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At least 559 records · Page 31Linked to original sources
USGS1988

Selenium accumulation in benthic bivalves and fine sediments of San Francisco Bay, the Sacramento-San Joaquin Delta, and selected tributaries

Spatial distributions of selenium were determined in fine-grained, oxidized, surface sediments and in two benthic bivalves ( Corbicula sp., a suspension-feeding freshwater clam, and Macoma balthica , a deposit-feeding brackish-water clam) within San Francisco Bay, the San Joaquin River and three river systems unlikely to be subject to selenium inputs. Biologically available selenium enters the middle reaches of the San Joaquin River from agricultural runoff. However, selenium concentrations in sediments and Corbicula in the lower San Joaquin, upstream from San Francisco Bay, were not significantly different from concentrations in rivers with no known selenium inputs. Biologically available selenium did not appear to enter the northernmost reach of San Francisco Bay from the San Joaquin River in levels which could measurably influence bioaccumulation by Corbicula . Selenium concentrations in Corbicula were enriched in the northernmost reach of San Francisco Bay compared with the rivers, but several lines of evidence suggested that local inputs (perhaps from urban/industrial waste discharges) were the most important sources. Selenium concentrations in Macoma balthica were also elevated at one station in the northern reach of the Bay and at one station in the extreme South Bay. However, no enrichment was evident at two other stations, suggesting a lack of bay-wide contamination. No significant correlation between selenium and mercury concentrations in Corbicula tissues was observed.

California↗
USGS2019

Recent trends in nutrient and sediment loading to coastal areas of the conterminous U.S.: Insights and global context

Coastal areas in the U.S. and worldwide have experienced massive population and land use changes contributing to significant degradation of coastal ecosystems. Excess nutrient pollution causes coastal ecosystem degradation, and both regulatory and management efforts have targeted reducing nutrient and sediment loading to coastal rivers. Decadal trends in flow-normalized nutrient and sediment loads were determined for 95 monitoring locations on 88 U.S. coastal rivers, including tributaries of the Great Lakes, between 2002 and 2012 for nitrogen (N), phosphorus (P), and sediment. N and P loading from urban watersheds generally decreased between 2002 and 2012. In contrast, N and P trends in agricultural watersheds were variable indicating uneven progress in decreasing nutrient loading. Coherent decreases in N loading from agricultural watersheds occurred in the Lake Erie basin, but limited benefit is expected from these changes because P is the primary driver of degradation in the lake. Nutrient loading from undeveloped watersheds was low, but increased between 2002 and 2012, possibly indicating degradation of coastal watersheds with a lower intensity of anthropogenic influence. Regional differences in trends were evident, with stable nutrient loads from the Mississippi River to the Gulf of Mexico, but commonly decreasing N loads and increasing P loads in Chesapeake Bay. Compared to global rivers, coastal rivers of the conterminous U.S have somewhat lower TN yields and slightly higher TP yields, but similarities exist among land use, nutrient sources, and changes in nutrient loads. Despite widespread decreases in N loading in coastal watersheds, recent N:P ratios remained elevated compared to historic values in many areas. Additional progress in reducing N and P loading to U.S. coastal waters, particularly outside of urban areas, would benefit coastal ecosystems.

Science of the Total Environment↗
USGS2015

Experimental dosing of wetlands with coagulants removes mercury from surface water and decreases mercury bioaccumulation in fish

Mercury pollution is widespread globally, and strategies for managing mercury contamination in aquatic environments are necessary. We tested whether coagulation with metal-based salts could remove mercury from wetland surface waters and decrease mercury bioaccumulation in fish. In a complete randomized block design, we constructed nine experimental wetlands in California’s Sacramento–San Joaquin Delta, stocked them with mosquitofish ( Gambusia affinis ), and then continuously applied agricultural drainage water that was either untreated (control), or treated with polyaluminum chloride or ferric sulfate coagulants. Total mercury and methylmercury concentrations in surface waters were decreased by 62% and 63% in polyaluminum chloride treated wetlands and 50% and 76% in ferric sulfate treated wetlands compared to control wetlands. Specifically, following coagulation, mercury was transferred from the filtered fraction of water into the particulate fraction of water which then settled within the wetland. Mosquitofish mercury concentrations were decreased by 35% in ferric sulfate treated wetlands compared to control wetlands. There was no reduction in mosquitofish mercury concentrations within the polyaluminum chloride treated wetlands, which may have been caused by production of bioavailable methylmercury within those wetlands. Coagulation may be an effective management strategy for reducing mercury contamination within wetlands, but further studies should explore potential effects on wetland ecosystems.

California↗
USGS2026

Assessing pesticide application contributions of per- and polyfluoroalkyl substances (PFAS) in agricultural streams

Research has documented per-and polyfluoroalkyl substances (PFAS) to be prevalent in streams impacted by urban sources; less is known regarding PFAS contributions via pesticide applications: PFAS coming from pesticide containers and “inert” ingredients not listed on pesticide formulation labels. To better understand co-occurrence of pesticides and PFAS in agricultural streams, 10 streams were sampled in two agricultural valleys in northern California, USA during two periods of pesticide application (May and July of 2024). Water samples were analyzed for 183 pesticides and 57 PFAS. Sixty pesticides were detected: 23 herbicides, 18 insecticides, 18 fungicides, and 1 synergist. Overall detection frequencies (DF) ranged from 0 to 100%, and concentrations ranged from non-detect (ND) to 782 ng/L (fluxapyroxad). Fourteen PFAS were detected: 6 perfluoroalkyl carboxylates, 5 perfluoroalkyl sulfonates, 2 perfluoroalkyl acid precursors, and 1 perfluoroalkyl phosphinic acid with DFs ranging from 0 to 60% (PFOA) and concentrations ranging from ND to 20 ng/L (PFBA). Co-occurrence of PFAS and pesticides was observed in 80% of samples. Adopting the global definition of PFAS (includes fluorinated pesticides), pesticide applications are a likely source of instream PFAS. Examination of total organic fluorine and transformations to terminal and ultra-short PFAS could further elucidate pesticide contributions to environmental PFAS.

California↗
USGS2016

Mercury and methylmercury in aquatic sediment across western North America

Large-scale assessments are valuable in identifying primary factors controlling total mercury (THg) and monomethyl mercury (MeHg) concentrations, and distribution in aquatic ecosystems. Bed sediment THg and MeHg concentrations were compiled for > 16,000 samples collected from aquatic habitats throughout the West between 1965 and 2013. The influence of aquatic feature type (canals, estuaries, lakes, and streams), and environmental setting (agriculture, forest, open-water, range, wetland, and urban) on THg and MeHg concentrations was examined. THg concentrations were highest in lake (29.3 ± 6.5 μg kg − 1 ) and canal (28.6 ± 6.9 μg kg − 1 ) sites, and lowest in stream (20.7 ± 4.6 μg kg − 1 ) and estuarine (23.6 ± 5.6 μg kg − 1 ) sites, which was partially a result of differences in grain size related to hydrologic gradients. By environmental setting, open-water (36.8 ± 2.2 μg kg − 1 ) and forested (32.0 ± 2.7 μg kg − 1 ) sites generally had the highest THg concentrations, followed by wetland sites (28.9 ± 1.7 μg kg − 1 ), rangeland (25.5 ± 1.5 μg kg − 1 ), agriculture (23.4 ± 2.0 μg kg − 1 ), and urban (22.7 ± 2.1 μg kg − 1 ) sites. MeHg concentrations also were highest in lakes (0.55 ± 0.05 μg kg − 1 ) and canals (0.54 ± 0.11 μg kg − 1 ), but, in contrast to THg, MeHg concentrations were lowest in open-water sites (0.22 ± 0.03 μg kg − 1 ). The median percent MeHg (relative to THg) for the western region was 0.7%, indicating an overall low methylation efficiency; however, a significant subset of data (n > 100) had percentages that represent elevated methylation efficiency (> 6%). MeHg concentrations were weakly correlated with THg (r 2 = 0.25) across western North America. Overall, these results highlight the large spatial variability in sediment THg and MeHg concentrations throughout western North America and underscore the important roles that landscape and land-use characteristics have on the MeHg cycle.

Science of the Total Environment↗
USGS2023

Near real-time detection of winter cover crop termination using harmonized Landsat and Sentinel-2 (HLS) to support ecosystem assessment

Cover crops are planted to reduce soil erosion, increase soil fertility, and improve watershed management. In the Delmarva Peninsula of the eastern United States, winter cover crops are essential for reducing nutrient and sediment losses from farmland. Cost-share programs have been created to incentivize cover crops to achieve conservation objectives. This program required that cover crops be planted and terminated within a specified time window. Usually, farmers report cover crop termination dates for each enrolled field (∼28,000 per year), and conservation district staff confirm the report with field visits within two weeks of termination. This verification process is labor-intensive and time-consuming and became restricted in 2020–2021 due to the COVID-19 pandemic. This study used Harmonized Landsat and Sentinel-2 (HLS, version 2.0) time-series data and the within-season termination (WIST) algorithm to detect cover crop termination dates over Maryland and the Delmarva Peninsula. The estimated remote sensing termination dates were compared to roadside surveys and to farmer-reported termination dates from the Maryland Department of Agriculture database for the 2020–2021 cover crop season. The results show that the WIST algorithm using HLS detected 94% of terminations (statuses) for the enrolled fields (n = 28,190). Among the detected terminations, about 49%, 72%, 84%, and 90% of remote sensing detected termination dates were within one, two, three, and four weeks of agreement to farmer-reported dates, respectively. A real-time simulation showed that the termination dates could be detected one week after termination operation using routinely available HLS data, and termination dates detected after mid-May are more reliable than those from early spring when the Normalized Difference Vegetation Index (NDVI) was low. We conclude that HLS imagery and the WIST algorithm provide a fast and consistent approach for generating near-real-time cover crop termination maps over large areas, which can be used to support cost-share program verification.

Maryland↗
USGS1999

Metolachlor and its metabolites in tile drain and stream runoff in the canajoharie creek watershed

Water samples collected during April−November 1997 from tile drains beneath cultivated fields in central New York indicate that two metabolites of the herbicide metolachlor metolachlor ESA (ethanesulfonic acid) and OA (oxanilic acid) can persist in agricultural soils for 4 or more years after application and that fine-grained soils favor the transport of metolachlor ESA over metolachlor and metolachlor OA. Concentrations of metolachlor ESA from the tile drains ranged from 3.27 to 23.4 μg/L (200−1800 times higher than those of metolachlor), metolachlor OA concentrations ranged from 1.14 to 13.5 μg/L, and metolachlor concentrations ranged from less than 0.01 to 0.1 μg/L. In the receiving stream, concentrations of metolachlor ESA were always below 0.6 μg/L except during a November storm, when concentrations reached 0.85 μg/L. Concentrations of metolachlor ESA in the stream were 2−45 times higher than those of metolachlor, reflecting the greater relative concentrations of metolachlor in surface water runoff than in tile drain runoff. These results are consistent with findings in other studies that acetanilide herbicide degredates are found in much higher concentrations than parent compounds in both surface water and groundwater.

New York↗
USGS2021

Groundwater development leads to decreasing arsenic concentrations in the San Joaquin Valley, California

In the San Joaquin Valley (SJV), California, about 10% of drinking water wells since 2010 had arsenic concentrations above the US maximum contaminant level of 10 μg/L. High concentrations of arsenic are often associated with high pH (greater than 7.8) or reduced geochemical conditions. Although most wells have low arsenic (<3 μg/L) and do not have changing arsenic concentrations, this study found that most wells with concentrations above 10 μg/L had arsenic trends. Overall, about 24% of wells had time-series trends since 2010 and 59% had paired-sample trends since 2000. Most wells had decreasing arsenic trends, even in wells with higher arsenic concentrations. These wells often had co-detections of increasing nitrate and sulfate trends that reflect oxic groundwater likely derived from agricultural recharge. Wells with increasing arsenic trends were deeper or located in the valley trough where aquifer materials are more fine-grained and where reducing conditions favor arsenic mobility. Wells with arsenic trends also tend to be clustered near areas of higher well density. Groundwater pumping in these areas has likely increased the contribution of younger, more oxic groundwater in wells with declining arsenic or, less frequently, increased the contribution of higher pH or reduced groundwater in wells with rising arsenic. Projections of arsenic trends indicate that 37 wells with high arsenic presently will be below 10 μg/L in ten years. Unfortunately, these improvements will be largely offset by 31 wells that are expected to increase above 10 μg/L in addition to expected rises in nitrate in wells where arsenic decreased. This study shows how human-altered flow systems can impact the natural geochemical character of water in both beneficial and deleterious ways.

California↗
USGS2000

Occurrence of cotton herbicides and insecticides in playa lakes of the High Plains of West Texas

During the summer of 1997, water samples were collected and analyzed for pesticides from 32 playa lakes of the High Plains that receive drainage from both cotton and corn agriculture in West Texas. The major cotton herbicides detected in the water samples were diuron, fluometuron, metolachlor, norflurazon, and prometryn. Atrazine and propazine, corn and sorghum herbicides, were also routinely detected in samples from the playa lakes. Furthermore, the metabolites of all the herbicides studied were found in the playa lake samples. In some cases, the concentration of metabolites was equal to or exceeded the concentration of the parent compound. The types of metabolites detected suggested that the parent compounds had been transported to and had undergone degradation in the playa lakes. The types of metabolites and the ratio of metabolites to parent compounds may be useful in indicating the time that the herbicides were transported to the playa lakes. The median concentration of total herbicides was 7.2 μg/l, with the largest total concentrations exceeding 30 μg/l. Organophosphate insecticides were detected in only one water sample. Further work will improve the understanding of the fate of these compounds in the playa lake area.

Science of Total Environment↗
USGS1999

Are shifts in herbicide use reflected in concentration changes in Midwestern rivers?

In many Midwestern rivers, elevated concentrations of herbicides occur during runoff events for 1-3 months following application. The highest or 'peak' herbicide concentration often occurs during one of these runoff events. Herbicide concentrations in rivers are affected by a number of factors, including herbicide use patterns within the associated basin. Changing agricultural practices, reductions in recommended and permitted herbicide applications, shifts to new herbicides, and greater environmental awareness in the agricultural community have resulted in changes to herbicide use patterns. In the Midwestern United States, alachlor use was much larger in 1989 than in 1995, while acetochlor was not used in 1989, and commonly used in 1995. Use of atrazine, cyanazine, and metolachlor was about the same in 1989 and 1995. Herbicide concentrations were measured in samples from 53 Midwestern rivers during the first major runoff event that occurred after herbicide application (postapplication) in 1989, 1990, 1994, and 1995. The median concentrations of atrazine, alachlor, cyanazine, metribuzin, metolachlor, propazine, and simazine all were significantly higher in 1989/90 than in 1994/95. The median acetochlor concentration was higher in 1995 than in 1994. Estimated daily yields for all herbicides and degradation products measured, with the exception of acetochlor, were higher in 1989/90 than in 1994/95. The differences in concentration and yield do not always parallel changes in herbicide use, suggesting that other changes in herbicide or crop management are affecting concentrations in Midwestern rivers during runoff events.In many Midwestern rivers, elevated concentrations of herbicides occur during runoff events for 1-3 months following application. The highest or `peak' herbicide concentration often occurs during one of these runoff events. Herbicide concentrations in rivers are affected by a number of factors, including herbicide use patterns within the associated basin. Changing agricultural practices, reductions in recommended and permitted herbicide applications, shifts to new herbicides, and greater environmental awareness in the agricultural community have resulted in changes to herbicide use patterns. In the Midwestern United States, alachlor use was much larger in 1989 than in 1995, while acetochlor was not used in 1989, and commonly used in 1995. Use of atrazine, cyanazine, and metolachlor was about the same in 1989 and 1995. Herbicide concentrations were measured in samples from 53 Midwestern rivers during the first major runoff event that occurred after herbicide application (postapplication) in 1989, 1990, 1994, and 1995. The median concentrations of atrazine, alachlor, cyanazine, metribuzin, metolachlor, propazine, and simazine all were significantly higher in 1989/90 than in 1994/95. The median acetochlor concentration was higher in 1995 than in 1994. Estimated daily yields for all herbicides and degradation products measured, with the exception of acetochlor, were higher in 1989/90 than in 1994/95. The differences in concentration and yield do not always parallel changes in herbicide use, suggesting that other changes in herbicide or crop management are affecting concentrations in Midwestern rivers during runoff events.

Environmental Science & Technology↗
USGS1990

Distribution of agrochemicals in the lower Mississippi River and its tributaries

The Mississippi River and its tributaries drain extensive agricultural regions of the Mid-Continental United States. Millions of pounds of herbicides are applied annually in these areas to improve crop yields. Many of these compounds are transported into the river from point and nonpoint sources, and eventually are discharged into the Gulf of Mexico. Studies being conducted by the U.S. Geological Survey along the lower Mississippi River and its major tributaries, representing a 2000 km river reach, have confirmed that several triazine and acetanilide herbicides and their degradation products are ubiquitous in this riverine system. These compounds include atrazine and its degradation products desethyl and desisopropylatrazine, cyanazine, simazine, metolachlor, and alachlor and its degradation products 2-chloro-2',6'-diethylacetanilide, 2-hydroxy-2',6-diethylacetanilide and 2,6-diethylaniline. Loads of these compounds were determined at 16 different sampling stations. Stream-load calculations provided information concerning (a) conservative or nonconservative behavior of herbicides; (b) point sources or nonpoint sources; (c) validation of sampling techniques; and (d) transport past each sampling station.

Lower Mississippi River↗
USGS2015

Density of river otters (Lontra canadensis) in relation to energy development in the Green River Basin, Wyoming

Exploration and extraction of oil and natural gas have increased in recent years and are expected to expand in the future. Reduction in water quality from energy extraction may negatively affect water supply for agriculture and urban use within catchments as well as down river. We used non-invasive genetic techniques and capture&ndash;recapture modeling to estimate the abundance and density of North American river otters ( Lontra canadensis ), a sentinel species of aquatic ecosystems, in Southwestern Wyoming. While densities in two of three river reaches were similar to those reported in other freshwater systems in the western US (1.45&ndash;2.39 km per otter), otters appeared to avoid areas near energy development. We found no strong difference in habitat variables, such as overstory cover, at the site or reach level. Also, fish abundance was similar among the three river reaches. Otter activity in our study area could have been affected by elevated levels of disturbance surrounding the industrial gas fields, and by potential surface water contamination as indicated by patterns in water conductivity. Continued monitoring of surface water quality in Southwestern Wyoming with the aid of continuously recording devices and sentinel species is warranted.

Wyoming↗
USGS2025

Resource selection of the southern fox squirrel (Sciurus niger niger) in the coastal plain of Virginia

The southern fox squirrel ( Sciurus niger niger ) is a subspecies of fox squirrel that ranges from southeastern Virginia to northern Florida. Throughout its Southeastern range, southern fox squirrel habitat of natural mixed pine-hardwood forests has been fragmented by agriculture and short-rotation pine plantations. In Virginia, remaining habitat has been transformed by fire suppression on the landscape and has in turn resulted in small, disjunct populations of southern fox squirrels. We sought to identify the home range and resource utilization of southern fox squirrels in the southern Coastal Plain of Virginia. From established nest boxes, we captured, radio collared and tracked four individuals at Big Woods Wildlife Management area and Piney Grove Complex in Sussex County in 2022. We observed an average male 95% and 50% adaptive kernel home range 173.49 ha (SE = 25.73, N = 2) and 40.62 ha (SE = 5.87, N = 2), respectively and an average female 95% and 50% adaptive kernel home range of 28.51 ha (SE = 0.49, N = 2) and 4.71 ha (SE = 0.34, N = 2), respectively. At both the second and third orders of habitat selection, squirrels selected for pine savanna cover types and short fire-return intervals.

Virginia↗
USGS2011

Removal of inorganic mercury and methylmercury from surface waters following coagulation of dissolved organic matter with metal-based salts

The presence of inorganic mercury (IHg) and methylmercury (MeHg) in surface waters is a health concern worldwide. This study assessed the removal potential use of metal-based coagulants as a means to remove both dissolved IHg and MeHg from natural waters and provides information regarding the importance of Hg associations with the dissolved organic matter (DOM) fraction and metal hydroxides. Previous research indicated coagulants were not effective at removing Hg from solution; however these studies used high concentrations of Hg and did not reflect naturally occurring concentrations of Hg. In this study, water collected from an agricultural drain in the Sacramento-San Joaquin Delta was filtered to isolate the dissolved organic matter (DOM) fraction. The DOM was then treated with a range of coagulant doses to determine the efficacy of removing all forms of Hg from solution. Three industrial-grade coagulants were tested: ferric chloride, ferric sulfate, and polyaluminum chloride. Coagulation removed up to 85% of DOM from solution. In the absence of DOM, all three coagulants released IHg into solution, however in the presence of DOM the coagulants removed up to 97% of IHg and 80% of MeHg. Results suggest that the removal of Hg is mediated by DOM-coagulant interactions. There was a preferential association of IHg with the more aromatic, higher molecular weight fraction of DOM but no such relationship was found for MeHg. This study offers new fundamental insights regarding large-scale removal of Hg at environmentally relevant regarding large-scale removal of Hg at environmentally relevant concentrations.

Science of the Total Environment↗
USGS2012

Simulation of climate change in San Francisco Bay Basins, California: Case studies in the Russian River Valley and Santa Cruz Mountains

As a result of ongoing changes in climate, hydrologic and ecologic effects are being seen across the western United States. A regional study of how climate change affects water resources and habitats in the San Francisco Bay area relied on historical climate data and future projections of climate, which were downscaled to fine spatial scales for application to a regional water-balance model. Changes in climate, potential evapotranspiration, recharge, runoff, and climatic water deficit were modeled for the Bay Area. In addition, detailed studies in the Russian River Valley and Santa Cruz Mountains, which are on the northern and southern extremes of the Bay Area, respectively, were carried out in collaboration with local water agencies. Resource managers depend on science-based projections to inform planning exercises that result in competent adaptation to ongoing and future changes in water supply and environmental conditions. Results indicated large spatial variability in climate change and the hydrologic response across the region; although there is warming under all projections, potential change in precipitation by the end of the 21st century differed according to model. Hydrologic models predicted reduced early and late wet season runoff for the end of the century for both wetter and drier future climate projections, which could result in an extended dry season. In fact, summers are projected to be longer and drier in the future than in the past regardless of precipitation trends. While water supply could be subject to increased variability (that is, reduced reliability) due to greater variability in precipitation, water demand is likely to steadily increase because of increased evapotranspiration rates and climatic water deficit during the extended summers. Extended dry season conditions and the potential for drought, combined with unprecedented increases in precipitation, could serve as additional stressors on water quality and habitat. By focusing on the relationship between soil moisture storage and evapotranspiration pressures, climatic water deficit integrates the effects of increasing temperature and varying precipitation on basin conditions. At the fine-scale used for these analyses, this variable is an effective indicator of the areas in the landscape that are the most resilient or vulnerable to projected changes. These analyses have shown that regardless of the direction of precipitation change, climatic water deficit is projected to increase, which implies greater water demand to maintain current agricultural resources or land cover. Fine-scale modeling provides a spatially distributed view of locations in the landscape that could prove to be resilient to climatic changes in contrast to locations where vegetation is currently living on the edge of its present-day bioclimatic distribution and, therefore, is more likely to perish or shift to other dominant species under future warming. This type of modeling and the associated analyses provide a useful means for greater understanding of water and land resources, which can lead to better resource management and planning.

California↗
USGS2006

Urban contributions of glyphosate and its degradate AMPA to streams in the United States

Glyphosate is the most widely used herbicide in the world, being routinely applied to control weeds in both agricultural and urban settings. Microbial degradation of glyphosate produces aminomethyl phosphonic acid (AMPA). The high polarity and water-solubility of glyphosate and AMPA has, until recently, made their analysis in water samples problematic. Thus, compared to other herbicides (e.g. atrazine) there are relatively few studies on the environmental occurrence of glyphosate and AMPA. In 2002, treated effluent samples were collected from 10 wastewater treatment plants (WWTPs) to study the occurrence of glyphosate and AMPA. Stream samples were collected upstream and downstream of the 10 WWTPs. Two reference streams were also sampled. The results document the apparent contribution of WWTP effluent to stream concentrations of glyphosate and AMPA, with roughly a two-fold increase in their frequencies of detection between stream samples collected upstream and those collected downstream of the WWTPs. Thus, urban use of glyphosate contributes to glyphosate and AMPA concentrations in streams in the United States. Overall, AMPA was detected much more frequently (67.5%) compared to glyphosate (17.5%).

Science of the Total Environment↗
USGS2024

The relative contributions of habitat area, configuration, and vegetative diversity on snake and lizard presence in agricultural landscapes

Nearly one in five reptile species is at risk of extinction. Changes in habitat area, its configuration, and vegetation diversity could affect habitat use, but their relative importance is understudied. We assessed how these factors affected reptile presence in agricultural landscapes figure in Iowa, United States, using 695 cover boards visited 16,441 times in 2015–2020. Species-wise encounter rates ranged 0.0001–0.012. Eight of 11 species and 54.2% of individuals were species of greatest conservation need. Habitat area, configuration, and vegetation diversity influenced reptile presence similarly. Mean patch occupancy was 0.18 for common garter snake (CG, Thamnophis sirtalis ) and 0.45 for all snakes (AS). Naïve presence was explained by effort (odds ratio [OR] AS = 1.83, OR CG = 1.79), vegetation diversity (OR AS = 1.28, OR CG = 1.28), woody cover (OR AS = 1.24, OR CG = 1.41), and patch size (OR AS = 1.30). Large patch prairies were more likely to contain snakes than other conservation practices ( 𝑟̂ encounter = 0.291), and more likely to contain CG (0.098) than prairie contour strips (0.031), waterways (0.018), grass contour strips (0.016), or terraces (0.015). While we documented low overall reptile presence, their higher presence in large prairie patches underscores the importance of core nature reserves for reptile conservation.

Iowa↗
USGS2005

Phosphate reactivity in long-term poultry litter-amended southern Delaware sandy soils

Eutrophication caused by dissolved P from poultry litter (PL)-amended agricultural soils has been a serious environmental concern in the Delaware-Maryland-Virginia Peninsula (Delmarva), USA. To evaluate state and federal nutrient management strategies for reducing the environmental impact of soluble P from long-term PL-amended Delaware (DE) soils, we investigated (i) inorganic P speciation; (ii) P adsorption capacity; and (iii) the extent of P desorption. Although the electron microprobe (EMP) analyses showed a strong correlation between P and Al/Fe, crystalline Al/Fe-P precipitates were not detected by x-ray diffraction (XRD). Instead, the inorganic P fractionation analyses showed high levels of oxalate extractable P, Al, and Fe fractions (615-858, 1215-1478, and 337-752 mg kg-1, respectively), which were susceptible to slow release during the long-term (30-d) P desorption experiments at a moderately acidic soil pHwater. The labile P in the short-term (24-h) desorption studies was significantly associated with oxalate and F extractable Fe and Al, respectively. This was evident in an 80% reduction maximum in total desorbable P from NH4 oxalate/F pretreated soils. In the adsorption experiments, P was strongly retained in soils at near targeted pH of lime (???6.0), but P adsorption gradually decreased with decreasing pH near the soil pHwater (???5.0). The overall findings suggest that P losses from the can be suppressed by an increase in the P retention capacity of soils via (i) an increase in the number of lime applications to maintain soil pHwater at near targeted pH values, and/or (ii) alum/iron sulfate amendments to provide additional Al- and Fe-based adsorbents. ?? Soil Science Society of America.

Soil Science Society of America Journal↗