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At least 55 records · Page 3Linked to original sources
USGS2007

Natural bitumen and extra-heavy oil

Since 2005, oil price increases have greatly increased investment in the production of extra- heavy oil and natural bitumen (tar sands or oil sands) to supplement conventional oil supplies. These oils are characterised by their high viscosity, high density (low API gravity), and high concentrations of nitrogen, oxygen, sulphur, and heavy metals. Extra-heavy oil and natural bitumen are the remnants of very large volumes of conventional oils that have been generated and subsequently degraded, principally by bacterial action. Chemically and texturally, they resemble the residuum produced by refinery distillation of light oil. Although these viscous oils are much more costly to extract, transport and refine than conventional oils, production levels have increased to more than 1.6 million barrels per day, or just under 2% of world crude oil production. The resource base of extra-heavy oil and natural bitumen is immense and can easily support a substantial expansion in production. This resource base can make a major contribution to oil supply, if it can be extracted and transformed into useable refinery feedstock at sufficiently high rates and at costs that are competitive with alternative resources. Technology must continue to be developed to address emerging challenges (both environmental and economic) in the market supply chain.

Book chapter↗
USGS1980

Crude oil degradation as an explanation of the depth rule

Previous studies of crude oil degradation by water washing and bacterial attack have documented the operation of these processes in many different petroleum basins of the world. Crude oil degradation substantially alters the chemical and physical makeup of a crude oil, changing a light paraffinic low-S "mature" crude to a heavy naphthenic or asphalt base, "immature appearing" high-S crude. Rough calculations carried out in the present study using experimentally determined solubility data of petroleum in water give insight into the possible magnitude of water washing and suggest that the process may be able to remove large amounts of petroleum in small divisions of geologic time. Plots of crude oil gravity vs. depth fail to show the expected correlation of increasing API gravity (decreasing specific gravity) with depth below 2.44 km (8000 ft.). Previous studies which have been carried out to document in-reservoir maturation have used crude oil gravity data shallower than 2.44 km (8000 ft.). The changes in crude oil composition as a function of depth which have been attributed to in-reservoir maturation over these shallower depths, are better explained by crude oil degradation. This study concludes that changes in crude oil composition that result from in-reservoir maturation are not evident from existing crude oil gravity data over the depth and temperature range previously supposed, and that the significant changes in crude oil gravity which are present over the shallow depth range are due to crude oil degradation. Thus the existence of significant quantities of petroleum should not necessarily be ruled out below an arbitrarily determined depth or temperature limit when the primary evidence for this is the change in crude oil gravity at shallow depths. ?? 1980.

Chemical Geology↗
USGS2015

U.S. Geological Survey assessment of reserve growth outside of the United States

The U.S. Geological Survey estimated volumes of potential additions to oil and gas reserves for the United States by reserve growth in discovered accumulations. These volumes were derived by using a new methodology developed by the U.S. Geological Survey and reviewed by the American Association of Petroleum Geologists Committee on Resource Evaluation. This methodology was used to assess reserve growth in individual accumulations (reservoirs, groups of reservoirs, or fields). Selected, large, well-studied, conventional accumulations in the United States that are estimated to contribute most to reserve growth were assessed using analysis of geology and engineering practices. Potential additions to oil and gas reserves for large, discovered, conventional accumulations outside of the United States due to reserve growth were assessed using the U.S. accumulations as analogs. Potential oil and gas volumes were assumed to be added to proven plus probable reserves. The U.S. Geological Survey estimated volumes of technically recoverable, conventional petroleum resources resulting from reserve growth for discovered fields outside the United States that have reported in-place oil and gas volumes of 500 million barrels of oil equivalent or greater. The mean volumes of reserve growth were estimated at 665 billion barrels of crude oil; 1,429 trillion cubic feet of natural gas; and 16 billion barrels of natural gas liquids. These volumes constitute a significant portion of the world’s oil and gas resources and represent the potential future growth of current global reserves over time based on better assessment methodology, new technologies, and greater understanding of reservoirs.

Scientific Investigations Report↗
USGS2007

Geochemistry of Selected Coal Samples from Sumatra, Kalimantan, Sulawesi, and Papua, Indonesia

Introduction Indonesia is an archipelago of more than 17,000 islands that stretches astride the equator for about 5,200 km in southeast Asia (figure 1) and includes major Cenozoic volcano-plutonic arcs, active volcanoes, and various related onshore and offshore basins. These magmatic arcs have extensive Cu and Au mineralization that has generated much exploration and mining in the last 50 years. Although Au and Ag have been mined in Indonesia for over 1000 years (van Leeuwen, 1994), it was not until the middle of the nineteenth century that the Dutch explored and developed major Sn and minor Au, Ag, Ni, bauxite, and coal resources. The metallogeny of Indonesia includes Au-rich porphyry Cu, porphyry Mo, skarn Cu-Au, sedimentary-rock hosted Au, epithermal Au, laterite Ni, and diamond deposits. For example, the Grasberg deposit in Papua has the world's largest gold reserves and the third-largest copper reserves (Sillitoe, 1994). Coal mining in Indonesia also has had a long history beginning with the initial production in 1849 in the Mahakam coal field near Pengaron, East Kalimantan; in 1891 in the Ombilin area, Sumatra, (van Leeuwen, 1994); and in South Sumatra in 1919 at the Bukit Asam mine (Soehandojo, 1989). Total production from deposits in Sumatra and Kalimantan, from the 19thth century to World War II, amounted to 40 million metric tons (Mt). After World War II, production declined due to various factors including politics and a boom in the world-wide oil economy. Active exploration and increased mining began again in the 1980's mainly through a change in Indonesian government policy of collaboration with foreign companies and the global oil crises (Prijono, 1989). This recent coal revival (van Leeuwen, 1994) has lead Indonesia to become the largest exporter of thermal (steam) coal and the second largest combined thermal and metallurgical (coking) coal exporter in the world market (Fairhead and others, 2006). The exported coal is desirable as it is low sulfur and ash (generally <1 and < 10 wt.%, respectively). Coal mining for both local use and for export has a very strong future in Indonesia although, at present, there are concerns about the strong need for a major revision in mining laws and foreign investment policies (Wahju, 2004; United States Embassy Jakarta, 2004). The World Coal Quality Inventory (WoCQI) program of the U.S. Geological Survey (Tewalt and others, 2005) is a cooperative project with about 50 countries (out of 70 coal-producing countries world-wide). The WoCQI initiative has collected and published extensive coal quality data from the world's largest coal producers and consumers. The important aspects of the WoCQI program are; (1) samples from active mines are collected, (2) the data have a high degree of internal consistency with a broad array of coal quality parameters, and (3) the data are linked to GIS and available through the world-wide-web. The coal quality parameters include proximate and ultimate analysis, sulfur forms, major-, minor-, and trace-element concentrations and various technological tests. This report contains geochemical data from a selected group of Indonesian coal samples from a range of coal types, localities, and ages collected for the WoCQI program.

Open-File Report↗
USGS2000

Growth in conventional fields in high-cost areas: A case study

Exploration managers commonly base future drilling decisions on past experience in an area. To do this well, they should consider both discovered and undiscovered resources to characterize total future potential. Discovery-size estimates should be adjusted to account for future field growth; otherwise, the relative efficiency of recent exploration will be undervalued. This study models and projects field growth for pre-1997 discoveries in the U.S. Federal Gulf of Mexico (GOM) Outer Continental Shelf (OCS). Projected additions to reserves for these fields from field growth through 2020 are 5.2 billion bbl of oil and 46 Tcfg. Projections include growth associated with sizable new oil discoveries in deepwater areas and initial reserve additions from new subsalt plays discovered through 1996. This article focuses on the U.S. GOM because it has produced longer than other worldwide offshore areas. Its field-growth profile may be prototypical of other offshore provinces such as the North Sea, Scotian Shelf and deepwater Angola, as well as high-cost onshore areas.

Gulf Of Mexico↗
USGS2011

From intuition to statistics in building subsurface structural models

Experts associated with the oil and gas exploration industry suggest that combining forward trishear models with stochastic global optimization algorithms allows a quantitative assessment of the uncertainty associated with a given structural model. The methodology is applied to incompletely imaged structures related to deepwater hydrocarbon reservoirs and results are compared to prior manual palinspastic restorations and borehole data. This methodology is also useful for extending structural interpretations into other areas of limited resolution, such as subsalt in addition to extrapolating existing data into seismic data gaps. This technique can be used for rapid reservoir appraisal and potentially have other applications for seismic processing, well planning, and borehole stability analysis.

World Oil↗
USGS2022

Pore systems and organic petrology of cretaceous Mowry and Niobrara source-rock reservoirs, Powder River Basin, Wyoming, USA

The Powder River Basin (PRB) is a world-class oil province, in large part thanks to contributions from premier source rocks, Cretaceous Mowry and Niobrara shales. Both formations are also unconventional reservoirs. A critical aspect of evaluating production potential and finding sweet spots is the nature of the pore systems in these fine-grained source-rock reservoirs. Variation by stratigraphic interval is important for selecting optimum target zones for horizontal wells. Understanding variation in pore type, size, and connectivity and relationships with mineralogy and fabric help in determining prospectivity in different parts of the basin. Deciphering controls on pore-system development helps predict intervals and locations of optimum reservoir quality. Imaging of Niobrara and Mowry samples from a range of thermal maturities provided observations and data on pore systems, organic matter (OM) types and associations with mineralogy and fabric, wettability, and microporosity associated with both diagenetic and detrital clays. Imaging techniques included scanning electron microscopy, organic petrography and correlative scanning electron microscopy, and mapping of mineralogy through energy dispersive spectroscopy. Mean solid bitumen (BR o ) and vitrinite reflectance (VR o ) values indicate all samples are in the oil window with values ranging from 0.52 to 1.15%. Organic fluorescence is prominent in amorphous OM, solid bitumen and some vitrinite in the early oil window. The fluorescence is extinguished at higher thermal maturity. Carbonate pellets (in Niobrara) mainly contain migrated solid bitumen and residual live oil and little or no terrigenous OM (vitrinite and inertinite). However, terrigenous OM is common in siliceous/argillaceous laminae in both formations, where it occurs with amorphous OM, some of which has converted in situ to a solid bitumen petroleum residue. One key finding is the widespread presence of migrated OM at very early oil window maturity. Distribution of such OM and associated wettability alteration is fabric-controlled, at all levels of thermal maturity studied. Clay morphology and abundance and supporting rigid mineral grain framework strongly influence pore development, preservation, and connectivity in both formations. Carbonate content is a good proxy for reservoir quality in Niobrara intervals due to association of porous solid bitumen with calcareous fecal pellets. High recrystallized microquartz content is associated with the best reservoir intervals in the Mowry.

Wyoming↗
USGS1999

The search for a source rock for the giant Tar Sand triangle accumulation, southeastern Utah

A large proportion (about 36%) of the world’s oil resource is contained in accumulations of heavy oil or tar. In these large deposits of degraded oil, the oil in place represents only a fraction of what was present at the time of accumulation. In many of these deposits, the source of the oil is unknown, and the oil is thought to have migrated over long distances to the reservoirs. The Tar Sand triangle in southeastern Utah contains the largest tar sand accumulation in the United States, with 6.3 billion bbl of heavy oil estimated to be in place. The deposit is thought to have originally contained 13-16 billion bbl prior to the biodegradation, water washing, and erosion that have taken place since the middle-late Tertiary. The source of the oil is unknown. The tar is primarily contained within the Lower Permian White Rim Sandstone, but extends into permeable parts of overlying and underlying beds. Oil is interpreted to have migrated into the White Rim sometime during the Tertiary when the formation was at a depth of approximately 3500 m. This conclusion is based on integration of fluid inclusion analysis, time-temperature reconstruction, and apatite fission-track modeling for the White Rim Sandstone. Homogenization temperatures cluster around 85-90°C for primary fluid inclusions in authigenic, nonferroan dolomite in the White Rim. The fluid inclusions are associated with fluorescent oil-bearing inclusions, indicating that dolomite precipitation was coeval with oil migration. Burial reconstruction suggests that the White Rim Sand stone reached its maximum burial depth from 60 to 24 Ma, and that maximum burial was followed by unroofing from 24 to 0 Ma. Time-temperature modeling indicates that the formation experienced temperatures of 85-90°C from about 35 to 40 Ma during maximum burial. Maximum formation temperatures of about 105-110°C were reached at about 24 Ma, just prior to unroofing. Thermal modeling is used to examine the history of potential source rocks for the White Rim oil. The most attractive potential sources for White Rim oil include beds within one or more of the following formations: the Proterozoic Chuar Group, which is present in the subsurface southwest of the Tar Sand triangle; the Mississippian Delle Phosphatic Member of the Deseret Limestone and equivalent formations, the Permian Kaibab Limestone, the Sinbad Limestone Member of the Triassic Moenkopi Formation, and the Jurassic Arapien Shale, Twin Creek Limestone, and Carmel Formation, which are present west of the Tar Sand triangle; the Pennsylvanian Paradox Formation in the Paradox basin east of the Tar Sand triangle; and the Permian Park City Formation northwest of the Tar Sand triangle. Each formation has a high total organic carbon content and is distributed over a wide enough geographic area to have provided a huge volume of oil. Source beds in all of the formations reached thermal maturity at times prior to or during the time that migration into the White Rim is interpreted to have occurred. Based on all available data, the most likely source for the Tar Sand triangle appears to be the Mississippian Delle Phosphatic Member of the Deseret Limestone. Secondary migration out of the Delle is interpreted to have occurred during the Cretaceous, during Sevier thrusting. Subsequent tertiary migration into the Tar Sand triangle reservoir is interpreted to have occurred later, during middle Tertiary Laramide deformation.

Utah↗
USGS1997

U.S. Geological Survey Studies of Energy Resources in Sub-Saharan Africa

The U.S. Government and the American public need access to information on energy resources in sub-Saharan Africa. Sub-Saharan Africa (mostly Nigeria) produces 5 percent of the world's oil, while supplying the United States with 15 percent of our imports (Energy Information Administration). In the next 10 years, sub-Saharan oil and gas will become increasingly more important to the export market. New discoveries in offshore provinces of West Africa ensure a bright future for the region. Projections indicate that increased oil production in sub-Saharan Africa will far outpace the growth of intraregional consumption, providing greater quantities of oil for export (Forman, 1996). Also, West Africa, although a marginal supplier of liquefied natural gas (LNG) today, will become an important LNG source to the international market by the year 2000 (Oil & Gas Journal, 1996). The United States needs up-to-date information about petroleum resources and the energy balance within the region to predict the future role of sub-Saharan Africa as a major oil and gas exporter. The data required to generate the needed information are often disseminated in archives of oil companies and African geologic surveys, or in obscure publications. For these reasons, the U.S. Geological Survey is collecting data on sub-Saharan energy and constructing a regional energy bibliography. The team of geoscientists will assure that this information is available quickly and from a scientifically based, objective view point.

Fact Sheet↗
USGS2001

A data management life-cycle

Documented, reliable, and accessible data and information are essential building blocks supporting scientific research and applications that enhance society's knowledge base (fig. 1). The U.S. Geological Survey (USGS), a leading provider of science data, information, and knowledge, is uniquely positioned to integrate science and natural resource information to address societal needs. The USGS Central Energy Resources Team (USGS-CERT) provides critical information and knowledge on the quantity, quality, and distribution of the Nation's and the world's oil, gas, and coal resources. By using a life-cycle model, the USGS-CERT Data Management Project is developing an integrated data management system to (1) promote access to energy data and information, (2) increase data documentation, and (3) streamline product delivery to the public, scientists, and decision makers. The project incorporates web-based technology, data cataloging systems, data processing routines, and metadata documentation tools to improve data access, enhance data consistency, and increase office efficiency

Fact Sheet↗
USGS2011

What's new in well logging and formation evaluation

A number of significant new developments is emerging in well logging and formation evaluation. Some of the new developments include an ultrasonic wireline imager, an electromagnetic free-point indicator, wired and fiber-optic coiled tubing systems, and extreme-temperature logging-while-drilling (LWD) tools. The continued consolidation of logging and petrophysical service providers in 2010 means that these innovations are increasingly being provided by a few large companies. Weatherford International has launched a slimhole cross-dipole tool as part of the company's line of compact logging tools. The 26-ft-long Compact Cross-Dipole Sonic (CXD) tool can be run as part of a quad-combo compact logging string. Halliburton has introduced a version of its circumferential acoustic scanning tool (CAST) that runs on monoconductor cable (CAST-M) to provide high-resolution images in open hole and in cased hole for casing and cement evaluation.

World Oil↗
USGS2019

Statistics of petroleum exploration in the world outside the United States and Canada through 2015

The world’s future oil and gas supplies depend on existing reserves and the additions to those reserves that may result, in part, from ongoing exploration and new discoveries. This Circular summarizes available oil and gas exploration data for the world outside the United States and Canada (the study area) through 2015. It updates U.S. Geological Survey Circulars 981, 1096, and 1288 (by D.H. Root, E.D. Attanasi, and R.L. Turner, 1987; E.D. Attanasi and D.H. Root, 1993; and E.D. Attanasi, P.A. Freeman, and J.A. Glovier, 2007). The exploration measures focus on the search for undiscovered conventional oil and gas accumulations. The goal of this compilation, presentation, and analysis of exploration and discovery data is to identify, at the reconnaissance level, the areas explored for oil and gas and to characterize their degree of exploration maturity. Maps and graphs provide a visual summary of the exploration maturity of an area. The maps include both land and offshore areas. The maps show delineated prospective areas, which are the industry-defined areas of interest in the search for undiscovered conventional oil and gas accumulations. The maps also show explored areas, which are areas where the density of exploration and development drilling rules out new discoveries of large conventional petroleum accumulations. Whereas the maps show the static state of oil and gas exploration, the dynamic measures of exploration progress are characterized graphically. The graphs show the growth in the delineated prospective and explored areas as a function of wildcat drilling. The relation between the expansion of the delineated prospective area and the rate of wildcat drilling is determined by the siting of the wildcat wells. Additional graphs show the magnitude of discoveries tied to specific delineated prospective areas. These graphs provide a way to evaluate the quality, in terms of discovered oil and gas, of areas identified by the dates when each area became prospective. From 2006 through 2015, the delineated prospective area within the study area expanded at a rate of about 48,100 square miles per year. This is slightly above the expansion rate of 46,200 square miles per year from 1996 through 2005. From 2006 through 2015, the explored area expanded at a rate of about 12,900 square miles per year, which is somewhat greater than the rate of 11,300 square miles per year for the period from 1996 through 2005. The delineated prospective area established by 1970 accounts for 35 percent of the delineated prospective area established through 2015 but contains 70 percent of the oil and 52 percent of the natural gas discovered through 2015. From 2006 through 2015, offshore discoveries accounted for 71 percent of the oil and 78 percent of the gas discovered in the study area and 40 percent of the offshore wildcat wells were drilled in deep offshore areas (deeper than 200 meters water depth). The delineated prospective area and explored area calculated with oil and gas wells and fields at depths of at least 10,000 feet are less than half of the respective areas calculated with all oil and gas wells and fields. The discovery histories of most regions indicate that average discovery sizes are generally larger in deeper geologic horizons. To correctly interpret the exploration maturity of a deep horizon, drilling and discovery data must be considered in the context of the geology of the area. Such analyses should be prepared at the level of the petroleum basin or subbasin.

Circular↗
USGS2000

USGS world petroleum assessment 2000; new estimates of undiscovered oil and natural gas, including reserve growth, outside the United States

Oil and natural gas account for approximately 63 percent of the world’s total energy consumption. The U.S. Geological Survey periodically estimates the amount of oil and gas remaining to be found in the world. Since 1981, each of the last four of these assessments has shown a slight increase in the combined volume of identified reserves and undiscovered resources. The latest assessment estimates the volume of technically recoverable conventional oil and gas that may be added to the world's reserves, exclusive of the United States, in the next 30 years. The USGS World Petroleum Assessment 2000 reports an increase in global petroleum resources, including a 20-percent increase in undiscovered oil and a 14-percent decrease in undiscovered natural gas compared to the previous assessment (table 1). These results have important implications for energy prices, policy, security, and the global resource balance.

Fact Sheet↗
USGS2016

Assessment of undiscovered hydrocarbon resources of sub-Saharan Africa

Introduction The main objective of the U.S. Geological Survey&rsquo;s (USGS) National and Global Petroleum Assessment Project is to assess the potential for undiscovered, technically recoverable oil and natural gas resources of the United States and the world (U.S. Geological Survey World Conventional Resources Assessment Team, 2012). The USGS updated assessments that were completed during the USGS World Petroleum Assessment 2000 (U.S. Geological Survey World Energy Assessment Team, 2000) and conducted new assessments in areas around the world that were not previously examined (U.S. Geological Survey World Conventional Resources Assessment Team, 2012). These assessments used the latest geology-based assessment methodology for conventional oil and gas resources. The new assessments are available at the USGS website, ( http://energy.usgs.gov/OilGas/AssessmentsData/WorldPetroleumAssessment.aspx ) . As part of this project, the USGS assessed 13 geologic provinces located in sub-Saharan Africa (U.S. Geological Survey World Conventional Resources Assessment Team, 2012). Coastal provinces were extended offshore to water depths ranging from 2,000 to 4,000 meters (m). Within these 13 geologic provinces 18 assessment units (figs. 1, 2) were identified. The west Africa provinces are (1) the Senegal, containing the passive-margin Senegal Basin of Middle Jurassic to Holocene age; (2) the West African Coastal, characterized by rift, passive-margin, and transform tectonics; (3) the Gulf of Guinea, characterized by transform tectonics; (4) the Niger Delta, containing more than 9,100 m of sedimentary rock and recent sediments; (5) the West-Central Coastal, which contains the Aptian salt basin, is dominated by both rift and sag tectonics, and includes the Congo Basin; and (6) the Orange River Coastal, containing more than 7,000 m of syn-rift and post-rift sedimentary rock. The West African Coastal Province was assessed for the first time, whereas the other five west Africa provinces were reassessed for the 2012 World Oil and Wandrey Gas Resource Assessment (fig. 1 of U.S. Geological Survey World Conventional Resources Assessment Team, 2012). More than 275 new oil and gas fields have been discovered in the six west Africa provinces (IHS Energy, 2008, 2009) since the USGS World Petroleum Assessment in 2000 (U.S. Geological Survey World Energy Assessment Team, 2000). These provinces were assessed because of increased energy exploration activity and new oil and gas discoveries within the provinces. Seven provinces not assessed as part of the World Petroleum Assessment 2000 (U.S. Geological Survey World Energy Assessment Team, 2000) were assessed by the USGS as part of the World Assessment 2012 (U.S. Geological Survey World Conventional Resources Assessment Team, 2012). These provinces are (1) the Chad Province, containing Cretaceous and Cenozoic-age lacustrine, continental, and minor marine rocks; (2) the Sud Province, containing Cretaceous and Paleogene age lacustrine, continental, and minor marine rocks; (3) the South Africa Coastal Province, which contains rift, transform, and passive-margin rocks; (4) the Mozambique Coastal Province, containing rift, drift, and passive-margin rocks; (5) the Morondava Province, which contains failed rift, drift, and passive-margin rocks; (6) the Tanzania Coastal Province, containing rift, drift, and passive-margin rocks; and (7) the Seychelles Province, which contains rift and drift rocks. At the time of this assessment 157 oil and gas fields had been discovered in the seven provinces (IHS Energy, 2009). These provinces were assessed because of increased interest and new oil and gas discoveries within the provinces. The assessment was geology-based and used the total petroleum system (TPS) concept. The geologic elements of a TPS are hydrocarbon source rocks (source rock maturation and hydrocarbon generation and migration), reservoir rocks (quality and distribution), and traps where hydrocarbon accumulates. Using these geologic criteria, 16 conventional total petroleum systems and 18 assessment units in the 13 provinces were defined. The undiscovered, technically recoverable oil and gas resources were assessed for all assessment units.

Data Series↗
USGS2013

Multivariate analysis of ATR-FTIR spectra for assessment of oil shale organic geochemical properties

In this study, attenuated total reflectance (ATR) Fourier transform infrared spectroscopy (FTIR) was coupled with partial least squares regression (PLSR) analysis to relate spectral data to parameters from total organic carbon (TOC) analysis and programmed pyrolysis to assess the feasibility of developing predictive models to estimate important organic geochemical parameters. The advantage of ATR-FTIR over traditional analytical methods is that source rocks can be analyzed in the laboratory or field in seconds, facilitating more rapid and thorough screening than would be possible using other tools. ATR-FTIR spectra, TOC concentrations and Rock–Eval parameters were measured for a set of oil shales from deposits around the world and several pyrolyzed oil shale samples. PLSR models were developed to predict the measured geochemical parameters from infrared spectra. Application of the resulting models to a set of test spectra excluded from the training set generated accurate predictions of TOC and most Rock–Eval parameters. The critical region of the infrared spectrum for assessing S1, S2, Hydrogen Index and TOC consisted of aliphatic organic moieties (2800–3000 cm −1 ) and the models generated a better correlation with measured values of TOC and S2 than did integrated aliphatic peak areas. The results suggest that combining ATR-FTIR with PLSR is a reliable approach for estimating useful geochemical parameters of oil shales that is faster and requires less sample preparation than current screening methods.

Organic Geochemistry↗