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Atomic weights of the elements. Review 2000 (IUPAC Technical Report)

A consistent set of internationally accepted atomic weights has long been an essential aim of the scientific community because of the relevance of these values to science and technology, as well as to trade and commerce subject to ethical, legal, and international standards. The standard atomic weights of the elements are regularly evaluated, recommended, and published in updated tables by the Commission on Atomic Weights and Isotopic Abundances (CAWIA) of the International Union of Pure and Applied Chemistry (IUPAC). These values are invariably associated with carefully evaluated uncertainties. Atomic weights were originally determined by mass ratio measurements coupled with an understanding of chemical stoichiometry, but are now based almost exclusively on knowledge of the isotopic composition (derived from isotope-abundance ratio measurements) and the atomic masses of the isotopes of the elements. Atomic weights and atomic masses are now scaled to a numerical value of exactly 12 for the mass of the carbon isotope of mass number 12. Technological advances in mass spectrometry and nuclear-reaction energies have enabled atomic masses to be determined with a relative uncertainty of better than 1 ×10−7 . Isotope abundances for an increasing number of elements can be measured to better than 1 ×10−3 . The excellent precision of such measurements led to the discovery that many elements, in different specimens, display significant variations in their isotope-abundance ratios, caused by a variety of natural and industrial physicochemical processes. While such variations increasingly place a constraint on the uncertainties with which some standard atomic weights can be stated, they provide numerous opportunities for investigating a range of important phenomena in physical, chemical, cosmological, biological, and industrial processes. This review reflects the current and increasing interest of science in the measured differences between source-specific and even sample-specific atomic weights. These relative comparisons can often be made with a smaller uncertainty than is achieved in the best calibrated “absolute ” (=SI-traceable) atomic-weight determinations. Accurate determinations of the atomic weights of certain elements also influence the values of fundamental constants such as the Avogadro, Faraday, and universal gas constants. This review is in two parts: the first summarizes the development of the science of atomic-weight determinations during the 20th century; the second summarizes the changes and variations that have been recognized in the values and uncertainties of atomic weights, on an element-by-element basis, in the latter part of the 20th century.

Pure and Applied Chemistry↗

Geologic and hydrogeologic framework of the Espa?ola basin -- Proceedings of the 5th annual Espa?ola basin workshop, Santa Fe, New Mexico, March 7-8, 2006

This report presents abstracts of technical studies that are focused on the hydrogeologic framework of the Espa?ola basin, a major subbasin of the Cenozoic Rio Grande rift. The Rio Grande, Rio Chama, Santa Fe River, and their tributaries carry important surface water in the Espa?ola basin. Sediments and interbedded volcanic rocks fill the Espa?ola basin and form extensive aquifer systems for ground water. Surface and ground water provide the principal sources of water for most residents of the basin, including people in the cities of Santa Fe, Espa?ola, and Los Alamos as well as Native Americans in several Pueblos. The abstracts describe results of technical studies that were presented either as poster exhibits or oral presentations at the fifth-annual Espa?ola basin workshop, held March 7-8 of 2006 in Santa Fe, New Mexico. The principal goal of this workshop was to share information about ongoing studies. The Espa?ola basin workshop was hosted by the Espa?ola basin technical advisory group (EBTAG) and sponsored by the U.S. Geological Survey, the New Mexico Bureau of Geology and Mineral Resources, and the Water Research Technical Assistance Office of Los Alamos National Laboratory. Abstracts in this report have been grouped into six information themes: Basic Water Data, Water Quality and Water Chemistry, Water Balance and Stream/Aquifer Interaction, Data Integration and Hydrologic Model Testing, Three-Dimensional Hydrogeological Architecture, and Geologic Framework. Abstracts submitted by U.S. Geological Survey authors in this report have had their technical content peer reviewed before they were included in the report. Technical reviews were not required for abstracts submitted by authors outside the USGS, although most did receive peer reviews within their originating agencies. Taken together, the abstracts in this report provide a view of the current status of hydrogeologic research within the Espa?ola basin.

Open-File Report↗

Managing conflicts in the River of Grass

Chances are, you would not pack up and move to a new home without first researching the neighborhood, reviewing your finances, and maybe investigating schools nearby. Similarly, you would not buy the first car you find on a magazine cover without first reviewing the technical specifications, exploring your options, and perhaps taking a test drive. Even when making simple purchases online, you probably shop around, check out customer reviews, and scan seller feedback ratings. Rarely do we act on impulse alone when faced with decisions. Rather, we typically start with a vision of what we want before gathering the necessary information, weighing our options, prioritizing our values, and evaluating possible tradeoffs. In making choices that range from lighthearted to life-changing, we use this commonsense strategy every day of our lives. Environmental decision-making is no different. For decades, natural resource managers faced with complicated problems have made decisions by breaking them into smaller components that are easier to approach. And like our day-to day decisions, the process is ideally guided by a shared vision of the future. However, it can become complicated when multiple, seemingly disparate views on what the future should hold emerge. As Lewis Carroll once wrote, “If you don’t know where you are going, any road will get you there.” Divining a vision of the future for the Florida Everglades and making supporting decisions is a complex undertaking. But unlike Alice thrust through the looking glass, we have tools and techniques to help us make sense of it all. The application of tools to help decision-making can move us closer to the successful restoration of this imperiled landscape.

Florida↗

Pentachlorophenol Hazards to Fish, Wildlife, and Invertebrates: A Synoptic Review

Pentachlorophenol (PCP) is now widely used as a wood preservative, and this has contributed to the detection of PCP residues in air, rain, groundwaters, surface waters, fish and aquatic invertebrates, and in human urine, blood, and milk of nursing mothers. This report briefly reviews the technical literature on ecological and toxicological aspects of PCP in the environment, with emphasis on fishery and wildlife resources. Subtopics include sources and uses, chemical properties, fate, background concentrations, lethal and sublethal effects, and current recommendations for resource protection

Contaminant Hazard Reviews↗

Editors' message: Hydrogeology Journal in 2003

Hydrogeology Journal appeared in six issues containing a total of 710 pages and 48 major articles, including 31 Papers and 14 Reports, as well as some Technical Notes and Book Reviews. The number of submitted manuscripts continues to increase. The final issue of 2003 also contained the annual volume index. Hydrogeology Journal ( HJ ) is an international forum for hydrogeology and related disciplines and authors in 2003 were from about 28 countries. Articles advanced hydrogeologic science and described hydrogeologic systems in many regions worldwide. These articles focused on a variety of general topics and on studies of hydrogeology in 24 countries: Afghanistan, Algeria, Argentina, Australia, Bangladesh, Belgium, Canada, Chile, China, Denmark, France, India, Italy, Mexico, Netherlands, New Zealand, Nigeria, Norway, Portugal, Russia, South Africa, Switzerland, Turkey, and U.S.A. The Guest Editor of the 2003 HJ theme issue on “Hydromechanics in Geology and Geotechnics”, Ove Stephansson, assembled a valuable collection of technical reviews and research papers from eminent authors on important aspects of the subject area.

Hydrogeology Journal↗

Proposed attributes of national wildlife health programmes

Wildlife health is important for conservation, healthy ecosystems, sustainable development, and biosecurity. It presents unique challenges for national programme governance and delivery because wildlife health crosses not only jurisdictional responsibilities and authorities but also inherently spans multiple sectors of expertise. The World Organisation for Animal Health (OIE) encourages its Members to have wildlife disease monitoring and notification systems. Where national wildlife health surveillance programmes do exist, they vary in scope and size. Evidence-based guidance is lacking on the critical functions and roles needed to meet the OIE’s recommendations and other expectations of a national programme. A literature review and consultation with national wildlife health programme leaders identified five key attributes of national programmes including: (1) being knowledge and science based; (2) fostering cross-nation equivalence and harmonisation; (3) developing partnerships and national coordination; (4) providing leadership and administration of national efforts and (5) capacity development. Proposed core purposes include: (1) establishing and communication of the national wildlife health status; (2) leading national planning; (3) centralising information and expertise; (4) developing national networks leading to harmonisation and collaborations; (5) developing wildlife health workforces and (6) centralising administration and management of national programmes. A national wildlife health programme should aim to identify, effectively communicate, and manage the risk to or from a country’s wildlife populations. It should generate the appropriate knowledge required to improve the effectiveness of wildlife policies and systems, including identifyinhttp://www.oie.int/en/publications-and-documentation/scientific-and-technical-review-free-access/peer-reviewed-papers-for-the-plurithematic-review-2018/g and assessing emerging priorities, thus increasing warning for preparedness and preventive actions.

Scientific and Technical Review↗

Wetland management practices and secretive marsh bird habitat in the Mississippi Flyway: A review

Management regimes on publicly owned freshwater wetlands in the Mississippi Flyway of North America (i.e., Flyway) have historically emphasized waterfowl, but there is limited information on how waterfowl-focused wetland management affects other wetland-dependent wildlife. Secretive marsh birds (SMBs) depend on wetlands with emergent vegetation throughout their migratory life cycle and often encounter vegetation and water conditions resulting from waterfowl-focused management regimes. Thus, there is a need for better understanding of how SMBs are affected by wetland management and the extent to which waterfowl-focused management regimes provide habitat for SMBs. In this review, we identify the vegetation and water conditions resulting from typical management objectives on freshwater emergent wetlands in the Flyway, review and qualitatively synthesize results from studies that directly evaluate how wetland management practices affect SMBs or their habitat, and assess how the vegetation and water conditions being produced for target species (mainly waterfowl) align with SMB habitat requirements. We searched online databases and used Google Scholar to locate peer-reviewed literature, technical reports, and graduate theses that pertained to responses of SMBs or their habitat to water-level manipulation, herbicide application, prescribed fire, disking, mowing, and planting crops. There are several management strategies that complement SMBs and waterfowl, such as reducing cover of woody species and providing flooded emergent vegetation. We also highlight management strategies that may not currently align with SMB life-cycle needs and suggest adjustments that might promote habitat for SMBs while still achieving waterfowl population objectives. For example, adjusting the dates and duration of spring water-level drawdowns on a portion of wetlands within a larger complex can provide for spring migrating waterfowl and ensure habitat for migrating and nesting SMBs. Ideally, future studies would address how modifications to management practices affect SMBs and monitor potential effects on waterfowl, resulting in a more holistic approach to wetland management.

The Journal of Wildlife Management↗

Interaction of fine sediment with alluvial streambeds

More knowledge is needed about the physical processes that control the transport of fine sediment moving over an alluvial bed. The knowledge is needed to design rational sampling and monitoring programs that assess the transport and fate of toxic substances in surface waters because the toxics are often associated with silt- and clay-sized particles. This technical note reviews some of the past research in areas that may contribute to an increased understanding of the processes involved. An alluvial streambed can have a large capacity to store fine sediments that are extracted from the flow when instream concentrations are high and it can gradually release fine sediment to the flow when the instream concentrations are low. Several types of storage mechanisms are available depending on the relative size distribution of the suspended load and bed material, as well as the flow hydraulics. Alluvial flow tends to segregate the deposited material according to size and density. Some of the storage locations are temporary, but some can store the fine sediment for very long periods of time.

Water Resources Research↗

One Health: A perspective from wildlife and environmental health sectors

Loss of biodiversity, habitat fragmentation and pollution, and subsequent degradation of natural environments threaten the range of ecosystem services that support all life on this planet. These changes, among others, are also driving the emergence of infectious diseases, with negative health outcomes for humans, animals, and our shared environment. Historically, interventions aimed at human and agricultural health issues did not always integrate wildlife or environmental health as part of the solution, which has resulted in unintended consequences. One Health recognises the interdependence of humans, animals and their shared environment, and provides a conceptual framework for developing interventions that optimise outcomes for human, animal and environmental health. However, there is a need to clearly articulate the core values, goals, and objectives of One Health for all relevant sectors in order to maximise synergies for communication, coordination, collaboration, and, ultimately, for joint actions on disease control and prevention. Application of systems and harm reduction approaches, focusing on the socio-economic and environmental determinants of health, and ensuring good governance and effective leadership will also maximise the opportunities to develop ‘win-win-win’ solutions to global health and environmental challenges. These solutions would help propel One Health forward to reach its full potential and truly optimise health outcomes for all.

Scientific and Technical Review↗

Wildlife health surveillance: Gaps, needs and opportunities

Disease emergence represent a global threat for public health, economy, and biological conservation and most of the emerging diseases have zoonotic origin from wildlife. To prevent their spread and to support the implementation of control measures, disease surveillance and reporting systems are needed, and due to globalisation, these activities should be carried at world level. To define the main gaps affecting the performances of wildlife health surveillance and reporting systems at word level, we analysed the Wildlife Disease Surveillance Survey submitted to all Members of World Organisation for Animal Health which inquire on structure and limits of surveillance and reporting systems. The response from 103 Members, covering all world areas, showed that 54.4% of them have a wildlife disease surveillance programme and 66% implemented a strategy to manage their spread. The lack of dedicated budget affected the possibility of outbreak investigations, sampling collection and diagnostic testing. Although most Members maintain records relating to wildlife mortality or morbidity events in centralised databases, data analyses and disease risk assessment are reported as main needs. Our evaluation of surveillance capacity showed an overall low level associated to great variability between Members not restricted to specific geographical area. A better recognition of the value of wildlife disease surveillance resulting in allocation of adequate resources by governments would make wildlife disease surveillance systems more functional. Moreover, the future comprehension of the influence of socio-economic, cultural and biodiversity aspects will be essential to increase better disease surveillance under One Health approach.

Scientific and Technical Review↗

New approaches to wildlife health

Recent environmental change and biodiversity loss have modified ecosystems, altering disease dynamics. For wildlife health, this trend has translated into increased potential for disease transmission and reduced capacity to overcome significant population-level impacts, which may place species at risk of extinction. Thus, current approaches to wildlife health focus not on the absence of disease but rather on the concept of health promotion. That is, wildlife populations will be more resilient to disease if they have the basic requirements for survival, as well as functioning ecosystems, within an enabling socio-economic environment. In this context, animal health programmes must adapt to design and implement wildlife health programmes that bridge knowledge gaps and fully integrate conservation goals. This article proposes new pathways and additions to the animal health management toolbox, including new approaches to surveillance and information management, partnerships and new wildlife health management practices. Solely because of risks to domesticated animals and human health, the traditional approach to disease surveillance in wild animals has now been replaced by a drive to recognise the intrinsic value of wildlife and the extended benefits of actively pursuing ecosystem health and associated life-sustaining ecosystem services. In this context, it is paramount to transition to holistic health programmes that embrace One Health as a pathway to set the health of all on equal footing.

Scientific and Technical Review↗

Methodology and technical input for the 2021 review and revision of the U.S. Critical Minerals List

Pursuant to Section 7002 (“Mineral Security”) of Title VII (“Critical Minerals”) of the Energy Act of 2020 (Public Law 116–260, December 27, 2020, 116th Cong.), the Secretary of the Interior, acting through the Director of the U.S. Geological Survey, is tasked with reviewing and revising the methodology used to evaluate mineral criticality and the U.S. Critical Minerals List no less than every 3 years. The initial Critical Minerals List was published in the Federal Register on May 18, 2018, in response to Executive Order No. 13817, A Federal Strategy to Ensure Secure and Reliable Supplies of Critical Minerals (3 CFR, 2017 Comp, p. 397–399). This report documents the updated evaluation methodology and the resultant updated draft list of minerals recommended for inclusion in the Critical Minerals List.

Open-File Report↗

Acidic Depositions: Effects on Wildlife and Habitats

The phenomenon of 'acid rain' is not new; it was recognized in the mid-1800s in industrialized Europe. In the 1960s a synthesis of information about acidification began in Europe, along with predictions of ecological effects. In the U.S. studies of acidification began in the 1920s. By the late 1970s research efforts in the U.S. and Canada were better coordinated and in 1980 a 10-year research program was undertaken through the National Acid Precipitation Assessment Plan (NAPAP) to determine the causes and consequences of acidic depositions. Much of the bedrock in the northeastern U.S. and Canada contains total alkalinity of <200 ?eq 1-1, thus, it lacks acid-neutralizing capacity. In the U.S. about 5% of the land area and in Canada about 43 % of the land area is sensitive to acidic depositions. Further, these areas receive >20 kg/ha/yr of wet sulphate depositions and are vulnerable to acidifying processes. Acidic depositions contribute directly to acidifying processes of soil and soil water. Soils must have sufficient acid-neutralizing capacity or acidity of soil will increase. Natural soil-forming processes that lead to acidification can be accelerated by acidic depositions. Long-term effects of acidification are predicted, which will reduce soil productivity mainly through reduced availability of nutrients and mobilization of toxic metals. Severe effects may lead to major alteration of soil chemistry, soil biota, and even loss of vegetation. Several species of earthworms and several other taxa of soil-inhabiting invertebrates, which are important food of many vertebrate wildlife species, are affected by low pH in soil. Loss of canopy in declining sugar maples results in loss of insects fed on by certain neotropical migrant bird species. No definitive studies categorically link atmospheric acidic depositions with direct or indirect effects on wild mammals. Researchers have concentrated on vegetative and aquatic effects. Circumstantial evidence suggests that effects are probable for certain species of aquatic-dependent mammals (water shrew, mink, and otter) and that these species are at risk from the loss of foods or contamination of these foods by metals, especially methylmercury. Continued acidification of terrestrial habitats, to the extent that earthworm populations are broadly reduced, might expose some fossorial mammalian species to risk because of decline in their major prey species. Acidic deposition affects primarily aquatic habitats of avian species by disrupting food webs (ecological effects) and increasing amounts of available heavy metals (mercury, aluminum, cadmium) in prey of avian species (toxicological effects). The ecological effects of acidifying wetlands are to reduce acid-intolerant prey (invertebrates) and to change prey quality from high-calcium bearing prey to low-calcium bearing prey. The toxicological effects are to increase contamination by heavy metals, especially methylated mercury, in foods of breeding waterbirds. The combination of these 2 types of effects results in potentially lower survival of adults and reduced production, growth, or survival of young of many bird species. Effects of acidification on herpteofauna and their habitats are mainly reproductive failure of susceptible species and reduced or metal-contaminated foods for both amphibians and reptiles.

Wildlife Society Technical Review↗

Ungulate management in national parks of the United States and Canada

Enabling legislation—that which gives appropriate officials the authority to implement or enforce the law—impacts management of ungulates in national parks of Canada and the United States (U.S.). The initial focus of such legislation in both countries centered on preserving natural and culturally significant areas for posterity. Although this objective remains primary, philosophies and practices have changed. A Canadian vision for ungulate management emerged during the latter half of the 20th century to protect and maintain or restore the ecological integrity of representative samples of the country’s 39 distinct landscapes, and to include provisions for traditional hunting and fishing practices representative of past cultural impacts on the environment. The current ungulate management approach in the U.S. relies on natural (ecological) processes, as long as normal conditions are promoted and there is no impairment of natural resources. Emphasizing natural processes as the basis has been a challenge because ecosystem dynamics are complex and management is multi-jurisdictional. Additionally, natural regulation typically will not prevent ungulates from reaching and sustaining densities that are incompatible with preservation or restoration of native flora and fauna, natural processes, or historical landscapes.

The Wildlife Society Technical Review↗