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At least 559 records · Page 31Linked to original sources

Jurassic ash-flow sheets, calderas, and related intrusions of the Cordilleran volcanic arc in southeastern Arizona: Implications for regional tectonics and ore deposits

Volcanologic, petrologic, and paleomagnetic studies of widespread Jurassic ash-flow sheets in the Huachuca-southern Dragoon Mountains area have led to identification of four large source calderas and associated comagmatic intracaldera intrusions. Stratigraphic, facies, and contact features of the caldera-related tuffs also provide constraints on the locations, lateral displacements, and very existence for some major northwest-trending faults and inferred regional thrusts in south-eastern Arizona. For example, the intricate Cochise thrust system, as mapped by others in the southern Dragoon Mountains, consists instead of primary depositional contacts within caldera-fill megabreccia, and the inferred regional thrusts do not exist, at least as previously interpreted. Silicic alkalic compositions of the Jurassic caldera-related, ash-flow tuffs; bimodal associated mafic magmatism; and interstratified coarse sedimentary deposits provide evidence for synvolcanic extension and rifting within the Cordilleran magmatic arc. Gold-copper mineralization is associated with subvolcanic intrusions at several of the Jurassic calderas.

Arizona↗

Volcanism and erosion during the past 930 k.y. at the Tatara-San Pedro complex, Chilean Andes

Geologic mapping, together with 73 new K-Ar and 40 Ar/ 39 Ar age determinations of 45 samples from 17 different volcanic units, plus paleomagnetic orientations, geochemical compositions, and terrestrial photogrammetry are used to define the chronostratigraphy of the Tatara–San Pedro complex, an eruptive center at 36°S on the volcanic front of the Andean southern volcanic zone. The Tatara–San Pedro complex preserves ≈55 km 3 of lavas that erupted from at least three central vent regions. Remnant, unconformity-bound sequences of lavas are separated by lacunae that include significant periods of erosion. Quaternary volcanism commenced ca. 930 ka with eruption of voluminous dacitic magma, followed 100 k.y. later by the only major rhyolitic eruption. From 780 ka onward, more than 80% of the preserved volume is basaltic andesite (52%–57% SiO 2 ), but petrographically and geochemically diverse dacitic magmas (63%–69% SiO 2 ) erupted sporadically throughout this younger, dominantly mafic phase of activity. A few basaltic lavas (49%–52% SiO 2 ) are present, mainly in portions of the complex older than 230 ka. The number of vents, the petrologic and geochemical diversity, and the temporal distribution of mafic and silicic lavas are consistent with emplacement of many separate batches of mafic magma into the shallow crust beneath the Tatara–San Pedro complex over the past million years.

Geological Society of America Bulletin↗

Geochemical surveillance of magmatic volatiles at Popocatepetl volcano, Mexico

Surveillance of Popocatépetl volcanic plume geochemistry and SO 2 flux began in early 1994 after fumarolic and seismic activity increased significantly during 1993. Volatile traps placed around the summit were collected at near-monthly intervals until the volcano erupted on December 21, 1994. Additional trap samples were obtained in early 1996 before the volcano erupted again, emplacing a small dacite dome in the summit crater. Abundances of volatile constituents (ppm/day of Cl, S total , F, CO 2 , Hg, and As) varied, but most constituents were relatively high in early and late 1994. However, ratios of these constituents to Cl were highest in mid-1994. δ 34 S-S total in trap solutions ranged from 1.5‰ to 6.4‰; lowest values generally occurred during late 1994. δ 13 C-CO 2 of trap solutions were greatly contaminated with atmospheric CO 2 and affected by absorption kinetics. When trap data are combined with SO 2 flux measurements made through November 1996, Popocatépetl released about 3.9 Mt SO 2 , 16 Mt CO 2 , 0.75 Mt HCl, 0.075 Mt HF, 260 t As, 2.6 t Hg, and roughly 200 Mt H 2 O. Near-vent gas concentrations in the volcanic plume measured by correlation spectrometer (COSPEC) and Fourier transform infrared (FTIR) commonly exceed human recommended exposure limits and may constitute a potential health hazard. Volatile geochemistry combined with petrologic observations and melt-inclusion studies show that mafic magma injection into a preexisting silicic chamber has accompanied renewed volcanism at Popocatépetl. Minor assimilation of Cretaceous wall rocks probably occurred in mid-1994.

Mexico↗

Time-predictable bimodal volcanism in the Coso Range, California

The bimodal Pleistocene part of the Coso volcanic field has erupted rhyolite and basalt at constant long-term rates during the past ∼0.5 m.y. Both basalt and high-silica rhyolite were erupted in several independent, geologically brief episodes. The interval between eruptions of rhyolite was proportional to the volume of the preceding eruption. Basaltic eruptions appear to have followed a similar pattern. These time-predictable relations would be expected if (1) extensional strain accumulates in roof rocks at a constant rate, (2) the accumulated strain is relieved by near-vertical fractures, which serve as conduits for eruptions, and (3) the volume of erupted material is proportional to the sum of the conduit (dike) widths. The long-term eruption rate of rhyolite is about 5.4 km 3 /m.y.; that of basalt is about 2.8 km 3 /m.y. These rates are less than those of magma supply inferred from heat-flow and petrologic arguments by factors of between 100 and 200.

California↗

Upper Jurassic mafic magmatic rocks of the eastern Klamath Mountains, northern California: remnant of a volcanic arc built on young continental crust

Diabasic and gabbroic dikes intruding the lower Paleozoic Trinity Ophiolite in the Lovers Leap section, Klamath Mountains, California, display strong calc-alkalic petrological and geochemical features (occurrence of primary amphiboles, zoned plagioclase phenocrysts and biotite, low TiO 2 , high incompatible trace-element contents, and light rare earth element enrichment). These dikes, of Late Jurassic age (149 ±6 Ma by K-Ar), are petrographically and geochemically similar to the contemporaneous calc-alkalic ultramafic-mafic magmatism well developed through the Klamath Mountains. They present negative Nb, Zr, and Ti anomalies typical of subduction-related magmatism and probably belong to a volcanic arc on an active continental margin. Their ϵ Sr (between -9.7 and -12.5) and ϵ Nd (between 5.6 and 6.3) values compare with some western U.S. Mesozoic granites. The Nd isotopic values, lower than those of mid-oceanic ridge basalts and intra-oceanic island arcs, suggest that these dikes, deriving from a depleted mantle source, have been slightly contaminated by continental material, probably subducted sediments. Values of ϵ Nd suggest, moreover, that no old continental crust underlies the Klamath Mountains.

Geology↗

Deep-sea sedimentary record of the late Wisconsin cataclysmic floods from the Columbia River

New results from Ocean Drilling Program Site 1037 and U.S. Geological Survey high-resolution seismic-reflection profiles confirm the great thickness, fast deposition rate, distant source, and convolute path of turbidites that fill the Escanaba Trough, the rift valley of the southernmost segment of the Gorda Ridge. Accelerator mass spectrometry 14 C measurements provide the first direct dating of the Escanaba Trough turbidites, demonstrating an average deposition rate faster than 10 m/k.y. between 32 and 11 ka and as fast as 15 m/k.y. during the oxygen isotope stage 2 lowstand. In the upper 60 m of sediment, the petrology of turbidite sand beds, which are as much as 12 m thick, show that the dominant source for the turbidites is from the Columbia River, which is more than 800 km to the north, rather than from the much closer rivers of northern California. New high-resolution seismic-reflection profiles show that, except for areas of very recent volcanism, the entire Escanaba Trough below 3200 m water depth is floored by the turbidite sequence that was cored in the upper 60 m at Site 1037B. The ages of the upper 120 m of turbidites correspond with the ages of channeled scabland deposits associated with latest Quaternary jokulhlaups from glacial Lake Missoula. The age and source characteristics suggest that these megaturbidite beds in Escanaba Trough are most likely deposits formed by hyperpycnally generated turbidity currents as the largest of the Lake Missoula floods entered the sea.

Geology↗

Seismic evidence for widespread serpentinized forearc upper mantle along the Cascadia margin

Petrologic models suggest that dehydration and metamorphism of subducting slabs release water that serpentinizes the overlying forearc mantle. To test these models, we use the results of controlled-source seismic surveys and earthquake tomography to map the upper mantle along the Cascadia margin forearc. We find anomalously low upper-mantle velocities and/or weak wide-angle reflections from the top of the upper mantle in a narrow region along the margin, compatible with recent teleseismic studies and indicative of a serpentinized upper mantle. The existence of a hydrated forearc upper-mantle wedge in Cascadia has important geological and geophysical implications. For example, shearing within the upper mantle, inferred from seismic reflectivity and consistent with its serpentinite rheology, may occur during aseismic slow slip events on the megathrust. In addition, progressive dehydration of the hydrated mantle wedge south of the Mendocino triple junction may enhance the effects of a slap gap during the evolution of the California margin.

Geology↗

The Boring Volcanic Field of the Portland-Vancouver area, Oregon and Washington: Tectonically anomalous forearc volcanism in an urban setting

More than 80 small volcanoes are scattered throughout the Portland-Vancouver metropolitan area of northwestern Oregon and southwestern Washington. These volcanoes constitute the Boring Volcanic Field, which is centered in the Neogene Portland Basin and merges to the east with coeval volcanic centers of the High Cascade volcanic arc. Although the character of volcanic activity is typical of many monogenetic volcanic fields, its tectonic setting is not, being located in the forearc of the Cascadia subduction system well trenchward of the volcanic-arc axis. The history and petrology of this anomalous volcanic field have been elucidated by a comprehensive program of geologic mapping, geochemistry, 40Ar/39Ar geochronology, and paleomag-netic studies. Volcanism began at 2.6 Ma with eruption of low-K tholeiite and related lavas in the southern part of the Portland Basin. At 1.6 Ma, following a hiatus of ~0.8 m.y., similar lavas erupted a few kilometers to the north, after which volcanism became widely dispersed, compositionally variable, and more or less continuous, with an average recurrence interval of 15,000 yr. The youngest centers, 50–130 ka, are found in the northern part of the field. Boring centers are generally monogenetic and mafic but a few larger edifices, ranging from basalt to low-SiO2 andesite, were also constructed. Low-K to high-K calc-alkaline compositions similar to those of the nearby volcanic arc dominate the field, but many centers erupted magmas that exhibit little influence of fluids derived from the subducting slab. The timing and compositional characteristics of Boring volcanism suggest a genetic relationship with late Neogene intra-arc rifting.

Portland, Vancouver↗

Making the case for the Picuris orogeny: Evidence for a 1500 to 1400 Ma orogenic event in the southwestern United States

The early Mesoproterozoic (ca. 1400 Ma) is an enigmatic time in the tectonic evolution of southern Laurentia. Circa 1400 Ma granites within Laurentia and multiple other continents have distinctive geochemistry consistent with crustal extension or mantle upwelling. In the southwestern United States, these granites are commonly foliated and are often spatially associated with km-scale ductile shear zones. Deformation is attributed to intracontinental tectonism driven by active convergence along the distal southern margin of Laurentia. The recent discovery of deformed and metamorphosed, ca. 1450 Ma sedimentary rocks in northern New Mexico has strengthened the case for regional deformation and orogenesis. However, important questions remain about the tectonic significance of these events and how to reconcile tectonic models with granite petrology at the regional to global scale. This trip focuses on the protolith age of Proterozoic metasedimentary rocks and the kinematics, timing, and tectonic significance of deformation, magmatism, and metamorphism for the Mesoproterozoic across different crustal levels in the southern Rocky Mountains to highlight the ongoing questions and controversies regarding the Mesoproterozoic tectonic setting of Laurentia. This field trip will examine some of the diverse and most recently discovered evidence for ca. 1400 Ma orogenesis in the southern Rocky Mountains. We hope this trip will promote new interest and discussion about the Mesoproterozoic tectonic evolution of Laurentia. We will visit multiple outcrops in the Wet Mountains of southern Colorado and the Picuris Mountains of northern New Mexico. Stops in the Wet Mountains are arranged from north to south to examine contrasting styles of ca. 1400 Ma deformation with increasing paleodepth across the tilted Proterozoic crustal section. In the Picuris Mountains, we focus on detrital zircon geochronology and revisions to the lithostratigraphy of Paleoproterozoic and recently documented Mesoproterozoic metasedimentary rocks, the nature of regional metamorphism, and the style of deformation, ca. 1450–1400 Ma.

Geological Society of America Field Guides↗

Thermochronology of Cretaceous batholithic rocks in the northern Peninsular Ranges batholith, southern California: Implications for the Late Cretaceous tectonic evolution of southern California

The thermochronology for several suites of Mesozoic metamorphic and plutonic rocks collected throughout the northern Peninsular Ranges batholith (PRB) was studied as part of a collaborative isotopic study to further our understanding of the magmatic and tectonic history of southern California. These sample suites include: a traverse through the plutonic rocks across the northern PRB ( N = 29), a traverse across a central structural and metamorphic transition zone of mainly metasedimentary rocks at Searl ridge ( N = 20), plutonic samples from several drill cores ( N = 7) and surface samples ( N = 2) from the Los Angeles Basin, a traverse across the Eastern Peninsular Ranges mylonite zone ( N = 6), and a suite of plutonic samples collected across the northern PRB ( N = 13) from which only biotite 40 Ar/ 39 Ar ages were obtained. These geochronologic data help to characterize five major petrologic, geochemical, and isotopic zonations of the PRB (western zone, WZ; western transition zone, WTZ; eastern transition zone, ETZ; eastern zone, EZ; and upper-plate zone, UPZ). Apparent cooling rates were calculated using U-Pb zircon (zr) and titanite (sphene) ages; 40 Ar/ 39 Ar ages from hornblende (hbl), biotite (bi), and K-feldspar (Kf); and apatite fission-track (AFT) ages from the same samples. The apparent cooling rates across the northern PRB vary from relatively rapid in the west (zr-hbl ~210 °C/m.y.; zr-bio ~160 °C/m.y.; zr-Kf ~80 °C/m.y.) to less rapid in the central (zr-hb ~280 °C/m.y.; zr-bio ~90 °C/m.y.; zr-Kf ~60 °C/m.y.) and eastern (zr-hbl ~185 °C/m.y.; zr-bio ~180 °C/m.y.; zr-Kf ~60 °C/m.y.) zones. An exception in the eastern zone, the massive San Jacinto pluton, appears to have cooled very rapidly (zr-bio ~385 °C/m.y.). Apparent cooling rates for the UPZ samples are consistently slower in comparison (~25–45 °C/m.y.), regardless of which geochronometers are used. Notable characteristics of the various ages from different dating methods include: (1) Zircon ages indicate a progressive younging of magmatic activity from west to east between ca. 125 and 90 Ma. (2) Various geochronometers were apparently affected by emplacement of the voluminous (ETZ and EZ) La Posta–type plutons emplaced between 99 and 91 Ma. Those minerals affected include K-feldspar in the western zone rocks, biotite and K-feldspar in the WTZ rocks, and white mica and K-feldspar in rocks from Searl ridge. (3) The AFT ages record the time the rocks cooled through the AFT closure temperature (~100 °C in these rocks), likely due to exhumation. Throughout most of the northern traverse, the apatite data indicate the rocks cooled relatively quickly through the apatite partial annealing zone (PAZ; from ~110 °C to 60 °C) and remained at temperatures less than 60 °C as continued exhumation cooled them to present-day surface temperatures. The ages indicate that the western “arc” terrane of the WZ was being uplifted and cooled at ca. 91 Ma, during or shortly after intrusion of the 99–91 Ma La Posta–type plutons to the east. Uplift and cooling occurred later, between ca. 70 Ma and ca. 55 Ma, in the central WTZ, ETZ, and EZ rocks, possibly as upwarping in response to events in the UPZ. The UPZ experienced differential exhumation at ca. 50–35 Ma: Cooling on the western edge was taking place at about the same time or shortly after cooling in the younger samples in the ETZ and EZ, whereas on the east side of the UPZ, the rocks cooled later (ca. 35 Ma) and spent a prolonged time in the apatite PAZ compared to most northern traverse samples. Apparent cooling rates from Los Angeles Basin drill core samples of plutonic rocks show that four are similar to the WTZ thermal histories, and two are similar to the WTZ histories, indicating that the eastern part of the Los Angeles Basin area is underlain by mainly western zone PRB rocks. Thermal histories revealed by samples from Searl ridge indicate that the WTZ magmatism intruded the metasedimentary rocks prior to their deformation and metamorphism at ca. 97 Ma. Both low-grade schists and metasandstones of the western side of the ridge and high-grade gneisses of the eastern side of the ridge have thermal histories consistent with eastern zone rocks—suggesting a temporal/thermal relationship between the western transition zone and the eastern zones. Limited ages from six samples across the Eastern Peninsular Ranges mylonite zone (EPRMZ) indicate that this zone underwent cooling after emplacement of the youngest UPZ rocks at 85 Ma, suggesting that thrusting along the EPRMZ was either coeval with emplacement of the UPZ plutonic rocks or occurred shortly afterwards (~10–15 m.y.). Alternatively, the EPRMZ thrusting may have occurred at temperatures under ~180 °C at yet a later date. The geochronology presented here differs slightly from previous studies for similar rocks exposed across the middle and southern portions of the PRB, in that our data define a relatively smooth progression of magmatism from west to east, and the transition from western, oceanic-arc plutonism to eastern, continental arc plutonism is interpreted to have occurred at ca. 99–97 Ma and not at ca. 105 Ma.

Book chapter↗

Chesapeake Bay impact structure—Development of "brim" sedimentation in a multilayered marine target

The late Eocene Chesapeake Bay impact structure was formed in a multilayered target of seawater underlain sequentially by a sediment layer and a rock layer in a continental-shelf environment. Impact effects in the “brim” (annular trough) surrounding and adjacent to the transient crater, between the transient crater rim and the outer margin, primarily were limited to the target-sediment layer. Analysis of published and new lithostratigraphic, biostratigraphic, sedimentologic, petrologic, and mineralogic studies of three core holes, and published studies of a fourth core hole, provided information for the interpretation of the impact processes, their interactions and relative timing, their resulting products, and sedimentation in the brim. Most studies of marine impact-crater materials have focused on those found in the central crater. There are relatively few large, complex marine craters, of which most display a wide brim around the central crater. However, most have been studied using minimal data sets. The large number of core holes and seismic profiles available for study of the Chesapeake Bay impact structure presents a special opportunity for research. The physical and chronologic records supplied by study of the sediment and rock cores of the Chesapeake Bay impact indicate that the effects of the initial, short-lived contact and compression and excavation stages of the impact event primarily were limited to the transient crater. Only secondary effects of these processes are evident in the brim. The preserved record of the brim was created primarily in the subsequent modification stage. In the brim, the records of early impact processes (e.g., outgoing tsunamis, overturned flap collapse) were modified or removed by later processes. Transported and rotated, large and small clasts of target sediments, and intervals of fluidized sands indicate that seismic shaking fractured and partially fluidized the Cretaceous and Paleogene target sediments, which led to their inward transport by collapse and lateral spreading toward the transient crater. The succeeding inward seawater-resurge flow quickly overtook and interacted with the lateral spreading, further facilitating sediment transport across the brim and into the transient crater. Variations in the cohesion and relative depth of the target sediments controlled their degree of disaggregation and redistribution during these events. Melt clasts and shocked and unshocked rock clasts in the resurge sediments indicate fallout from the ejecta curtain and plume. Basal parautochthonous remnant sections of target Cretaceous sediments in the brim thin toward the collapsed transient crater. Overlying seawater-resurge deposits consist primarily of diamictons that vary laterally in thickness, and vertically and laterally in maximum grain size. After cessation of resurge flow and re-establishment of pre-impact sea level, sandy sediment gravity flows moved from the margin to the center of the partially filled impact structure (shelf basin). The uppermost unit consists of stratified sediments deposited from suspension. Postimpact clayey silts cap the crater fill and record the return to shelf sedimentation at atypically large paleodepths within the shelf basin. An unresolved question involves a section of gravel and sand that overlies Neoproterozoic granite in the inner part of the brim in one core hole. This section may represent previously unrecognized, now parautochthonous Cretaceous sediments lying nonconformably above basement granite, or it may represent target sediments that were moved significant distances by lateral spreading above basement rocks or above a granite megaclast from the overturned flap. The Chesapeake Bay impact structure is perhaps the best documented example of the small group of multilayer, marine-target impacts formed in continental shelves or beneath epeiric seas.

Chesapeake Bay↗

Geoelectric constraints on the Precambrian assembly and architecture of southern Laurentia

Using images from an updated and expanded three-dimensional electrical conductivity synthesis model for the contiguous United States (CONUS), we highlight the key continent-scale geoelectric structures that are associated with the Precambrian assembly of southern Laurentia. Conductivity anomalies are associated with the Trans-Hudson orogen, the Penokean suture, the ca. 1.8–1.7 Ga Cheyenne belt and Spirit Lake tectonic zone, and the Grenville suture zone; the geophysical characteristics of these structures indicate that the associated accretionary events involved the closure of ancient ocean basins along discrete, large-scale structures. In contrast, we observe no large-scale conductivity anomalies through the portion of southern Laurentia that is generally viewed as composed of late Paleoproterozoic–early Mesoproterozoic accretionary crust. The lack of through-going conductors places constraints on the structure, petrology, and geodynamic history of crustal growth in southern Laurentia during that time period. Overall, our model highlights the enigmatic nature of the concealed Precambrian basement of much of southern Laurentia, as it in some places supports and in other places challenges prevailing models of Laurentian assembly. The revised CONUS electrical conductivity model thus provides important constraints for testing new models of Precambrian tectonism in this region.

continental United States↗

Eruptive and noneruptive calderas, northeastern San Juan Mountains, Colorado: Where did the ignimbrites come from?

The northeastern San Juan Mountains, the least studied portion of this well-known segment of the Southern Rocky Mountains Volcanic Field are the site of several newly identified and reinterpreted ignimbrite calderas. These calderas document some unique eruptive features not described before from large volcanic systems elsewhere, as based on recent mapping, petrologic data, and a large array of newly determined high-precision, laser-fusion 40 Ar/ 39 Ar ages (140 samples). Tightly grouped sanidine ages document exceptionally brief durations of 50–100 k.y. or less for individual Oligocene caldera cycles; biotite ages are more variable and commonly as much as several hundred k.y. older than sanidine from the same volcanic unit. A previously unknown ignimbrite caldera at North Pass, along the Continental Divide in the Cochetopa Hills, was the source of the newly distinguished 32.25-Ma Saguache Creek Tuff (~400–500 km 3 ). This regionally distinctive crystal-poor alkalic rhyolite helps fill an apparent gap in the southwestward migration from older explosive activity, from calderas along the N-S Sawatch locus in central Colorado (youngest, Bonanza Tuff at 33.2 Ma), to the culmination of Tertiary volcanism in the San Juan region, where large-volume ignimbrite eruptions started at ca. 29.5 Ma and peaked with the enormous Fish Canyon Tuff (5000 km 3 ) at 28.0 Ma. The entire North Pass cycle, including caldera-forming Saguache Creek Tuff, thick caldera-filling lavas, and a smaller volume late tuff sheet, is tightly bracketed at 32.25–32.17 Ma. No large ignimbrites were erupted in the interval 32–29 Ma, but a previously unmapped cluster of dacite-rhyolite lava flows and small tuffs, areally associated with a newly recognized intermediate-composition intrusion 5 × 10 km across (largest subvolcanic intrusion in San Juan region) centered 15 km north of the North Pass caldera, marks a near- caldera-size silicic system active at 29.8 Ma. In contrast to the completely filled North Pass caldera that has little surviving topographic expression, no voluminous tuffs vented directly from the adjacent Cochetopa Park caldera, which is morphologically beautifully preserved. Instead, Cochetopa Park subsided passively as the >500 km 3 Nelson Mountain Tuff vented at 26.9 Ma from an “underfit” caldera (youngest of the San Luis complex) 30 km to the SW. Three separate regional ignimbrites were erupted sequentially from San Luis calderas within an interval of less than 50–100 k.y., a more rapid recurrence rate for large explosive eruptions than previously documented elsewhere. In eruptive processes, volcanic compositions, areal extent, duration of activity, and magmatic production rates and volumes, the Southern Rocky Mountains Volcanic Field represents present-day erosional remnants of a composite volcanic field, comparable to younger ignimbrite terranes of the Central Andes.

Colorado↗

Peninsular terrane basement ages recorded by Paleozoic and Paleoproterozoic zircon in gabbro xenoliths and andesite from Redoubt volcano, Alaska

Historically Sactive Redoubt volcano is an Aleutian arc basalt-to-dacite cone constructed upon the Jurassic–Early Tertiary Alaska–Aleutian Range batholith. The batholith intrudes the Peninsular tectonostratigraphic terrane, which is considered to have developed on oceanic basement and to have accreted to North America, possibly in Late Jurassic time. Xenoliths in Redoubt magmas have been thought to be modern cumulate gabbros and fragments of the batholith. However, new sensitive high-resolution ion microprobe (SHRIMP) U-Pb ages for zircon from gabbro xenoliths from a late Pleistocene pyroclastic deposit are dominated by much older, ca. 310 Ma Pennsylvanian and ca. 1865 Ma Paleoproterozoic grains. Zircon age distributions and trace-element concentrations indicate that the ca. 310 Ma zircons date gabbroic intrusive rocks, and the ca. 1865 Ma zircons also are likely from igneous rocks in or beneath Peninsular terrane basement. The trace-element data imply that four of five Cretaceous–Paleocene zircons, and Pennsylvanian low-U, low-Th zircons in one sample, grew from metamorphic or hydrothermal fluids. Textural evidence of xenocrysts and a dominant population of ca. 1865 Ma zircon in juvenile crystal-rich andesite from the same pyroclastic deposit show that this basement has been assimilated by Redoubt magma. Equilibration temperatures and oxygen fugacities indicated by Fe-Ti–oxide minerals in the gabbros and crystal-rich andesite suggest sources near the margins of the Redoubt magmatic system, most likely in the magma accumulation and storage region currently outlined by seismicity and magma petrology at ∼4–10 km below sea level. Additionally, a partially melted gabbro from the 1990 eruption contains zircon with U-Pb ages between ca. 620 Ma and ca. 1705 Ma, as well as one zircon with a U-Th disequilibrium model age of 0 ka. The zircon ages demonstrate that Pennsylvanian, and probably Paleoproterozoic, igneous rocks exist in, or possibly beneath, Peninsular terrane basement. Discovery of Pennsylvanian gabbro similar in age to Skolai arc plutons 500 km to the northeast indicates that the Peninsular terrane, along with the Wrangellia and Alexander terranes, has been part of the Wrangellia composite terrane since at least Pennsylvanian time. Moreover, the zircon data suggest that a Paleoproterozoic continental fragment may be present in the mid-to-upper crust in southern Alaska.

Alaska↗

Faulting within the Mount St. Helens conduit and implications for volcanic earthquakes

The 2004–2008 eruption of Mount St. Helens produced seven dacite spines mantled by cataclastic fault rocks, comprising an outer fault core and an inner damage zone. These fault rocks provide remarkable insights into the mechanical processes that accompany extrusion of degassed magma, insights that are useful in forecasting dome-forming eruptions. The outermost part of the fault core consists of finely comminuted fault gouge that is host to 1- to 3-mm-thick layers of extremely fine-grained slickenside-bearing ultracataclasite. Interior to the fault core, there is an ∼2-m-thick damage zone composed of cataclastic breccia and sheared dacite, and interior to the damage zone, there is massive to flow-banded dacite lava of the spine interior. Structures and microtextures indicate entirely brittle deformation, including rock breakage, tensional dilation, shearing, grain flow, and microfaulting, as well as gas and fluid migration through intergranular pores and fractures in the damage zone. Slickenside lineations and consistent orientations of Riedel shears indicate upward shear of the extruding spines against adjacent conduit wall rocks. Paleomagnetic directions, demagnetization paths, oxide mineralogy, and petrology indicate that cataclasis took place within dacite in a solidified steeply dipping volcanic conduit at temperatures above 500 °C. Low water content of matrix glass is consistent with brittle behavior at these relatively high temperatures, and the presence of tridymite indicates solidification depths of <1 km. Cataclasis was coincident with the eruption’s seismogenic zone at <1.5 km. More than a million small and low-frequency “drumbeat” earthquakes with coda magnitudes (M d ) <2.0 and frequencies <5 Hz occurred during the 2004–2008 eruption. Our field data provide a means with which to estimate slip-patch dimensions for shear planes and to compare these with estimates of slip patches based on seismic moments and shear moduli for dacite rock and granular fault gouge. Based on these comparisons, we find that aseismic creep is achieved by micron-scale displacements on Riedel shears and by granular flow, whereas the drumbeat earthquakes require millimeter to centimeter displacements on relatively large (e.g., ∼1000 m 2 ) slip patches, possibly along observed extensive principal shear zones within the fault core but probably not along the smaller Riedel shears. Although our field and structural data are compatible with stick-slip models, they do not rule out seismic and infrasound models that call on resonance of steam-filled fractures to generate the drumbeat earthquakes. We suggest that stick-slip and gas release processes may be coupled, and that regardless of the source mechanism, the distinctive drumbeat earthquakes are proving to be an effective precursor for dome-forming eruptions. Our data document a continuous cycle of deformation along the conduit margins beginning with episodes of fracture in the damage zone and followed by transfer of motion to the fault core. We illustrate the cycle of deformation using a hypothetical cross section of the Mount St. Helens conduit, extending from the surface to the depth of magmatic solidification.

Washington↗

Evidence of wildfires and elevated atmospheric oxygen at the Frasnian–Famennian boundary in New York (USA): Implications for the Late Devonian mass extinction

The Devonian Period experienced significant fluctuations of atmospheric oxygen (O 2 ) levels (∼25–13%), for which the extent and timing are debated. Also characteristic of the Devonian Period, at the Frasnian–Famennian (F–F) boundary, is one of the “big five” mass extinction events of the Phanerozoic. Fossilized charcoal (inertinite) provides a record of wildfire events, which in turn can provide insight into the evolution of terrestrial ecosystems and the atmospheric composition. Here, we report organic petrology, programmed pyrolysis analysis, major and trace element analyses, and initial osmium isotope (Os i ) stratigraphy from five sections of Upper Devonian (F–F interval) from western New York, USA. These data are discussed to infer evidence of a wildfire event at the F–F boundary. Based on the evidence for a wildfire at the F–F boundary we also provide an estimate of atmospheric O 2 levels of ∼23–25% at this interval, which is in agreement with the models that predict elevated p O 2 levels during the Late Devonian. This, coupled with our Os isotope records, support the currently published Os i data that lacks any evidence for an extra-terrestrial impact or volcanic event at the F–F interval, and therefore to act as a trigger for the F–F mass extinction. The elevated O 2 level at the F–F interval inferred from this study supports the hypothesis that p CO 2 drawdown and associated climate cooling may have acted as a driving mechanism of the F–F mass extinction.

New York↗

Global geologic context for rock types and surface alteration on Mars

Petrologic interpretations of thermal emission spectra from Mars orbiting spacecraft indicate the widespread occurrence of surfaces having basaltic and either andesitic or partly altered basalt compositions. Global concentration of ice-rich mantle deposits and near-surface ice at middle to high latitudes and their spatial correlation with andesitic or partly altered basalt materials favor the alteration hypothesis. We propose the formation of these units through limited chemical weathering from basalt interactions with icy mantles deposited during periods of high obliquity. Alteration of sediments in the northern lowlands depocenter may have been enhanced by temporary standing bodies of water and ice. ?? 2004 Geological Society of America.

Geology↗

Vapor transfer prior to the October 2004 eruption of Mount St. Helens, Washington

Dome lavas from the 2004 eruption of Mount St. Helens show elevated Li contents in plagioclase phenocrysts at the onset of dome growth in October 2004. These cannot be explained by variations in plagioclase-melt partitioning, but require elevated Li contents in coexisting melt, a fact confirmed by measurements of Li contents as high as 207 µg/g in coexisting melt inclusions. Similar Li enrichment has been observed in material erupted prior to and during the climactic May 1980 eruption, and is likewise best explained via pre-eruptive transfer of an exsolved alkali-rich vapor phase derived from deeper within the magma transport system. Unlike 1980, however, high Li samples from 2004 show no evidence of excess ( 210 Pb)/( 226 Ra), implying that measurable Li enrichments may occur despite significant differences in the timing and/or extent of magmatic degassing. Diffusion modeling shows that Li enrichment occurred within ∼1 yr before eruption, and that magma remained Li enriched until immediately before eruption and cooling. This short flux time and the very high Li contents in ash produced by phreatomagmatic activity prior to the onset of dome extrusion suggest that vapor transfer and accumulation were associated with initiation of the current eruption. Overall, observation of a high Li signature in both 1980 and 2004 dacites indicates that Li enrichment may be a relatively common phenomenon, and may prove useful for petrologic monitoring of Mount St. Helens and other silicic volcanoes. Lithium diffusion is also sufficiently rapid to constrain vapor transfer on similar time scales to short-lived radionuclides.

Geology↗