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At least 595 records · Page 33Linked to original sources
USGS2021

Groundwater hydrology and chemistry of Jamestown Island, Virginia—Potential effects of tides, storm surges, and sea-level rise on archaeological, cultural, and ecological resources

As the site of the first permanent English settlement in North America in 1607, Jamestown Island, Colonial National Historical Park (COLO), Virginia, contains a rich archaeological record that extends from the Paleoindian period (15,000 to 8,000 years ago) through the 20th century. The island is located on the lower James River near the mouth of Chesapeake Bay. Jamestown Island vegetation is dominated by upland forests surrounded by tidal, freshwater-to-oligohaline marshes. Along the Virginia coast, relative sea-level rise was more than 2.5 times the global average during the 20th century. Consequently, the National Park Service (NPS) has identified COLO as one of the 25 national parks most threatened by climate change. Surface waters across the island are hydraulically connected to the laterally continuous Surficial aquifer. The land-surface altitude of the island is low, with two-thirds of the island less than 5 feet (ft) above the North American Vertical Datum of 1988 (NAVD 88). Consequently, sea-level rise, combined with tides and storm surges, threatens the island and its resources as surface-water and groundwater levels rise, saltwater enters the Surficial aquifer, and groundwater chemistry changes. The impact of sea-level rise on the island’s surface-water resources has been well studied, but groundwater effects have been largely ignored. Quantifying the effects of tides, storm surges, and sea-level rise on groundwater levels and chemistry is essential to developing an effective strategy for managing climate-induced changes. The first step in developing a response strategy includes a parkwide general risk assessment for archaeological sites on the island, so that sites can be prioritized for management actions. The U.S. Geological Survey and the NPS began a study in 2015 to develop a long-term groundwater-monitoring program to evaluate this risk and to develop an updated management strategy. The groundwater-monitoring program consists of 45 wells and piezometers in two individual clusters and three transects across the island in different hydrologic and chemical settings. Samples for water quality were collected from the wells and piezometers from October 2015 through September 2018 at variable time intervals. Results of the monitoring identified disparate hydrologic and chemical responses to saltwater intrusion across the island. Specific conductance (an indicator of salinity) of groundwater beneath several marshes responded differently to changes in James River salinity. Groundwater response to changes in James River specific conductance appeared to be controlled by land-surface altitude and slope, differences in lateral and vertical sediment characteristics, distance from surface waters, and the degree of surface water/groundwater connectivity between channels and the aquifer. Groundwater chemistry data from monitoring wells at Black Point, a low-altitude, upland setting, are in contrast with conditions observed in Island House observation wells, a high-altitude, upland setting. Specific conductance (less than 200 microsiemens per centimeter [μS/cm]) and pH (greater than 5.0) of groundwater beneath much of the uplands that characterize the Island House observation wells are typical of groundwater in noncarbonate sedimentary aquifers recharged by precipitation. At Black Point, specific conductance ranged from 2,490 to 15,200 μS/cm, and pH ranged from 3.1 to 6.6 standard units. At the Black Point observation wells, the most saline and dense water was at the water table rather than deeper in the aquifer, causing a density inversion that persisted throughout the study. The density inversion likely resulted from differences in permeability between the shallow clay and fine-grained sands and the deeper coarse-grained sand and gravel. Groundwater with the lowest pH was at the water table. As saline groundwater flows through organic sediment beneath the marshes, bacterial biodegradation of organic matter creates anoxic conditions. Continued biodegradation concomitantly reduces iron-oxide minerals in the sediment and sulfate in saline water. When oxygen is reintroduced into groundwater, iron and sulfur can reoxidize to form sulfuric acid, locally lowering the pH of the water. This report describes the groundwater monitoring network design, rationale for site selection, monitoring approach, and results of monitoring from October 2015 through September 2018. Maps of inundation at selected water-level altitudes are included to identify the risk to archaeological, cultural, and ecological resources. The monitoring results of the hydrology and chemistry data are interpreted, and the different hydrologic and chemical settings are described. The implications of the study results for management decisions are presented, and suggestions for improving the monitoring network are included.

Virginia↗
USGS1985

Experimental chemical weathering of various bedrock types at different pH-values. 1. Sandstone and granite

Experimental chemical weathering of the so-called Old Rag Granite and Massanutten Sandstone, Virginia, U.S.A., has produced a comparison with the natural environment, and prediction of the effect of acid precipitation. The experimental results of the release of elements, dissolution of minerals, total rock weathered and the degree of weathering as function of volume of leachate were plotted. These data were compared with the natural environment. The use of the plots to predict the effect of high levels of rain acidity on weathering of these rocks is demonstrated. A nonexpandable 14-Å clay was developed from the alteration of biotite during the experimental chemical weathering of the granite at pH 4. This interstratified Al(OH)—mica clay resembles those of the soil developed on the granite and sandstone. Hydroxy-Al may be precipitating between the mica interlayers and producing a 14-Å spacing. Development of this clay by chemical alteration of biotite may change the current hypotheses about its origin in the soils of northeastern U.S.A. While Al-hydroxide seems to regulate Al concentrations in stream waters at the present level of rain acidity, it was found that at lower pH and in the presence of high sulfate concentrations, Al solubility may be controlled by Al-sulfate phase(s).

Virginia↗
USGS1993

Heavy metal anomalies in the Tinto and Odiel River and estuary system, Spain

The Tinto and Odiel rivers drain 100 km from the Rio Tinto sulphide mining district, and join at a 20-km long estuary entering the Atlantic Ocean. A reconnaissance study of heavy metal anomalies in channel sand and overbank mud of the river and estuary by semi-quantitative emission dc-arc spectrographic analysis shows the following upstream to downstream ranges in ppm (??g g-1): As 3,000 to <200, Cd 30 to <0.1, Cu 1,500 to 10, Pb 2,000 to <10, Sb 3000 to <150, and Zn 3,000 to <200. Organic-rich (1.3-2.6% total organic carbon, TOC), sandysilty overbank clay has been analyzed to represent suspended load materials. The high content of heavy metals in the overbank clay throughout the river and estuary systems indicates the importance of suspended sediment transport for dispersing heavy metals from natural erosion and anthropogenic mining activities of the sulfide deposit. The organic-poor (0.21-0.37% TOC) river bed sand has been analyzed to represent bedload transport of naturally-occurring sulfide minerals. The sand has high concentrations of metals upstream but these decrease an order of magnitude in the lower estuary. Although heavy metal contamination of estuary mouth beach sand has been diluted to background levels estuary mud exhibits increased contamination apparently related to finer grain size, higher organic carbon content, precipitation of river-borne dissolved solids, and input of anthropogenic heavy metals from industrial sources. The contaminated estuary mud disperses to the inner shelf mud belt and offshore suspended sediment, which exhibit metal anomalies from natural erosion and mining of upstream Rio Tinto sulphide lode sources (Pb, Cu, Zn) and industrial activities within the estuary (Fe, Cr, Ti). Because heavy metal contamination of Tinto-Odiel river sediment reaches or exceeds the highest levels encountered in other river sediments of Spain and Europe, a detailed analysis of metals in water and suspended sediment throughout the system, and epidemiological analysis of heavy metal effects in humans is appropriate. ?? 1993 Estuarine Research Federation.

Estuaries↗
USGS2011

Aqueous mineralogy and stratigraphy at and around the proposed Mawrth Vallis MSL Landing Site: New insights into the aqueous history of the region

In this work, we have confirmed the mineralogical stratigraphy previously inferred by other authors, but also demonstrate the presence of additional minerals, including a possible acid-leaching product near the top of the sequence, an Mh-OH bearing phyllosilicate at the to of the sequence, and potentially a Ca-sulfate at the bottom of the phyllosilicate sequence. The latter has important implications regarding the relative timing of sulfate vs clay formation on Mars.

Mars, The International Journal of Mars Science an↗
USGS2008

Geochemical controls of elevated arsenic concentrations in groundwater, Ester Dome, Fairbanks district, Alaska

Ester Dome, an upland area near Fairbanks, Alaska, was chosen for a detailed hydrogeochemical study because of the previously reported elevated arsenic in groundwater, and the presence of a large set of wells amenable to detailed sampling. Ester Dome lies within the Fairbanks mining district, where gold-bearing quartz veins, typically containing 2–3 vol.% sulfide minerals (arsenopyrite, stibnite, and pyrite), have been mined both underground and in open cuts. Gold-bearing veins on Ester Dome occur in shear zones and the sulfide minerals in these veins have been crushed to fine-grained material by syn- or post-mineralization movement. Groundwater at Ester Dome is circumneutral, Ca–HCO 3 to Ca–SO 4 type, and ranges from dilute (specific conductance of 48 µS/cm) to more concentrated (specific conductance as high as 2070 µS/cm). In general, solute concentrations increase down hydrologic gradient. Redox species indicate that the groundwaters range from oxic to sub-oxic (low dissolved oxygen, Fe(III) reduction, no SO 4 reduction). Waters with the highest Fe concentrations, as high as 10.7 mg/L, are the most anoxic. Dissolved As concentrations range from < 1 to 1160 µg/L, with a median value of 146 µg/L. Arsenic concentrations are not correlated with specific conductance or Fe concentrations, suggesting that neither groundwater residence time, nor reductive dissolution of iron oxyhydroxides, control the arsenic chemistry. Furthermore, As concentrations do not covary with other constituents that form anions and oxyanions in solution (e.g., HCO 3 , Mo, F, or U) such that desorption of arsenic from clays or oxides also does not control arsenic mobility. Oxidation of arsenopyrite and dissolution of scorodite, in the near-surface environment appears to be the primary control of dissolved As in this upland area. More specifically, the elevated As concentrations are spatially associated with sulfidized shear zones and localities of gold-bearing quartz veins. Consistent with this interpretation, elevated dissolved Sb concentrations (as high as 59 µg/L), also correlated with occurrences of hypogene sulfide minerals, were measured in samples with high dissolved As concentrations.

Chemical Geology↗
USGS2017

Wisconsin Glaciation of the Sierra Nevada (79,000-15,000 yr B.P.) as recorded by rock flour in sediments of Owens Lake, California

Chemical analyses of the clay-sized fractions of 564 continuous sediment samples (200-yr resolution) from composite core OL90/92 allow quantification of an abundance of glacial rock flour. Rock flour produced during glacier advances is represented by clay-sized plagioclase, K-feldspar, and biotite in homogeneous internal composition. The abundance of rock flour is deemed proportional to the intensity of glacies advances. Age control for the composite section is provided by combining previously published radiocarbon dates on organics, U/Th dates on ostracode shells, and U/Th dates on saline minerals from nearby Searles Lake correlated to OL92 by pollen. The rock flour record displays three levels of variability: (1) a dominant one of about 20,000 yr related to summer insolation and precipitation; (2) an intermediate one of 3000-5000 yr, perhaps related to North Atlantic Heinrich events; and (3) a minor one of 1000-2000 yr, perhaps related to North Atlantic thermohaline-driven air-temperature variation. ?? 2001 University of Washington.

Quaternary Research↗
USGS1964

Origin of precambrian iron formations

A statistical study of the chemical composition of the Precambrian iron formations of the Canadian Shield affords a new approach to the origin of these unusual formations . The average total iron content of 2,200 samples from the literature and from unpublished mining company analyses is 26.7 percent Fe. The average Fe content for 16 iron formations in the United States and Canada ranges from 24.5 to 34.1 percent. Low contents of A1203, Ti02, P2O5, and CaO characterize the Precambrian iron formations compared to the relatively large amounts of these constituents in the post- Precambrian iron -bearing sediments. The chemical data emphasize that whereas iron , manganese, and silica were transported and deposited together in the cherty iron formations of the Precambrian , these same elements were chemically differentiated in younger geological time in large but separate deposits of iron and silica. Isotopic age determinations indicate that cherty iron formations were deposited during a long interval of geologic time from approximately 1,700 to 3,000 million years ago. A model is proposed to explain the origin of the iron formations of the Lake Superior type based on the absence or marked deficiency of free oxygen in the atmosphere prior to the Late Precambrian . Lateritic weathering under these conditions permitted the transport of iron and manganese together with silica. The weathered mantle effectively retained aluminum, titanium, phosphorus, and colloidal clay. Graphitic material of biogenic origin is closely associated with the Precambrian iron formations . Although it is uncertain whether iron was precipitated directly through biologic processes, the removal of C02 and the liberation of oxygen to the sea water through photosynthesis of primitive plants undoubtedly influenced the energy relationships among the iron minerals. As a result of the variable conditions the iron formations commonly are characterized by nonequilibrium mineral assemblages. In Late Precambrian time a critical level of free oxygen in the atmosphere was attained permitting a marked acceleration in plant growth and in accretion of oxygen. This stage in the development of an oxygenated atmosphere was reached at least 1,200 million years ago and effectively curtailed the development of cherty iron formations of the Lake Superior type.

Economic Geology↗
USGS1983

Preliminary appraisal of the hydrology of the Stigler area, Haskell County, Oklahoma

Bed rock in the Stigler area of southeastern Oklahoma consists principally of shale, siltstone, and sandstone of the McAlester, Savanna, and Boggy Formations of Pennsylvanian age. These rocks have been folded to form the Stigler syncline on the north and the Antioch anticline on the south. An area of several square miles is underlain by terrace deposits, mostly sandy silt, as much as 25 feet thick. Alluvium along the streams is 5 to 10 feet thick and consists mainly of sandy silt. Neither the terrace deposits nor the alluvium are hydrologically significant. Water in the bedrock is under artesian conditions. Well depths range from 34 to 235 feet and average 95 feet. The water level in most wells is less than 30 feet below the land surface. Because the rocks have minimal permeability, well yields probably are less than 5 gallons per minute. Much of the area is provided with water by a rural water district. Based on specific-conductance measurements, dissolved-solids concentrations in ground water are estimated to range from 200 to 2,500 milligrams per liter. Nor relationship between variations in specific conductance and well depth, geographic distribution, or geologic formation is apparent. Streams in the area are ephemeral and extended periods of no flow can be expected. During much of the period of record, streamflow in Taloka Creek was maintained by water pumped from an active coal mine. Water upstream from the mine area had a mean dissolved-solids concentration of 72 milligrams per liter whereas water downstream from the mine area had a mean concentration of 1,323 milligrams per liter. At times, downstream concentrations of some toxic metals exceeded the standards for drinking water set by the U.S. Environmental Protection Agency. Samples of water collected from Taloka Creek since mining ceased did not have excessive concentrations of toxic metals. Maximum suspended-sediment discharge of Taloka Creek was about 1,660 tons per day. Silt-clay particles (diameters less than 0.062 millimeter) were the dominant grain size. Observed and measured effects of surface mining for coal on the hydrologic system include (1) creation of additional water storage in the surface mine pond, (2) disruption of drainage in an area of about 1 square mile, and (3) increased mineralization of water in Taloka Creek. Other possible effects include (4) changes in permeability and storage of water in mine spoil, (5) minor changes in streamflow and runoff characteristics, and (6) temporary increase in the sediment load of Taloka Creek.

Water-Resources Investigations Report↗
USGS1973

Gold-bearing arsenian pyrite determined by microprobe analysis, Cortez and Carlin Gold Mines, Nevada

Studies of polished sections and chemical analyses made by electron microprobe show that gold and arsenic in the unoxidized ores from the Cortez and Carlin mines are most abundant in pyrite. Gold, as particles too small to be seen under the microscope, along with arsenic is concentrated in tiny pyrite grains (<0.005 mm) and in thin rims of larger pyrite grains. It is concentrated also in arsenopyrite which is sparsely distributed in the Cortez ore. Traces of gold are contained in sphalerite and chalcopyrite sparsely disseminated in Carlin ore. Mercury and antimony occur also in the pyrite, and antimony is in illite as well. Little if any gold or arsenic is contained in quartz, carbonate, clay, and carbonaceous material. In oxidized ore, the sulfur and carbonaceous material have been removed and gold and arsenic occur in iron oxide pseudomorphs after pyrite. Gold can be seen in the oxidized ore, indicating that it has been mobilized and concentrated. No association was found between gold and the carbonaceous material. During mineralization, calcite was removed from the fractured silty carbonate of the Roberts Mountains Formation, creating micropore space in which pyrite, quartz, and illite were deposited. The average tenor of the pyrite, if all the gold were in the pyrite, would be 0.10 percent at Cortez and 0.14 percent at Carlin. These calculated values are similar to the analytical values. The calculated tenor of the carbonaceous material, however-if such material were considered to be the mineral host of the gold-would be 0.28 percent at Cortez and 1 percent at Carlin. These figures are unreasonable when compared with the analytical data, which show that the carbonaceous material contains no detectable amounts of gold. © 1973 Society of Economic Geologists, Inc.

Nevada↗
USGS2013

Nickel-cobalt laterites: A deposit model

Nickel-cobalt (Ni-Co) laterite deposits are supergene enrichments of Ni±Co that form from intense chemical and mechanical weathering of ultramafic parent rocks. These regolith deposits typically form within 26 degrees of the equator, although there are a few exceptions. They form in active continental margins and stable cratonic settings. It takes as little as one million years for a laterite profile to develop. Three subtypes of Ni-Co laterite deposits are classified according to the dominant Ni-bearing mineralogy, which include hydrous magnesium (Mg)-silicate, smectite, and oxide. These minerals form in weathering horizons that begin with the unweathered protolith at the base, saprolite next, a smectite transition zone only in profiles where drainage is very poor, followed by limonite, and then capped with ferricrete at the top. The saprolite contains Ni-rich hydrous Mg-silicates, the Ni-rich clays occur in the transition horizon, and Ni-rich goethite occurs in the limonite. Although these subtypes of deposits are the more widely used terms for classification of Ni-Co laterite deposits, most deposits have economic concentrations of Ni in more than one horizon. Because of their complex mineralogy and heterogeneous concentrations, mining of these metallurgically complex deposits can be challenging. Deposits range in size from 2.5 to about 400 million tonnes, with Ni and Co grades of 0.66–2.4 percent (median 1.3) and 0.01–0.15 percent (median 0.08), respectively. Modern techniques of ore delineation and mineralogical identification are being developed to aid in streamlining the Ni-Co laterite mining process, and low-temperature and low-pressure ore processing techniques are being tested that will treat the entire weathered profile. There is evidence that the production of Ni and Co from laterites is more energy intensive than that of sulfide ores, reflecting the environmental impact of producing a Ni-Co laterite deposit. Tailings may include high levels of magnesium, sulfate, and manganese and have the potential to be physically unstable.

Scientific Investigations Report↗
USGS1979

Mineral resources of the Citico Creek Wilderness Study Area, Monroe County, Tennessee

The proposed Citico Creek Wilderness comprises about 5,670 hectares (56.7 km2) in the Cherokee National Forest south of the Little Tennessee River in easternmost Monroe County, Tennessee. Principal drainages are Citico Creek and Doublecamp Creek. Rocks of the study area include greenschist-facies arkosic metasandstone, metagraywacke, slate, and metaconglomerate of the Great Smoky Group of late Precambrian age. Minor deposits of unconsolidated Quaternary alluvium locally mantle the bedrock. Deformation is shown by asymmetric and overturned folds and by several major faults. More than 500 sample s of soil, rock, and stream sediment were collected and analyzed for 31 major, minor, and trace elements by semiquantitative spectrographic, atomic absorption, and fire assay methods No significant metal anomalies were detected. Concentrations of Cu, Co, As, Pb, and Zn slightly higher than background are found within sulfidic parts of a distinctive stratigraphic unit composed of graphitic slate and metagraywacke. Pyrite and pyrrhotite are the chief sulfide minerals, with traces o f accessory sphalerite, chalcopyrite, galena, and arsenopyrite occurring as microscopic intergrowths. A reconnaissance ground radiometric survey and subsequent neutron activation analyses of selected radioactive rock samples show that the sulfidic parts of the graphitic slate unit have a relatively high content of Th and U, but are not potentially economic. No metallic mineral resources appear to exist within the Citico Creek Wilderness Study Area. Resources of slate, silica, and stone are present, but they display no special qualities to differentiate them from other such material throughout the region. Ceramic evaluation tests on selected samples of slate indicate that the slate would have only marginal use for structural clay products such as brick and tile. Minor sand and gravel deposits occur along a few streams but are present in larger quantities and are more easily recovered in other areas.

Tennessee↗
USGS1971

Selected fluvial monazite deposits in the southeastern United States

Farther southwest in Georgia, around Griffin and Zebullon, along streams tributary to the Flint River in the monazite belt the flood plains are generally small and discontinuous, and only about 1 percent of the sediment is gravel. The area between Griffin, Zebullon, and the Flint River is underlain by biotite schist and biotite gneiss into which biotite granite has been intruded. Only along one stream, Flat Creek, which drains monazite-bearing granite near Zetella, Ga., are the tenors in monazite even moderately high, but a combination of thick, clayey overburden and discontinuous flood plains make the stream unsuitable for placer mining. Elsewhere in the Flint River area the heavy-mineral concentrates contain less than 1 percent monazite. The southwesternmost area in which reconnaissance of the monazite belt was conducted includes a groups of southwest-flowing tributaries to the Chattahoochee River north of Pine Mountain and near La Grange, Ga. A combination of three characteristics of the alluvium make the area unfavorable for mining: (1) the upper half of the sedimentary sequence is clay and silt, (2) there is scant gravel, and (3) much of the sand is fine grained. Monazite is associated with the Snelson Granite, schists, and gneisses north of the Towaliga fault, but even in this area the tenor of most riffle sediments is only 0.1 to 0.5 pound of monazite per cubic yard, and the average tenor of the alluvium is about 0.2 pound per cubic Yard. Rocks south of the Towaliga fault contain scant monazite. The monazite-bearing area in the drainage basin of the Chattahoochee River has no monazite placers. Evidence from the areas on the Flint and Chattahoochee Rivers shows that streams in western Georgia are a much poorer source of monazite than streams farther to the northeast in Georgia, South Carolina, and North Carolina. Also, the northeastern part of the belt in the drainage basins of the Yadkin and Dan Rivers is a poorer source for monazite than the area between the Savannah and Catawba Rivers, S.C.-N.C. Monazite-bearing crystalline rocks in the western belt contain about 0.06 pound of monazite per cubic yard. Residual soil derived from the crystalline rocks contains about 0.3 to 0.4 pound of monazite per cubic yard, and colluvial sediments formed by sheet-wash from saprolite, residual soil, and, rarely, old stream deposits, have an average of 3.1 pounds of monazite to the cubic yard. The data on the tenors of residual and colluvial deposits are far less comprehensive than those an the quantity of monazite in the crystalline rocks, but the tenors are probably of the correct order of magnitude. Neither the crystalline rocks nor the residual soils are ores of monazite. Because the colluvial deposits are thin and have patch distribution they could not be mined independently, but some colluvium could be stripped from the adjoining hills in conjunction with the mining of alluvial deposits in the valleys. It is most unlikely that alluvial monazite placers have formed in the trunk streams leading southeastward out of the monazite belt. Churn drilling on the Broad and North Tyger Rivers, South Carolina, at the east edge of the belt has shown that the bulk of the alluvium is fine-grained sediment that contains 0.2 to 0.4 pound of monazite per cubic yard--tenors that represent no considerable enrichment over those in the crystalline rocks and residual soils. The probable persistence of predominantly fine-grained alluvium downstream to the Coastal Plain and the certain dilution of monazite-bearing concentrates by the inflow of monazite-free suites of heavy minerals between the belt and the fall line suggest that the trunk streams east of the belt are the least favorable sources for alluvial monazite in the Piedmont?

Open-File Report↗
USGS2023

Stratigraphic architecture and fluvial interpretations of the Upper Cretaceous (Turonian?) Middendorf Formation, Chesterfield County, South Carolina, U.S.A.

The Upper Cretaceous (Turonian?) Middendorf Formation is a sand-rich stratigraphic unit of fluvial origin that forms a large aquifer in the U.S. Atlantic Coastal Plain. In Chesterfield County (South Carolina), which is the site of the type locality, the formation ranges in thickness from 66.5 to > 119.7 meters. The base of the formation is an unconformity above Paleozoic metasiltstone, and the upper contact is an unconformity above which lies sand of the Quaternary Pinehurst Formation. Outcrops display the following five facies assemblages: 1) sandstone to conglomeratic sandstone (fluvial bar and channel deposits), 2) beds of alternating laminae of sandstone and mudstone (fluvial overbank or floodplain deposits), 3) ≥ 1 m-thick beds of clay (swamp deposits, floodplain deposits, and/or sediment that accumulated in abandoned fluvial channels), 4) 0.2–0.5 m-thick planar to slightly undulatory beds of framework-supported sandstone with a mud matrix (traction-dominated current deposits at the top of fluvial bars, upper-flow-regime bedform deposits in subsidiary fluvial channels, or coarse-grained overbank deposits), and 5) sandstone to conglomeratic sandstone cemented by iron (interpreted as fluvial bar and channel deposits, with the iron cement being a diagenetic “groundwater ferricrete” that formed via the circulation of shallow groundwater and the oxidation of iron-bearing minerals). Kaolinite in various forms is pervasive throughout the formation and is interpreted as an early diagenetic phenomenon that formed by prolonged postdepositional weathering and flushing by meteoric water under a warm and humid paleoclimate. The fluvial system that formed the Middendorf Formation prograded into the area from the west or northwest from uplifted margins of Mesozoic rift basins and/or the Appalachian Mountains. This progradation was a response to a base-level fall and the sediment accumulated during base-level lowstand and subsequent early transgression. In Chesterfield County, the Middendorf Formation can be subdivided into three fining-upward sequences. Each sequence consists predominantly of medium to coarse sand with a greater abundance of gravel in the lower part of the sequence and a greater abundance of clay and silt beds in the upper part. Each sequence is interpreted as either a response to autogenic processes or a response to allogenic sea-level changes, specifically a higher-order (higher-frequency) progression from relative lowstand conditions to early transgression whereby coarse sand and gravel (e.g., fluvial bar and channel deposits) were preserved during initial lowstand conditions and a greater proportion of mud and finer-grained sand (floodplain deposits) were preserved during subsequent early transgression. The Middendorf Formation is correlative with several other kaolinite-rich fluvial sandstones in North America including the Raritan Formation in New Jersey, the Tuscaloosa Formation of the eastern Gulf of Mexico (Alabama, Mississippi, Louisiana), the Woodbine Formation of the central Gulf of Mexico (Texas), and the Frontier Formation of Wyoming. The accumulation and preservation of these formations occurred in response to a Turonian eustatic sea-level fall and subsequent transgression, and the early diagenetic kaolinite in these formations is attributed to similar warm and humid paleoclimate conditions.

South Carolina↗
USGS1979

Geology and industrial mineral resources of the Macon-Gordon kaolin district, Georgia

The Macon-Gordon kaolin district is about 80 miles (130 km) southeast of Atlanta, Georgia. It extends across the boundary between, and includes parts of, the Piedmont and Atlantic Coastal Plain physiographic provinces. The rocks in the Piedmont are mainly intensely folded sericite schist and granite gneiss containing irregular masses of amphibolite and feldspathic biotite gneiss and scattered igneous intrusive rocks. Most of the crystalline rocks are thought to be of Paleozoic age, but some of the intrusive rocks may be younger. The crystalline rocks are cut by a major unconformity and are overlain by sedimentary formations ranging in age from Cretaceous to Miocene. The valuable kaolin deposits occur in the Cretaceous beds, undivided, and in the Huber Formation which is of Paleocene to middle Eocene age. The resources of kaolin in the district are estimated in millions of metric tons as follows: reserves, 100; subeconomic resources, 700 to 900; undiscovered resources, probably 700 to 1,000. In addition to kaolin, the leading mineral commodity mined in the district, crushed stone and sand are now being produced, and fuller's earth and a minor amount of limestone were formerly produced. The crushed stone is quarried from igneous rocks in the Piedmont province. The sand is washed from the Cretaceous beds, undivided. The fuller's earth was mined from the Twiggs Clay Member of the Barnwell Formation, and limestone was dug from the Tivola Limestone.

Georgia↗
USGS2004

Summary of the hydrogeology of the Valley and Ridge, Blue Ridge, and Piedmont Physiographic Provinces in the eastern United States

The Appalachian Valley and Piedmont Regional Aquifer-System Analysis study (1988-1993) analyzed rock types in the 142,000-square-mile study area, identified hydrogeologic terranes, determined transmissivity distributions, determined the contribution of ground water to streamflow, modeled ground-water flow, described water quality, and identified areas suitable for the potential development of municipal and industrial ground-water supplies. Ground-water use in the Valley and Ridge, the Blue Ridge, and the Piedmont Physiographic Provinces exceeds 1.7 billion gallons per day. Thirty-three rock types in the study area were analyzed, and the rock types with similar water-yielding characteristics were combined and mapped as 10 hydrogeologic terranes. Based on well records, the interquartile ranges of estimated transmissivities are between 180 to 17,000 feet squared per day (ft 2 /d) for five hydrologic terranes in the Valley and Ridge; between 9 to 350 ft 2 /d for two terranes in the Blue Ridge; and between 9 to 1,400 ft 2 /d for three terranes in the Piedmont Physiographic Province. Based on streamflow records, the interquartile ranges of estimated transmissivities for all three physiographic provinces are between 290 and 2,900 ft 2 /d. The mean ground-water contribution to streams from 157 drainage basins ranges from 32 to 94 percent of mean streamflow with a median of 67 percent. In three small areas in two of the physiographic provinces, more than 54 percent of ground-water flow was modeled as shallow and local. Although ground-water chemical composition in the three physiographic provinces is distinctly different, the water generally is not highly mineralized, with a median dissolved-solids concentration of 164 milligrams per liter, and is mostly calcium, magnesium, and bicarbonate. Based on aquifer properties and current pumpage, areas favorable for the development of municipal and industrial ground-water supplies are underlain by alluvium of glacial origin near the northeastern part of the study area, by clay-free carbonate rocks primarily in the Valley and Ridge Physiographic Province, and by siliciclastic rocks in the three northernmost Mesozoic basins.

Alabama, Delaware, Georgia, Maryland, New Jersey, ↗
USGS1974

Geology and mineralogy of phosphate rock in the Bambui group near Cedro do Abaete and vicinity, Minas Gerais, Brazil

Discontinuous lenticular masses of phosphate rock are present near or at the contact between the green mudstone and the underlying red and yellow clay-stone units of the Serra da Saudade Member of the Rio Paraopeba Formation of the Bambui Group of late Precambrian to early Paleozoic age. The lenses are as much as 8 meters thick and 400 meters long. The phosphate rock is folded and faulted and is overlain by flat-lying rocks of Cretaceous age. The phosphate mineral is a carbonate fluorapatite, but only a small amount of C0 2 substitutes for PO 4 . Crystalline apatite in veinlets is clearly younger than the groundmass apatite, and contains almost no C0 2 . Surficial parts of the phosphate lenses have been altered to a rock characterized by aluminum phosphate. Samples of the green mudstone contain muscovite-illite, quartz, and what is believed to be glauconite. Samples collected adjacent to the phosphate lenses also contain veinlets of apatite or wavellite. Chemical analyses of the phosphate rock show that it contains from 16 to 35 percent P 2 0 5 , and all samples are deficient in Ca0 relative to P 2 0 5 , indicating that some of the phosphate in all samples is combined with alumina. The samples contain as much as 8 percent K 2 0 in the minerals muscovite-illite or glauconite. All the samples collected are extremely fine grained. The rocks are laminated and show the effects of slight deformation; for example, crumpled bedding, offset veinlets, and slight development of muscovite along bedding planes. The phosphate probably is not economically important on the world market, but possibly could be used locally for direct application depending on agricultural lands.

Minas Gerais↗
USGS2006

A 16-year record of eolian dust in Southern Nevada and California, USA: Controls on dust generation and accumulation

An ongoing project monitors modern dust accumulation in the arid southwestern United States to (1) determine the rate and composition of dust inputs to soils and (2) relate dust accumulation to weather patterns to help predict the effects of climate change on dust production and accumulation. The 16-year records of 35 dust-trap sites in the eastern Mojave Desert and southern Great Basin reveal how generation and accumulation of dust, including the silt-clay, carbonate, and soluble-salt fractions, is affected by the amount and seasonal distribution of rainfall and the behavior of different source types (alluvium, dry playas, and wet playas). Accumulation rates (fluxes) of the silt-clay fraction of dust, including carbonates, range from about 2-20 g/m2/yr. Average rates are higher in the southern part of the study area (south of latitude 36.5??N) and annually fluctuate over a larger range than rates in the northern part of the area. Sites throughout the study area show peaks in dust flux in the 1984-1985 sampling period and again in 1997-1999; northern sites also show increased flux in 1987-1988 and southern sites in 1989-1991. These peaks of dust flux correspond with both La Nina (dry) conditions and with strong El Nino (wet) periods. The accumulation rates of different components of mineral dusts fluctuate differently. For example, soluble-salt flux increases in 1987-1988, coincident with a moderate El Nino event, and increases very strongly in 1997-1999, overlapping with a strong El Nino event. Both of these high-rainfall winters were preceded and accompanied by strong summer rains. In contrast, little or no change in soluble-salt flux occurred during other periods of high winter rainfall but little summer rain, e.g. 1992-1995. The differences between northern vs. southern sites and between sites with playa dust sources vs. alluvial dust sources indicate that regional differences in the response of precipitation and vegetation growth to ENSO influence and differences in the response of source types control dust production and accumulation. A major factor is the hydrologic condition of surface sediments. The silt-clay and soluble-salt fluxes increased during the El Nino events of 1987-1988 and 1997-1998 at sites close to "wet" playas with shallow depths to groundwater (<10 m), consistent with the concept that active evaporative concentration of salts disrupts surface crusts and increases the susceptibility of surface sediment to deflation. The silt-clay flux also increased during drought periods (1989-1991, 1995-1997) at sites downwind of alluvial sources and "dry" playas with deeper groundwater (<10 m). These increases are probably related to the die-off of drought-stressed vegetation on alluvial sediments, and in some cases to local runoff events that deliver fresh sediment to playa margins and distal portions of alluvial fans. ?? 2006 Elsevier Ltd. All rights reserved.

Journal of Arid Environments↗
USGS2008

Hydrated silicate minerals on Mars observed by the Mars Reconnaissance Orbiter CRISM instrument

Phyllosilicates, a class of hydrous mineral first definitively identified on Mars by the OMEGA (Observatoire pour la Mineralogie, L’Eau, les Glaces et l’Activitié) instrument 1 , 2 , preserve a record of the interaction of water with rocks on Mars. Global mapping showed that phyllosilicates are widespread but are apparently restricted to ancient terrains and a relatively narrow range of mineralogy (Fe/Mg and Al smectite clays). This was interpreted to indicate that phyllosilicate formation occurred during the Noachian (the earliest geological era of Mars), and that the conditions necessary for phyllosilicate formation (moderate to high pH and high water activity 3 ) were specific to surface environments during the earliest era of Mars’s history 4 . Here we report results from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) 4 of phyllosilicate-rich regions. We expand the diversity of phyllosilicate mineralogy with the identification of kaolinite, chlorite and illite or muscovite, and a new class of hydrated silicate (hydrated silica). We observe diverse Fe/Mg-OH phyllosilicates and find that smectites such as nontronite and saponite are the most common, but chlorites are also present in some locations. Stratigraphic relationships in the Nili Fossae region show olivine-rich materials overlying phyllosilicate-bearing units, indicating the cessation of aqueous alteration before emplacement of the olivine-bearing unit. Hundreds of detections of Fe/Mg phyllosilicate in rims, ejecta and central peaks of craters in the southern highland Noachian cratered terrain indicate excavation of altered crust from depth. We also find phyllosilicate in sedimentary deposits clearly laid by water. These results point to a rich diversity of Noachian environments conducive to habitability.

Nature↗