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At least 577 records · Page 32Linked to original sources
USGS2007

Questa baseline and pre-mining ground-water quality investigation 15.—Methods of phase II and III well installation and development and results of well logging, hydraulic testing, and water-level measurements in the Red River Valley, New Mexico, 2002-04

In April 2001, the U.S. Geological Survey and the New Mexico Environment Department began a cooperative study to infer the pre-mining ground-water chemistry at the Molycorp molybdenum mine site in the Red River Valley of north- central New Mexico. This report is one in a series of reports that can be used to determine pre-mining ground-water conditions at the mine site. Weathering of hydrothermally altered bedrock in the study area has resulted in steep, highly erosive, and sparsely vegetated scar areas that are clearly visible from the ground and in aerial photographs. Runoff from intense summer rainfall over tributary drainages containing scar areas can transport large quantities of sediment and form debris fans where these tributaries join the Red River. Twenty-nine observation wells were installed in three phases as part of this study in the Red River Valley and tributary drainages. Eight Phase II observation wells were drilled using an air-rotary/hammer rig. Three Phase II and 10 phase III small-diameter wells were installed using a direct-push rig. Lithologic logs were recorded for all eight Phase II drilled wells. Borehole geophysical logging (including natural gamma, induction, and single-detector neutron) was conducted in three Phase II wells. Aquifer tests conducted during 2003 to estimate the hydraulic properties of debris-flow and Red River alluvial deposits in and near Straight Creek included a flow-meter survey, slug tests, and a pumping test. Results of a flow-meter survey in well SC-7A indicated that about 77 percent of the water entered the well from a 10-foot-thick zone near the top of the screened interval and about 23 percent of the water entered the well from a 15-foot-thick zone near the bottom of the screened interval. Slug tests, performed in 11 wells during June 3-5, 2003, indicated that the mean and median estimated hydraulic conductivities for debris-flow deposits were 15.25 and 15.35 feet per day, respectively, for bedrock were 0.12 and 0.08 feet per day, respectively, and for mixed debris flow and Red River alluvium were 73-207 (estimated range) and 80 feet per day. In general, bedrock has the smallest hydraulic conductivity, debris-flow material has the next highest hydraulic conductivity, and mixed debris flow and Red River alluvium has the largest hydraulic conductivity. A pumping test conducted December 3-4, 2003, using well AWWT-1 as the pumped well, and wells AWWT-2, SC-5A, SC-5B, SC-7A, and SC-8A as observation wells, indicated estimated transmissivity of 12,000 to 34,000 feet squared per day and estimated hydraulic conductivity of 230 to 340 feet per day. Water-level measurements in wells SC-6A, SC-7A, SC-8A, and the Hottentot, Hansen, and La Bobita wells show that water levels typically rose rapidly during melting of the winter snowpack in the springtime and then generally declined during the rest of the year. The water-level rise in response to spring snowmelt occurred earlier and was smaller at larger distances from the Red River. Differences between the stage in the Red River and water levels in wells SC-8A and SC-9A, and the absence of water in well SC-9A at the time of well completion, indicate that the Red River has a poor hydraulic connection to the underlying ground-water system and the surface-water system is perched above the ground-water system at this site. Water levels in Phase III wells indicate that the Red River and the shallow ground-water system are connected hydraulically from near wells 4-1D and 4-1S downstream to near wells 2-1 and 2-2 but are poorly connected near the La Bobita well and well 1.

New Mexico↗
USGS2015

Chloride concentrations, loads, and yields in four watersheds along Interstate 95, southeastern Connecticut, 2008-11: factors that affect peak chloride concentrations during winter storms

Chloride (Cl - ) concentrations and loads and other water chemistry characteristics were assessed to evaluate potential effects of road-deicer applications on streamwater quality in four watersheds along Interstate 95 (I–95) in southeastern Connecticut from November 1, 2008, through September 30, 2011. Streamflow and water quality were studied in the Four Mile River, Oil Mill Brook, Stony Brook, and Jordan Brook watersheds, where developed land ranged from 9 to 32 percent. Water-quality samples were collected and specific conductance was measured continuously at paired water-quality monitoring sites, upstream and downstream from I–95. Specific conductance values were related to Cl - concentrations to assist in determining the effects of road-deicing operations on the levels of Cl - in the streams. Streamflow and water-quality data were compared with weather data and with the timing, amount, and composition of deicers applied to State highways. Grab samples were collected during winter stormwater-runoff events, such as winter storms or periods of rain or warm temperatures in which melting takes place. Grab samples were also collected periodically during the spring and summer and during base-flow conditions. The estimated Cl - concentrations at the eight water-quality monitoring sites during winter storms peaked as high as 270 milligrams per liter (mg/L) and were well below the U.S. Environmental Protection Agency (EPA) recommended acute chloride toxicity criterion of 860 mg/L and the chronic 4-day average toxicity criterion of 230 mg/L. Cl - concentrations in streams, particularly at sites downstream from I–95, peaked during increased streamflow in the winter and early spring as a result of deicers applied to roads and washed off by stormwater or meltwater. Cl - concentrations during most of the nonwinter seasons decreased during increases in streamflow because storm runoff was more dilute than base flow. However, peaks in specific conductance and estimated chloride concentrations at streams in more urbanized watersheds corresponded to peaks in streamflow well after winter snow or ice events; these delayed peaks in Cl - concentration likely resulted from deicer residue that remained in melting snow piles and on roadsides and (or) that were flushed from soils and shallow groundwater, then discharged downstream. Estimated peak Cl - concentrations varied with the type of winter storm event and were highest during or after winter storms of frozen precipitation and rain, in which the rain or meltwater effectively washed off the deicers. Estimated peak Cl - concentrations correlated positively with the duration of deicer application but generally not with streamflow. Estimated peak Cl - concentrations during the winter season were highest during low streamflow at most sites. Chloride concentrations varied considerably in shallow groundwater as a result of land-use differences. Cl - concentrations were very high (as high as 800 mg/L) in shallow groundwater downstream from I–95 at the Four Mile River site. Chloride/bromide mass concentration ratios and the proximity of a former landfill and sewage lagoon upstream indicate a likely source of Cl - is landfill leachate and possibly sewage leachate. Cl - loads in streams generally were highest in the winter and early spring. The estimated daily Cl - yield for the four monitoring sites downstream from I–95 ranged from 0.0004 ton per day per square mile for one of the least developed watersheds to 0.052 ton per day per square mile for the watershed with the highest percentage of urban development and impervious area. The estimated median contribution of Cl - load from atmospheric deposition was small and ranged from 0.07 percent of Cl - load at the Jordan Brook watershed to 0.57 percent at the Oil Mill Brook watershed. The Cl - loads in streams (outputs) were compared with Cl - load inputs, which include atmospheric deposition and deicer applications; Cl - load inputs were slightly larger than the Cl - load outputs at most of the sites during most years but do not account for the Cl - load in groundwater leaving the watersheds. A multiple linear regression model was developed to describe the variability of the natural log of peak specific conductance, as well as estimated Cl - concentrations. Five significant variables best explained the variability in the natural log of the peak specific conductance after deicing events: (1) snow on ground before deicing event; (2) winter precipitation with rain; (3) specific conductance in base flow; (4) State-operated road lane miles divided by watershed area; and (5) amount of Cl - from deicers applied to State-operated roads per lane mile. In this report, winter precipitation is defined as any type of precipitation, including frozen precipitation and rain, that occurs during the active deicing season, typically November through March. Frozen precipitation is defined here as snow, sleet, freezing rain, or any winter precipitation except rain. The addition of a lane mile in both directions on I–95 would result in an estimate of approximately 2 to 11 percent increase in Cl - input from deicers applied to I–95 and other roads maintained by Connecticut Department of Transportation. The largest estimated increase in Cl - load was in the watersheds with the greatest number miles of I–95 corridor relative to the total lane miles maintained by Connecticut Department of Transportation. On the basis of these estimates and the estimated peak Cl - concentrations during the study period, it is unlikely that the increased use of deicers on the additional lanes would lead to Cl - concentrations that exceed the aquatic habitat criteria.

Connecticut↗
USGS2011

Trends in lake chemistry in response to atmospheric deposition and climate in selected Class I wilderness areas in Colorado, Idaho, Utah, and Wyoming, 1993-2009

In 2010, the U.S. Geological Survey, in cooperation with the U.S. Department of Agriculture Forest Service, Air Resource Management, began a study to evaluate long-term trends in lake-water chemistry for 64 high-elevation lakes in selected Class I wilderness areas in Colorado, Idaho, Utah, and Wyoming during 1993 to 2009. The purpose of this report is to describe trends in the chemical composition of these high-elevation lakes. Trends in emissions, atmospheric deposition, and climate variables (air temperature and precipitation amount) are evaluated over a similar period of record to determine likely drivers of changing lake chemistry. Sulfate concentrations in precipitation decreased over the past two decades at high-elevation monitoring stations in the Rocky Mountain region. The trend in deposition chemistry is consistent with regional declines in sulfur dioxide emissions resulting from installation of emission controls at large stationary sources. Trends in nitrogen deposition were not as widespread as those for sulfate. About one-half of monitoring stations showed increases in ammonium concentrations, but few showed significant changes in nitrate concentrations. Trends in nitrogen deposition appear to be inconsistent with available emission inventories, which indicate modest declines in nitrogen emissions in the Rocky Mountain region since the mid-1990s. This discrepancy may reflect uncertainties in emission inventories or changes in atmospheric transformations of nitrogen species that may be affecting deposition processes. Analysis of long-term climate records indicates that average annual mean air temperature minimums have increased from 0.57 to 0.75 °C per decade in mountain areas of the region with warming trends being more pronounced in Colorado. Trends in annual precipitation were not evident over the period 1990 to 2006, although wetter than average years during 1995 to 1997 and drier years during 2001 to 2004 caused a notable decline in precipitation in the middle part of the record.

Colorado;Idaho;Utah;Wyoming↗
USGS2007

Biological conditions in streams of Johnson County, Kansas, and nearby Missouri, 2003 and 2004

Johnson County is one of the fastest growing and most populated counties in Kansas. Urban development affects streams by altering stream hydrology, geomorphology, water chemistry, and habitat, which then can lead to adverse effects on fish and macroinvertebrate communities. In addition, increasing sources of contaminants in urbanizing streams results in public-health concerns associated with exposure to and consumption of contaminated water. Biological assessments, or surveys of organisms living in aquatic environments, are crucial components of water-quality programs because they provide an indication of how well water bodies support aquatic life. This fact sheet describes current biological conditions of Johnson County streams and characterizes stream biology relative to urban development. Biological conditions were evaluated by collecting macroinvertebrate samples from 15 stream sites in Johnson County, Kansas, in 2003 and 2004 (fig. 1). Data from seven additional sites, collected as part of a separate study with similar objectives in Kansas and Missouri (Wilkison and others, 2005), were evaluated to provide a more comprehensive assessment of watersheds that cross State boundaries. Land-use and water- and streambed-sediment-quality data also were used to evaluate factors that may affect macroinvertebrate communities. Metrics are indices used to measure, or evaluate, macroinvertebrate response to various factors such as human disturbance. Multimetric scores, which integrated 10 different metrics that measure various aspects of macroinvertebrate communities, including organism diversity, composition, tolerance, and feeding characteristics, were used to evaluate and compare biological health of Johnson County streams. This information is useful to city and county officials for defining current biological conditions, evaluating conditions relative to State biological criteria, evaluating effects of urbanization, developing effective water-quality management plans, and documenting changes in biological conditions and water quality.

Kansas, Missouri↗
USGS2008

Questa baseline and pre-mining ground-water quality investigation. 17. Geomorphology of the Red River Valley, Taos County, New Mexico, and influence on ground-water flow in the shallow alluvial aquifer

In April 2001, the U.S. Geological Survey (USGS) and the New Mexico Environment Department (NMED) began a cooperative study to infer the pre-mining ground-water chemistry at the Molycorp molybdenum mine site in the Red River Valley of north-central New Mexico. This report is one in a series of reports that can be used to determine pre-mining ground-water conditions at the mine site. Molycorp’s Questa molybdenum mine in the Red River Valley, northern New Mexico, is located near the margin of the Questa caldera in a highly mineralized region. The bedrock of the Taos Range surrounding the Red River is composed of Proterozoic rocks of various types, which are intruded and overlain by Oligocene volcanic rocks associated with the Questa caldera. Locally, these rocks were altered by hydrothermal activity. The alteration zones that contain sulfide minerals are particularly important because they constitute the commercial ore bodies of the region and, where exposed to weathering, form sites of rapid erosion referred to as alteration scars. Over the past thousand years, if not over the entire Holocene, erosion rates were spatially variable. Forested hillslopes eroded at about 0.04 millimeter per year, whereas alteration scars eroded at about 2.7 millimeters per year. The erosion rate of the alteration scars is unusually rapid for naturally occurring sites that have not been disturbed by humans. Watersheds containing large alteration scars delivered more sediment to the Red River Valley than the Red River could remove. Consequently, large debris fans, as much as 80 meters thick, developed within the valley. The geomorphology of the Red River Valley has had several large influences on the hydrology of the shallow alluvial aquifer, and those influences were in effect before the onset of mining within the watershed. Several reaches where alluvial ground water emerges to become Red River streamflow were observed by a tracer dilution study conducted in 2001. The aquifer narrows where erosion-resistant bedrock, which tends to form vertical cliffs, restricts the width of the valley bottom. Although the presence of a shallow bedrock sill, overlain by shallow alluvium, is a plausible cause of ground-water emergence, this cause was not demonstrated in the study area. The water-table gradient can locally decrease in the downstream direction because of changes in the hydraulic properties of the alluvium, and this may be a contributing cause of ground-water emergence. However, at one site (near Cabin Springs), ground-water emergence could not be explained by spatial changes in geometric or hydraulic properties of the aquifer. Furthermore, the available evidence demonstrates that ground water flowing through bedrock fractures or colluvium entered the north side of the alluvial aquifer, and is the cause of ground-water emergence. At that location the alluvial aquifer was already flowing full, causing the excess water to emerge into the stream. An indirect consequence of altered rock in the tributary watersheds is the rapid erosion rate of alteration scars combined with the hydraulic properties of sediments shed from those scars. Where alteration scars are large the debris fans at the mouths of the tributary watersheds substantially encroach into the Red River Valley. At such locations debris-fan materials dominate the width and thickness of the alluvium in the valley and reduce the rate of flow of ground water within the Red River alluvial aquifer. Most sites of groundwater emergence are located immediately upstream from or along the margins of debris fans. A substantial fraction of the ground water approaching a debris fan can emerge to become streamflow. This last observation has three implications. First, very little water can flow the entire length of the study area entirely within the alluvial aquifer because the ground water repeatedly contacts debris-fan sediments over that length. Second, it follows that emerging water containing unique elemental constituents must have entered the alluvial aquifer at a relatively short distance upstream. Third, a gravel aquifer downstream from a large debris fan can transmit more ground water than flows into it through the debris fan. This observation explains how the water table can be naturally, and permanently, located well beneath the level of the bed of a perennial stream.

New Mexico↗
USGS2016

Groundwater quality, age, and susceptibility and vulnerability to nitrate contamination with linkages to land use and groundwater flow, Upper Black Squirrel Creek Basin, Colorado, 2013

The Upper Black Squirrel Creek Basin is located about 25 kilometers east of Colorado Springs, Colorado. The primary aquifer is a productive section of unconsolidated deposits that overlies bedrock units of the Denver Basin and is a critical resource for local water needs, including irrigation, domestic, and commercial use. The primary aquifer also serves an important regional role by the export of water to nearby communities in the Colorado Springs area. Changes in land use and development over the last decade, which includes substantial growth of subdivisions in the Upper Black Squirrel Creek Basin, have led to uncertainty regarding the potential effects to water quality throughout the basin. In response, the U.S. Geological Survey, in cooperation with Cherokee Metropolitan District, El Paso County, Meridian Service Metropolitan District, Mountain View Electric Association, Upper Black Squirrel Creek Groundwater Management District, Woodmen Hills Metropolitan District, Colorado State Land Board, and Colorado Water Conservation Board, and the stakeholders represented in the Groundwater Quality Study Committee of El Paso County conducted an assessment of groundwater quality and groundwater age with an emphasis on characterizing nitrate in the groundwater. Groundwater-quality samples were collected from 50 randomly selected wells between May and June 2013. The samples were analyzed for major ions, nutrients, dissolved gases, tritium ( 3 H), chlorofluorocarbons (CFC-11, CFC-12, and CFC-113), and fuel products (such as benzene, toluene, ethylbenzene, and xylenes). None of the groundwater samples exceeded the U.S. Environmental Protection Agency (EPA) National Primary Drinking Water Regulations for primary maximum contaminant levels (MCL) for major ions. Secondary maximum contaminant levels, which are not health concerns and affect mainly taste, color, or odor of the water, were observed in rare instances for pH (2 samples), chloride (1 sample), iron (3 samples), and manganese (8 samples). The secondary maximum contaminant level for total dissolved solids was also exceeded for two samples. Nitrate (nitrite plus nitrate as nitrogen in groundwater) was elevated above the estimated background concentration of natural recharge waters of 1 milligram per liter (mg/L) in 44 of the 50 wells sampled and showed a median concentration of 5.4 mg/L. Nitrate concentrations were above the MCL of 10 mg/L in 5 of the 50 wells sampled and above half of the EPA MCL (5 mg/L) in 27 of the 50 wells sampled, which included samples above the MCL. Dissolved-oxygen concentrations exceeded 0.5 mg/L in 95 percent of reported values (40 of 42 samples) and exceeded 2.0 mg/L in 90 percent of reported values (38 of 42 samples). The oxidized conditions observed in most areas indicate that nitrate from fertilizers and animal or human waste was geochemically stable and could persist in the groundwater for decades or perhaps longer. A historical analysis of median nitrate concentrations over nearly three decades showed an increase in nitrate of approximately 1 mg/L from 4.3 to 5.4 mg/L, although the increase was not determined to be significantly different using nonparametric statistical methods. Major-ion data indicate that groundwater representative of the primary aquifer was classified as calcium-sodium bicarbonate type water. Other water samples from wells located mainly along the periphery of the primary aquifer had cation-anion compositions consistent with distinct water sources, including groundwater contributions from the underlying bedrock aquifers. The areas with differentiable water sources were located mainly where alluvial deposits were thin and geologic contacts to the underlying bedrock aquifers were relatively shallow. Nitrate concentrations in the groundwater were evaluated for relations to land use. An agricultural region was defined using a sequence of land satellite imagery. Groundwater flow directions interpreted from median water-table elevations measured from 2000 to 2013 were used in conjunction with cropland locations to define the agricultural region boundaries by encompassing potential pathways of nitrate transport in the groundwater from nitrogen-based fertilizers. A statistically significant higher median nitrate concentration was observed for areas inside the agricultural region (6.7 mg/L) compared to areas outside the agricultural region (2.3 mg/L), although median concentrations in both areas were below the MCL (10 mg/L). Median nitrate concentration was also significantly greater in land parcels with septic use (4.9 mg/L) compared to nonseptic parcels (1.7 mg/L). In general, agriculture or septic use was identified as the primary source of nitrate, depending on location, while commercial, county, grazing, and residential land uses were generally secondary sources of nitrate. Apparent groundwater ages were estimated from chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) and tritium ( 3 H) data using models that assumed piston flow and binary mixing (dilution of a young component with old, tracer-free water). The mean and median groundwater ages were about 30 years and the standard deviation was 6 years, indicating that most groundwater in the primary aquifer was “young” water that had recharged to the aquifer over the last few decades (post-1950s). The median fraction of young water was about 71 percent, and the standard deviation was 29 percent. The remaining water predated the 1950s, which may have originated from deeper geologic formations or may represent slow moving groundwater within the primary aquifer. Some of the oldest groundwater ages (older than 30 years) were observed in the upper reaches of the aquifer to the northwest where the primary aquifer is thin and intersects bedrock, supporting the hypothesis of geochemically distinct groundwater entering the primary aquifer from below. Groundwater that had reached the central part of the aquifer from upgradient areas of the basin was variable in age because of differences in flow paths and travel velocities. The groundwater age analysis showed that current (2013) land-use practices could affect water quality over decades to come, and that responses to remedial actions could be slow, especially for constituents, such as nitrate, that are stable under oxidized conditions. Fuel products (including acetone, benzene, diisopropyl ether, ethylbenzene, methyl acetate, methyl tertiary butyl ether (MTBE), methyl tert-pentyl ether, m- + p-xylene, o-xylene, tert-amyl alcohol, tert-butyl alcohol, tert-butyl ethyl ether, and toluene) were analyzed in groundwater from 49 of the 50 wells. Water from seven sites had detections for fuel compounds; all concentrations were below MCL. The results provided assurance of water quality and a valuable baseline to evaluate future trends of fuel constituents as the region is further developed. Probability maps were developed from logistic regression models to examine the likelihood that nitrate concentrations in groundwater exceeded specified levels. Susceptibility analysis examined relations between mid-level (5.0 mg/L) nitrate concentrations and climatic, hydrologic, and geologic variables; the significant variables were identified as depth to groundwater, soil organic matter, and soil water storage to 25-centimeter (cm) depth. The vulnerability assessments included natural factors driving susceptibility but also human factors related to land use and septic use. Vulnerability to low-level (2.5 mg/L) nitrate was related to depth to groundwater, septic zoning, and soil organic matter. The results highlighted that septic zoning affected low-level nitrate concentrations. Vulnerability to mid-level (5.0 mg/L) nitrate was examined using all 50 samples and also with two data outliers removed, which showed relatively high nitrate concentrations but also anomalous water chemistry or were located beyond the primary study area. Vulnerability to mid-level (5.0 mg/L) nitrate using all 50 samples was related to depth to groundwater, land use, septic use within a 500-meter (m) radius, soil water storage to a 25-cm depth, soil organic matter, and whether a location was within the agricultural region. The mid-level (5.0 mg/L) vulnerability model using 48 samples (two outliers removed) produced the best overall fit and was related to the same variables as when using all samples except septic use. The results for mid-level vulnerability provided additional support that septic use was associated with low levels of nitrate in the groundwater. Soil properties and land use were identified as the main drivers of moderate nitrate concentrations. Probabilities of exceeding low-level nitrate concentrations were high in most areas with the lowest probabilities usually to the northwest along thin geologic deposits in the upper part of the basin. The results of this investigation offer the foundational information needed for developing best management practices to mitigate nitrate contamination, basic concepts on water quality to aid public education, and information to guide regulatory measures if policy makers determine this is warranted. Science-based decision making will require continued monitoring and analysis of water quality in the future.

Colorado↗
USGS1980

Quality of ground water in Routt County, northwestern Colorado

Chemical and bacteriological data were collected to describe the quality of water from selected geologic units in Routt County, Colo. Calcium bicarbonate was the dominant water-chemistry type; magnesium, sodium, and sulfate frequently occurred as codominant ions. Specific conductance values ranged from 50 to 6,000 micromhos. Mean values of specific conductance, dissolved solids , and hardness from the sampled aquifers were generally greatest in waters from the older sedimentary rocks of the Lance Formation, Lewis Shale, Mesaverde Group, and Mancos Shale, and least in the ground waters from the alluvial deposits, Browns Park Formation, and the basement complex. Correlations of specific conductance with dissolved solids and specific conductance with hardness were found within specified concentration ranges. On the basis of water-quality analyses, water from the alluvial desposits, Browns Park Formation, and the basement complex generally is the most suitable for domestic uses. Chemical constituents in water from wells or springs exceeded State and Federal standards for public-water supplies or State criteria for agricultural uses were pH, arsenic, boron, chloride, iron, fluoride, manganese, nitrite plus nitrate, selenium, sulfate, or dissolved solids. Total-coliform bacteria were detected in water from 29 sites and fecal-coliform bacteria were detected in water from 6 of the 29 sites. (USGS)

Water-Resources Investigations Report↗
USGS2013

High-density grass carp stocking effects on a reservoir invasive plant and water quality

Stocking grass carp [Ctenopharyngodon idella (Valenciennes)] is a commonly applied technique to control nuisance aquatic vegetation in reservoirs. Factors that influence the degree of aquatic vegetation control are fish stocking density, regional climate, abundance and species composition of the aquatic plant community, and relative grass carp feeding preferences for plant species. We evaluated high-density grass carp stocking in a southeastern U.S. reservoir for control of parrot-feather [Myriophyllum aquaticum (Vell) Verdc.], an invasive aquatic plant that is not preferentially consumed by grass carp and the associated effects on water quality. Lookout Shoals Lake, a 528-ha piedmont North Carolina reservoir, was stocked with triploid grass carp at a density of 100 fish per vegetated hectare. Parrot-feather biomass in the lake was significantly reduced three months after grass carp stocking, compared to biomass in in-situ exclosures. During the second year after grass carp stocking, parrot-feather biomass in the lake compared to biomass in in-situ exclosures indicated continued control, but unexplained lack of growth within most experimental exclosures precluded biomass analyses. Increases in ambient water chlorophyll a, reactive phosphorus, and nitrate-nitrite concentrations were measured after grass carp stocking. The biological significance of observed changes in water chemistry and long-term effects on lake biota remain undetermined. Our results demonstrate that intensive grass carp stocking can control an invasive aquatic plant that is not preferentially consumed by grass carp and reveal associated changes in water quality.

North Carolina↗
USGS2007

Water-quality characteristics for selected sites within the Milwaukee Metropolitan Sewerage District planning area, Wisconsin, February 2004-September 2005

The Milwaukee Metropolitan Sewerage District (MMSD) Corridor Study is a three-phase project designed to improve the understanding of water resources in the MMSD planning area to assist managers and policy makers in their decisions. Phase I of the Study involved the compilation of existing data from multiple agencies into a single database. These data were analyzed to identify spatial, temporal, and technological gaps in the planning area, and were used to develop Phase II of the Study. Phase II, the subject of this report, involved an intensive data-collection effort by the U.S. Geological Survey (USGS) in cooperation with MMSD (from February, 2004, through September, 2005). This phase addressed the data gaps identified in Phase I and completed a baseline assessment of water quality for selected stream and harbor sites in the MMSD planning area. This baseline assessment included evaluations of surface-water chemistry and microbial concentrations in the streams and harbor sites; additionally, stream sites were evaluated for discharge, sediment chemistry, fish-tissue chemistry, habitat, and the quality of biological communities (including fish, macroinvertebrates, and algae). In all, data were collected at 15 stream and 6 harbor sites within the MMSD planning area, including manual sampling and analysis for more than 220 water-quality properties and constituents at all 21 sites, stream-discharge data for 14 stream sites, and automated water-quality sampling at 4 stream sites. A bioassessment during autumn 2004 included collection of biologic-community data and stream-habitat data at wadeable streams. Quartiles of Phase II aggregate bioassessment rankings were used to divide the 14 wadeable stream sites into four groups to investigate relations between bioassessment data and site characteristic and water-quality data. Quartile numbers reflect relative water quality: quartile 1 contained sites where the bioassessment data indicated the least-degraded water quality among those sampled, and quartile 4 contained sites that indicated the most-degraded water quality. Quartiles contained the following stream sites: Quartile 1: Milwaukee River near Cedarburg, Milwaukee River at Milwaukee, Jewel Creek, and Menomonee River at Menomonee Falls; Quartile 2: Willow Creek, Root River near Franklin, and Root River at Grange Avenue; Quartile 3: Menomonee River at Wauwatosa, Oak Creek, and Little Menomonee River; and Quartile 4: Honey Creek, Underwood Creek, Lincoln Creek, and Kinnickinnic River. Site characteristics (in this case, drainage area and land use) and selected water-quality data were summarized based on the four bioassessment quartiles to determine if there were relations with the aggregate bioassessment rankings. In general, sites having the largest drainage basins with the lowest proportion of urban land use were in quartile 1, and the smallest drainage basins with the highest proportion of urban land use were in quartile 4. Major ions, indicator organisms, and wastewater compounds generally had the lowest overall results in quartile 1 and highest overall results in quartile 4, with intermediate results in quartiles 2 and 3. Results for other constituent types (nutrients, mercury, pathogenic organisms, and bed sediment) were mixed, with results for some constituents decreasing from quartile 1 to quartile 4. Where sufficient Phase I data were available, summary statistics (including medians) for chemical and biological data were calculated, allowing some comparisons to be made between Phase I and Phase II data. Comparisons between Phase I and Phase II results indicated a variety of changes with respect to water quality. Concentrations of chloride, nitrate, chlorophyll a, total phosphorus in water; arsenic in bed sediment; and fish Index of Biotic Integrity ratings generally indicated declines in water quality. However, concentrations of total nitrogen, suspended sediment, and fecal coliform in water; some trace eleme

Wisconsin↗
USGS1983

Preliminary appraisal of the hydrology of the Red Oak area, Latimer County, Oklahoma

Bed rock in the Red Oak area consists of shale, siltstone, and sandstone of the McAlester and Savanna Formations of Pennsylvanian age. Water in bedrock occurs in bedding planes, joints, and fractures and is confined. The potentiometric surface generally is less than 20 feet below the land surface. Wells yield enough water for domestic and stock use, but larger amounts of ground water are not available. Ground water commonly is a sodium or mixed cation carbonate/bicarbonate type with dissolved-solids concentrations ranging from 321 to 714 milligrams per liter. Although variable in quality, ground water generally is suitable for domestic use. No relationship between water chemistry and well depth or location is apparent. Brazil Creek, the principal stream in the area, has no flow 15 percent of the time, and flow is less than 1 cubic foot per second about 25 percent of the time. Water in Brazil Creek is a mixed cation carbonate/bicarbonate type. Dissolved-solids concentrations in Brazil Creek upstream from areas of old and recent mining ranged from 31 to 99 milligrams per liter with a mean of 58 milligrams per liter, whereas concentrations downstream from the mine areas ranged from 49 to 596 milligrams per liter with a mean of 132 milligrams per liter. Water in Brazil and Rock Creeks had concentrations of cadmium, chromium, lead, and mercury that exceeded maximum contaminant levels established by the U.S. Environmental Protection Agency at least once during the 1979-81 water years. Maximum suspended-sediment discharge, in tons per day, was 2,500 for Brazil Creek and 3,318 for Rock Creek. Silt-clay particles (diameters less than 0.062 millimeter) were the dominant sediment size. A significant hydrologic effect of surface mining is creation of additional water storage in mine ponds; one such pond supplies water for the town of Red Oak. Other effects or potential effects of surface mining include changes in rock permeability and ground-water storage, changes in drainage patterns, and changes in the chemical quality and sediment loads of streams.

Water-Resources Investigations Report↗
USGS2017

Application of molluscan analyses to the reconstruction of past environmental conditions in estuaries

Molluscs possess a number of attributes that make them an excellent source of past environmental conditions in estuaries: they are common in estuarine environments; they typically have hard shells and are usually well preserved in sediments; they are relatively easy to detect in the environment; they have limited mobility as adults; they grow by incremental addition of layers to their shells; and they are found in all the major environments surrounding estuaries—terrestrial, freshwater, brackish, and marine waters. Analysis of molluscan assemblages can contribute information about past changes in sea level, climate, land use patterns, anthropogenic alterations, salinity, and other parameters of the benthic habitat and water chemistry within the estuary. High-resolution (from less than a day to annual) records of changes in environmental parameters can be obtained by analyzing the incremental growth layers in mollusc shells (sclerochronology). The shell layers retain information on changes in water temperature, salinity, seasonality, climate, river discharge, productivity, pollution and human activity. Isotopic analyses of mollusc shell growth layers can be problematic in estuaries where water temperatures and isotopic ratios can vary simultaneously; however, methods are being developed to overcome these problems. In addition to sclerochronology, molluscs are important to Holocene and Pleistocene estuarine palaeoenvironmental studies because of their use in the development of age models through radiocarbon dating, amino acid racemization, uranium-thorium series dating, and electron spin resonance (ESR) dating.

Book chapter↗
USGS2021

Biological and chemical recovery of acidified Catskill Mountain streams in response to the Clean Air Act Amendments of 1990

Decades of acidic deposition have adversely affected aquatic and terrestrial ecosystems in acid-sensitive watersheds in parts of the eastern United States. The national Acid Rain Program (Title IV of the 1990 Clean Air Act Amendments - CAAA) helped reduce emissions of sulfur dioxide (SO 2 ) and nitrogen oxides (NO x ) and resulted in sharp decreases in the acidity of atmospheric deposition. The decrease in acidic deposition produced a steady decline in the acidity of streams in many poorly buffered waters across the western Adirondacks and parts of the Catskill Mountains of New York. Until recently, however, there has been little evidence of biological recovery in most acid-sensitive streams in both regions. Long-term deposition and stream-chemistry records and fish-community data from quantitative surveys done during 1991–93 and again during 2012–19 at 13 sites in the upper Neversink River and its tributaries were evaluated to determine if chemical and biological recovery were evident in this Catskill Mountain watershed and if they could be linked to regional declines in acidic deposition. Between 1991 and 2019, large decreases in sulfate and nitrate deposition in the basin mirrored declines in total nationwide SO 2 and NO x emissions. There were corresponding decreases in sulfate and nitrate concentrations in deposition at a National Trends Network station at Frost Valley (NY68) and coincident declines in sulfate concentrations at four long-term monitoring sites in the Neversink River watershed. Mean acid neutralizing capacity and pH increased and inorganic aluminum (Al i ) concentrations from routine summertime samples decreased significantly at most moderately to severely acidified sites between the two study periods. Richness, density, and biomass of fish communities increased at most sites, while the density and biomass of brook trout Salvelinus fontinalis populations increased at fewer sites that were undergoing chemical recovery. Although recovery is far from complete, trends in deposition chemistry, water quality, and fish assemblages in streams of the upper Neversink watershed indicate that the 1990 CAAA is having positive impacts on aquatic ecosystems in the Catskill Mountain region, New York.

New York↗
USGS2014

Small reservoir distribution, rate of construction, and uses in the upper and middle Chattahoochee basins of the Georgia Piedmont, USA, 1950-2010

Construction of small reservoirs affects ecosystem processes in numerous ways including fragmenting stream habitat, altering hydrology, and modifying water chemistry. While the upper and middle Chattahoochee River basins within the Southeastern United States Piedmont contain few natural lakes, they have a high density of small reservoirs (more than 7500 small reservoirs in the nearly 12,000 km2 basin). Policymakers and water managers in the region have little information about small reservoir distribution, uses, or the cumulative inundation of land cover caused by small reservoir construction. Examination of aerial photography reveals the spatiotemporal patterns and extent of small reservoir construction from 1950 to 2010. Over that 60 year timeframe, the area inundated by water increased nearly six fold (from 19 reservoirs covering 0.16% of the study area in 1950 to 329 reservoirs covering 0.95% of the study area in 2010). While agricultural practices were associated with reservoir creation from 1950 to 1970, the highest rates of reservoir construction occurred during subsequent suburban development between 1980 and 1990. Land cover adjacent to individual reservoirs transitioned over time through agricultural abandonment, land reforestation, and conversion to development during suburban expansion. The prolific rate of ongoing small reservoir creation, particularly in newly urbanizing regions and developing counties, necessitates additional attention from watershed managers and continued scientific research into cumulative environmental impacts at the watershed scale.

Georgia↗
USGS2012

Upper Clear Creek watershed aquatic chemistry and biota surveys, 2004-5, Whiskeytown National Recreation Area, Shasta County, California

The U.S. Geological Survey, in cooperation with the National Park Service and Whiskeytown National Recreation Area, performed a comprehensive aquatic biota survey of the upper Clear Creek watershed, Shasta County, California, during 2004-5. Data collected in this study can provide resource managers with information regarding aquatic resources, watershed degradation, and regional biodiversity within Whiskeytown National Recreation Area. Surveys of water chemistry, bed-sediment chemistry, algae assemblages, benthic macroinvertebrate assemblages, aquatic vertebrate assemblages, in-stream habitat characteristics, and sediment heterogeneity were conducted at 17 stream sites during both 2004 and 2005, with an additional 4 sites surveyed in 2005. A total of 67 bed-sediment samples were analyzed for major and trace inorganic element concentrations. Forty-six water samples were analyzed for trace metals and nutrients. A total of 224 taxa of invertebrates were collected during these surveys. Eleven fish species, seven of which were native, and two species of larval amphibians, were collected. A total of 24 genera of soft algae and 159 taxa of diatoms were identified. To date, this survey represents the most comprehensive inventory of aquatic resources within Whiskeytown National Recreation Area, and this information can serve as a baseline for future monitoring efforts and to inform management decisions.

California↗
USGS2009

Summary of surface-water quality data from the Illinois River Basin in Northeast Oklahoma, 1970-2007

The quality of streams in the Illinois River Basin of northeastern Oklahoma is potentially threatened by increased quantities of wastes discharged from increasing human populations, grazing of about 160,000 cattle, and confined animal feeding operations raising about 20 million chickens. Increasing numbers of humans and livestock in the basin contribute nutrients and bacteria to surface water and groundwater, causing greater than the typical concentrations of those constituents for this region. Consequences of increasing contributions of these substances can include increased algal growth (eutrophication) in streams and lakes; impairment of habitat for native aquatic animals, including desirable game fish species; impairment of drinking-water quality by sediments, turbidity, taste-and-odor causing chemicals, toxic algal compounds, and bacteria; and reduction in the aesthetic quality of the streams. The U.S. Geological Survey, in cooperation with the Oklahoma Scenic Rivers Commission, prepared this report to summarize the surface-water-quality data collected by the U.S. Geological Survey at five long-term surface-water-quality monitoring sites. The data summarized include major ions, nutrients, sediment, and fecal-indicator bacteria from the Illinois River Basin in Oklahoma for 1970 through 2007. General water chemistry, concentrations of nitrogen and phosphorus compounds, chlorophyll-a (an indicator of algal biomass), fecal-indicator bacteria counts, and sediment concentrations were similar among the five long-term monitoring sites in the Illinois River Basin in northeast Oklahoma. Most water samples were phosphorus-limited, meaning that they contained a smaller proportion of phosphorus, relative to nitrogen, than typically occurs in algal tissues. Greater degrees of nitrogen limitation occurred at three of the five sites which were sampled back to the 1970s, probably due to use of detergents containing greater concentrations of phosphorus than in subsequent periods. Concentrations of nitrogen, phosphorus, and sediment, and counts of bacteria generally increased with streamflow at the five sites, probably due to runoff from the land surface and re-suspension of streambed sediments. Phosphorus concentrations typically exceeded the Oklahoma standard of 0.037 milligrams per liter for Scenic Rivers. Concentrations of chlorophyll-a in phytoplankton in water samples collected at the five sites were not well correlated with streamflow, nor to concentrations of the nutrients nitrogen and phosphorus, probably because much of the algae growing in these streams are periphyton attached to streambed cobbles and other debris, rather than phytoplankton in the water column. Sediment concentrations correlated with phosphorus concentrations in water samples collected at the sites, probably due to sorption of phosphorus to soil particles and streambed sediments and runoff of soils and animal wastes at the land surface and resuspension of streambed sediments and phosphorus during wet, high-flow periods. Fecal coliform bacteria counts at the five sites sometimes exceeded the Oklahoma Primary Body Contact Standard of 400 colonies per 100 milliliters when streamflows were greater than 1000 cubic feet per second. Ultimately, Lake Tenkiller, an important ecological and economic resource for the region, receives the compounds that runoff the land surface or seep to local streams from groundwater in the basin. Because of eutrophication from increased nutrient loading, Lake Tenkiller is listed for impairment by diminished dissolved oxygen concentrations, phosphorus, and chlorophyll-a by the State of Oklahoma in evaluation of surface-water quality required by section 303d of the Clean Water Act. Stored phosphorus in soils and streambed and lakebed sediments may continue to provide phosphorus to local streams and lakes for decades to come. Steps are being made to reduce local sources of phosphorus, including upgrades in capacity and effective

Arkansas, Oklahoma↗
USGS2016

Baseline assessment of groundwater quality in Wayne County, Pennsylvania, 2014

The Devonian-age Marcellus Shale and the Ordovician-age Utica Shale, geologic formations which have potential for natural gas development, underlie Wayne County and neighboring counties in northeastern Pennsylvania. In 2014, the U.S. Geological Survey, in cooperation with the Wayne Conservation District, conducted a study to assess baseline shallow groundwater quality in bedrock aquifers in Wayne County prior to potential extensive shale-gas development. The 2014 study expanded on previous, more limited studies that included sampling of groundwater from 2 wells in 2011 and 32 wells in 2013 in Wayne County. Eighty-nine water wells were sampled in summer 2014 to provide data on the presence of methane and other aspects of existing groundwater quality throughout the county, including concentrations of inorganic constituents commonly present at low levels in shallow, fresh groundwater but elevated in brines associated with fluids extracted from geologic formations during shale-gas development. Depths of sampled wells ranged from 85 to 1,300 feet (ft) with a median of 291 ft. All of the groundwater samples collected in 2014 were analyzed for bacteria, major ions, nutrients, selected inorganic trace constituents (including metals and other elements), radon-222, gross alpha- and gross beta-particle activity, selected man-made organic compounds (including volatile organic compounds and glycols), dissolved gases (methane, ethane, and propane), and, if sufficient methane was present, the isotopic composition of methane. Results of the 2014 study show that groundwater quality generally met most drinking-water standards, but some well-water samples had one or more constituents or properties, including arsenic, iron, pH, bacteria, and radon-222, that exceeded primary or secondary maximum contaminant levels (MCLs). Arsenic concentrations were higher than the MCL of 10 micrograms per liter (µg/L) in 4 of 89 samples (4.5 percent) with concentrations as high as 20 µg/L; arsenic concentrations were higher than the Health Advisory level of 2 µg/L in 27 of 89 samples (30 percent). Total iron concentrations exceeded the secondary maximum contaminant level (SMCL) of 300 µg/L in 9 of 89 samples (10 percent). The pH ranged from 5.4 to 9.3 and did not meet the SMCL range of greater than 6.5 to less than 8.5 in 27 samples (30 percent); 22 samples had pH values less than 6.5, and 5 samples had pH values greater than 8.5. Total coliform bacteria were detected in 22 of 89 samples (25 percent); Escherichia coli were detected in only 2 of those 22 samples. Radon-222 activities ranged from 25 to 7,400 picocuries per liter (pCi/L), with a median of 2,120 pCi/L, and exceeded the proposed drinking-water standard of 300 pCi/L in 86 of 89 samples (97 percent); radon-222 activities were higher than the alternative proposed standard of 4,000 pCi/L in 12 of 89 samples (13.5 percent). Water from 8 of the 89 wells (9 percent) had concentrations of methane greater than the reporting level of 0.24 milligrams per liter (mg/L) with the detectable methane concentrations ranging from 0.74 to 9.6 mg/L. Of 16 replicate samples submitted to another laboratory with a lower reporting level of 0.0002 mg/L, 15 samples had detectable methane concentrations that ranged from 0.0011 to 9.7 mg/L. Of these 15 samples, low levels of ethane (0.00032 to 0.0017 mg/L) were detected in 6 of 7 samples with methane concentrations greater than 0.75 mg/L. The isotopic composition of methane in 6 of 8 samples with sufficient dissolved methane (about 1 mg/L) for isotopic analysis is consistent with a predominantly thermogenic methane source (sample carbon isotopic ratio δ13C CH4 values ranging from -56.36 to -45.97 parts per thousand (‰) and hydrogen isotopic ratio δD CH4 values ranging from -233.1 to -141.1 ‰). However, the low levels of ethane relative to methane indicate that the methane may be of microbial origin and subsequently underwent oxidation. Isotopic compositions indicated a possibly mixed thermogenic and microbial source (carbon dioxide reduction process) for the methane in 1 of the 8 samples (δ 13 C CH4 of -63.72 and δD CH4 of -192.3 ‰) and potential oxidation of microbial and (or) thermogenic methane in the remaining sample (δ 13 C CH4 of -46.56 and δD CH4 of -79.7 ‰). Groundwater samples with relatively elevated methane concentrations (near or greater than 1 mg/L) had a chemical composition that differed in some respects (pH, selected major ions, and inorganic trace constituents) from groundwater with relatively low methane concentrations (less than 0.75 mg/L). The seven well-water samples with the highest methane concentrations (from about 1 to 9.6 mg/L) also had among the highest pH values (8.1 to 9.3, respectively) and the highest concentrations of sodium, lithium, boron, fluoride, arsenic, and bromide. Relatively elevated concentrations of some other constituents, such as barium, strontium, and chloride, commonly were present in, but not limited to, those well-water samples with elevated methane. Groundwater samples with the highest methane concentrations had chloride/bromide ratios that indicate mixing with a small amount of brine (0.02 percent or less, by volume) similar in composition to that reported for gas and oil well brines in Pennsylvania. Most other samples with low methane concentrations (less than about 1 mg/L) had chloride/bromide ratios that indicate predominantly man-made sources of chloride, such as road salt, septic systems, and (or) animal waste. Although naturally occurring brines may originate from deeper parts of the aquifer system, the man-made sources are likely to affect shallow groundwater. Geochemical modeling showed that the water chemistry of samples with elevated pH, sodium, lithium, bromide, and alkalinity could result from dissolution of calcite (calcium carbonate) combined with cation exchange and mixing with a small amount of brine. Through cation exchange reactions (which are equivalent to processes in a water softener) calcium ions released by calcite dissolution are exchanged for sodium ions on clay minerals. The spatial distribution of groundwater compositions generally shows that (1) relatively dilute, slightly acidic, oxygenated, calcium-carbonate type waters tend to occur in the uplands along the western border of Wayne County; (2) waters of near neutral pH with the highest amounts of hardness (calcium and magnesium) generally occur in areas of intermediate altitudes; and (3) waters with pH values greater than 8, low oxygen concentrations, and the highest arsenic, sodium, lithium, bromide, and methane concentrations can occur in deep wells in uplands but most frequently occur in stream valleys, especially at low elevations (less than about 1,200 ft above North American Vertical Datum of 1988) where groundwater may be discharging regionally, such as to the Delaware River. Thus, the baseline assessment of groundwater quality in Wayne County prior to gas-well development shows that shallow (less than about 1,000 ft deep) groundwater is generally of good quality, but methane and some constituents present in high concentrations in brine (and produced waters from gas and oil wells) may be present at low to moderate concentrations in some parts of Wayne County.

Pennsylvania↗
USGS2021

Groundwater and surface-water data from the C-aquifer monitoring program, Northeastern Arizona, 2012–2019

The Coconino aquifer (C aquifer) is a regionally extensive multiple-aquifer system supplying water for municipal, agricultural, and industrial use in northeastern Arizona, northwestern New Mexico, and southeastern Utah. This report focuses on the C aquifer in the arid to semi-arid area between St. Johns, Ariz., and Flagstaff, Ariz., along the Interstate-40 corridor where an increase in groundwater withdrawals coupled with ongoing drought conditions increase the potential for substantial water-level decline within the aquifer. The U.S. Geological Survey (USGS) C-aquifer Monitoring Program began in 2005 to establish baseline groundwater and surface-water conditions and to quantify physical and water-chemistry responses to pumping stresses and climate. This report presents data previously reported in Brown and Macy (2012) that extend back as far as the 1950s, along with new data collected from the USGS C-aquifer Monitoring Program since that publication, from water years 2012 to 2019. Water levels in 17 wells are measured quarterly as part of the C-aquifer Monitoring Program, and five of those are continuously monitored at 15-minute intervals. Water levels in an additional 18 wells in the study area are measured periodically by the USGS or other agencies. The largest historical change in water level in the study area was a decrease of 81.20 feet in Lake Mary 1 Well near Flagstaff between 1962 and 2018. Changes in water levels were greatest around major pumping centers and in the eastern extent of the study area. Surface-water water-quality parameters (pH, water temperature, specific conductance, and dissolved oxygen) and streamflow discharge measurements were collected and analyzed along perennial, groundwater-fed reaches of Clear Creek, Chevelon Creek, and the Little Colorado River during nine baseflow investigations of varying extent between 2005 and 2019. Both Clear Creek and Chevelon Creek gain in flow from the beginning of their perennial reaches to their outflow into the Little Colorado River. The Little Colorado River has relatively steady streamflow in the reach between where the two tributaries enter the river. Chevelon Creek showed an increase in median specific conductance during all baseflow investigations of nearly 4,000 microsiemens per centimeter (μS/cm) from near the headwaters to the confluence with the Little Colorado River; Clear Creek also showed an increase in median specific conductance of almost 5,000 μS/cm from headwaters to confluence. Water temperature, dissolved oxygen, and pH do not show substantial trends along the reaches of Clear Creek, Chevelon Creek, or the Little Colorado River.

Arizona↗
USGS2000

Hydrogeology of the regional aquifer near Flagstaff, Arizona, 1994-97

Sandstones, siltstones, and limestones that are Pennsylvanian to Permian in age underlie the southern part of the Colorado Plateau near Flagstaff, Arizona, and contain a complex regional aquifer that has become increasingly important as a source of water for domestic, municipal, and recreational uses. Ground-water flow in the regional aquifer is poorly understood in this area because (1) depth of the aquifer limits exploratory drilling and testing and (2) the geologic structure increases the complexity of the aquifer characteristics and the ground-water flow system. Four methods were used to improve the understanding of the hydrogeology of the regional aquifer near Flagstaff. • Remote-sensing techniques and geologic mapping provided data to identify many structural features that indicate a more complex structural environment and history than previously realized. • Data from surface-geophysical techniques that included ground-penetrating radar, seismic reflection and seismic refraction, and square-array resistivity, verified that some of the geologic structures expressed at land surface propagate deep into the subsurface and through the principal water-bearing zones of the regional aquifer at near-vertical angles. • A well and spring inventory, borehole-geophysical methods, and well and aquifer tests provided additional information relating aquifer and ground-water flow characteristics to geologic structure. • Water-chemistry data, which included major ion, nutrient, trace-element, and radioactive and stable-isotope analyses, provided an independent means of verifying the hydrogeologic characteristics of the aquifer and were used to determine recharge and discharge areas, groundwater movement, and ground-water age. Ground-water recharge occurs throughout the area but is greatest at higher altitudes where precipitation is greater and in areas where heavily fractured rock units of the aquifer are exposed. The estimated annual average recharge to the regional aquifer in the study area is about 290,000 acre-feet. Ground water flows laterally and vertically through pore spaces in the rock and along faults and other fractures from high-altitude areas in the southern part of the study area to regional drains north of the study area along the Little Colorado and Colorado Rivers, and to drains south of the study area along Oak Creek and the Verde Valley. Ground-water discharge in these areas—about 400,000 acre-feet per year—exceeds the annual recharge to the aquifer in the Flagstaff area, but ground water from areas outside the study area contributes to this discharge as well. The saturated thickness of the regional aquifer averages about 1,200 feet, and the amount of water in storage could be as much as 4,800,000 acrefeet, or about 10 percent of the total volume of the aquifer. The quality of water in the regional aquifer in terms of dissolved-solids concentrations is good for most uses throughout the area. Dissolvedsolids concentrations generally are less than 500 milligrams per liter. Water in the regional aquifer is primarily a calcium magnesium bicarbonate type. In some areas near the Rio de Flag, the water has significant nitrate and chloride components, which indicate direct recharge in these areas from the Rio de Flag. Oxygen and deuterium data indicate a common recharge source for water in the aquifer and that some sites receive recharge from surface waters where evaporation has occurred. Estimated carbon-14 ages and tritium activities indicate ground-water ages from less than 200 years in the Lake Mary area to more than 5,000 years in the Wupatki area. The regional aquifer is heterogeneous and anisotrophic and has a complex ground-water flow system. The most productive water-bearing material tends to be fine- to medium-grained sandstones, and ground-water flow and potential well yields are related to geologic structure. Fracturing associated with structural deformation increases recharge locally and also increases the potential for high well yields. Surface-geophysical techniques provided information on the orientation of high-angle, deep-seated structure in the saturated zone. Borehole-geophysical data identified horizontal to near-horizontal fractures as significant components of the fracture-flow system not apparent in the surface-geophysical data. Structural features that strike northwest appear to be areas that have the greatest potential for high well yields. A north-northeastward-striking structure may be just as promising, but additional data are needed to verify this relation.

Arizona↗