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Groundwater quality in the Santa Clara River Valley, California

The Santa Clara River Valley (SCRV) study unit is located in Los Angeles and Ventura Counties, California, and is bounded by the Santa Monica, San Gabriel, Topatopa, and Santa Ynez Mountains, and the Pacific Ocean. The 460-square-mile study unit includes eight groundwater basins: Ojai Valley, Upper Ojai Valley, Ventura River Valley, Santa Clara River Valley, Pleasant Valley, Arroyo Santa Rosa Valley, Las Posas Valley, and Simi Valley (California Department of Water Resources, 2003; Montrella and Belitz, 2009). The SCRV study unit has hot, dry summers and cool, moist winters. Average annual rainfall ranges from 12 to 28 inches. The study unit is drained by the Ventura and Santa Clara Rivers, and Calleguas Creek. The primary aquifer system in the Ventura River Valley, Ojai Valley, Upper Ojai Valley, and Simi Valley basins is largely unconfined alluvium. The primary aquifer system in the remaining groundwater basins mainly consists of unconfined sands and gravels in the upper portion and partially confined marine and nonmarine deposits in the lower portion. The primary aquifer system in the SCRV study unit is defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the California Department of Public Health (CDPH) database. Public-supply wells typically are completed in the primary aquifer system to depths of 200 to 1,100 feet below land surface (bls). The wells contain solid casing reaching from the land surface to a depth of about 60-700 feet, and are perforated below the solid casing to allow water into the well. Water quality in the primary aquifer system may differ from the water in the shallower and deeper parts of the aquifer. Land use in the study unit is approximately 40 percent (%) natural (primarily shrubs, grassland, and wetlands), 37% agricultural, and 23% urban. The primary crops are citrus, avocados, alfalfa, pasture, strawberries, and dry beans. The largest urban areas in the study unit are the cities of Ventura, Oxnard, Camarillo, Simi Valley, Newhall, and Santa Clarita. Currently, groundwater pumping for agricultural use accounts for the greatest amount of discharge from the aquifer system in the SCRV study unit, followed by municipal use. Recharge to the groundwater system is through stream-channel infiltration from the three main river systems and by direct infiltration of precipitation and irrigation. Recharge facilities in the Oxnard forebay play an important role in recharging the local aquifer systems.

Fact Sheet↗

Four-dimensional isotopic approach to identify perchlorate sources in groundwater: Application to the Rialto-Colton and Chino subbasins, southern California (USA)

Perchlorate (ClO 4 − ) in groundwater can be from synthetic or natural sources. Natural sources include ClO 4 − associated with historical application of imported natural nitrate fertilizer from the Atacama Desert of Chile, and indigenous ClO 4 − that accumulates locally in arid regions from atmospheric deposition. The Rialto-Colton groundwater subbasin, 80 km east of Los Angeles, California, includes two mapped ClO 4 − plumes from known military/industrial sources. Larger areas downgradient from those plumes, and in the Chino subbasin to the southwest, also contain ClO 4 − . Perchlorate from wells was analyzed for chlorine and oxygen stable isotope ratios (δ 37 Cl, δ 18 O, Δ 17 O) and radioactive chlorine-36( 36 Cl) isotopic abundance, along with other geochemical, isotopic, and hydrogeologic data. Isotopic data show that synthetic ClO 4 − was the dominant source within the mapped plumes. Downgradient from the mapped plumes, and in the Chino subbasin, the dominant source of ClO 4 − was related to past agricultural use of Chilean (Atacama) nitrate fertilizer. The 36 Cl and δ 18 O data indicate that wells having predominantly synthetic or Atacama ClO 4 − also contained small fractions of indigenous ClO 4 − . Little or no differences were observed in isotopic composition or ClO 4 − source with depth in depth-dependent data from selected wells. Indigenous ClO 4 − was most evident in upgradient wells having ClO 4 − concentrations <1 μg/L, consistent with its occurrence as a background constituent throughout the region. Stable isotope ratios of chlorine and oxygen and 36 Cl isotopic abundance data provided relatively unambiguous discrimination of synthetic and Atacama sources in most wells having ClO 4 − concentrations greater than 1 μg/L.

California↗

Geohydrology and water chemistry of the Alexander Valley, Sonoma County, California

This study of the geohydrology and water chemistry of the Alexander Valley, California, was done to provide an improved scientific basis for addressing emerging water-management issues, including potential increases in water demand and changes in flows in the Russian River. The study tasks included (1) evaluation of existing geohydrological, geophysical, and geochemical data; (2) collection and analysis of new geohydrologic data, including subsurface lithologic data, ground-water levels, and streamflow records; and (3) collection and analysis of new water-chemistry data. The estimated total water use for the Alexander Valley for 1999 was approximately 15,800 acre-feet. About 13,500 acre-feet of this amount was for agricultural use, primarily vineyards, and about 2,300 acre-feet was for municipal/industrial use. Ground water is the main source of water supply for this area. The main sources of ground water in the Alexander Valley are the Quaternary alluvial deposits, the Glen Ellen Formation, and the Sonoma Volcanics. The alluvial units, where sufficiently thick and saturated, comprise the best aquifer in the study area. Average recharge to the Alexander Valley is estimated from a simple, basinwide water budget. On the basis of an estimated annual average of 298,000 acre-feet of precipitation, 160,000 acre-feet of runoff, and 113,000 to 133,000 acre-feet of evapotranspiration, about 5,000 to 25,000 acre-feet per year is available for ground-water recharge. Because this estimate is based on differences between large numbers, there is significant uncertainty in this recharge estimate. Long-term changes in ground-water levels are evident in parts of the study area, but because of the sparse network and lack of data on well construction and lithology, it is uncertain if any significant changes have occurred in the northern part of the study area since 1980. In the southern half of the study area, ground-water levels generally were lower at the end of the 2002 irrigation season than at the end of the 1980 season, which suggests that a greater amount of ground water is being pumped in the southern half of the study area in recent years compared with that pumped in the early 1980s. Water-chemistry data for samples collected from 11 wells during 2002-04 indicate that water quality in the study area generally is acceptable for potable use. Two wells, however, each contained one constituent (241 ?g/L of manganese and 1,350 ?g/L of boron) in excess of the recommended standards for drinking water (50 ?g/L and 1,000 ?g/L, respectively). The chemical composition of water from most of the wells sampled for major ions plot as a mixed cation-bicarbonate, magnesium-bicarbonate, or calcium-bicarbonate type water. The ionic composition of the historical and recent samples from wells in the Alexander Valley is similar to that of the historical surface-water samples collected from the Russian River near Healdsburg. This suggests a similar source of water, particularly for wells that are less than 200 feet total depth and perforated in Quaternary alluvial deposits. Water from deeper, non-alluvial wells may contain slightly higher concentrations of sodium as a result of cation exchange. Water samples collected from several wells over an approximately 30-year period suggest a progressive change in water chemistry over time. Samples from the southern part of the valley show a trend towards higher ionic concentrations and increasing concentrations of particular constituents such as sulfate.

California↗

Water quality in the Santa Ana Basin, California, 1999-2001

This report contains the major findings of a 1999-2001 assessment of water quality in the Santa Ana River Basin. It is one of a series of reports by the National Water-Quality Assessment (NAWQA) Program that present major findings in 51 major river basins and aquifer systems across the Nation. In these reports, water quality is discussed in terms of local, State, and regional issues. Conditions in a particular basin or aquifer system are compared to conditions found elsewhere and to selected national benchmarks, such as those for drinking-water quality and the protection of aquatic organisms. This report is intended for individuals working with water-resource issues in Federal, State, or local agencies, universities, public interest groups, or in the private sector. The information will be useful in addressing a number of current issues, such as the effects of agricultural and urban land use on water quality, human health, drinking water, source-water protection, hypoxia and excessive growth of algae and plants, pesticide registration, and monitoring and sampling strategies. This report is also for individuals who wish to know more about the quality of streams and ground water in areas near where they live and how that water quality compares to other areas across the Nation. The water-quality conditions in the Santa Ana River Basin summarized in this report are discussed in detail in other reports that can be accessed from http://ca.water.usgs.gov/ sana_nawqa/. Detailed technical information, data and analyses, collection and analytical methodology, models, graphs, and maps that support the findings presented in this report in addition to other reports in this series from other basins can be accessed from the national NAWQA Web site (http://water.usgs.gov/nawqa).

Circular↗

Organic matter sources and rehabilitation of the Sacramento-San Joaquin Delta (California, USA)

1. The Sacramento San Joaquin River Delta, a complex mosaic of tidal freshwater habitats in California, is the focus of a major ecosystem rehabilitation effort because of significant long-term changes in critical ecosystem functions. One of these functions is the production, transport and transformation of organic matter that constitutes the primary food supply, which may be sub-optimal at trophic levels supporting fish recruitment. A long historical data set is used to define the most important organic matter sources, the factors underlying their variability, and the implications of ecosystem rehabilitation actions for these sources. 2. Tributary-borne loading is the largest organic carbon source on an average annual Delta-wide basis; phytoplankton production and agricultural drainage are secondary; wastewater treatment plant discharge, tidal marsh drainage and possibly aquatic macrophyte production are tertiary; and benthic microalgal production, urban run-off and other sources are negligible. 3. Allochthonous dissolved organic carbon must be converted to particulate form - with losses due to hydraulic flushing and to heterotroph growth inefficiency - before it becomes available to the metazoan food web. When these losses are accounted for, phytoplankton production plays a much larger role than is evident from a simple accounting of bulk organic carbon sources, especially in seasons critical for larval development and recruitment success. Phytoplankton-derived organic matter is also an important component of particulate loading to the Delta. 4. The Delta is a net producer of organic matter in critically dry years but, because of water diversion from the Delta, transport of organic matter from the Delta to important, downstream nursery areas in San Francisco Bay is always less than transport into the Delta from upstream sources. 5. Of proposed rehabilitation measures, increased use of floodplains probably offers the biggest increase in organic matter sources. 6. An isolated diversion facility - channelling water from the Sacramento River around the Delta to the water projects - would result in substantial loading increases during winter and autumn, but little change in spring and summer when food availability probably matters most to developing organisms. 7. Flow and fish barriers in the channel could have significant effects, especially on phytoplankton sources and in dry years, by eliminating 'short-circuits' in the transport of organic matter to diversion points. 8. Finally, productivity of intentionally flooded islands probably would exceed that of adjacent channels because of lower turbidity and shallower mean depth, although vascular plants rather than phytoplankton could dominate if depths were too shallow.

California↗

Search for geothermal seismic noise in the East Mesa area, Imperial Valley, California

The U. S. Geological Survey made seismic noise measurements in the East Mesa area of Imperial Valley, California, to find out if a noise anomaly was associated with the Mesa thermal anomaly. Thirty-three locations were occupied in the area using slow-speed tape-recording seismic systems. One of the stations (CEN) was operated close to where a geothermal test well was subsequently drilled by the U. S. Bureau of Reclamation. Several sources of cultural noise are present in the area. Large fluctuations in noise level, superposed on a constant high level of noise, occur from traffic on a freeway to the south of the region. There is noise generated by canals to the west and south and agricultural activity to the west of the region. Noise at 2.5 Hz frequency generated by a small waterfall (power drop) on the All American Canal propagates as far as 10 km. Average noise levels were computed at each station using several quiet samples selected from 4-hour sections of data recorded at night and contoured. Spatial distribution of 2-3 Hz noise show noise radiating from the power drop. Noise in 0-2, 3-5, and 5-10 Hz bands show high levels extending along the freeway to the south and East High Line Canal to the west of the area. The Mesa thermal anomaly is centered about 2.5 km from the freeway and canal and does not seem to have any anomalous noise amplitudes associated with it. Additional results using data from two arrays of closely-spaced instruments extending from the freeway to the Mesa thermal anomaly also show no indications of high noise levels over the anomaly. This conclusion differs from the results of two previous surveys in the area (Douze and Sorrells, 1972; Geothermal Staff of Teledyne-Geotech, 1972) which show well defined noise anomalies in the 0-2, and 3-5 Hz frequency bands. A search was also made for anomalous features in noise spectra and for coherent wave trains indicating the presence of discrete sources of noise. The only predominant feature in the spectra is the 2.5 Hz peak seen at most stations, from noise generated by the power drop. Records from several three-element, L-shaped arrays with 0.3 km instrument spacing show very little visual coherence. Measurements using a cross-spectral method, however, show that highly coherent waves are found at 0.4 and 2.5 Hz; coherence is less, though significant, at 3.4 and 4.4 Hz; direction studies using phase delays from the arrays give many non-unique solutions, as the array spacing is larger than the wavelengths involved. Using the knowledge that 2.5 Hz waves are generated by the power drop, the velocity of seismic noise waves in the East Mesa area is estimated to be 0.5 km/sec.

California↗

Environmental Setting of the Lower Merced River Basin, California

In 1991, the U.S. Geological Survey began to study the effects of natural and anthropogenic influences on the quality of ground water, surface water, biology, and ecology as part of the National Water-Quality Assessment (NAWQA) Program. As part of this program, the San Joaquin-Tulare Basins study unit is assessing parts of the lower Merced River Basin, California. This report provides descriptions of natural and anthropogenic features of this basin as background information to assess the influence of these and other factors on water quality. The lower Merced River Basin, which encompasses the Mustang Creek Subbasin, gently slopes from the northeast to the southwest toward the San Joaquin River. The arid to semiarid climate is characterized by hot summers (highs of mid 90 degrees Fahrenheit) and mild winters (lows of mid 30 degrees Fahrenheit). Annual precipitation is highly variable, with long periods of drought and above normal precipitation. Population is estimated at about 39,230 for 2000. The watershed is predominately agricultural on the valley floor. Approximately 2.2 million pounds active ingredient of pesticides and an estimated 17.6 million pounds active ingredient of nitrogen and phosphorus fertilizer is applied annually to the agricultural land.

Scientific Investigations Report↗

The occurrence of trace elements in bed sediment collected from areas of varying land use and potential effects on stream macroinvertebrates in the conterminous western United States, Alaska, and Hawaii, 1992-2000

As part of the National Water-Quality Assessment Program of the U.S. Geological Survey, this study examines the occurrence of nine trace elements in bed sediment of varying mineralogy and land use and assesses the possible effects of these trace elements on aquatic-macroinvertebrate community structure. Samples of bed sediment and macroinvertebrates were collected from 154 streams at sites representative of undeveloped, agricultural, urban, mined, or mixed land-use areas and 12 intermediate-scale ecoregions within the conterminous western United States, Alaska, and Hawaii from 1992 to 2000. The nine trace elements evaluated during this study—arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), mercury (Hg), nickel (Ni), selenium (Se), and zinc (Zn)—were selected on the basis of potential ecologic significance and availability of sediment-quality guidelines. At most sites, the occurrence of these trace elements in bed sediment was at concentrations consistent with natural geochemical abundance, and the lowest concentrations were in bed-sediment samples collected from streams in undeveloped and agricultural areas. With the exception of Zn at sampling sites influenced by historic mining-related activities, median concentrations of all nine trace elements in bed sediment collected from sites representative of the five general land-use areas were below concentrations predicted to be harmful to aquatic macroinvertebrates. The highest concentrations of As, Cd, Pb, and Zn were in bed sediment collected from mined areas. Median concentrations of Cu and Ni in bed sediment were similarly enriched in areas of mining, urban, and mixed land use. Concentrations of Cr and Ni appear to originate largely from geologic sources, especially in the western coastal states (California, Oregon, and Washington), Alaska, and Hawaii. In these areas, naturally high concentrations of Cr and Ni can exceed concentrations that may adversely affect aquatic macroinvertebrates. Generally, Hg concentrations were below the sediment-quality guideline for this trace element but appeared elevated in urbanized areas and at sites contaminated by historic mining practices. Lastly, although there was no distinctive pattern in Se concentrations with land use, median bed-sediment concentrations were slightly elevated in urbanized areas. Macroinvertebrate community structure was influenced by topographic, geologic, climatic, and in-stream characteristics. To account for inherent distribution patterns resulting from these influences, samples of macroinvertebrates were stratified by ecoregion to assess the influence of trace elements on community structure. Cumulative toxic units (CTUs) were used to evaluate gradients in trace-element concentrations in mixture. Correlation analyses among the trace elements under different land-use conditions indicate that trace-element mixtures vary among bed sediment and can have a marked influence on CTU composition. Macroinvertebrate response to bed-sediment trace-element exposure was evident only at the most highly contaminated sites, notably at sites classified as contaminated by the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) as a result of historic mining activities. Results of this study agree with the findings of other studies evaluating trace-element exposure to in-stream macroinvertebrate community structure in that generally lower richness metrics and taxa dominance occur in streams where high trace-element enrichment occurs; however, not all streams in all areas have the same characterizing taxa. In the mountain and xeric ecosystems, the mayfly, Baetis sp.; the Diptera, Simulium sp.; caddisflies in the family Hydropsychiidae; midges in the family Orthocladiinae; and the worms belonging to Turbellaria and Naididae all demonstrated resilience to trace-element exposure and, in some cases, possible changes in physical habitat within stream ecosystems. The taxa characteristics within the Ozark Highland ecoregion were different than other ecoregions as evidenced by generally more diverse mayfly populations. In addition, Baetis sp. was common and dominated many of the mayfly populations found in the Rocky Mountain streams within the Mountain Southern Rockies and Mountain Northern Rockies ecoregions; however, within the Ozark Highland ecoregion, Tricorythodes sp. appeared to be more common than Baetis sp.

Alaska, Arizona, California, Colorado, Hawai'i, Id↗

Anthropogenic and geologic causes of anomalously high uranium concentrations in groundwater used for drinking water supply in the southeastern San Joaquin Valley, CA

Concentrations of uranium (U) >30 µg/L in groundwater are relatively uncommon in drinking water in the United States but can be of concern in those areas where complex interactions of aquifer materials and anthropogenic alterations of the natural flow regime mobilize uranium. High concentrations (>30 µg/L) of U in the southeastern San Joaquin Valley, California, USA, have been detected in 24 percent of 257 domestic, irrigation, and public-supply wells sampled across an approximately 110,000 km2 area. The location of high concentrations depends on the interactions of U sources from fluvial fans that originate in the Sierra Nevada to the east and seepage of irrigation water that contains high concentrations of HCO3 that leaches U from the sediments. In addition, interactions with phosphate (PO4) from fertilized irrigated fields may sequester U in the aquifer. Principal component analysis of the data demonstrates that HCO3 and ions associated with high total dissolved solids in the aquifer and the percentage of agriculture near the well sampled are associated with high U concentrations. Nitrate concentrations do not appear to control release of U to the aquifer. Age dating of the groundwater and generally increasing U concentrations of the past 25 years in resampled wells where irrigation is prevalent suggests that high U concentrations are associated with younger water, indicating that irrigation of fields over the past 100 years has significantly contributed to increasing concentrations and mobilizing U. In some places, the groundwater is supersaturated with uranyl-containing minerals, as would be expected in roll front deposits. In general, the interaction of natural geological sources high in U, the anthropogenically driven addition of HCO3 and possibly phosphate fertilizer, control the location and concentration of U in each individual fluvial fan, but the addition of nitrate in fertilizer does not appear control the location of high U. These geochemical interactions can be used to determine controls on anomalously high U in alluvial aquifers

California↗

Concentration, UV-spectroscopic characteristics and fractionation of DOC in stormflow from an urban stream, Southern California, USA

The composition of dissolved organic carbon (DOC) in stormflow from urban areas has been greatly altered, both directly and indirectly, by human activities and there is concern that there may be public health issues associated with DOC, which has unknown composition from different sources within urban watersheds. This study evaluated changes in the concentration and composition of DOC in stormflow in the Santa Ana River and its tributaries between 1995 and 2004 using a simplified approach based on the differences in the optical properties of DOC and using operationally defined differences in molecular weight and solubility. The data show changes in the composition of DOC in stormflow during the rainy season and differences associated with runoff from different parts of the basin, including extensive upland areas burned prior to the 2004 rainy season. Samples were collected from the Santa Ana River, which drains ~6950 km 2 of the densely populated coastal area of southern California, during 23 stormflows between 1995 and 2004. Dissolved organic carbon (DOC) concentrations during the first stormflows of the ‘winter’ (November to March) rainy season increased rapidly with streamflow and were positively correlated with increased faecal indicator bacteria concentrations. DOC concentrations were not correlated with streamflow or with other constituents during stormflows later in the rainy season and DOC had increasing UV absorbance per unit carbon as the rainy season progressed. DOC concentrations in stormflow from an urban drain tributary to the river also increased during stormflow and were greater than concentrations in the river. DOC concentrations in stormflow from a tributary stream, draining urban and agricultural land that contained more than 320 000 animals, mostly dairy cows, were higher than concentrations in stormflow from the river and from the urban drain. Fires that burned large areas of the basin before the 2004 rainy season did not increase DOC concentrations in the river during stormflow after the fires – possibly because the large watershed of the river damped the effect of the fires. However, the fires increased the hydrophobic neutral organic carbon fraction of DOC in stormflow from the urban drain and the tributary stream.

California↗

Changes in the abundance and distribution of waterfowl wintering in the Central Valley of California, 1973–2000

The Central Valley of California is one of the most important areas for wintering waterfowl in the world and the focus of extensive conservation efforts to mitigate for historical losses and counter continuing stressors to habitats. To guide conservation, we analyzed trends in the abundance and distribution (spatiotemporal abundance patterns) of waterfowl and their habitats in the Central Valley and its major subregions (Sacramento Valley, Suisun Marsh, Delta, San Joaquin Valley), from 1973 through 2000. We used existing databases, satellite imagery, and aerial photography to measure habitat area, and aerial surveys and radio telemetry to track the abundance and distribution of wintering waterfowl. Wetlands increased throughout the Central Valley, but agricultural fields flooded after harvest increased greatly to the north in the Sacramento Valley and decreased to the south in the San Joaquin Valley, resulting in an overall increase in the relative availability of winter habitat in the former region. Reflecting the continental decline of the most abundant wintering species (Northern Pintail, Anas acuta ), the overall abundance of wintering waterfowl in the Central Valley declined during our study. By contrast, numbers of the American Wigeon ( A. americana ), Mallard ( A. platyrhynchos ), and Northern Shoveler ( A. clypeata ) were stable, and numbers of the Green-winged Teal ( A. crecca ), Gadwall ( A. strepera ), diving ducks, and geese increased from 1973–1982 to 1998–2000. The areas of greatest abundance of wintering waterfowl within the Central Valley shifted northward as many species responded to changes in the distribution of habitats. Wintering waterfowl migrated earlier in fall and winter from the San Joaquin Valley, Suisun Marsh, and Delta to the Sacramento Valley, and fewer waterfowl emigrated from the Sacramento Valley to other parts of the Central Valley. Because changes in waterfowl distribution were primarily a response to the increase of a beneficial agricultural practice (i.e., the flooding of rice after harvest) in the Sacramento Valley, changing agro-economics, reduction of water supplies, or other factors that reduce this practice could change the abundance and distribution of wintering waterfowl in the Central Valley rapidly. Thus to maintain abundant suitable habitat and restore the historical distribution of wintering waterfowl, our results suggest a continuing need for the conservation of wetlands and other waterfowl habitats with secure water supplies throughout the Central Valley. Despite our findings, achieving goals for winter waterfowl populations in the Central Valley likely will depend on a combination of factors including some acting in breeding ranges farther north or elsewhere outside of the valley.

California↗

Groundwater simulation and management models for the upper Klamath Basin, Oregon and California

The upper Klamath Basin encompasses about 8,000 square miles, extending from the Cascade Range east to the Basin and Range geologic province in south-central Oregon and northern California. The geography of the basin is dominated by forested volcanic uplands separated by broad interior basins. Most of the interior basins once held broad shallow lakes and extensive wetlands, but most of these areas have been drained or otherwise modified and are now cultivated. Major parts of the interior basins are managed as wildlife refuges, primarily for migratory waterfowl. The permeable volcanic bedrock of the upper Klamath Basin hosts a substantial regional groundwater system that provides much of the flow to major streams and lakes that, in turn, provide water for wildlife habitat and are the principal source of irrigation water for the basin's agricultural economy. Increased allocation of surface water for endangered species in the past decade has resulted in increased groundwater pumping and growing interest in the use of groundwater for irrigation. The potential effects of increased groundwater pumping on groundwater levels and discharge to springs and streams has caused concern among groundwater users, wildlife and Tribal interests, and State and Federal resource managers. To provide information on the potential impacts of increased groundwater development and to aid in the development of a groundwater management strategy, the U.S. Geological Survey, in collaboration with the Oregon Water Resources Department and the Bureau of Reclamation, has developed a groundwater model that can simulate the response of the hydrologic system to these new stresses. The groundwater model was developed using the U.S. Geological Survey MODFLOW finite-difference modeling code and calibrated using inverse methods to transient conditions from 1989 through 2004 with quarterly stress periods. Groundwater recharge and agricultural and municipal pumping are specified for each stress period. All major streams and most major tributaries for which a substantial part of the flow comes from groundwater discharge are included in the model. Groundwater discharge to agricultural drains, evapotranspiration from aquifers in areas of shallow groundwater, and groundwater flow to and from adjacent basins also are simulated in key areas. The model has the capability to calculate the effects of pumping and other external stresses on groundwater levels, discharge to streams, and other boundary fluxes, such as discharge to drains. Historical data indicate that the groundwater system in the upper Klamath Basin fluctuates in response to decadal climate cycles, with groundwater levels and spring flows rising and declining in response to wet and dry periods. Data also show that groundwater levels fluctuate seasonally and interannually in response to groundwater pumping. The most prominent response is to the marked increase in groundwater pumping starting in 2001. The calibrated model is able to simulate observed decadal-scale climate-driven fluctuations in the groundwater system as well as observed shorter-term pumping-related fluctuations. Example model simulations show that the timing and location of the effects of groundwater pumping vary markedly depending on the pumping location. Pumping from wells close (within a few miles) to groundwater discharge features, such as springs, drains, and certain streams, can affect those features within weeks or months of the onset of pumping, and the impacts can be essentially fully manifested in several years. Simulations indicate that seasonal variations in pumping rates are buffered by the groundwater system, and peak impacts are closer to mean annual pumping rates than to instantaneous rates. Thus, pumping effects are, to a large degree, spread out over the entire year. When pumping locations are distant (more than several miles) from discharge features, the effects take many years or decades to fully impact those features, and much of the pumped water comes from groundwater storage over a broad geographic area even after two decades. Moreover, because the effects are spread out over a broad area, the impacts to individual features are much smaller than in the case of nearby pumping. Simulations show that the discharge features most affected by pumping in the area of the Bureau of Reclamation's Klamath Irrigation Project are agricultural drains, and impacts to other surface-water features are small in comparison. A groundwater management model was developed that uses techniques of constrained optimization along with the groundwater flow model to identify the optimal strategy to meet water user needs while not violating defined constraints on impacts to groundwater levels and streamflows. The coupled groundwater simulation-optimization models were formulated to help identify strategies to meet water demand in the upper Klamath Basin. The models maximize groundwater pumping while simultaneously keeping the detrimental impacts of pumping on groundwater levels and groundwater discharge within prescribed limits. Total groundwater withdrawals were calculated under alternative constraints for drawdown, reductions in groundwater discharge to surface water, and water demand to understand the potential benefits and limitations for groundwater development in the upper Klamath Basin. The simulation-optimization model for the upper Klamath Basin provides an improved understanding of how the groundwater and surface-water system responds to sustained groundwater pumping within the Bureau of Reclamation's Klamath Project. Optimization model results demonstrate that a certain amount of supplemental groundwater pumping can occur without exceeding defined limits on drawdown and stream capture. The results of the different applications of the model demonstrate the importance of identifying constraint limits in order to better define the amount and distribution of groundwater withdrawal that is sustainable.

Oregon;California↗

Use of a three-dimensional model for the analysis of the ground-water flow system in Parker Valley, Arizona and California

A three-dimensional, finite-difference model was used to simulate ground-water flow conditions in Parker Valley. The study evaluated present knowledge and concepts of the ground-water system and the ability of the model to represent the system. Modeling assumptions and generalized physical parameters that were used may have transfer value in the construction and calibration of models of other basins along the lower Colorado River. The aquifer was simulated in two layers to represent the three-dimensional system. Ground-water conditions were simulated for 1940-41, the mid-1960's, and 1980. Overall model results generally compared favorably with available field information. The model results showed that for 1940-41 the Colorado River was a losing stream through out Parker Valley. Infiltration of surface water from the river was the major source of recharge. The dominant mechanism of discharge was evapotranspiration by phreatophytes. Agricultural development between 1941 and the mid-1960 's resulted in significant changes to the ground-water system. Model results for conditions in the mid-1960 's showed that the Colorado River had become a gaining stream in the northern part of the valley as a result of higher water levels. The rise in water levels was caused by infiltration of applied irrigation water. Diminished water-level gradients from the river in the rest of the valley reduced the amount of infiltration of surface water from the river. Models results for conditions in 1980 showed that ground-water level rises of several feet caused further reduction in the amount of surface-water infiltration from the river. (USGS)

Open-File Report↗

Predatory bird populations in the east Mojave Desert, California

We surveyed 7 species of predatory birds weekly during a 12-month period (December 1992 through November 1993) in the east Mojave Desert, California. The Common Raven (Corvus corax) was the most frequently observed species with an average of 6.9 sightings per 100 km. Turkey Vultures (Cathartes aura), Red-tailed Hawks (Buteo jamaicensis), Loggerhead Shrikes (Lanius ludovicianus), American Kestrels (Falco sparverius), Golden Eagles (Aquila chrysaetos), and Prairie Falcons (Falco mexicanus) were seen in decreasing order of frequency of observation through the study period. Ravens, Red-tailed Hawks, Loggerhead Shrikes, American Kestrels, and Prairie Falcons were seen throughout the year. Turkey Vultures were not present during winter months, while Golden Eagles were seen only during November and December. Turkey Vultures, Red-tailed Hawks, and ravens were most numerous on agricultural lands, while Loggerhead Shrikes were most Common at urban areas. Raven numbers increased with increasing number of linear rights-of-way parallel to the survey route. Perching was the most common behavior type, although Turkey Vultures and ravens were often observed soaring, flying, or standing on the ground near highways. Transmission powerline towers and telephone poles were used as perch sites disproportionately to availability.

Great Basin Naturalist↗

Linkages between land-use change and groundwater management foster long-term resilience of water supply in California

Study Region We created a 270-m coupled model of land-use and groundwater conditions, LUCAS-W[ater], for California’s Central Coast. This groundwater-dependent region is undergoing a dramatic reorganization of groundwater management under California’s 2014 Sustainable Groundwater Management Act (SGMA). Study Focus Understanding land-use and land-cover change supports long-term sustainable water management. Anthropogenic water demand has depleted groundwater aquifers worldwide, while future water shortages will likely affect land-use change, creating system feedbacks. Our novel participatory approach fused changes in land-use and associated water use from county-scale data to local water agencies’ estimates of total sustainable supply, scaling up local hydro-geologic knowledge from heterogeneous aquifers and diverse management approaches to a regional level. We assessed five stakeholder-driven scenarios with the same historic rates of urban and agricultural land-use change, but different water and land-use management, analyzing how management strategies altered both the spatial pattern of development and subsequent water sustainability from 2001 to 2061. New Hydrological Insights for the Region Transformative strategies using demand-side interventions that coupled water availability to land-use more effectively achieved long-term sustainability than adaptive strategies using supply-side interventions to increase water supplies. Limiting water withdrawals within SGMA regulated basins resulted in leakage of development into unregulated basins, increasing groundwater pumping there. Protecting ecosystems, farmlands, and recharge areas from development reduced leakage into undeveloped basins without negatively affecting water sustainability.

California↗

Occurrence and distribution of volatile organic compounds and pesticides in ground water in relation to hydrogeologic characteristics and land use in the Santa Ana basin, southern California

This report presents an evaluation of the occurrence and distribution of VOCs and pesticides in the Santa Ana ground-water basins in relation to two types of explanatory factors: hydrogeologic characteristics and land use. The Santa Ana Basin is subdivided into the San Jacinto, the Inland, and the Coastal ground-water basins. Most wells sampled were deep and used for public supply. Data from regional studies were used to evaluate the occurrence and distribution of pesticides and volatile organic compounds (VOCs) in relation to hydrogeologic characteristics and land uses that could potentially explain variations between basins. Additional data from special studies (flow path and aquifer susceptibility) were used to evaluate potential factors affecting water quality for individual basins. The hydrogeologic characteristics evaluated in this report were hydrogeologic setting, ground-water age, depth to the top of the well screen (top of well perforations), and proximity to engineered recharge facilities. Urban land use, agricultural land use, and population density were characterized within a 500-meter radius of sampled wells and at the basin scale. Aquifers in the San Jacinto Basin are generally unconfined, and major land-use categories are urban (33 percent), agricultural (37 percent), and undeveloped (25 percent). Recharge is primarily from the overlying landscape, but engineered recharge is locally important in the Hemet area. VOCs and pesticides were detected more frequently in younger ground water (less than 50 years old) than in older ground water, and more frequently in shallower wells than deeper wells; the numbers of VOCs and pesticides detected also were significantly higher in the younger ground water and in the shallower wells. In the Hemet area of the San Jacinto Basin, VOCs and pesticides were detected more frequently in wells proximal to engineered recharge facilities than in distal wells. These patterns illustrate the importance of proximity to sources of recharge in relation to the occurrence and distribution of VOCs and pesticides in ground water. Aquifers in the Inland Basin also are generally unconfined, and the major land-use category is urban (58 percent), with lesser amounts of agricultural (13 percent) and undeveloped (28 percent) land. Recharge is from engineered facilities that utilize local runoff and imported water and from vertical infiltration. VOCs and pesticides were detected more frequently in younger ground water than in older ground water, and more frequently in shallower wells than deeper wells. The number of VOCs detected per well also was significantly higher in the younger ground water and in the shallower wells. Several solvent plumes extending between 5 and 10 kilometers illustrate the large distances that contaminants travel in basins with intensive use of ground water. Aquifers in the Coastal Basin, in contrast to the other basins, are generally confined. Land use in the basin is largely urban (80 percent), with lesser amounts of agricultural (7 percent) and undeveloped (12 percent) land. Recharge is primarily from engineered facilities that utilize water diverted from the Santa Ana River and imported water. Consequently, VOCs and pesticides were detected more frequently in wells proximal to engineered recharge facilities than in distal wells. These compounds were also detected more frequently in the unconfined area than in the confined area of the basin. In the confined area, the numbers of VOCs and pesticides detected per well were not significantly different in wells with shallower and deeper screens. This distribution reflects the dominance of lateral flow and insulation from overlying land use in the confined aquifers of the Coastal Basin. In the unconfined area of the Coastal Basin, the numbers of VOCs and pesticides detected per well were significantly higher in shallower wells than in deeper wells. VOC and pesticide detections were not statist

Scientific Investigations Report↗

Salinity, alkalinity, and dissolved and particulate organic carbon in the Sacramento River water at Rio Vista, California, and at other locations in the Sacramento-San Joaquin Delta, 1980

Salinity, alkalinity, and dissolved and particulate organic carbon (DOC and POC respectively) concentrations in the Sacramento River water at Rio Vista were measured every three to five days during 1980 as part of an effort to identify time-dependent variations in the composition of the freshwater flow from the Sacramento-San Joaquin Delta to San Francisco Bay. Concentration ranges were generally small compared to the seasonal range of river flow rate; transport rates to the Delta and to the Bay varied primarily as a function of flow rate. Surface runoff from winter storms diluted salinity and alkalinity concentrations. DOC and POC were generally more concentrated during winter than during other times of the year. Variations in tributary flows resulted in sometimes-large salinity and alkalinity variations during spring through fall. Late summer concentrations were high because of large inflows of agricultural waste waters. POC and DOC concentrations were lowest during summer.

California↗

An initial SPARROW model of land use and in-stream controls on total organic carbon in streams of the conterminous United States

Watersheds play many important roles in the carbon cycle: (1) they are a site for both terrestrial and aquatic carbon dioxide (CO2) removal through photosynthesis; (2) they transport living and decomposing organic carbon in streams and groundwater; and (3) they store organic carbon for widely varying lengths of time as a function of many biogeochemical factors. Using the U.S. Geological Survey (USGS) Spatially Referenced Regression on Watershed Attributes (SPARROW) model, along with long-term monitoring data on total organic carbon (TOC), this research quantitatively estimates the sources, transport, and fate of the long-term mean annual load of TOC in streams of the conterminous United States. The model simulations use surrogate measures of the major terrestrial and aquatic sources of organic carbon to estimate the long-term mean annual load of TOC in streams. The estimated carbon sources in the model are associated with four land uses (urban, cultivated, forest, and wetlands) and autochthonous fixation of carbon (stream photosynthesis). Stream photosynthesis is determined by reach-level application of an empirical model of stream chlorophyll based on total phosphorus concentration, and a mechanistic model of photosynthetic rate based on chlorophyll, average daily solar irradiance, water column light attenuation, and reach dimensions. It was found that the estimate of in-stream photosynthesis is a major contributor to the mean annual TOC load per unit of drainage area (that is, yield) in large streams, with a median share of about 60 percent of the total mean annual carbon load in streams with mean flows above 500 cubic feet per second. The interquartile range of the model predictions of TOC from in-stream photosynthesis is from 0.1 to 0.4 grams (g) carbon (C) per square meter (m-2) per day (day-1) for the approximately 62,000 stream reaches in the continental United States, which compares favorably with the reported literature range for net carbon fixation by phytoplankton in lakes and streams. The largest contributors per unit of drainage area to the mean annual stream TOC load among the terrestrial sources are, in descending order: wetlands, urban lands, mixed forests, agricultural lands, evergreen forests, and deciduous forests . It was found that the SPARROW model estimates of TOC contributions to streams associated with these land uses are also consistent with literature estimates. SPARROW model calibration results are used to simulate the delivery of TOC loads to the coastal areas of seven major regional drainages. It was found that stream photosynthesis is the largest source of the TOC yields ( about 50 percent) delivered to the coastal waters in two of the seven regional drainages (the Pacific Northwest and Mississippi-Atchafalaya-Red River basins ), whereas terrestrial sources are dominant (greater than 60 percent) in all other regions (North Atlantic, South Atlantic-Gulf, California, Texas-Gulf, and Great Lakes).

Conterminous United States↗