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At least 595 records · Page 33Linked to original sources
USGS1981

U-Th-Pb systematics of some granitoids from the northeastern Yilgarn Block, Western Australia and implications for uranium source rock potential

The Mount Boreas‐type granite and spatially associated syenitic granitoid of Western Australia yield Pb‐Pb ages of 2370 ± 100 Ma and 2760 ± 210 Ma, respectively. Th‐Pb ages, although less precise, are concordant with these ages, and therefore the apparent ages are interpreted to be the crystallisation ages for these two units. U‐Pb ages are variable and for the most part anomalously old, which suggests a Cainozoic uranium loss. However, this loss is generally small (< 3 μ g/g); therefore, neither granitoid in its fresh state provides a good source for nearby calcrete‐hosted uranium deposits. The possibility remains that the Mount Boreas‐type granite that has been completely weathered during the Tertiary could have been a source for the calcrete‐type uranium deposits in W.A. Although the Mount Boreas‐type granite is highly fractionated, it does not bear a strong geochemical imprint of a sedimentary precursor. This feature contrasts it with apparently fresh granitoids from other parts of the world that have lost large amounts of uranium (∼ 20 μ g/g ) and are associated with large roll‐type and other low temperature‐type uranium deposits.

Journal of the Geological Society of Australia↗
USGS2007

Development of inverted metamorphic isograds in the western metamorphic belt, Juneau, Alaska

An inverted metamorphic gradient is preserved in the western metamorphic belt near Juneau, Alaska. The western metamorphic belt is part of the Coast plutonic–metamorphic complex of western Canada and southeastern Alaska that developed as a result of tectonic overlap and/or compressional thickening of crustal rocks during collision of the Alexander and Stikine terranes. Detailed mapping of pelitic single-mineral isograds, systematic changes in mineral assemblages, and silicate geothermometry indicate that thermal peak metamorphic conditions increase structurally upward over a distance of about 8 km. Peak temperatures of metamorphism increase progressively from about 530 °C for the garnet zone to about 705 °C for the upper kyanite–biotite zone. Silicate geobarometry suggests that the thermal peak metamorphism occurred under pressures of 9–11 kbar. The metamorphic isograds are in general parallel to the tonalite sill that is regionally continuous along the east side of the western metamorphic belt, although truncation of the isograds north of Juneau indicates that the sill intrusion continued after the isograds were established. Our preferred interpretation of the cause of the inverted gradient is that it formed during compression of a thickened wedge of relatively wet and cool rocks in response to heat flow associated with the formation and emplacement of the tonalite sill magma. Garnet rim compositions and widespread growth of chlorite suggest partial re-equilibration of the schists under pressures of 5–6 kbar during uplift in response to final emplacement and crystallization of the tonalite sill. The combined results of this study with previous studies elsewhere in the western metamorphic belt indicate that high-T/high-P metamorphism associated with the collision of the Alexander and Stikine terranes was a long-lived event, extending from about 98 Ma to about 67 Ma.

Journal of Metamorphic Geology↗
USGS2007

On the formation of granulites

The tectonic settings for the formation and evolution of regional granulite terranes and the lowermost continental crust can be deduced from pressure–temperature–time ( P–T –time) paths and constrained by petrological and geophysical considerations. P–T conditions deduced for regional granulites require transient, average geothermal gradients of greater than 35°C km −1 , implying minimum heat flow in excess of 100 mWm −2 . Such high heat flow is probably caused by magmatic heating. Tectonic settings wherein such conditions are found include convergent plate margins, continental rifts, hot spots and at the margins of large, deep-seated batholiths. However, particular P–T –time paths do not allow specific tectonic settings to be distinguished at this time. Under different conditions, both clockwise, CW ( P max attained before T max ), and anticlockwise, ACW ( P max attained slightly after T max ), paths are possible in the same tectonic setting. Both CW and ACW end-member paths can yield nearly isobaric cooling, IBC, paths. Such cooling paths are clearly not an artefact of thermobarometry, but can be constrained by solid–solid and devolatilization equilibria and geophysical modelling. In terms of understanding the evolution of the deep crust, a potentially significant group of regional granulite terranes are those that show evidence for ACW-IBC paths. Such paths are the likely result of: (i) episodic igneous activity resulting in intrusions within all levels of the crust, (ii) thickening of the crust by magmatic underplating, (iii) slow uplift as a result of the formation of a deep, garnet-rich crustal root and (iv) excavation resulting from a later tectonic event unrelated to that resulting in the formation of the granulites. The later event might be triggered by the delamination of the garnet-rich, lowermost crust.

Journal of Metamorphic Geology↗
USGS2007

Distribution and characteristics of metamorphic belts in the south-eastern Alaska part of the North American Cordillera

The Cordilleran orogen in south-eastern Alaska includes 14 distinct metamorphic belts that make up three major metamorphic complexes, from east to west: the Coast plutonic–metamorphic complex in the Coast Mountains; the Glacier Bay–Chichagof plutonic–metamorphic complex in the central part of the Alexander Archipelago; and the Chugach plutonic–metamorphic complex in the northern outer islands. Each of these complexes is related to a major subduction event. The metamorphic history of the Coast plutonic–metamorphic complex is lengthy and is related to the Late Cretaceous collision of the Alexander and Wrangellia terranes and the Gravina overlap assemblage to the west against the Stikine terrane to the east. The metamorphic history of the Glacier Bay–Chichagof plutonic–metamorphic complex is relatively simple and is related to the roots of a Late Jurassic to late Early Cretaceous island arc. The metamorphic history of the Chugach plutonic–metamorphic complex is complicated and developed during and after the Late Cretaceous collision of the Chugach terrane with the Wrangellia and Alexander terranes. The Coast plutonic–metamorphic complex records both dynamothermal and regional contact metamorphic events related to widespread plutonism within several juxtaposed terranes. Widespread moderate- P/T dynamothermal metamorphism affected most of this complex during the early Late Cretaceous, and local high- P/T metamorphism affected some parts during the middle Late Cretaceous. These events were contemporaneous with low- to moderate- P , high- T metamorphism elsewhere in the complex. Finally, widespread high- P–T conditions affected most of the western part of the complex in a culminating late Late Cretaceous event. The eastern part of the complex contains an older, pre-Late Triassic metamorphic belt that has been locally overprinted by a widespread middle Tertiary thermal event. The Glacier Bay–Chichagof plutonic–metamorphic complex records dominantly regional contact-metamorphic events that affected rocks of the Alexander and Wrangellia terranes. Widespread low- P , high- T assemblages occur adjacent to regionally extensive foliated granitic, dioritic and gabbroic rocks. Two closely related plutonic events are recognized, one of Late Jurassic age and another of late Early and early Late Cretaceous age; the associated metamorphic events are indistinguishable. A small Late Devonian or Early Mississippian dynamothermal belt occurs just north-east of the complex. Two older low-grade regional metamorphic belts on strike with the complex to the south are related to a Cambrian to Ordovician orogeny and to a widespread Middle Silurian to Early Devonian orogeny. The Chugach plutonic–metamorphic complex records a widespread late Late Cretaceous low- to medium/high- P , moderate- T metamorphic event and a local transitional or superposed early Tertiary low- P , high- T regional metamorphic event associated with mesozonal granitic intrusions that affected regionally deformed and metamorphosed rocks of the Chugach terrane. The Chugach complex also includes a post-Late Triassic to pre-Late Jurassic belt with uncertain relations to the younger belts.

Journal of Metamorphic Geology↗
USGS2007

High-pressure amphibolite facies dynamic metamorphism and the Mesozoic tectonic evolution of an ancient continental margin, east- central Alaska

Ductilely deformed amphibolite facies tectonites comprise two adjacent terranes in east-central Alaska: the northern, structurally higher Taylor Mountain terrane and the southern, structurally lower Lake George subterrane of the Yukon-Tanana terrane. The pressure, temperature, kinematic and age data are interpreted to indicate that the metamorphism of the Taylor Mountain terrane and Lake George subterrane took place during different phases of a latest Palaeozoic through early Mesozoic shortening episode resulting from closure of an ocean basin now represented by klippen of the Seventymile-Slide Mountain terrane. High- to intermediate-pressure metamorphism of the Taylor Mountain terrane took place within a SW-dipping (present-day coordinates) subduction system. High- to intermediate-pressure metamorphism of the Lake George subterrane and the structural contact zone occurred during NW-directed overthrusting of the Taylor Mountain, Seventymile-Slide Mountain and Nisutlin terranes, and imbrication of the continental margin in Jurassic time. -from Authors

Alaska↗
USGS2007

Metamorphic and structural history of continental crust at a Mesozoic collisional margin, the Ruby terrane, central Alaska

The Ruby terrane is an elongate fragment of continental crustal rocks that is structurally overlain by thrust slices of oceanic crust. Our results from the Kokrines Hills, in the south‐central part of the Ruby terrane, demonstrate that the low‐angle schistose fabric formed under high‐ P /low‐ T conditions, at peak conditions of 10.8‐13.2 kbar and 425‐550° C, consistent with the rare occurrence of glaucophane. White mica 40 Ar/ 39 Ar cooling ages from these blueschists indicate that the metamorphism occurred prior to 144 ± 1 Ma. The blueschist facies assemblages are partially replaced by greenschist facies assemblages in the eastern Kokrines Hills. In contrast, in the central and western Kokrines Hills, upper amphibolite to lower granulite facies metamorphism associated with extensive late Early Cretaceous plutonism has completely overprinted any evidence of an earlier high‐ P/T metamorphic history. Deformation accompanying the plutonism produced recumbent isoclinal folds in the plutonic rocks and pelitic gneisses of the wallrock; decompression reactions in the pelitic gneisses suggest that the deformation occurred during exhumation. Thermochronological data bracket the time of intrusion and cooling below 500° C between 118 ± 3 and 109 ± 1 Ma. Our data from the schists of the Ruby terrane support the general assumption of many authors that the Ruby terrane was subducted beneath an oceanic island arc. This tectonic history is similar to that described for other large continental crustal blocks in northern and central Alaska, in the Brooks Range, Seward Peninsula and Yukon‐Tanana Upland. The current orientation of the Ruby terrane at an oblique angle to these other crustal blocks and to the Cordilleran trend is due to post‐collisional tectonic processes that have greatly modified the original continental margin.

Alaska↗
USGS2007

Scales of equilibrium and disequilibrium during cleavage formation in chlorite and biotite-grade phyllites, SE Vermont

Detailed electron microprobe analyses of phyllosilicates in crenulated phyllites from south-eastern Vermont show that grain-scale zoning is common, and sympathetic zoning in adjacent minerals is nearly universal. We interpret this to reflect a pressure-solution mechanism for cleavage development, where precipitation from a very small fluid reservoir fractionated that fluid. Multiple analyses along single muscovite, biotite and chlorite grains (30–200 μ m in length) show zoning patterns indicating Tschermakitic substitutions in muscovite and both Tschermakitic and di/trioctahedral substitutions in biotite and chlorite. Using cross-cutting relationships and mineral chemistry it is shown that these patterns persist in cleavages produced at metamorphic conditions of chlorite-grade, chlorite-grade overprinted by biotite-grade and biotite-grade. Zoning patterns are comparable in all three settings, requiring a similar cleavage-forming mechanism independent of metamorphic grade. Moreover, the use of 40 Ar/ 39 Ar geochronology demonstrates this is true regardless of age. Furthermore, samples with chlorite-grade cleavages overprinted by biotite porphyroblasts suggest the closure temperatures for the diffusion of Al, Si, Mg and Fe ions are greater than the temperature of the biotite isograd (>∼400 °C). Parallel and smoothly fanning tie lines produced by coexisting muscovite–chlorite, and muscovite–biotite pairs on compositional diagrams demonstrate effectively instantaneous chemical equilibrium and probably indicate simultaneous crystallization. These results do not support theories suggesting cleavages form in fluid-dominated systems. If crenulation cleavages formed in systems in which the chemical potentials of all major components are fixed by an external reservoir, then the compositions of individual grains defining these cleavages would be uniform. On the contrary, the fine-scale chemical zoning observed probably reflects a grain-scale process consistent with a pressure-solution mechanism in which the aqueous activities of major components are defined by local dissolution and precipitation. Thus the role of fluids was probably limited to one of catalysing pressure-solution and fluids apparently did not drive cleavage development.

Journal of Metamorphic Geology↗
USGS2007

A problem with estimating the pseudo- activation energy of kerogen thermal maturation from Connan's time-temperature relation in oil genesis.

Connan's time-temperature relation in oil genesis as derived from first-order reaction kinetics is algebraically correct, but its application to natural petroleum generation is invalidated by the assumption that the ratio of initial kerogen concentration to degraded kerogen concentration is constant from deposition to the initiation of intense oil generation. The ratio can only remain constant if no reaction is occurring and, therefore, Connan's data on 'reaction time' in petroleum generation (assumed to be the age of the sediment) only measures the time elapsed since the system formed. Thus, the widely cited pseudo-activation energy of 11-14 kcal/mole computed from Connan's equation for the start of oil generation from kerogen is meaningless.-Author

Journal of Petroleum Geology↗
USGS2007

Organic metamorphism in the Lower Mississippian-Upper Devonian Bakken shales. Part 1: Rock-Eval pyrolysis and vitrinite reflectance

Detailed organic geochemistry has been performed on a large number of Lower Mississippian-Upper Devonian Bakken shales from the North Dakota portion of the Williston Basin, and 28 oils mainly from Mississippian Madison Group rocks from different basinal areas. Here we report results of Rock-Eval pyrolysis and vitrinite reflectance ( R o ) analyses. Variable paleoheat flows in the Williston Basin caused the threshold of intense hydrocarbon generation to occur at different depths in different basinal areas. In higher paleogeothermal gradient basinal areas, this event occurred at depths of 7,650-8,000 ft, and at 10,000 ft or deeper in lower paleogeothermal gradient areas of the Basin. Distinct organic metamorphic imprints in Williston Basin sediments were also caused by extreme, but variable, paleoheat flows in the basin, as well as secondary migration of crude oils from deep basinal source areas. The high paleoheat flows are postulated as being due to a Late Cretaceous - Paleocene aborted rift event. Only a small volume of Bakken shales in restricted areas of the Williston Basin was responsible for the oil found reservoired in Mississippian Madison Group rocks. However, this small shale volume has been responsible for a relatively large amount of crude oil. R o profiles in the Tertiary through Middle Jurassic rocks in the Williston Basin had steep, linear R o versus depth gradients, with strong reversals of R o values occurring in the Lower Jurassic rocks. The lower Mesozoic through Paleozoic rocks of the Basin had strongly suppressed R o values compared to the values in the Tertiary through Middle Jurassic rocks. This was especially true of the R o values in the Bakken shales. This R o suppression was due to a change in organic matter (OM) type from oxygen-rich terrestrially derived OM in the younger rocks, to a hydrogen-rich marine derived OM in the deeper, older rocks. The threshold of intense oil generation (TIHG) occurred in the Bakken shales of the Williston Basin at R o values somewhere between 0.9 and 1.7% (best estimate 0.9), as would be read in oxygen-rich OM. Much higher burial temperatures (and consequently R o values) than usually held to be necessary were required for both the TIHG as well as mainstage hydrocarbon generation in the Bakken shales. These results are most likely applicable in general to source rocks with hydrogen-rich OM. The data of this study have major implications to petroleum exploration as well as to petroleum resource assessment.

Journal of Petroleum Geology↗
USGS2007

Organic metamorphism in the Lower Mississippian-Upper Devonian Bakken shales-II: Soxhlet extraction.

We report on Soxhlet extraction (and subsequent related analyses) of 39 Lower Mississippian-Upper Devonian Bakken shales from the North Dakota portion of the Williston Basin, and analyses of 28 oils from the Basin. Because of the influence of primary petroleum migration, no increase in the relative or absolute concentrations of hydrocarbons or bitumen was observed at the threshold of intense hydrocarbon generation (TIHG), or during mainstage hydrocarbon generation in the Bakken shales. Thus, the maturation indices that have been so useful in delineating the TIHG and mainstage hydrocarbon generation in other studies were of no use in this study, where these events could clearly be identified only by Rock-Eval pyrolysis data. The data of this study demonstrate that primary petroleum migration is a very efficient process. Four distinctive classes of saturated hydrocarbon gas chromatograms from the Bakken shales arose from facies, maturation, and primary migration controls. As a consequence of maturation, the % of saturated hydrocarbons increased in the shale extract at the expense of decreases in the resins and asphaltenes. Measurements involving resins and asphaltenes appear to be excellent maturation indices in the Bakken shales. Two different and distinct organic facies were present in immature Bakken shales. -from Authors

Journal of Petroleum Geology↗
USGS2007

Basin richness and source rock disruption - a fundamental relationship

Primary petroleum migration (expulsion from source rocks) remains the least understood parameter controlling the genesis of oil deposits. It is hypothesised that source rocks must be physically disrupted before meaningful expulsion can occur. Faulting, with accompanying significant fracturing, would appear to be the optimum naturally-occurring process for physical disruption of source rocks. If these hypotheses are valid, intensity of faulting in deeply-buried HC "kitchens' containing mature source rocks should strongly correlate with increasing basin richness. This possible relationship is examined in this paper; it is found that there is a strong correlation of increasing basin richness with increasing structural intensity over and adjacent to basin depocentres. This correlation thus supports the hypothesis that physical disruption of mature source rocks is a necessary, and previously unappreciated, controlling parameter for oil expulsion. -from Author

Journal of Petroleum Geology↗
USGS2007

Hydrocarbon source potential and maturation in eocene New Zealand vitrinite-rich coals: Insights from traditional coal analyses, and Rock-Eval and biomarker studies

The results of traditional methods of coal characterisation (proximate, specific energy, and ultimate analyses) for 28 Eocene coal samples from the West Coast of New Zealand correspond well with biomarker ratios and Rock-Eval analyses. Isorank variations in vitrinite fluorescence and reflectance recorded for these samples are closely related to their volatile-matter content, and therefore indicate that the original vitrinite chemistry is a key controlling factor. By contrast, the mineral-matter content and the proportion of coal macerals present appear to have had only a minor influence on the coal samples' properties. Our analyses indicate that a number of triterpane biomarker ratios show peak maturities by high volatile bituminous A rank; apparent maturities are then reversed and decline at the higher medium volatile bituminous rank. The Rock-Eval S1 +S2 yield also maximizes by high volatile bituminous A rank, and then declines; however, this decline is retarded in samples with the most hydrogen-rich (perhydrous) vitrinites. These Rock-Eval and biomarker trends, as well as trends in traditional coal analyses, are used to define the rank at which expulsion of gas and oil occurs from the majority of the coals. This expulsion commences at high volatile A bituminous rank, and persists up to the threshold of medium volatile bituminous rank (c. 1.1% Ro ran. or 1.2% Ro max in this sample set), where marked hydrocarbon expulsion from perhydrous vitrinites begins to take place.

Journal of Petroleum Geology↗
USGS2007

Oceanic methane hydrate: The character of the Blake Ridge hydrate stability zone, and the potential for methane extraction

Oceanic methane hydrates are mineral deposits formed from a crystalline 'ice' of methane and water in sea-floor sediments (buried to less than about 1 km) in water depths greater than about 500 m; economic hydrate deposits are probably restricted to water depths of between 1.5 km and 4 km. Gas hydrates increase a sediment's strength both by 'freezing' the sediment and by filling the pore spaces in a manner similar to water-ice in permafrost. Concentrated hydrate deposits may be underlain by significant volumes of methane gas, and these localities are the most favourable sites for methane gas extraction operations. Seismic reflection records indicate that trapped gas may blow-out naturally, causing large-scale seafloor collapse. In this paper, we consider both the physical properties and the structural integrity of the hydrate stability zone and the associated free gas deposits, with special reference to the Blake Ridge area, SE US offshore, in order to help establish a suitable framework for the safe, efficient, and economic recovery of methane from oceanic gas hydrates. We also consider the potential effects of the extraction of methane from hydrate (such as induced sea-floor faulting, gas venting, and gas-pocket collapse). We assess the ambient pressure effect on the production of methane by hydrate dissociation, and attempt to predict the likelihood of spontaneous gas flow in a production situation.Oceanic methane hydrates are mineral sits formed from a crystalline `ice' of methane and water in sea-floor sediments (buried to less than about 1 km) in water depths greater than about 500 m; economic hydrate deposits are probably restricted to water depths of between 1.5 km and 4 km. Gas hydrates increase a sediment's strength both by `freezing' the sediment and by filling the pore spaces in a manner similar to water-ice in permafrost. Concentrated hydrate deposits may be underlain by significant volumes of methane gas, and these localities are the most favourable sites for methane gas extraction operations. Seismic reflection records indicate that trapped gas may blow-out naturally, causing large-scale seafloor collapse. In this paper, we consider both the physical properties and the structural integrity of the hydrate stability zone and the associated free gas deposits, with special reference to the Blake Ridge area, SE US offshore, in order to help establish a suitable framework for the safe, efficient, and economic recovery of methane from oceanic gas hydrates. We also consider the potential effects of the extraction of methane from hydrate (such as induced sea-floor faulting, gas venting, and gas-pocket collapse). We assess the ambient pressure effect on the production of methane by hydrate dissociation, and attempt to predict the likelihood of spontaneous gas flow in a production situation.

Journal of Petroleum Geology↗
USGS2007

Abnormal organic-matter maturation in the Yinggehai Basin, South China Sea: Implications for hydrocarbon expulsion and fluid migration from overpressured systems

Three superimposed pressure systems are present in the Yinggehai Basin, South China Sea. A number of commercial, thermogenic gas accumulations have been found in an area in which shale diapirs occur. Because the reservoir intervals are shallow and very young, they must have filled with gas rapidly. The thick (up to 17 km) Tertiary and Quaternary sedimentary succession is dominated by shales, and is not disrupted by major faulting in the study area, a factor which seems to have had an important effect on both hydrocarbon generation and fluid migration. Organic-matter maturation in the deepest, most overpressured compartment has been significantly retarded as a result of the combined effects of excess pressure, the presence of large volumes of water, and the retention of generated hydrocarbons. This retardation is indicated by both kerogen-related parameters (vitrinite reflectance and Rock-Eval T(max)); and also by parameters based on the analysis of soluble organic matter (such as the C15+ hydrocarbon content, and the concentration of isoprenoid hydrocarbons relative to adjacent normal alkanes). In contrast to this, organic-matter maturation in shallow, normally-pressured strata in the diapiric area has been enhanced by hydrothermal fluid flow, which is clearly not topography-driven in origin. As a result, the hydrocarbon generation 'window' in the basin is considerably wider than could be expected from traditional geochemical modelling. These two unusual and contrasting anomalies in organic-matter maturation, together with other lines of evidence, suggest that there was a closed fluid system in the overpressured compartment until shale diapirs developed. The diapirs developed as a result of the intense overpressuring, and their growth was triggered by regional extensional stresses. They served as conduits through which fluids (both water and hydrocarbons) retained in the closed system could rapidly migrate. Fluid migration led to the modification of the thermal regime and the enhancement of organic maturation, as well as the accumulation of commercial volumes of gas in a relatively short time interval.Three superimposed pressure systems are present in the Yinggehai Basin, South China Sea. To date, a number of commercial, thermogenic gas accumulations have been found in an area in which shale diapirs occur. In fact, two unusual and contrasting anomalies in organic-matter maturation have been documented. These two anomalies, together with other lines of evidence, suggest that there was a closed fluid system in the overpressured compartment until shale diapirs developed. The diapirs developed as a result of intense overpowering, and their growth was triggered by regional extensional stresses. They served as conduits through which fluids retained in the closed system could rapidly migrate. Fluid migration led to the modification of the thermal regime and the enhancement of organic maturation, as well as the accumulation of commercial volumes of gas in a relatively short time interval.

Journal of Petroleum Geology↗
USGS2016

Reaction softening by dissolution–precipitation creep in a retrograde greenschist facies ductile shear zone, New Hampshire, USA

We describe strain localization by a mixed process of reaction and microstructural softening in a lower greenschist facies ductile fault zone that transposes and replaces middle to upper amphibolite facies fabrics and mineral assemblages in the host schist of the Littleton Formation near Claremont, New Hampshire. Here, Na-poor muscovite and chlorite progressively replace first staurolite, then garnet, and finally biotite porphyroblasts as the core of the fault zone is approached. Across the transect, higher grade fabric-forming Na-rich muscovite is also progressively replaced by fabric-forming Na-poor muscovite. The mineralogy of the new phyllonitic fault-rock produced is dominated by Na-poor muscovite and chlorite together with late albite porphyroblasts. The replacement of the amphibolite facies porphyroblasts by muscovite and chlorite is pseudomorphic in some samples and shows that the chemical metastability of the porphyroblasts is sufficient to drive replacement. In contrast, element mapping shows that fabric-forming Na-rich muscovite is selectively replaced at high-strain microstructural sites, indicating that strain energy played an important role in activating the dissolution of the compositionally metastable muscovite. The replacement of strong, high-grade porphyroblasts by weaker Na-poor muscovite and chlorite constitutes reaction softening. The crystallization of parallel and contiguous mica in the retrograde foliation at the expense of the earlier and locally crenulated Na-rich muscovite-defined foliation destroys not only the metastable high-grade mineralogy, but also its stronger geometry. This process constitutes both reaction and microstructural softening. The deformation mechanism here was thus one of dissolution–precipitation creep, activated at considerably lower stresses than might be predicted in quartzofeldspathic rocks at the same lower greenschist facies conditions.

New Hampshire↗
USGS2024

Deformation-induced graphitization and muscovite recrystallization in a ductile fault zone

A suite of slate samples collected along a 2 km transect crossing the Lishan fault in central Taiwan were evaluated to assess the role of ductile deformation in natural graphitization at lower greenschist facies metamorphic conditions. The process of natural aromatization, or graphitization, of an organic precursor is well established as a thermally driven process; however, experimental studies have shown that the energy provided by deformation can substantially reduce the activation energy required for graphitization. This study provides a natural example of deformation-induced graphitization. A strain gradient approaching the Lishan fault was established by scanning electron microscope imaging and X-ray diffraction analysis of phyllosilicates and quartz that showed an increase in the strength of slaty cleavage development via dissolution-precipitation processes. Thermal conditions were constrained to be near isothermal using calcite-dolomite geothermometry. Raman spectroscopic results from carbonaceous material, including D1-full width-at-half-maximum (FWHM), G-FWHM, Raman band separation (RBS), and a lesser-known vibrational mode B 2g -FWHM, showed robust linear trends across the same sampling transect. However, the G-FWHM parameter showed a trend opposite of that expected from thermally driven graphitization. The Raman results are interpreted to reflect a strain-driven reduction in graphite crystallite size (decrease in G-FWHM) but improvement in structural ordering in individual coherent domains. A multiple linear regression with an R 2 value of 0.92 predicts the graphite D1-FWHM values from the XRD-derived ratio of muscovite populations and muscovite microstrain, demonstrating the concomitant recrystallization of silicates and carbonaceous material across the strain gradient, despite the disparate processes accommodating the deformation. This study demonstrates the role of deformation in natural graphitization and provides a new perspective on the use of graphite as a geothermometer in strongly deformed greenschist facies rocks.

Journal of Metamorphic Geology↗
USGS2022

Quaternary fans and terraces in the Khumbu Himal south of Mount Everest: their characteristics, age and formation

Large fans and terraces are frequent in the Khumbu Himal within the high Himalayan valleys south of Mt. Everest. These features are composed of massive matrix- and clast-supported diamicts that were formed from both hyperconcentrated flows and coarse-grained debris flows. Cosmogenic radionuclide (CRN) exposure ages for boulders on fans and terraces indicate that periods of fan and terrace formation occurred at c. 16, c. 12, c. 8, c. 4 and c. 1.5 ka, and are broadly coincident with the timing of glaciation in the region. The dating precision is insufficient to resolve whether the surfaces formed before, during or after the correlated glacial advance. However, the sedimentology, and morphostratigraphic and geomorphological relationships suggest that fan and terrace sedimentation in this part of the Himalaya primarily occurs during glacier retreat and is thus paraglacial in origin. Furthermore, modern glacial-lake outburst floods and their associated deposits are common in the Khumbu Himal as the result of glacial retreat during historical times. We therefore suggest that Late Quaternary and Holocene fan and terrace formation and sediment transfer are probably linked to temporal changes in discharge and sediment load caused by glacier oscillations responding to climate change. The timing of major sedimentation events in this region can be correlated with fans and terraces in other parts of the Himalaya, suggesting that major sedimentation throughout the Himalaya is synchronous and tied to regional climatic oscillations. Bedrock incision rates calculated from strath terrace ages average c. 3.9 mm a −1 , suggesting that the overall rate of incision is set by regional uplift.

Imja Khola Valley, Khumbu Himal, Mount Everest↗