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Surface-water/ground-water relations in the Lemhi River Basin, east-central Idaho

This report summarizes work carried out in cooperation with the Bureau of Reclamation to provide hydrologic information to help Federal, State, and local agencies meet the goals of the Lemhi River Model Watershed Project. The primary goal of the project is to maintain, enhance, and restore anadromous and resident fish habitat in the Lemhi River, while maintaining a balance between resource protection and established water uses. The main objectives of the study were to carry out seepage measurements to determine seasonal distributed gains and losses in the Lemhi River and to estimate annual ground-water underflow from the basin to the Salmon River. In 1997, seepage measurements were made during and after the irrigation season along a 60-mile reach of the Lemhi River between Leadore and Salmon. Except for one 4-mile reach that lost 1.3 cubic feet per second per mile, the river gained from ground water in early August when ground-water levels were high. Highest flows in the Lemhi River in early August were about 400 cubic feet per second. In October, when ground-water levels were low, river losses to ground water were about 1 to 16 cubic feet per second per mile. In October, highest flows in the Lemhi River were about 500 cubic feet per second, near the river's mouth. Annual ground-water underflow from the Lemhi River Basin to the Salmon River was estimated by using a simplified water budget and by using Darcy's equation. The water-budget method contained large uncertainties associated with estimating precipitation and evapotranspiration. Results of both methods indicate that the quantity of ground water leaving the basin as underflow is small, probably less than 2 percent of the basin's total annual water yield.

Idaho↗

Water-data program of the US Geological Survey in Kansas, fiscal year 1983

The U.S. Geological Survey is the principal Federal agency responsible for the collection of hydrologic data needed for the planning, development, use, and management of the water resources in Kansas. Hydrologic-data collection by the U.S. Geological Survey in Kansas began in 1895. The fiscal-year 1983 water-data program, operated in cooperation with several Federal , State, and local agencies, included 270 stations for collection of river, lake, and reservoir data, 1,940 wells for collection of ground-water data; 53 sampling stations and 215 wells for collection of water-quality data. This report provides a detailed description of the water-data program, including coordination and funding, data-collection activities, quality-assurance plans, availability of data, network design, and future needs for water data. (USGS)

Water-Resources Investigations Report↗

General hydrogeology of the aquifers of Mesozoic age, Upper Colorado River Basin - excluding the San Juan Basin - Colorado, Utah, Wyoming, and Arizona

The objective of the Upper Colorado Regional Aquifer Systems Analyses (RASA) project is to assess quantitatively the occurrence, movement, and availability of water stored in rock formations underlying the basin. This is one of a series of preliminary reports that describe what is currently known (1984) about the geometry and hydrologic properties of the aquifer systems, and the chemistry of the water in known or potential aquifers. This report provides the foundation needed for the assessment of the ground-water resources of the region. The report describes only part of the hydrologic system; that is, formations of Mesozoic age. Younger and older formations significant to the hydrologic system are described in other reports.

Arizona, Colorado, Utah, Wyoming↗

Three-dimensional digital-computer model of the principal ground-water reservoir of the Sevier Desert, Utah

The principal ground-water reservoir in part of the Sevier Desert, Utah was modeled using a three-dimensional finite-difference model. The model was calibrated by comparing computed and observed water-level measurements in 1952, simulating results of aquifer tests, and simulating ground-water withdrawals during 1952-81 and comparing computed water-level changes during 1952-82 to observed changes. The results indicate the model is capable of predicting future water-level changes. The report includes a complete listing of the model data for the 1952-82 simulation.

Utah↗

Plan of study for the Regional Aquifer-System Analysis, Columbia Plateau, Washington, northern Oregon, and northwestern Idaho

The U.S. Geological Survey began a 4-year study of the regional aquifer system underlying the Columbia Plateau, in central and eastern Washington, northern Oregon, and northwestern Idaho in October 1983, as part of the Regional Aquifer System Analysis program. The study will describe the geohydrology, geochemistry, and quality of water in the Columbia River Basalt Group, the Miocene rocks that underlie 70,000 square miles in three States. Water from the basalts is used for municipal and industrial purposes, and most importantly, for agriculture. As more land is brought under cultivation and surface water becomes totally allocated, the groundwater is an increasingly important supply for agriculture and related activities. In addition, the basalts are being considered as a repository site for high-level nuclear wastes. For management agencies to make the best decisions regarding the future development of this area, the regional groundwater flow system, its relation to the surfacewater system , and the quality of the water need to be quantified. This report describes the geohydrologic setting, hydrologic problems, objectives, and approach for the region. (USGS)

Water-Resources Investigations Report↗

A comparison of simultaneous plasma, atomic absorption, and iron colorimetric determinations of major and trace constituents in acid mine waters

Sixty-three water samples collected during June to October 1982 from the Leviathan/Bryant Creek drainage basin were originally analyzed by simultaneous multielement direct-current plasma (DCP) atomic-emission spectrometry, flame atomic-absorption spectrometry, graphite-furnace atomic-absorption spectrometry (GFAAS) (thallium only), ultraviolet-visible spectrometry, and hydride-generation atomic-absorption spectrometry.Determinations were made for the following metallic and semi-metallic constituents: AI, As, B, Ba, Be, Bi, Cd, Ca, Cr, Co, Cu, Fe(11), Fe(total), Li, Pb, Mg, Mn, Mo, Ni, K, Sb, Se, Si, Na, Sr, TI, V, and Zn. These samples were re-analyzed later by simultaneous multielement inductively coupled plasma (ICP) atomic-emission spectrometry and Zeeman-corrected GFAAS to determine the concentrations of many of the same constituents with improved accuracy, precision, and sensitivity. The result of this analysis has been the generation of comparative concentration values for a significant subset of the solute constituents. Many of the more recently determined values replace less-than-detection values for the trace metals; others constitute duplicate analyses for the major constituents. The multiple determinations have yielded a more complete, accurate, and precise set of analytical data. They also have resulted in an opportunity to compare the performance of the plasma-emission instruments operated in their respective simultaneous multielement modes. Flame atomic-absorption spectrometry was judged best for Na and K and hydride-generation atomic-absorption spectrometry was judged best for As because of their lower detection limit and relative freedom from interelement spectral effects. Colorimetric determination using ferrozine as the color agent was judged most accurate, precise, and sensitive for Fe. Cadmium, lead, and vanadium concentrations were too low in this set of samples to enable a determination of whether ICP or DCP is a more suitable technique. Of the remaining elements, Ba, Be, Ca, Cr, Mg, Mn, Sr, and Zn have roughly equivalent accuracy, precision, and detection limit by ICP and DCP. Cobalt and Ni were determined to be better analyzed by ICP, because of lower detection limits; B, Cu, Mo, and Si were determined to be better analyzed by DCP, because of relative freedom from interferences. The determination oral by DCP was far more sensitive, owing to the use of a more sensitive wavelength, compared with the ICP. However, there is a very serious potential interference from a strong Ca emission line near the 396.15 nanometer DCP wavelength. Thus, there is no clear choice between the plasma techniques tested, for the determination oral. The ICP and DCP detection limits are typically between 0.001 and 0.5 milligrams per liter in acid mine waters. For those metals best analyzed by ICP and/or DCP, but below these limits, GFAAS is the method of choice because of its relatively greater sensitivity and specificity. Six of the elements were not determined by DCP, ICP or Zeeman-corrected GFAAS, and are not discussed in this report. These elements are: Bi, Fe(11), Li, Sb, Se, and TI.

Water-Resources Investigations Report↗

Magnitude and frequency of floods in Arkansas

Methods are presented for estimating the magnitude and frequency of peak discharges of streams in Arkansas. Regression analyses were developed in which a stream's physical and flood characteristics were related. Four sets of regional regression equations were derived to predict peak discharges with selected recurrence intervals of 2, 5, 10, 25, 50, 100, and 500 years on streams draining less than 7,770 square kilometers. The regression analyses indicate that size of drainage area, main channel slope, mean basin elevation, and the basin shape factor were the most significant basin characteristics that affect magnitude and frequency of floods. The region of influence method is included in this report. This method is still being improved and is to be considered only as a second alternative to the standard method of producing regional regression equations. This method estimates unique regression equations for each recurrence interval for each ungaged site. The regression analyses indicate that size of drainage area, main channel slope, mean annual precipitation, mean basin elevation, and the basin shape factor were the most significant basin and climatic characteristics that affect magnitude and frequency of floods for this method. Certain recommendations on the use of this method are provided. A method is described for estimating the magnitude and frequency of peak discharges of streams for urban areas in Arkansas. The method is from a nationwide U.S. Geeological Survey flood frequency report which uses urban basin characteristics combined with rural discharges to estimate urban discharges. Annual peak discharges from 204 gaging stations, with drainage areas less than 7,770 square kilometers and at least 10 years of unregulated record, were used in the analysis. These data provide the basis for this analysis and are published in the Appendix of this report as supplemental data. Large rivers such as the Red, Arkansas, White, Black, St. Francis, Mississippi, and Ouachita Rivers have floodflow characteristics that differ from those of smaller tributary streams and were treated individually. Regional regression equations are not applicable to these large rivers. The magnitude and frequency of floods along these rivers are based on specific station data. This section is provided in the Appendix and has not been updated since the last Arkansas flood frequency report (1987b), but is included at the request of the cooperator.

Water-Resources Investigations Report↗

Simulated peak flows and water-surface profiles for Scott Creek near Sylva, North Carolina

Peak flows were simulated for Scott Creek, just upstream from Sylva, in Jackson County, North Carolina, in order to provide Jackson County officials with information that can be used to improve preparation for and response to flash floods along the reach of Scott Creek that flows through Sylva. A U.S. Geological Survey rainfall-runoff model was calibrated using observed rainfall and streamflow data collected from March 1994 through September 1995. Standard errors for calibration were 34 percent for runoff volumes and 21 percent for peak flows. The calibrated model was used to simulate peak flows resulting from syn- thetic rainfall amounts of 1.0, 2.5, 5.0, and 7.5 inches in 24-hour periods. For each rainfall amount, peak flows were simulated under low-, moderate-, and high-antecedent soil-moisture conditions, represented by selected 3-month periods of daily rainfall and evaporation record from nearby climatic-data measuring stations. Simulated peak flows ranged from 89 to 10,100 cubic feet per second. Profiles of water-surface elevations for selected observed and simu- lated peak flows were computed for the reach of Scott Creek that flows through Sylva, North Carolina. The profiles were computed using the U.S. Army Corps of Engineers HEC-2 Water Surface Profiles computer program and channel cross-section data collected by the Tennessee Valley Authority. The stage-discharge relation for Scott Creek at the simulation site has changed since the collection of the cross-section data. These changes, however, are such that the water-surface profiles presented in this report likely overestimate the true water-surface elevations at the simulation site for a given peak flow

North Carolina↗

Ground-water sampling methods and quality-control data for the Red River of the North basin, Minnesota, North Dakota, and South Dakota, 1993-95

Ground-water-quality samples were collected for the intensive data-collection phase of the Red River of the P Torth Basin study unit, one of 60 study units of the National Water Quality Assessment (NAWQA) Program throughout the United States. The sampling protocols used were designed for the NAWQA Program. The protocols include sampling equipment, cleaning procedures, sample-collection methods, and quality-control plans to monitor the accuracy of the data collected. One of the goals of the NAWQA Program was to collect data using similar methcds to build a nationally consistent water-quality data base. Quality-control data demonstrated that most constituents measured for this study yielded reproducible data, with low to undetectable contamination from the sampling and analytical procedures. Several constituents were occasionally or frequently detected in blank samples at levels similar to low-concentration ground-water-quality samples. For example, iron was detected in 75 percent of the blank samples, with a maximum concentration of 27 [ig/L, indicating that iron contamination may interfere with its determination at low levels in ground waters. Copper, aluminum, and dissolved organic carbon concentrations in blank samples overlap those determined in ground-waterquality samples, thereby precluding quantitative reporting of those constituents. Most pesticide data are reproducible, with minimal bias. Some pesticides had low but consistent recoveries; these data may be useful if spike and surrogate data are carefully considered. Data for some pesticides measured in this study should not be quantitatively reported or used, because they may underestimate the concentrations of those pesticides in ground waters.

Minnesota, North Dakota, South Dakota↗

Potentiometric surface of the Cockfield aquifer in southeastern Arkansas and the Wilcox aquifers in southern and northeastern Arkansas, October 1996-July 1997

The Cockfield and Wilcox aquifers are secondary sources of water for local use in southern and northeastern Arkansas, where in 1995 more than 51 million gallons per day of water was withdrawn. During October 1996 to July 1997, water levels in the Cockfield and Wilcox aquifers were measured in 104 wells in Arkansas. The potentiometric surface data reveal spatial trends in both aquifers across the study areas. The regional direction of ground-water flow of the Cockfield aquifer is generally southeastward, away from the outcrop area, except where affected by intense ground-water withdrawals. The potentiometric surface indicates that heavy pumpage has altered or reversed the natural direction of flow in some areas. Flow in these areas is toward centers of pumping within cones of depression. A cone of depression caused by the pumpage near Greenville, Mississippi, extends into Chicot, Desha, and Drew Counties. This cone of depression has altered flow patternArkansas. Long-term hydrographs of six wells, during the period 1971-1996, showed water levels declined at an average rate between 0.5 and 1.0 foot per year at these locations. The regional direction of ground-water flow in the Wilcox aquifers is generally toward the east and south, away from the outcrop except where water levels are affected by intense ground-water withdrawals. The potentiometric surface indicates that heavy pumpage has altered or reversed the natural direction of ground-water flow in some areas. Flow in these areas is toward centers of pumping within cones of depression. Two cones of depression are centered in the vicinity of Paragould and West Memphis, Arkansas, where ground-water withdrawals have altered the natural direction of flow. Long-term hydrographs of seven wells, during the period 1971- 1996, show water-level declines in the Wilcox aquifer in northeastern Arkansas generally were between 0.5 and 1.0 foot per year but were more than 1.0 foot per year in two wells. The U.S. Geological Survey in cooperation with the Arkansas Soil and Water Conservation Commission and the Arkansas Geological Commission has monitored water levels in the Cockfield and Wilcox aquifers since the 1960's. During October 1996 to July 1997, 53 water-level measurements were made in wells completed in the Cockfield aquifer, 13 water-level measurements were made in wells completed in the Wilcox aquifer in southern Arkansas, and 38 water-level measurements were made in wells com- pleted in the Wilcox aquifer in northeastern Arkansas. The purpose of these measurements was to provide information to describe the recent potentiometric surfaces and long-term water-level trends in the Cockfield and Wilcox aquifers. This report presents the results as potentiometric surface maps and as long-term water-level hydrographs.

Arkansas↗

Statewide water-quality network for Massachusetts

A water-quality monitoring program is proposed that would provide data to meet multiple information needs of Massachusetts agencies and other users concerned with the condition of the State's water resources. The program was designed by the U.S. Geological Survey and the Massachusetts Department of Environmental Protection, Division of Watershed Management, with input from many organizations involved in water-quality monitoring in the State, and focuses on inland surface waters (streams and lakes). The proposed monitoring program consists of several components, or tiers, which are defined in terms of specific monitoring objectives, and is intended to complement the Massachusetts Watershed Initiative (MWI) basin assessments. Several components were developed using the Neponset River Basin in eastern Massachusetts as a pilot area, or otherwise make use of data from and sampling approaches used in that basin as part of a MWI pilot assessment in 1994. To guide development of the monitoring program, reviews were conducted of general principles of network design, including monitoring objectives and approaches, and of ongoing monitoring activities of Massachusetts State agencies.Network tiers described in this report are primarily (1) a statewide, basin-based assessment of existing surface-water-quality conditions, and (2) a fixed-station network for determining contaminant loads carried by major rivers. Other components, including (3) targeted programs for hot-spot monitoring and other objectives, and (4) compliance monitoring, also are discussed. Monitoring programs for the development of Total Maximum Daily Loads for specific water bodies, which would constitute another tier of the network, are being developed separately and are not described in this report. The basin-based assessment of existing conditions is designed to provide information on the status of surface waters with respect to State water-quality standards and designated uses in accordance with the reporting requirements [Section 305(b)] of the Clean Water Act (CWA). Geographic Information System (GIS)-based procedures were developed to inventory streams and lakes in a basin for these purposes. Several monitoring approaches for this tier and their associated resource requirements were investigated. Analysis of the Neponset Basin for this purpose demonstrated that the large number of sites needed in order for all the small streams in a basin to be sampled (about half of stream miles in the basin were headwater or first-order streams) pose substantial resource-based problems for a comprehensive assessment of existing conditions. The many lakes pose similar problems. Thus, a design is presented in which probabilistic monitoring of small streams is combined with deterministic or targeted monitoring of large streams and lakes to meet CWA requirements and to provide data for other information needs of Massachusetts regulatory agencies and MWI teams.The fixed-station network is designed to permit the determination of contaminant loads carried by the State's major rivers to sensitive inland and coastal receiving waters and across State boundaries. Sampling at 19 proposed sites in 17 of the 27 major basins in Massachusetts would provide information on contaminant loads from 67 percent of the total land area of the State; unsampled areas are primarily coastal areas drained by many small streams that would be impossible to sample within realistic resource limitations. Strategies for hot-spot monitoring, a targeted monitoring program focused on identifying contaminant sources, are described with reference to an analysis of the bacteria sampling program of the 1994 Neponset Basin assessment. Finally, major discharge sites permitted under the National Pollutant Discharge Elimination System (NPDES) were evaluated as a basis for ambient water-quality monitoring. The discharge sites are well distributed geographically among basins, but are primarily on large rivers (two-thirds or more

Water-Resources Investigations Report↗

Sources and summaries of water-quality information for the Rapid Creek basin, western South Dakota

This report provides a compilation of water quality information for the Rapid Creek basin in western South Dakota. Two types of information are included: First, past and current water quality monitoring data collected by the South Dakota Department of Water and Natural Resources, U.S. Forest Service, U.S. Geological Survey, and others are described. Second, a summary is included for all past water quality reports, publications, and theses that could be located during this study. A total of 62 documents were abstracted and included journal articles, abstracts, Federal agency reports and publications, university and State agency reports, local agency reports, and graduate theses. The report should be valuable to water resources managers, regulators, and others contemplating water quality research, monitoring, and regulatory programs in the Rapid Creek basin. (USGS)

Open-File Report↗

Water resources inventory of Connecticut Part 3: lower Thames and southeastern coastal river basins

The lower Thames and southeastern coastal river basins have a relatively abundant supply of water of generally good quality which is derived from streams entering the area and precipitation that has fallen on the area. Annual precipitation has ranged from about 32 inches to 65 inches and has averaged about 48 inches over a 30-year period. Approximately 22 inches of water are returned to the atmosphere each year by evaporation and transpiration; the remainder of the annual precipitation either flows overland to streams or percolates downward to the water table and ultimately flows out of the report area through estuaries and coastal streams or as underflow through the deposits beneath. During the autumn and winter months precipitation normally is sufficient to cause a substantial increase in the amount of water stored underground and in surface reservoirs within the report area, whereas in the summer most of the precipitation is lost through evaporation and transpiration, resulting in sharply reduced stream-flow and lowered ground-water levels. The mean monthly storage of water on an average is about 3.8 inches higher in November than it is in June. The amount of water that flows through and out of the report area represents the total amount of water potentially available for use by man. For the 30-year period 1931 through 1960, the annual runoff from the report area has averaged nearly 26 inches (200 billion gallons), from the entire Thames River basin above Norwich about 24 inches (530 billion gallons), and from the Pawcatuck River basin about 26 inches (130 billion gallons). A total average annual runoff of 860 billion gallons is therefore available. Although runoff indicates the total amount of water potentially available, it is usually not economically feasible for man to use all of it. On the other hand, with increased development, it is possible that some water will be reused several times. The water available may be tapped as it flows through the area or is temporarily stored in streams, lakes, and aquifers. The amounts that can be developed vary from place to place and time to time, depending on the amount of precipitation, on the size of drainage area, on the thickness, permeability, and areal extent of aquifers, and on the variations in chemical and physical quality of the water. Differences in streamflow from point to point are due primarily to differences in the proportion of stratified drift in the drainage basin above each point, which affect the timing of streamflow, and to differences in precipitation, which affect the amount of streamflow. Ground water can be obtained from wells almost anywhere in the area, but the amount obtainable at any particular point depends upon the type and water-bearing properties of the aquifers. For practical purposes, the earth materials in the report area comprise three aquifers--stratified drift, bedrock, and till. Stratified drift is the only aquifer generally capable of yielding more than 100 gpm (gallons per minute) to individual wells. It covers about 20 percent of the area and occurs chiefly in lowlands where it overlies till and bedrock. The coefficient of permeability of the coarse-grained unit of stratified drift averages about 1,500 gbd (gallons per day) per sq ft. Drilled, screened wells tapping this unit are known to yield from 4 to 88o gpm and average 146 gpm. Dug wells in coarse-grained stratified drift supply about 2 gpm per foot of drawdown over a period of a few hours. Fine-grained stratified drift has an average coefficient of permeability of about 300 gpd per sq ft and can usually yield supplies sufficient for household use to dug wells. Bedrock and till are widespread in extent but generally provide only small water supplies. Bedrock is tapped chiefly by drilled wells, about 90 percent of which will supply at least 3 gpm. Very few, however, will supply more than 50 gpm. Till is tapped in a few places by dug wells which can yield small supplies of only a few hundred gpd throughout all or most of the year. The coefficient of permeability of till ranges from about 0.2 gpd per sq ft to 120 gpd per sq ft. The amount of ground water potentially available in the report area depends upon the amount of ground-water outflow, the amount of ground water in storage, and the quantity of water available by induced infiltration from streams and lakes. From data on permeability, saturated thickness, recharge, yield from aquifer storage, well performance, and streamflow, preliminary estimates of ground-water availability can be made for any point in the report area. Long-term yields estimated for 18 areas of stratified drift especially favorable for development of large ground-water supplies ranged from 1.3 to 66 mgd. Detailed site studies to determine optimum yields, drawdowns, and spacing of individual wells are needed before major ground-water development is undertaken in these or other areas. The chemical quality of water in the report area is generally good to excellent. Samples of naturally occurring surface water collected at 24 sites contained less than 151 ppm (parts per million) of dissolved solids and less than 63 ppm of hardness. Water from wells is more highly mineralized than naturally occurring water from streams. Even so only 12 percent of the wells sampled yielded water with more than 200 ppm of dissolved solids and only 8 percent yielded water with more than 120 ppm of hardness. Even in major streams, which are used to transport industrial waste, hardness rarely exceeds 60 ppm and the dissolved mineral content is generally less than 200 ppm. At a few places in the town of Montville however, waters may contain dissolved mineral concentrations of 2,000 to 4,000 ppm. Iron and manganese in both ground water and surface water are the only constituents whose concentrations commonly exceed recommended limits for domestic and industrial use. Most wells in the report area yield clear water with little or no iron or manganese, but distributed among them are wells yielding ground water that contains enough of these dissolved constituents to be troublesome for most uses. Iron concentrations in naturally occurring stream water exceed 0.3 ppm under low-flow conditions at 33 percent of the sites sampled. Large concentrations of iron in stream water result from discharge of iron-bearing water from aquifers or from swamps where it is released largely from decaying vegetation. Ground water more than 30 feet below the land surface has a relatively constant temperature, usually between 48°F and 52°F. Water temperature in very shallow wells may fluctuate from about 38°F in February or March to about 55°F in late summer. Water temperature in the larger streams fluctuates much more widely, ranging from 32°F at least for brief periods in winter, to about 85°F occasionally during summer. The quality of suspended sediment transported by streams in the area is negligible. Turbidity in streams is generally not a problem although amounts large enough to be troublesome may occur locally at times. The total amount of water used in the report area for all purposes during 1964 was about 118,260 million gallons, of which 105,600 million gallons was estuarine water used for cooling by industry. The average per capita water use, excluding estuarine, temporary summer residence, and institutional water was equivalent to 186 gpd. Public water systems supplied the domestic needs of nearly tw0-thirds the population of the report area. All of the 19 systems, which were sampled, provided water of better quality than the U.S. Public Health Service suggests for drinking water standards.

Connecticut↗

Ground-water and stream-water interaction in the Owl Creek basin, Wyoming

Understanding of the interaction of ground-water and surface-water resources is vital to water management when water availability is limited.Inflow of ground water is the primary source ofwater during stream base flow. The water chemistry of streams may substantially be affected by that inflow of ground water. This report is part of a study to examine ground-water and surface-water interaction in the Owl Creek Basin, Wyoming, completed by the U.S. Geological Survey incooperation with the Northern Arapaho Tribe and the Shoshone Tribe. During a low flow period between November\x1113 - 17, 1991, streamflowmeasurements and water-quality samples were collected at 16 selected sites along major streams and tributaries in the Owl Creek Basin,Wyoming. The data were used to identify stream reaches receiving ground-water inflow and to examine causes of changes in stream chemistry.Streamflow measurements, radon-222 activity load, and dissolved solids load were used to identified stream reaches receiving ground-water inflow.Streamflow measurements identified three stream reaches receiving ground-water inflow. Analysis of radon-222 activity load identified five stream reaches receiving ground-water inflow. Dissolvedsolids load identified six stream reaches receiving ground-water inflow. When these three methods were combined, stream reaches in two areas, theEmbar Area and the Thermopolis Anticline Area, were identified as receiving ground-water inflow.The Embar Area and the Thermopolis Anticline Area were then evaluated to determine the source of increased chemical load in stream water. Three potential sources were analyzed: tributary inflow, surficial geology, and anticlines. Two sources,tributary inflow and surficial geology, were related to changes in isotopic ratios and chemical load in the Embar Area. In two reaches in the Embar Area, isotopic ratios of 18O/16O, D/H, and 34S/32S indicated that tributary inflow affected stream-water chemistry. Increased chemical load of dissolved solids and dissolved sulfate in North Fork andSouth Fork Owl Creek appear to be related to the percentage of unconsolidated Quaternary deposits and of Cretaceous-Jurassic deposits in the drainage area. In the Thermopolis Anticline Area, changes in water chemistry in Owl Creek were not related to tributary inflow, surficial geology, or anticlines.The three tributaries that flow into Owl Creek in the Thermopolis Anticline Area did not substantially affect the isotopic ratios or contribute to the chemical load. Changes in the chemical load were not associated with changes in the surficial geologybetween the stream-water sampling sites. Water levels and chemical ratios indicate no ground-water inflow from the Thermopolis Anticline geothermal system to Owl Creek.

Water-Resources Investigations Report↗

Saline ground-water resources of the Tularosa Basin, New Mexico

This report describes the location, extent, and quality of saline ground water in the Tularosa Basin, a north-trending elongated, intermontane, desert basin in south-central New Mexico. There are no through-flowing streams; runoff from the bordering mountains flows to ephemeral lakes in the center of the basin. Fresh-water supplies in the Tularosa Basin are limited; however, large volumes of saline ground-water underlie most of the basin. Consolidated rocks ranging from Precambrian through Cretaceous in age form "bedrock" aquifers in the basin. Where these rocks are exposed in the mountains bordering the basin, and in the north part of the basin, they may yield up to 150 gallons per minute, although yields are usually less than 20 gpm. Water at shallow depths in these rocks usually contain 1-3 g/l. Water quality deteriorates with depth, and more than 35 g/l water is present in some rock units. Few wells have penetrated these rocks beneath the alluvial deposits in the central part of the basin, where well yields and water quality are generally unknown. The most widely developed aquifer in the basin is the alluvial fill of Tertiary to Holocene age which exceeds 6,000 feet in thickness in the southern part of the basin. Well yields of as much as 1,400 gallons per minute have been measured. Fresh water lenses occur in the alluvial fill adjacent to the mountains on the east and west sides of the southern part of the basin. The water below the fresh-water lenses in the alluvial fill increases in salinity with depth. Salinity also increases toward the center of the basin. The altitude of isosaline surfaces and thickness of the saline-water zones are shown on maps of the entire basin and of the following detailed areas within the basin: Alamogordo, Tularosa, Carrizozo, and the western margin of the basin.

New Mexico↗

Theoretical considerations and a simple method for measuring alkalinity and acidity in low-pH waters by gran titration

Titrations for alkalinity and acidity using the technique described by Gran (1952, Determination of the equivalence point in potentiometric titrations, Part II: The Analyst, v. 77, p. 661-671) have been employed in the analysis of low-pH natural waters. This report includes a synopsis of the theory and calculations associated with Gran's technique and presents a simple and inexpensive method for performing alkalinity and acidity determinations. However, potential sources of error introduced by the chemical character of some waters may limit the utility of Gran's technique. Therefore, the cost- and time-efficient method for performing alkalinity and acidity determinations described in this report is useful for exploring the suitability of Gran's technique in studies of water chemistry.

Water-Resources Investigations Report↗

Water-quality changes and organic-carbon characterization during recharge with recycled water at a research basin in Montebello Forebay, Los Angeles County, California, 1991-1996

During the early 1990s, the U.S. Geological Survey (USGS) investigated water-quality changes that occur in treated municipal wastewater (recycled water) at a small research basin constructed in the Montebello Forebay of the Central Ground-Water Basin in south-central Los Angeles County. The instrumented research basin is located on a 1/2-acre site at the upgradient end of the San Gabriel River Coastal Spreading Grounds where recharge has been augmented using recycled water since 1961. The facility was used to measure attenuation in selected constituents as recycled water delivered to the basin percolates downward and moves laterally beneath the basin. Attenuation in aqueous concentration was found to range from 20 to 60 percent for total dissolved nitrogen and was about one-third for dissolved organic carbon (DOC). Isotopic data confirmed permanent loss of nitrogen by denitrification. Detailed investigations showed that there were no large differences in the loss of various components of the DOC at the structural or compound level, although surfactants and their metabolites were abundant and did persist in the subsurface. The DOC of wastewater origin was found to have a lower trihalomethane (THM) formation potential upon chlorination than does organic matter of natural origin from most surface-water sources. The organization of this report into 12 topical chapters, and the report's relation to additional USGS publications from this study, is noted in a preface.

Water-Resources Investigations Report↗