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An estimate of chemical loads from ground water to the Grand Calumet River and Indiana Harbor Canal, northwestern Indiana

Chemical loads from ground water to the Grand Calumet River and the Indiana Harbor Canal in northwestern Indiana were estimated to aid in determining the total maximum daily load. Data from two previous studies, completed in 1987 and 1993, were used to compute loads. The first study included a ground-water-flow model. Results from this model were used to determine ground-water fluxes to eight distinct reaches of the Grand Calumet River and the Indiana Harbor Canal at assumed horizontal hydraulic conductivities of 50 and 100 feet per day. In addition, water quality data collected during the first study and a second study that further described the quality of water from wells screened in the Calumet aquifer, were used with the ground-water fluxes to compute estimates of chemical loads for selected constituents contributing to the Grand Calumet River and Indiana Harbor Canal. Constituents included trace elements, polychlorinated biphenyls, pesticides, polynuclear aromatic hydrocarbons, and selected general chemistry properties. Total dissolved solids, sulfate, chloride, and dissolved ammonia as nitrogen had the largest estimated loads to the Grand Calumet River and the Indiana Harbor Canal for any river reach. The estimated loads for total dissolved solids ranged from 239 to 12,800 kilograms per day. Dissolved iron had the largest estimated load for the trace elements and exceeded 1 kilogram per day for all river reaches for which data were available. The majority of ground-water concentrations for polychlorinated biphenyls, pesticides, and polynuclear aromatic hydrocarbons were reported as less than the method reporting limit, resulting in small computed loads to the river and canal.

Indiana↗

The Benchmark Farm Program: A method for estimating irrigation water use in southwest Florida

Irrigation water-use data are summarized in this report for 74 farms in the Southwest Florida Water Management District. Most data are for 1978-90, but 18 farms have data extending back to the early 1970's. Data include site number and location, season and year, crop type, irrigation system, monitoring method, and inches of water applied per acre. Crop types include citrus, cucumbers, pasture, peanuts, sod, strawberries, and tropical fish farms are also included. Water-application rates per growing season ranged from 0 inches per acre for several citrus and pasture sites to 239.7 inches per acre for a nursery site. The report also includes rainfall data for 12 stations throughout the study area. (USGS)

Florida↗

Water-level declines in the Amargosa Valley area, Nye County, Nevada, 1962-84

Groundwater flow in the Amargosa Valley area is in Nevada complex and involves a valley fill aquifer and an underlying carbonate rock aquifer. Groundwater development in the area is in the valley fill aquifer, about 10 mi. south-west of Lathrop Wells. Water levels measured in selected wells in the area in 1984 are lower than those measured in 1962, demonstrating that water levels have undergone a net decline since 1962. An implied water level rise and resulting groundwater mound suggested on a map from a U.S. Bureau of Reclamation report appear to be based on the inadvertent misplotting of two wells. Data presented in this report indicate that the implied mound does not exist. (Lantz-PTT)

Water-Resources Investigations Report↗

Comparison of irrigation pumpage and change in water storage of the High Plains Aquifer in Castro and Parmer counties, Texas, 1975-83

An understanding of the relationship between irrigation pumpage and change in ground-water storage was needed to quantify the amount of water returning to the High Plains aquifer as a result of intensive irrigation in Castro and Parmer Counties, Texas. Irrigation pumpage for the 9-year period, 1975-83, was estimated by using the Blaney-Criddle consumptive-use formula adjusted by a factor to account for irrigation demand and field-measured crop applications. Total estimated pumpage for the 9-year period was 11,269,000 acre-feet and 8,914,000 acre-feet. The estimated pumpage was based upon reported crop acreage data and LANDSAT acreage data, respectively. Aquifer storage for the same period was estimated as the product of specific yield, net water-level change, and area. Change in storage was 5,168,000 acre-feet. Many of the areas of the largest change in storage also were the areas of the largest saturated thickness. The only locations that did not experience substantial water-level declines were the northwest and northeast parts of the study area. A comparison was made of water returning to the aquifer by calculating the difference between irrigation pumpage and the change in aquifer storage. Two estimates of this comparison, expressed as a percentage of irrigation pumpage, were obtained on the basis of two different sources of acreage data. This comparison was 54 percent of pumpage based on reported crop acreage data and 42 percent of pumpage based on LANDSAT interpreted acreage data.

Texas↗

US Geological Survey urban-stormwater data base of constituent storm loads; characteristics of rainfall, runoff, and antecedent conditions; and basin characteristics

A data base which consists of constituent storm loads, characteristics of rainfall, runoff, and antecedent conditions, and basin characteristics measured at most of the stations in the U.S. Geological Survey urban-stormwater data-collection network in metropolitan areas throughout the United States has been compiled. Tables of these constituents storm loads and characteristics are presented in this report. The data base also is available on magnetic tape. The data represent 1,144 storms at 97 stations in 21 metropolitan areas. Storm loads for 18 constituents and 15 characteristics of rainfall, runoff, and antecedent conditions are reported. Twenty-eight selected basin characteristics also are reported, including 11 categories of land use. (USGS)

Water-Resources Investigations Report↗

Compilation of water-resources data for Montana, water year 2006

The U.S. Geological Survey, Montana Water Science Center, in cooperation with other Federal, State, and local agencies, and Tribal governments, collects a large amount of data pertaining to the water resources of Montana each water year. This report is a compilation of Montana site-data sheets for the 2006 water year, which consists of records of stage and discharge of streams; water quality of streams and ground water; stage and contents of lakes and reservoirs; water levels in wells; and precipitation data. Site-data sheets for selected stations in Canada and Wyoming also are included in this report. The data for Montana, along with data from various parts of the Nation, are included in 'Water-Resources Data for the United States, Water Year 2006', which is published as U.S. Geological Survey Water-Data Report WDR-US-2006 and is available at http://pubs.water.usgs.gov/wdr2006. Additional water year 2006 data collected at crest-stage gage and miscellaneous-measurement stations were collected but were not published. These data are stored in files of the U.S. Geological Survey Montana Water Science Center in Helena, Montana, and are available on request.

Montana↗

Water resources of the Grand Portage Indian Reservation, northeastern Minnesota

The Grand Portage Indian Reservation Tribal Council needs information about the availability and quality of the ground water in the Reservation to develop, protect, and manage this resource for future use. The U.S. Geological Survey, in cooperation with the Grand Portage Indian Reservation Tribal Council, did a three-year study of the ground water in the Reservation to provide this needed information. This report presents the results of that study. Presently, ground water from bedrock is the principal source of supply for municipal, commercial, and residential water use. The bedrock aquifers are the (1) North Shore Volcanic Group basalt, (2) Keweenawan Volcanic and intrusive rocks, which are gabbro and diabase, and (3) Rove Formation argillite, slate, and graywacke. Sand and gravel aquifers are a small source of ground water. The storage coefficient of the bedrock aquifers was estimated to be 1 x 10 -4 , which is a small value typical of confined, fractured rock aquifers. The median estimate of transmissivity determined from data for 17 wells completed in bedrock was 20 feet squared per day; the range was from 3 to 500 feet squared per day. Reported yield of 19 wells completed in bedrock had a range of 1 to 100 gallons per minute and a median of 7 gallons per minute. The median yield of 11 wells completed in the North Shore Volcanic Group was 16 gallons per minute; the median yield of 8 wells completed in the Keweenawan Volcanic and intrusive rocks and Rove Formation was 4 gallons per minute. Geophysical logs and televiewer images of two wells completed in bedrock indicated the boreholes penetrated many fractures. Hydrofracturing of the two wells increased their yield from about 0.05 and 0.25 gallons per minute to about 1.5 and 1.2 gallons per minute, respectively. Although the estimated yield from the two wells was increased by 30 and by nearly 5 times after hydrofracturing, the well yield after hydrofracturing was still small. Water types determined from analyses of water from nine wells completed in bedrock were sodium-chloride, calcium-chloride, sodium-bicarbonate, and calcium-bicarbonate. Water from three wells had concentrations of dissolved solids (800 to 3,110 milligrams per liter) and dissolved chloride (410 to 1,600 milligrams per liter) that were higher than their respective Secondary Maximum Contaminant Levels of 500 and 250 milligrams per liter established by the U.S. Environmental Protection Agency. Water from two wells had concentrations of dissolved iron (1,600 and 1,300 micrograms per liter) that were higher than the Secondary Maximum Contaminant Level of 300 micrograms per liter. Water from an observation well located about 200 feet downgradient from an abandoned landfill and screened from 79 to 84 feet below land surface in a gravel aquifer had a trace amount of toluene (0.2 micrograms per liter). The presence of toluene suggested possible contamination.

Minnesota↗

Comprehensive water quality of the Boulder Creek Watershed, Colorado, during high-flow and low-flow conditions, 2000

Executive Summary The Boulder Creek Watershed, Colorado, is 1160 square kilometers in area and ranges in elevation from 1480 to 4120 meters above sea level. Streamflow originates primarily as snowmelt near the Continental Divide, and thus discharge varies seasonally and annually (Chapter 1). Most of the water in Boulder Creek is diverted for domestic, agricultural, and industrial use. Some diverted water is returned to the creek as wastewater effluent and by ditch returns, and additional water enters as groundwater and by transbasin diversions. These diversions and returns lead to complex temporal and spatial variations in discharge. The variations in discharge, along with natural factors such as geology and climate, and anthropogenic factors such as wastewater treatment, agriculture, mining, and urbanization, can affect water chemistry. As with many watersheds in the American West, dependable water quality and sufficient water supply are issues facing local water managers and users. Detailed water-quality and sediment sampling allows the identification of sources and sinks of chemical constituents and an understanding of the processes at work in a river system. This study, the most comprehensive water-quality analysis performed for Boulder Creek to date, was a cooperative effort of the U.S. Geological Survey (USGS) and the city of Boulder. Geographic information systems and modeling programs were used to delineate watershed boundaries, land cover, and geology (Chapter 2). During high-flow (June 2000) and low-flow (October 2000) conditions, researchers evaluated 226 water-quality variables, including basic water-quality indicators (Chapter 3), major ions and trace elements (Chapter 4), wastewater-derived organic compounds (Chapter 5), and pesticides (Chapter 6). Discharge (Chapter 1) and bed-sediment particle size and mineralogy (Chapter 7) were also evaluated. This cooperative study was facilitated by the Boulder Area Sustainability Information Network (BASIN), which provides public access to environmental information about the Boulder Creek Watershed on a website, www.basin.org. In addition to the USGS and city of Boulder data, researchers at the Institute of Arctic and Alpine Research at the University of Colorado provided water chemistry data for the headwaters of North Boulder Creek, upstream of the reach of the USGS/city of Boulder sampling sites (Chapter 8). Snowmelt produces high flows in Boulder Creek in late spring to early summer (Chapter 1). Because precipitation falling in the headwaters is very dilute (specific conductance about 5 microsiemens per centimeter), most chemical constituents are present in lower concentrations during high flows (Chapters 3, 4, 5, 6, and 8). However, concentrations of some constituents, such as total suspended solids (Chapter 3) and organic carbon (Chapter 5), increase during the spring snowmelt flush. The upper basin, which consists of alpine, subalpine, montane, and foothills regions west of the mouth of Boulder Canyon, is underlain by Precambrian igneous and metamorphic rocks (Chapter 1). Major dissolved inorganic constituents in headwater sites were found to be enriched by factors of 10 to 20 relative to precipitation; this is consistent with minor weathering of the local crystalline bedrock (Chapter 4). Some anthropogenic input is observed in the headwaters; precipitation introduces nitrogen derived from fossil fuel combustion and agricultural activities (Chapter 8). The lower basin, which consists of the plains region east of the mouth of Boulder Canyon, is underlain by Mesozoic sedimentary rock and Quaternary alluvium, and has substantially more anthropogenic sources. Concentrations of most dissolved inorganic constituents increased in the lower basin. Differentiation between natural and anthropogenic sources of some dissolved constituents is difficult because both sources contribute to the water composition in this region. The increase of most major constituents (bicarbonate, calcium, chloride, magnesium, sodium, and sulfate) is consistent with weathering of the underlying sedimentary bedrock (Chapter 4). It is likely that anthropogenic loading of constituents in this reach occurs during storm events. Fecal coliform concentrations were variable and in some cases exceeded state standards, primarily during low-flow conditions (Chapter 3). Effluent from Boulder’s 75th Street Wastewater Treatment Plant (WWTP) has a substantial impact on the water chemistry of lower Boulder Creek. The WWTP increases the concentrations of nutrients such as nitrogen and phosphorus (Chapter 3), major ions and trace metals (Chapter 4), and organic carbon (Chapter 5) in Boulder Creek. The effluent contained a spike in gadolinium, a rare earth element that is ingested for magnetic resonance imaging as a contrasting agent and then excreted to the urban wastewater system. The effluent also contained trace organic compounds such as surfactants, pharmaceuticals, hormones (Chapter 5), and pesticides (Chapter 6), which also were detected at downstream Boulder Creek sites. Water chemistry of Boulder Creek downstream of the WWTP is largely controlled by the degree of dilution of the wastewater effluent, which varies depending on the baseflow of Boulder Creek, the volume of wastewater effluent, and depletion by agricultural diversions. Coal Creek, a tributary of Boulder Creek, contains wastewater effluent from four additional WWTPs, and increases the load of many constituents in Boulder Creek. In addition to the impact from wastewater effluent, lower Boulder Creek is affected by agricultural land use. Eleven of 84 analyzed pesticides were detected in Boulder Creek or its inflows, primarily in the eastern section of the watershed (Chapter 6). This collaborative study provides an in-depth evaluation of the hydrology, water chemistry, and sediment mineralogy of North Boulder Creek, Middle Boulder Creek, Boulder Creek, and major inflows. The detailed sampling and analysis in this report provide a baseline for future reference, as well as information on the effect of land use and geology on water chemistry.

Colorado↗

Water-use analysis program for the Neshaminy Creek basin, Bucks and Montgomery counties, Pennsylvania

A water-use analysis computer program was developed for the Neshaminy Creek Basin to assist in managing and allocating water resources in the basin. The program was developed for IBM-compatible personal computers. Basin analysis and the methodologies developed for the Neshaminy Creek Basin can be transferred to other watersheds. The development and structure of the water-use analysis program is documented in this report. The report also serves as a user's guide. The program uses common relational database-management software that allows for water use-data input, editing, updating and output and can be used to generate a watershed water-use analysis report. The watershed-analysis report lists summations of public-supply well withdrawals; a combination of industrial, commercial, institutional, and ground-water irrigation well withdrawals; spray irrigation systems; a combination of public, industrial, and private surface-water withdrawals; wastewater-tratement-facility dishcarges; estimates of aggregate domestic ground-water withdrawals on an areal basin or subbasin basis; imports and exports of wastewater across basin or subbasin divides; imports and exports of public water supplies across basin or subbasin divides; estimates of evaporative loss and consumptive loss from produce incorporation; industrial septic-system discharges to ground water; and ground-water well-permit allocations.

Pennsylvania↗

General field and office procedures for indirect discharge measurements

The discharge of streams is usually measured by the current-meter method. During flood periods, however, it is frequently impossible or impractical to measure the discharges by this method when they occur. Consequently, many peak discharges must be determined after the passage of the flood by indirect methods, such as slope-area, contracted-opening, flow-over-dam, and flow-through-culvert, rather than by direct current-meter measurement. Indirect methods of determining peak discharge are based on hydraulic equations which relate the discharge to the water-surface profile and the geometry of the channel. A field survey is made after the flood to determine the location and elevation of high-water marks and the characteristics of the channel. Detailed descriptions of the general procedures used in collecting the field data and in computing the discharge are given in this report. Each of the methods requires special procedures described in subsequent chapters.

Techniques of Water-Resources Investigations↗

Ground-water discharge determined from estimates of evapotranspiration, Death Valley regional flow system, Nevada and California

The Death Valley regional flow system (DVRFS) is one of the larger ground-water flow systems in the southwestern United States and includes much of southern Nevada and the Death Valley region of eastern California. Centrally located within the ground-water flow system is the Nevada Test Site (NTS). The NTS, a large tract covering about 1,375 square miles, historically has been used for testing nuclear devices and currently is being studied as a potential repository for the long-term storage of high-level nuclear waste generated in the United States. The U.S. Department of Energy, as mandated by Federal and State regulators, is evaluating the risk associated with contaminants that have been or may be introduced into the subsurface as a consequence of any past or future activities at the NTS. Because subsurface contaminants can be transported away from the NTS by ground water, components of the ground-water budget are of great interest. One such component is regional ground-water discharge. Most of the ground water leaving the DVRFS is limited to local areas where geologic and hydrologic conditions force ground water upward toward the surface to discharge at springs and seeps. Available estimates of ground-water discharge are based primarily on early work done as part of regional reconnaissance studies. These early efforts covered large, geologically complex areas and often applied substantially different techniques to estimate ground-water discharge. This report describes the results of a study that provides more consistent, accurate, and scientifically defensible measures of regional ground-water losses from each of the major discharge areas of the DVRFS. Estimates of ground-water discharge presented in this report are based on a rigorous quantification of local evapotranspiration (ET). The study identifies areas of ongoing ground-water ET, delineates different ET areas based on similarities in vegetation and soil-moisture conditions, and determines an ET rate for each delineated area. Each area, referred to as an ET unit, generally consists of one or more assemblages of local phreatophytes or a unique moist soil environment. Ten ET units are identified throughout the DVRFS based on differences in spectral-reflectance characteristics. Spectral differences are determined from satellite imagery acquired June 21, 1989, and June 13, 1992. The units identified include areas of open playa, moist bare soils, sparse to dense vegetation, and open water. ET rates estimated for each ET unit range from a few tenths of a foot per year for open playa to nearly 9 feet per year for open water. Mean annual ET estimates are computed for each discharge area by summing estimates of annual ET from each ET unit within a discharge area. The estimate of annual ET from each ET unit is computed as the product of an ET unit's acreage and estimated ET rate. Estimates of mean annual ET range from 450 acre-feet in the Franklin Well area to 30,000 acre-feet in Sarcobatus Flat. Ground-water discharge is estimated as annual ET minus that part of ET attributed to local precipitation. Mean annual ground-water discharge estimates range from 350 acre-feet in the Franklin Well area to 18,000 acre-feet in Ash Meadows. Generally, these estimates are greater for the northern discharge areas (Sarcobatus Flat and Oasis Valley) and less for the southern discharge areas (Franklin Lake, Shoshone area, and Tecopa/ California Valley area) than those previously reported.

California;Nevada↗

Estimating the magnitude of peak flows for streams in Kentucky for selected recurrence intervals

This report gives estimates of, and presents techniques for estimating, the magnitude of peak flows for streams in Kentucky for recurrence intervals of 2, 5, 10, 25, 50, 100, 200, and 500 years. A flowchart in this report guides the user to the appropriate estimates and (or) estimating techniques for a site on a specific stream. Estimates of peak flows are given for 222 U.S. Geological Survey streamflow-gaging stations in Kentucky. In the development of the peak-flow estimates at gaging stations, a new generalized skew coefficient was calculated for the State. This single statewide value of 0.011 (with a standard error of prediction of 0.520) is more appropriate for Kentucky than the national skew isoline map in Bulletin 17B of the Interagency Advisory Committee on Water Data. Regression equations are presented for estimating the peak flows on ungaged, unregulated streams in rural drainage basins. The equations were developed by use of generalized-least-squares regression procedures at 187 U.S. Geological Survey gaging stations in Kentucky and 51 stations in surrounding States. Kentucky was divided into seven flood regions. Total drainage area is used in the final regression equations as the sole explanatory variable, except in Regions 1 and 4 where main-channel slope also was used. The smallest average standard errors of prediction were in Region 3 (from -13.1 to +15.0 percent) and the largest average standard errors of prediction were in Region 5 (from -37.6 to +60.3 percent). One section of this report describes techniques for estimating peak flows for ungaged sites on gaged, unregulated streams in rural drainage basins. Another section references two previous U.S. Geological Survey reports for peak-flow estimates on ungaged, unregulated, urban streams. Estimating peak flows at ungaged sites on regulated streams is beyond the scope of this report, because peak flows on regulated streams are dependent upon variable human activities.

Kentucky↗

River mileages and drainage areas for Illinois streams—Volume 1, Illinois except Illinois River basin

River mileages are presented for points of interest on Illinois streams draining 10 square miles or more. Points of interest include bridges, dams, gaging stations, county lines, hydrologic unit boundaries, and major tributaries. Drainage areas are presented for selected sites, including total drainage area for any stream draining at least 100 square miles. The report is contained in two volumes. This volume (Volume I) includes Illinois except Illinois River basin.

Illinois↗

Magnitude and frequency of floods in Alabama

Methods of estimating flood magnitudes for recurrence intervals of 2, 5, 10, 25, 50,100, 200, and 500 years are described for rural streams in Alabama that are not affected by regulation or urbanization. Flood-frequency characteristics are presented for 198 gaging stations in Alabama having 10 or more years of record through September 1991, that are used in the regional analysis. Regression relations were developed using generalized least-squares regression techniques to estimate flood magnitude and frequency on ungaged streams as a function of the drainage area of a basin. Sites on gaged streams should be weighted with gaging station data that are presented in the report Graphical relations of peak discharges to drainage areas are also presented for siter along the Alabama, Black Warrior, Cahaba, Choctawhatchee, Conecuh, and Tombigbee Rivers. Equations for estimating flood magnitudes on ungaged urban streams (taken from a previous report) that use drainage area and percentage of impervious cover as independent variables also are given.

Alabama↗

Water resources investigations in Tennessee: Programs and activities of the U.S. Geological Survey, 1987-1988

This report summarizes the principal programs and activities of the Water Resources Division of the U.S. Geological Survey in Tennessee during the last 12 months. It has been an exciting period of many varied activities, projects, and investigations. The variety of these activities is a reflection of the complexity of the water issues in Tennessee and points out the need for a strong ongoing water-resources research program. The USGS is in a position to meet this challenge with an outstanding staff, necessary resources, and pertinent programs in partnership with other county, state, and federal agencies that participate in the District cooperative programs. During the last year, we have witnessed a significant shift in the orientation of the projects and investigations we conduct. Ground water has emerged as one of the most important environmental issues in the Nation and the State. In Tennessee, ground water provides about 51 percent of the drinking-water supplies, and its use is increasing at a faster rate than surface-water supplies. Several communities, including Memphis and Jackson, depend entirely on ground water as their source of drinking water. There are significant concerns among the people and government officials about the quality, quantity, and occurrence of ground water in Tennessee. The USGS is meeting these concerns through assigning higher priorities and additional funds to investigations involving ground-water issues. In the years to come, this trend will continue. The mission of the USGS in Tennessee is to provide timely, accurate, and unbiased water-resources information to citizens and government officials, We intend to continue meeting the goals of this mission by maintaining excellence in our staff and programs. We feel proud of the accomplishments of the last year. I wish to share these successes with the cooperating agencies and organizations that have made these programs possible.

Tennessee↗

Water-resources activities of the U.S. Geological Survey in Utah, October 1, 1996, to September 30, 1997

This report contains summaries of the progress of water-resources activities of the U.S. Geological Survey (USGS), Water Resources Division, Utah District, from October 1, 1996, to September 30,1997. The waterresources program in Utah during this period consisted of 25 projects, and a discussion of each project is presented. The following sections outline the origin of the USGS, the mission of the Water Resources Division, the organizational structure of the Utah District, office addresses of the Utah District, the distribution of program funding as source of funds and type of activity funded in Federal Fiscal Year 1997 (FY97) (October 1,1996, to September 30, 1997), and the agencies with which the District cooperates. The last part of the introduction is a list of reports produced by the District from October 1996 to September 1997.

Utah↗

Geohydrology of the French Creek Basin and simulated effects of drought and ground-water withdrawals, Chester County, Pennsylvania

This report describes the results of a study by the U.S. Geological Survey, in cooperation with the Delaware River Basin Commission, to develop a regional ground-water-flow model of the French Creek Basin in Chester County, Pa. The model was used to assist water-resource managers by illustrating the interconnection between ground-water and surface-water systems. The 70.7-square mile French Creek Basin is in the Piedmont Physiographic Province and is underlain by crystalline and sedimentary fractured-rock aquifers. Annual water budgets were calculated for 1969-2001 for the French Creek Basin upstream of streamflow-measurement station French Creek near Phoenixville (01472157). Average annual precipitation was 46.28 in. (inches), average annual streamflow was 20.29 in., average annual base flow determined by hydrograph separation was 12.42 in., and estimated average annual ET (evapotranspiration) was 26.10 in. Estimated average annual recharge was 14.32 in. and is equal to 31 percent of the average annual precipitation. Base flow made up an average of 61 percent of streamflow. Ground-water flow in the French Creek Basin was simulated using the finite-difference MODFLOW-96 computer program. The model structure is based on a simplified two-dimensional conceptualization of the ground-water-flow system. The modeled area was extended outside the French Creek Basin to natural hydrologic boundaries; the modeled area includes 40 square miles of adjacent areas outside the basin. The hydraulic conductivity for each geologic unit was calculated from reported specific-capacity data determined from aquifer tests and was adjusted during model calibration. The model was calibrated for above-average conditions by simulating base-flow and water-level measurements made on May 1, 2001, using a recharge rate of 20 in/yr (inches per year). The model was calibrated for below-average conditions by simulating base-flow and water-level measurements made on September 11 and 17, 2001, using a recharge rate of 6.2 in/yr. Average conditions were simulated by adjusting the recharge rate until simulated streamflow at streamflow-measurement station 01472157 matched the long-term (1968-2001) average base flow of 54.1 cubic feet per second. The recharge rate used for average conditions was 15.7 in/yr. The effect of drought in the French Creek Basin was simulated using a drought year recharge rate of 8 in/yr for 3 months. After 3 months of drought, the simulated streamflow of French Creek at streamflow-measurement station 01472157 decreased 34 percent. The simulations show that after 6 months of average recharge (15.7 in/yr) following drought, streamflow and water levels recovered almost to pre-drought conditions. The effect of increased ground-water withdrawals on stream base flow in the South Branch French Creek Subbasin was simulated under average and drought conditions with pumping rates equal to 50, 75, and 100 percent of the Delaware River Basin Commission Ground Water Protected Area (GWPA) withdrawal limit (1,393 million gallons per year) with all pumped water removed from the basin. For average recharge conditions, the simulated streamflow of South Branch French Creek at the mouth decreased 18, 28, and 37 percent at a withdrawal rate equal to 50, 75, and 100 percent of the GWPA limit, respectively. After 3 months of drought recharge conditions, the simulated streamflow of South Branch French Creek at the mouth decreased 27, 40, and 52 percent at a withdrawal rate equal to 50, 75, and 100 percent of the GWPA limit, respectively. The effect of well location on base flow, water levels, and the sources of water to the well was simulated by locating a hypothetical well pumping 200 gallons per minute in different places in the Beaver Run Subbasin with all pumped water removed from the basin. The smallest reduction in the base flow of Beaver Run was from a well on the drainage divide between the French Creek Basin and the Marsh Creek Basin to the south; the simulated base flow of Beaver Run at the mouth was reduced 1 percent. The greatest reduction in the base flow of Beaver Creek was from a well close to Beaver Run; the simulated base flow of Beaver Run at the mouth was reduced 8 percent. The simulations showed that (1) if the contributing area of a well is in a basin, pumping will affect stream base flow and water levels in that basin whether the well is inside or outside that basin; (2) wells in different areas of a basin away from a divide produce a similar reduction in base flow; (3) a well within a basin will derive more water from diverted base flow and less water from storage than a well on or near a basin divide; and (4) the reduction in base flow at the mouth of the stream is the same for a well in the headwaters and a well downstream near the confluence. Model simulations illustrate some of the typical analyses and results that can be produced. The model was calibrated using annual values for recharge and ground-water ET and then was run using the annual values in a seasonally independent transient mode to show changes with time. The timing and relative magnitude of some of the changes simulated with the model when viewed in terms of a normal climatic year may be subject to considerable uncertainty because of the variability in seasonal recharge and ground-water ET rates. Transient model simulations for short-term periods are indicative of possible hydrologic system response and are considered an approximation.

Pennsyvlania↗

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of organochlorine pesticides and polychlorinated biphenyls in bottom and suspended sediment by gas chromatography with electron-capture detection

A method applicable for the determination of 19 organochlorine (OC) pesticides, including total toxaphene as a complex mixture, and 3 polychlorinated biphenyl (PCB) mixtures as Aroclor equivalents--Aroclor 1016/1242, 1254, and 1260--in soil, aquatic bottom sediment, and suspended sediment is described. Method performance data are presented. The solvent system is designed to extract simultaneously selected OC pesticides and PCBs from the same sample matrix. The compounds are extracted by conventional Soxhlet extraction with dichloromethane, followed by partial isolation using gel permeation chromatography (GPC) to remove inorganic sulfur and large naturally present molecules from the sediment extract. The aliquot of extract collected from the GPC for OCs (OC pesticides and PCBs) is split into two sample fractions by alumina/silica combined-column chromatography, followed by Florisil adsorption chromatography to remove interfering compounds in the second fraction. The OC fractions are analyzed by dual capillary-column gas chromatography with electron-capture detection (GC/ECD). This report is limited to the determination of selected OC pesticides and PCBs by GC/ECD using this method. Interim reporting levels (IRLs) have been set at 0.400 to 3.12 micrograms per kilogram for 18 individual OC pesticides, 200 micrograms per kilogram for toxaphene, and 4.04 to 4.68 micrograms per kilogram for the PCBs, based on a sample size of 25-gram equivalent dry weight. These reporting levels may change following additional determinations of method detection limits.

Water-Resources Investigations Report↗