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Changes in event‐based streamflow magnitude and timing after suburban development with infiltration‐based stormwater management

Green stormwater infrastructure implementation in urban watersheds has outpaced our understanding of practice effectiveness on streamflow response to precipitation events. Long‐term monitoring of experimental urban watersheds in Clarksburg, Maryland, USA, provided an opportunity to examine changes in event‐based streamflow metrics in two treatment watersheds that transitioned from agriculture to suburban development with a high density of infiltration‐focused stormwater control measures (SCMs). Urban Treatment 1 has predominantly single family detached housing with 33% impervious cover and 126 SCMs. Urban Treatment 2 has a mix of single family detached and attached housing with 44% impervious cover and 219 SCMs. Differences in streamflow‐event magnitude and timing were assessed using a before‐after‐control‐reference‐impact design to compare urban treatment watersheds to a forested control and an urban control with detention‐focused SCMs. Streamflow and precipitation events were identified from 14 years of sub‐daily monitoring data with an automated approach to characterize peak streamflow, runoff yield, runoff ratio, streamflow duration, time to peak, rise rate, and precipitation depth for each event. Results indicated that streamflow magnitude and timing were altered by urbanization in the urban treatment watersheds, even with SCMs treating 100% of the impervious area. The largest hydrologic changes were observed in streamflow magnitude metrics, with greater hydrologic change in Urban Treatment 2 compared to Urban Treatment 1. While streamflow changes were observed in both urban treatment watersheds, SCMs were able to mitigate peak flows and runoff volumes compared to the urban control. The urban control had similar impervious cover to Urban Treatment 2, but Urban Treatment 2 had more than twice the precipitation depth needed to initiate a flow response and lower median peak flow and runoff yield for events less than 20 mm. Differences in impervious cover between the Urban Treatment watersheds appeared to be a large driver of differences in streamflow response, rather than SCM density. Overall, use of infiltration‐focused SCMs implemented at a watershed‐scale did provide enhanced attenuation of peak flow and runoff volumes compared to centralized‐detention SCMs.

Maryland

Evaluating drivers of hydrology, water quality, and benthic macroinvertebrates in streams of Fairfax County, Virginia, 2007–18

In 2007, the U.S. Geological Survey partnered with Fairfax County, Virginia, to establish a long-term water-resources monitoring program to evaluate the hydrology, water quality, and ecology of Fairfax County streams and the watershed-scale effects of management practices. Fairfax County uses a variety of management practices, policies, and programs to protect and restore its water resources, but the effects of such strategies are not well understood. This report used streamflow, water-quality, and ecological monitoring data collected from 20 Fairfax County watersheds from 2007 through 2018 to assess the effects of management practices, landscape factors, and climatic conditions on observed nutrient, sediment, salinity, and benthic-macroinvertebrate community responses. Urbanization, climatic variability, and an increase in management practices occurred within Fairfax County during the study period. Impervious cover, housing units, wastewater infrastructure, and (or) stormwater infrastructure increased in most study watersheds. Climatic conditions varied among study years; countywide estimates of average-annual air temperature differed by about 3 degrees Celsius, and total precipitation ranged from about 34 to 63 inches per year. The effects of the management practices, implemented to reduce nitrogen, phosphorus, and (or) sediment loads, are considered in this study. These management practices primarily consist of stormwater retrofits and stream restorations; however, stream restorations account for most of the financial investment and expected load reductions. Management practices were implemented in half of the study watersheds, and most practices were installed and reductions credited late in the study period. Changes in hydrologic response during storm events were evaluated over the study period because many management practices that were implemented were designed to achieve nutrient and sediment reductions by slowing or intercepting runoff. The average number and length of storm events was mostly unchanged throughout the monitoring network. Four watersheds with 10 years of streamflow data showed a mixture of trends in stormflow peak, volume, and rate-of-change. Event-mean nutrient and sediment concentrations from these watersheds were evaluated during storm events and generally showed increases in total phosphorus (TP) and suspended sediment and reductions or no changes in total nitrogen (TN). Landscape inputs of nitrogen and phosphorus and the percentage of inputs delivered to streams were estimated for the study watersheds. Estimated phosphorus from fertilizer and nitrogen from atmospheric deposition represented large nutrient inputs in most watersheds; amounts of other nonpoint sources varied based on land use. Estimated nitrogen inputs declined throughout Fairfax County and in most study watersheds from 2008 through 2018; in comparison, phosphorus input changes were relatively small. Most nonpoint-nutrient inputs were retained on the landscape and did not reach streams, with slightly more nitrogen retention than phosphorus, on average. Retention rates were lower for years with more precipitation and streamflow. After adjusting for streamflow, TN and TP loads were generally higher for years with more nutrient inputs. Calculated as a function of flow-adjusted loads, TP retention declined at most stations from 2009 through 2018, in comparison, TN retention was relatively unchanged. Landscape and climatic conditions affected spatial differences and changes in Fairfax County stream conditions from 2009 through 2018. TN concentrations were higher and increases over time were larger in watersheds with elevated septic-system density. TP concentrations were higher in watersheds with more turfgrass; concentrations were lower, but had larger increases over time, in watersheds with deeper soils. Suspended-sediment concentrations were higher in watersheds with greater stream densities. Specific conductance was higher in watersheds with more developed land use and shallower soils. Benthic-macroinvertebrate index of biotic integrity (IBI) scores were lower in watersheds with high road density and had larger increases over time in bigger, more developed watersheds. Annual variability in TN and TP concentrations and benthic-macroinvertebrate IBI scores was affected by precipitation; annual variability in suspended sediment concentrations and specific conductance was affected by air temperature. After accounting for influences from landscape and climatic conditions, expected management-practice effects were not consistently observed in monitored stream responses. These effects were assessed by comparing expected management-practice load reductions with the timing, direction, and magnitude of changes in storm-event hydrology, nutrient and sediment loads, median-annual water-quality conditions, and benthic-macroinvertebrate IBI scores. An important consideration for future investigations of management-practice effects is how to control for water-quality and ecological variability caused by geologic properties, the urban environment, precipitation, and (or) air temperature. The interpretation of management-practice effects in this report was likely influenced by a combination of factors, including (1) the amount, timing, and location of management-practice implementation; (2) unmeasured landscape and climatic factors; (3) uncertain management-practice expectations; (4) hydrologic variability; and (5) analytical assumptions. Through continued data-collection efforts, particularly after management practices have been completed, many of these factors may become less influential in the future.

Virginia

Predicting aquatic habitat connectivity across watershed boundaries: Implications for interbasin spread of nonindigenous aquatic species.

Understanding habitat connectivity is critical for managing nonindigenous aquatic species (NAS) spread. Dams and watershed boundaries can be impassable to NAS during typical conditions but may become temporarily passable during flooding. The goal of our project was to develop an approach for identifying locations of aquatic connectivity at a fine spatial scale along watershed boundaries using readily available data. To develop this approach, we focused on the potential for range expansion of invasive fish in the United States via possible cross-boundary habitat connections. First, we developed an index using metrics of elevation, watershed size, and geology at regular points along a watershed boundary to stratify points by likelihood of connectivity during high precipitation (>20 mm of precipitation in a 3-day period). We then used a subset of points across a gradient of connectivity likelihoods to gather Landsat-derived observed surface water data and developed a statistical model to predict surface water presence from landscape characteristics. We applied the model throughout the entire watershed boundary to identify locations of hydrologic connectivity during high-water events. The presence of surface water on watershed boundaries was predicted by the interactions between watershed boundary point elevation relative to the minimum adjacent HUC-12 elevations and watershed boundary point elevation relative to neighboring point elevations (marginal R 2 = 0.94). Our approach can be used to identify potential areas of surface water connectivity between watersheds quickly and easily at a fine spatial scale using readily available, remotely sensed data that can inform conservation and management actions across disciplines.

North Dakota, South Dakota

Human and bovine viruses in the Milwaukee River Watershed: hydrologically relevant representation and relations with environmental variables

To examine the occurrence, hydrologic variability, and seasonal variability of human and bovine viruses in surface water, three stream locations were monitored in the Milwaukee River watershed in Wisconsin, USA, from February 2007 through June 2008. Monitoring sites included an urban subwatershed, a rural subwatershed, and the Milwaukee River at the mouth. To collect samples that characterize variability throughout changing hydrologic periods, a process control system was developed for unattended, large-volume (56–2800 L) filtration over extended durations. This system provided flow-weighted mean concentrations during runoff and extended (24-h) low-flow periods. Human viruses and bovine viruses were detected by real-time qPCR in 49% and 41% of samples (n = 63), respectively. All human viruses analyzed were detected at least once including adenovirus (40% of samples), GI norovirus (10%), enterovirus (8%), rotavirus (6%), GII norovirus (1.6%) and hepatitis A virus (1.6%). Three of seven bovine viruses analyzed were detected including bovine polyomavirus (32%), bovine rotavirus (19%), and bovine viral diarrhea virus type 1 (5%). Human viruses were present in 63% of runoff samples resulting from precipitation and snowmelt, and 20% of low-flow samples. Maximum human virus concentrations exceeded 300 genomic copies/L. Bovine viruses were present in 46% of runoff samples resulting from precipitation and snowmelt and 14% of low-flow samples. The maximum bovine virus concentration was 11 genomic copies/L. Statistical modeling indicated that stream flow, precipitation, and season explained the variability of human viruses in the watershed, and hydrologic condition (runoff event or low-flow) and season explained the variability of the sum of human and bovine viruses; however, no model was identified that could explain the variability of bovine viruses alone. Understanding the factors that affect virus fate and transport in rivers will aid watershed management for minimizing human exposure and disease transmission.

Wisconsin

Post-wildfire curve number estimates for the southern Rocky Mountains in Colorado, USA

The curve number method first developed by the US Department of Agriculture Soil Conservation Service (now the Natural Resources Conservation Service) is often used for post-wildfire runoff assessments. These assessments are critical for land and emergency managers making decisions on life and property risks following a wildfire event. Three approaches (i.e., historical event observations, linear regression model, and regression tree model) were used to help estimate a post-wildfire curve number from watershed and wildfire parameters. For the first method, we used runoff events from 102 burned watersheds in Colorado, southern Wyoming, northern New Mexico, and eastern Utah to quantify changes in curve number values from pre- to post-wildfire conditions. The curve number changes from the measured runoff events vary substantially between positive and negative values. The measured curve number changes were then associated with watershed characteristics (e.g., slope, elevation, northness, and eastness) and land cover type to develop prediction models that provide estimates of post-wildfire curve number changes. Finally, we used a regression tree method to demonstrate that accurate predications can be developed using the measured curve number changes from our study domain. These models can be used for future post-wildfire assessments within the region.

Colorado, New Mexico, Utah, Wyoming

Hysteretic response of suspended-sediment in wildfire affected watersheds of the Pacific Northwest and Southern Rocky Mountains

Wildfires can have a profound impact on hydrosedimentary interactions, or the relationship between sediment and runoff, in forested headwater streams. Quantification of sediment-runoff dynamics at the event scale is integral for understanding source areas and transport of suspended-sediment through a watershed following wildfire. Here we used high-frequency turbidity and stream discharge data, coupled with discrete suspended-sediment measurements, in burned and unburned watersheds in the Southern Rocky Mountains and the western Cascades Range to evaluate the response of fine-grained (clay- and silt-sized particles) suspended-sediment. Hysteresis analysis was conducted on estimated suspended-sediment concentrations (using turbidity as a proxy) and streamflow through measurement of the difference in sediment concentration on the rising and falling limbs of the event hydrograph. All burned watersheds exhibited elevated fine suspended-sediment concentrations relative to concentrations found in pre-fire conditions. Changes to hysteretic response vary and may depend on a watershed's sediment connectivity limitations. Results suggest a watershed's inherent hillslope-to-channel (or lateral) connectivity is the primary factor controlling the relative magnitude of event-driven fine sediment fluxes in watersheds affected by wildfire. While wildfire did promote lateral connectivity through activation of hillslope sources, snowmelt, precipitation characteristics and antecedent conditions were more important drivers of hysteretic response than wildfire. For watersheds influenced by annual snowpack, we identified a predominantly clockwise hysteretic response during snowmelt and counterclockwise events during the late spring and summer months. There were also proportionally more counterclockwise events after wildfire in watersheds with high sediment connectivity. Results suggest contrasting wildfire-related sediment risk potential. Rivers in burned watersheds with high sediment connectivity may pose a higher risk to receiving waterbodies, such as larger tributaries or reservoirs, while rivers with low sediment connectivity may experience long-term sediment-related risk within the watershed above the outlet.

Oregon

Hydrologic conditions and quality of rainfall and storm runoff in agricultural and rangeland areas in San Patricio County, Texas, 2000-2001

During 2000–2001, rainfall and runoff were monitored in one mixed agricultural watershed and two rangeland watersheds in San Patricio County, located in the Coastal Bend area of South Texas. During this period, five rainfall samples were collected and analyzed for selected nutrients. Ten runoff samples from nine runoff events were collected at the three watershed monitoring stations. Runoff samples were analyzed for selected nutrients, major ions, trace elements, pesticides, and bacteria. Study area rainfall during 2000 and 2001 was 33.27 and 28.20 inches, respectively, less than the long-term average annual of 36.31 inches. Total runoff from the study area watersheds during 2000–2001 was 2.46 inches; the regional average is about 2 inches per year. Rainfall and runoff during the study period was typical of historical patterns, with periods of below average rainfall interspersed with extreme events. Three individual storm events accounted for about 29 percent of the total rainfall and 86 percent of the total runoff during 2000– 2001. Runoff concentrations of nutrients, major ions, and trace elements generally were larger in the mixed agricultural watershed than runoff concentrations in the rangeland watersheds. Pesticides were detected in two of eight runoff samples. Three pesticides (atrazine, deethylatrazine, and trifluralin) were detected in very small concentrations; only deethylatrazine was detected in a concentration greater than the laboratory minimum reporting level. Bacteria in agricultural and rangeland runoff is a potential water-quality concern as all fecal coliform and E. coli densities in the runoff samples exceeded Texas Surface Water Quality Standards for receiving waters. However, runoff and relatively large bacteria densities represent very brief and infrequent conditions, and the effect on downstream water is not known. Rainfall deposition is a major source of nitrogen delivered to the study area. Rainfall nitrogen (mostly ammonia and nitrate) exceeded the runoff yield. The average annual rainfall deposition of total nitrogen on the study area watersheds was 1.3 pounds per acre. In contrast, an average annual yield of 0.57 and 0.21 pound per acre of total nitrogen in runoff exited the mixed agricultural watershed and the rangeland watersheds, respectively.

Texas

Chemical data and lead isotopic compositions of geochemical baseline samples from streambed sediments and smelter slag, lead isotopic compositions in fluvial tailings, and dendrochronology results from the Boulder River watershed, Jefferson County, Montana

Introduction As a part of the U.S. Geological Survey Abandoned Mine Lands Initiative, metal-mining related wastes in the Boulder River study area in northern Jefferson County, Montana, have been evaluated for their environmental effects. The study area includes a 24-km segment of the Boulder River in and around Basin, Montana and three principal tributaries to the Boulder River: Basin Creek, Cataract Creek, and High Ore Creek. Mine and prospect waste dumps and mill wastes are located throughout the drainage basins of these tributaries and in the Boulder River. Mine-waste material has been transported into and down streams, where it has mixed with and become incorporated into the streambed sediments. In some localities, mine waste material was placed directly in stream channels and was transported downstream forming fluvial tailings deposits along the stream banks. Water quality and aquatic habitat have been affected by trace-element-contaminated sediment that moves from mine wastes into and down streams during snowmelt and storm runoff events within the Boulder River watershed. Present-day trace element concentrations in the streambed sediments and fluvial tailings have been extensively studied. However, in order to accurately evaluate the impact of mining on the stream environments, it is also necessary to evaluate the pre-mining trace-element concentrations in the streambed sediments. Three types of samples have been collected for estimation of pre-mining concentrations: 1) streambed sediment samples from the Boulder River and its tributaries located upstream from historical mining activity, 2) stream terrace deposits located both upstream and downstream of the major tributaries along the Boulder River, and 3) cores through sediment in overbank deposits, in abandoned stream channels, or beneath fluvial tailings deposits. In this report, we present geochemical data for six stream-terrace samples and twelve sediment-core samples and lead isotopic data for six terrace and thirteen core samples. Sample localities are in table 1 and figures 1 and 2, and site and sample descriptions are in table 2. Geochemical data have been presented for cores through fluvial tailings on High Ore Creek, on upper Basin Creek, and on Jack Creek and Uncle Sam Gulch. Geochemical and lead isotopic data for modern streambed-sediment samples have been presented by Fey and others. Lead isotopic determinations in bed sediments have been shown to be an effective tool for evaluating the contributions from various sources to the metals in bed sediments. However, in order to make these calculations, the lead isotopic compositions of the contaminant sources must also be known. Consequently, we have determined the lead isotopic compositions of five streambed-sediment samples heavily contaminated with fluvial mine waste immediately downstream from large mines in the Boulder River watershed in order to determine the lead isotopic signatures of the contaminants. Summary geochemical data for the contaminants are presented here and geochemical data for the streambed-sediment samples are given by Fey and others. Downstream from the Katie mill site and Jib tailings, fluvial deposits of mill tailings are present on a 10-m by 50-m bar in the Boulder River below the confluence with Basin Creek. The source of these tailings is not known, but fluvial tailings are also present immediately downstream from the Katie mill site, which is immediately upstream from the confluence with Basin Creek. Nine cores of fluvial tailings from this bar were analyzed. Dendrochronology samples were taken at several stream terrace localities to provide age control on the stream terrace deposits. Trees growing on the surfaces of stream terraces provide a minimum age for the terrace deposits, although floods subsequent to the trees' growth could have deposited post-mining overbank deposits around the trees. Historical data were also used to provide estimates of minimum ages of cultural features and to bracket the age of events.

Montana

Contributing areas to domestic wells in dipping sedimentary rocks under extreme recharge events

We use particle tracking to determine contributing areas (CAs) to wells for transient flow models that simulate cyclic domestic pumping and extreme recharge events in a small synthetic watershed underlain by dipping sedimentary rocks. The CAs consist of strike-oriented bands at locations where the water table intersects high-hydraulic conductivity beds, and from which groundwater flows to the pumping well. Factors that affect the size and location of the CAs include topographic flow directions, rock dip direction, cross-bed fracture density, and position of the well relative to streams. For an effective fracture porosity (n e ) of 10 -4 , the fastest advective travel times from CAs to wells are only a few hours. These results indicate that wells in this type of geologic setting can be highly vulnerable to contaminants or pathogens flushed into the subsurface during extreme recharge events. Increasing n e to 10 -3 results in modestly smaller CAs and delayed well vulnerability due to slower travel times. CAs determined for steady-state models of the same setting, but with long-term average recharge and pumping rates, are smaller than CAs in the models with extreme recharge. Also, the earliest-arriving particles arrive at the wells later in the steady-state models than in the extreme-recharge models. The results highlight the importance of characterizing geologic structure, simulating plausible effective porosities, and simulating pumping and recharge transience when determining CAs in fractured rock aquifers to assess well vulnerability under extreme precipitation events.

Groundwater

Invasive African clawed frogs ( Xenopus laevis ) in Washington State: Status, response efforts, and lessons learned

The African clawed frog (ACF, Xenopus laevis ), which is indigenous to sub-Saharan Africa, is an aquatic invasive species known to have severe ecological impacts on native fauna when introduced into non-endemic regions. In 2015, ACFs were detected in Washington State, U.S. for the first time, and the species is now documented at three cities across western Washington: Lacey, Bothell, and Issaquah. We cataloged the known ACF occurrences, early management efforts, biological data about the frogs, and status of these invasive populations at the three sites from 2015–2023. The ACFs appear to be established in at least three watersheds in the Puget Sound region despite substantial effort at eradicating them at one site. Presence of ACFs in watersheds that lack surface connectivity implies independent introduction events, and the capture of frogs in multiple subbasins in the same watershed may reflect the potential for further spread. Because the ACF is nocturnal and otherwise behaviorally and visually highly cryptic, other established populations may go undetected. Where the ACFs are largely confined to stormwater ponds — as many of our current observations suggest — eradication may still be possible, though a substantial, focused effort would be required. In addition, significant refinement of eradication approaches will be needed to ensure effectiveness in topographically and vegetatively complex Pacific Northwest aquatic environments.

Washington

Assessment of effects of channelization mitigation alternatives of Stoney Brook, Carlton and St. Louis Counties, Minnesota

The U.S. Geological Survey, in cooperation with the Fond du Lac Band of Lake Superior Chippewa (FDLB), studied the effects of channel modification alternatives on lake levels and floodplain inundation in the Stoney Brook watershed in northeast Minnesota. Northern wild rice ( Zizania palustris ), also referred to as manoomin by the Ojibwe/Chippewa people, is a natural and cultural resource to the FDLB and is sensitive to water levels and rates of water-level changes, particularly during the early stages of growth. Drainage ditches constructed in the early 1900s in the Stoney Brook watershed lowered lake-water levels, caused greater fluctuations in the lakes, and created a loss in wetland coverage. The FDLB is committed to minimizing large fluctuations of the lakes with natural wild rice production in the Stoney Brook watershed and restoring a more natural hydrology to Stoney Brook. The hydrologic response of these lakes and floodplain storage to simulated channel modification alternatives were examined. Hydrologic and hydraulic models were developed for the watershed and calibrated to historical rainfall events. The models used probabilistic frequency rainfall events of 24-hour duration for 1-, 2-, 5-, and 10-year annual recurrence intervals (100-, 50-, 20-, and 10-percent annual exceedance probability) to simulate watershed management scenarios with existing and alternative conditions. The hydraulic model outputs for peak flows, volume accumulation, water levels, and inundation duration and depths were assessed to quantify the effects of the channel modification alternatives. The channel modification alternatives were simulated with four different terrain conditions: existing conditions, bank spoil breach, original channel reconnection, and original channel reconnection with bank spoil breach. Hydrologic characteristics from six distinct areas were used in the model to evaluate the effects from the channel modification alternatives. The simulated results of two lakes in which wild rice was planted demonstrated that the lakes would take longer to draw down following an event with the channel modification alternatives compared to existing conditions with little change to peak water-surface elevations. The alternatives provided minor to no increases in flows or conveyances at the downstream reference location at Pine Drive bridge. The restored floodplain locations had increased flows and conveyances for the channel modification alternatives that could be considered substantial when compared to flows with existing conditions. The inundation extent, duration, and water-depth distribution were assessed within selected floodplain areas. Generally, the channel modification alternatives produced increases in the higher depth (3–4 and greater than 4 feet) and duration (10–14 and greater than 14 days) categories for these areas, which may be beneficial to increases in wetland coverage and floodplain storage.

Minnesota

Quantifying the hydrological responses to climate change in an intact forested small watershed in southern China

Responses of hydrological processes to climate change are key components in the Intergovernmental Panel for Climate Change (IPCC) assessment. Understanding these responses is critical for developing appropriate mitigation and adaptation strategies for sustainable water resources management and protection of public safety. However, these responses are not well understood and little long-term evidence exists. Herein, we show how climate change, specifically increased air temperature and storm intensity, can affect soil moisture dynamics and hydrological variables based on both long-term observation and model simulations using the Soil and Water Assessment Tool (SWAT) in an intact forested watershed (the Dinghushan Biosphere Reserve) in Southern China. Our results show that, although total annual precipitation changed little from 1950 to 2009, soil moisture decreased significantly. A significant decline was also found in the monthly 7-day low flow from 2000 to 2009. However, the maximum daily streamflow in the wet season and unconfined groundwater tables have significantly increased during the same 10-year period. The significant decreasing trends on soil moisture and low flow variables suggest that the study watershed is moving towards drought-like condition. Our analysis indicates that the intensification of rainfall storms and the increasing number of annual no-rain days were responsible for the increasing chance of both droughts and floods. We conclude that climate change has indeed induced more extreme hydrological events (e.g. droughts and floods) in this watershed and perhaps other areas of Southern China. This study also demonstrated usefulness of our research methodology and its possible applications on quantifying the impacts of climate change on hydrology in any other watersheds where long-term data are available and human disturbance is negligible.

Guangdong Province

Hydrology and cycling of nitrogen and phosphorus in Little Bean Marsh: A remnant riparian wetland along the Missouri River in Platte County, Missouri, 1996–97

The lack of concurrent water-quality and hydrologic data on riparian wetlands in the Midwestern United States has resulted in a lack of knowledge about the water-quality functions that these wetlands provide. Therefore, Little Bean Marsh, a remnant riparian wetland along the Missouri River, was investigated in 1996 and 1997 primarily to determine the magnitude and character of selected water-quality benefits that can be produced in such a wetland and to identify critical processes that can be managed in remnant or restored riparian wetlands for amelioration of water quality. Little Bean Marsh averages 69 hectares in size, has a maximum depth of about 1 meter, and the majority of the marsh is covered by macrophytes. In 1997, 41 percent of the water received by Little Bean Marsh was from direct precipitation, 14 percent was from ground-water seepage, 30 percent from watershed runoff, and 15 percent was backflow from Bean Lake. Although, Little Bean Marsh was both a ground-water recharge and discharge area, discharge to the marsh was three times the recharge to ground water. Ground-water levels closely tracked marsh water levels indicating a strong hydraulic connection between ground water and the marsh. Reduced surface runoff and ground-water availability are stabilizing influences on marsh hydrology and probably contribute to the persistence of emergent vegetation. The rapid hydraulic connection between Little Bean Marsh and ground water indicates that the hydrologic regime of most wetlands along the lower Missouri River is largely a function of the altitude of the marsh bottom relative to the altitude of the water table. More water was lost from the marsh through evapotranspiration (59 percent) than all other pathways combined. This is partially because the transpiration process of abundant macrophytes can greatly contribute to the evapotranspiration above that lost from open water surfaces. Surface outflow accounted for 36 percent and ground-water seepage accounted for only 5 percent of the losses. Large residence times allows the marsh to greatly affect water quality before water escapes as ground-water recharge or surface outflow. The shallowness of Little Bean Marsh and ion exclusion during ice formation caused the highest specific conductances of 1,100 to 1,300 microsiemens per centimeter at 25 degrees Celsius to occur during the winter. This concentration of dissolved solutes under ice can make wetlands more vulnerable to toxic contaminants than deeper surface-water bodies. Dissolved oxygen was less than 5 mg/L (milligrams per liter) for 3 to 4 months and near 0 mg/L for about 1 month in summer. Despite depths of less than 1 meter, temperature stratification persisted more than 3 months during the summers of 1996 and 1997, preventing mixing and contributing to periods of anoxia. Shallow depths and extended periods of anoxia in the marsh limit the ability of some organisms to escape high-temperature stress. Turbidity in Little Bean Marsh usually was low for several reasons: sediment loadings from the largely flood-plain drainage were low, emergent vegetation shade out algae and shield the water from wind, and high concentrations of bivalent cations increase flocculation rates of inorganic suspended material. The high concentrations of bivalent cations was largely because of a substantial amount of ground-water seepage into the marsh. Dissolved organic nitrogen was the dominant nitrogen species in Little Bean Marsh. Denitrification and biotic uptake kept more than 62 percent of nitrate (NO3) and 43 percent of ammonium (NH4) concentrations in marsh samples less than a detection limit of 0.005 mg/L. This contrasts with the Missouri River where inorganic NO3 dominates. Consequently, artificial flood-plain drainage that bypasses riparian wetlands likely deliver substantially more biotically available inorganic nitrogen to receiving waters than surface water that has been routed through a remnant wetland. Average total nitrogen concentrations in Little Bean Marsh were substantially less than those at other Missouri River wetlands, roughly one-half the mean concentrations in the Missouri River, but roughly twice the average nitrogen values in reservoirs of the glaciated plains of Missouri. The largest concentrations of nearly all species of nitrogen and phosphorus and the most intense period of hypereutrophy coincided with a phytoplankton bloom and senescence of River Bulrush (Scirpus fluviatilis) and common cattail (Typha latifolia) in September 1997. The rapid leaching of nitrogen that occurs soon after macrophyte senescence combined with a recent destratification of the marsh probably provided nitrogen to the nitrogen-limited open-water areas and triggered a phytoplankton bloom. Despite the rarity of runoff events, surface runoff from the watershed, combined with atmospheric deposition, contributed more than seven times the 530 kg (kilograms) of nitrogen that escaped Little Bean Marsh in surface outflow during 1997. Atmospheric deposition alone was more than 530 kg. Seepage to ground water contained less than 1.5 percent of the nitrogen leaving the marsh in surface outflow. The slow decay rate of Scirpus fluviatilis and reducing conditions in bottom sediments make burial of organic nitrogen a substantial sink of nitrogen. Denitrification experiments indicate that denitrification rates were limited by NO3 in the water column. Consequently, decomposition and nitrification of NH4 and organic nitrogen are the rate limiting steps of nitrogen removal in Little Bean Marsh. The NO3-limited rates of denitrification also indicate that Little Bean Marsh has a large unused capacity for nitrogen removal. These data indicate that the vast extent of riparian marshes along the Missouri and Mississippi Rivers may have had a substantial role in limiting NO3 loads to the Gulf of Mexico before agricultural development of flood plains. Drainage and removal of riparian marshes may be a major cause of the increased NO3 loads to the Gulf of Mexico. Periods of anoxia had much larger effects on phosphorus release than the other variables. The largest concentrations of phosphorus occurred in late summer and corresponded with senescing macrophytes, periods of anoxia, and a large algal bloom in Little Bean Marsh. Low water levels prevented the escape of phosphorus in surface outflow during these periods of highest phosphorus concentrations. Dry weather in late summer is typical and probably makes the correspondence of low water levels, anoxia, and consequent low phosphorus release a common occurrence in marshes along the Missouri River. Little Bean Marsh retained more than 95 percent of the phosphorus it received. The amount of phosphorus in surface inflows to the marsh were more than one order of magnitude greater than that escaping in surface outflows. The long hydraulic residence time of the marsh and large contributions of iron from ground water (that provide many sorption sites for phosphorus) make the marsh an effective sediment and phosphorus trap.

Missouri

Comparison of total mercury and methylmercury cycling at five sites using the small watershed approach

The small watershed approach is well-suited but underutilized in mercury research. We applied the small watershed approach to investigate total mercury (THg) and methylmercury (MeHg) dynamics in streamwater at the five diverse forested headwater catchments of the US Geological Survey Water, Energy, and Biogeochemical Budgets (WEBB) program. At all sites, baseflow THg was generally less than 1 ng L −1 and MeHg was less than 0.2 ng L −1 . THg and MeHg concentrations increased with streamflow, so export was primarily episodic. At three sites, THg and MeHg concentration and export were dominated by the particulate fraction in association with POC at high flows, with maximum THg (MeHg) concentrations of 94 (2.56) ng L −1 at Sleepers River, Vermont; 112 (0.75) ng L −1 at Rio Icacos, Puerto Rico; and 55 (0.80) ng L −1 at Panola Mt., Georgia. Filtered (<0.7 μm) THg increased more modestly with flow in association with the hydrophobic acid fraction (HPOA) of DOC, with maximum filtered THg concentrations near 5 ng L −1 at both Sleepers and Icacos. At Andrews Creek, Colorado, THg export was also episodic but was dominated by filtered THg, as POC concentrations were low. MeHg typically tracked THg so that each site had a fairly constant MeHg/THg ratio, which ranged from near zero at Andrews to 15% at the low-relief, groundwater-dominated Allequash Creek, Wisconsin. Allequash was the only site with filtered MeHg consistently above detection, and the filtered fraction dominated both THg and MeHg. Relative to inputs in wet deposition, watershed retention of THg (minus any subsequent volatilization) was 96.6% at Allequash, 60% at Sleepers, and 83% at Andrews. Icacos had a net export of THg, possibly due to historic gold mining or frequent disturbance from landslides. Quantification and interpretation of Hg dynamics was facilitated by the small watershed approach with emphasis on event sampling.

Environmental Pollution

Testing a two-scale focused conservation strategy for reducing phosphorus and sediment loads from agricultural watersheds

This study tested a focused strategy for reducing phosphorus (P) and sediment loads in agricultural streams. The strategy involved selecting small watersheds identified as likely to respond relatively quickly, and then focusing conservation practices on high-contributing fields within those watersheds. Two 5,000 ha (12,360 ac) watersheds in the Driftless Area of south central Wisconsin, previously ranked in the top 6% of similarly sized Wisconsin watersheds for expected responsiveness to conservation efforts to reduce high P and sediment loads, were chosen for the study. The stream outlets from both watersheds were monitored from October of 2006 through September of 2016 for streamflow and concentrations of sediment, total P, and, beginning in October of 2009, total dissolved P. Fields and pastures having the highest potential P delivery to the streams in each watershed were identified using the Wisconsin P Index (Good et al. 2012). After three years of baseline monitoring (2006 to 2009), farmers implemented both field- and farm-based conservation practices in one watershed (treatment) as a means to reduce sediment and P inputs to the stream from the highest contributing areas, whereas there were no out-of-the-ordinary conservation efforts in the second watershed (control). Implementation occurred primarily in 2011 and 2012. In the four years following implementation of conservation practices (2013 through 2016), there was a statistically significant reduction in storm-event suspended sediment loads in the treatment watershed compared to the control watershed when the ground was not frozen ( p = 0.047). While there was an apparent reduction in year-round suspended sediment event loads, it was not statistically significant at the 95% confidence level ( p = 0.15). Total P loads were significantly reduced for runoff events ( p < 0.01) with a median reduction of 50%. Total P and total dissolved P concentrations for low-flow conditions were also significantly reduced ( p < 0.01) compared to the control watershed. This study demonstrated that a strategy that first identifies watersheds likely to respond to conservation efforts and then focuses implementation on relatively high-contributing fields within those watersheds can be successful in reducing stream P concentrations and loads.

Wisconsin

The application of electrical conductivity as a tracer for hydrograph separation in urban catchments

Two-component hydrograph separation was performed on 19 low-to-moderate intensity rainfall events in a 4.1-km2 urban watershed to infer the relative and absolute contribution of surface runoff (e.g. new water) to stormflow generation between 2001 and 2003. The electrical conductivity (EC) of water was used as a continuous and inexpensive tracer, with order of magnitude differences in precipitation (12-46 ??S/cm) and pre-event streamwater EC values (520-1297 ??S/cm). While new water accounted for most of the increased discharge during storms (61-117%), the contribution of new water to total discharge during events was typically lower (18-78%) and negatively correlated with antecedent stream discharge (r2 = 0??55, p < 0??01). The amount of new water was positively correlated with total rainfall (r2 = 0??77), but hydrograph separation results suggest that less than half (9-46%) of the total rainfall on impervious surfaces is rapidly routed to the stream channel as new water. Comparison of hydrograph separation results using non-conservative tracers (EC and Si) and a conservative isotopic tracer (??D) for two events showed similar results and highlighted the potential application of EC as an inexpensive, high frequency tracer for hydrograph separation studies in urban catchments. The use of a simple tracer-based approach may help hydrologists and watershed managers to better understand impervious surface runoff, stormflow generation and non-point-source pollutant loading to urban streams. Copyright ?? 2007 John Wiley & Sons, Ltd.

Hydrological Processes

Evaluating streamwater dissolved organic carbon dynamics in context of variable flowpath contributions with a tracer-based mixing model

This study focuses on characterizing the contributions of key terrestrial pathways that deliver dissolved organic carbon (DOC) to streams during hydrological events and on elucidating factors governing variation in water and DOC fluxes from these pathways. We made high-frequency measurements of discharge, specific conductance (SC), and fluorescent dissolved organic matter (FDOM) during 221 events recorded over 2 years within four Vermont (USA) watersheds that range in area from 0.4 to 139 km 2 . Using the SC measurements, together with statistical information on discharge, we separated the event hydrographs into contributions from three terrestrial pathways, which we refer to as riparian quickflow, subsurface quickflow, and slow-flow groundwater. The pathway discharges were used as input to a mixing model that closely approximated sub-hourly streamwater DOC concentrations as measured with the FDOM sensors. Subsurface quickflow, comprised of pre-event water, was the leading contributor to streamwater DOC fluxes, while riparian quickflow, comprised of event water, was the second-leading contributor to streamwater DOC fluxes, despite comprising the smallest proportion of streamflow yield among the three end-member pathways. Fixed-effects regression analysis revealed that the relationship between DOC fluxes from the end-member pathways and event magnitude was consistent across the four watersheds. This analysis also showed that DOC fluxes from the quickflow pathways increased significantly with temperature and varied inversely, but weakly, with catchment antecedent wetness. We believe that our approach, which leverages in-stream sensors that enable high-frequency measurements over extended periods, may be applicable for evaluating controls on DOC export from other watersheds within and beyond our study region.

New Hampshire, Vermont

Water quality, sources of nitrate, and chemical loadings in the Geronimo Creek and Plum Creek watersheds, south-central Texas, April 2015–March 2016

Located in south-central Texas, the Geronimo Creek and Plum Creek watersheds have long been characterized by elevated nitrate concentrations. From April 2015 through March 2016, an assessment was done by the U.S. Geological Survey, in cooperation with the Guadalupe-Blanco River Authority and the Texas State Soil and Water Conservation Board, to characterize nitrate concentrations and to document possible sources of elevated nitrate in these two watersheds. Water-quality samples were collected from stream, spring, and groundwater sites distributed across the two watersheds, along with precipitation samples and wastewater treatment plant (WWTP) effluent samples from the Plum Creek watershed, to characterize endmember concentrations and isotopic compositions from April 2015 through March 2016. Stream, spring, and groundwater samples from both watersheds were collected during four synoptic sampling events to characterize spatial and temporal variations in water quality and chemical loadings. Water-quality and -quantity data from the WWTPs and stream discharge data also were considered. Samples were analyzed for major ions, selected trace elements, nutrients, and stable isotopes of water and nitrate. The dominant land use in both watersheds is agriculture (cultivated crops, rangeland, and grassland and pasture). The upper part of the Plum Creek watershed is more highly urbanized and has five major WWTPs; numerous smaller permitted wastewater outfalls are concentrated in the upper and central parts of the Plum Creek watershed. The Geronimo Creek watershed, in contrast, has no WWTPs upstream from or near the sampling sites. Results indicate that water quality in the Geronimo Creek watershed, which was evaluated only during base-flow conditions, is dominated by groundwater, which discharges to the stream by numerous springs at various locations. Nitrate isotope values for most Geronimo Creek samples were similar, which indicates that they likely have a common source (or sources) of nitrate. Nitrate sources in the Geronimo Creek watershed include a predominance of nitrate from fertilizer applications, as well as a contribution from septic systems. Additional nitrate loading from these sources is ongoing. Chemical loadings of dissolved solids, chloride, and sulfate varied little among sampling events and were low at most sites because of low streamflow. In contrast to the Geronimo Creek watershed, nitrate sources in the Plum Creek watershed are dominated by effluent discharge from the major WWTPs in the upper and central parts of the watershed. Results indicate that discharge from these WWTPs accounts for the majority of base flow in the watershed. Nitrate concentrations in Plum Creek were dependent on flow conditions, with the highest concentrations measured at lower flows, when flow is dominated by WWTP effluent discharge. In addition to WWTP effluent discharge, the Plum Creek watershed, similar to the Geronimo Creek watershed, also is affected by historical and current loading of nitrate from fertilizer applications and from septic systems in the watershed. Chemical loadings of dissolved solids, chloride, sulfate, and nitrate in Plum Creek at lower flow conditions are highest at the upstream sites and decrease downstream as distance from the WWTPs increases, which is consistent with WWTP effluent as an important control on water quality. Under higher flow conditions, however, nitrate loads to Plum Creek increased by about a factor of three. These higher nitrate loads cannot be accounted for by WWTP effluent discharge from the five major WWTPs in the watershed. This additional loading indicates that nitrate is exported from the northeastern part of the watershed. In the lower part of the Plum Creek watershed, higher concentrations of dissolved solids, chloride, and sulfate occur, which might be affected by produced water associated with oil and gas exploration, or mixing with saline groundwater.

Texas