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At least 595 records · Page 33Linked to original sources

Modes of occurrence of mercury and other trace elements in coals from the warrior field, Black Warrior Basin, Northwestern Alabama

The mineralogic residence and abundance of trace metals is an important environmental issue. Data from the USGS coal quality database show that potentially toxic elements, including Hg, As, Mo, Se, Cu, and Tl are enriched in a subset of coal samples in the Black Warrior Basin of Alabama, USA. Although the coal as-mined typically is low in these elements, localized enrichments occur in high-pyrite coals and near faults. Microscopic analyses demonstrate that the residence of these elements is dominantly in a late-stage pyrite associated with structurally disrupted coal. Further, our data suggest addition of Hg to the coal matrix as well. The source of these trace elements was hydrothermal fluids driven into the Black Warrior Basin by Alleghanian age tectonism. ?? 2004 Published by Elsevier B.V.

International Journal of Coal Geology↗

Organic petrology of the Aptian-age section in the downdip Mississippi Interior Salt Basin, Mississippi, USA: Observations and preliminary implications for thermal maturation history

This study identifies a thermal maturity anomaly within the downdip Mississippi Interior Salt Basin (MISB) of southern Mississippi, USA, through examination of bitumen reflectance data from Aptian-age strata (Sligo Formation, Pine Island Shale, James Limestone, and Rodessa Formation). U.S. Geological Survey (USGS) reconnaissance investigations conducted in 2011–2012 examined Aptian-age thermal maturity trends across the onshore northern Gulf of Mexico region and indicated that the section in the downdip MISB is approaching the wet gas/condensate window (R o ~1.2%). A focused study in 2012–2013 used 6 whole core, one sidewall core, and 49 high-graded cutting samples (depth range of 13,000–16,500 ft [3962.4–5029.2 m] below surface) collected from 15 downdip MISB wells for mineralogy, fluid inclusion, organic geochemistry, and organic petrographic analysis. Based on native solid bitumen reflectance (R o generally > 0.8%; interpreted to be post-oil indigenous bitumens matured in situ), R o values increase regionally across the MISB from the southeast to the northwest. Thermal maturity in the eastern half of the basin (R o range 1.0 to 1.25%) appears to be related to present-day burial depth and shows a gradual increase with respect to depth. To the west, thermal maturity continues to increase even as the Aptian section shallows structurally on the Adams County High (R o range 1.4 to > 1.8%). After evaluating the possible thermal agents responsible for increasing maturity at shallower depths (i.e., igneous activity, proximity to salt, variations in regional heat flux, and uplift), we tentatively propose that either greater paleoheat flow or deeper burial coupled with uplift in the western part of the MISB could be responsible for the thermal maturity anomaly. Further research and additional data are needed to determine the cause(s) of the thermal anomaly.

International Journal of Coal Geology↗

The Niobrara Formation as a challenge to water quality in the Arkansas River, Colorado, USA

Study region Arkansas River, east of the Rocky Mountains. Study focus Cretaceous sedimentary rocks in the western United States generally pose challenges to water quality, often through mobilization of salts and trace metals by irrigation. However, in the Arkansas River Basin of Colorado, patchy exposure of multiple Cretaceous formations has made it difficult to identify which formations are most problematic. This paper examines water quality in surface-water inflows along a 26-km reach of the Arkansas River relative to the presence or absence of the Cretaceous Niobrara Formation within the watershed. New hydrological insights for the region Principal component analysis (PCA) shows Niobrara-influenced inflows have distinctive geochemistry, particularly with respect to Na, Mg, SO4 2− , and Se. Uranium concentrations are also greater in Niobrara-influenced inflows. During the irrigation season, median dissolved solids, Se, and U concentrations in Niobrara-influenced inflows were 83%, 646%, and 55%, respectively, greater than medians where Niobrara Formation surface exposures were absent. During the non-irrigation season, which better reflects geologic influence, the differences were more striking. Median dissolved solids, Se, and U concentrations in Niobrara-influenced inflows were 288%, 863%, and 155%, respectively, greater than median concentrations where the Niobrara Formation was absent. Identification of the Niobrara Formation as a disproportionate source for dissolved solids, Se, and U will allow for more targeted studies and management, particularly where exposures underlie irrigated agriculture.

Colorado↗

Risk at the margins: A natural hazards perspective on the Syrian refugee crisis in Lebanon

Quantitative landslide risk analysis is a key step in creating appropriate land use policies. The forced migration of those displaced by recent armed conflict in Syria has highlighted the need for studies to guide humanitarian aid and resettlement policies. Over 1.5 million displaced Syrians now reside in Lebanon, self-settling throughout the country through urban integration and informal encampment due to Lebanon's prohibition of formal refugee camps. The Syrian-Lebanon refugee crisis coincides with the recent reexamination of the established aid practice of camp-based resettlement, focused on issues of aid efficacy, security, and human dignity but lacking an environmental hazards perspective. In light of these issues, we quantitatively assess the landslide risk profile of Lebanon, finding a 75% increase in landslide risk since the start of the Syrian crisis. The risk is highest in the debris flow-prone mountains of central and northeastern Lebanon. Additionally, Syrian refugees settled in informal camps experience 9–11 times greater risk then urban populations due to sub-standard shelter, suggesting that urban rather than camp-based resettlement policies are preferable from an environmental-hazards perspective.

International Journal of Disaster Risk Reduction↗

Social vulnerability and geographic access barriers to earthquake early warning education in museums and other free choice learning environments

Given the earthquake risk on the West Coast of the United States, individuals and communities require a basic understanding of ShakeAlert earthquake early warning technology, which may provide crucial seconds of warning. Free choice learning environments (FCLEs), such as museums, public libraries, and national parks, are uniquely positioned to expand the reach of earthquake early warning through educational initiatives and resources. Earthquake education in these spaces creates awareness of earthquake hazards and risk in areas where people live or visit and may also increase engagement in preparedness behavior as they are trusted sources of information in their communities. However, population demographics within the ShakeAlert states has yet to be examined; audience segmentation theories require a better understanding of the demographics of the people the system seeks to serve. Here we build upon previous typology research that examined over 150 earthquake displays around the United States and found that most did not include information about earthquake preparedness or associated protective actions. This new research shifts to a hierarchical clustering analysis that identifies seven main population groups within the ShakeAlert states. We also find that the cost of admission and the geographic distance away from FCLEs, including the potential cost and time of transportation, may lead to an urban-rural divide in visitor access. Using audience segmentation theories as related to earthquakes, we can understand critical barriers to FCLEs and opportunities for ShakeAlert education. As earthquake early warning systems expand internationally, thoughtful and equitable education initiatives are beneficial to reach critical audiences.

International Journal of Disaster Risk Reduction↗

Automated mapping of persistent ice and snow cover across the western U.S. with Landsat

We implemented an automated approach for mapping persistent ice and snow cover (PISC) across the conterminous western U.S. using all available Landsat TM and ETM+ scenes acquired during the late summer/early fall period between 2010 and 2014. Two separate validation approaches indicate this dataset provides a more accurate representation of glacial ice and perennial snow cover for the region than either the U.S. glacier database derived from US Geological Survey (USGS) Digital Raster Graphics (DRG) maps (based on aerial photography primarily from the 1960s–1980s) or the National Land Cover Database 2011 perennial ice and snow cover class. Our 2010–2014 Landsat-derived dataset indicates 28% less glacier and perennial snow cover than the USGS DRG dataset. There are larger differences between the datasets in some regions, such as the Rocky Mountains of Northwest Wyoming and Southwest Montana, where the Landsat dataset indicates 54% less PISC area. Analysis of Landsat scenes from 1987–1988 and 2008–2010 for three regions using a more conventional, semi-automated approach indicates substantial decreases in glaciers and perennial snow cover that correlate with differences between PISC mapped by the USGS DRG dataset and the automated Landsat-derived dataset. This suggests that most of the differences in PISC between the USGS DRG and the Landsat-derived dataset can be attributed to decreases in PISC, as opposed to differences between mapping techniques. While the dataset produced by the automated Landsat mapping approach is not designed to serve as a conventional glacier inventory that provides glacier outlines and attribute information, it allows for an updated estimate of PISC for the conterminous U.S. as well as for smaller regions. Additionally, the new dataset highlights areas where decreases in PISC have been most significant over the past 25–50 years.

ISPRS Journal of Photogrammetry and Remote Sensing↗

Next generation of global land cover characterization, mapping, and monitoring

Land cover change is increasingly affecting the biophysics, biogeochemistry, and biogeography of the Earth's surface and the atmosphere, with far-reaching consequences to human well-being. However, our scientific understanding of the distribution and dynamics of land cover and land cover change (LCLCC) is limited. Previous global land cover assessments performed using coarse spatial resolution (300 m–1 km) satellite data did not provide enough thematic detail or change information for global change studies and for resource management. High resolution (∼30 m) land cover characterization and monitoring is needed that permits detection of land change at the scale of most human activity and offers the increased flexibility of environmental model parameterization needed for global change studies. However, there are a number of challenges to overcome before producing such data sets including unavailability of consistent global coverage of satellite data, sheer volume of data, unavailability of timely and accurate training and validation data, difficulties in preparing image mosaics, and high performance computing requirements. Integration of remote sensing and information technology is needed for process automation and high-performance computing needs. Recent developments in these areas have created an opportunity for operational high resolution land cover mapping, and monitoring of the world. Here, we report and discuss these advancements and opportunities in producing the next generations of global land cover characterization, mapping, and monitoring at 30-m spatial resolution primarily in the context of United States, Group on Earth Observations Global 30 m land cover initiative (UGLC).

International Journal of Applied Earth Observation↗

Quantitative estimation of minimum offset for multichannel surface-wave survey with actively exciting source

Multichannel analysis of surface waves is a developing method widely used in shallow subsurface investigations. The field procedures and related parameters are very important for successful applications. Among these parameters, the source-receiver offset range is seldom discussed in theory and normally determined by empirical or semi-quantitative methods in current practice. This paper discusses the problem from a theoretical perspective. A formula for quantitatively evaluating a layered homogenous elastic model was developed. The analytical results based on simple models and experimental data demonstrate that the formula is correct for surface wave surveys for near-surface applications. ?? 2005 Elsevier B.V. All rights reserved.

Journal of Applied Geophysics↗

Biogeochemical and ecological impacts of livestock grazing in semi-arid southeastern Utah, USA

Relatively few studies have examined the ecological and biogeochemical effects of livestock grazing in southeastern Utah. In this study, we evaluated how grazing has affected soil organic carbon and nitrogen to a depth of 50 cm in grasslands located in relict and actively-grazed sites in the Canyonlands physiographic section of the Colorado Plateau. We also evaluated differences in plant ground cover and the spatial distribution of soil resources. Results show that areas used by domestic livestock have 20% less plant cover and 100% less soil organic carbon and nitrogen compared to relict sites browsed by native ungulates. In actively grazed sites, domestic livestock grazing also appears to lead to clustered, rather than random, spatial distribution of soil resources. Magnetic susceptibility, a proxy for soil stability in this region, suggests that grazing increases soil erosion leading to an increase in the area of nutrient-depleted bare ground. Overall, these results, combined with previous studies in the region, suggest that livestock grazing affects both plant cover and soil fertility with potential long-term implications for the sustainability of grazing operations in this semi-arid landscape. ?? 2007 Elsevier Ltd. All rights reserved.

Journal of Arid Environments↗

Using packrat middens to assess grazing effects on vegetation change

Research on grazing effects usually compares the same sites through time or grazed and ungrazed sites over the same time period. Both approaches are complicated in arid environments where grazing can have a long undocumented history and landscapes can be spatially heterogenous. This work employs both approaches simultaneously by comparing grazed and ungrazed samples through both time and space using fossil plant macrofossils and pollen from packrat middens. A series of 27 middens, spanning from 995 yr BP to the present, were collected from Glen Canyon in southeastern Utah, USA. These middens detail vegetation change just prior to, and following, the historical introduction of domesticated grazers and also compares assemblages from nearby ungrazable mesas. Pre-grazing middens, and modern middens from ungrazed areas, record more native grasses, native herbs, and native shrubs such as Rhus trilobata, Amelanchier utahensis, and Shepherdia rotundifolia than modern middens from grazed areas. Ordinations demonstrate that site-to-site variability is more important than any temporal changes, making selection of comparable grazed versus ungrazed study treatments difficult. But within similar sites, the changes through time show that grazing lowered the number of taxa recorded, and lessened the pre-existing site differences, homogenizing the resultant plant associations in this desert grassland.

Journal of Arid Environments↗

Microbial characterization of nitrification in a shallow, nitrogen-contaminated aquifer, Cape Cod, Massachusetts and detection of a novel cluster associated with nitrifying Betaproteobacteria

Groundwater nitrification is a poorly characterized process affecting the speciation and transport of nitrogen. Cores from two sites in a plume of contamination were examined using culture-based and molecular techniques targeting nitrification processes. The first site, located beneath a sewage effluent infiltration bed, received treated effluent containing O 2 (> 300 µM) and NH 4 + (51–800 µM). The second site was 2.5 km down-gradient near the leading edge of the ammonium zone within the contaminant plume and featured vertical gradients of O 2 , NH 4 + , and NO 3 − (0–300, 0–500, and 100–200 µM with depth, respectively). Ammonia- and nitrite-oxidizers enumerated by the culture-based MPN method were low in abundance at both sites (1.8 to 350 g − 1 and 33 to 35,000 g − 1 , respectively). Potential nitrifying activity measured in core material in the laboratory was also very low, requiring several weeks for products to accumulate. Molecular analysis of aquifer DNA (nested PCR followed by cloning and 16S rDNA sequencing) detected primarily sequences associated with the Nitrosospira genus throughout the cores at the down-gradient site and a smaller proportion from the Nitrosomonas genus in the deeper anoxic, NH 4 + zone at the down-gradient site. Only a single Nitrosospira sequence was detected beneath the infiltration bed. Furthermore, the majority of Nitrosospira -associated sequences represent an unrecognized cluster. We conclude that an uncharacterized group associated with Nitrosospira dominate at the geochemically stable, down-gradient site, but found little evidence for Betaproteobacteria nitrifiers beneath the infiltration beds where geochemical conditions were more variable.

Journal of Contaminant Hydrology↗

The Lake Ontario zooplankton community before (1987-1991) and after (2001-2005) invasion-induced ecosystem change

We assessed changes in Lake Ontario zooplankton biomass, production, and community composition before (1987–1991) and after (2001–2005) invasion-induced ecosystem changes. The ecosystem changes were associated with establishment of invasive dreissenid mussels and invasive predatory cladocerans ( Bythotrephes and Cercopagis ). Whole-lake total epilimnetic plus metalimnetic zooplankton production declined by approximately half from 42.45 (g dry wt∙m −2 ∙ year −1 ) during 1987–1991 to 21.91 (g dry wt∙m −2 ∙ year −1 ) in 2003 and averaged 21.01 (g dry wt∙m −2 ∙ year −1 ) during 2001–2005. Analysis of two independent data sets indicates that the mean biomass and biomass proportion of cyclopoid copepods declined while the same measures increased for the invasive predatory cladocerans. Changes in means and proportions of all other zooplankton groups were not consistent between the data sets. Cyclopoid copepod biomass and production declined by factors ranging from 3.6 to 5.7. Invasive predatory cladoceran biomass averaged from 5.0% to 8.0% of the total zooplankton biomass. The zooplankton community was otherwise resilient to the invasion-induced disruption as zooplankton species richness and diversity were unaffected. Zooplankton production was likely reduced by declines in primary productivity but may have declined further due to increased predation by alewives and invasive predatory cladocerans. Shifts in zooplankton community structure were consistent with increased predation pressure on cyclopoid copepods by alewives and invasive predatory cladocerans. Predicted declines in the proportion of small cladocerans were not evident. This study represents the first direct comparison of changes in Lake Ontario zooplankton production before and after the invasion-induced disruption and will be important to food web-scale investigations of invasion effects.

Journal of Great Lakes Research↗

Tracking changes in nutrient delivery to western Lake Erie: Approaches to compensate for variability and trends in streamflow

Tracking changes in stream nutrient inputs to Lake Erie over multidecadal time scales depends on the use of statistical methods that can remove the influence of year-to-year variability of streamflow but also explicitly consider the influence of long-term trends in streamflow. The methods introduced in this paper include an extended version of Weighted Regressions on Time, Discharge, and Season (WRTDS) modeling that explicitly considers nonstationary streamflow by incorporating information on changes in the frequency distribution of daily measured streamflow (discharge) over time. Soluble reactive phosphorus (SRP) trends in annual flow-normalized fluxes (loads) at five long-term monitoring sites in the western Lake Erie drainage basin show increases of 109 to 322% over the period 1995 to 2015. About one-third of the increase appears attributable to increasing discharge trends, while the remaining two-thirds appears to be driven by changes in concentration versus discharge relationships reflecting higher concentrations for any given discharge during recent years. Trends in total phosphorus and three nitrogen parameters (total nitrogen, nitrate-nitrite, and total Kjeldahl nitrogen) at the 10 sites analyzed were much less pronounced, and commonly show decreases in concentration-discharge relationships accompanied by increases in discharge, resulting in little net change in total flux. Trends in monthly SRP fluxes and discharge, dissolved versus particulate fractions of nutrients, and N:P flux ratios were also evaluated. The methods described here provide tools to more clearly discern the effectiveness of nutrient-control strategies and can serve as ongoing measures of progress, or lack of progress, towards nutrient-reduction goals.

Journal of Great Lakes Research↗

Hydrologic properties of coal beds in the Powder River Basin, Montana I. Geophysical log analysis

As part of a multidisciplinary investigation designed to assess the implications of coal-bed methane development on water resources for the Powder River Basin of southeastern Montana, six wells were drilled through Paleocene-age coal bedsalong a 31-km east–west transect within the Tongue River drainage basin. Analysis of geophysical logs obtained in these wells provides insight into the hydrostratigraphic characteristics of the coal and interbedded siliciclastic rocks and their possible interaction with the local stress field. Natural gamma and electrical resistivity logs were effective in distinguishing individual coal beds. Full-waveform sonic logs were used to determine elastic properties of the coal and an attendant estimate of aquifer storage is in reasonable agreement with that computed from a pumping test. Inspection of magnetically oriented images of the borehole walls generated from both acoustic and optical televiewers and comparison with coal cores infer a face cleat orientation of approximately N33°E, in close agreement with regional lineament patterns and the northeast trend of the nearby Tongue River. The local tectonic stress field in this physiographic province as inferred from a nearby 1984 earthquake denotes an oblique strike-slip faulting regime with dominant east–west compression and north–south extension. These stress directions are coincident with those of the primary fracture sets identified from the televiewer logs and also with the principle axes of the drawdown ellipse produced from a complementary aquifer test, but oblique to apparent cleat orientation. Consequently, examination of these geophysical logs within the context of local hydrologic characteristics indicates that transverse transmissivity anisotropy in these coals is predominantly controlled by bedding configuration and perhaps a mechanical response to the contemporary stress field rather than solely by cleat structure.

Montana↗

Trends in the suspended-sediment yields of coastal rivers of northern California, 1955–2010

Time-dependencies of suspended-sediment discharge from six coastal watersheds of northern California – Smith River, Klamath River, Trinity River, Redwood Creek, Mad River, and Eel River – were evaluated using monitoring data from 1955 to 2010. Suspended-sediment concentrations revealed time-dependent hysteresis and multi-year trends. The multi-year trends had two primary patterns relative to river discharge: (i) increases in concentration resulting from both land clearing from logging and the flood of record during December 1964 (water year 1965), and (ii) continual decreases in concentration during the decades following this flood. Data from the Eel River revealed that changes in suspended-sediment concentrations occurred for all grain-size fractions, but were most pronounced for the sand fraction. Because of these changes, the use of bulk discharge-concentration relationships (i.e., “sediment rating curves”) without time-dependencies in these relationships resulted in substantial errors in sediment load estimates, including 2.5-fold over-prediction of Eel River sediment loads since 1979. We conclude that sediment discharge and sediment discharge relationships (such as sediment rating curves) from these coastal rivers have varied substantially with time in response to land use and climate. Thus, the use of historical river sediment data and sediment rating curves without considerations for time-dependent trends may result in significant errors in sediment yield estimates from the globally-important steep, small watersheds.

California↗

Inter-annual and spatial variability of Hamon potential evapotranspiration model coefficients

Monthly calibrated values of the Hamon PET coefficient ( C ) are determined for 109,951 hydrologic response units (HRUs) across the conterminous United States (U.S.). The calibrated coefficient values are determined by matching calculated mean monthly Hamon PET to mean monthly free-water surface evaporation. For most locations and months the calibrated coefficients are larger than the standard value reported by Hamon. The largest changes in the coefficients were for the late winter/early spring and fall months, whereas the smallest changes were for the summer months. Comparisons of PET computed using the standard value of C and computed using calibrated values of C indicate that for most of the conterminous U.S. PET is underestimated using the standard Hamon PET coefficient, except for the southeastern U.S.

Journal of Hydrology↗

Vestiges of an Iapetan rift basin in the New Jersey Highlands: Implfications for the Neoproterozoic Laurentian margin

Thin, discontinuous remnants of Neoproterozoic intracratonic rift-basin deposits of the Chestnut Hill Formation occur in the western New Jersey Highlands. These deposits form an important link between well-documented Iapetan rift-basins in both the northern and southern Appalachians. The close spatial relations of Chestnut Hill rocks to Paleozoic sedimentary rocks open the possibility that additional Iapetan rift-basins could be concealed beneath the rocks of the Valley and Ridge Province to the west indicating a much broader zone of rifting than has been previously proposed. The Chestnut Hill Formation is intermittently exposed along a 100 km-long band that extends northeast from Pennsylvania nearly to New York State. The lower part of the Chestnut Hill Formation is composed of interbedded lithic pebble- to boulder-conglomerate and feldspathic sandstone grading upward into interbedded phyllite, feldspathic and quartz sandstone, local paleosaprolite, quartz-pebble conglomerate, thin limestone lenses, volcanic, and volcaniclasic rocks, abundant bedded ironstone (hematite ore), and ultimately into diamictites that are interpreted as possible tilloids and containing rounded intra and extrabasinal clasts of the other lithologies. Extensive soft-sediment deformation, cross bedding, and clastic dikes are common in all but the lowest and upper facies. Banded hematite layers occur preferentially in fine-grained tuffs and tuffaceous sediments, but hematitization has affected most lithologies. Volcanic rocks consist of altered rhyolitic tuffs and lapilli tuffs that are interbedded with sediments. The Chestnut Hill Formation is interpreted to have been deposited in early alluvial, and later a complex of fluvial, lacustrine and deltaic environments. Provenance studies based upon petrographic and geochemical analysis of clastic rocks indicate that the sediments are predominantly immature and reflect derivation from local uplifted felsic basement sources in a rifted-margin tectonic setting. Low to moderate weathering of the source rocks is indicated by the geochemistry of most samples, as is the locally intense effect of hydrothermal alteration. Most occurrences of the Chestnut Hill Formation are associated with major faults that exhibit normal movement of apparent Neoproterozoic age. Rocks from the Morgan Hill fault near Easton, Pennsylvania display consistent normal shear sense and vary from low temperature S-C mylonites to breccia that contains deformed pieces of Chestnut Hill Formation. ?? 2004 Elsevier Ltd. All rights reserved.

Journal of Geodynamics↗