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Ground-water availability in carbonate rocks of the Dandridge area, Jefferson County, Tennessee

Groundwater in Jefferson County, Tenn., occurs in solution openings that follow bedding planes and strike joints in the dense limestone and dolomite. Recharge beginning at topographic highs in the northwest moves across strike to lows in the southeast; it is intercepted and collected by high permeability beds in the middle of the Knox Group and is routed along strike to discharge at large springs. Exploratory wells were drilled at two sites to test this concept of the flow system. Three wells at Moore Spring site in the recharge area penetrated only mud and solid rock. Four wells at Riley Spring site in the discharge area each penetrated at least five water-bearing openings that gave these wells an average production of 93 gallons per minute and a maximum of 180 gallons per minute. (USGS)

Open-File Report↗

Tin

Tin (Sn) is one of the first metals to be used by humans. Almost without exception, tin is used as an alloy. Because of its hardening effect on copper, tin was used in bronze implements as early as 3500 B.C. The major uses of tin today are for cans and containers, construction materials, transportation materials, and solder. The predominant ore mineral of tin, by far, is cassiterite (SnO 2 ). In 2015, the world’s total estimated mine production of tin was 289,000 metric tons of contained tin. Total world reserves at the end of 2016 were estimated to be 4,700,000 metric tons. China held about 24 percent of the world’s tin reserves and accounted for 38 percent of the world’s 2015 production of tin. The proportion of scrap used in tin production is between 10 and 25 percent. Unlike many metals, tin recycling is relatively efficient, and the fraction of tin in discarded products that get recycled is greater than 50 percent. Only about 20 percent of the world’s identified tin resources occur as primary hydrothermal hard-rock veins, or lodes. These lodes contain predominantly high-temperature minerals and almost invariably occur in close association with silicic, peraluminous granites. About 80 percent of the world’s identified tin resources occur as unconsolidated secondary or placer deposits in riverbeds and valleys or on the sea floor. The largest concentration of both onshore and offshore placers is in the extensive tin belt of Southeast Asia, which stretches from China in the north, through Thailand, Burma (also referred to as Myanmar), and Malaysia, to the islands of Indonesia in the south. Furthermore, tin placers are almost always found closely allied to the granites from which they originate. Other countries with significant tin resources are Australia, Bolivia, and Brazil. Most hydrothermal tin deposits belong to what can be thought of as a superclass of porphyry-greisen deposits. The hydrothermal tin deposits are all characterized by a close spatial, temporal, and genetic association with highly differentiated, peraluminous porphyritic granite intrusions. The intrusions form pegmatites; disseminated ore; parallel or subparallel, greisen-bordered sheeted veins that either cross-cut the intrusion or are peripheral to it; skarns; and (or) limestone replacements that contain different amounts of cassiterite, molybdenite, and wolframite. The tectonic settings of tin-bearing granites are relatively well understood and of limited variety. Tin and tungsten deposits and their associated igneous rocks are found mainly in continental settings. Historically, prospecting for tin has been carried out by the time-honored methods of panning, drilling, trenching, and assaying. Geophysical and geochemical surveys have been employed to cover large areas more rapidly, isolating areas of possible tin deposits so that drilling can be more effective and less costly. Elemental concentrations and relationships of the lithophile elements, especially barium, lithium, niobium, potassium, rubidium, and zirconium, are the most reliable chemical indicators of ore-forming processes and tin-bearing potential. The average human diet includes an intake of about 10 milligrams per day of tin. Ingestion of tin in significantly greater amounts than 10 milligrams per day may lead to a stomach ache, anemia, and liver and kidney problems. Exposure to some organo-tin compounds can interfere with brain and nervous system function and, in severe cases, can cause death. Extended inhalation of tin oxide—an issue mainly for those people who work in the tin industry—results in a higher potential to develop stannosis, which is a mild disease of the lungs caused by the inhalation of tin-bearing dust. Inorganic tin is poorly absorbed by the body, and no evidence exists for the carcinogenicity of metallic tin and tin compounds in humans. Most placer tin deposits are mined by open pit and (or) dredging methods. Mining of alluvial placers in modern streambeds and riverbeds is likely to increase the amount of sediment delivered downstream. This, combined with potential diversion of rivers and streams, may negatively affect downstream ecosystems. Many of the placer deposits located in Burma, Indonesia, Malaysia, and Thailand are located offshore. Most offshore placer tin deposits are mined by dredging methods, which have the potential to negatively affect benthic, midwater, and pelagic ecosystems. In a congressionally mandated U.S. Department of Defense study of strategic minerals published in 2013, tin has the greatest shortfall amount (insufficient supply to meet demand) at \$416 million; this amount is more than twice that of antimony ($182 million), which is the strategic mineral with the next largest shortfall amount (U.S. Department of Defense, 2013). The United States imported 75 percent of its tin supply in 2015. During the period 2012–15, these imports were from, in descending order of amount imported, Peru, Indonesia, Malaysia, and Bolivia. A promising advancement concerning research into the origin of tin deposits is the recent development of a reliable method of analyzing tin isotopes in cassiterite. Although the mechanism of transport and deposition of tin is fairly well understood, the means by which tin is incorporated into the parent magma at the points of magma generation and ascent needs further investigation. Tin metallogenic provinces worldwide are well known. Consequently, any undiscovered tin deposits will likely be spatially close to known deposits or extensions of the same.

Professional Paper↗

Stratabound copper-silver deposits of the Mesoproterozoic Revett Formation, Montana and Idaho, with a section on databases and spatial-data files for the geology and mineral deposits of the Revett Formation

The western Montana copper belt in western Montana and northern Idaho contains several large stratabound copper-silver deposits in fine- to medium-grained quartzite beds of the Revett Formation of the Mesoproterozoic (1,470-1,401 Ma) Belt Supergroup. Production from the deposits at the Troy Mine and lesser production from the Snowstorm Mine has yielded 222,237 tons Cu and 1,657.4 tons Ag. Estimates of undeveloped resources, mostly from the world-class Rock Creek-Montanore deposits, as well as lesser amounts at the Troy Mine, total more than 2.9 million tons Cu and 2,600 tons Ag in 406 million tons of ore.The Rock Creek-Montanore and Troy deposits, which are currently the most significant undeveloped resources identified in the copper belt, are also among the largest stratabound copper-silver deposits in North America and contain about 15 percent of the copper in such deposits in North America. Worldwide, stratabound copper-silver deposits contain 23 percent of all copper resources and are the second-most important global source of the metal after porphyry copper deposits.The Revett Formation, which consists of subequal amounts of argillite, siltite, and quartzite, is informally divided into lower, middle, and upper members on the basis of the proportions of the dominant rock types. The unit thickness increases from north to south, from 1,700 ft near the Troy Mine, 55 mi north of Wallace, Idaho, to more than 5,300 ft at Wallace, Idaho, in the Coeur d'Alene Trough south of the Osburn Fault, a major right-lateral strike-slip fault.Mineral deposits in the Revett Formation occur mostly in the A-D beds of the lower member and in the middle quartzite of the upper member. The deposits are concentrated along a preore pyrite/hematite interface in relatively coarse grained, thick quartzite beds that acted as paleoaquifers for ore fluids. The deposits are characterized by mineral zones (alteration-mineral assemblages) that are a useful guide to the locations of mineral deposits. In particular, the gradational zone between the chalcopyrite-ankerite and pyrite-calcite zones is the site of most mineral deposits. Detailed information on the geology and mineral deposits of the Revett Formation is presented in the accompanying files that include (1) a tab-delimited text file providing details of the geologic and mineral-resource data for 57 Revett-subtype stratabound copper-silver deposits, occurrences, and prospects; (2) the stratigraphic records of 40 diamond-drill cores and 86 measured sections, totaling 150,752 ft of true thickness, which are provided in Excel spreadsheet and Adobe Portable Document Format files; and (3) spatial geologic data consisting of geologic maps of the Revett Formation, the subsurface locations of resources in Revett-subtype stratabound copper-silver deposits based on diamond-drill-core data, and the locations of diamond-drill holes and measured sections. The spatial data are contained in Arc/Info interchange files. Spatial information derived from these data includes the locations of mineral zones, a digital database showing untested exploration areas, and a digital database of permissive tracts for undiscovered mineral deposits.

Idaho, Montana↗

Uranium deposits in Fall River County, South Dakota

In 1951 uranium deposits contained carnotite were discovered in the southern Black Hills near Edgemont, Fall River County, S. Dak. Numerous carnotite deposits have since been found in sandstones in the Inyan Kara group of early Cretaceous age, and uranium-bearing material has been discovered in the Pennsylvania Minnelusa sandstone of Pennsylvanian age and the Deadwood formation of Cambrian age in the southern Black Hills. Ore has been produced only from the Inyan Kara group, mostly within an area of about 30 square miles along the southwest flank of the Black Hills uplift between Dewey and Hot Springs in Custer and Fall River Counties. In addition, occurrences of uranium in other parts of the Black Hills and the surrounding area are known or reported from sedimentary, igneous, and metamorphic rocks of pre-Cambrian to Tertiary age. The upper and lowermost formations of the Inyan Kara group - the Fall River and Lakota sandstones - contain the productive uranium deposits. These terrestrial formations are composed predominantly of massive sandstone lenses within units of thinly bedded sandstone and mudstone, but locally these formations contain abundant mudstone and thinly bedded sandstone. Massive sandstone lenses in the Lakota sandstone commonly overlap and truncate underlying lenses. The lenses are separated by thin units of thinly bedded sandstone and mudstone. Iron stain, carbonaceous material, thin seams of gypsum, ripple marks, concretions, and fossil roots are common in the mudstone and thinly bedded portions of these formations. Some high angle normal faults of small displacement are found in the area containing the largest number of uranium occurrences in the Inyan Kara group. Although no ore deposits seen were cut by faults, high-angle fractures parallel and at right angles to the faults contain carnotite for short distances. The productive uranium deposits are most common where the Fall River and Lakota sandstones locally contain a large proportion of mudstone and thinly bedded sandstone. Other deposits are in the massive sandstone lenses of the Lakota sandstone and in the thin units between the lenses. Although carnotite is the most conspicuous and important mineral in most deposits, corvusite is an important constituent of some deposits. Other uranium minerals in the deposits are tyuyamunite, rauvite, and autunite. Ore produced in 1952 from the Fall River and Lakota sandstones contained about 0.2 percent U 3 O 8 and 0.6 percent V 2 O 5 . In general, deposits in the Fall River and Lakota sandstones contain about the same percentage of U 3 O 8 , but the deposits in the Fall River sandstone appear to have a higher percentage of vanadium. The grade of individual deposits, however, is highly variable. Most deposits are small, but a few have yielded as much as a thousand tons of ore.

South Dakota↗

Conceptual framework and approach for conducting a geoenvironmental assessment of undiscovered uranium resources

This report presents a novel conceptual framework and approach for conducting a geologically based environmental assessment, or geoenvironmental assessment, of undiscovered uranium resources within an area likely to contain uranium deposits. The framework is based on a source-to-receptor model that prioritizes the most likely contaminant sources, contaminant pathways, and affected environmental media for three common uranium extraction methods—open pit or underground mining with milling and in situ recovery (ISR). Data on regional geology, hydrology, and climate, as well as historical uranium mining and milling records are used to estimate the probable amounts of waste rock, tailings, wastewater, surface land disturbance, and subsurface aquifer disturbance for likely mining methods. Constituents of concern that might take the form of leachates, dust, radon, and sediments formed by chemical and physical weathering are also identified in the geoenvironmental assessment. Finally, areas where constituents of concern are likely to occur and persist in air, land, surface water, and groundwater are indicated by the potential for dispersion of dust by wind, accumulation of radon because of air stagnation, dispersion of sediments and wastewater by runoff, and infiltration of wastewater or leachates with consideration of the likely mobility of contaminants in surface water and groundwater. The geoenvironmental assessment output can be summarized in the following primary products: (1) a descriptive geoenvironmental model; (2) maps and statistics of variables that indicate the potential for constituents of concern to occur and persist in air, land, surface water, and groundwater within a tract that is geologically permissive for the occurrence of uranium; and (3) tables providing estimated or indicated quantities of waste rock, tailings, wastewater, dust, and radon emissions that could be associated with undiscovered uranium resources, if extracted, for each permissive tract. The uranium geoenvironmental assessment could help natural resource managers to prioritize and (or) identify (1) important potential contaminant pathways, (2) management practices required depending on the types of constituents that could be of concern, (3) areas for response in the event of accidental release, and (4) future directions for study. Furthermore, indicators of rock and water volumes potentially associated with an undiscovered uranium deposit may be evaluated to make quantitative comparisons of water required for uranium production or potential waste products generated during uranium extraction from areas permissive for uranium resource occurrence throughout the United States.

Scientific Investigations Report↗

Geology and ore deposits of the Whitepine area, Tomichi mining district, Gunnison County, Colorado

The Tomichi mining district is on the western slope of the Continental Divide near the southern end of the Sawatch Range in southeastern Gunnison County, Colorado. The most productive part of the Tomichi district was the Whitepine area. It is estimated that since the discovery of ore in 1879 the area has produced approximately $7,000,000, principally in lead and zinc, with lesser amounts of silver, copper, and gold. Geologically, the Whitepine area is a faulted syncline of Paleozoic rocks that was intruded by Tertiary igneous rocks. The oldest rock of the area is the Silver Plume granite of pre-Cambrian age. Deposited upon this successively were the Sawatch quartzite (Late Cambrian), Manitou dolomite (Early Ordovician), Harding quartzite (Middle Ordovician), Fremont dolomite (Lade Ordovician), Chaffee formation (Late Devonian), Leadville limestone (Late Mississippian), and Beldon shale (Late Pennsylvanian); a total thickness of about 1,450 feet. During the Laramide Revolution, the sedimentary rocks were folded into a broad northward-plunging syncline, faulted, and intruded by a series of igneous rocks. The igneous rocks, in order of relative age from oldest to youngest, are: a rhyolite stock, the Princeton quartz monzonite batholith, quartz monzonite or quartz latite porphyry dikes, and rhyolite or pitchstone porphyry dikes. The ore deposits of the Whitepine area may be classified into replacement deposits, vein deposits, and contact metamorphic deposits. The replacement deposits may be further subdivided into deposits along faults and bedded deposits. Of the types of deposits, the most productive have been the replacement deposits along faults. The major replacement deposits along faults are those of the Akron, Morning Star, and Victor mines. The ore deposits of these mines are in the foot wall of the Star faults in the Akron mine in the Manitou dolomite and in the Morning Star and Victor mines in the Leadville limestone. The chief bedded replacement deposits are those of the Erie, North Star, and Tenderfoot mines. In the Erie mine the ore deposits are in the Leadville limestone at, or just below, its contact with the Belden shale. In the North Star and Tenderfoot mines the ore bodies are in the Manitou dolomite along the crest of an anticline and the trough of a syncline, respectively. The vein deposits occur in the Silver Plume granite, Princeton quartz monzonite, and Paleozoic sedimentary rocks. The only vein of commercial importance was that of the Spar Copper mine, which is in the Silver Plume granite. Contact metamorphic minerals are found chiefly in the top of the Leadville limestone in the vicinity of the Erie mine, and in the limestone of the Belden shale. Magnetite is the only ore mineral and it was produced only from the Iron King mine. The replacement deposits consist, in general, of sphalerite, galena, pyrite, and chalcopyrite in a gangue of siliclfied limestone or dolomite, quartz, and calcite. The veins, for the most part, consist of pyrite and quartz with only minor amounts of galena, sphalerite, and chalcopyrite. In both types of deposits gold is believed to be associated with the pyrite and sphalerite and silver with the galena. Oxidized ore was the chief product of the early mining. This ore consists of calamine, cerussite, smithsonite, or anglesite, or a combination of these minerals, in a gangue of siliceous limestone or silicified limestone or dolomite. Oxidation did not extend, in most cases, for more than 150 feetbelow the surface. The ore deposits are believed to be genetically related to the Princeton quartz monzonite batholith. Ore-bearing solutions derived from the cooling of magma are believed to have migrated upwards along the pre-existing faults replacing favorable zones in the sedimentary rocks, or depositing quartz and ore minerals in open fissures in the igneous rocks.

Open-File Report↗

Coal and petroleum resources in the Appalachian basin: index maps of included studies

This chapter B.1 of U.S. Geological Survey (USGS) Professional Paper 1708 provides index maps for many of the studies described in other chapters of the report. Scientists of the USGS and State geological surveys studied coal and petroleum resources in the central and southern Appalachian structural basins. In the southern Appalachian basin, studies focused on the coal-bearing parts of the Black Warrior basin in Alabama. The scientists used new and existing geologic data sets to create a common spatial geologic framework for the fossil-fuel-bearing strata of the central Appalachian basin and the Black Warrior basin in Alabama. Digital data have been compiled into a geographic information system (GIS) that is included in chapter I.1 (Trippi and others, this volume). Shape files and related metadata for features shown in the index maps of this chapter can be downloaded from chapter I.1. The study area for the Appalachian basin resource framework study includes the fossil-fuel-bearing strata of the following States (listed alphabetically): Alabama, Kentucky, Maryland, New York, Ohio, Pennsylvania, Tennessee, Virginia, and West Virginia. The outline of the study area is shown in figure 1; it differs from the boundary of the Appalachian Basin Province (Province 67) defined for the 1995 National Oil and Gas Assessment (NOGA) by the U.S. Geological Survey (1996a). The difference is that the study area includes regions where the Pennsylvanian coal-bearing strata crop out but does not include all of the oil- and gas-bearing strata of the Black Warrior basin, Alabama. The reasons for providing the index maps in this chapter are to show the locations of different studies, to give an overview of topics covered, and to help the user choose which chapter to read. Figures 1 and 2 show the study area outline and county names. Figure 3 shows oil and gas production in 1995 and 2005. Figure 4 shows locations of Upper Devonian sandstone oil and gas fields. Figure 5 shows major coal regions and coal fields. Figure 6 shows coal production by county. Figure 7 shows the locations of 10 cross sections of regional extent through the subsurface of the Appalachian basin. Figure 8 shows conodont alteration index sample locations and interpreted isograds for Ordovician rocks. Figure 9 shows vitrinite-reflectance data for Pennsylvanian coal in the Appalachian basin. Figure 10 shows the locations of coalbed-methane (CBM) assessment units in the study area, and figure 12 shows counties producing CBM. Figure 12 shows sulfur content of coal delivered to powerplants from coal-producing counties in the Appalachian basin and Black Warrior basin. Figure 13 shows locations of wells in Ohio and Pennsylvania where oil and gas were sampled in Lower Silurian reservoirs. Figure 14 shows the Conasauga-Rome/Conasauga Total Petroleum System and selected wells in the Rome trough in Kentucky and West Virginia having oil and gas production and shows. Figure 15 shows the locations of samples from Silurian reservoirs in Kentucky, New York, Ohio, Pennsylvania, and West Virginia; the samples yielded total organic carbon data. Figure 16 shows the locations of the Ben Hur and Rose Hill oil fields, Virginia, and the Swan Creek oil field, Tennessee. The one index map that is not shown is the areal extent of the shale gas plays in the basin. The extents of the plays can be found in Coleman and others (this volume, chap. G.13).

Appalachian basin↗

Secular trends in the geologic record and the supercontinent cycle

Geologic secular trends are used to refine the timetable of supercontinent assembly, tenure, and breakup. The analysis rests on what is meant by the term supercontinent, which here is defined broadly as a grouping of formerly dispersed continents. To avoid the artificial pitfall of an all-or-nothing definition, quantitative measures of “supercontinentality” are presented: the number of continents, and the area of the largest continent, which both can be gleaned from global paleogeographic maps for the Phanerozoic. For the secular trends approach to be viable in the deep past when the very existence of supercontinents is debatable and reconstructions are fraught with problems, it must first be calibrated in the Phanerozoic against the well-constrained Pangea supercontinent cycle. The most informative geologic variables covering both the Phanerozoic and Precambrian are the abundances of passive margins and of detrital zircons. Both fluctuated with size of the largest continent during the Pangea supercontinent cycle and can be quantified back to the Neoarchean. The tenure of Pangea was a time represented in the rock record by few zircons and few passive margins. Thus, previously documented minima in the abundance of detrital zircons (and orogenic granites) during the Precambrian (Condie et al., 2009a, Gondwana Research 15, 228–242) now can be more confidently interpreted as marking the tenures of supercontinents. The occurrences of carbonatites, granulites, eclogites, and greenstone-belt deformation events also appear to bear the imprint of Precambrian supercontinent cyclicity. Together, these secular records are consistent with the following scenario. The Neoarchean continental assemblies of Superia and Sclavia broke up at ca. 2300 and ca. 2090 Ma, respectively. Some of their fragments collided to form Nuna by about 1750 Ma; Nuna then grew by lateral accretion of juvenile arcs during the Mesoproterozoic, and was involved in a series of collisions at ca. 1000 Ma to form Rodinia. Rodinia broke up in stages from ca. 1000 to ca. 520 Ma. Before Rodinia had completely come apart, some of its pieces had already been reassembled in a new configuration, Gondwana, which was completed by 530 Ma. Gondwana later collided with Laurentia, Baltica, and Siberia to form Pangea by about 300 Ma. Breakup of Pangea began at about 180 Ma (Early Jurassic) and continues today. In the suggested scenario, no supercontinent cycle in Earth history corresponded to the ideal, in which all the continents were gathered together, then broke apart, then reassembled in a new configuration. Nuna and Gondwana ended their tenures not by breakup but by collision and name change; Rodinia's assembly overlapped in time with its disassembly; and Pangea spalled Tethyan microcontinents throughout much of its tenure. Many other secular trends show a weak or uneven imprint of the supercontinent cycle, no imprint at all. Instead, these secular trends together reveal aspects of the shifting background against which the supercontinents came and went, making each cycle unique. Global heat production declined; plate tectonics sped up through the Proterozoic and slowed down through the Phanerozoic; the atmosphere and oceans became oxidized; life emerged as a major geochemical agent; some rock types went extinct or nearly so (BIF, massif-type anorthosite, komatiite); and other rock types came into existence or became common (blueschists, bioclastic limestone, coal).

Earth-Science Reviews↗

'Snake River (SR)-type' volcanism at the Yellowstone hotspot track: Distinctive products from unusual, high-temperature silicic super-eruptions

A new category of large-scale volcanism, here termed Snake River (SR)-type volcanism, is defined with reference to a distinctive volcanic facies association displayed by Miocene rocks in the central Snake River Plain area of southern Idaho and northern Nevada, USA. The facies association contrasts with those typical of silicic volcanism elsewhere and records unusual, voluminous and particularly environmentally devastating styles of eruption that remain poorly understood. It includes: (1) large-volume, lithic-poor rhyolitic ignimbrites with scarce pumice lapilli; (2) extensive, parallel-laminated, medium to coarse-grained ashfall deposits with large cuspate shards, crystals and a paucity of pumice lapilli; many are fused to black vitrophyre; (3) unusually extensive, large-volume rhyolite lavas; (4) unusually intense welding, rheomorphism, and widespread development of lava-like facies in the ignimbrites; (5) extensive, fines-rich ash deposits with abundant ash aggregates (pellets and accretionary lapilli); (6) the ashfall layers and ignimbrites contain abundant clasts of dense obsidian and vitrophyre; (7) a bimodal association between the rhyolitic rocks and numerous, coalescing low-profile basalt lava shields; and (8) widespread evidence of emplacement in lacustrine-alluvial environments, as revealed by intercalated lake sediments, ignimbrite peperites, rhyolitic and basaltic hyaloclastites, basalt pillow-lava deltas, rhyolitic and basaltic phreatomagmatic tuffs, alluvial sands and palaeosols. Many rhyolitic eruptions were high mass-flux, large volume and explosive (VEI 6-8), and involved H2O-poor, low-??18O, metaluminous rhyolite magmas with unusually low viscosities, partly due to high magmatic temperatures (900-1,050??C). SR-type volcanism contrasts with silicic volcanism at many other volcanic fields, where the fall deposits are typically Plinian with pumice lapilli, the ignimbrites are low to medium grade (non-welded to eutaxitic) with abundant pumice lapilli or fiamme, and the rhyolite extrusions are small volume silicic domes and coule??es. SR-type volcanism seems to have occurred at numerous times in Earth history, because elements of the facies association occur within some other volcanic fields, including Trans-Pecos Texas, Etendeka-Paran, Lebombo, the English Lake District, the Proterozoic Keewanawan volcanics of Minnesota and the Yardea Dacite of Australia. ?? Springer-Verlag 2007.

Bulletin of Volcanology↗

Advances in carbonate exploration and reservoir analysis

The development of innovative techniques and concepts, and the emergence of new plays in carbonate rocks are creating a resurgence of oil and gas discoveries worldwide. The maturity of a basin and the application of exploration concepts have a fundamental influence on exploration strategies. Exploration success often occurs in underexplored basins by applying existing established geological concepts. This approach is commonly undertaken when new basins ‘open up’ owing to previous political upheavals. The strategy of using new techniques in a proven mature area is particularly appropriate when dealing with unconventional resources (heavy oil, bitumen, stranded gas), while the application of new play concepts (such as lacustrine carbonates) to new areas (i.e. ultra-deep South Atlantic basins) epitomizes frontier exploration. Many low-matrix-porosity hydrocarbon reservoirs are productive because permeability is controlled by fractures and faults. Understanding basic fracture properties is critical in reducing geological risk and therefore reducing well costs and increasing well recovery. The advent of resource plays in carbonate rocks, and the long-standing recognition of naturally fractured carbonate reservoirs means that new fracture and fault analysis and prediction techniques and concepts are essential.

Geological Society Special Publication↗

Ophiolite and volcanic arc assemblages on the Vizcaino Peninsula and Cedros Island region, Baja California Sur, Mexico: Mesozoic forearc lithosphere of the Cordilleran magmatic arc

Mesozoic ophiolites in the Vizcaíno Peninsula and Cedros Island region of Baja California Sur are suprasubduction zone Cordilleran-type ophiolites structurally juxtaposed with underlying high pressure-temperature subduction complex assemblages. The region is divided into three separate tectonostratigraphic terranes, but here we recognize stratigraphic, intrusive, and petrologie links between these terranes and interpret the evolution of the entire region within the same Late Triassic to Early Cretaceous tectonic framework. Several phases of extension are recognized, including two major phases that resulted in development of distinct ophiolite assemblages. The Late Triassic Vizcaine Peninsula Ophiolite (221 ± 2 Ma) represents the earliest stage of this history and comprises a complete spreading center sequence with depleted upper mantle and mafie crustal rocks, including sheeted dike complex, Jurassic are magmatic rocks with low-Ti are tholelite and boninite geochemical affinities were intruded through and constructed on the Triassic ophiolite basement. Ultra-depleted are-ankaramites on Cedros Island may represent an initial phase of are rifting that was followed by major Middle Jurassic extension and production of the Cedros Island Ophiolite (173 ± 2 Ma). The Late Jurassic-Early Cretaceous Coloradito and Eugenia Formations contain mudflows and olistostrome blocks intercalated with are volcanogenic sediment and rift-related pillow lavas; these units record extension and/or transtension and provide the earliest definite evidence of are-continent interaction in the region. Middle Jurassic to Early Cretaceous are plutonic rocks (ca. 165-135 Ma) were shallowly intruded into low greenschist-facies ophiolite and are volcanic basement. Plutonic rocks range in composition from gabbro to granodiorite, but tonalite dominates. These intrusions are typical I-type Cordilleran batholithic rocks with relatively primitive are geochemical affinities (initial Sr 87 / 86 Sr range from ~0.704 to 0.706), but they are distinctly calcic in nature, a feature common to the adjacent Cretaceous Peninsular Ranges batholith. The Vizca í no-Cedros region correlates to ophiolitic terranes of the western Sierra Klamath belt and Coast Ranges of California and Oregon that were constructed in part across the North American margin. Age, stratigraphic, and petrochemical data from the Vizca í no-Cedros region support previously proposed forearc rifting models developed for the U.S. sector of the Cordilleran orogen that interpret the ophiolite assemblages as autochthonous or parautochthonous forearc lithosphere constructed outboard of the Mesozoic continental margin arc.

GSA Special Papers↗

Molecular and isotopic analyses of the hydrocarbon gases within gas hydrate-bearing rock units of the Prudhoe Bay-Kuparuk River area in northern Alaska

Gas hydrates, which are crystalline substances of water molecules that encase gas molecules, have the potential for being a significant source of natural gas. World-wide estimates for the amount of gas contained in hydrates range from 1.1 x 105 to 2.7 x 108 trillion cubic feet. Gas hydrates exist in many Arctic regions, including the North Slope of Alaska. The two primary objectives of the U.S. Geological Survey Gas Hydrate Research Project are (1) to map the distribution of in-situ gas hydrates on the North Slope of Alaska, and (2) to evaluate the geologic parameters that control the distribution of these gas hydrates. To aid in this study, British Petroleum Exploration, ARCO Alaska, Exxon Company USA, and the Continental Oil Company allowed the U.S. Geological Survey to collect geochemical samples from drilling North Slope production wells. Molecular analysis of gaseous drill cutting and free-flowing gas samples from 10 production wells drilled in the Prudhoe Bay, Kuparuk River, and Milne Point oil fields indicates that methane is the primary hydrocarbon gas in the gas hydrate-bearing stratigraphic units. Isotopic data for several of these rock units indicate that the methane within the inferred gas hydrate occurences originated from both microbial and thermogenic processes.

Open-File Report↗

Copahue volcano and its regional magmatic setting

Copahue volcano (Province of Neuquen, Argentina) has produced lavas and strombolian deposits over several 100,000s of years, building a rounded volcano with a 3 km elevation. The products are mainly basaltic andesites, with the 2000–2012 eruptive products the most mafic. The geochemistry of Copahue products is compared with those of the main Andes arc (Llaima, Callaqui, Tolhuaca), the older Caviahue volcano directly east of Copahue, and the back arc volcanics of the Loncopue graben. The Caviahue rocks resemble the main Andes arc suite, whereas the Copahue rocks are characterized by lower Fe and Ti contents and higher incompatible element concentrations. The rocks have negative Nb-Ta anomalies, modest enrichments in radiogenic Sr and Pb isotope ratios and slightly depleted Nd isotope ratios. The combined trace element and isotopic data indicate that Copahue magmas formed in a relatively dry mantle environment, with melting of a subducted sediment residue. The back arc basalts show a wide variation in isotopic composition, have similar water contents as the Copahue magmas and show evidence for a subducted sedimentary component in their source regions. The low 206 Pb/ 204 Pb of some backarc lava flows suggests the presence of a second endmember with an EM1 flavor in its source. The overall magma genesis is explained within the context of a subducted slab with sediment that gradually looses water, water-mobile elements, and then switches to sediment melt extracts deeper down in the subduction zone. With the change in element extraction mechanism with depth comes a depletion and fractionation of the subducted complex that is reflected in the isotope and trace element signatures of the products from the main arc to Copahue to the back arc basalts.

Copahue volcano↗

Major brazilian gold deposits - 1982 to 1999

Brazil has been a major but intermittent producer of gold since its discovery in 1500. Brazil led the world in gold production during the 18th and early 19th centuries. From the late 19th century to the late 20th century, total mining company and garimpeiro production was small and relatively constant at about 5 to 8 t/year. The discovery of alluvial deposits in the Amazon by garimpeiros in the 1970s and the opening of eight mines by mining companies from 1983 to 1990 fueled a major boom in Brazil's gold production, exceeding 100 t/year in 1988 and 1989. However, garimpeiro alluvial production decreased 'rapidly in the 1990s, to about 10 t/year by 1999. Company production increased about tenfold from about 4 t/year in 1982 to 40 t in 1992. Production from 1992 to the present remained relatively stable, even though several mines were closed or were in the process of closing and no new major mines were put into production during that period. Based on their production history from 1982-1999, 17 gold mines are ranked as major (> 20 t) and minor (3-8 t) mines. From 1982-1999, deposits hosted in Archean rocks produced 66% of the gold in Brazil, whereas deposits in Paleoproterozoic and Neoproterozoic rocks accounted for 19% and 15%, respectively. Deposits in metamorphosed sedimentary rocks, especially carbonate-rich rocks and carbonate iron-formation, yielded the great bulk of the gold. Deposits in igneous rocks were of much less importance. The Archean and Paleoproterozoic terranes of Brazil largely lack base-metal-rich volcanogenic massive sulfide deposits, porphyry deposits, and polymetallic veins and sedimentary exhalative deposits. An exception to this is in the Caraja??s Mineral Province.

Mineralium Deposita↗

When oil and water mix: Understanding the environmental impacts of shale development

Development of shale gas and tight oil, or unconventional oil and gas (UOG), has dramatically increased domestic energy production in the U.S. UOG resources are typically developed through the use of hydraulic fracturing, which creates high-permeability flow paths into large volumes of tight rocks to provide a means for hydrocarbons to move to a wellbore. This process uses significant volumes of water, sand, and chemicals, raising concerns about risks to the environment and to human health. Researchers in various disciplines have been working to make UOG development more efficient, and to better understand the risks to air quality, water quality, landscapes, human health, and ecosystems. Risks to air include releases of methane, carbon dioxide, volatile organic compounds, and particulate matter. Water-resource risks include excessive withdrawals, stray gas in drinking-water aquifers, and surface spills of fluids or chemicals. Landscapes can be significantly altered by the infrastructure installed to support large drilling platforms and associated equipment. Exposure routes, fate and transport, and toxicology of chemicals used in the hydraulic fracturing process are poorly understood, as are the potential effects on terrestrial and aquatic ecosystems and human health. This is made all the more difficult by an adaptable and evolving industry that frequently changes methods and constantly introduces new chemicals. Geoscientists responding to questions about the risks of UOG should refer to recent, rigorous scientific research.

GSA Today↗

Coal resources of the United States, A progress report, November 1, 1950

Interest in the quantity and quality of the coal reserves of the United States has increased greatly since the end of World War II, principally because of the growing realization that the ultimate reserves of petroleum and natural gas, although largely undefined, still. have finite limits. With the greatly increased use of petroleum and natural gas, it has become further apparent that the reserves of these two fuels, whatever their ultimate limits may prove to be, are being consumed at a rate far surpassing that anticipated a few years ago. At some time in the future, therefore, the contribution of coal to the total production of energy in this country must inevitably be enlarged to include some of the needs now served by petroleum and natural gas. Although coal-bearing rocks cover 14 percent of the total area of the United States (fig. 1) and contain enormous reserves, it is equally apparent that reserves of coal also have limits. In the extensively mined sections in the East it is already increasingly difficult to locate new areas containing thick beds of high-rank and high-quality coal to replace areas that have been mined out. Furthermore, a considerable part of the total reserves of the United States consists of coal of lignite and subbituminous ranks and coal contained in thin beds that can be mined only with great difficulty and expense. At the present time, therefore, the depletion of reserves of high-rank and high-quality coal, particularly the Eastern coal that is suitable for the manufacture of metallurgical coke, is a more serious problem than the percentage depletion of the total coal reserves. Recognizing the need for more detailed estimates of coal reserves than those that have been available in the past, the U. S. Geological Survey is now preparing a reappraisal of the coal reserves of the United States in which primary emphasis is placed on the amounts of coal in separate categories according to rank,thickness of coal, and thickness of overburden. Many of the state geological surveys in coal-producing areas are also preparing new appraisals of coal reserves. The increasing volume of geologic data available on the occurrence of coal and the detailed and careful methods now employed in calculating reserves should ultimately provide a more reliable estimate for the coal reserves of the United States than has been obtainable previously, although much additional work remains to be done.

Circular↗

Genetic diversity and population structure in the threatened Oregon silverspot butterfly ( Speyeria zerene hippolyta ) in western Oregon and northwestern California— Implications for future translocations and the establishment of new populations

Executive Summary We present results of population genetic analyses performed on Oregon silverspot butterflies (OSB; Speyeria zerene hippolyta ) in western Oregon and northwestern California. We used DNA sequences from a 561-base pair region of the mitochondrial cytochrome oxidase subunit I (COI) gene for a dataset comprised of 112 S. z. hippolyta and 32 S. z. gloriosa individuals collected at 9 locations in western Oregon and northwestern California. The most pertinent findings thus far are summarized as follows: Among OSB populations, genetic diversity is lowest at Mount Hebo and highest at Rock Creek and Bray Point. Of the 32 haplotypes detected in OSB, only 2 were shared among populations (1 shared by Mount Hebo, Cascade Head, Bray Point, and Rock Creek, and 1 shared by Rock Creek and Lake Earl). The remaining 30 haplotypes were identified in individual populations, highlighting the strong differentiation among sites. It is unclear if the shared haplotypes represent widespread, naturally occurring genetic variation or if allele sharing among populations is due to translocation history. Using full siblings of individuals that were released at Rock Creek and Bray Point in 2012 as comparison standards, the analyses suggest that 54 percent of the sampled individuals from Bray Point were naturally recruited into the population and were not originating from the 2012 release of captive reared individuals. Likewise, 33 percent of the analyzed individuals from Rock Creek were naturally recruited. Both of these estimates may be underestimates if the shared alleles that we identified among populations are naturally occurring and not a product of the 2012 translocations. The results suggest that there are about 12–13 COI haplotypes in the Mount Hebo population. The U.S. Fish and Wildlife Service anticipates using Mount Hebo as the source of individuals when establishing new populations in the future. Nonlinear regression models based on a series of rarefaction analyses suggest that progeny from 12, 37, 109, and 326 female individuals would be required to respectively capture 25, 50, 75, and 90 percent of the allelic diversity from Mount Hebo. Phylogenetic analyses identified two different haplotype groups, but the two groups did not correspond to the different subspecies used in the analysis. One group included 22 S. z. hippolyta haplotypes and 7 haplotypes identified in S. z. gloriosa . The second group included eight haplotypes from S. z. hippolyta, three haplotypes from S. z. gloriosa , and one haplotype that was detected in both subspecies.

California, Oregon↗

Compilation of geologic, hydrologic, and ground-water flow modeling information for the Spokane Valley-Rathdrum Prairie aquifer, Spokane County, Washington, and Bonner and Kootenai Counties, Idaho

The U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources and Washington Department of Ecology compiled and described geologic, hydrologic, and ground-water flow modeling information about the Spokane Valley-Rathdrum Prairie (SVRP) aquifer in northern Idaho and northeastern Washington. Descriptions of the hydrogeologic framework, water-budget components, ground- and surface-water interactions, computer flow models, and further data needs are provided. The SVRP aquifer, which covers about 370 square miles including the Rathdrum Prairie, Idaho and the Spokane valley and Hillyard Trough, Washington, was designated a Sole Source Aquifer by the U.S. Environmental Protection Agency in 1978. Continued growth, water management issues, and potential effects on water availability and water quality in the aquifer and in the Spokane and Little Spokane Rivers have illustrated the need to better understand and manage the region's water resources. The SVRP aquifer is composed of sand, gravel, cobbles, and boulders primarily deposited by a series of catastrophic glacial outburst floods from ancient Glacial Lake Missoula. The material deposited in this high-energy environment is coarser-grained than is typical for most basin-fill deposits, resulting in an unusually productive aquifer with well yields as high as 40,000 gallons per minute. In most places, the aquifer is bounded laterally by bedrock composed of granite, metasedimentary rocks, or basalt. The lower boundary of the aquifer is largely unknown except along the margins or in shallower parts of the aquifer where wells have penetrated its entire thickness and reached bedrock or silt and clay deposits. Based on surface geophysics, the thickness of the aquifer is about 500 ft near the Washington-Idaho state line, but more than 600 feet within the Rathdrum Prairie and more than 700 feet in the Hillyard trough based on drilling records. Depth to water in the aquifer is greatest in the northern Rathdrum Prairie (about 500 feet) and least near the city of Spokane along the Spokane River (less than about 50 feet). Ground-water flow is south from near the southern end of Lake Pend Oreille and Hoodoo Valley, through the Rathdrum Prairie, then west toward Spokane. In Spokane, the aquifer splits and water moves north through the Hillyard Trough as well as west through the Trinity Trough. From the Trinity Trough water flows north along the western arm of the aquifer. The aquifer's discharge area is along the Little Spokane River and near Long Lake, Washington. A compilation of estimates of water-budget components, including recharge (precipitation, irrigation, canal leakage, septic tank effluent, inflow from tributary basins, and flow from the Spokane River) and discharge (withdrawals from wells, flow to the Spokane and Little Spokane Rivers, evapotranspiration, and underflow to Long Lake) illustrates that these estimated values should be compared with caution due to several variables including the area and time period of interest as well as methods employed in making the estimates. Numerous studies have documented the dynamic ground-water and surface-water interaction between the SVRP aquifer and the Spokane and Little Spokane Rivers. Gains and losses vary throughout the year, as well as the locations of gains and losses. September 2004 streamflow measurements indicated that the upper reach of the Spokane River between Post Falls and downstream at Flora Road lost 321 cubic feet per second. A gain of 736 cubic feet per second was measured between the Flora Road site and downstream at Green Street Bridge. A loss of 124 cubic feet per second was measured for the reach between the Green Street Bridge and the Spokane River at Spokane gaging station. The river gained about 87 cubic feet per second between the Spokane River at Spokane gaging station and the TJ Meenach Bridge. Overall, the Spokane River gained about 284 cubic feet per second between the Post Falls,

Scientific Investigations Report↗