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At least 577 records · Page 32Linked to original sources
USGS2011

Hydrology, phosphorus, and suspended solids in five agricultural streams in the Lower Fox River and Green Bay watersheds, Wisconsin, water years 2004-06

A 3-year study was conducted by the U.S. Geological Survey and the University of Wisconsin-Green Bay to characterize water quality in agricultural streams in the Fox/Wolf watershed in northeastern Wisconsin and provide information to assist in the calibration of a watershed model for the area. Streamflow, phosphorus, and suspended solids data were collected between October 1, 2003, and September 30, 2006, in five streams, including Apple Creek, Ashwaubenon Creek, Baird Creek, Duck Creek, and the East River. During this study, total annual precipitation was close to the 30-year normal of 29.12 inches. The 3-year mean streamflow was highest in the East River (113 ft 3 /s), followed by Duck Creek (58.2 ft 3 /s), Apple Creek (26.9 ft 3 /s), Baird Creek (12.8 ft 3 /s), and Ashwaubenon Creek (9.1 ft 3 /s). On a yield basis, during these three years, the East River had the highest flow (0.78 ft 3 /s/mi 2 ), followed by Baird Creek (0.61 ft 3 /s/mi 2 ), Apple Creek (0.59 ft 3 /s/mi 2 ), Duck Creek (0.54 ft 3 /s/mi 2 ), and Ashwaubenon Creek (0.46 ft 3 /s/mi 2 ). The overall median total suspended solids (TSS) concentration was highest in Baird Creek (73.5 mg/L), followed by Apple and Ashwaubenon Creeks (65 mg/L), East River (40 mg/L), and Duck Creek (30 mg/L). The median total phosphorus (TP) concentration was highest in Ashwaubenon Creek (0.60 mg/L), followed by Baird Creek (0.47 mg/L), Apple Creek (0.37 mg/L), East River (0.26 mg/L), and Duck Creek (0.22 mg/L). The average annual TSS yields ranged from 111 tons/mi 2 in Apple Creek to 45 tons/mi2 in Duck Creek. All five watersheds yielded more TSS than the median value (32.4 tons/mi 2 ) from previous studies in the Southeastern Wisconsin Till Plains (SWTP) ecoregion. The average annual TP yields ranged from 663 lbs/mi 2 in Baird Creek to 382 lbs/mi 2 in Duck Creek. All five watersheds yielded more TP than the median value from previous studies in the SWTP ecoregion, and the Baird Creek watershed yielded more TP than the statewide median of 650 lbs/mi 2 from previous studies.Overall, Duck Creek had the lowest median and volumetric weighted concentrations and mean yield of TSS and TP. The same pattern was true for dissolved phosphorus (DP), except the volumetrically weighted concentration was lowest in the East River. In contrast, Ashwaubenon, Baird, and Apple Creeks had greater median and volumetrically weighted concentrations and mean yields of TSS, TP, DP than Duck Creek and the East River. Water quality in Duck Creek and East River were distinctly different from Ashwaubenon, Baird, and Apple Creeks. Loads from individual runoff events for all of these streams were important to the total annual mass transport of the constituents. On average, about 20 percent of the annual TSS loads and about 17 percent of the TP loads were transported in 1-day events in each stream.

Wisconsin↗
USGS2017

Electrical resistivity investigation of fluvial geomorphology to evaluate potential seepage conduits to agricultural lands along the San Joaquin River, Merced County, California, 2012–13

Increased flows in the San Joaquin River, part of the San Joaquin River Restoration Program, are designed to help restore fish populations. However, increased seepage losses could result from these higher restoration flows, which could exacerbate existing drainage problems in neighboring agricultural lands and potentially damage crops. Channel deposits of abandoned river meanders that are hydraulically connected to the river could act as seepage conduits, allowing rapid and widespread water-table rise during restoration flows. There is a need to identify the geometry and properties of these channel deposits to assess their role in potential increased seepage effects and to evaluate management alternatives for reducing seepage. Electrical and electromagnetic surface geophysical methods have provided a reliable proxy for lithology in studies of fluvial and hyporheic systems where a sufficient electrical contrast exists between deposits of differing grain size. In this study, direct-current (DC) resistivity was used to measure subsurface resistivity to identify channel deposits and to map their subsurface geometry. The efficacy of this method was assessed by using DC resistivity surveys collected along a reach of the San Joaquin River in Merced County, California, during the summers of 2012 and 2013, in conjunction with borings and associated measurements from a hydraulic profiling tool. Modeled DC resistivity data corresponded with data from cores, hand-auger samples, a hydraulic profiling tool, and aerial photographs, confirming that DC resistivity is effective for differentiating between silt and sand deposits in this setting. Modeled DC resistivity data provided detailed two-dimensional cross-sectional resistivity profiles to a depth of about 20 meters. The distribution of high-resistivity units in these profiles was used as a proxy for identifying areas of high hydraulic conductivity. These data were used subsequently to guide the location and depth of wells installed onsite for monitoring flow in the channel deposits. Estimates of the cross-sectional area of channel deposits from DC resistivity pseudosections can provide critical input for groundwater-flow models designed to simulate river seepage and evaluate seepage-management alternatives.

California↗
USGS2018

Monitoring the water-quality response of agricultural conservation practices in the Bucks Branch watershed, Sussex County, Delaware, 2014–16

The purpose of this study was to evaluate the effects of irrigation and cover crops as conservation practices on water quality in groundwater and streams. Bucks Branch, a stream in the Nanticoke River watershed in southwestern Delaware, was identified as having one of the highest concentrations of nitrate in all surface-water sites sampled by the Delaware Department of Natural Resources and Environmental Control (DNREC). The study site is on two adjacent fields bordering Bucks Branch, one that has used irrigation since 2000 and one with dryland farming; both under conservation tillage and long-term rotation of corn, soybean, and small grain crops. A streamgage was installed near the study site fields to measure streamflow and water quality. The study area is typical of farming practices and environmental conditions throughout much of the intensively farmed agricultural land of the Coastal Plain of Delaware and surrounding parts of Maryland. Monitoring was conducted from January 2014 through June 2016. Corn was grown on both fields during the two growing seasons of the study period, and cover crops were planted before or shortly after harvest on both fields. During the second year of data collection, the effects of radish and rye grass cover crops on nutrient transport were studied. The combined results from data collected for this study show that water and nitrate moved below the root zone year round when soil moisture was high, especially after significant rainfall and frequently after irrigation. Soil water sampled 2 to 3 weeks after nutrients were applied had nitrate concentrations greater than 50 milligrams per liter as nitrogen (mg/L as N) and may be a significant source of nitrate to groundwater. Whereas recharge containing elevated nitrate concentrations also occurred under the dryland field, it was less frequent and of lower concentration than recharge under the irrigated field. Nitrate was present in all groundwater samples from these sites. Groundwater estimated to have recharged within 10 years or less had higher median concentrations of nitrate than in older water samples. The oldest groundwater encountered was over 30 years old, and had traveled along the longest, deep flowpaths from upland fields to the stream. The median nitrate concentration was 18 mg/L as N in younger water (less than 10 years old) beneath the irrigated field, compared to about 10 mg/L as N in younger water beneath the dryland field. Samples from the shallow upland wells in both study fields showed little, if any, evidence of denitrification. Several samples from deeper wells and from wells near forested riparian zone wetlands that border both fields did show partial denitrification. A mixing model estimated that between 12 and 22 percent of the nitrate discharging to the stream was lost through uptake and denitrification upstream of the streamgage on Bucks Branch. Continuous data collected at this site and evidence of denitrification in the surface-water samples showed a greater potential for loss of nitrate during the warmer months than the colder months. This pattern was similar to that seen below the streamgage at the most downstream site in the watershed. A mixed cover crop of radishes and rye was planted prior to removal (radishes) and just after harvest (rye) of the corn crop on the irrigated field. Rye grass was planted shortly after crop harvest on the dryland field. Cover crop biomass samples collected while radishes were growing and after they were killed by freezing temperatures indicates that the early planted radish crop effectively scavenged available nitrogen from the soil. Whereas radish biomass initially held more nitrogen than rye, at 55 to 8 pounds per acre, respectively, leaching of inorganic nitrate following radish die-off was minimal. Soil-water nitrate concentrations during the cover-crop growing period were lower than during the growing season prior to planting of the cover crop. There also was an increase in soil fertility and dissolved organic nitrate in samples of soil water that was likely related to increased soil microbial metabolism. Results indicate that cover crops stored plant nutrients over the winter and did not increase shallow groundwater concentrations of nitrate. Although conservation practices such as cover crops and nutrient management have been applied to these fields, there was still significant leaching of nitrate to groundwater, especially under the irrigated field. This will likely continue to be a challenge in this area and other parts of the Coastal Plain where soil moisture capacity is relatively low and managing irrigation around rainfall is difficult. Cover crops, when planted in standing corn, are one practice that can effectively pull nitrate from below the root zone to the top layer of soil, thus limiting the amount of potential nitrate leaching to groundwater. Irrigation management that would lower average soil moisture conditions during the growing season also could potentially limit nitrogen transport.

Delaware↗
USGS2021

Characterization of groundwater quality and discharge with emphasis on selenium in an irrigated agricultural drainage near Delta, Colorado, 2017–19

Selenium is a water-quality constituent of concern for aquatic ecosystems in the lower Gunnison River Basin. Selenium is derived from bedrock of the Mancos Shale and is mobilized and transported to groundwater and surface water by application of irrigation water. Although it is recognized that groundwater contributes an appreciable amount of selenium to surface water, few studies have addressed interactions between the two. The U.S. Geological Survey in cooperation with the Colorado Water Conservation Board conducted a study during 2017–19 to characterize the quality and quantity of groundwater discharging to an agricultural drainage near Delta, Colorado, locally known as Sunflower Drain. Water quality in the study area is characterized by high dissolved solids with elevated concentrations of selenium and nitrate resulting from dissolution of soluble salts in the Mancos Shale. Selenium concentrations have decreased by 50 percent since the early 2000s, possibly in response to irrigation system improvements. Stable water isotopes indicate streamflow is dominated by canal water during the irrigation season (April to October) and, during the nonirrigation season (November to March), is dominated by groundwater that has undergone some degree of evaporation. Pesticide and pharmaceutical compounds were infrequently detected, and results indicate they were derived from sources outside the study area such that they do not appear to be useful as tracers of groundwater sources. Stable isotopes of nitrate indicate that nitrate originates from the Mancos Shale, and the isotopic composition is enriched by denitrification in the groundwater system. Using a mass-balance approach, estimated groundwater discharge rates to Sunflower Drain ranged from 0.15 to 0.27 cubic feet per second per mile with one losing reach identified. Selenium, sulfate, and nitrate concentrations in groundwater estimated by mass-balance calculations were similar to concentrations measured in the Poly 17 observation well, located in a largely irrigated area in east tributary. One tributary reach had higher concentrations of selenium, sulfate, and nitrate likely reflecting localized inputs of more concentrated groundwater, similar to the concentrations in the Poly 7 observation well, which is downgradient from a residential area in the west tributary. Three pilot studies were conducted, including fiber optic distributed temperature sensing to detect groundwater discharge zones in the stream channel, a passive seismic technique to estimate depth to bedrock, and use of radon-222 as a geochemical tracer of groundwater discharge. All three techniques show promise as additional approaches for investigating groundwater discharge surface-water systems in irrigated drainage areas on Mancos Shale. The factors that affect groundwater movement mainly include when and where irrigation water is transported and applied, and the distribution of bedrock of the Mancos Shale and overlying alluvial deposits. The average groundwater recharge rate for the study area was estimated at 8.1 inches per year, based on mass balance calculations from synoptic survey data. Along the western tributary of Sunflower Drain, there was evidence that spills from the East Canal may recharge the groundwater aquifer adjacent to the stream channel. Groundwater movement to the stream channel may be controlled by the topography of the alluvial/bedrock interface or focused along human-made features, such as tile drains and ditches constructed around irrigated fields. On larger scales, the top of bedrock was also important, creating a topographic constriction that caused a zone of groundwater discharge. The groundwater system is complex, and further study could better define the system, possibly through application of a groundwater flow model and more extensive studies using some of the exploratory methods evaluated in this study.

Colorado↗
USGS2021

Aquaculture and Irrigation Water-Use Model (AIWUM) version 1.0—An agricultural water-use model developed for the Mississippi Alluvial Plain, 1999–2017

Water use is a critical and often uncertain component of quantifying any water budget and securing reliable and sustainable water supplies. Recent water-level declines in the Mississippi Alluvial Plain (MAP), especially in the central part of the Mississippi Delta, pose a threat to water sustainability. Aquaculture and Irrigation Water-Use Model (AIWUM) 1.0, one of the first national agricultural water-use models that provides water use at the scale of most groundwater models, was developed and compared to other reported and estimated aquaculture and irrigation water-use values within the MAP study area for 1999 through 2017 to improve water-use estimates needed as input to a hydrologic decision-support system in the MAP. Results indicate annual total water-use estimates from 1999 through 2017 ranged from about 5 to 13 billion gallons per day and, on average, a majority of the water use was applied to rice (about 51 percent), followed by soybeans (about 26 percent), and less than (<) 10 percent each was applied to aquaculture, corn, cotton, and other crops. Comparisons indicated that annual total water-use estimates from AIWUM 1.0 were smaller than or comparable to all other sources of water-use data. Although there is disagreement at the monthly timescale in estimates in the Mississippi Delta within each part of the growing season, the annual total water use is comparable between AIWUM 1.0 and the Mississippi Embayment Regional Aquifer Study groundwater model 2.1. Estimates from AIWUM 1.0 could be used in models at all scales (for example, local, regional, national) and could provide a nationally consistent methodology in estimating water use driven by regional crop-specific withdrawal rates.

Arkansas, Illinois, Kentucky, Louisiana, Mississip↗
USGS2021

Workflow for using unmanned aircraft systems and traditional geospatial data to delineate agricultural drainage tiles at edge-of-field sites

Managing nutrient and sediment runoff from fields that drain to the Great Lakes is key to mitigating harmful algal blooms. Implementation of best management practices on agricultural land is considered a critical step to improving water quality in these streams, however the effect of these best management practices is difficult to quantify. The purpose of this study was to use a suite of high-resolution imagery acquired with unmanned aircraft systems (including a combination of visible, multispectral, and thermal cameras) to better characterize edge-of-field (EOF) sites in Michigan and Wisconsin that are monitored in cooperation with the Great Lakes Restoration Initiative. This high-resolution imagery (2.5–12-centimeter ground resolution) was used to delineate artificial subsurface drainage (tile-drain) networks and surface water flow paths that indicate contributing areas (that is, all area that drains to a monitored point) at these EOF sites, providing better characterization of each study site. Contributing areas for these sites ranged from 2.86 to 5.07 hectares and, among the sites, tile drains were identified as those that followed soil properties and those that were more densely patterned networks. These surveys also indicated that the contributing area monitored at the EOF sites may cross field boundaries and is not always coincident with the area underlain by subsurface drainage.

Indiana, Michigan, Ohio, Wisconsin↗
USGS2024

Pesticides in surface water downstream of and near agricultural and developed land in Hawai‘i, 2015–19

Pesticides and pesticide degradates (herein referred to as pesticides) in surface water were assessed at 78 sites on 4 Hawaiian Islands (Kauaʻi, Oʻahu, Maui, and Island of Hawaiʻi) during 2015–19. Each site was downstream of or near agricultural land, developed land, or both. Most (58) sites were streams; the remaining sites were canals, ditches, anchialine pools, coastal ponds, and the nearshore ocean. Pesticides in water at each site were assessed by collection of one to four water samples, by a weeks-long deployment of a passive sampler, or both. Passive-sampler extracts and water samples, which consisted of fair-weather samples and storm samples, were analyzed for as many as 253 pesticides that consisted of 129 herbicides, 101 insecticides, and 23 fungicides. A total of 117 pesticides were detected in water. Of these, 30 pesticides were detected at more than 20 percent of their assessment sites and thus were considered “common” pesticides. The common pesticides included 17 herbicides (ametryn, atrazine, bentazon, bromacil, diuron, hexazinone, metolachlor, propazine, simazine, triclopyr, prometryn, and degradates of atrazine [4], diuron, hexazinone, and prometryn); 8 insecticides (carbaryl, dinotefuran, fipronil, flubendiamide, imidacloprid, methoxyfenozide and 2 degradates of fipronil); and 5 fungicides (azoxystrobin, metalaxyl, propiconazole, a degradate of chlorothalonil, and a degradate of thiophanate-methyl and benomyl). Common pesticides typically were present more frequently in storm samples than in fair-weather samples. A mixture of two or more pesticides was detected in 86 percent of the water samples and in water during every passive-sampler deployment. About 92 percent of all pesticide detections had concentrations less than 100 nanograms per liter. Pesticide concentrations were less than Federal aquatic-life benchmarks (ALBs) for vertebrates and typically were less than ALBs for invertebrates, nonvascular plants, and vascular plants. Acute ALBs were exceeded by acetochlor, atrazine, carbaryl, chlorpyrifos, cis-permethrin, diazinon, diuron, halosulfuron methyl, and imidacloprid in storm samples at one to four sites. ALBs for invertebrates were exceeded by clothianidin, diazinon, fipronil, and imidacloprid in fair-weather samples, during passive-sampler deployments, or both at 1 to 17 sites. Federal drinking water standards were available for only five pesticides detected in water, and the standard for atrazine was exceeded in one storm sample. Pesticide concentrations did not exceed any Federal human-health benchmarks, but many of the detected pesticides did not have a benchmark.

Hawaii↗
USGS2000

Ground-water quality and vulnerability to contamination in selected agricultural areas of southeastern Michigan, northwestern Ohio, and northeastern Indiana

Ground-water quality was assessed in the northeastern part of the Corn Belt, where tile-drained row crops are underlain by fractured glacial till. Data were collected from 30 shallow monitor wells and 18 co-located domestic wells as part of the U.S. Geological Survey’s National Water- Quality Assessment in the Lake Erie-Lake St. Clair Basin. Pesticides or pesticide degradates were detected in 41 percent of the monitor wells and 6 percent of the domestic wells. The pesticides detected closely correspond to those most heavily applied—herbicides used on corn and soybeans. Pesticide degradates were detected three times more frequently, and at higher concentrations, than were parent compounds. No pesticide concentration exceeded a USEPA Maximum Contaminant Level (MCL), but MCL’s have not been established for 9 of the 11 compounds detected. Thirty-seven percent of monitor-well samples had nitrate concentrations indicative of human influences such as fertilizer, manure or septic systems. Nitrate was the only chemical constituent detected at a concentration greater than an MCL. The MCL was exceeded in 7 percent of samples from monitor wells which were too shallow to be used as a source of drinking water. Pesticide and nitrate concentrations in the study area are low relative to other agricultural areas of the Nation. Several authors have suggested that ground water in parts of the Upper Midwest is minimally contaminated because it is protected by the surficial glacial till or tile drains. These ideas are examined in light of the relations between concentration, well depth, and groundwater age in the study area. Most of the shallow ground water is hydraulically connected to the land surface, based on the observations that 83 percent of waters from monitor wells were recharged after 1953, and 57 percent contained a pesticide or an elevated nitrate concentration. Fractures or sand-and-gravel stringers within the till are the probable pathways. In some areas, deeper parts of the groundwater- flow system are also hydraulically connected to the land surface. Almost half the waters from wells 50 to 100 feet deep were recharged after 1953. Anthropogenic constituents were detected in samples from three domestic wells 60 to 121 feet deep, in areas where the till is relatively coarse-grained. The hydrogeologic system has several geochemical characteristics conducive to transformations or sorption of nitrate or pesticides: (1) the till is clay-rich, has a high organic-carbon content, and contains an abundance of pyrite-rich shale fragments, (2) the ground water has low dissolved- oxygen concentrations, and (3) iron and manganese oxides and oxyhyroxides line the faces of fractures in the unsaturated zone. Although the aquifer system appears be protected from contamination in some areas, the fact that the surficial till is heterogeneous and of variable thickness suggests that the protection is not uniform. The protection can be breached by fractures or sand-and-gravel stringers, which are apparent in core samples but not noted on domestic-well logs.

Indiana, Michigan, Ohio↗
USGS2002

Evapotranspiration from selected fallowed agricultural fields on the Tule Lake National Wildlife Refuge, California, during May to October 2000

An investigation of evapotranspiration, vegetation quantity and composition, and depth to the water table below the land surface was made at three sites in two fallowed agricultural lots on the 15,800-hectare Tule Lake National Wildlife Refuge in northern California during the 2000 growing season. All three sites had been farmed during 1999, but were not irrigated since the 1999 growing season. Vegetation at the lot C1B and lot 6 stubble sites included weedy species and small grain plants. The lot 6 cover crop site supported a crop of cereal rye that had been planted during the previous winter. Percentage of coverage by live vegetation ranged from 0 to 43.2 percent at the lot C1B site, from approximately 0 to 63.2 percent at the lot 6 stubble site, and it was estimated to range from 0 to greater than 90 percent at the lot 6 cover crop site. Evapotranspiration was measured using the Bowen ratio energy balance technique and it was estimated using a model that was based on the Priestley-Taylor equation and a model that was based on reference evapotranspiration with grass as the reference crop. Total evapotranspiration during May to October varied little among the three evapotranspiration measurement sites, although the timing of evapotranspiration losses did vary among the sites. Total evapotranspiration from the lot C1B site was 426 millimeters, total evapotranspiration from the lot 6 stubble site was 444 millimeters, and total evapotranspiration from the lot 6 cover crop site was 435 millimeters. The months of May to July accounted for approximately 78 percent of the total evapotranspiration from the lot C1B site, approximately 63 percent of the evapotranspiration from the lot 6 stubble site, and approximately 86 percent of the total evapotranspiration from the lot 6 cover crop site. Estimated growing season precipitation accounted for 16 percent of the growing-season evapotranspiration at the lot C1B site and for 17 percent of the growing-season evapotranspiration at the lot 6 stubble and cover crop sites. The ratio of evapotranspiration rate to the reference evapotranspiration rate was strongly correlated with percentage of site coverage by vegetation at the lot C1B and lot 6 stubble sites (correlation coefficient = 0.95, sample size = 6), where percentage of site coverage was determined from quantitative vegetation surveys. It is concluded that evapotranspiration was mediated by the vegetation at all three sites, and that the differences in seasonal timing of evapotranspiration losses were caused by differences in timing of vegetation growth and development and senescence among the sites. Depth to the water table below the land surface at lot C1B ranged from 0.67 meters in early July to greater than 1.39 meters in late August. Depth to the water table at lot 6 ranged from 0.77 meter in late May to greater than 1.40 meters in late August.

Water-Resources Investigations Report↗
USGS2002

Ground-water monitoring plan, water quality, and variability of agricultural chemicals in the Missouri River alluvial aquifer near the City of Independence, Missouri, well field, 1998-2000

A detailed ground-water sampling plan was developed and executed for 64 monitoring wells in the city of Independence well field to characterize ground-water quality in the 10-year zone of contribution. Samples were collected from monitoring wells, combined Independence well field pumpage, and the Missouri River at St. Joseph, Missouri, from 1998 through 2000. In 328 ground-water samples from the 64 monitoring wells and combined well field pumpage samples, specific conductance values ranged from 511 to 1,690 microsiemens per centimeter at 25 degrees Celsius, pH values ranged from 6.4 to 7.7, water temperature ranged from 11.3 to 23.6 degrees Celsius, and dissolved oxygen concentrations ranged from 0 to 3.3 milligrams per liter. In 12 samples from the combined well field pumpage samples, specific conductance values ranged from 558 to 856 microsiemens per centimeter at 25 degrees Celsius, pH values ranged from 6.9 to 7.7, water temperature ranged from 5.8 to 22.9 degrees Celsius, and dissolved oxygen concentrations ranged from 0 to 2.4 milligrams per liter. In 45 Missouri River samples, specific conductance values ranged from 531 to 830 microsiemens per centimeter at 25 degrees Celsius, pH ranged from 7.2 to 8.7, water temperature ranged from 0 to 30 degrees Celsius, and dissolved oxygen concentrations ranged from 5.0 to 17.6 milligrams per liter. The secondary maximum contaminant level for sulfate in drinking water was exceeded once in samples from two monitoring wells, the maximum contaminant level (MCL) for antimony was exceeded once in a sample from one monitoring well, and the MCL for barium was exceeded once in a sample from one monitoring well. The MCL for iron was exceeded in samples from all monitoring wells except two. The MCL for manganese was exceeded in all samples from monitoring wells and combined well field pumpage. Enzyme linked immunoassay methods indicate total benzene, toluene, ethyl benzene, and xylene (BTEX) was detected in samples from five wells. The highest total BTEX concentration was less than the MCL of toluene, ethyl benzene, or xylene but greater than the MCL for benzene. Total BTEX was not detected in samples from any well more than once. Atrazine was detected in samples from nine wells, and exceeded the MCL once in a sample from one well. Alachlor was detected in samples from 22 wells but the MCL was never exceeded in any sample. Samples from five wells analyzed for a large number of organic compounds indicate concentrations of volatile organic compounds did not exceed the MCL for drinking water. No semi-volatile organic compounds were detected; dieldrin was detected in one well sample, and no other pesticides, herbicides, polychlorinated biphenyls, or polychlorinated napthalenes were detected. Dissolved ammonia, dissolved nitrite plus nitrate, dissolved orthophosphorus, alachlor, and atrazine analyses were used to determine the spatial and temporal variability of agricultural chemicals in ground water. Detection frequencies for dissolved ammonia increased with well depth, decreased with depth for dissolved nitrite plus nitrate, and remained relatively constant with depth for dissolved orthophosphorus. Maximum concentrations of dissolved ammonia, dissolved nitrite plus nitrate, and dissolved orthophosphorus were largest in the shallowest wells and decreased with depth, which may indicate the land surface as the source. However, median concentrations increased with depth for dissolved ammonia, were less than the detection limit for dissolved nitrite plus nitrate, and decreased with depth for dissolved orthophosphorus. This pattern does not indicate a well-defined single source for these constituents. Dissolved orthophosphorus median concentrations were similar, but decreased slightly with depth, and may indicate the land surface as the source. Seasonal variability of dissolved ammonia, dissolved nitrite plus nitrate, and dissolved orthophosphorus concentrations is not well-defined for samples grouped by month. Individual sample results from the Missouri River and the combined Independence well field pumpage show a seasonal trend that may indicate the effect of induced recharge from the Missouri River on the well field. Individual results and samples from seven wells indicate relatively constant dissolved ammonia concentrations, low dissolved nitrite plus nitrate concentrations in all but one well, and a more well-defined seasonal variation of dissolved orthophosphorus than either dissolved ammonia or dissolved nitrite plus nitrate. Larger detection frequencies in the shallow depth intervals and the large maximum concentrations of alachlor and atrazine in the shallower wells indicate that the source of these chemicals to shallow ground water most likely is the land surface rather than induced river recharge. Seasonal variability of alachlor is not well-defined from samples grouped by month. Individual results from the combined Independence well field pumpage and samples from seven wells indicate variation in both alachlor and atrazine with time, but the degree and timing of the variation is not consistent. This inconsistency most likely is caused by varying rates of transport from the land surface to wells, different rates of degradation of both alachlor and atrazine in soil and ground water, the timing and area of application, and multiple source areas in and around the Independence well field. Alachlor and atrazine concentrations in the Missouri River at Hermann, Missouri, increased in spring, greater concentrations continued until late summer or early fall, and lower concentrations occurred in late fall and winter. Alachlor and atrazine concentrations most likely followed a similar trend in the Missouri River near the Independence well field. The lack of a seasonal trend similar to that of the Missouri River in the combined Independence well field pumpage and the monitoring wells may indicate that the source of alachlor and atrazine to ground water is the land surface rather than the Missouri River.

Missouri↗
USGS2003

Changes in nutrient and pesticide concentrations in urban and agricultural areas of the South Platte River Basin, Colorado, Wyoming, and Nebraska, 1994–2000

As part of the National Water-Quality Assessment (NAWQA) Program, the U.S. Geological Survey (USGS) monitored two sites on the main-stem South Platte River? an urban site in Denver and a mixed urban/agricultural site near Kersey?to determine changes in nutrient and pesticide concentrations from 1994 through 2000. Concentrations of nitrate, nitrite, ammonia, and orthophosphorus decreased at the Denver site during the study period, likely due to an increase in instream dilution of wastewater-treatment plant (WWTP) discharge and upgrades at the WWTPs. In contrast, only concentrations of orthophosphorus decreased at the Kersey site; agricultural inputs between Denver and Kersey may have offset the observed decreases in other nutrients upstream. During the extreme low-flow conditions in 1994, when there was relatively little snowmelt to dilute instream pesticide concentrations, total median pesticide concentrations at both sites were the highest of the study period. During the less extreme conditions in 1997 through 2000, greater amounts of snowmelt likely led to lower total median pesticide concentrations at both sites. Because pesticide-use data are not available, the contribution of changes in the amount and type of pesticides applied on the land to changes in the concentration of pesticides in the river is not known but likely was substantial. In general, insecticides predominated at the Denver site, whereas herbicides predominated at the Kersey site.

Colorado, Nebraska, Wyoming↗
USGS2000

Water-quality assessment of part of the Upper Mississippi River Basin, Minnesota and Wisconsin - Ground-water quality in an agricultural area of Sherburne County, Minnesota, 1998

The quality of shallow ground water in a 75-mi 2 agricultural area of the Anoka Sand Plain aquifer in central Minnesota is described as part of the National Water Quality Assessment (NAWQA) Program - a national-scale assessment of the quality of water resources within large study units in various hydrologic settings. Data were collected during 1998 from 29 wells completed in the aquifer, which predominantly consists of surficial glacial sand and gravel sediments. The depth below land surface to the water table ranged from 3.3 to 44 ft (median of 15.5 ft). Ground water was of the calciummagnesium bicarbonate type. Ionic constituents also included sodium, sulfate, and chloride. Iron and manganese concentrations generally were not greater than their U.S. Environmental Protection Agency (USEPA) Secondary Maximum Contaminant Levels (300 and 50 ug/L, respectively). About 38 percent of 29 samples had nitrate-N (nitrogen) concentrations greater than the USEPA Maximum Contaminant Level (MCL) of 10 mg/L. About 72 percent of the samples had nitrate-N concentrations greater than the presumed natural background level of 3 mg/L. The maximum nitrate-N concentration was 47 mg/L. The median nitrate-N concentration of 7.1 mg/L, although not greater than the MCL, exceeded the natural background level. Nitrogen isotope ratios indicate that the sources of nitrate were commercial fertilizer and soil organic matter. Concentrations of total dissolved phosphorus and orthophosphate were generally less than 1 mg/L. About 86 percent of 29 samples had detectable concentrations of at least 1 of 13 pesticide compounds. The samples were analyzed for 83 pesticide compounds. Frequencies of detection of these compounds were: deethylatrazine-79 percent; atrazine-76 percent; metolachlor-41 percent; metribuzin and bentazon-21 percent; prometon-10 percent; tebuthiuron-7 percent; and alachlor, 2,6-diethylaniline, dicamba, dinoseb, malathion, and simazine-3 percent. The detected pesticide compounds had concentrations less than 1 ug/L. Detected compounds with USEPA MCLs (atrazine, bentazon, alachlor, dinoseb, and simazine) had concentrations less than their respective MCLs. About 50 percent of 20 samples analyzed for 86 volatile organic compounds (VOCs) had detectable concentrations of at least 1 of 7 VOCs. Frequencies of detection of these 7 VOCs were: 1,2,3,4-tetramethylbenzene-40 percent; and trichlorofluoromethane, styrene, chloromethane, benzene, methylbenzene, and trichloromethane-5 percent. The detected VOCs had concentrations less than 0.120 ug/L. Detected VOCs with USEPA MCLs - styrene, benzene, methylbenzene, and trichloromethane - were present at concentrations 2-4 orders of magnitude less than their respective MCLs. Tritium concentrations had a range of from 7.5 to 18.8 tritium units (TUs) and a median of 12.5 TUs. These concentrations indicate that the ground water predominantly recharged after testing of thermonuclear weapons during the early 1950's.

Minnesota↗
USGS1979

Pesticide residues in agricultural drains, southeastern desert area, California

A study is being made to determine the occurrence and distribution of pesticides in the agricultural drains for approximately 3/4 million irrigated acres in the southeastern desert area of California. This report describes the results of the first year of sampling and analyzing (1) water in the drains , (2) bed material in the drains, (3) water from field tile-drainage lines, and (4) irrigation tailwater and water in the drains directly exposed to drift from aerial application of pesticides. Residues of almost all the pesticides selected for monitoring were found in water in the drains. Examination of the data to determine the probable source of pesticides indicated generally slight concentrations from bed material in the drains, usually no detectable concentrations from field tile-drainage lines, and apparently large concentrations from irrigation tailwater and drift from aerial application. (Woodard-USGS)

Water-Resources Investigations Report↗
USGS1978

A preliminary appraisal of the impact of agriculture on ground-water availability in southwest Georgia

Irrigated acreage in the study area in southwest Georgia increased from 130,000 acres in 1976 to 261,000 in 1977. Acreage irrigated entirely by ground water increased 85 percent for the same period. The largest quantity of ground water used for irrigation was in the Dougherty Plain district, where 92 percent of supplemental irrigation water comes from wells. In the Tifton Upland district, ground water is the source for only 16 percent of the irrigation water used. The major ground-water reservoir supplying the irrigation water is the principal artesian aquifer. The Dougherty Plain, because of the gently rolling land surface and large fields, is suitable for the use of large self-propelled center-pivot irrigation systems requiring 1,200 to 1,500 gallons per minute. The installed pump capacity of the irrigation systems in the Dougherty Plain using ground water was 1.8 billion gallons per day in 1977. The total amount of water pumped for irrigation in the Dougherty Plain in 1977 was more than 42 billion gallons, 30 billion gallons more than in 1976. This quantity could be considerably higher in 1978 as preparations were being made to irrigate more than 214,000 acres during the 1978 growing season. There were no concentrations of selected organic compounds or trace metals used in agricultural chemicals above the recommended limits for public consumption in water analyzed from 19 wells. However, concentrations of total nitrite plus nitrate ranged from 0.3 to 7.8 milligrams per liter in wells in the Dougherty Plain, and this could indicate that the downward percolation of water through sandy soils has carried soluble nitrate, a byproduct of fertilizer, into the ground-water reservoir.

Georgia↗
USGS1984

Runoff, sediment transport, and water quality in a northern Illinois agricultural watershed before urban development, 1979-81

A study designed to quantify and evaluate changes in runoff and sediment transport attributable to construction activities during urban development of a watershed required identification of pre-construction hydrologic conditions. Data collected before construction on a 2.81 sq m (7.28 sq km) agricultural watershed (upper Spring Creek) near Rockford, IL, show that during a 2-year period ending June 30, 1981, 2,890 tons (2,620 Mg) of suspended sediment were transported from the watershed. Of the 2 ,890 tons (2,620 Mg), 2,690 tons (2,440 Mg) or 93.1 % were transported during a storm in a 46.6-hour period of June 13-14, 1981. Runoff from a 0.031 sq m (0.080 sq km) subbasin (Spring Creek tributary) transported 33.9 tons (30.9 Mg) of suspended sediment during a 3.2-hour storm period on June 13, 1981. Regression models relating storm suspended-sediment yields and peak-water discharge per square mile for upper Spring Creek and Spring Creek tributary have average standard errors of 57 and 24 %, respectively. Trace amounts of currently banned pesticides, including Aldrin and DDT, were detected in streambed material samples. Documented sediment yields, chemical quality, and relations between runoff and sediment discharge provide baseline information for future evaluation of hydrologic conditions in the watershed. (USGS)

Water-Resources Investigations Report↗
USGS1986

Ground-water yield and potential for irrigated agriculture in the area of the Naval Magazine and Radio Transmitting Facility, Lualualei, Oahu, Hawaii

An estimated additional 2 million gallons per day (mgd) of fresh and slightly brackish water can be developed in Lualualei Valley , Hawaii, for the agricultural outleasing project. Several of these wells could be located in the volcanic aquifer which presently produces water of excellent quality. A secondary line of wells designed to develop water from the Coralline aquifer would capture the flow not captured by the wells in the volcanic aquifer. The chloride concentration of the water pumped from these wells is expected to range between 500 and 1,500 mg/L. The amount of acreage devoted to crops would depend primarily on the water quality and quantity requirements of the type of crops cultivated and on the type of irrigation system employed. The remaining acreage could be allocated for pasture to graze beef cattle. (Author 's abstract)

Water-Resources Investigations Report↗
USGS1988

Effects of agricultural irrigation on water resources in the St. Joseph River basin, Indiana, and implications for aquifer yield

During the past decade, the acreage of irrigated agricultural land in Indiana has tripled, causing public concern about competition for water and resulting in several State laws for regulating water withdrawals. The St. Joseph River basin represents less than one-tenth of the area of the State, but it contains one-third of the State 's irrigated land. Irrigated land in the basin is composed of permeable soils that are underlain by productive glacial aquifers. A computer model was used to analyze the effects of maximum irrigation withdrawals on aquifer drawdown and streamflow in a 16.5 sq mi area of intensive irrigation. Simulation of maximum pumping resulted in predicted aquifer drawdowns of one-fourth of the total available drawdown. Flow in a nearby stream was decreased by 40%. Areas of most intensive irrigation in the basin also are areas that have productive aquifers and well-sustained streamflows. Aquifer yield is based on the concept of capture - the volume of increased recharge to the aquifer or decreased discharge from the aquifer that results from pumping. The high rates of capture for aquifers in the basin supply ample water for present (1982) irrigation and for substantial future development. (USGS)

Indiana↗
USGS1989

Evaluation of a watershed model to simulate sediment transport in a small agricultural watershed in Indiana

The streamflow and sediment components of the watershed model, ' Hydrologic Simulation Program-Fortran ', were evaluated using 2 years and 9 months of data from a 2.7-sq mi agricultural watershed in Indiana. Hydrographs of simulated sediment concentration generally have smaller peaks and longer recessions than do hydrographs of measured data. The attenuation of simulated peaks was partly caused by difficulties in designing a representative channel system. Simulated surface runoff during low-intensity rainfall was greater than measured surface runoff; this caused an overestimation of sediment concentration and discharge. Rainfalls of low intensity were mostly absorbed by the soil, but the model predicted that the amount of surface runoff from such storms would be large. The overly large volume of simulated surface runoff transported more sediment than actually occurred. The mean absolute error of mean sediment concentrations during storms is 45% of the measured average concentration. The error resulted from a combination of error in recording streamflow and rainfall, in simulating streamflows, and in simulating sedimentation processes. The largest percent errors are associated with simulated maximum streamflows and average sediment discharges. The root-mean-square errors are 93 and 102% of the measured maximum streamflow and average sediment discharges. (USGS)

Indiana↗