layers is poor and, overall, reservoir permeability is probably less than 0.4 md. Connecting passageways between siltstone lenses are 0.1 µm or less in diameter. Organic matter in the low-permeability reservoirs served as the source of biogenic methane, and capillary forces acted as the trapping mechanism for gas accumulation. At Little Missouri field, reservoirs and non-reservoirs cannot be distinguished on the basis of lithology, and much of the Gammon interval is potentially economic. Future research should be directed toward determining the physical basis of log response in the low-permeability reservoirs and toward the development or application of water-free recovery technology.

North Dakota↗