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Water-soluble organic carbon release from mineral soils and sediments in an irrigated agricultural system

Water interactions with soil and vegetation are greatly altered in agricultural watersheds compared to natural landscapes, which impacts sources and fates of organic carbon (OC). While mineral soil horizons in natural ecosystems primarily act as filters for dissolved organic carbon (DOC) leached from organic surface horizons, tilled soils largely lack an organic horizon and their mineral horizons therefore act as a source for both DOC and sediment to surface waters. Irrigated watersheds highlight this difference, as DOC and total suspended sediment (TSS) concentrations simultaneously increase during the low-discharge irrigation season, suggesting that sediment-associated OC may constitute a significant source of DOC. While water-soluble OC (WSOC) from sediments and soils has been found to be compositionally similar to stream DOC, these contributions remain poorly quantified in agricultural streams. To address this, we conducted abiotic solubilization experiments using sediments (suspended and bed) and soils from an irrigated agricultural watershed in northern California, USA. Sediments (R 2 > 0.99) and soils (0.74 < R 2 < 0.89) displayed linear solubilization behaviors over the range of concentrations tested. Suspended sediment from the irrigation season exhibited the largest solubilization efficiency (10.9 ± 1.6% TOC sediment solubilized) and potential (1.79 ± 0.26 mg WSOC g −1 dry sediment), followed by suspended sediment from a winter storm, then bed sediment and soils. Successive solubilization experiments increased the total release of WSOC by ∼50%, but most (88–97%) of the solid-phase OC remained insoluble in water. Using these solubilization potential estimates and measured TSS concentrations, we estimated that WSOC from suspended sediment in streams represented 4–7% of the annual DOC export from the watershed. However, field sediment export is much higher than what is represented by suspended sediment in the water column, therefore field-scale contributions from sediments could be much higher than estimated.

California

Blind identification of the Millikan Library from earthquake data considering soil–structure interaction

The Robert A. Millikan Library is a reinforced concrete building with a basement level and nine stories above the ground. Located on the campus of California Institute of Technology (Caltech) in Pasadena California, it is among the most densely instrumented buildings in the U.S. From the early dates of its construction, it has been the subject of many investigations, especially regarding soil&ndash;structure interaction effects. It is well accepted that the structure is significantly interacting with the surrounding soil, which implies that the true foundation input motions cannot be directly recorded during earthquakes because of inertial effects. Based on this limitation, input&ndash;output modal identification methods are not applicable to this soil&ndash;structure system. On the other hand, conventional output-only methods are typically based on the unknown input signals to be stationary whitenoise, which is not the case for earthquake excitations. Through the use of recently developed blind identification (i.e. output-only) methods, it has become possible to extract such information from only the response signals because of earthquake excitations. In the present study, we employ such a blind identification method to extract the modal properties of the Millikan Library. We present some modes that have not been identified from force vibration tests in several studies to date. Then, to quantify the contribution of soil&ndash;structure interaction effects, we first create a detailed Finite Element (FE) model using available information about the superstructure; and subsequently update the soil&ndash;foundation system's dynamic stiffnesses at each mode such that the modal properties of the entire soil&ndash;structure system agree well with those obtained via output-only modal identification.

California

Untangling the biological contributions to soil stability in semiarid shrublands

Communities of plants, biological soil crusts (BSCs), and arbuscular mycorrhizal (AM) fungi are known to influence soil stability individually, but their relative contributions, interactions, and combined effects are not well understood, particularly in arid and semiarid ecosystems. In a landscape-scale field study we quantified plant, BSC, and AM fungal communities at 216 locations along a gradient of soil stability levels in southern Utah, USA. We used multivariate modeling to examine the relative influences of plants, BSCs, and AM fungi on surface and subsurface stability in a semiarid shrubland landscape. Models were found to be congruent with the data and explained 35% of the variation in surface stability and 54% of the variation in subsurface stability. The results support several tentative conclusions. While BSCs, plants, and AM fungi all contribute to surface stability, only plants and AM fungi contribute to subsurface stability. In both surface and subsurface models, the strongest contributions to soil stability are made by biological components of the system. Biological soil crust cover was found to have the strongest direct effect on surface soil stability (0.60; controlling for other factors). Surprisingly, AM fungi appeared to influence surface soil stability (0.37), even though they are not generally considered to exist in the top few millimeters of the soil. In the subsurface model, plant cover appeared to have the strongest direct influence on soil stability (0.42); in both models, results indicate that plant cover influences soil stability both directly (controlling for other factors) and indirectly through influences on other organisms. Soil organic matter was not found to have a direct contribution to surface or subsurface stability in this system. The relative influence of AM fungi on soil stability in these semiarid shrublands was similar to that reported for a mesic tallgrass prairie. Estimates of effects that BSCs, plants, and AM fungi have on soil stability in these models are used to suggest the relative amounts of resources that erosion control practitioners should devote to promoting these communities. This study highlights the need for system approaches in combating erosion, soil degradation, and arid-land desertification.

Utah

Does the stress-gradient hypothesis hold water? Disentangling spatial and temporal variation in plant effects on soil moisture in dryland systems

The nature of the relationship between water limitation and facilitation has been one of the most contentious debates surrounding the stress-gradient hypothesis (SGH), which states that plant-plant interactions shift from competition to facilitation with increasing environmental stress. We take a closer look at the potential role of soil moisture in mediating plant-plant interaction outcomes by assessing effects of climate and soil texture on plant modulation of soil moisture. Using an empirically-parameterized soil moisture model, we simulated soil moisture dynamics beneath shrubs and in un-vegetated coarse and fine soils for 1000 sites in the Western United States with <700 mm mean annual precipitation. This threshold reflects the transition from dryland (<600 mm precipitation) to mesic ecosystems. Positive effects of shrubs on shallow soil moisture (i.e. the difference between shrub and interspace soil moisture) decreased along the aridity gradient when long-term average conditions were considered, contrary to expectations based on the SGH. Negative effects of shrubs on deeper soil moisture also increased with aridity. However, when extreme years were considered, positive effects of shrub on soil moisture were greatest at intermediate points along the spatial aridity gradient, consistent with a hump-backed model of plant-plant interactions. When viewed through time within a site, shrub effects on shallow soil moisture were positively related to precipitation, with more complex relationships exhibited in deeper soils Taken together, the results of this simulation study suggest that plant effects on soil moisture are predictable based on relatively general relationships between precipitation inputs and differential evaporation and transpiration rates between plant and interspace microsites that are largely driven by temperature. In particular, this study highlights the importance of differentiating between temporal and spatial variation in weather and climate, respectively, in determining plant effects on available soil moisture. Rather than focusing on the somewhat coarse-scale predictions of the SGH, it may be more beneficial to explicitly incorporate plant effects on soil moisture into predictive models of plant-plant interaction outcomes in drylands.

Functional Ecology

Growth responses of five desert plants as influenced by biological soil crusts from a temperate desert, China

In almost all dryland systems, biological soil crusts (biocrusts) coexist alongside herbaceous and woody vegetation, creating landscape mosaics of vegetated and biocrusted patches. Results from past studies on the interaction between biocrusts and vascular plants have been contradictory. In the Gurbantunggut desert, a large temperate desert in northwestern China, well-developed lichen-dominated crusts dominate the areas at the base and between the sand dunes. We examined the influence of these lichen-dominated biocrusts on the germination, growth, biomass accumulation, and elemental content of five common plants in this desert: two shrubs ( Haloxylon persicum , Ephedra distachya ) and three herbaceous plants ( Ceratocarpus arenarius , Malcolmia africana and Lappula semiglabra ) under greenhouse conditions. The influence of biocrusts on seed germination was species-specific. Biocrusts did not affect percent germination in plants with smooth seeds, but inhibited germination of seeds with appendages that reduced or eliminated contact with the soil surface or prevented seeds from slipping into soil cracks. Once seeds had germinated, biocrusts had different influences on growth of shrub and herbaceous plants. The presence of biocrusts increased concentrations of nitrogen but did not affect phosphorus or potassium in tissue of all tested species, while the uptake of the other tested nutrients was species-specific. Our study showed that biocrusts can serve as a biological filter during seed germination and also can influence growth and elemental uptake. Therefore, they may be an important trigger for determining desert plant diversity and community composition in deserts.

Ecological Research

Wildland fire ash: Production, composition and eco-hydro-geomorphic effects

Fire transforms fuels (i.e. biomass, necromass, soil organic matter) into materials with different chemical and physical properties. One of these materials is ash, which is the particulate residue remaining or deposited on the ground that consists of mineral materials and charred organic components. The quantity and characteristics of ash produced during a wildland fire depend mainly on (1) the total burned fuel (i.e. fuel load), (2) fuel type and (3) its combustion completeness. For a given fuel load and type, a higher combustion completeness will reduce the ash organic carbon content, increasing the relative mineral content, and hence reducing total mass of ash produced. The homogeneity and thickness of the ash layer can vary substantially in space and time and reported average thicknesses range from close to 0 to 50 mm. Ash is a highly mobile material that, after its deposition, may be incorporated into the soil profile, redistributed or removed from a burned site within days or weeks by wind and water erosion to surface depressions, footslopes, streams, lakes, reservoirs and, potentially, into marine deposits. Research on the composition, properties and effects of ash on the burned ecosystem has been conducted on material collected in the field after wildland and prescribed fires as well as on material produced in the laboratory. At low combustion completeness (typically T < 450 °C), ash is organic-rich, with organic carbon as the main component. At high combustion completeness (T > 450 °C), most organic carbon is volatized and the remaining mineral ash has elevated pH when in solution. It is composed mainly of calcium, magnesium, sodium, potassium, silicon and phosphorous in the form of inorganic carbonates, whereas at T > 580 °C the most common forms are oxides. Ash produced under lower combustion completeness is usually darker, coarser, and less dense and has a higher saturated hydraulic conductivity than ash with higher combustion completeness, although physical reactions with CO 2 and when moistened produce further changes in ash characteristics. As a new material present after a wildland fire, ash can have profound effects on ecosystems. It affects biogeochemical cycles, including the C cycle, not only within the burned area, but also globally. Ash incorporated into the soil increases temporarily soil pH and nutrient pools and changes physical properties such as albedo, soil texture and hydraulic properties including water repellency. Ash modifies soil hydrologic behavior by creating a two-layer system: the soil and the ash layer, which can function in different ways depending on (1) ash depth and type, (2) soil type and (3) rainfall characteristics. Key parameters are the ash's water holding capacity, hydraulic conductivity and its potential to clog soil pores. Runoff from burned areas carries soluble nutrients contained in ash, which can lead to problems for potable water supplies. Ash deposition also stimulates soil microbial activity and vegetation growth. Further work is needed to (1) standardize methods for investigating ash and its effects on the ecosystem, (2) characterize ash properties for specific ecosystems and wildland fire types, (3) determine the effects of ash on human and ecosystem health, especially when transported by wind or water, (4) investigate ash's controls on water and soil losses at slope and catchment scales, (5) examine its role in the C cycle, and (6) study its redistribution and fate in the environment.

Earth-Science Reviews

A new model for humic materials and their interactions with hydrophobic organic chemicals in soil-water or sediment-water systems

A generalized model of humic materials in soils and sediments, which is consistent with their observed properties, is presented. This model provides a means of understanding the interaction of hydrophobic pollutants with humic materials. In this model, it is proposed that the humic materials in soils and sediments consist of a number of different oligomers and simple compounds which result from the partial degradation of plant remains. These degradation products are stabilized by incorporation into humic aggregates bound together by weak bonding mechanisms, such as hydrogen bonding, pi bonding, and hydrophobic interactions. The resulting structures are similar to micelles or membranes, in which the interiors of the structures are hydrophobic and the exteriors are hydrophilic. Hydrophobic compounds will partition into the hydrophobic interiors of the humic micelles or "membrane-like" structures. ?? 1986.

Journal of Contaminant Hydrology

Permeability of soils in Mississippi

The permeability of soils in Mississippi was determined and mapped using a geographic information system (GIS). Soil permeabilities in Mississippi were determined to range in value from nearly 0.0 to values exceeding 5.0 inches per hour. The U.S. Soil Conservation Service's State Soil Geographic Data Base (STATSGO) was used as the primary source of data for the determination of area-weighted soil permeability. STATSGO provides soil layer properties that are spatially referenced to mapped areas. These mapped areas are referred to as polygons in the GIS. The polygons arc boundaries of soils mapped as a group and are given unique Map Unit Identifiers (MUIDs). The data describing the physical characteristics of the soils within each polygon are stored in a tabular data base format and are referred to as attributes. The U.S. Soil Conservation Service developed STATSGO to be primarily used as a guide for regional resource planning, management, and monitoring. STATSGO was designed so that soil information could be extracted from properties tables at the layer level, combined by component, and statistically expanded to cover the entire map unit. The results of this study provide a mapped value for permeability which is representative of the vertical permeability of soils in that area. The resultant permeability map provides a representative vertical soil permeability for a given area sufficient for county, multi- county, and area planning, and will be used as the soil permeability data component in the evaluation of the susceptibility of major aquifers to contami- nation in Mississippi.

Water-Resources Investigations Report

Geotechnical soil characterization of intact Quaternary deposits forming the March 22, 2014 SR-530 (Oso) landslide, Snohomish County, Washington

During the late morning of March 22, 2014, a devastating landslide occurred near the town of Oso, Washington. The landslide with an estimated volume of 10.9 million cubic yards (8.3 x 10 6 m 3 ) of both intact glacially deposited and previously disturbed landslide sediments, reached speeds averaging 40 miles per hour (64 kilometers per hour) and crossed the entire 2/3-mile (~1100 m) width of the adjacent North Fork Stillaguamish River floodplain in approximately 60 seconds, resulting in the complete destruction of an entire neighborhood (Iverson and others, 2015). More than 40 homes were destroyed as the debris overran the neighborhood, resulting in the deaths of 43 people. Landslides in glacial deposits are common in the Pacific Northwest (for example, Baum and others, 2008), and in fact, the site of the March 22, 2014 SR-530 landslide had experienced significant reactivation several times in past decades, with the most recent event occurring in 2006 (for example, Miller and Sias, 1998). However, these previous landslides were of considerably less volume and mobility (Iverson and others, 2015), and debris had never reached the Steelhead Haven neighborhood. Further, no landslides with the type of mobility that the March 22, 2014 landslide underwent have been recorded in historic times within the North Fork Stillaguamish River valley. However, mapping performed immediately following the landslide indicates that several other slopes in the North Fork Stillaguamish River valley have experienced large-volume landslides exhibiting high mobility in prehistoric times (Haugerud, 2014). The presence of previous high-mobility landslides in the valley, and the now well-documented occurrence of one involving many fatalities, underscores both the hazard and risk for those that live and travel in this and other river valleys in the Pacific Northwest with similar glacial deposits and precipitation patterns. To understand the hazards posed by highly mobile landslides in the Pacific Northwest, the U.S. Geological Survey (USGS), together with its project partners, the University of California, Berkeley Department of Civil and Environmental Engineering (UCB), and the Washington State Department of Transportation (WSDOT), is undertaking a critically needed study to identify the geologic, hydrogeologic, and geotechnical conditions in which these large landslides initiate, as well as the processes responsible for the exceptional mobility of this, and potentially other, landslides in the region. One of the first study activities involves characterizing the stratigraphy and materials from which the landslide deposits are derived, so that the fundamental geotechnical nature of the soils can be understood. This understanding is required to begin identifying possible conditions leading to slope failure and their relation to the landslide's high mobility. In addition, detailed characterization of each stratigraphic unit encountered in initial geotechnical borings is needed to relate stratigraphy between borings for this study and as a part of ongoing investigations by WSDOT and other project partners. This report provides a description of the methods used to obtain and test the intact soil stratigraphy behind the headscarp of the March 22 landslide. Detailed geotechnical index testing results are presented for 24 soil samples representing the stratigraphy at 19 different depths along a 650 ft (198 m) soil profile. The results include (1) the soil's in situ water content and unit weight (where applicable); (2) specific gravity of soil solids; and (3) each sample's grain-size distribution, critical limits for fine-grain water content states (that is, the Atterberg limits), and official Unified Soil Classification System (USCS) designation. In addition, preliminary stratigraphy and geotechnical relations within and between soil units are presented.

Washington

Measuring the electrical properties of soil using a calibrated ground-coupled GPR system

Traditional methods for estimating vadose zone soil properties using ground penetrating radar (GPR) include measuring travel time, fitting diffraction hyperbolae, and other methods exploiting geometry. Additional processing techniques for estimating soil properties are possible with properly calibrated GPR systems. Such calibration using ground-coupled antennas must account for the effects of the shallow soil on the antenna's response, because changing soil properties result in a changing antenna response. A prototype GPR system using ground-coupled antennas was calibrated using laboratory measurements and numerical simulations of the GPR components. Two methods for estimating subsurface properties that utilize the calibrated response were developed. First, a new nonlinear inversion algorithm to estimate shallow soil properties under ground-coupled antennas was evaluated. Tests with synthetic data showed that the inversion algorithm is well behaved across the allowed range of soil properties. A preliminary field test gave encouraging results, with estimated soil property uncertainties (????) of ??1.9 and ??4.4 mS/m for the relative dielectric permittivity and the electrical conductivity, respectively. Next, a deconvolution method for estimating the properties of subsurface reflectors with known shapes (e.g., pipes or planar interfaces) was developed. This method uses scattering matrices to account for the response of subsurface reflectors. The deconvolution method was evaluated for use with noisy data using synthetic data. Results indicate that the deconvolution method requires reflected waves with a signal/noise ratio of about 10:1 or greater. When applied to field data with a signal/noise ratio of 2:1, the method was able to estimate the reflection coefficient and relative permittivity, but the large uncertainty in this estimate precluded inversion for conductivity. ?? Soil Science Society of America.

Conference Paper

Evaluating the spatial variation of total mercury in young-of-year yellow perch (Perca flavescens), surface water and upland soil for watershed-lake systems within the southern Boreal Shield

The primary objective of this research is to investigate relationships between mercury in upland soil, lake water and fish tissue and explore the cause for the observed spatial variation of THg in age one yellow perch ( Perca flavescens ) for ten lakes within the Superior National Forest. Spatial relationships between yellow perch THg tissue concentration and a total of 45 watershed and water chemistry parameters were evaluated for two separate years: 2005 and 2006. Results show agreement with other studies where watershed area, lake water pH, nutrient levels (specifically dissolved NO 3 − -N) and dissolved iron are important factors controlling and/or predicting fish THg level. Exceeding all was the strong dependence of yellow perch THg level on soil A-horizon THg and, in particular, soil O-horizon THg concentrations (Spearman ρ = 0.81). Soil B-horizon THg concentration was significantly correlated (Pearson r = 0.75) with lake water THg concentration. Lakes surrounded by a greater percentage of shrub wetlands (peatlands) had higher fish tissue THg levels, thus it is highly possible that these wetlands are main locations for mercury methylation. Stepwise regression was used to develop empirical models for the purpose of predicting the spatial variation in yellow perch THg over the studied region. The 2005 regression model demonstrates it is possible to obtain good prediction (up to 60% variance description) of resident yellow perch THg level using upland soil O-horizon THg as the only independent variable. The 2006 model shows even greater prediction ( r 2 = 0.73, with an overall 10 ng/g [tissue, wet weight] margin of error), using lake water dissolved iron and watershed area as the only model independent variables. The developed regression models in this study can help with interpreting THg concentrations in low trophic level fish species for untested lakes of the greater Superior National Forest and surrounding Boreal ecosystem.

Science of the Total Environment

Toxicological significance of soil ingestion by wild and domestic animals

Most wild and domestic animals ingest some soil or sediment, and some species may routinely, or under special circumstances, ingest considerable amounts. Ingested soil supplies nutrients, exposes animals to parasites and pathogens, and may play a role in developing immune systems. 1 Soil ingestion is also sometimes the principal route of exposure to various environmental contaminants. 2-7 Ingestion of soil and earthy material is defined as geophagy and may be either intentional or unintentional, occurring as an animal eats or grooms.

Book chapter

An alternative to soil taxonomy for describing key soil characteristics

We are pleased to see the letter by Schimel and Chadwick (Front Ecol Environ 2013; 11[8]: 405–06), highlighting the importance of soil characterization in ecological and biogeochemical research and explaining the value of soil taxonomy, and we agree with the authors that reporting soil taxonomic classification would greatly increase the interpretive value of many studies. However, in our extensive work with land managers and scientists, we have found that taxonomic classifications are not particularly useful because they are poorly understood. For those unfamiliar with soil taxonomy, deconstructing the meaning of a classification is not a simple task. Furthermore, because the US system of soil taxonomy is not applied universally, its utility as a means for effectively describing soil characteristics to readers in other countries is limited. Finally, and most importantly, even at the finest level of soil classification there are often large within-taxa variations in critical properties that can determine ecosystem responses to drivers such as climate and land-use change.

Frontiers in Ecology and the Environment

Soil CO2 emissions as a proxy for heat and mass flow assessment, Taupō Volcanic Zone, New Zealand

The quantification of heat and mass flow between deep reservoirs and the surface is important for understanding magmatic and hydrothermal systems. Here, we use high-resolution measurement of carbon dioxide flux (φCO 2 ) and heat flow at the surface to characterize the mass (CO 2 and steam) and heat released to the atmosphere from two magma-hydrothermal systems. Our soil gas and heat flow surveys at Rotokawa and White Island in the Taupō Volcanic Zone, New Zealand, include over 3000 direct measurements of φCO 2 and soil temperature and 60 carbon isotopic values on soil gases. Carbon dioxide flux was separated into background and magmatic/hydrothermal populations based on the measured values and isotopic characterization. Total CO 2 emission rates (ΣCO 2 ) of 441 ± 84 t d −1 and 124 ± 18 t d −1 were calculated for Rotokawa (2.9 km 2 ) and for the crater floor at White Island (0.3 km 2 ), respectively. The total CO 2 emissions differ from previously published values by +386 t d −1 at Rotokawa and +25 t d −1 at White Island, demonstrating that earlier research underestimated emissions by 700% (Rotokawa) and 25% (White Island). These differences suggest that soil CO 2 emissions facilitate more robust estimates of the thermal energy and mass flux in geothermal systems than traditional approaches. Combining the magmatic/hydrothermal-sourced CO 2 emission (constrained using stable isotopes) with reservoir H 2 O:CO 2 mass ratios and the enthalpy of evaporation, the surface expression of thermal energy release for the Rotokawa hydrothermal system (226 MW t ) is 10 times greater than the White Island crater floor (22.5 MW t ).

Taupō Volcanic Zone

Soil warming effects on tropical forests with highly weathered soils

The tropics are a region encircling the equator, delineated to the north by the Tropic of Cancer (23°26′14.0″N) and to the south by the Tropic of Capricorn (23°26′14.0″S). While we often think of the tropics as consistently warm and wet throughout the year, in reality, the tropics maintain a myriad of climates. Of the 116 Holdridge life zones (a global bioclimatic classification scheme), the tropics contain more life zones than the sum of all the planet's other geographic regions combined ( Holdridge, 1967 ). In addition to high climatic diversity, the tropics support a wide range of parent materials, landforms, geomorphic characteristics, and soil ages, and maintain all 12 soil types of the USDA soil taxonomy system ( Palm et al., 2007 ; Porder et al., 2007 ; Quesada et al., 2010 ; Richter and Babbar, 1991 ; Sanchez, 1977 ; Soil Survey Staff, 2006 ; Townsend et al., 2008 ). Accordingly, there is no single representative tropical ecosystem. Given the diversity of tropical biomes, this chapter will focus specifically on tropical forested ecosystems and their responses to warming because of their global importance, potential sensitivity to change, and the fact that an improved understanding of how these ecosystems may respond to warmer climate conditions is of significant importance to ecology and society. Furthermore, while generally considering all tropical forest types, emphasis in this chapter is on the humid tropics for which we have most data.

Book chapter

Physical basis and potential estimation techniques for soil erosion parameters in the Precipitation-Runoff Modeling System (PRMS)

Simulation of upland-soil erosion by the Precipitation-Runoff Modeling System currently requires the user to estimate two rainfall detachment parameters and three hydraulic detachmment paramenters. One rainfall detachment parameter can be estimated from rainfall simulator tests. A reformulation of the rainfall detachment equation allows the second parameter to be computed directly. The three hydraulic detachment parameters consist of one exponent and two coefficients. The initial value of the exponent is generally set equal to 1.5. The two coefficients are functions of the soil 's resistance to erosion and one of the two also accounts for sediment delivery processes not simulated in the model. Initial estimates of these parameters can be derived from other modeling studies or from published empirical relations. (USGS)

Water-Resources Investigations Report

Determining the spatial variability of wetland soil bulk density, organic matter, and the conversion factor between organic matter and organic carbon across coastal Louisiana, U.S.A.

Soil bulk density (BD), soil organic matter (SOM) content, and a conversion factor between SOM and soil organic carbon (SOC) are often used in estimating SOC sequestration and storage. Spatial variability in BD, SOM, and the SOM–SOC conversion factor affects the ability to accurately estimate SOC sequestration, storage, and the benefits ( e.g., land building area and vertical accretion) associated with wetland restoration efforts, such as marsh creation and sediment diversions. There are, however, only a few studies that have examined large-scale spatial variability in BD, SOM, and SOM–SOC conversion factors in coastal wetlands. In this study, soil cores, distributed across the entire coastal Louisiana (approximately 14,667 km 2 ) were used to examine the regional-scale spatial variability in BD, SOM, and the SOM–SOC conversion factor. Soil cores for BD and SOM analyses were collected during 2006–09 from 331 spatially well-distributed sites in the Coastwide Reference Monitoring System network. Soil cores for the SOM–SOC conversion factor analysis were collected from 15 sites across coastal Louisiana during 2006–07. Results of a split-plot analysis of variance with incomplete block design indicated that BD and SOM varied significantly at a landscape level, defined by both hydrologic basins and vegetation types. Vertically, BD and SOM varied significantly among different vegetation types. The SOM–SOC conversion factor also varied significantly at the landscape level. This study provides critical information for the assessment of the role of coastal wetlands in large regional carbon budgets and the estimation of carbon credits from coastal restoration.

Louisiana

Engineering-geology site appraisal of the Federal Capital Territory, Nigeria

The 7,700-km 2 -area Federal Capital Territory, Nigeria, is underlain by crystalline igneous and metamorphic rocks of Precambrian age. Sandstone and claystone of Cretaceous age overlie Precambrian rocks in the southwestern part of the Territory. Laterite caps many hills of Cretaceous rock, some hills of Precambrian rock, and crops out near stream banks in the east and northeast. The most conspicuous structural features are a broad “J”-shaped fold traversing the eastern and central part of the Territory and a north-trending shear zone along the eastern boundary. The soils of the Territory are lateritic and belong to the SW-SP-SM (Unified Soil Classification System) groups covering Precambrian migmatites gneisses and granites and the SC group covering Cretaceous sediments and Precambrian mica-rich schists. The average penetrometer shear strength of the soil is 3.11 bars. The engineering characteristics of the rocks are (1) medium- to high-strength massive and gneissic rock, (2) low-to medium-strength bedded rock, and (3) low-strength foliated and sheared rock. An area of at least 800 km 2 is free from apparent geological hazards and should be suitable for construction of a capital city, its environs and supporting facilities.

Bulletin of the International Association of Engin