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USGS1985

Crystalline gold in soil and the problem of supergene nugget formation: Freezing and exclusion as genetic mechanisms

Many of the world's richest gold placer deposits now occur in cold regions despite differences in their climatic history. It therefore seems possible that there may be some fundamental connection between freezing climates and the local chemical behavior of gold in the weathering cycle. This hypothesis, along with the problematical occurrence of gold as euhedral crystals in arctic gravel and soil placers, has led me to review low temperature phenomena that may bear on the geochemistry of gold. Several effects which may influence the weathering of natural gold-bearing rocks, the chemical complexation of gold, and its subsequent mobility and deposition appear to be strongly connected with freeze action. The exclusion of dissolved solutes, solute gases, and particles from ice, subjects rock and soil minerals to increased corrosion from thin, unfrozen, adsorbed water films which remain at particle surfaces throughout the freezing of rocks and soils. The preferential exclusion of cations (over anions) from growing ice crystals creates charge separations and measurable current flow across waterice phase boundaries in freezing soil — a phenomenon which leads to troublesome seasonal electrolytic corrosion of pipelines buried in soil; this phenomenon may also favor the dissolution of normally insoluble metals such as gold during geologic time periods. The ice-induced accumulation of clays, organic acids, bacteria, and other organic matter at mineral surfaces may also speed chemical attack by providing a nearby sink of alternate cation-binding sites and hence rapid removal of liberated cations from solution. The latter mechanism may be operative in both the dissolution and redeposition of gold. These physical, chemical, and electrical effects are favorable to the dissolution of rocks (in addition to frost shattering) and to the dissolution, mobilization, and redeposition of gold and other noble metals and must therefore contribute significantly to the behavior of gold at low temperatures. The occurrence of large numbers of gold placer deposits in northern Canada, Alaska, and Siberia may thus be due in part to the low temperatures common to these regions.

Precambrian Research↗

USGS2007

Type region of the Ione Formation (Eocene), central California: Stratigraphy, paleogeography, and relation to auriferous gravels

The middle Eocene Ione Formation extends over 200 miles (320 km) along the western edge of the Sierra Nevada. Our study was concentrated in the type region, 30 miles (48 km) along strike. There a bedrock ridge forms the seaward western side of the Ione depositional tract, defining a subbasin margin. The eastern limit of the type Ione is locally defined by high-angle faults. Ione sediments were spread over Upper Mesozoic metamorphic and plutonic bedrock, fed by gold-bearing streams dissecting the western slope of the ancestral Sierra Nevada. By middle Eocene time, a tropical or subtropical climate prevailed, leading to deep chemical weathering (including laterization) and a distinctively mature mineral assemblage was fed to and generated within Ione deposits. The Ione is noted for its abundant kaolinitic clay, some of it coarsely crystalline; the clay is present as both detrital grains and authigenic cement. Quartz is abundant, mostly as angular grains. Heavy mineral fractions are dominated by altered ilmenite and zircon. Distribution of feldspar is irregular, both stratigraphically and areally. Non-marine facies are most voluminous, and include conglomerates, especially at the base and along the eastern margins of the formation where they pass into Sierran auriferous gravels. Clays, grading into lignites, and gritty sands are also common facies. Both braided and meandering fluvial facies have been recognized. Shallow marine waters flooded the basin probably twice. Tongues of sediment exhibiting a variety of estuarine to marine indicators are underlain and overlain by fluvial deposits. Marine body fossils are found at only a few localities, but burrows identified as Ophiomorpha and cf. Thalassinoides are abundant in many places. Other clues to marginal marine deposition are the occurrence of glauconite in one bed, typical relations of lagoonal to beach (locally heavy-mineral-rich) lithofacies, closed-basin three-dimensional morphology of basinal facies, and high sulfur content of some marginal coals. The Ione has been said to be deltaic; however the two transgressional-regressional cycles we propose imply that only the regressional parts were deltaic. At other times, much of the type Ione would better be termed an intertidal estuary. Because the lower marine sequence was deposited against a paleobasin margin on the west, deltaic morphology was constrained, but apparently progradation was from north to south despite drainage into the basin from the east. Relations to the south are unclear due to the Stockton arch. The eastern margin of the type-Ione basin, and to some extent even its marine facies, are poorly constrained. A surface on Sierran bedrock to the east may have been stripped of some Ione basinal facies, leaving only coeval entrenched fluvial channel deposits.

California↗

USGS1991

Maps showing industrial mineral resources of the Joplin 1° x 2° quadrangle, Kansas and Missouri

This map is part of a folio of maps of the Joplin 1° X 2° quadrangle, Kansas and Missouri prepared under the Conterminuous United States Mineral Assessment Program (CUSMAP). Other publications in this folio to date include U.S. Geological Survey Miscellaneous Field Studies Map MF-2125-A (Erickson and others, 1990). Additional maps showing various geologic aspects of the Joplin quadrangle will be published as U.S. Geological Survey Miscellaneous Field Studies Maps bearing this same serial number with different letter suffixes (MF-2125-C, -D, and so on). The industrial mineral resources of the Joplin 1° X 2° quadrangle are crushed stone, dimension stone, clay and shale, construction sand and gravel (including chat, or chert-rich tailings from metal mines), and asphaltic sandstone. At present only crushed stone, clay and shale, and construction sand and gravel are of economic importance; the remainder are considered hypothetical resources. The value of industrial mineral production during 1987, the most recent year of complete data as supplied by the U.S. Bureau of Mines, was nearly $25,600,000. In terms of finished products such as cement and brick, the value is several times that amount. Figure 1 shows the annual value of industrial mineral production within the quadrangle from 1960 through 1987.

Kansas;Missouri↗

USGS2014

Local-area-enhanced, 2.5-meter resolution natural-color and color-infrared satellite-image mosaics of the Ghazni1 mineral district in Afghanistan

The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Defense Task Force for Business and Stability Operations, prepared databases for mineral-resource target areas in Afghanistan. The purpose of the databases is to (1) provide useful data to ground-survey crews for use in performing detailed assessments of the areas and (2) provide useful information to private investors who are considering investment in a particular area for development of its natural resources. The set of satellite-image mosaics provided in this Data Series (DS) is one such database. Although airborne digital color-infrared imagery was acquired for parts of Afghanistan in 2006, the image data have radiometric variations that preclude their use in creating a consistent image mosaic for geologic analysis. Consequently, image mosaics were created using ALOS (Advanced Land Observation Satellite; renamed Daichi) satellite images, whose radiometry has been well determined (Saunier, 2007a,b). This part of the DS consists of the locally enhanced ALOS image mosaics for the Ghazni1 mineral district, which has spectral reflectance anomalies indicative of clay, aluminum, gold, silver, mercury, and sulfur deposits. ALOS was launched on January 24, 2006, and provides multispectral images from the AVNIR (Advanced Visible and Near-Infrared Radiometer) sensor in blue (420-500 nanometer, nm), green (520-600 nm), red (610-690 nm), and near-infrared (760-890 nm) wavelength bands with an 8-bit dynamic range and a 10-meter (m) ground resolution. The satellite also provides a panchromatic band image from the PRISM (Panchromatic Remote-sensing Instrument for Stereo Mapping) sensor (520-770 nm) with the same dynamic range but a 2.5-m ground resolution. The image products in this DS incorporate copyrighted data provided by the Japan Aerospace Exploration Agency ((c)JAXA, 2008, 2009), but the image processing has altered the original pixel structure and all image values of the JAXA ALOS data, such that original image values cannot be recreated from this DS. As such, the DS products match JAXA criteria for value added products, which are not copyrighted, according to the ALOS end-user license agreement. The selection criteria for the satellite imagery used in our mosaics were images having (1) the highest solar-elevation angles (near summer solstice) and (2) the least cloud, cloud-shadow, and snow cover. The multispectral and panchromatic data were orthorectified with ALOS satellite ephemeris data, a process which is not as accurate as orthorectification using digital elevation models (DEMs); however, the ALOS processing center did not have a precise DEM. As a result, the multispectral and panchromatic image pairs were generally not well registered to the surface and not coregistered well enough to perform resolution enhancement on the multispectral data. Therefore, it was necessary to (1) register the 10-m AVNIR multispectral imagery to a well-controlled Landsat image base, (2) mosaic the individual multispectral images into a single image of the entire area of interest, (3) register each panchromatic image to the registered multispectral image base, and (4) mosaic the individual panchromatic images into a single image of the entire area of interest. The two image-registration steps were facilitated using an automated control-point algorithm developed by the USGS that allows image coregistration to within one picture element. Before rectification, the multispectral and panchromatic images were converted to radiance values and then to relative-reflectance values using the methods described in Davis (2006). Mosaicking the multispectral or panchromatic images started with the image with the highest sun-elevation angle and the least atmospheric scattering, which was treated as the standard image. The band-reflectance values of all other multispectral or panchromatic images within the area were sequentially adjusted to that of the standard image by determining band-reflectance correspondence between overlapping images using linear least-squares analysis. The resolution of the multispectral image mosaic was then increased to that of the panchromatic image mosaic using the SPARKLE logic, which is described in Davis (2006). Each of the four-band images within the resolution-enhanced image mosaic was individually subjected to a local-area histogram stretch algorithm (described in Davis, 2007), which stretches each band's picture element based on the digital values of all picture elements within a 500-m radius. The final databases, which are provided in this DS, are three-band, color-composite images of the local-area-enhanced, natural-color data (the blue, green, and red wavelength bands) and color-infrared data (the green, red, and near-infrared wavelength bands). All image data were initially projected and maintained in Universal Transverse Mercator (UTM) map projection using the target area's local zone (42 for Ghazni1) and the WGS84 datum. The images for the Ghazni1 area are provided as embedded geotiff images, which can be read and used by most geographic information system (GIS) and image-processing software. The tiff world files (tfw) are provided, even though they are generally not needed for most software to read an embedded geotiff image.

Ghazni1 Mineral District↗

USGS1985

Hydrogeologic appraisal of five selected aquifers in Erie County, New York

Hydrogeologic conditions and water quality at four stratified-drift aquifers and a bedrock (Onondaga Limestone) aquifer were investigated by the U.S. Geological Survey in cooperation with the Erie County Department of Environment and Planning. The Clarence-Lancaster-Newstead area includes two aquifers--one is a complex of morainal, beach, and outwash sand and gravel; the second is the underlying production aquifer in Onondage Limestone. Most wells tap the limestone aquifer. Water quality is suitable for most uses in both aquifers except for road-salt contamination at shallow wells near the New York State Thruway. A landfill on the aquifer has affected the water quality in some areas along its perimeter. The Sardinia and Springville areas each include an aquifer consisting of surficial outwash sand and gravel ranging in thickness from less than 10 feet to 95 feet. Several deeper water-bearing zones occur within till and lacustrine deposits 400 to 600 feet thick in the valleys. Ground water moves from the north and from the aquifer 's edges to the center of the valley and discharges into the main streams in the middle of the valley and to springs along the southern edge of the aquifers. Water quality is generally suitable for most uses. A landfill adjacent to the Sardinia aquifer has not significantly affected the aquifer. The Alden area includes an aquifer that consists of two sand and gravel zones separated by 10 to 20 feet of clay or till. The more productive lower zone has mineralized water derived from underlying shale.

New York↗

USGS1991

Assessing the solubilities and reaction kinetics of aluminous minerals in soils

The use of chemical thermodynamics and reaction kinetics is necessary to quantitatively model the transformation of aluminous minerals and their dissolved constituents in soils and other geochemical systems. Soils are thermodynamically open systems subject to atmospheric and biological forces and do not attain overall thermodynamic equilibrium with respect to either mass or time. However, local or partial equilibrium conditions may persist for particular minerals and their dissolved constituents. Igneous and metamorphic primary minerals break down chemically to yield disordered gels or colloids and constituent ions, which can then reorganize or precipitate to form more stable hydrous oxides, silicates, carbonates or other mineral species. Naturally-occurring iron and aluminum hydrous oxides and kaolin clays, abundant in highly weathered soils, are commonly believed to be the ultimate, stable end products of weathering reactions, but usually are thermodynamically metastable with respect to more perfectly ordered, synthetic specimens. Thermodynamic stability is no guaranty of mineral persistence; with sufficient time, even the most perfectly crystallized, stable mineral will yield to the solubilizing assault of undersaturated surface waters. All of the dissolution and precipitation reactions of soil minerals are driven by energy differences in the thermodynamic stabilities of reactants and products, and the velocities (or kinetics) of such reactions are regulated by variables of the hydrogeochemical environment.

Book chapter↗

USGS1998

Geological factors affecting the distribution of trace metals in glacial sediments of central Newfoundland

In central Newfoundland (NTS 12A/10, 15, 16, 2H/1), As, Pb, and Zn concentrations in the clay-sized (< 0.002 mm) and silt and clay-sized (< 0.063 mm) fractions of till reflect compositional differences among and within rock terranes at scales of kilometers to tens of kilometers. In those fractions, till derived from volcanic bedrock of Victoria Lake Group (Tulks Hill) is notably enriched in As (50- > 1000 ppm), exceeding levels commonly set for purposes of environmental protection. Near Pb-Zn mines at Buchans, geochemical variation with depth reflects the dispersal of detritus from mineralized bedrock, and differences in sediment type and provenance. There, surface sediments are rich in granitic debris derived from the Topsails igneous terrane 5 km north of Buchans and contain low concentrations of trace metals. These sediments are compositionally unrelated to either Buchans Group volcanic rock or an underlying, older till enriched in sulphide minerals and trace metals. Metal-rich till extending up to 10 km southwest of Buchans results from combined glacial and debris flow transport related to two distinct geological events. Trace metals are enriched (two- to fourfold) in the clay-sized fraction of till compared to the silt and clay-sized, and are associated with Al- and Mg-bearing minerals that preferentially concentrate in the clay fraction. The geochemistry of the silt and clay-sized fraction can approximate that of the < 2-mm fraction. Background variations in till illustrate the important role of a geological framework to the interpretation of geochemical surveys and the origins of trace metals in the environment.

Environmental Geology↗

USGS2005

Evolution of the magmatic-hydrothermal acid-sulfate system at Summitville, Colorado: Integration of geological, stable-isotope, and fluid-inclusion evidence

The Summitville Au-Ag-Cu deposit is a classic volcanic dome-hosted high-sulfidation deposit. It occurs in the Quartz Latite of South Mountain, a composite volcanic dome that was emplaced along the coincident margins of the Platoro and Summitville calderas at 22.5??0.5 Ma, penecontemporaneous with alteration and mineralization. A penecontemporaneous quartz monzonite porphyry intrusion underlies the district and is cut and overlain by pyrite-quartz stockwork veins with traces of chalcopyrite and molybdenite. Alteration and mineralization proceeded through three hypogene stages and a supergene stage, punctuated by at least three periods of hydrothermal brecciation. Intense acid leaching along fractures in the quartz latite produced irregular pipes and lenticular pods of vuggy silica enclosed sequentially by alteration zones of quartz-alunite, quartz-kaolinite, and clay. The acid-sulfate-altered rocks host subsequent covellite+enargite/luzonite+chalcopyrite mineralization accompanied by kaolinite, and later barite-base-metal veins, some containing high Au values and kaolinite. The presence of both liquid- and vapor-rich fluid inclusions indicates the episodic presence of a low-density fluid at all levels of the system. In the mineralized zone, liquid-rich fluid inclusions in healed fractures in quartz phenocrysts and in quartz associated with mineralization homogenize to temperatures between 160 and 390 ??C (90% between 190 and 310 ??C), consistent with the range (200-250 ??C) estimated from the fractionation of sulfur isotopes between coexisting alunite and pyrite. A deep alunite-pyrite pair yielded a sulfur-isotope temperature of 390 ??C, marking a transition from hydrostatic to lithostatic pressure at a depth of about 1.5 km. Two salinity populations dominate the liquid-rich fluid inclusions. One has salinities between 0 and 5 wt.% NaCl equivalent; the other has salinities of up to 43 wt.% NaCl equivalent. The occurrence of high-salinity fluid inclusions in vein quartz associated with mineralization, as well as in the deep stockwork veins, suggests that brines originating deep in the system transported the metals. The ??34S values of sulfides in magnetite (-2.3???) and of sulfate in apatite (5.4???) in unaltered quartz latite indicate that ??34S???S was near 0???. The ??34S values of coexisting alteration alunite and pyrite are 18.2??? to 24.5??? and -8.1??? to -2.2???, respectively. Deep in the system, most of the change in ??34S values occurs in the sulfates, indicating that the fluids were initially H2S-dominant, their redox state buffered at depth by equilibration with igneous rocks. However, in the main alteration zone, most of the change in ??34S values occurs in pyrite, indicating that the fluids moved off the rock buffer and became SO42- -dominant as pyrite precipitated and SO2 disproportionation produced the sulfuric acid requisite for acid leaching. The ??34S values of the late-stage barite and sulfides indicate that the system returned to high H2S/SO42- ratios typical of the original rock-buffered fluid. The ??DH2O of alunite parent fluids was near -45??? and their ??18O ranged from 7??? to -1???, depending on the degree of exchange in the alteration zone at low water-rock ratio, or mixing with unexchanged meteoric water. The low ??D values of some alunite samples are interpreted to result from postdepositional exchange with later ore fluids. Fluid exsolved fr om the magma at depth had ??DH2O and ??18OH2O values near -70??? and 10???, respectively. During and following migration to the top of the magma chamber, the fluid underwent isotopic exchange with the partially crystallized magma and its solid and cooler, but still plastic, carapace just below the transition from a lithostatic to hydrostatic pressure regime. These evolved magmatic fluids had ??DH2O and ??18OH2O values close to -40??? and 5???, respectively, prior to release into the superjacent hydrostatically pressured fracture zone, wherein the fluids separat

Chemical Geology↗

USGS2007

Ball clay

The article offers information on ball clay. Among the companies that mine ball clay in the U.S. are H.C. Spinks Clay, Kentucky-Tennessee Clay and Old Hickory Clay. In 2006, an estimated 1.2 million tons of the mineral was sold or used domestically and exported. Forty-percent of the total sales is accounted for ceramic floor and wall tile followed by sanitaryware and miscellaneous ceramics. Its average value was $ 45 per ton in 2006.

Mining Engineering↗

USGS1997

Epithermal mercury-antimony and gold-bearing vein lodes of southwestern Alaska

Epithermal mineral deposits and occurrences of southwestern Alaska consist of Hg-Sb and gold- and sulfide-bearing vein lodes. Numerous Hg-Sb lodes are located throughout a region measuring several tens of thousands of square kilometers in and surrounding the Kuskokwim River basin in southwestern Alaska. The Hg-Sb lodes are hosted in sedimentary rocks of the Cretaceous Kuskokwim Group, the Triassic to Cretaceous Gemuk Group, and the Paleozoic Holitna Group, as well as in Late Cretaceous and early Tertiary mafic to felsic intrusive rocks. Mineralized Hg-Sb vein and vein breccia lodes are found in the sedimentary or igneous rocks or at their contacts. The minerology of the Hg-Sb lodes is dominated by cinnabar and stibnite, with subordinate realgar, orpiment, and native mercury, pyrite, gold, and hematite, as well as solid and liquid hydrocarbons; quartz, carbonate, limonite, dickite, and sercite are alteration gangue minerals. The largest mercury mine in Alaska, Red Devil, produced about 36,000 flasks of mercury, but the Hg-Sb lodes of southwestern Alaska generally consist of small, discontinuous veins that rarely exceed a few meters in width and a few tens of meters in strike length. The Hg-Sb lodes generally contain about 1 to 5 percent Hg and less than 1 percent Sb and As but are generally poor in base emtals and precious metals. Anomalous concentrations of gold in some lodes, however, suggest that gold deposits may be present in higher temperature environments below some of the Hg-Sb lodes. The formation of the Hg-Sb lodes is closely correlated with igneous activity of a Late Cretaceous and early tertiary magmatic arc in southwestern Alaska. Geologic and geochemical characteristics of the Hg-Sb lodes suggest that ore fluids were generated in local sedimentary rocks as they were intruded by magmas. These intrusions provided the heat to initiate dehydration reactions and expel fluids from hydrous minerals and formational waters in the sedimentary rocks, causing thermal convection and hydrothermal fluid flow along fractures and faults. Isotopic data from sulfide and alteration minerals of the Hg-Sb lodes indicate multiple sources for the ore fluids; most fluids appear to have originated from local sedimentary rocks. Hydrothermal fluids with isotopically heavy oxygen but isotopically light hydrogen and sulfur compositions indicate derivation of these species from sedimentary rocks. Isotopically shifted, evolved meteoric water was a primary component in ore fluids from a few Hg-Sb lodes. Geochemical, isotopic, and fluid inclusion data also indicate that Hg, Co 2 , CH 4 , N2, and local hydrocarbons were derived from breakdown of organic matter in sedimentary rocks when they were heated by intrusions. Radiometric 40 Ar/ 39 Ar ages of 70 ± 3 Ma from hydrothermal sercites in the Hg-Sb lodes indicate a temporal association of igneous activity and mineralization, which is consistent with the geologic characteristics. Most epithermal gold-bearing vein lodes on the Alaska Peninsula and Aleutian Islands are located in Eocene to Pleistocene volcanic-arc rocks, commonly andesite and dacite. These vein and vein breccia lodes, such as the Alaska-Apollo and Shumagin deposits on Unga Island, tend to be aligned along regional, northeast-striking, steeply dipping faults and fractures. The Alaska-Apollo mine produced about 500,000 metric tons (t) of ore that yielded an estimated 3,500 kg (130,000 oz) of gold from veins that were as much as 12 m wide and extended for 1,500 m laterally and 420 m vertically. Ore minerals include gold, galena, sphalerite, chalcopyrite, pyrite, marcasite, arsenopyrite, and native copper; gangue minerals are quartz, sericite, calcite, and chlorite and locally, barsite, clay, rhodonite, and adularia. Ores generally have Au-Ag-Te-Pb-Zn-Mn-Cu geochemical signatures, with wide As-Hg aureoles around some veins. Geologic and mineralogical characteristics of these lodes are similar to adularia-sericite volcanic-hosted epithermal deposits. The gold-bearing vein lodes may be related to arc porphyry systems, but more data are required to verify this association.

Alaska↗

USGS1984

Interlaboratory comparison of mineral constituents in a sample from the Herrin (No. 6) coal bed from Illinois

Approximately 20 kg of the Herrin (No. 6) coal was collected from a strip mine in St. Clair County, Ill. A 10-kg portion was ground to -60 mesh, homogenized, and riffled into 128 splits of 70-80 g each. Homogeneity of these splits was confirmed by moisture, ash, and sulfur analyses of six randomly selected splits. Results of these analyses were within the ASTM (American Society for Testing and Materials) guidelines for interlaboratory precision. Splits of the Herrin (No. 6) coal were then transmitted to more than 30 laboratories for analysis. Low-temperature plasma oxidation was used to isolate inorganic matter for quantitative chemical and mineralogical analysis. Despite a wide variation in ashing conditions, only minor variations in ash yields were obtained; these variations were attributed to differences in operating temperature and moisture content. Mineralogical analyses of low-temperature ash (LTA) concentrates prepared by five different laboratories indicated variations within the limits of analytical error. The mean values, in weight percent, for the major minerals are as follows: calcite, 9; quartz, 20; pyrite, 23; kaolinite, 14; and illite+mixed-layer clays, 31. Normative mineralogical calculations and Fourier transform infrared analysis (FTIR) yielded results similar to those obtained from X-ray diffraction (XRD). Choosing appropriate mineral standards was found to be critical for the proper use of analytical techniques such as XRD and FTIR. Good interlaboratory agreement was obtained for most major, minor, and trace elements despite differences in analytical procedures and in the type of sample analyzed (coal, high-temperature ash, or LTA). Discrepancies between analyses for zinc, strontium, manganese, and iron may be attributed to sampling inhomogeneity problems. Mossbauer spectroscopy showed that approximately 44 percent of the pyritic sulfur was lost through weathering in the first year after preparation of the interlaboratory sample. Szomolnokite and possibly coquimbite and jarosite were also identified. Scanning electron microscopy studies indicated ubiquitous pyrite framboids and, less commonly, euhedral crystals, skeletal grains, irregularly shaped particles, and vein fillings. Minor accessory minerals such as rare-earth phosphates and possibly silicates, zircon, barium sulfate, titanium oxide, and sphalerite were also found. The textural evidence indicates that the minerals in the banded material are detrital whereas the minerals occurring as vein and pore fillings are authigenic. Magnetic measurements indicate that coal crushed in a steel pulverizer is contaminated by small quantities of abrasion fragments from the crusher, which seriously affect the measured magnetic properties of the coal.

Circular↗

USGS1950

Mineral resources of Colombia (other than petroleum)

The following report summarizes data acquired during 1942-45, in Colombia, by geologists and engineers of the Foreign Economic Administration, with whom the United States Geological Survey cooperated. Twenty-nine mineral commodities are considered, but the data for five of them are scant because they were of no interest to FEA personnel. Petroleum is not considered. Preliminary to a review of individual mineral commodities, resumes are given of the general geography and geology of Colombia and of the country's mining laws. The principal mineral commodities, besides petroleum, produced in Colombia are (1) emeralds, gold, platinum, and silver, mainly for export, and (2) barite, cement, clay, coal, gypsum, salt, sand and gravel, silica, and stone, mainly for the domestic market. A large number of other mineral commodities are known in "raw" prospects, some of which may eventually become productive. Their distribution and apparent potentialities, as of 1945, are given. Factors unfavorable to mining are the ruggedness of the terrain, the scarcity of outcrops, and the very high transportation costs.

Bulletin↗

USGS1986

Origin of the Mariano Lake uranium deposit, McKinley County, New Mexico

The Mariano Lake uranium deposit, hosted by the Brushy Basin Member of the Jurassic Morrison Formation, occurs in the Smith Lake district of the Grants uranium region, New Mexico. The orebody, contains abundant amorphous organic material, which suggests that it represents a primary-type deposit; however, the orebody is close to a regional reduction-oxidation interface, which suggests that uranium was secondarily redistributed by oxidative processes. Uranium contents correlate positively with organic carbon contents. Petrographic evidence points to uranium residence in amorphous organic material that was post- depositionally introduced in the diagenetic history of the host sandstone. Uranium mineralization was preceded by precipitation of pyrite (δ 34 S values of — 11.0 to — 38.2 per mil), mixed-layer smectite-illite clays, and quartz and potassium feldspar overgrowths; and also partial dissolution of some detrital feldspars. Alterations associated with uranium mineralization include precipitation of the organic material, microcrys- talline quartz, and pyrite and marcasite (δ 34 S values of -29.4 to -41.6 per mil), and the destruction of detrital Fe-Ti oxide grains. Following mineralization, calcite, dolomite, barite, and kaolinite were precipitated, and some iron disulfides were replaced by ferric oxides. Geochemical data and petrographic observations both indicate that the Mariano Lake orebody is a primary-type deposit. Oxidative processes have not noticeably redistributed uranium in the immediate vicinity of the deposit, nor have they greatly modified geochemical characteristics in the ore. Impedance of ground-water flow by local folds and the lower porosity characteristics of ore zones may have helped to preserve the deposit.

New Mexico↗

USGS2001

Mars Global Surveyor Thermal Emission Spectrometer experiment: Investigation description and surface science results

The Thermal Emission Spectrometer (TES) investigation on Mars Global Surveyor (MGS) is aimed at determining (1) the composition of surface minerals, rocks, and ices; (2) the temperature and dynamics of the atmosphere; (3) the properties of the atmospheric aerosols and clouds; (4) the nature of the polar regions; and (5) the thermophysical properties of the surface materials. These objectives are met using an infrared (5.8- to 50-μm) interferometric spectrometer, along with broadband thermal (5.1- to 150-μm) and visible/near-IR (0.3- to 2.9-μm) radiometers. The MGS TES instrument weighs 14.47 kg, consumes 10.6 W when operating, and is 23.6×35.5×40.0 cm in size. The TES data are calibrated to a 1-σ precision of 2.5 −6 ×10 −8 W cm −2 sr −1 /cm −1 , 1.6×10 −6 W cm −2 sr −1 , and ∼0.5 K in the spectrometer, visible/near-IR bolometer, and IR bolometer, respectively. These instrument subsections are calibrated to an absolute accuracy of ∼4×10 −8 W cm −2 sr −1 /cm −1 (0.5 K at 280 K), 1–2%, and ∼1–2 K, respectively. Global mapping of surface mineralogy at a spatial resolution of 3 km has shown the following: (1) The mineralogic composition of dark regions varies from basaltic, primarily plagioclase feldspar and clinopyroxene, in the ancient, southern highlands to andesitic, dominated by plagioclase feldspar and volcanic glass, in the younger northern plains. (2) Aqueous mineralization has produced gray, crystalline hematite in limited regions under ambient or hydrothermal conditions; these deposits are interpreted to be in-place sedimentary rock formations and indicate that liquid water was stable near the surface for a long period of time. (3) There is no evidence for large-scale (tens of kilometers) occurrences of moderate-grained (>50-μm) carbonates exposed at the surface at a detection limit of ∼10%. (4) Unweathered volcanic minerals dominate the spectral properties of dark regions, and weathering products, such as clays, have not been observed anywhere above a detection limit of ∼10%; this lack of evidence for chemical weathering indicates a geologic history dominated by a cold, dry climate in which mechanical, rather than chemical, weathering was the significant form of erosion and sediment production. (5) There is no conclusive evidence for sulfate minerals at a detection limit of ∼15%. The polar region has been studied with the following major conclusions: (1) Condensed CO 2 has three distinct end-members, from fine-grained crystals to slab ice. (2) The growth and retreat of the polar caps observed by MGS is virtually the same as observed by Viking 12 Martian years ago. (3) Unique regions have been identified that appear to differ primarily in the grain size of CO 2 ; one south polar region appears to remain as black slab CO 2 ice throughout its sublimation. (4) Regional atmospheric dust is common in localized and regional dust storms around the margin and interior of the southern cap. Analysis of the thermophysical properties of the surface shows that (1) the spatial pattern of albedo has changed since Viking observations, (2) a unique cluster of surface materials with intermediate inertia and albedo occurs that is distinct from the previously identified low-inertia/bright and high-inertia/dark surfaces, and (3) localized patches of high-inertia material have been found in topographic lows and may have been formed by a unique set of aeolian, fluvial, or erosional processes or may be exposed bedrock.

Journal of Geophysical Research E: Planets↗

USGS2003

Hydrogeology of the Tully Trough, southern Onondaga County and northern Cortland County, New York

A trough valley near Tully, N.Y. was formed by the same glacial processes that formed the Finger Lake valleys to the west. Glacial ice eroded a preglacial bedrock divide along the northern rim of the Allegheny Plateau and deepened a preglacial valley to form a trough valley. Subsequent meltwater issuing from the ice transported and deposited large amounts of sediment which partly filled the trough. The Tully trough contains three distinct segments—the West Branch valley of the southward-flowing Tioughnioga River in the south, the Valley Heads Moraine near Tully, and the Tully valley of the northward-flowing Onondaga Creek in the north. The West Branch valley segment south of the moraine contains a two-aquifer system—a surficial unconfined sand and gravel aquifer and a confined basal sand and gravel aquifer that rests on bedrock, separated by a thick, fine-grained glaciolacustrine fine sand, silt, and clay unit. Water quality in the surficial aquifer is generally good, although it is typically hard. Water in the basal, confined aquifer is more mineralized and yields less water to wells than the surficial aquifer. The Valley Heads Moraine near Tully consists of layers of sand and gravel, fine sand, silt, clay, and till. The land surface contains many kettle-hole lakes, ponds, wetlands, and dry depressions. The moraine contains several aquifers, some of which are discontinuous. Water quality in the shallow aquifers is generally good, although hard. Water quality in the deep aquifer is generally good, although slightly mineralized by water discharging upward from shale. The Tully valley segment north of the moraine has a confined basal sand-and-gravel aquifer that is overlain by a thick layer of lacustrine silt and clay in the southern part of the valley and becomes interlayered with sand and some fine gravel in the northern part. Most homeowners obtain their water supply from streams or springs along the valley walls or from wells. Water from wells completed in coarse-grained sediment on the north side of the moraine and from the basal aquifer is generally fresh, but water from deep wells finished in the basal aquifer north of Solvay Road contains high concentrations of sodium chloride and calcium sulfate that presumably leached from halite and gypsum minerals within the bedrock.

New York↗

USGS2016

Groundwater

Introduction Groundwater represents the terrestrial subsurface component of the hydrologic cycle. As such, groundwater is generally in motion, moving from elevated areas of recharge to lower areas of discharge. Groundwater usually moves in accordance with Darcy’s law (Dalmont, Paris: Les Fontaines Publiques de la Ville de Dijon, 1856). Groundwater residence times can be under a day in small upland catchments to over a million years in subcontinental-sized desert basins. The broadest definition of groundwater includes water in the unsaturated zone, considered briefly here. Water chemically bound to minerals, as in gypsum (CaSO 4 • 2H 2 O) or hydrated clays, cannot flow in response to gradients in total hydraulic head (pressure head plus elevation head); such water is thus usually excluded from consideration as groundwater. In 1940, M. King Hubbert showed Darcy’s law to be a special case of thermodynamically based potential field equations governing fluid motion, thereby establishing groundwater hydraulics as a rigorous engineering science ( Journal of Geology 48, pp. 785–944). The development of computer-enabled numerical methods for solving the field equations with real-world approximating geometries and boundary conditions in the mid-1960s ushered in the era of digital groundwater modeling. An estimated 30 percent of global fresh water is groundwater, compared to 0.3 percent that is surface water, 0.04 percent atmospheric water, and 70 percent that exists as ice, including permafrost ( Shiklomanov and Rodda 2004 , cited under Groundwater Occurrence ). Groundwater thus constitutes the vast majority—over 98 percent—of the unfrozen fresh-water resources of the planet, excluding surface-water reservoirs. Environmental dimensions of groundwater are equally large, receiving attention on multiple disciplinary fronts. Riparian, streambed, and spring-pool habitats can be sensitively dependent on the amount and quality of groundwater inputs that modulate temperature and solutes, including nutrients and dissolved oxygen. Groundwater withdrawals can negatively impact riparian habitats by depriving ecosystems of adequate fresh water and fragmenting communities when streams go dry. Biochemical reactions in shallow groundwater can remove anthropogenically elevated nitrogen compounds and reduce—but only to a point—the greening of waterways and shorelines with periphyton and harmful algal blooms. Groundwater extraction for beneficial use is increasingly limited by water-quality constraints imposed by naturally occurring and introduced substances. Overdrafting can cause land-surface subsidence, damaging buildings and roads and disrupting canals, sewers, and other gravity-flow conveyances. Increases in groundwater levels can cause soil salinization in dry regions and erosive sapping and flooding in wet regions. Coastal saltwater intrusion, groundwater flooding, salinization associated with groundwater-irrigated agriculture, induced seismicity from injected wastes, and the detrimental impacts of groundwater depletion are among the major environmental challenges of our time.

Book chapter↗

USGS2004

Analysis of MASTER thermal data in the Greeley area of the Front Range Urban Corridor, Colorado — Delineation of sites for infrastructure resource characterization

Sand and soils southwest of Greeley, Colorado, were characterized for mineral composition and industrial quality. Radi-ance data from the thermal channels of the MASTER simulator were calibrated using estimated atmospheric parameters. Chan-nel emissivities were approximated using an estimated ground temperature. Subsequently, a decorrelation algorithm was used to calculate inverse wave emissivity images. Six soil classes, one vegetation class, water, and several small classes were defined using an unsupervised classification algorithm. Ground covered by each of the derived emissivity spectral classes was studied using color-infrared air photos, color-infrared composite MAS-TER data, geologic maps, NASA/JPL Airborne Visible and Infra-red Imaging Spectrometer (AVIRIS) data, and field examination. Spectral classes were characterized by their responses and related to their mineral content through field examination. Classes with a minimum at channel 44, and having a similar spectral shape to quartz, field checked as containing abundant quartz. Classes with a minimum at channel 45, and having a spectral shape similar to the sheet minerals, were found in the field to contain abundant mica and clay. Sandy soil was found to have a positive slope at the longer wavelengths; the more clay rich soils had a negative slope. Spectra with a strong downturn at channel 50 generally indicated low vegetation cover, whereas an upturn indicated more vegetation cover. Mapping revealed a range of classified soils with varying amounts of quartz, silt, clay, and plant humus. Sand and gravel operations along the St. Vrain River, gravel lots, and some fields spectrally classified as quartz-rich sands were confirmed through field examination. Other fields mapped as sandy soils, ranging from quartz-rich sandy soil to quartz-rich silt-sand soil with clay. Flood plains mapped as sandy-silty-organic-rich clay. The city of Greeley contained all classes of materials, with the sand classes mapping as various types of asphalt. Abundant quartz gravel was apparent within the asphalt during field check-ing. The clay classes mapped silt-clay soils in areas of irrigated grass landscaping, some fields, and roofing materials.

Colorado↗

USGS2006

Geologic map of the Kings Mountain and Grover quadrangles, Cleveland and Gaston Counties, North Carolina, and Cherokee and York Counties, South Carolina

This geologic map of the Kings Mountain and Grover 7.5-minute quadrangles, N.C.-S.C., straddles a regional geological boundary between the Inner Piedmont and Carolina terranes. The Kings Mountain sequence (informal name) on the western flank of the Carolina terrane in this area includes the Neoproterozoic Battleground and Blacksburg Formations. The Battleground Formation has a lower part consisting of metavolcanic rocks and interlayered schist, and an upper part consisting of quartz-sericite phyllite and schist interlayered with quartz-pebble metaconglomerate, aluminous quartzite, micaceous quartzite, manganiferous rock, and metavolcanic rocks. The Blacksburg Formation consists of phyllitic metasiltstone interlayered with thinner units of marble, laminated micaceous quartzite, hornblende gneiss, and amphibolite. Layered metamorphic rocks of the Inner Piedmont terrane include muscovite-biotite gneiss, muscovite schist, and amphibolite. The Kings Mountain sequence has been intruded by metatonalite and metatrondhjemite (Neoproterozoic), metadiorite and metagabbro (Paleozoic), and High Shoals Granite (Pennsylvanian). Layered metamorphic rocks of the Inner Piedmont in this area have been intruded by Toluca Granite (Ordovician?), Cherryville Granite and associated pegmatite (Mississippian), and spodumene pegmatite (Mississippian). Diabase dikes (early Jurassic) are locally present throughout the area. Ductile fault zones of regional scale include the Kings Mountain and Kings Creek shear zones. In this area, the Kings Mountain shear zone forms the boundary between the Inner Piedmont and Carolina terranes, and the Kings Creek shear zone separates the Battleground Formation from the Blacksburg Formation. Structural styles change across the Kings Mountain shear zone from steeply-dipping layers, foliations, and folds on the southeast to gently- and moderately-dipping layers, foliations, and recumbent folds on the northwest. Mineral assemblages in the Kings Mountain sequence show a westward decrease from upper amphibolite facies (sillimanite zone) near the High Shoals Granite on the east side of the map to greenschist (epidote-amphibolite) facies in the south-central part of the area near the Kings Mountain shear zone. Amphibolite-facies mineral assemblages in the Inner Piedmont terrane increase in grade from the kyanite zone near the Kings Mountain shear zone to the sillimanite zone in the northwest part of the map. Surficial deposits include alluvium in the stream valleys and colluvium along ridges and steep slopes. These quadrangles are unusual in their richness and variety of mineral deposits, which include spodumene (lithium), cassiterite (tin), mica, feldspar, silica, clay, marble, kyanite and sillimanite, barite, manganese, sand and gravel, gold, pyrite, and iron. (Abstract from pamphlet.)

Open-File Report↗