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At least 613 records · Page 34Linked to original sources
USGS2023

Interlaboratory study: Testing reproducibility of solid biofuels component identification using reflected light microscopy

Considering global market trends and concerns about climate change and sustainability, increased biomass use for energy is expected to continue. As more diverse materials are being utilized to manufacture solid biomass fuels, it is critical to implement quality assessment methods to analyze these fuels thoroughly. One such method is reflected light microscopy (RLM), which has the potential to complement and enhance current standard testing, leading to improving fuel quality assessment and, ultimately, preventing avoidable air pollution. An interlaboratory study (ILS) was conducted to test the reproducibility of biomass fuels component identification using a reflected light microscopy technique. The exercise was conducted on thirty photomicrographs showing biomass and various undesired components (like plastics or mineral matter), which were purposely added (by the ILS organizers) to contaminate wood pellets and charcoal-based grilling fuels. Forty-six participants had various levels of difficulty identifying the marked components, and as a result, the percentage of correct answers ranged from 52.2 to 94.4%. Among the most difficult components to distinguish were petroleum products and inorganic matter. Various reasons led to the misidentification, including insufficient morphological descriptions of the components provided to participants, ambiguities of the nomenclature, limitations of the analytical and exercise method, and insufficient experience of the participants. Overall, the results indicate that RLM has the potential to enhance the quality assessment of biomass fuels. However, they also demonstrate that the petrographic classification used in this exercise requires further refinement before it can be standardized. While a new simplified classification of solid biomass fuels components was created as an outcome of this study, future research is necessary to refine the nomenclature, develop a microscopic morphological description of the components, and verify the accuracy of component identification with a follow-up ILS.

International Journal of Coal Geology↗
USGS2021

A new approach for representing agent-environment feedbacks: Coupled agent-based and state-and-transition simulation models

Context Agent-based models (ABMs) and state-and-transition simulation models (STSMs) have proven useful for understanding processes underlying social-ecological systems and evaluating practical questions about how systems might respond to different scenarios. ABMs can simulate a variety of agents (autonomous units, such as wildlife or people); agent characteristics, decision-making, adaptive behavior, and mobility; and agent-environment interactions. STSMs are flexible and intuitive stochastic landscape models that can track scenarios and integrate diverse data. Both can be run spatially and track metrics of management success. Objectives Due to the complementarity of these approaches, we sought to couple them through a dynamic linkage and demonstrate the relevance of this advancement for modeling landscape processes and patterns. Methods We developed analytical techniques and software tools to couple these modeling approaches using NetLogo, R, and the ST-Sim package for SyncroSim. We demonstrated the capabilities and value of this coupled approach through a proof-of-concept case study of bison-vegetation interactions in Badlands National Park. Results The coupled ABM-STSM: (1) streamlined handling of model inputs and outputs; (2) allowed representation of processes at multiple temporal scales; (3) minimized assumptions; and (4) generated spatial and temporal patterns that better reflected agent-environment interactions. Conclusions These developments constitute a new approach for representing agent-environment feedbacks; modelers can now use output from an ABM to dictate landscape changes within an STSM that in turn influence agents. This facilitates experimentation across domains (agent and environment) and creation of more realistic and management-relevant projections, and opens new opportunities for communicating models and linking to other methods.

Landscape Ecology↗
USGS1997

U.S. Geological Survey Subsidence Interest Group Conference; proceedings of the Technical Meeting, Las Vegas, Nevada, February 14-16, 1995

Introduction to Papers: This report is a compilation of short papers that are based on oral presentations summarizing the results of recent research that were given at the third meeting of the Subsidence Interest Group held in Las Vegas, Nevada, February 14-16, 1995. The report includes case studies of land subsidence and aquifer-system deformation resulting from fluid withdrawal, geothermal development, and mine collapse. Methods for monitoring land subsidence using Global Positioning System technology for the rapid and accurate measurement of changes in land-surface altitude also are described. The current status of numerical simulation of land subsidence in the USGS is summarized, and several of the short papers deal with the development and application of new numerical techniques for simulation and quantification of aquifer system deformation. Not all oral presentations made at the meeting are documented in this report. Several of the presentations were of ongoing research and as such, the findings were provisional in nature and were offered at the meeting to stimulate scientific discussion and debate among colleagues. The information presented in this report, although only a subset of the proceedings of the meeting in Las Vegas, should help expand the scientific basis for management decisions to mitigate or control the effects of land subsidence. The short papers describing the results of these studies provide a cross section of ongoing research in aquifer mechanics and land subsidence and also form an assessment of the current technology and 'state of the science.' The analytical and interpretive methods described in this report will be useful to scientists involved in studies of ground-water hydraulics and aquifer-system deformation.

Open-File Report↗
USGS1985

Methods for determination of inorganic substances in water and fluvial sediments

Chapter Al of the laboratory manual contains methods used by the Geological Survey to analyze samples of water, suspended sediments, and bottom material for their content of inorganic constituents. Included are methods for determining the concentration of dissolved constituents in water, total recoverable and total of constituents in water-suspended sediment samples, and recoverable and total concentrations of constituents in samples of bottom material. Essential definitions are included in the introduction to the manual, along with a brief discussion of the use of significant figures in calculating and reporting analytical results. Quality control in the water-analysis laboratory is discussed, including accuracy and precision of analyses, the use of standard reference water samples, and the operation of an effective quality assurance program. Methods for sample preparation and pretreatment are given also. A brief discussion of the principles of the analytical techniques involved and their particular application to water and sediment analysis is presented. The analytical methods involving these techniques are arranged alphabetically according to constituent. For each method given, the general topics covered are application, principle of the method, interferences, apparatus and reagents required, a detailed description of the analytical procedure, reporting results, units and significant figures, and analytical precision data, when available. More than 125 methods are given for the determination of 70 different inorganic constituents and physical properties of water, suspended sediment, and bottom material.

Open-File Report↗
USGS2017

Comparisons of 210Pb and pollen methods for determining rates of estuarine sediment accumulation

Comparisons of sedimentation rates obtained by 210 Pb and pollen analyses of 1-m cores collected throughout the Potomac Estuary show good agreement in the majority of cores that can be analyzed by both methods. Most of the discrepancy between the methods can be explained by the analytical precision of the 210 Pb method and by the exactness with which time horizons can be identified and dated for the pollen method. X-radiographs of the cores and the distinctness of the pollen horizons preclude significant displacement by reworking and/or mixing of sediments. Differences between the methods are greatest where uncertainties exist in assigning a rate by one or both methods (i.e., 210 Pb trends and/or “possible” horizon assignments). Both methods show the same relative rates, with greater sediment accumulation more common in the upper and middle estuary and less toward the mouth. The results indicate that geochronologic studies of estuarine sediments should be preceded by careful observation of sedimentary structures, preferably by X-radiography, to evaluate the extent of mixing of the sediments. Time horizons, whether paleontologic or isotopic, are generally blurred where mixing has occurred, precluding precise identification. Whenever possible, two methods should be used for dating sediments because a rate, albeit erroneous, can be obtained isotopically in sediments that are mixed; accurate sedimentation rates are also difficult to determine where the time boundary is a zone rather than a horizon, where the historical record does not provide a precise date for the pollen horizon, or where scouring has removed some of the sediment above a dated pollen horizon.

Maryland, Virginia↗
USGS2024

The petrology of dispersed organic matter in sedimentary rocks: Review and update

Organic petrology developed from coal petrology, and, in the 1960s, it began to be applied to the study of dispersed organic matter (DOM) in sedimentary rocks other than coal. Over the last few decades, the petrology of DOM has been used to characterize organic matter in sedimentary basins with an emphasis on fossil fuel resource exploration. Today, due to the global research shift on topics related to climate, organic petrology has expanded into new application areas, such as geothermal exploration, biological carbon storage (biochar), disposal, and management of radioactive waste. From the publication of the International Handbook of Coal Petrology (mid-20th century) to the present day, a large number of standards, books, and articles have been published as a result of the work of organic petrographers and petrologists around the world and efforts of the International Committee for Coal and Organic Petrology (ICCP) and The Society for Organic Petrology (TSOP) to promote the study of organic petrology. The current fundamentals and standards of organic petrology provide the international scientific community with well-informed guidance and recommendations to promote in-depth research. However, this information is currently widely scattered, leading to discrepancies in methodology and terminology. Therefore, this paper aims to present a comprehensive review of the main analytical standard test methods and techniques currently used in the petrology of DOM under reflected white light and UV and blue-light excitation, and to provide an efficient and well-defined reference guide. Furthermore, considering the important role of the ICCP in the development of organic petrology since the 1950s, a brief review of the ongoing activities of ICCP dealing with DOM is also presented.

International Journal of Coal Geology↗
USGS2019

Detrital K-feldspar Pb isotopic evaluation of extraregional sediment transported through an Eocene tectonic breach of southern California's Cretaceous batholith

Sedimentary provenance studies have come to be overwhelmingly based upon U–Pb geochronologic measurements performed with detrital zircon while alternative and potentially complementary approaches such as conglomerate clast studies and heavy mineral analysis have faded in importance. Measurement of Pb isotopic compositions in detrital K-feldspar is among the under-utilized approaches available to ascertain sedimentary source regions. While it has been long recognized that common Pb isotope compositions recorded by K-feldspar vary widely and reflect the crustal provinces from which the host basement rocks crystallized, use of the approach has suffered due to a lack of appropriate statistical models and ground truth compositional data from source regions. In this paper, we: (1) present high-throughput LA-ICPMS analysis protocols needed to generate statistically meaningful detrital K-feldspar Pb isotope data sets; (2) develop an interpretative approach based upon 208 Pb/ 206 Pb vs. 207 Pb/ 206 Pb that incorporate information from the U- and Th-decay systems into one two-dimensional plot that is amenable to analysis using two-dimensional Kolmogorov–Smirnoff statistical tests; (3) generate new Pb isotopic data from basement rocks from southwestern North America to improve knowledge of the Pb isotopic properties of potential source regions; and (4) generate new Pb isotopic data from Lower Eocene to Lower Miocene sedimentary rocks to evaluate changes in drainage patterns that occurred in response to deformation that affected the southern California margin. Through this case study, we demonstrate how our new analytical and interpretative methods could be profitably applied to future geochemical and provenance studies and tectonically driven re-organization of drainage patterns.

Earth and Planetary Science Letters↗
USGS2022

Sediment source fingerprinting as an aid to large-scale landscape conservation and restoration: A review for the Mississippi River Basin

Reliable quantitative information on sediment sources to rivers is critical to mitigate contamination and target conservation and restoration actions. However, the determination of the relative importance of sediment sources is complicated at the scale of large river basins by immense variability in erosional processes and sediment sources over space and time, heterogeneity in sediment transport and deposition, and a paucity of sediment monitoring data. Sediment source fingerprinting is an increasingly adopted field-based technique that identifies the nature and relative source contribution of sediment transported in waterways. Notably, sediment source fingerprinting provides information that is independent of other field, modeling, or remotely sensed techniques. However, the diversity in sediment fingerprinting sampling, analytical, and interpretive methods has been recognized as a problem in terms of developing standardized procedures for its application at the scale of large river basins. Accordingly, this review focuses on established sediment source fingerprinting studies conducted within the Mississippi River Basin (MRB), summarizes unique information provided by sediment source fingerprinting that is distinct from traditional monitoring techniques, evaluates consistency and reliability of methodological approaches among MRB studies, and provides prospects for the use of the sediment source fingerprinting technique as an aid to large-scale landscape conservation and restoration under current management frameworks. Most established MRB studies got creditable fingerprinting results and considered near-channel sources as the dominant sediment sources in most cases, while the comparability of their results suffers from a lack of standardization in procedural steps. Findings from MRB studies demonstrate that sediment source fingerprinting is a highly valuable and reliable sediment source assessment approach to assist land and water resource management under current management frameworks, but efforts are still needed to make this technique ready to be used in a more predominant way in large-scale landscape conservation and restoration efforts. We summarized research needs and suggested the best fingerprinting practices for management purposes with the aim of ensuring that this technique is as robust and reliable as it moves forward.

Mississippi River Basin↗
USGS2000

On the modified Mercalli intensities and magnitudes of the 1811-1812 New Madrid earthquakes

We reexamine original felt reports from the 1811–1812 New Madrid earthquakes and determine revised isoseismal maps for the three principal mainshocks. In many cases we interpret lower values than those assigned by earlier studies. In some cases the revisions result from an interpretation of original felt reports with an appreciation for site response issues. Additionally, earlier studies had assigned modified Mercalli intensity (MMI) values of V-VII to a substantial number of reports that we conclude do not describe damage commensurate with intensities this high. We investigate several approaches to contouring the MMI values using both analytical and subjective methods. For the first mainshock on 02∶15 LT December 16, 1811, our preferred contouring yields M ω7.2–7.3 using the area-moment regressions of Johnston [1996]. For the 08∶00 LT on January 23, 1812, and 03∶45 LT on February 7, 1812, mainshocks, we obtain M ω7.0 and M ω7.4–7.5, respectively. Our magnitude for the February mainshock is consistent with the established geometry of the Reelfoot fault, which all evidence suggests to have been the causative structure for this event. We note that the inference of lower magnitudes for the New Madrid events implies that site response plays a significant role in controlling seismic hazard at alluvial sites in the central and eastern United States. We also note that our results suggest that thrusting may have been the dominant mechanism of faulting associated with the 1811–1812 sequence.

Arkansas, Illinois, Kentucky, Missouri, Tennessee↗
USGS2010

Estimation of distributional parameters for censored trace level water quality data: 1. Estimation techniques

A recurring difficulty encountered in investigations of many metals and organic contaminants in ambient waters is that a substantial portion of water sample concentrations are below limits of detection established by analytical laboratories. Several methods were evaluated for estimating distributional parameters for such censored data sets using only uncensored observations. Their reliabilities were evaluated by a Monte Carlo experiment in which small samples were generated from a wide range of parent distributions and censored at varying levels. Eight methods were used to estimate the mean, standard deviation, median, and interquartile range. Criteria were developed, based on the distribution of uncensored observations, for determining the best performing parameter estimation method for any particular data set. The most robust method for minimizing error in censored-sample estimates of the four distributional parameters over all simulation conditions was the log-probability regression method. With this method, censored observations are assumed to follow the zero-to-censoring level portion of a lognormal distribution obtained by a least squares regression between logarithms of uncensored concentration observations and their z scores. When method performance was separately evaluated for each distributional parameter over all simulation conditions, the log-probability regression method still had the smallest errors for the mean and standard deviation, but the lognormal maximum likelihood method had the smallest errors for the median and interquartile range. When data sets were classified prior to parameter estimation into groups reflecting their probable parent distributions, the ranking of estimation methods was similar, but the accuracy of error estimates was markedly improved over those without classification.

Water Resources Research↗
USGS2022

Spatial personalities: A meta-analysis of consistent individual differences in spatial behavior

Individual variation in behavior, particularly consistent among-individual differences (i.e., personality), has important ecological and evolutionary implications for population and community dynamics, trait divergence, and patterns of speciation. Nevertheless, individual variation in spatial behaviors, such as home range behavior, movement characteristics, or habitat use has yet to be incorporated into the concepts or methodologies of ecology and evolutionary biology. To evaluate evidence for the existence of consistent among-individual differences in spatial behavior – which we refer to as “spatial personality” – we performed a meta-analysis of 200 repeatability estimates of home range size, movement metrics, and habitat use. We found that the existence of spatial personality is a general phenomenon, with consistently high repeatability (r) across classes of spatial behavior (r = 0.67–0.82), taxa (r = 0.31–0.79), and time between repeated measurements (r = 0.54–0.74). These results suggest: 1) repeatable spatial behavior may either be a cause or consequence of the environment experienced and lead to spatial personalities that may limit the ability of individuals to behaviorally adapt to changing landscapes; 2) interactions between spatial phenotypes and environmental conditions could result in differential reproduction, survival, and dispersal, suggesting that among-individual variation may facilitate population-level adaptation; 3) spatial patterns of species' distributions and spatial population dynamics may be better understood by shifting from a mean field analytical approach towards methods that account for spatial personalities and their associated fitness and ecological dynamics.

Behavioral Ecology↗
USGS2017

Apparent annual survival estimates of tropical songbirds better reflect life history variation when based on intensive field methods

Aim Adult survival is central to theories explaining latitudinal gradients in life history strategies. Life history theory predicts higher adult survival in tropical than north temperate regions given lower fecundity and parental effort. Early studies were consistent with this prediction, but standard-effort netting studies in recent decades suggested that apparent survival rates in temperate and tropical regions strongly overlap. Such results do not fit with life history theory. Targeted marking and resighting of breeding adults yielded higher survival estimates in the tropics, but this approach is thought to overestimate survival because it does not sample social and age classes with lower survival. We compared the effect of field methods on tropical survival estimates and their relationships with life history traits. Location Sabah, Malaysian Borneo. Time period 2008–2016. Major taxon Passeriformes. Methods We used standard-effort netting and resighted individuals of all social and age classes of 18 tropical songbird species over 8 years. We compared apparent survival estimates between these two field methods with differing analytical approaches. Results Estimated detection and apparent survival probabilities from standard-effort netting were similar to those from other tropical studies that used standard-effort netting. Resighting data verified that a high proportion of individuals that were never recaptured in standard-effort netting remained in the study area, and many were observed breeding. Across all analytical approaches, addition of resighting yielded substantially higher survival estimates than did standard-effort netting alone. These apparent survival estimates were higher than for temperate zone species, consistent with latitudinal differences in life histories. Moreover, apparent survival estimates from addition of resighting, but not from standard-effort netting alone, were correlated with parental effort as measured by egg temperature across species. Main conclusions Inclusion of resighting showed that standard-effort netting alone can negatively bias apparent survival estimates and obscure life history relationships across latitudes and among tropical species.

Kinabalu Park↗
USGS2005

Combined use of flowmeter and time-drawdown data to estimate hydraulic conductivities in layered aquifer systems

The vertical distribution of hydraulic conductivity in layered aquifer systems commonly is needed for model simulations of ground-water flow and transport. In previous studies, time-drawdown data or flowmeter data were used individually, but not in combination, to estimate hydraulic conductivity. In this study, flowmeter data and time-drawdown data collected from a long-screened production well and nearby monitoring wells are combined to estimate the vertical distribution of hydraulic conductivity in a complex multilayer coastal aquifer system. Flowmeter measurements recorded as a function of depth delineate nonuniform inflow to the wellbore, and this information is used to better discretize the vertical distribution of hydraulic conductivity using analytical and numerical methods. The time-drawdown data complement the flowmeter data by giving insight into the hydraulic response of aquitards when flow rates within the wellbore are below the detection limit of the flowmeter. The combination of these field data allows for the testing of alternative conceptual models of radial flow to the wellbore.

Ground Water↗
USGS2025

Using machine learning in Minnesota’s StreamStats to predict fluvial sediment

A thorough understanding of fluvial sediment transport is essential for addressing key environmental issues such as aquatic habitat degradation, flooding, excess nutrients, and challenges with river restoration. Fluvial sediment samples are valuable for addressing these concerns, but their collection is often impractical across all rivers and timeframes of interest. In addition, previously used analytical and numerical methods have not allowed for the transfer of knowledge from sites that have data to sites that do not have data. To overcome this limitation, the U.S. Geological Survey developed machine learning models to predict suspended-sediment concentrations and bedload transport in Minnesota rivers that lack physical sediment data and integrated them into the U.S. Geological Survey StreamStats web application.

Minnesota↗
USGS2000

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of ammonium plus organic nitrogen by a Kjeldahl digestion method and an automated photometric finish that includes digest cleanup by gas diffusion

The National Water Quality Laboratory (NWQL) determined ammonium plus organic nitrogen (Kjeldahl nitrogen) by using semiautomated, block digester methods for filtered and whole-water samples from 1986 until October 1, 1991. During that time, phosphorus was determined by a persulfate digestion method. In 1991, projected increases in demand for both tests by the U.S. Geological Survey?s National Water-Quality Assessment Program led the NWQL to develop and validate methods for determining both analytes in a common digest. This report describes a rapid and accurate method to determine Kjeldahl nitrogen. The batch, high-temperature (block digester), Hg (II)-catalyzed digestion step used in the new methods I-2515-91/4515-91 is similar to U.S. Geological Survey methods I-2552-85/4552-85 and U.S. Environmental Protection Agency method 351.2 except that sample and reagent volumes are halved. Prepared digests are desolvated at 220 degrees Celsius (oC) and digested at 370oC in separate block digesters set at these temperatures, rather than in a single, temperatureprogrammed block digester. This approach permits 40 calibrants, reference materials, and samples to be digested and resolvated in about an hour. Ammonium ions originally present in samples, along with those released during the digestion step, are determined photometrically by an automated, salicylatehypochlorite Berthelot reaction procedure at a rate of 90 tests per hour. About 100 microliters of digest are required per determination. The upper concentration level is 10 milligrams per liter (mg/L) with a method detection level of 0.05 mg/L. Repeatability for a sample containing about 4.1 mg/L of Kjeldahl nitrogen in a high suspended-solids matrix is 3.1 percent. Between-day precision for the same sample is 4.8 percent. A gas diffusion cell in the air-segmented continuous flow analyzer eliminates particulates and ions that otherwise would interfere in the photometric finish. A singlechannel analyzer can process the resolvated digests from two pairs of block digesters each hour. Statistical analysis of paired data for about 1,500 samples determined by U.S. Geological Survey methods I-2552-85/4552- 85 and I-2515-91/4515-91 during method validation revealed a median concentration difference between the former and the latter methods of about 0.1 mg-N/L. This result was expected because digestion blank concentrations (nearly equal to 0.1 mg/L) were not subtracted from concentrations reported by methods I-2552-85/4552-85. A 10-year record of National Water Quality Laboratory Kjeldahl nitrogen blind blank concentration data also supports a step-change decrease in Kjeldahl nitrogen concentrations of about 0.1 mg/L after methods I-2552-85/4552-85 were replaced by methods I-2515-91/4515-91 on October 1, 1991. Somewhat larger concentration differences between the two methods were observed for a subset of about 350 samples with nitrate plus nitrite concentrations greater than 1 mg-N/L.

Open-File Report↗
USGS1975

Geochemical prospecting for soluble salts in Kuchakki hamun, Chagai District, Pakistan

The surface soil consisting of clay, silt, sand, and salt crust in Kuchakki hamun (dry lake) contains nitrates, sulfates, salts of boron, magnesium, and widely dispersed traces of potassium. No bromine or iodine salts were detected. Several hundred samples of soil were analyzed by spot-test methods, and the results were given comparative weighted-qualitative values. Isohaline-type geochemical maps, based on weighted-qualitative values, were prepared to show the dispersion patterns of boron, magnesium, potassium, nitrates, and sulfates in Kuchakki hamun. Boron and magnesium salts are concentrated in the southern and southeastern part of the hamun. Nitrates and sulfates are more widely distributed and have higher concentrations in the central area of Kuchakki hamun. More detailed qualitative work and quantitative studies on material collected in Kuchakki hamun are required to appraise the reliability of applied field methods and preliminary analytical data, and to determine the presence, abundance, and grade of economically important salts.

Chagai District↗
USGS2008

Use of Superposition Models to Simulate Possible Depletion of Colorado River Water by Ground-Water Withdrawal

According to the 'Law of the River', wells that draw water from the Colorado River by underground pumping need an entitlement for the diversion of water from the Colorado River. Consumptive use can occur through direct diversions of surface water, as well as through withdrawal of water from the river by underground pumping. To develop methods for evaluating the need for entitlements for Colorado River water, an assessment of possible depletion of water in the Colorado River by pumping wells is needed. Possible methods include simple analytical models and complex numerical ground-water flow models. For this study, an intermediate approach was taken that uses numerical superposition models with complex horizontal geometry, simple vertical geometry, and constant aquifer properties. The six areas modeled include larger extents of the previously defined river aquifer from the Lake Mead area to the Yuma area. For the modeled areas, a low estimate of transmissivity and an average estimate of transmissivity were derived from statistical analyses of transmissivity data. Aquifer storage coefficient, or specific yield, was selected on the basis of results of a previous study in the Yuma area. The USGS program MODFLOW-2000 (Harbaugh and others, 2000) was used with uniform 0.25-mile grid spacing along rows and columns. Calculations of depletion of river water by wells were made for a time of 100 years since the onset of pumping. A computer program was set up to run the models repeatedly, each time with a well in a different location. Maps were constructed for at least two transmissivity values for each of the modeled areas. The modeling results, based on the selected transmissivities, indicate that low values of depletion in 100 years occur mainly in parts of side valleys that are more than a few tens of miles from the Colorado River.

Scientific Investigations Report↗
USGS2016

Evaluation of National Atmospheric Deposition Program measurements for colocated sites CO89 and CO98 at Rocky Mountain National Park, water years 2010–14

Atmospheric wet-deposition monitoring in Rocky Mountain National Park included precipitation depth and aqueous chemical measurements at colocated National Atmospheric Deposition Program/National Trends Network (NADP/NTN) sites CO89 and CO98 (Loch Vale) during water years 2010–14 (study period). The colocated sites were separated by approximately 6.5 meters horizontally and 0.5 meter in elevation, in accordance with NADP siting criteria. Assessment of the 5-year record of colocated data is intended to inform man-agement decisions pertaining to the achievement of nitrogen deposition reduction goals of the Rocky Mountain National Park Nitrogen Deposition Reduction Plan. The data at site CO98 met NADP completeness criteria for the first time in 29 years of operation in 2011 and then again in 2012. During the study period, data at site CO89 met completeness criteria in 2012. Median weekly relative precipitation-depth differences between sites CO89 and CO98 ranged from 0 to 0.25 millimeter during the study period. Median weekly absolute percent differences in sample volume ranged from 5 to 10 percent. Median relative concentration differences for weekly ammonium (NH 4 + ) and nitrate (NO 3 - ) concentrations were near the NADP Central Analytical Laboratory’s method detection limits and thus were considered small. Absolute percent differences for water-year 2010–14 precipitation-weighted mean concentrations of NH 4 + , NO 3 - , and inorganic nitrogen (N inorg ) ranged from 0.0 to 25.7 percent. Absolute percent differences for water-year 2010–14 NH 4 + , NO 3 - , and N inorg deposition ranged from 2.1 to 18.9 percent, 3.3 to 24.5 percent, and 0.3 to 17.4 percent, respectively.

Colorado↗