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USGS2017

U.S. Geological Survey—Energy and wildlife research annual report for 2017

Introduction Terrestrial and aquatic ecosystems provide valuable services to humans and are a source of clean water, energy, raw materials, and productive soils. The Nation’s food supply is more secure because of wildlife. For example, native pollinators enhance agricultural crops, and insect-eating bats provide pest control services worth billions of dollars to farmers annually. Fish and wildlife are also vital to a vibrant outdoor recreation and tourism industry. Recreational activities, such as hunting, shooting, boating, and angling, generated \$1.1 billion in excise taxes paid to State wildlife agencies in 2017. National parks, wildlife refuges, and monuments accounted for $35 billion in economic output and 318,000 jobs nationwide in 2016. Additional economic benefits are generated from the use and enjoyment of wildlife in State-owned lands and waters. Although the United States is rich in natural resources, human activity continues to place new pressures on fish and wildlife and the habitats they rely on. The United States became the world’s top producer of petroleum and natural gas products in 2012, surpassing Russia’s natural gas production levels in 2009 and Saudi Arabia’s petroleum production in 2013. The U.S. Energy Information Administration projects that the demand for liquid fuel, natural gas, and renewable energy will show strong growth in the next 20 years. Wind energy has demonstrated consistent growth since 2007 with now more than 53,000 wind turbines contributing to power grids in 41 States, Guam, and Puerto Rico. Solar energy has seen rapid growth since 2013 and made up nearly one-third of the total electricity generation additions in 2016. Yet as our Nation works to advance energy security and sustain wildlife, some conflicts have surfaced. Impacts of an expanding energy infrastructure include fragmentation and loss of habitat as well as mortality of birds, bats, fish, and other animals from interactions with energy generation facilities. Because energy development can often occur in wildlife habitats, ecological science can help guide project siting and operational decisions to areas that present the lowest risk to wildlife and energy developers. To address these challenges and make the most of new opportunities, the U.S. Geological Survey is producing innovative science to develop workable solutions that can help sustain wildlife and the habitat they rely upon, while allowing informed development.

Circular↗
USGS2009

Water Use in Wisconsin, 2005

The U.S. Geological Survey (USGS) Wisconsin Water Science Center is responsible for presenting data collected or estimated for water withdrawals and diversions every 5 years to the National Water-Use Information Program (NWUIP). This program serves many purposes such as quantifying how much, where, and for what purpose water is used; tracking and documenting water-use trends and changes; and providing these data to other agencies to support hydrologic projects. In 2005, data at both the county and subbasin levels were compiled into the USGS national water-use database system; these data are published in a statewide summary report and a national circular. This publication, Water Use in Wisconsin, 2005, presents the water-use estimates for 2005; this publication also describes how these water-use data were determined (including assumptions used), limitations of using these data, and trends in water-use data presented to the NWUIP. Estimates of water use in Wisconsin indicate that about 8,608 million gallons per day (Mgal/d) were withdrawn during 2005. Of this amount, about 7,622 Mgal/d (89 percent) were from surface-water sources and about 986 Mgal/d (11 percent) were from ground-water sources. Surface water used for cooling at thermoelectric-power plants constituted the largest portion of daily use at 6,898 Mgal/d. Water provided by public-supply water utilities is the second largest use of water and totaled 552 Mgal/d. Public supply served approximately 71 percent of the estimated 2005 Wisconsin population of 5.54 million people; two counties - Milwaukee and Dane - accounted for more than one-third of the public-supply withdrawal. Industrial and irrigation were the next major water uses at 471 and 402 Mgal/d, respectively. Non-irrigational agricultural (livestock and aquaculture) accounted for approximately 155 Mgal/d and is similar to the combined withdrawal for the remaining water-use categories of domestic, commercial, and mining (131 Mgal/d). Data on water use in Wisconsin by source of water and category of use have been compiled at 5-year intervals since 1950. During the past 55 years (1950-2005), water withdrawn to meet demands for public supply and self-supplied irrigation, industrial, commercial, domestic, and livestock increased 333 percent (1,117 Mgal/d). The greatest increases were for public supply, industrial, and irrigation, and are reflected in the increasing total per-capita water-use values. In recent (2000 and 2005) water-use estimation years, both public-supply and self-supplied domestic per-capita-use values have been declining. This can be attributed, at least in part, to a reduction in industrial-water deliveries, increased water-efficiency standards, and the implementation of leak-detection programs and water-conservation practices. However, when making comparisons to evaluate trends among other Wisconsin water-use estimation years, it is important to be aware of changes that may have occurred in estimation methods or objectives that create differences. Some changes that have occurred are the availability of data and information about water use, changes in data sources and estimation methods, and the inclusion and exclusion of certain water-use categories. These differences may have an effect on apparent trends and make comparing trends difficult.

Open-File Report↗
USGS2018

Bioactive contaminants of emerging concern in National Park waters of the northern Colorado Plateau, USA

Pharmaceuticals and personal care products (PPCPs), wastewater indicators (WWIs), and pesticides (herein, Contaminants of Emerging Concern [CECs]) have been documented in surface waters throughout the world and have associated risks to aquatic life. While much research has focused on temperate and urbanized watersheds, less is known about CEC presence in semi-arid landscapes, where water availability is limited and populations are low. CEC presence in water and sediment is reported for 21 sites in eight U.S. national parks in the northern Colorado Plateau region. From 2012 to 2016, at least one PPCP and/or WWI was detected at most sites on over half of sampling visits, indicating that CECs are not uncommon even in isolated areas. CEC detections were generally fewer and at lower concentrations than in urbanized or agricultural watersheds. Consistent with studies from other U.S. regions, the most frequently detected CECs in this study include DEET, caffeine, organophosphorus flame retardants, and bisphenol A in water and fecal indicators and polycyclic aromatic hydrocarbons in sediment. Maximum concentrations in this study were generally below available water quality benchmarks, sediment quality guidelines, and risk assessment thresholds associated with vertebrates. Additional work is needed to assess the potential activity of hormones, which had high reporting limits in our study, and potential bioactivity of environmental concentrations for invertebrates, microbial communities, and algae. Potential sources of CEC contamination include upstream wastewater effluent discharges and National Park Service invasive-plant-control herbicide applications. CEC occurrence patterns and similarities between continuous and isolated flow locations suggest that direct contamination from individual visitors may also occur. While our data indicate there is little aquatic health risk associated with CECs at our sites, our results demonstrate the ubiquity of CECs on the landscape and a continued need for public outreach concerning resource-use ethics and the potential effects of upstream development.

Colorado Plateau↗
USGS2008

Distribution of pesticides, PAHs, PCBs, and bioavailable metals in depositional sediments of the lower Missouri River, USA

The lower Missouri River was studied to determine the distribution of selected persistent organic pollutants and bioavailable metals in depositional sediments. Nineteen sites between Omaha, Nebraska and Jefferson City, Missouri were sampled. This stretch of the river receives point-source and non-point-source inputs from industrial, urban, and agricultural activities. As part of an ecological assessment of the river, concentrations of 29 legacy organochlorine pesticides (OC pesticides), including chlordanes, DDTs, and hexachlorocyclohexanes; a select list of current-use pesticides, including trifluralin, diazinon, chlorpyrifos, and permethrin, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), divalent metals (copper, nickel, zinc, cadmium, and lead), and polybrominated diphenyl ethers (PBDEs) were determined. Concentrations (dry weight basis) of OC pesticides in the sediments were less than 1 ng/g, with the exception of the backwater sediment collected from the mouth of the Blue River in the Kansas City metropolitan area, which contained up to 20 ng/g total chlordane, 8.1 ng/g p,p???-DDE, 1.5 ng/g lindane, 4.8 ng/g dieldrin, and 3 ng/g endrin. Concentrations of chlorpyrifos and permethrin ranged from less than 1 ng/g to 5.5 ng/g and 44 ng/g, respectively. Concentrations of PCBs ranged from less than 11 ng/g to 250 ng/g, with the Blue River and Sibley sediments containing 100 and 250 ng/g total PCBs, respectively. Concentrations of total PAHs at 17 of the 19 sites ranged from 250 to 700 ng/g, whereas the Riverfront and Blue River sites in Kansas City contained 1100 ng/g and nearly 4000 ng/g, respectively. Concentrations of the metals did not vary significantly among most sites; however, the Blue River site contained elevated concentrations of zinc (104 ??g/g), cadmium (0.7 ??g/g), and lead (34 ??g/g) compared to the other sites. The moderately high concentrations of acid-volatile sulfide in the sediments suggest a low potential for metal toxicity to benthic organisms along this reach of the Missouri River. The depositional area sediments contained concentrations of the targeted persistent organic chemicals and metals that were below published probable effect level concentrations. ?? 2008 Springer Science+Business Media, LLC.

Archives of Environmental Contamination and Toxico↗
USGS1998

Airborne pesticide residues along the Mississippi River

The occurrence, concentration, and geographical distribution of agricultural pesticides were determined in air over the Mississippi River from New Orleans, LA, to St. Paul, MN, during the first 10 days of June 1994. Air samples were collected from a research vessel by pulling air through polyurethane foam plugs at about 100 L/min for up to 24 h. Each sample was analyzed for 42 pesticides and 3 pesticide transformation products. Twenty-five compounds 15 herbicides, 7 insecticides, and 3 pesticide transformation products were detected in one or more samples with concentrations ranging from 0.05 to 80 ng/m 3 . Alachlor, chlorpyrifos, diazinon, fonofos, malathion, methyl parathion, metolachlor, metribuzin, pendimethalin, and trifluralin were detected in 80% or more of the samples. The highest concentrations for chlorpyrifos (1.6 ng/m 3 ), diazinon (0.36 ng/m 3 ), and malathion (4.6 ng/m 3 ) all occurred near major metropolitan areas. These samples represent a “snapshot in time”, a spatial and temporal integration of which pesticides were present in the air during each sampling period. The occurrence and atmospheric concentrations of the observed pesticides were most closely related to their use on cropland within 40 km of the river.

Mississippi River↗
USGS2023

Bifenthrin, a ubiquitous contaminant, impairs the development and behavior of the threatened Longfin Smelt during early life stages

The Longfin Smelt ( Spirinchus thaleichthys ) population in the San Franscisco Bay/Sacramento-San Joaquin Delta (Bay-Delta) has declined to ∼1% of its pre-1980s abundance and, as a result, is listed as threatened under the California Endangered Species Act. The reasons for this decline are multiple and complex, including the impacts of contaminants. Because the spawning and rearing seasons of Longfin Smelt coincide with the rainy season, during which concentrations of contaminants increase due to runoff, we hypothesized that early life stages may be particularly affected by those contaminants. Bifenthrin, a pyrethroid insecticide commonly used in agricultural and urban sectors, is of concern. Concentrations measured in the Bay-Delta have been shown to disrupt the behavior, development, and endocrine system of other fish species. The objective of the present work was to assess the impact of bifenthrin on the early developmental stages of Longfin Smelt. For this, embryos were exposed to 2, 10, 100, and 500 ng/L bifenthrin from fertilization to hatch, and larvae were exposed to 2, 10, and 100 ng/L bifenthrin from one day before to 3 days post-hatch. We assessed effects on size at hatch, yolk sac volume, locomotory behavior, and upper thermal susceptibility (via cardiac endpoints). Exposure to these environmentally relevant concentrations of bifenthrin did not significantly affect the cardiac function of larval Longfin Smelt; however, exposures altered their behavior and resulted in smaller hatchlings with reduced yolk sac volumes. This study shows that bifenthrin affects the fitness-determinant traits of Longfin Smelt early life stages and could contribute to the observed population decline.

Environmental Science and Technology↗
USGS2003

Global forest cover mapping for the United Nations Food and Agriculture Organization forest resources assessment 2000 program

Many countries periodically produce national reports on the status and changes of forest resources, using statistical surveys and spatial mapping of remotely sensed data. At the global level, the Food and Agriculture Organization (FAO) of the United Nations has conducted a Forest Resources Assessment (FRA) program every 10 yr since 1980, producing statistics and analysis that give a global synopsis of forest resources in the world. For the year 2000 of the FRA program (FRA2000), a global forest cover map was produced to provide spatial context to the extensive survey. The forest cover map, produced at the U.S. Geological Survey (USGS) EROS Data Center (EDC), has five classes: closed forest, open or fragmented forest, other wooded land, other land cover, and water. The first two forested classes at the global scale were delineated using combinations of temporal compositing, modified mixture analysis, geographic stratification, and other classification techniques. The remaining three FAO classes were derived primarily from the USGS global land cover characteristics database (Loveland et al. 1999). Validated on the basis of existing reference data sets, the map is estimated to be 77% accurate for the first four classes (no reference data were available for water), and 86% accurate for the forest and nonforest classification. The final map will be published as an insert to the FAO FRA2000 report.

Forest Science↗
USGS1998

Surface-water-quality assessment of the upper Illinois River Basin in Illinois, Indiana, and Wisconsin: Pesticides and other synthetic organic compounds in water, sediment, and biota, 1975-90

The distribution of pesticides and other synthetic organic compounds in water, sediment, and biota in the upper Illinois River Basin in Illinois, Indiana, and Wisconsin was examined from 1987 through 1990 as part of the pilot National Water-Quality Assesssment Program conducted by the U.S. Geological Survey. Historical data for water and sediment collected from 1975 through 1986 were similar to data collected from 1987 through 1990. Some compounds were detected in concentrations that exceed U.S. Environmental Protection Agency water-quality criteria. Results from pesticide sampling at four stations in 1988 and 1989 identified several agricultural pesticides that were detected more frequently and at higher concentrations in urban areas than in agricultural areas. Results from herbicide sampling at 17 stations in the Kankakee and Iroquois River Basins in 1990 indicated that atrazine concentrations exceeded the U.S. Environmental Protection Agency's maximum contaminant level for drinking water during runoff periods. Results from sampling for volatile and semivolatile organic compounds in water indicate that, with one exception, all stations at which more than one compound was detected were within 2 miles downstream from the nearest point source. Detections at two stations in the Chicago urban area accounted for 37 percent of the total number of detections. Concentrations of tetrachloroethylene, trichloroethylene, and 1,2-dichlorethane from stations in the Des Plaines River Basin exceeded the U.S. Environmental Protection Agency's maximum contaminant level for drinking water in one and two samples from the two stations in the Chicago area. Phenols and pentachlorophenols were detected most frequently in the Des Plaines River Basin where point-source discharges were common. Phenol concentrations were significantly different among the Des Plaines, Kankakee, and Fox River Basins. Phenols and pentachlorophenols never exceeded the general use and secondary contact standards. Results from a 1989 synoptic survey of semivolatile organic compounds in sediment indicate that these compounds were detected most frequently at sites in the Chicago urban area. Of the 17 stations at which 10 or more compounds were detected, 14 were located in the Des Plaines River subbasin, and 1 was on the Illinois River mainstem. As was the case with organic compounds in water, each of these sites was located within 2 miles downstream from point sources. Biota samples were collected and analyzed for organochlorines and polynuclear aromatic hydrocarbons in 1989 and 1990. The most commonly detected compound in both years was p,p'-DDE. National Academy of Science recommendations for chlordane and dieldrin for protection of predators were exceeded in 19 and 10 samples, respectively, when the 1989 and 1990 data were combined. In the nine fish-fillet samples collected in 1989, concentrations exceeded U.S. Environmental Protection Agency fish-tissue criteria in nine fillets for p,p'-DDE and five fillets for dieldrin.

Illinois, Indiana, Wisconsin↗
USGS2021

Impacts of neonicotinoid seed treatments on the wild bee community in agricultural field margins

Wild bees support global agroecosystems via pollination of agricultural crops and maintaining diverse plant communities. However, with an increased reliance on pesticides to enhance crop production, wild bee communities may inadvertently be affected through exposure to chemical residues. Laboratory and semi-field studies have demonstrated lethal and sublethal effects of neonicotinoids on limited genera (e.g., Apis , Bombus , Megachile ), yet full field studies evaluating impacts to wild bee communities remain limited. Here, we conducted a two-year field study to assess whether neonicotinoid seed treatment and presence in environmental media (e.g., soil, flowers) influenced bee nest and diet guild abundance and richness. In 2017 and 2018, we planted 23 Missouri agricultural fields to soybeans ( Glycine max) using one of three seed treatments: untreated (no insecticide), treated (imidacloprid), or previously-treated (untreated, but neonicotinoid use prior to 2017). During both years, wild bees were collected in study field margins monthly (May to September) in tandem with soil and flowers from fields and field margins that were analyzed for neonicotinoid residues. Insecticide presence in soils and flowers varied over the study with neonicotinoids infrequently detected in both years within margin flowers (0%), soybean flowers (<1%), margin soils (<8%), and field soils (~39%). Wild bee abundance and species richness were not significantly different among field treatments. In contrast, neonicotinoid presence in field soils was associated with significantly lower richness (ground- and aboveground-nesting, diet generalists) of wild bee guilds. Our findings support that soil remains an underexplored route of exposure and long-term persistence of neonicotinoids in field soils may lead to reduced diversity in regional bee communities. Future reduction or elimination of neonicotinoid seed treatment use on areas managed for wildlife may facilitate conservation goals to sustain viable, diverse wild bee populations.

Missouri↗
USGS2000

Fate and origin of 1,2-dichloropropane in an unconfined shallow aquifer

A shallow aquifer with different redox zones overlain by intensive agricultural activity was monitored for the occurrence of 1,2-dichloropropane (DCP) to assess the fate and origin of this pollutant. DCP was detected more frequently in groundwater samples collected in aerobic and nitrate-reducing zones than those collected from iron-reducing zones. Simulated DCP concentrations for groundwater entering an iron-reducing zone were calculated from a fate and transport model that included dispersion, sorption, and hydrolysis but not degradation. Simulated concentrations were well in excess of measured values, suggesting that microbial degradation occurred in the iron-reducing zone. Microcosm experiments were conducted using aquifer samples collected from iron-reducing and aerobic zones to evaluate the potential for microbial degradation of DCP and to explain field observations. Hydrogenolysis of DCP and production of monochlorinated propanes in microcosm experiments occurred only with aquifer materials collected from the iron-reducing zone, and no dechlorination was observed in microcosms established with aquifer materials collected from the aerobic zones. Careful analyses of the DCP/1,2,2-trichloropropane ratios in groundwater indicated that older fumigant formulations were responsible for the high levels of DCP present in this aquifer.A shallow aquifer with different redox zones overlain by intensive agricultural activity was monitored for the occurrence of 1,2-dichloropropane (DCP) to assess the fate and origin of this pollutant. DCP was detected more frequently in groundwater samples collected in aerobic and nitrate-reducing zones than those collected from iron-reducing zones. Simulated DCP concentrations for groundwater entering an iron-reducing zone were calculated from a fate and transport model that included dispersion, sorption, and hydrolysis but not degradation. Simulated concentrations were well in excess of measured values, suggesting that microbial degradation occurred in the iron-reducing zone. Microcosm experiments were conducted using aquifer samples collected from iron-reducing and aerobic zones to evaluate the potential for microbial degradation of DCP and to explain field observations. Hydrogenolysis of DCP and production of monochlorinated propanes in microcosm experiments occurred only with aquifer materials collected from the iron-reducing zone, and no dechlorination was observed in microcosms established with aquifer materials collected from the aerobic zones. Careful analyses of the DCP/1,2,2-trichloropropane ratios in groundwater indicated that older fumigant formulations were responsible for the high levels of DCP present in this aquifer.

Washington↗
USGS2002

Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999-2000: A national reconnaissance

To provide the first nationwide reconnaissance of the occurrence of pharmaceuticals, hormones, and other organic wastewater contaminants (OWCs) in water resources, the U.S. Geological Survey used five newly developed analytical methods to measure concentrations of 95 OWCs in water samples from a network of 139 streams across 30 states during 1999 and 2000. The selection of sampling sites was biased toward streams susceptible to contamination (i.e. downstream of intense urbanization and livestock production). OWCs were prevalent during this study, being found in 80% of the streams sampled. The compounds detected represent a wide range of residential, industrial, and agricultural origins and uses with 82 of the 95 OWCs being found during this study. The most frequently detected compounds were coprostanol (fecal steroid), cholesterol (plant and animal steroid), N , N -diethyltoluamide (insect repellant), caffeine (stimulant), triclosan (antimicrobial disinfectant), tri(2-chloroethyl)phosphate (fire retardant), and 4-nonylphenol (nonionic detergent metabolite). Measured concentrations for this study were generally low and rarely exceeded drinking-water guidelines, drinking-water health advisories, or aquatic-life criteria. Many compounds, however, do not have such guidelines established. The detection of multiple OWCs was common for this study, with a median of seven and as many as 38 OWCs being found in a given water sample. Little is known about the potential interactive effects (such as synergistic or antagonistic toxicity) that may occur from complex mixtures of OWCs in the environment. In addition, results of this study demonstrate the importance of obtaining data on metabolites to fully understand not only the fate and transport of OWCs in the hydrologic system but also their ultimate overall effect on human health and the environment.

Environmental Science & Technology↗
USGS2025

Landowners' cognitions and motivations coupled with practice durability influence persistence in grazing agricultural conservation practices in southwest Virginia

Agricultural conservation practices are often used to protect stream health while continuing food production. However, recovery of stream health is often not as rapid or extensive as planned. The efficacy of practices may be improved by promoting their continued use by landowners (i.e., persistence) after cost-share contracts with government agencies end. Persistence rates and their drivers are typically unknown. Therefore, we mail-surveyed 889 landowners to understand persistence in grazing practices in southwest Virginia. Survey responses were analyzed quantitatively using logistic regression and qualitatively via coding. We found that persistence rates for vegetative practices, cattle-exclusion fencing, off-stream watering structures, and pasture management were 74%, 84%, 94%, and 94%, respectively. Both the quantitative and qualitative analyses indicated that landowner cognitions (i.e., attitudes toward practices, environment, and agencies), environmental motivations, and practice durability influence persistence. Our results highlight that persistence could be encouraged by: (1) providing targeted messaging that demonstrates persistence benefits and aligns with landowners' motivations, (2) ensuring that responsibility to maintain practices is transferred during land-tenure changes, and (3) allocating more agency funding to practice maintenance.

Virginia↗
USGS2020

A critical review on the potential impacts of neonicotinoid insecticide use: Current knowledge of environmental fate, toxicity, and implications for human health

Neonicotinoid insecticides are widely used in both urban and agricultural settings around the world. Historically, neonicotinoid insecticides have been viewed as ideal replacements for more toxic compounds, like organophosphates, due in part to their perceived limited potential to affect the environment and human health. This critical review investigates the environmental fate and toxicity of neonicotinoids and their metabolites and the potential risks associated with exposure. Neonicotinoids are found to be ubiquitous in the environment, drinking water, and food, with low-level exposure commonly documented below acceptable daily intake standards. Available toxicological data from animal studies indicate possible genotoxicity, cytotoxicity, impaired immune function, and reduced growth and reproductive success at low concentrations, while limited data from ecological or cross-sectional epidemiological studies have identified acute and chronic health effects ranging from acute respiratory, cardiovascular, and neurological symptoms to oxidative genetic damage and birth defects. Due to the heavy use of neonicotinoids and potential for cumulative chronic exposure, these insecticides represent novel risks and necessitate further study to fully understand their risks to humans.

Environmental Science: Processes and Impacts↗
USGS2019

Financing agricultural drought risk through ex-ante cash transfers

Despite advances in drought early warning systems, forecast information is rarely used for triggering and financing early actions, such as cash transfer. Scaling up cash transfer pay-outs , and overcoming the barriers to actions based on forecasts, requires an understanding of costs resulting from False Alarms, and the potential benefits associated with appropriate early interventions. On this study, we evaluate the potential cost-effectiveness of cash transfer responses, comparing the relative costs of ex-ante cash transfers during the maize growing season to ex-post cash transfers after harvesting in Kenya. For that, we developed a forecast model using Fast-and Frugal Trees that unravels early warning relationships between climate variability, vegetation coverage, and maize yields at multiple lead times. Results indicate that our models correctly forecast low maize yield events 85% of the time across the districts studied, some already six months before harvesting. The models’ performance improves towards the end of the growing season driven by a decrease of 39% in the probability of False Alarms. Overall, we show that timely cash transfers ex-ante to a disaster can often be more cost-effective than investing in ex-post expenditures. Our findings suggest that early response can yield significant cost savings, and can potentially increase the effectiveness of existing cash transfer systems.

Science of the Total Environment↗
USGS2006

Widespread presence of naturally occurring perchlorate in high plains of Texas and New Mexico

Perchlorate (ClO4-) occurrence in groundwater has previously been linked to industrial releases and the historic use of Chilean nitrate fertilizers. However, recently a number of occurrences have been identified for which there is no obvious anthropogenic source. Groundwater from an area of 155 000 km2 in 56 counties in northwest Texas and eastern New Mexico is impacted by the presence of ClO4-. Concentrations were generally low (<4 ppb), although some areas are impacted by concentrations up to 200 ppb. ClO4- distribution is not related to well type (public water system, domestic, agricultural, or water-table monitoring) or aquifer (Ogallala, Edward Trinity High Plains, Edwards Trinity Plateau, Seymour, or Cenozoic). Results from vertically nested wells strongly indicate a surface source. The source of ClO4- appears to most likely be atmospheric deposition. Evidence supporting this hypothesis primarily relates to the presence of ClO 4- in tritium-free older water, the lack of relation between land use and concentration distribution, the inability of potential anthropogenic sources to account for the estimated mass of ClO4-, and the positive relationship between conserved anions (e.g., IO3-, Cl-, SO4-2) and ClO4-. The ClO4- distribution appears to be mainly related to evaporative concentration and unsaturated transport. This process has led to higher ClO4- and other ion concentrations in groundwater where the water table is relatively shallow, and in areas with lower saturated thickness. Irrigation may have accelerated this process in some areas by increasing the transport of accumulated salts and by increasing the number of evaporative cycles. Results from this study highlight the potential for ClO4- to impact groundwater in arid and semiarid areas through long-term atmospheric deposition. ?? 2006 American Chemical Society.

Environmental Science & Technology↗
USGS2007

Effects of flow diversions on water and habitat quality: Examples from California's highly manipulated Sacramento–San Joaquin Delta

We use selected monitoring data to illustrate how localized water diversions from seasonal barriers, gate operations, and export pumps alter water quality across the Sacramento-San Joaquin Delta (California). Dynamics of water-quality variability are complex because the Delta is a mixing zone of water from the Sacramento and San Joaquin Rivers, agricultural return water, and the San Francisco Estuary. Each source has distinct water-quality characteristics, and the contribution of each source varies in response to natural hydrologic variability and water diversions. We use simulations with a tidal hydrodynamic model to reveal how three diversion events, as case studies, influence water quality through their alteration of Delta-wide water circulation patterns and flushing time. Reduction of export pumping decreases the proportion of Sacramento- to San Joaquin-derived fresh water in the central Delta, leading to rapid increases in salinity. Delta Cross Channel gate operations control salinity in the western Delta and alter the freshwater source distribution in the central Delta. Removal of the head of Old River barrier, in autumn, increases the flushing time of the Stockton Ship Channel from days to weeks, contributing to a depletion of dissolved oxygen. Each shift in water quality has implications either for habitat quality or municipal drinking water, illustrating the importance of a systems view to anticipate the suite of changes induced by flow manipulations, and to minimize the conflicts inherent in allocations of scarce resources to meet multiple objectives.

California↗
USGS2019

Impacts of the 2015 eruption of Calbuco volcano on Chilean infrastructure, utilities, agriculture, and health

This report presents data and summarises the findings of a reconnaissance trip investigating the impacts of the April 2015 eruption of Calbuco volcano, Chile, undertaken in November-December 2016. This study is mostly focused on the Los Lagos region, focusing on impacts occurring within ~30 km of the volcano, which includes the tourism town of Puerto Varas and port city of Puerto Montt. Eruption impacts and response strategies may be similar for moderate size eruptions from other stratovolcanoes in temperate regions. As such, this study provides useful information for development of contingency plans at active volcanoes around the world. The 2015 eruption of Calbuco volcano began at 18:04 (local time) on 22 April 2015 and consisted of three eruptive phases. The first lasted for 1.5 hours and generated a 15-km eruption column and plume that was directed towards the northeast. Pyroclastic density currents (PDCs) were generated locally and distributed radially, affecting many of the major rivers. A second phase began at 01:00 (local time) on 23 April 2015, lasted six hours and generated a 17-km high eruption column and plume that was dispersed towards the north-northeast, and the most voluminous pyroclastic density currents of the sequence. A third eruptive phase occurred on 30 April 12:10 (local time) resulting in a 5-km column and plume dispersed towards the east.

Calbuco volcano↗
USGS2009

Remote sensing of global croplands for food security: Way forward

This book opens a new pathway for global mapping that is focused on a specific land use theme, such as irrigated or rain-fed croplands and classes within these themes. Since croplands use most of the water consumed by humans, specific knowledge of irrigated and rain-fed croplands will be critical for precise estimates of water use. At present and in the coming decades, irrigated and rain-fed cropland area mapping is crucial for food security studies. Throughout this book, various subjects pertaining to global croplands are discussed comprehensively.

Book chapter↗