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USGS2021

Long-term African dust delivery to the eastern Atlantic Ocean from the Sahara and Sahel regions: Evidence from Quaternary paleosols on the Canary Islands, Spain

Africa is the most important source of dust in the world today and dust storms from that continent frequently deposit sediment on the nearby Canary Islands. Many investigators have inferred African dust inputs to Canary Islands paleosols based only on the presence of quartz. However, some local rocks do contain this mineral, so quartz alone is insufficient proof of dust deposition. Further, it is not known whether the Sahara Desert or the Sahel region is more important as a dust source. We address these issues by study of sequences of Pleistocene aeolian sands on the islands of Lanzarote and Fuerteventura. Aeolian sands are composed mostly of marine carbonate minerals and locally derived volcanic minerals. They date from the early-middle Pleistocene to the Holocene. Trace element geochemistry shows that the soils formed from both locally derived basalt and African dust. Major element geochemistry and clay mineralogy indicate that dust additions to the Canary Islands likely come from both the Sahara and Sahel. Dust delivered from the Sahel indicates that droughts in that region have had a history extending through much of the Quaternary. Accretionary-inflationary profile development, from dust accretion, is evident in the upward growth of Canary Islands paleosols.

Quaternary Science Reviews↗

USGS2001

Widespread potential for microbial MTBE degradation in surface-water sediments

Microorganisms indigenous to stream and lake bed sediments, collected from 11 sites throughout the United States, demonstrated significant mineralization of the fuel oxygenate, methyl-tert-butyl ether (MTBE). Mineralization of [U-14C]MTBE to 14CO2 ranged from 15 to 66% over 50 days and did not differ significantly between sediments collected from MTBE contaminated sites and from sites with no history of MTBE exposure. This result suggests that even the microbial communities indigenous to newly contaminated surface water systems will exhibit some innate ability to attenuate MTBE under aerobic conditions. The magnitude of MTBE mineralization was related to the sediment grain size distribution. A pronounced, inverse correlation (p < 0.001; r2 = 0.73) was observed between the final recovery of 14CO2 and the percentage content of silt and clay sized grains (grain diameter < 0.125 mm). The results of this study indicate that the microorganisms that inhabit the bed sediments of streams and lakes can degrade MTBE efficiently and that this capability is widespread in the environment. Thus aerobic bed sediment microbial processes may provide a significant environmental sink for MTBE in surface water systems throughout the United States and may contribute to the reported transience of MTBE in some surface waters.

Environmental Science & Technology↗

USGS1995

Comparison of hydrothermal alteration of carboniferous carbonate and siliclastic rocks in the Valles caldera with outcrops from the Socorro caldera, New Mexico

Continental Scientific Drilling Program (CSDP) drill hole VC-2B [total depth 1761.7 m (5780 ft); maximum temperature 295 °C] was continuously cored through the Sulphur Springs hydrothermal system in the western ring-fracture zone of the 1.14 Ma Valles caldera. Among other units, the hole penetrated 760.2 m (2494.1 ft) of Paleozoic carbonate and siliciclastic strata underlying caldera fill and precaldera volcanic and epiclastic rocks. Comparison of the VC-2B Paleozoic rocks with corresponding lithologies within and around the 32.1 Ma Socorro caldera, 192 km ( 119 miles) to the south-southwest, provides insight into the variability of alteration responses to similar caldera-related hydrothermal regimes. The Pennsylvanian Madera Limestone and Sandia Formation from VC-2B preserve many of the sedimentological and diagenetic features observed in these units on a regional basis and where unaffected by high temperatures or hydrothermal activity. Micrites in these formations in VC-2B are generally altered and mineralized only where fractured or brecciated, that is, where hydrothermal solutions could invade carbonate rocks which were otherwise essentially impermeable. Alteration intensity (and correspondingly inferred paleopermeability) is only slightly higher in carbonate packstones and grainstones, low to intermediate in siltstones and claystones, and high in poorly cemented sandstones. Hydrothermal fracture-filling phases in these rocks comprise sericite (and phengite), chlorite, allanite, apatite, an unidentified zeolite and sphene in various combinations, locally with sphalerite, galena, pyrite and chalcopyrite. Terrigenous feldspars and clays are commonly altered to chlorite and seriate, and euhedral anhydrite “porphyroblasts” with minor chlorite occur in Sandia Formation siltstone. Fossils are typically unaltered, but the walls of some colonial bryozoans in the Madera Limestone are altered to the assemblage chlorite-sericite-epidote-allanite. La, Ce and Nd are present in an unidentified hydrothermal mineral occurring throughout much of the VC-2B Pennsylvanian sequence. Carboniferous carbonate and siliciclastic formations within and around the Socorro caldera show a similar style of alteration and mineralization to their Valles caldera counterparts, but by contrast locally host commercial, caldera-related, base-metal sulfide deposits. As in the Valles rocks, mineralization and alteration in those of the Socorro caldera were strongly controlled by porosity. Unless disrupted by fractures, breccias, or karst cavities ( not identified in Valles caldera drill holes), the rocks remained relatively unaltered. Where these features allowed ingress of mineralizing hydrothermal solutions, base-metal sulfides and rare-earth-element-bearing minerals were precipitated.

New Mexico↗

USGS2021

The trajectory of soil development and its relationship to soil carbon dynamics

It has been postulated that the amount of soil organic carbon (SOC) associated with soil minerals exhibits a threshold relationship in response to effective soil moisture (estimated as precipitation less evapotranspiration). To better characterize the role of moisture in influencing mechanisms of SOC storage during pedogenesis, we compare soils from two different chronosequence sites: the Santa Cruz and Mattole River marine terraces that together form a soil age-by-climate gradient (i.e., climo-chronosequence). Our results demonstrate how variation in the effective soil moisture may drive soil development along divergent pedogenic trajectories, resulting in variations in the form and depth distribution of secondary weathering products. In particular, the residual metals Fe and Al are directly related to the type of secondary minerals that accumulate during weathering, and these variations are coupled to differences in the storage and long-term preservation of SOC both within and between soils. Over time, these differences in soil development may lead to ‘pedogenic thresholds’ that further differentiate soil characteristics and influence SOC dynamics. In this case, the pedogenic threshold takes the form of clay-rich argillic horizons that once formed, inhibit aqueous transport, decouple shallow and deep soil environments, and potentially limit SOC inputs and increase microbial recycling in deep soils. Our data suggest argillic horizon development is favorable in the drier Santa Cruz soils, where kaolinite is the dominant secondary weathering product. In contrast, greater available moisture in soils of the Mattole chronosequence drive a different weathering trajectory characterized by the accumulation of more amorphous secondary minerals. As a result, the Mattole soils and do not exhibit argillic horizon development but are instead characterized by greater accumulation of SOC across all depths sampled. Overall, our results illustrate how the interaction of climate (i.e., moisture) and time may shape the trajectory of soil development and the dynamics of SOC storage and preservation.

California↗

USGS1983

Mapping of hydrothermally altered rocks using airborne multispectral scanner data, Marysvale, Utah, mining district

Multispectral data covering an area near Marysvale, Utah, collected with the airborne National Aeronautics and Space Administration (NASA) 24-channel Bendix multispectral scanner, were analyzed to detect areas of hydrothermally altered, potentially mineralized rocks. Spectral bands were selected for analysis that approximate those of the Landsat 4 Thematic Mapper and which are diagnostic of the presence of hydrothermally derived products. Hydrothermally altered rocks, particularly volcanic rocks affected by solutions rich in sulfuric acid, are commonly characterized by concentrations of argillic minerals such as alunite and kaolinite. These minerals are important for identifying hydrothermally altered rocks in multispectral images because they have intense absorption bands centered near a wavelength of 2.2 ??m. Unaltered volcanic rocks commonly do not contain these minerals and hence do not have the absorption bands. A color-composite image was constructed using the following spectral band ratios: 1.6??m/2.2??m, 1.6??m/0.48??m, and 0.67??m/1.0??m. The particular bands were chosen to emphasize the spectral contrasts that exist for argillic versus non-argillic rocks, limonitic versus nonlimonitic rocks, and rocks versus vegetation, respectively. The color-ratio composite successfully distinguished most types of altered rocks from unaltered rocks. Some previously unrecognized areas of hydrothermal alteration were mapped. The altered rocks included those having high alunite and/or kaolinite content, siliceous rocks containing some kaolinite, and ash-fall tuffs containing zeolitic minerals. The color-ratio-composite image allowed further division of these rocks into limonitic and nonlimonitic phases. The image did not allow separation of highly siliceous or hematitically altered rocks containing no clays or alunite from unaltered rocks. A color-coded density slice image of the 1.6??m/2.2??m band ratio allowed further discrimination among the altered units. Areas containing zeolites and some ash-fall tuffs containing montmorillonite were readily recognized on the color-coded density slice as having less intense 2.2-??m absorption than areas of highly altered rocks. The areas of most intense absorption, as depicted in the color-coded density slice, are dominated by highly altered rocks containing large amounts of alunite and kaolinite. These areas form an annulus, approximately 10 km in diameter, which surrounds a quartz monzonite intrusive body of Miocene age. The patterns of most intense alteration are interpreted as the remnants of paleohydrothermal convective cells set into motion during the emplacement of the central intrusive body. ?? 1983.

Advances in Space Research↗

USGS1957

Core logs from Owens, China, Searles, and Panamint basins, California

Detailed logs of drill cores are presented in this report. The drill cores are of sediments from four basins that were occupied during the Pleistocene by a continuous chain of lakes. Owens Lake basin (one hole, 920 feet) contains fine-grained sediments and includes locally many diatoms and ostracodes. China Lake basin (one hole, 700 feet) contains silt- to sand-sized clastic sediments and some calcite and gaylussite; a few diatoms, ostracodes, and mollusks are present. Searles Lake basin (one hole, 875 feet) contains many layers of gaylussite- or pirssonite-bearing sediments intercalated with beds of halite, trona, and lesser amounts of other minerals peculiar to Searles Lake; the top 120 feet consists of thicker evaporite bodies with a more complex mineralogy. Panamint basin (three holes, 500, 375, and 995 feet) contains clastic deposits ranging from clay to gravel, a small amount of gypsum, anhydrite, a trace of bassanite, and thick bodies of halite in the basin center; a few diatoms and ostracodes are present.

Bulletin↗

USGS1987

Dinosaurs, spherules, and the “magic” layer: A new K-T boundary clay site in Wyoming

A new Cretaceous-Tertiary (K-T) boundary clay site has been found along Dogie Creek in Wyoming in the drainage of Lance Creek—the type area of the Lance Formation of latest Cretaceous age. The boundary clay was discovered in the uppermost part of the Lance Formation, 4–7 cm beneath the lowest lignite in the Paleocene Fort Union Formation and approximately 1 m above a fragmented dinosaur bone. The boundary clay consists of a basal kaolinitic claystone layer as much as 3 cm thick containing hollow goyazite spherules, overlain by a 2–3 mm smectitic layer (the “magic” layer) containing both shock-metamorphosed minerals and an iridium anomaly of 21 ppb. A palynological break coincides with the base of the claystone layer; numerous Late Cretaceous palynomorph species terminate at this boundary. The paleontological significance of this new boundary site lies in its close association with the well-studied assemblage of dinosaurs and other vertebrates and flora within the type area of the Lance Formation. The spherules at the Dogie Creek site are extremely well preserved by virtue of their replacement by the mineral goyazite. This preservation should facilitate the resolution of the origin of the spherules and of their host layer.

Wyoming↗

USGS2008

Deposition of talc - kerolite-smectite - smectite at seafloor hydrothermal vent fields: Evidence from mineralogical, geochemical and oxygen isotope studies

Talc, kerolite-smectite, smectite, chlorite-smectite and chlorite samples from sediments, chimneys and massive sulfides from six seafloor hydrothermal areas have been analyzed for mineralogy, chemistry and oxygen isotopes. Samples are from both peridotite- and basalt-hosted hydrothermal systems, and basaltic systems include sediment-free and sediment-covered sites. Mg-phyllosilicates at seafloor hydrothermal sites have previously been described as talc, stevensite or saponite. In contrast, new data show tri-octahedral Mg-phyllosilicates ranging from pure talc and Fe-rich talc, through kerolite-rich kerolite-smectite to smectite-rich kerolite-smectite and tri-octahedral smectite. The most common occurrence is mixed-layer kerolite-smectite, which shows an almost complete interstratification series with 5 to 85% smectitic layers. The smectite interstratified with kerolite is mostly tri-octahedral. The degree of crystal perfection of the clay sequence decreases generally from talc to kerolite-smectite with lower crystalline perfection as the proportion of smectite layers in kerolite-smectite increases. Our studies do not support any dependence of the precipitated minerals on the type/subtype of hydrothermal system. Oxygen isotope geothermometry demonstrates that talc and kerolite-smectite precipitated in chimneys, massive sulfide mounds, at the sediment surface and in open cracks in the sediment near seafloor are high-temperature (> 250????C) phases that are most probably the result of focused fluid discharge. The other end-member of this tri-octahedral Mg-phyllosilicate sequence, smectite, is a moderate-temperature (200-250????C) phase forming deep within the sediment (??? 0.8??m). Chlorite and chlorite-smectite, which constitute the alteration sediment matrix around the hydrothermal mounds, are lower-temperature (150-200????C) phases produced by diffuse fluid discharge through the sediment around the hydrothermal conduits. In addition to temperature, other two controls on the precipitation of this sequence are the silica activity and Mg/Al ratio (i.e. the degree of mixing of seawater with hydrothermal fluid). Higher silica activity favors the formation of talc relative to tri-octahedral smectite. Vent structures and sedimentary cover preclude complete mixing of hydrothermal fluid and ambient seawater, resulting in lower Mg/Al ratios in the interior parts of the chimneys and deeper in the sediment which leads to the precipitation of phyllosilicates with lower Mg contents. Talc and kerolite-smectite have very low trace- and rare earth element contents. Some exhibit a negative or flat Eu anomaly, which suggests Eu depletion in the original hydrothermal fluid. Such Eu depletion could be caused by precipitation of anhydrite or barite (sinks for Eu2+) deeper in the system. REE abundances and distribution patterns indicate that chlorite and chlorite-smectite are hydrothermal alteration products of the background turbiditic sediment. ?? 2007 Elsevier B.V. All rights reserved.

Chemical Geology↗

USGS1998

Ordovician K-bentonites in the Argentine Precordillera: Relations to Gondwana margin evolution

Ordovician K-bentonites have now been recorded from >20 localities in the vicinity of the Argentine Precordillera. Most occur in the eastern thrust belts, in the San Juan Limestone and the overlying the Gualcamayo Formation, but a few ash beds are known also from the central thrust belts. The oldest occur in the middle Arenig I. victoriae lunatus graptolite ( Oe. evae conodont) Zone, and the youngest in the middle Llanvirn P. elegans ( P. suecicus ) Zone. Mineralogical characteristics, typical of other Ordovician K-bentonites, include a matrix of illite/smectite mixed-layer clay and a typical felsic volcanic phenocryst assemblage: biotite, beta-form quartz, alkali and plagioclase feldspar, apatite, and zircon, with lesser amounts of hornblende, clinopyroxene, titanite and Fe-Ti oxides. The proportions of the mineral phases and variations in their crystal chemistry are commonly unique to individual (or small groups of) K-bentonite beds. Glass melt inclusions preserved in quartz are rhyolitic in composition. The sequence is unique in its abundance of K-bentonite beds, but a close association between the Precordillera and other Ordovician sedimentary basins cannot be established. The ash distribution is most consistent with palaeogeographical reconstructions in which early Ordovician drifting of the Precordillera occurred in proximity to one or more volcanic arcs, and with eventual collision along the Andean margin of Gondwana during the mid-Ordovician Ocloyic event of the Famatinian orogeny. The Puna-Famatina terrane northeast of the Precordillera might have served as the source of the K-bentonite ashes, possibly in concert with active arc magmatism on the Gondwana plate itself.

Geological Society Special Publication↗

USGS2006

Environmental aspects of produced-water salt releases in onshore and coastal petroleum-producing areas of the conterminous U.S. - a bibliography

Environmental effects associated with the production of oil and gas have been reported since the first oil wells were drilled in the Appalachian Basin in Pennsylvania and Kentucky in the early to mid-1800s. The most significant of these effects are the degradation of soils, ground water, surface water, and ecosystems they support by releases of suspended and dissolved hydrocarbons and co-produced saline water. Produced water salts are less likely than hydrocarbons to be adsorbed by mineral phases in the soil and sediment and are not subject to degradation by biologic processes. Sodium is a major dissolved constituent in most produced waters and it causes substantial degradation of soils through altering of clays and soil textures and subsequent erosion. Produced water salts seem to have the most wide-ranging effects on soils, water quality, and ecosystems. Trace elements, including boron, lithium, bromine, fluorine, and radium, also occur in elevated concentrations in some produced waters. Many trace elements are phytotoxic and are adsorbed and may remain in soils after the saline water has been flushed away. Radium-bearing scale and sludge found in oilfield equipment and discarded on soils pose additional hazards to human health and ecosystems. This bibliography includes studies from across the oil- and natural-gas-producing areas of the conterminous United States that were published in the last 80 yrs. The studies describe the effects of produced water salts on soils, water quality, and ecosystems. Also included are reports that describe (1) the inorganic chemistry of produced waters included in studies of formation waters for various purposes, (2) other sources of salt affecting water quality that may be mistaken for produced water effects, (3) geochemical and geophysical techniques that allow discrimination of salt sources, (4) remediation technologies designed to repair damage caused to soils and ground water by produced water salts, and (5) contamination by naturally occurring radioactive materials (NORM)at oilfield sites.

Open-File Report↗

USGS2010

Mineral resource of the month: perlite

The article talks about perlite, which is a mineral used as an aggregate for lightweight construction products, filler for paints and horticultural soil blends. Perlite comes from viscous lava, mined and processed to produce lightweight material that competes with pumice, exfoliated vermiculite and expanded clay and shale. It is mined in about 35 countries that include Greece, Japan and the U.S. Other uses include insulation, concrete and plaster aggregate, and stonewashing.

Earth↗

USGS1990

A geochemical sampling technique for use in areas of active alpine glaciation: an application from the central Alaska Range

In mountainous regions containing extensive glacier systems there is a lack of suitable material for conventional geochemical sampling. As a result, in most geochemical sampling programs a few stream-sediment samples collected at, or near, the terminus of valley glaciers are used to evaluate the mineral potential of the glaciated area. We have developed and tested a technique which utilizes the medial moraines of valley glaciers for systematic geochemical exploration of the glacial catchment area. Moraine sampling provides geochemical information that is site-specific in that geochemical anomalies can be traced directly up-ice to bedrock sources. Traverses were made across the Trident and Susitna glaciers in the central Alaska Range where fine-grained (clay to sand size) samples were collected from each medial moraine. These samples were prepared and chemically analyzed to determine the concentration of specific elements. Fifty pebbles were collected at each moraine for archival purposes and for subsequent lithologic identification. Additionally, fifty cobbles and fifty boulders were examined and described at each sample site to determine the nature and abundance of lithologies present in the catchment area, the extent and nature of visible mineralization, the presence and intensity of hydrothermal alteration and the existence of veins, dikes and other minor structural features. Results from the central Alaska Range have delineated four distinct multi-element anomalies which are a response to potential mineralization up-ice from the medial moraine traverse. By integrating the lithologic, mineralogical and geochemical data the probable geological setting of the geochemical anomalies is determined.

Journal of Geochemical Exploration↗

USGS2006

Unusual Holocene and late Pleistocene carbonate sedimentation in Bear Lake, Utah and Idaho, USA

Bear Lake (Utah-Idaho, USA) has been producing large quantities of carbonate minerals of varying mineralogy for the past 17,000 years. The history of sedimentation in Bear Lake is documented through the study of isotopic ratios of oxygen, carbon, and strontium, percent organic carbon, percent CaCO3, X-ray diffraction mineralogy, HCl-leach inorganic geochemistry, and magnetic properties on samples from three piston cores. Historically, the Bear River, the main source of water for Great Salt Lake, did not enter Bear Lake until it was artificially diverted into the lake at the beginning of the 20th century. However, during the last glacial interval, the Bear River did enter Bear Lake depositing red, calcareous, silty clay. About 18,000 years ago, the Bear River became disconnected from Bear Lake. A combination of warmer water, increased evaporation, and increased organic productivity triggered the precipitation of calcium carbonate, first as calcite. As the salinity of the lake increased due to evaporation, aragonite began to precipitate about 11,000 years ago. Aragonite is the dominant mineral that accumulated in bottom sediments of the lake during the Holocene, comprising an average of about 70 wt.% of the sediments. Aragonite formation in a large, cold, oligotrophic, high latitude lake is highly unusual. Lacustrine aragonite usually is found in small, saline lakes in which the salinity varies considerably over time. However, Bear Lake contains endemic ostracodes and fish, which indicate that the chemistry of the lake has remained fairly constant for a long time. Stable isotope data from Holocene aragonite show that the salinity of Bear Lake increased throughout the Holocene, but never reached highly evolved values of ??18O in spite of an evaporation-dominated water balance. Bear Lake hydrology combined with evaporation created an unusual situation that produced large amounts of aragonite, but no evaporite minerals.

Sedimentary Geology↗

USGS2011

Mineral resource of the month: gypsum

You may not realize it, but the walls of your office are probably made from a mineral: gypsum. Gypsum is an abundant, evaporite-derived sedimentary mineral with deposits located throughout the world. It is often associated with paleoenvironmental lake and marine environments. In its pure form, gypsum consists of calcium sulfate dihydrate, although most crude gypsum naturally occurs in combination with anhydrite, clay, dolomite and/or limestone.

Earth↗

USGS2012

The impact of biotic/abiotic interfaces in mineral nutrient cycling: A study of soils of the Santa Cruz chronosequence, California

Biotic/abiotic interactions between soil mineral nutrients and annual grassland vegetation are characterized for five soils in a marine terrace chronosequence near Santa Cruz, California. A Mediterranean climate, with wet winters and dry summers, controls the annual cycle of plant growth and litter decomposition, resulting in net above-ground productivities of 280–600 g m −2 yr −1 . The biotic/abiotic (A/B) interface separates seasonally reversible nutrient gradients, reflecting biological cycling in the shallower soils, from downward chemical weathering gradients in the deeper soils. The A/B interface is pedologically defined by argillic clay horizons centered at soil depths of about one meter which intensify with soil age. Below these horizons, elevated solute Na/Ca, Mg/Ca and Sr/Ca ratios reflect plagioclase and smectite weathering along pore water flow paths. Above the A/B interface, lower cation ratios denote temporal variability due to seasonal plant nutrient uptake and litter leaching. Potassium and Ca exhibit no seasonal variability beneath the A/B interface, indicating closed nutrient cycling within the root zone, whereas Mg variability below the A/B interface denotes downward leakage resulting from higher inputs of marine aerosols and lower plant nutrient requirements. The fraction of a mineral nutrient annually cycled through the plants, compared to that lost from pore water discharge, is defined their respective fluxes F j,plants = q j,plants /( q j,plants + q j,discharge ) with average values for K and Ca ( F K,plants = 0.99; F Ca,plants = 0.93) much higher than for Mg and Na ( F Mg,plants 0.64; F Na,plants = 0.28). The discrimination against Rb and Sr by plants is described by fractionation factors ( K Sr/Ca = 0.86; K Rb/K = 0.83) which are used in Rayleigh fractionation-mixing calculations to fit seasonal patterns in solute K and Ca cycling. K Rb/K and K 24 Mg / 22 Mg "> K24Mg/22Mg values (derived from isotope data in the literature) fall within fractionation envelopes bounded by inputs from rainfall and mineral weathering. K Sr/Ca and K 44 Ca / 40 Ca "> K44Ca/40Ca fractionation factors fall outside these envelopes indicating that Ca nutrient cycling is closed to these external inputs. Small net positive K and Ca fluxes (6–14 mol m −2 yr −1 ), based on annual mass balances, indicate that the soils are accumulating mineral nutrients, probably as a result of long-term environmental disequilibrium.

California↗

USGS1990

Collection and analysis of colloidal particles transported in the Mississippi River, U.S.A.

Sediment transport has long been recognized as an important mechanism for the transport of contaminants in surface waters. Suspended sediment has traditionally been divided into three size classes: sand-sized (>63 ??m), silt-sized (<63 ??m but settleable) and clay-sized (non-settleable). The first two classes are easily collected and characterized using screens (sand) and settling (silt). The clay-sized particles, more properly called colloids, are more difficult to collect and characterize, and until recently received little attention. From the hydrologic perspective, a colloid is a particle, droplet, or gas bubble with at least one dimension between 0.001 and 1 ??m. Because of their small size, colloids have large specific surface areas and high surface free energies which may facilitate sorption of hydrophobic materials. Understanding what types of colloids are present in a system, how contaminants of interest interact with these colloids, and what parameters control the transport of colloids in natural systems is critical if the relative importance of colloid-mediated transport is to be understood. This paper describes the collection, concentration and characterization of colloidal materials in the Mississippi River. Colloid concentrations, particle-size distributions, mineral composition and electrophoretic mobilities were determined. Techniques used are illustrated with samples collected at St. Louis, Missouri, U.S.A.Sediment transport has long been recognized as an important mechanism for the transport of contaminants in surface waters. Suspended sediment has traditionally been divided into three size classes: sand-sized (> 63 ??m), silt-sized (< 63 ??m but settleable) and clay-sized (non-settleable). The first two classes are easily collected and characterized using screens (sand) and settling (silt). The clay-sized particles, more properly called colloids, are more difficult to collect and characterize, and until recently received little attention. From the hydrologic perspective, a colloid is a particle, droplet, or gas bubble with at least one dimension between 0.001 and 1 ??m. Because of their small size, colloids have large specific surface areas and high surface free energies which may facilitate sorption of hydrophobic materials. Understanding what types of colloids are present in a system, how contaminants of interest interact with these colloids, and what parameters control the transport of colloids in natural systems is critical if the relative importance of colloid-mediated transport is to be understood. This paper describes the collection, concentration and characterization of colloidal materials in the Mississippi River. Colloid concentrations, particle-size distributions, mineral composition and electrophoretic mobilities were determined. Techniques used are illustrated with samples collected at St. Louis, Missouri, U.S.A.

Journal of Contaminant Hydrology↗

USGS1989

Geochemical expression of early diagenesis in middle Eocene-lower Oligocene pelagic sediments in the southern Labrador Sea, Site 647, ODP Leg 105

Geochemical analyses of the middle Eocene through lower Oligocene lithologic Unit IIIC (260-518 meters below sea floor [mbsf]) indicate a relatively constant geochemical composition of the detrital fraction throughout this depositional interval at Ocean Drilling Program (ODP) Site 647 in the southern Labrador Sea. The main variability occurs in redox-sensitive elements (e.g., iron, manganese, and phosphorus), which may be related to early diagenetic inability in anaerobic pore waters during bacterial decomposition of organic matter. Initial preservation of organic matter was mediated by high sedimentation rates (36 m/m.Y.). High iron (Fe) and manganese (Mn) contents are associated with carbonate concretions of siderite, manganosiderite, and rhodochrosite. These concretions probably formed in response to elevated pore-water alkalinity and total dissolved carbon dioxide (CO2) concentrations resulting from bacterial sulfate reduction, as indicated by nodule stable-isotope compositions and pore-water geochemistry. These nodules differ from those found in upper Cenozoic hemipelagic sequences in that they are not associated with methanogenesis. Phosphate minerals (carbonate-fluorapatite) precipitated in some intervals, probably as the result of desorption of phosphorus from iron and manganese during reduction. The bulk chemical composition of the sediments differs little from that of North Atlantic Quaternary abyssal red clays, but may contain a minor hydrothermal component. The silicon/ aluminum (Si/Al) ratio, however, is high and variable and probably reflects original variations in biagenic opal, much of which is now altered to smectite and/or opal CT. An increase in the sodium/potassium (Na/K) ratio in the upper Eocene corresponds to the beginning of coarser-grained feldspar flux to the site, possibly marking the onset of more vigorous deep currents. Although the Site 647 cores provide a nearly complete high-resolution, high-latitude Eocene-Oligocene record, the high sedimentation rate and somewhat unusual diagenetic conditions have led to variable alteration of benthic foraminifers and fine-fraction carbonate and have overprinted the original stable-isotope records. Planktonic foraminifers are less altered, but on the whole, there is little chance of sorting out the nature and timing of environmental change on the basis of our stable-isotope analyses.

Proceedings of the Ocean Drilling Program: Scienti↗

USGS1998

Oreshoot zoning in the Carlin-type Betze orebody, Goldstrike Mine, Eureka County, Nevada

Field and laboratory investigations of the giant Betze gold orebody, the largest Carlin-type deposit known, in the north-central Carlin trend, Nevada document that the orebody is composed of individual high-grade oreshoots that contain different geologic, mineralogic, and textural characteristics. The orebody is typical of many structurally controlled Carlin-type deposits, and is hosted in thin-bedded, impure carbonate or limy siltstone, breccia bodies, and intrusive or calc-silicate rock. Most ores in the Betze orebody are highly sheared or brecciated and show evidence of syndeformational hydrothermal deposition. The interplay between rock types and pre- and syn-structural events accounts for most of the distribution and zoning of the oreshoots. Hydrothermal alteration is scale dependent, either in broad, pervasive alteration patterns, or in areas related to various oreshoots. Alteration includes decarbonatization (~decalcification) of carbonate units, argillization (illite-clay), and silicification. Patterns of alteration zoning in and surrounding the Betze orebody define a large porous, dilated volume of rock where high fluid flow predominated. Local restriction of alteration to narrow illite- and clay-rich selvages around unaltered marble or calc-silicate rock phacoids implies that fluid flow favored permeable structures and deformed zones. Gold mainly is present as disseminated sub-micron-sized particles, commonly associated with Asñrich pyrite, although one type of oreshoot contains micron-size free gold. Oreshoots form a three-dimensional zoning pattern in the orebody within a WNW-striking structural zone of shearing and shear folding, termed the Dillon deformation zone (DDZ). Main types of oreshoots are: (1) rutile-bearing siliceous oreshoots; (2) illite-clay-pyrite oreshoots; (3) realgar- and orpiment-bearing oreshoots; (4) stibnite-bearing siliceous oreshoots; and (5) polymetallic oreshoots. Zoning patterns result from paragenetically early development of illite-clay-pyrite oreshoots during movement along the DDZ, and subsequent silicification and brecciation, associated with formation of the realgar- and orpiment-bearing, and stibnite-bearing oreshoots. Additional shear movement along the DDZ followed. Polymetallic oreshoots, which contain minerals rich in Hg, Cu, Zn, Ag, and native Au, were the last ores to form and overprint most earlier oreshoots. Ore textures, gouge, phyllonitic rock, alteration style, and previously documented isotopic and fluid-inclusion data, all indicate a weakly to moderately saline fluid that ascended and cooled during structural displacements. Changing conditions, due to water-wall rock reactions and P-T changes during deformation, are probably responsible for fluid variation that resulted in zoning of the different oreshoots during dynamic interaction of the Au-bearing fluid with the wall rock. This investigation indicates that isolated As-, Sb-, and Hg-rich ores are separate parts of a larger single gold system. This large gold system was contemporaneous with post-Jurassic brittle-ductile deformation, on the basis of deformed mineralized pods of the Jurassic Goldstrike pluton, and large-scale hydrothermal flow, and together they appear to be an integral part of the formation of some Carlin-type gold deposits in north-central Nevada.

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