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At least 577 records · Page 32Linked to original sources
USGS2022

Exposure and effects of bioaccumulative contaminants of emerging concern in tree swallows nesting across the Laurentian Great Lakes

Contaminants of emerging concern (CECs) are a loosely defined group of chemicals whose wide-spread usage or presence in the environment has occurred more recently or for which there has been relatively little research done until recently. Many of these CECs are not currently regulated. The National Toxicology Program within the U.S. Department of Health and Human Services estimates that about 2000 CECs are introduced each year (https://ntp.niehs.nih.gov/about/). An unknown number may pose a risk to human or animal health. The Phase 1 (2010 – 2014) CEC work in birds, which is the subject of this report, assessed exposure across the Great Lakes to polybrominated diphenyl ethers (PBDEs), perfluorinated compounds (PFASs), and polycyclic aromatic hydrocarbons (PAHs), and put those exposures into context with data from biologically relevant endpoints such as reproductive success, as well as, physiological response indicators (bioindicators) to assess possible effects. The group of chemicals included in Phase 1 were mainly those chemicals that bioaccumulate in tissues. Phase 2 (2015 – 2019) CEC work with tree swallows was expanded to include CECs whose occurrence in the environment is more temporary or seasonal, and that do not necessarily bioaccumulate. These are often called pseudo-persistent, because, while they are not long-lived in the environment, there are often daily inputs via waste water treatment plants, and run-off from farm fields and storm drainages, thereby making them available to biota year-round. These include pharmaceuticals, personal care products, and newer pesticides including herbicides. Tree swallow work on these less persistent CECs will be reported in the future, however see other Appendices in this report for information on some of these types of CECs (Appendices A, B, D).

Laurentian Great Lakes↗
USGS2004

Snakeheads ( Pisces, Channidae ): A biological synopsis and risk assessment

Snakeheads (family Channidae) are airbreathing freshwater fishes containing two genera, Channa with 26 species native to Asia, Malaysia, and Indonesia; and Parachanna with 3 species native to tropical Africa. Some snakeheads are small, reaching about 17 centimeters, but most are much larger, the largest reported to be 1.8 meters in length. All are considered thrust predators with most being piscivorous as adults. A few of the smaller snakeheads and colorful juveniles of some larger ones have been available to hobbyists through the aquarium fish trade. Several species are highly valued as food fishes within parts of their native ranges, especially in Asia where they are an important part of capture fisheries and aquaculture. Because of these uses by humans, introductions far beyond native ranges have occurred. One Asian snakehead has been established in Oahu, Hawaii, since before 1900. Another species was discovered established in southeastern Florida in 2000, and a third in a pond in Maryland in 2002. Others have been captured from natural waters of the United States without evidence of reproduction and likely represent released aquarium fishes. That snakeheads at or near sexual maturity were being sold alive in ethnic food markets raised fears that they could be introduced into novel waters. These concerns led to this study on the biology of snakeheads. A risk assessment is included that examines environmental and related aspects of snakehead introductions.

Circular↗
USGS1996

Instream investigations in the Beaver Creek Watershed in West Tennessee, 1991-95

The U.S. Geological Survey (USGS), in cooperation with the Tennessee Department of Agriculture, began a long-term scientific investigation in 1989 to evaluate the effect of agricultural activities on water quality and the effectiveness of agricultural best management practices in the Beaver Creek watershed, West Tennessee. In 1993 as a part of this study, the USGS, in cooperation with the Natural Resources Conservation Service, Shelby County Soil Conservation District, and the Tennessee Soybean Promotion Board, began an evaluation of the physical, chemical, biological and hydrological factors that affect water quality in streams and wetlands, and instream resource-management systems to treat agricultural nonpoint-source runoff and improve water quality. The purpose of this report is to present the results of three studies of stream and wetland investigations and a study on the transport of aldicarb from an agricultural field in the Beaver Creek watershed. A natural bottomland hardwood wetland and an artificially constructed wetland were evaluated as instream resource-management systems. These two studies showed that wetlands are an effective way to improve the quality of agricultural nonpoint-source runoff. The wetlands reduced concentrations and loads of suspended sediments, nutrients, and pesticides in the streams. A third paper documents the influence of riparian vegetation on the biological structure and water quality of a small stream draining an agricultural field. A comparison of the upper reach lined with herbaceous plants and the lower reach with mature woody vegetation showed a more stable biological community structure and Water- quality characteristics in the woody reach than in the herbaceous reach. The water-quality characteristics monitored were pH, temperature, dissolved oxygen, and specific conductance. The herbaceous reach had a greater diversity and abundance of organisms during spring and early summer, but the abundance dropped by approximately 85 percent during late summer. A fourth study describes the transport of aldicarb and its metabolites--aldicarb sulfoxide and aldicarb sulfone-in runoff at a small stream draining a cotton field. During 1991 to 1995, aldicarb and its metabolites were detected in runoff events. The highest concentrations occurred when aldicarb was applied to the field just hours before a rain storm. Aldicarb was not detectable in runoff a few weeks after application. The metabolites of aldicarb were detectable for 76 days after application. These studies demonstrate streambank vegetation and wetlands have a significant influence on stream water quality. The importance of weather conditions to herbicide application and runoff also is evident. This information can be used by resource managers to sustain and improve our Nation's streams for future generations.

Water-Resources Investigations Report↗
USGS2010

Lesions and behavior associated with forced copulation of juvenile Pacific harbor seals (Phoca vitulina richardsi) by southern sea otters (Enhydra lutris nereis)

Nineteen occurrences of interspecific sexual behavior between male southern sea otters ( Enhydra lutris nereis ) and juvenile Pacific harbor seals ( Phoca vitulina richardsi ) were reported in Monterey Bay, California, between 2000 and 2002. At least three different male sea otters were observed harassing, dragging, guarding, and copulating with harbor seals for up to 7 d postmortem. Carcasses of 15 juvenile harbor seals were recovered, and seven were necropsied in detail by a veterinary pathologist. Necropsy findings from two female sea otters that were recovered dead from male sea otters exhibiting similar behavior are also presented to facilitate a comparison of lesions. The most frequent lesions included superficial skin lacerations; hemorrhage around the nose, eyes, flippers, and perineum; and traumatic corneal erosions or ulcers. The harbor seals sustained severe genital trauma, ranging from vaginal perforation to vagino-cervical transection, and colorectal perforations as a result of penile penetration. One harbor seal developed severe pneumoperitoneum subsequent to vaginal perforation, which was also observed in both female sea otters and has been reported as a postcoital lesion in humans. This study represents the first description of lesions resulting from forced copulation of harbor seals by sea otters and is also the first report of pneumoperitoneum secondary to forced copulation in a nonhuman animal. Possible explanations for this behavior are discussed in the context of sea otter biology and population demographics.

California↗
USGS1996

U.S. Geological Survey programs in Texas

The U.S. Geological Survey (USGS) is the Federal Government's primary source of data on the quantity and quality of the Nation's water resources, its principal civilian map making agency, and its primary provider of information on natural hazards and mineral, energy, and biological resources. The USGS makes unbiased scientific information available equally to all interested parties. Most USGS work in Texas involves the appraisal of the State's water resources in cooperation with more than 80 local, State, and Federal agencies. The foundation of a wide range of hydrologic data-collection and interpretive programs is the stream-gaging program. The Texas network of streamflow-gaging stations, which provides water data for water-resources planning and design, hydrologic research, and operation of water-resources projects, is part of a nationwide aggregation of networks that is unique because of nationally consistent, prescribed standards by which the data are collected and processed. The USGS continues to expand collection of data for paper and digital maps. The best-known products of the USGS in Texas are its 1:24,000-scale topographic maps. These maps depict basic natural and cultural features of the landscape. Maps at this scale (1 inch on the map represents 2,000 feet on the ground) are useful for civil engineering, land-use planning, and natural-resource monitoring, and have long been favorites with the general public for a wide variety of outdoor uses. The USGS also continues to monitor geologic conditions in Texas associated with rare but potentially dangerous earthquakes. Recently, the Nation Biological Service (now the Biological Resources Division) joined the USGS to continue their appraisal of the nation's biological resources.

Fact Sheet↗
USGS2007

Biological conditions in streams of Johnson County, Kansas, and nearby Missouri, 2003 and 2004

Johnson County is one of the fastest growing and most populated counties in Kansas. Urban development affects streams by altering stream hydrology, geomorphology, water chemistry, and habitat, which then can lead to adverse effects on fish and macroinvertebrate communities. In addition, increasing sources of contaminants in urbanizing streams results in public-health concerns associated with exposure to and consumption of contaminated water. Biological assessments, or surveys of organisms living in aquatic environments, are crucial components of water-quality programs because they provide an indication of how well water bodies support aquatic life. This fact sheet describes current biological conditions of Johnson County streams and characterizes stream biology relative to urban development. Biological conditions were evaluated by collecting macroinvertebrate samples from 15 stream sites in Johnson County, Kansas, in 2003 and 2004 (fig. 1). Data from seven additional sites, collected as part of a separate study with similar objectives in Kansas and Missouri (Wilkison and others, 2005), were evaluated to provide a more comprehensive assessment of watersheds that cross State boundaries. Land-use and water- and streambed-sediment-quality data also were used to evaluate factors that may affect macroinvertebrate communities. Metrics are indices used to measure, or evaluate, macroinvertebrate response to various factors such as human disturbance. Multimetric scores, which integrated 10 different metrics that measure various aspects of macroinvertebrate communities, including organism diversity, composition, tolerance, and feeding characteristics, were used to evaluate and compare biological health of Johnson County streams. This information is useful to city and county officials for defining current biological conditions, evaluating conditions relative to State biological criteria, evaluating effects of urbanization, developing effective water-quality management plans, and documenting changes in biological conditions and water quality.

Kansas, Missouri↗
USGS2007

U.S. Geological Survey Menlo Park campus: Self-guided tour

The U.S. Geological Survey (USGS), established by an act of Congress in 1879, is the Nation's largest natural science and civilian mapping agency. The USGS works in cooperation with more than 2,000 organizations across the country to provide reliable, impartial scientific information. This information is used to minimize the loss of life and property from natural disasters, safeguard the Nation's natural resources, and enhance quality of life through careful monitoring of water, biological, energy, and mineral resources.

California↗
USGS2007

The USGS Salton Sea Science Office

The U.S. Geological Survey's (USGS) Salton Sea Science Office (SSSO) provides scientific information and evaluations to decisionmakers who are engaged in restoration planning and actions associated with the Salton Sea. The primary focus is the natural resources of the Salton Sea, including the sea?s ability to sustain biological resources and associated social and economic values.

Fact Sheet↗
USGS2021

Microplastics in the Delaware River, northeastern United States

Microplastics are a contaminant of increasing concern in aquatic environments. Our understanding of microplastics in freshwater environments has increased dramatically over the past decade, but we still lack information on microplastic occurrence and biological uptake in National Park Service (NPS) waters. During 2015–19, the U.S. Geological Survey and the NPS conducted a three-phase study of microplastic occurrence and biological uptake in NPS waters. This fact sheet summarizes results from Phase 3 in which microplastics were sampled at nine locations spanning various land uses on the Upper Delaware, Middle Delaware, and Lower Delaware Scenic and Recreational River and its tributaries in the northeastern United States. Water and sediment samples were collected during baseflow conditions at each location to assess microplastic occurrence, and fish and mussels were collected at a subset of locations to assess potential biological uptake of microplastics.

Delaware, New Jersey, New York, Pennsylvania↗
USGS2014

Influences of the Tamarisk Leaf Beetle ( Diorhabda carinulata ) on the diet of insectivorous birds along the Dolores River in Southwestern Colorado

We examined the effects of a biologic control agent, the tamarisk leaf beetle (Diorhabda carinulata), on native avifauna in southwestern Colorado, specifically, addressing whether and to what degree birds eat tamarisk leaf beetles. In 2010, we documented avian foraging behavior, characterized the arthropod community, sampled bird diets, and undertook an experiment to determine whether tamarisk leaf beetles are palatable to birds. We observed that tamarisk leaf beetles compose 24.0 percent (95-percent-confidence interval, 19.9-27.4 percent) and 35.4 percent (95-percent-confidence interval, 32.4-45.1 percent) of arthropod abundance and biomass in the study area, respectively. Birds ate few tamarisk leaf beetles, despite a superabundance of D. carinulata in the environment. The frequency of occurrence of tamarisk leaf beetles in bird diets was 2.1 percent (95-percent-confidence interval, 1.3- 2.9 percent) by abundance and 3.4 percent (95-percent-confidence interval, 2.6-4.2 percent) by biomass. Thus, tamarisk leaf beetles probably do not contribute significantly to the diets of birds in areas where biologic control of tamarisk is being applied.

Colorado;Utah↗
USGS2007

Systematic mapping of bedrock and habitats along the Florida Reef tract — Central Key Largo to Halfmoon Shoal (Gulf of Mexico)

The fragile coral reefs of the Florida Keys form the largest living coral reef ecosystem in the continental United States. Lining the shallow outer shelf approximately 5 to 7 km seaward of the keys, the reefs have national aesthetic and resource value. As recently as the 1970s, the coral reefs were the heart of a vibrant ecosystem. Since then, the health of all ecosystem components has declined markedly due to a variety of environmental stressors . Corals are succumbing to bleaching and diseases. Species that are the building blocks of solid reef framework are increasingly being replaced by species that do not construct reef framework. Algal proliferation is increasing competition for space and hard surfaces needed by coral larvae for settlement. Decline of the coral reef ecosystem has significant negative implications for economic vitality of the region, ranging from viability of the tourism industry attracted by the aesthetics to commercial fisheries drawn by the resources. At risk of loss are biologic habitats and reef resources, including interconnected habitats for endangered species in shoreline mangroves, productive nearshore marine and wetland nurseries, and economic offshore fisheries. In 1997, the U.S. Geological Survey's Coastal and Marine Geology Program undertook a comprehensive 7-year-long mission to consolidate, synthesize, and map new (1997) and existing geologic and biologic information into a digitized regional database and one-volume reference source on the geologic history of the Florida Keys reef tract (this report). The project was conducted in cooperation with the National Oceanic and Atmospheric Administration's National Marine Sanctuary Program. The purpose was to examine the natural evolution and demise of several coral reef ecosystems over the past 325,000 years, with an eye toward gaining a better understanding of the cause of the reef decline observed today. Scientific data and datasets presented in this report are intended for use by others in ongoing efforts to delineate which components of reef decline in the Florida Keys may be natural and which may be a result of human activities. Beyond scientific baseline datasets, this report also incorporates environmental, social, and historical aspects of the Florida Keys, including the impact of exploratory oil wells on benthic habitats off Florida.

Florida↗
USGS2013

Selenium in ecosystems within the mountaintop coal mining and valley-fill region of southern West Virginia-assessment and ecosystem-scale modeling

Coal and associated waste rock are among environmental selenium (Se) sources that have the potential to affect reproduction in fish and aquatic birds. Ecosystems of southern West Virginia that are affected by drainage from mountaintop coal mines and valleys filled with waste rock in the Coal, Gauley, and Lower Guyandotte watersheds were assessed during 2010 and 2011. Sampling data from earlier studies in these watersheds (for example, Upper Mud River Reservoir) and other mining-affected watersheds also are included to assess additional hydrologic settings and food webs for comparison. Basin schematics give a comprehensive view of sampled species and Se concentration data specific to location and date. Food-web diagrams document the progression of Se trophic transfer across suspended particulate material, invertebrates, and fish for each site to serve as the basis for developing an ecosystem-scale model to predict Se exposure within the hydrologic conditions and food webs of southern West Virginia. This approach integrates a site-specific predator’s dietary exposure pathway into modeling to ensure an adequate link to Se toxicity and, thus, to species vulnerability. Site-specific fish abundance and richness data in streams documented various species of chub, shiner, dace, darters, bass, minnow, sunfish, sucker, catfish, and central stoneroller (Campostoma anomalum), mottled sculpin (Cottus bairdii), and least brook lamprey (Lampetra aepyptera). However, Se assessment species for streams, and hence, model species for streams, were limited to creek chub (Semotilus atromaculatus) and central stoneroller. Both of these species of fish are generally considered to have a high tolerance for environmental stress based on traditional comparative fish community assessment, with creek chub being present at all sites. Aquatic insects (mayfly, caddisfly, stonefly, dobsonfly, chironomid) were the main invertebrates sampled in streams. Collection of suspended particulate material acted as an integrator of organic-rich, fine-grained biomass present in streams. The base-case food web modeled for streams was suspended particulate material to aquatic insect to creek chub, with comparative modeling of a direct particulate-to-stoneroller food web. Model species for a reservoir setting were based on an earlier study of bluegill sunfish (Lepomis macrochirus), green sunfish (Lepomis cyanellus), and largemouth bass (Micropterus salmoides). Several reservoir food webs were considered based on a variety of invertebrates (insect, snail, clam). For stream and reservoir settings, predicted Se concentrations in exposure scenarios showed a high degree of correlation (r 2 = 0.91 for invertebrates and 0.75 for fish) with field observations of Se concentrations when modeling was initiated from suspended-particulate-material Se concentrations and model transfer parameters defined previously in the literature were used. These strong correlations validate the derived site-specific model and establish sufficient confidence that the predictions from the developed model can be quantitatively applied to the ecosystems in southern West Virginia. An application of modeling used a metric describing the partitioning of Se between particulate material and dissolved phases (K d ) to allow determination of a dissolved Se concentration that would be necessary to attain a site-specific Se fish body burden. The operationally defined K d quantifies the complex process of transformation at the base of a food web on a site-specific basis. The magnitude of this metric is known to vary with such factors as Se speciation, particulate-material type, and hydrology. This application (1) ties dissolved Se concentrations to fish tissue concentrations; (2) allows consideration of different choices for intervening site-specific exposure steps that set Se bioaccumulation, partitioning, and bioavailability; and (3) generates implications for management decisions that define protection through different regulatory pathways and guidelines. The range of model outcomes accounts for critical sources of variability and establishes whether site and food-web characterization were adequate to represent the dynamics of the system with certainty. This is especially true in terms of particulate-material phases at the base of the food web and utilization of K d in different hydrologic settings. For streams, a range of field-derived K d ds were applied to food-web exposure scenarios within a framework of locational and hydrologic variables (area of stream basin; stream gradient and discharge) that may affect the magnitude of K d . Overlaying even a coarse temporal scale that acknowledges variability in stream dissolved Se and Se speciation, such as through seasonal derivation of K d , can substantially narrow model uncertainty. Modeling that constrains the place and time of greatest ecosystem Se sensitivity within a specified food web gives insight into Se risk and identifies controlling management alternatives within a watershed or stream basin. If there is a range of hydrologic settings, specificity is needed to establish a hierarchy of in-stream and off-stream habitats for a watershed approach that takes into account Se-enriched water moving through different K d and food web environments. If there is a range of predator vulnerabilities (measured as a combination of food-web Se biodynamics and response in Se toxicity tests) within the site-specific community of fish species to be protected, then choice of fish species is critical to protection because it determines the food web and, hence, the magnitude of biotransfer through which Se is modeled. Whether creek chub is representative of the vulnerability to Se of all fish species encountered within the study-site ecosystems will require additional species-specific data and analysis. A range of site-specific scenarios illustrated here set model outcomes, but the final quantitative evaluation of alternatives and their implications will be those generated through choices and guidance formulated by state and other agencies in their decisionmaking processes. Proposed additions and refinements to the ecosystem-scale site-specific approach developed here include consideration of: measurement of temporally matched pairs of dissolved and suspended-particulate-material Se concentrations across a broader range of stream sites to expand the stream K d database and to test the representativeness of a suspended-particulate-material sample within a stream; characterization of different phases of particulate material across seasons to better define the base of the food web and connect to invertebrate feeding; refinement of model assumptions concerning dietary preferences and composition for fish to develop additional trophic transfer factors (TTFs) (for example, calculation of TTFinvertebrate composite for mixed diets); expansion of modeling of fish species and their food webs to include Se-vulnerable species; temporal characterization of a predator’s life cycle and habitat use as additional model layers to integrate with Se biodynamics in streams; investigation of the effect of stream gradient on K d based on a finer scale than presented here in terms of such variables as residence time, watershed dilution, and physical habitat attributes (for example, amount of ponding versus run or riffle within a stream); and linkage to discharge through use of stream gaging to record variability and enable model organization within water-year types and discharge seasons. Investigating the presence and variability of prey and predator species in demographically open systems such as streams also is key to model outcomes given the overall environmental stressors (for example, general landscape change, food-web disruption, recolonization potential) imposed on the composition of biological communities in coal mining and valley-fill affected watersheds

West Virginia↗
USGS1992

Hydrogeology, ground-water quality, and potential for water-supply contamination near the Shelby County landfill in Memphis, Tennessee

An investigation was conducted from 1989 to 1991 to collect and interpret hydrogeologic and ground-water-quality data specific to the Shelby County landfill in east Memphis, Tennessee. Eighteen wells were installed in the alluvial and Memphis aquifers at the landfill. Hydrogeologic data collected showed that the confining unit separating the alluvial aquifer from the Memphis aquifer was thin or absent just north of the landfill and elsewhere consists predominantly of fine sand and silt with lenses of clay. A water-table map of the landfill vicinity confirms the existence of a depression in the water table north and northeast of the landfill and indicates that ground water flows northeast from the Wolf River passing beneath the landfill toward the depression in the water table. A map of the potentiometric surface of the Memphis aquifer shows that water levels were anomalously high just north of the landfill, indicating downward leakage of water from the alluvial aquifer to the Memphis aquifer. An analysis of water-quality data for major and trace inorganic constituents and nutrients confirms that leachate from the landfill has migrated northeastward in the alluvial aquifer toward the depression in the water table and that contaminants in the alluvial aquifer have migrated downward into the Memphis aquifer. The leachate plume can be characterized by concentrations of certain major and trace inorganic constituents that are 2 to 20 times higher than samples from upgradient and background alluvial aquifer wells. The major and trace constituents that best characterize the leachate plume are total organic carbon, chloride, dissolved solids, iron, ammonia nitrogen, calcium, sodium, iodide, barium, strontium, boron, and cadmium. Several of these constituents (specifically dissolved solids, calcium, sodium, and possibly ammonia nitrogen, chloride, barium, and strontium) were detected in elevated concentrations in samples from certain Memphis aquifer wells. Elevated concentrations were detected in samples from the Memphis aquifer beneath the leachate plume where the confining unit is thin or absent. The distribution of halogenated alkanes (specifically dichlorodifluoromethane and trichlorofluoromethane) and halogenated alkenes (specifically 1,2-trans-dichloroethene and vinyl chloride) in samples from wells screened in both the alluvial and Memphis aquifers is similar to the distribution of major and trace inorganic constituents that characterize the leachate plume. The ground-water supply most susceptible to contamination from the Shelby County landfill is the Sheahan well field of the Memphis Light, Gas and Water Division. This well field is about 5 miles downgradient from the landfill in the direction of ground-water flow. Based on an estimated velocity of 0.5 to 1.5 feet per day, ground water would require about 50 to 150 years to travel from the Shelby County landfill to the Sheahan wellfield. Given the time and distance of transport, any contaminants in the ground water would not likely persistto reach this well field because of the effects of various physical, chemical, and biological processes, including dilution and adsorption.

Tennessee↗
USGS1987

A flow-simulation model of the tidal Potomac River

A one-dimensional model capable of simulating flow in a network of interconnected channels has been applied to the tidal Potomac River including its major tributaries and embayments between Washington, D.C., and Indian Head, Md. The model can be used to compute water-surface elevations and flow discharges at any of 66 predetermined locations or at any alternative river cross sections definable within the network of channels. In addition, the model can be used to provide tidal-interchange flow volumes and to evaluate tidal excursions and the flushing properties of the riverine system. Comparisons of model-computed results with measured watersurface elevations and discharges demonstrate the validity and accuracy of the model. Tidal-cycle flow volumes computed by the calibrated model have been verified to be within an accuracy of ? 10 percent. Quantitative characteristics of the hydrodynamics of the tidal river are identified and discussed. The comprehensive flow data provided by the model can be used to better understand the geochemical, biological, and other processes affecting the river's water quality.

District of Columbia, Maryland, Virginia↗
USGS2016

Sources, distributions and dynamics of dissolved organic matter in the Canada and Makarov Basins

A comprehensive survey of dissolved organic carbon (DOC) and chromophoric dissolved organic matter (CDOM) was conducted in the Canada and Makarov Basins and adjacent seas during 2010–2012 to investigate the dynamics of dissolved organic matter (DOM) in the Arctic Ocean. Sources and distributions of DOM in polar surface waters were very heterogeneous and closely linked to hydrological conditions. Canada Basin surface waters had relatively low DOC concentrations (69 ± 6 μmol L −1 ), CDOM absorption ( a 325 : 0.32 ± 0.07 m −1 ) and CDOM-derived lignin phenols (3 ± 0.4 nmol L −1 ), and high spectral slope values ( S 275–295 : 31.7 ± 2.3 μm −1 ), indicating minor terrigenous inputs and evidence of photochemical alteration in the Beaufort Gyre. By contrast, surface waters of the Makarov Basin had elevated DOC (108 ± 9 μmol L −1 ) and lignin phenol concentrations (15 ± 3 nmol L −1 ), high a 325 values (1.36 ± 0.18 m −1 ), and low S 275–295 values (22.8 ± 0.8 μm −1 ), indicating pronounced Siberian river inputs associated with the Transpolar Drift and minor photochemical alteration. Observations near the Mendeleev Plain suggested limited interactions of the Transpolar Drift with Canada Basin waters, a scenario favoring export of Arctic DOM to the North Atlantic. The influence of sea-ice melt on DOM was region-dependent, resulting in an increase (Beaufort Sea), a decrease (Bering-Chukchi Seas), and negligible change (deep basins) in surface DOC concentrations and a 325 values. Halocline structures differed between basins, but the Canada Basin upper halocline and Makarov Basin halocline were comparable in their average DOC (65–70 μmol L −1 ) and lignin phenol concentrations (3–4 nmol L −1 ) and S 275–295 values (22.9–23.7 μm −1 ). Deep-water DOC concentrations decreased by 6–8 μmol L −1 with increasing depth, water mass age, nutrient concentrations, and apparent oxygen utilization. Maximal estimates of DOC degradation rates (0.036–0.039 μmol L −1 yr −1 ) in the deep Arctic were lower than those in other ocean basins, possibly due to low water temperatures. DOC concentrations in bottom waters (>2500 m; 46 ± 2 μmol L −1 ) of the Canada and Makarov Basins were slightly lower than those reported for deep waters of the Eurasian Basin and Nordic Seas. Elevated a 325 values (by 10–20%) were observed near the seafloor, indicating biological activity in Arctic basin sediments.

Frontiers in Marine Science↗