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At least 559 records · Page 31Linked to original sources
USGS2024

Toxicity of crude oil-derived polar unresolved complex mixtures to Pacific herring embryos: Insights beyond polycyclic aromatic hydrocarbons

Crude oil toxicity to early life stage fish is commonly attributed to polycyclic aromatic hydrocarbons (PAHs). However, it remains unclear how the polar unresolved complex mixture (UCM), which constitutes the bulk of the water-soluble fraction of crude oil, contributes to crude oil toxicity. Additionally, the role of photomodification-induced toxicity in relation to the polar UCM is not well understood. This study addresses these knowledge gaps by assessing the toxicity of two laboratory generated polar UCMs from Cook Inlet crude oil, representing the readily water-soluble fraction of crude oil and photoproduced hydrocarbon oxidation products (HOPs), to Pacific herring ( Clupea pallasii ) embryos. A small-scale semi-static exposure design was utilized with a range of polar UCM concentrations (0.5–14 mg/L) in nonvolatile dissolved organic carbon (NVDOC) units, quantifying the entire polar UCM. Compositional analyses revealed a photochemical-driven shift toward more complex aromatic compositions, naphthenic acids, and no detectable levels of PAHs (above 0.3 μg/L). Exposure to the dark polar UCM resulted in higher mortality than exposure to the light polar UCM. Both dark and light polar UCMs induced developmental abnormalities commonly attributed to the PAH fraction, including edema, reduced heart rate, body axis defects, and decreased body lengths, with these effects observed at the lowest dose group (0.5 mg/L NVDOC). These responses suggest photomodification-induced toxicity is driven by exposure to increased concentrations of dissolved HOPs rather than photochemical induced compositional changes. Gene expression analyses focusing on xenobiotic metabolism and cardiac morphogenesis yielded results consistent with previous studies examining the biological mechanisms of crude oil toxicity. In summary, these phenotypic and genotypic responses in Pacific herring embryos indicate that the polar UCM is a significant driver of crude oil toxicity. These findings emphasize the importance of considering the polar UCM in future studies, metric reporting, and risk assessments related to crude oil toxicity.

Science of the Total Environment↗
USGS2024

Increased mercury concentrations in walleye and yellow perch in lakes invaded by zebra mussels

Zebra mussels ( Dreissena polymorpha ) are invasive species that alter ecosystems and food webs with the potential to affect aquatic mercury cycling and bioaccumulation in fishes, although the effect of zebra mussels on fish tissue mercury has not been tested in inland lakes. We assessed differences in fish tissue mercury concentrations and food webs in Minnesota lakes with and without zebra mussels while controlling for other lake and watershed characteristics. Mercury concentrations in adult walleye ( Sander vitreus ) and yellow perch ( Perca flavescens ) were 72 % and 157 % higher, respectively, in lakes containing zebra mussels compared to uninvaded lakes. Mercury in young of year (age-0) fish was also elevated, with mercury concentrations 97 % and 82 % higher in age-0 walleye and yellow perch, respectively, in zebra mussel lakes. Walleye mercury concentrations exceeded 0.22 ppm — a threshold triggering more restrictive human consumption advisories for sensitive populations — at a 23 % smaller size, and average-sized walleye (420 mm) exceeded this threshold at a rate of 77 % in invaded lakes, compared to 35 % in uninvaded lakes. Walleye and yellow perch relied more on littoral resources in lakes with zebra mussels but did not feed at meaningfully higher trophic levels. Increased fish tissue mercury in lakes invaded by zebra mussels have consequential implications for fisheries and human health.

Minnesota↗
USGS2025

Groundwater flowpath characteristics drive variability in per- and polyfluoroalkyl substances (PFAS) loading across a stream-wetland system

Groundwater-dependent ecosystems in areas with industrial land use are at risk of exposure to a PFAS chemicals. We investigated one such system with several known PFAS source areas, where high and low permeability sediments (glacial) coupled with groundwater-lake and groundwater/surface-water interactions created complex ‘source to seep’ dynamics. Using heat-tracing and chemical methods, numerous preferential groundwater discharge zones were identified and sampled across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, downgradient of Joint Base Cape Cod (JBCC). Surface-water and groundwater samples were analyzed for 40 PFAS compounds between March and October 2022. Samples were collected from groundwater seeps identified as preferential discharge points (PDPs), wells upgradient of the stream-wetland system, contributing flow-through kettle lakes, and along Quashnet River surface-waters. PFAS from sampled waters contained perfluorinated carboxylates (PFPea, PFHxA, PFNA), perfluorinated sulfonates (PFBS, PFPeS, PFHxS, PFOS), fluorotelomer sulfonates (6:2, 8:2 FtS), and perfluoroalkyl sulfonamides (PFOSA). Samples from PDPs and wells had measured PFAS concentrations ranging from non-detect to 4677 ng/L ng/L (mean = 418 ng/L, std. = 709 ng/L), and a range of deuterium excess values (3.2 to 15.9 per mil) indicative of varying degrees of groundwater-lake interaction prior to groundwater flowpath emergence at PDPs. Correlations ( p < 0.01) between deuterium excess, %PFAS precursors, and terminal PFAS compounds highlighted potential precursor transformations associated with lake-groundwater exchange along flowpaths sourcing PDPs. However, some seepages had higher total PFAS concentrations (>1000 ng/L) than upgradient kettle lakes despite showing lake (evaporative) isotopic signatures, indicating the potential for groundwater flowpath convergence at wetland discharge zones and the influence of lakebed PFAS precursor reactions. Results from these synoptic surveys address gaps in the existing PFAS literature by demonstrating the importance of subsurface fate and transport on PFAS compound concentrations and mass loading in preferential groundwater discharge zones.

Massachusetts↗
USGS2025

Pesticide contamination detected across five wildlife refuges in the Sacramento Valley of California

An important goal for the applied ecological sciences is to understand the extent to which the biodiversity on conserved or managed lands is exposed to anthropogenic stressors. Among the various categories of conserved lands in the United States, the National Wildlife Refuge System is focused on the protection and management of native wildlife and plant populations. Refuge lands can be associated with wetlands and, especially in California, tend to be near areas of intense human use, including agriculture. The proximity of refuges to cultivated lands results in potential exposure to pesticide drift, which increases the possibility of non-target effects on plants and wildlife. We used a passive sampler approach to quantify aerial pesticide deposition during 28 days in spring of 2023, across five refuges in the Sacramento Valley of California. Pesticides were detected across all refuges and plots within the study area, with 36 individual compounds identified, including insecticides, herbicides, and fungicides, from 176 silicone bands from 49 plots. Distance to agriculture was not an important predictor in our models for most indices of contamination. However, our models revealed that the nearest crop type was an important mediator of the importance of distance to agriculture, as fungicide contamination decreased with distance to agriculture only when orchards were the nearest crop type. The overall lack of distance effects suggests that the interior of refuges in the study area do not necessarily provide more protection from pesticides than refuge edges, although larger refuges could offer more protection. We currently lack information on how the level of contamination found herein is biologically relevant to wildlife, and ongoing monitoring efforts have found productive communities of insects in the study area. The results of this study provide a foundation for future investigations on refuges to analyze impacts of specific pesticide compounds on plants and wildlife.

California↗
USGS2025

A geospatial analysis of water-quality threats from orphan wells in principal and secondary aquifers of the United States

Throughout the history of oil and gas production in the United States, millions of wells have been drilled for exploration and energy production. Hundreds of thousands of unplugged wells are no longer actively producing and are currently under orphan status, with no responsible party obligated for plugging. Orphan wells can pose threats to water resources by providing pathways for contaminants such as hydrocarbons and brines to migrate into water-supply aquifers. In this study, we investigate the potential threats to groundwater resources posed by orphan wells at the national scale. Water-quality data is extremely sparse in relation to orphan wells nationally and may not be suitable for identifying contamination from oil and gas development. We used geospatial and statistical methods to evaluate which principal and secondary aquifer systems may be most susceptible to contamination from orphan wells. Analysis involved three sets of susceptibility factors including: 1) factors related to the number and density of orphan wells; 2) factors that can threaten well integrity and contribute to transport of contaminants; and 3) factors related to groundwater withdrawal rates and the affected populations/communities in the event of water quality disturbances. From a dataset of 117,672 documented orphan wells, 64,203 fall within a principal aquifer system, while the remainder fall within a secondary aquifer system. By assessing the combination of well integrity and hydrogeologic factors within these aquifer systems, five groupings of principal aquifers were identified, where groups ranged from aquifer systems with high numbers of orphan wells, multiple well integrity threats and high withdrawals, to aquifers with a relatively low number of orphan wells, limited well integrity threats and minimal water use. Three regions of the country emerge containing aquifers with higher susceptibility to contamination from orphan oil and gas wells. These regions include 1) The Appalachian Basin (including the Pennsylvanian Aquifer System), 2) The Gulf Coast Aquifers (including the Coastal Lowlands Aquifer system) and 3) The California Aquifers (including the California Coastal Basin Aquifer system). This work is the first multivariate geospatial investigation of orphan wells and groundwater resources on a national scale, and sheds light on which aquifers are most susceptible to groundwater contamination from orphan wells.

Science of the Total Environment↗
USGS2025

Temporal and spatial comparison of coal mine ventilation methane emissions and mitigation quantified using PRISMA satellite data and on-site measurements

Emission monitoring at the facility level (bottom-up, BU) is key for accurate reporting of coal mine methane (CMM) emissions. Recent advances in aerial and satellite observations (top-down, TD) indicate that these methods have the potential to support CMM emissions monitoring and reporting of, as well as track the effectiveness of, mitigation actions. That said, studies have shown discrepancies between BU and TD estimations. Performing TD monitoring with concurrent BU measurements at the same mines may help address the observed discrepancies and improve quantification methods to narrow the gap between BU and TD data. This paper presents a comparison of concurrent BU-TD methane emission fluxes monitored from two ventilation shafts at a southwestern Virginia, USA, longwall mine to complement the existing body of studies on satellite-based monitoring of coal mines by incorporating continuous ground-based monitoring with concurrent TD monitoring of methane emission fluxes to address the gap and provide valuable insights into temporal emission patterns. The shafts were monitored on multiple dates between 2020 and 2023. BU monitoring was performed at the exhaust fans, while TD quantifications used PRISMA hyperspectral satellite data and two different wind reanalysis datasets (i.e., GEOS-FP and ERA5). This mine also offered a unique opportunity for BU-TD comparisons before and after ventilation air methane (VAM) oxidizer operation, which was installed at one of the shafts in 2022. The results showed that TD-estimated mean fluxes were generally lower than BU data, which were attributed to quantification difficulties associated with the low albedo caused by heavy vegetation and the terrain of the area. However, despite the discrepancies in mean emissions, both the interquartile range and the data range of the distributions generally overlapped, and the estimates correctly showed the emission trends.

Virginia↗
USGS2025

A review of post-wildfire adaptations of surface-water-quality models: Synthesis, gaps, and opportunities

As wildfires increasingly affect water-supply watersheds, the demand for models to predict water-quality responses is increasing. This work reviews and synthesizes existing post-wildfire applications of water-quality models in the context of geographic and ecohydrological distribution, hydrologic and water-quality response process representation, model parameterization, model and input data scales, model calibration data availability, as well as calibration and performance evaluation approaches. Emphasis is placed on models that simulate water-quality output, rather than sediment and erosional response as the primary focus. Here, identified gaps and opportunities to advance the post-wildfire application of water-quality models include: 1. applying models in under-represented geographic and ecohydrologic regions, 2. simulating multiple streamflow generation mechanisms, including groundwater, with an emphasis on shifting dominant flow pathways as the landscape recovers following wildfire, 3. adding studies that include the simulation of metals, 4. incorporating more biogeochemical and in-stream processes to model applications, 5. applying finer spatial and temporal resolution of precipitation data input as well as finer spatial resolution hydrologic response units, 6. implementing fully distributed grid or element models or finer resolution response units to capture burn severity heterogeneity, 7. collecting enhanced water-quality data for model calibration and validation, 8. conducting model-intercomparison studies, and 9. developing model parameter value guidance in post-wildfire applications. These identified gaps and opportunities may assist users in deciding on key processes and approaches to consider in modeling post-wildfire water-quality conditions.

Science of the Total Environment↗
USGS2025

Relations of groundwater quality to long-term surface disposal of produced water near the Midway-Sunset and Buena Vista Oil Fields, California, USA

Contamination of groundwater by oil-field fluids in proximity to oil and gas development has been an issue of concern to water users and regulators given long histories of development and legacy disposal practices. A robust set of geochemical tracers including petroleum hydrocarbon compounds, thermogenic gases, inorganic ion concentrations, stable isotopes, radioactive isotopes, and noble gases were used to assess if oil-field fluids mixed with groundwater near the Midway-Sunset and Buena Vista Oil Fields in California, USA. Results show evidence of mixing of oil-field fluids with groundwater within the study area from either anthropogenic or natural processes. Produced water plumes associated with modern surface disposal facilities, used since the late 1950s, extend up to 1.5 km and currently remain within the boundaries of the oil fields. Plumes associated with earlier routing of produced water down natural drainages and in large retention structures (Midway Basin and Sunset Basin) near the Buena Vista Lake Bed are present in groundwater east of the oil fields. Based on geochemical tracer evidence, aerial imagery, and aerial electromagnetic surveys, these legacy plumes reach the western portion of the Central Valley aquifer system, an important groundwater resource for agricultural and domestic supply. The legacy plume associated with Sunset Basin may further be detected downgradient in deeper groundwater beneath the southern extent of the Buena Vista Lake Bed based on the presence of thermogenic gases and petroleum hydrocarbon compounds.

California↗
USGS2025

Streamflow regime characterization in the changing boreal ecosystem: Wildfire impacts from stream-to-regional scales

The boreal ecosystem has experienced significant changes over recent decades as wildfires become more frequent, intense, and severe. As streams are highly prevalent and ecologically relevant, understanding interactions among wildfire and hydrologic patterns is important for effective aquatic ecosystem management. This study used a Bayesian mixture model to classify streamflow regimes from modeled streamflow data for 32,730 stream reaches (totaling 295,880 km) across the Yukon and Kuskokwim basins and the Northwestern Boreal Ecosystem in Alaska, USA, and Yukon Territory, Canada. We assessed time since burn and calculated the total length of stream (km) within burn perimeters for each streamflow class from 1985 to 2015. Additionally, we used field observations (2018–2022) to compare streamflow regimes in four burned and four unburned headwater streams (drainage basins ≤150 km 2 ) in interior Alaska. Modeled stream reaches were grouped into twenty-two classes and reduced to eleven metaclasses based on similarities in streamflow statistics. These metaclasses formed two broad groups: 1) large rivers with lower variability and strong seasonal signals, and 2) mid- to small-sized tributaries with high variability, frequent high flow events, and weaker seasonal signals. The stream length burned analysis indicated an average increase of 47 km per year with first- and second-order streams experiencing more frequent fire. Empirical streamflow metrics from headwater stream gages revealed additional differences in streamflow patterns between burned and unburned streams. This streamflow classification establishes a baseline for understanding boreal stream responses to wildfire, detecting climate-induced regime shifts, and facilitating management and conservation of important boreal aquatic species.

Alaska↗
USGS2025

Soil-microbial communities respond less than plant communities to synthetic- or bio-herbicides applied to address the exotic grass-fire cycle in rangelands

The exotic grass-fire cycle is degrading semiarid rangelands, such as the vast areas of shrub-steppe in North America now invaded by fire-promoting cheatgrass. Chemical- or bio-herbicides are sprayed onto soils to inhibit the invaders, but information on chemical- or bio-herbicide impacts to soil microbial communities is limited. We asked how the soil-microbiome responded to the bioherbicide Pseudomonas fluorescens strain ACK55 in comparison to the separate and combined effects of a conventional pre-emergent chemical herbicide, imazapic, in two cheatgrass-invaded sagebrush-steppe sites. First-year microbial responses were evaluated using targeted sequencing of the 16S and LSU rRNA genes for bacteria+archaea and fungi, respectively, and were related to plant-community responses. A strong cheatgrass reduction with imazapic at one site was accompanied by a small shift in bacteria+archaea (16S) community composition with no effect on microbial alpha diversity, and this shift was small in comparison to natural microbiome variation between sites. ACK55 was not detected in soil a year after application, and it caused only transient and marginally significant reductions in annual grass cover accompanied by small reductions in soil fungi species richness. Full-length sequencing of the ACK55 16S rRNA gene and phylogenetic analyses revealed that ACK55 is more likely P. salmonii than P. fluorescens . Knowledge gaps remain on the duration and consequences of microbial-community shifts with imazapic and why molecular analyses showed ACK55 did not persist in soils. Confusion regarding microbial biopesticides can result where isolation, effectiveness testing, commercial release, and regulation are not guided by molecular taxonomic analyses.

Idaho↗
USGS2025

Projecting stream water quality using Weighted Regression on Time, Discharge, and Season (WRTDS): An example with drought conditions in the Delaware River Basin

Future water availability depends on understanding the responses of constituent concentrations to hydrologic change. Projecting future water quality remains a methodological challenge, particularly when using discrete observations with limited temporal resolution. This study introduces Weighted Regression on Time, Discharge, and Season for Projection (WRTDS-P), a novel, computationally efficient method that enables the projection of daily stream water quality under varying hydrologic conditions using commonly available discrete monitoring data. WRTDS-P model performance was validated using 39 sites in the Delaware River Basin (DRB) and four key constituents: specific conductance (SC), nitrate (NO 3 − ), magnesium (Mg 2+ ) and calcium (Ca 2+ ). Projections were tested against holdout data from the final 1 to 5 years of each time series, demonstrating robust predictive capability, with median Nash-Sutcliffe efficiencies of 0.67 for SC, 0.56 for NO 3 − , 0.65 for Ca 2+ , and 0.79 for Mg 2+ . Model uncertainty was correlated with indicators of hydrologic or geochemical mass-sinks, such as groundwater storage and adsorption in wetland soils. Drought scenario analyses for SC used ranges of reduced discharge including flows from the 1965 drought of record. Scenarios predicted widespread increases of SC, especially in southern DRB streams where baseline SC levels are already elevated. Fractional increases of SC were more uniformly distributed, indicating potential risk to sensitive ecosystems. Notably, drought-induced SC increases were positively correlated with interannual SC trends, indicating that hydrologic extremes could exacerbate ongoing salinization. This work provides a transferable and interpretable framework for projecting future water quality and assessing hydrologic risk to water resources and aquatic ecosystems.

Delaware, New Jersey, New York, Pennsylvania↗
USGS2025

Spatially resolved source apportionment of per- and polyfluoroalkyl substances (PFAS) within a post-industrial river catchment

Source apportionment of per- and polyfluoroalkyl substances (PFAS) in rivers is typically based on water concentrations, which cannot quantify PFAS loads or define geographical source areas. This study applied a river catchment-scale approach to identify PFAS source zones and assess the relative importance of industrial PFAS sources in the River Mersey, UK – a post-industrial, densely populated catchment with diverse PFAS sources. Synoptic sampling and PFAS river load analysis identified key sub-catchments and river stretches contributing the majority of PFAS. Notably, the highest PFAS concentrations did not always correspond to the greatest loads. Most PFOS (64 %), PFOA (49 %), 6:2FTS (46 %) and PFHxS (56 %) were exported from the Upper Mersey sub-catchment, despite higher concentrations in northern sub-catchments, emphasising the importance of load-based monitoring. Mass balance analysis of loads highlighted substantial inputs from specific river stretches, notably the Lower Irwell (Bolton to Manchester City Centre), River Tame (Marple Bridge to Stockport), and Upper Mersey (Stockport to Urmston). While PFAS loads generally scaled with catchment area, yield (load per unit area) analysis identified disproportionately high exports from small headwater catchments, notably the upper River Roch (PFOA, PFHpA and PFHxA) and Glaze Brook (PFBS). Industrial sources in these sub-catchments (a waste management facility and landfills, respectively) were confirmed using gadolinium anomaly analysis and consented discharge records. More widely, gadolinium data suggested industrial discharges may contribute to PFAS occurrence at 62 % of our sample sites throughout the catchment. These findings demonstrate that spatial analysis of PFAS loads, rather than concentrations alone, is critical for identifying PFAS source areas. We present a scalable monitoring framework for PFAS source apportionment applied at the river catchment-scale that can be used by environmental managers to target and prioritise PFAS source areas for detailed monitoring and remediation.

River Mersey↗
USGS2025

Identifying organic contaminants at trespass cannabis grows on federal land in California, USA

Despite the legalization of recreational cannabis in California, USA, illegal cannabis cultivation remains pervasive, partly through the establishment of illegal cultivation on public lands (trespass grows). These operations often illegally divert water for irrigation and perform unauthorized applications of chemical fertilizers and pesticides. This work investigates a broad suite of these chemicals, focusing on their persistence in topsoil and presence in water and bed sediment in adjacent streams. Quantitative analyses of pesticides were conducted (183 compounds in water; 176 in topsoil/bed sediment), supplemented by qualitative nontargeted screening at three trespass grows that had no active cultivation for 8 months to 2 years. Targeted multi-residue analysis of topsoil detected the insecticides bifenthrin, cyfluthrin, malathion and imidacloprid (with concentrations up to 38 ng/g dry weight, d.w.), and the fungicides fluopyram, myclobutanil, and triadimefon (concentrations up to 8.1 ng/g d.w.). No pesticides were detected in the companion water or streambed sediment samples from adjacent streams. In addition, no water samples were found to have measurable estrogenic activity. Nontargeted screening uncovered additional pesticides (i.e., spiromesifen, trinexapac) in the topsoil and cannabis-related compounds (i.e., cannabidol, delta9-tetrahydrocannabinol) in both topsoil and streambed sediment suggesting the likelihood of offsite transport of cannabis related compounds. Phthalate plasticizers, rubber-related compounds, pharmaceuticals and personal care product chemicals were detected in topsoil, water, and streambed sediment and may be related to extensive irrigation infrastructure installed at these trespass grows. This work begins to establish a contaminant profile associated with illegal cannabis growing activities, providing a foundation for future research focused on their potential ecological impacts.

California↗
USGS2025

Global recreational consumption of non-native inland fish: Higher economic benefits, but lower nutritional value and climate resilience

Inland recreational fisheries are globally significant leisure pursuits, with well-documented benefits to human health and well-being, but also one of the principal drivers of non-native fish introductions to enhance fishing opportunities, whether for sport or sustenance. In this study, we assess the relative reliance of global inland recreational fisheries on non-native versus native species for harvest. We further examine how this reliance varies by economic and nutritional value as well as the climate vulnerability of the species involved. We demonstrate that, of the 1,325,851 t of inland recreational fishes recreationally harvested for consumption worldwide in 2021, non-native fish were a small proportion (4 %; 53,651 t). On a global scale, non-native fish contributed a net positive 38.2 % economic value to inland recreational harvest. However, they also contributed a net negative −21.9 % nutritional value to inland recreational harvest. Non-native fishes were also more climate vulnerable (i.e., higher average climate vulnerability index values) and thus proportionally increased overall estimates of climate vulnerability with a net positive of 70.9 %. Our results quantitatively demonstrate that non-native species play a more important role in inland consumptive recreational fisheries than their mere harvest volume would suggest. However, many nuances were seen on the continent and country scale, which reflect the complexity of fisher behavior, fish distribution and socio-economic factors. Our findings help unravel the complex effects of non-native species on human activities and underscore the need to evaluate their global impacts holistically.

Science of the Total Environment↗
USGS2025

Phytoplankton biomass dynamics in wet (2019) and dry (2023) years in Lake Pontchartrain estuary, Louisiana from Sentinel 2-MSI and PACE-OCI observations

This study provides a comprehensive assessment of phytoplankton biomass dynamics in Lake Pontchartrain, Louisiana, by combining monthly water quality data with multispectral and hyperspectral satellite observations using a machine learning algorithm. A machine learning model based on Variational Autoencoder (VAE), globally applicable, was used to estimate phytoplankton biomass via chlorophyll- a (Chl- a ) from Sentinel 2-MSI and NASA's new hyperspectral mission, PACE-OCI, enabling the first direct comparison between the two sensors. The model performed well in this complex estuarine system, with higher accuracy from PACE-OCI (MAE: 1.48, RMSE: 10.40, slope: 0.87) than Sentinel 2-MSI (MAE: 1.57, RMSE: 11.08, slope: 0.83). This approach enabled continuous high-resolution monitoring of phytoplankton biomass across space and time. Comparative analysis of 2019, a wet year with Bonnet Carré Spillway (BCS) openings, and 2023, a dry year with extremely low riverine inputs, revealed distinct biomass dynamics. In 2019, BCS discharge initially suppressed Chl- a within turbid waters (<5 mg Chl- a m −3 ) but later acted as a nutrient and hydrodynamic driver, transporting nutrients toward the lake outlet and Mississippi coast, promoting high biomass (25–45 mg Chl- a m −3 ) near the entrance. In contrast, dry conditions in 2023 led to more frequent-than-expected high biomass (>35 mg Chl- a m −3 ), persisting in the lake center. Similar spatial patterns were observed again in 2024, revealed for the first time by PACE-OCI. This study demonstrates the value of satellite-derived observations for capturing transient phytoplankton biomass events and highlights the potential of PACE-OCI's hyperspectral capabilities to better distinguish phytoplankton communities and improve understanding of their responses to freshwater inflows and associated processes driving pulses into estuaries.

Louisiana↗
USGS2026

Hydrologic variability drives environmental and geospatial relationships in Smallmouth Bass (Micropterus dolomieu) distribution

Hydrologic variation is a primary driver of stream ecosystems. Changing hydrology can lead to assemblage shifts and alterations in suitable habitat for freshwater species. As climate change is predicted to alter flow patterns in addition to increasing water temperatures, insight into relationships between species occupancy, hydrology, and temperature is critical for understanding current and future distributions. We examined how hydrologic variability, temperature, and other environmental variables interact to influence Micropterus dolomieu (Smallmouth Bass) occurrence. We used Spatial Stream Network models, allowing for the incorporation of spatial autocorrelation along streams' unique dendritic network, to examine Smallmouth Bass occupancy across a range of hydrologic variation in the Ozark-Ouachita Interior Highlands, USA. Hydrologic variation was the main driver of Smallmouth Bass occurrence, with occurrence more likely in groundwater streams with low hydrologic variation and high flow permanence. For groundwater streams, occurrence was positively associated with summer stream temperature and negatively associated with annual stream temperature. As variation increased, more variables showed significant relationships with occurrence. Distance metrics were important for all models, however as hydrologic disturbance increased, flow connected distance played a lesser role and stream distance played a greater role. Hydrologic variability was the overarching determinant of Smallmouth Bass occurrence and strongly influenced the predictive importance of environmental variables and geospatial relationships. Greater hydrologic variability resulted in stronger statistical relationships between occurrence and environmental variables and an increased importance of system connectivity. As climate change alters hydrologic processes and streams become more variable, understanding and accounting for these shifting relationships is essential.

Arkansas, Kansas, Missouri, Oklahoma↗
USGS2026

Continuous measurements reveal wind and temperature affect orphan well methane emissions on the Kevin-Sunburst Dome, Montana

Fifteen leaking orphan wells on the Kevin-Sunburst Dome in northern Montana had emission rates that were affected by surface winds and diurnal temperature swings based on continuous monitoring data. Some wells showed correlating spikes in emissions when temperatures changed or wind speed increased while others demonstrated independent flow behavior despite being drilled into the same reservoir and located only a few hundred meters apart. Time-weighted mean methane emission rates ranged from non-detectable levels up to 2.7 kg/h in their as-discovered conditions, with leaking wells averaging 211 g/h. Emissions were measured continuously for up to 452 h per well during monitoring, revealing that leak rates can fluctuate by an order of magnitude within hours. Fluctuations in emission rates often synchronized between wells with overlapping emission measurement intervals, suggesting weather conditions, such as temperature and wind, affect emission rates (up to a factor of 4) with the most relevant factor being the effect of wind on wells with open holes. Additionally, this study presents the first methane emissions measured from an orphan well in two distinct conditions: as initially discovered (closed leaking valve, 2.7 kg/h) and again under unrestricted flow conditions (open valve, 11.8 kg/h), illustrating the maximum unobstructed leak rate and quantifying the constraints restricted leaking wells can have on emissions compared to open holes.

Montana↗
USGS2026

Hybrid particulate matter generated by lava-ignited wildfires at the Litli-Hrutur 2023 eruption, Iceland

Lava flows from the Litli-Hrútur 2023 eruption ignited the largest moss wildfires since modern record keeping in Iceland began. Volcanically ignited wildfires present a cascading and more complex hazard than standalone volcanic eruptions and are likely to become more frequent globally due to climate change. Both volcanic eruptions and wildfire events generate well-characterized air pollution hazards through the emission of gas and particulate matter, but the physicochemical consequences of mixing between end-member emission types during compound events remain poorly understood. In this study, we collected samples of end-member volcanic, wildfire, and mixed plume particulate matter during the Litli-Hrútur 2023 eruption and wildfires. Geochemical and morphological analysis showed that wildfire smoke and lava flow outgassing have distinctive chemical signatures and PM size distributions, but that when mixing occurs between them, either directly at the lava-moss burning interface or during downwind transport, it can result in the formation of hybrid PM. This hybrid PM may be formed through mechanical interactions via well-established processes such as agglomeration and particle scavenging, although interactions are unique in the context of a compound volcanic-wildfire event as they occur between emissions from two different sources (e.g. scavenging of smaller volcanic particles the by larger partially combusted moss particles). We demonstrate that the formation of hybrid PM via these mechanisms may result in altered physicochemical characteristics and suggest that this may have consequences for depositional processes and atmospheric and environmental transport pathways of key species, when compared to stand-alone volcanic eruptions.

Litli-Hrutur volcano↗