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At least 55 records · Page 3Linked to original sources

Reflectance spectroscopy for the assessment of soil salt content in soils of the yellow river delta of China

There has been growing interest in the use of reflectance spectroscopy as a rapid and inexpensive tool for soil characterization. In this study, we collected 95 soil samples from the Yellow River Delta of China to investigate the level of soil salinity in relation to soil spectra. Sample plots were selected based on a field investigation and the corresponding soil salinity classification map to maximize variations of saline characteristics in the soil. Spectral reflectances of air-dried soil samples were measured using an Analytical Spectral Device (ASD) spectrometer (350-2500 nm) with an artificial light source. In the Yellow River Delta, the dominant chemical in the saline soil was NaCl and MgCl2. Soil spectra were analysed using two-thirds of the available samples, with the remaining one-third withheld for validation purposes. The analysis indicated that with some preprocessing, the reflectance at 1931-2123 nm and 2153-2254 nm was highly correlated with soil salt content (SSC). In the spectral region of 1931-2123 nm, the correlation R ranged from -0.80 to -0.87. In the region of 2153-2254 nm, the SSC was positively correlated with preprocessed reflectance (0.79-0.88). The preprocessing was done by fitting a convex hull to the reflectance curve and dividing the spectral reflectance by the value of the corresponding convex hull band by band. This process is called continuum removal, and the resulting ratio is called continuum removed reflectance (CR reflectance). However, the SSC did not have a high correlation with the unprocessed reflectance, and the correlation was always negative in the entire spectrum (350-2500 nm) with the strongest negative correlation at 1981 nm (R = -0.63). Moreover, we found a strong correlation (R=0.91) between a soil salinity index (SSI: Constructed using CR reflectance at 2052 nm and 2203 nm) and SSC. We estimated SSC as a function of SSI and SSI' (SSI': Constructed using unprocessed reflectance at 2052 nm and 2203 nm) using univariate regression. Validation of the estimation of SSC was conducted by comparing the estimated SSC with the holdout sample points. The comparison produced an estimated root mean squared error (RMSE) of 0.986 (SSC ranging from 0.06 to 12.30 g kg-1) and R2 of 0.873 for SSC with SSI as independent variable and RMSE of 1.248 and R2 of 0.8 for SSC with SSI' as independent variable. This study showed that a soil salinity index developed for CR reflectance at 2052 nm and 2203 nm on the basis of spectral absorption features of saline soil can be used as a quick and inexpensive method for soil salt-content estimation.

International Journal of Remote Sensing↗

Spatially explicit patterns in a dryland's soil respiration and relationships with climate, whole plant photosynthesis and soil fertility

Arid and semiarid ecosystems play a significant role in regulating global carbon cycling, yet our understanding of the controls over the dominant pathways of dryland CO 2 exchange remains poor. Substantial amounts of dryland soil are not covered by vascular plants and this patchiness in cover has important implications for spatial patterns and controls of carbon cycling. Spatial variation in soil respiration has been attributed to variation in soil moisture, temperature, nutrients and rhizodeposition, while seasonal patterns have been attributed to changes in moisture, temperature and photosynthetic inputs belowground. To characterize how controls over respiration vary spatially and temporally in a dryland ecosystem and to concurrently explore multiple potential controls, we estimated whole plant net photosynthesis (A net ) and soil respiration at four distances from the plant base, as well as corresponding fine root biomass and soil carbon and nitrogen pools, four times during a growing season. To determine if the controls vary between different plant functional types for Colorado Plateau species, measurements were made on the C 4 shrub, Atriplex confertifolia , and C 3 grass, Achnatherum hymenoides . Soil respiration declined throughout the growing season and diminished with distance from the plant base, though variations in both were much smaller than expected. The strongest relationship was between soil respiration and soil moisture. Soil respiration was correlated with whole plant A net , although the relationship varied between species and distance from plant base. In the especially dry year of this study we did not observe any consistent correlations between soil respiration and soil carbon or nitrogen pools. Our findings suggest that abiotic factors, especially soil moisture, strongly regulate the response of soil respiration to biotic factors and soil carbon and nitrogen pools in dryland communities and, at least in dry years, may override expected spatial and seasonal patterns.

Oikos↗

Hydrologic connectivity to streams increases nitrogen and phosphorus inputs and cycling in soils of created and natural floodplain wetlands

Greater connectivity to stream surface water may result in greater inputs of allochthonous nutrients that could stimulate internal nitrogen (N) and phosphorus (P) cycling in natural, restored, and created riparian wetlands. This study investigated the effects of hydrologic connectivity to stream water on soil nutrient fluxes in plots (n = 20) located among four created and two natural freshwater wetlands of varying hydrology in the Piedmont physiographic province of Virginia. Surface water was slightly deeper; hydrologic inputs of sediment, sediment-N, and ammonium were greater; and soil net ammonification, N mineralization, and N turnover were greater in plots with stream water classified as their primary water source compared with plots with precipitation or groundwater as their primary water source. Soil water-filled pore space, inputs of nitrate, and soil net nitrification, P mineralization, and denitrification enzyme activity (DEA) were similar among plots. Soil ammonification, N mineralization, and N turnover rates increased with the loading rate of ammonium to the soil surface. Phosphorus mineralization and ammonification also increased with sedimentation and sediment-N loading rate. Nitrification flux and DEA were positively associated in these wetlands. In conclusion, hydrologic connectivity to stream water increased allochthonous inputs that stimulated soil N and P cycling and that likely led to greater retention of sediment and nutrients in created and natural wetlands. Our findings suggest that wetland creation and restoration projects should be designed to allow connectivity with stream water if the goal is to optimize the function of water quality improvement in a watershed.

Journal of Environmental Quality↗

Remote sensing of soil moisture using airborne hyperspectral data

Landscape assessment of soil moisture is critical to understanding the hydrological cycle at the regional scale and in broad-scale studies of biophysical processes affected by global climate changes in temperature and precipitation. Traditional efforts to measure soil moisture have been principally restricted to in situ measurements, so remote sensing techniques are often employed. Hyperspectral sensors with finer spatial resolution and narrow band widths may offer an alternative to traditional multispectral analysis of soil moisture, particularly in landscapes with high spatial heterogeneity. This preliminary research evaluates the ability of remotely sensed hyperspectral data to quantify soil moisture for the Little River Experimental Watershed (LREW), Georgia. An airborne hyperspectral instrument with a short-wavelength infrared (SWIR) sensor was flown in 2005 and 2007 and the results were correlated to in situ soil moisture values. A significant statistical correlation ( R 2 value above 0.7 for both sampling dates) for the hyperspectral instrument data and the soil moisture probe data at 5.08 cm (2 inches) was determined. While models for the 20.32 cm (8 inches) and 30.48 cm (12 inches) depths were tested, they were not able to estimate soil moisture to the same degree.

GIScience and Remote Sensing↗

Modeling carbon dynamics in vegetation and soil under the impact of soil erosion and deposition

Soil erosion and deposition may play important roles in balancing the global atmospheric carbon budget through their impacts on the net exchange of carbon between terrestrial ecosystem and the atmosphere. Few models and studies have been designed to assess these impacts. In this study, we developed a general ecosystem model, Erosion-Deposition-Carbon-Model (EDCM), to dynamically simulate the influences of rainfall-induced soil erosion and deposition on soil organic carbon (SOC) dynamics in soil profiles. EDCM was applied to several landscape positions in the Nelson Farm watershed in Mississippi, including ridge top (without erosion or deposition), eroding hillslopes, and depositional sites that had been converted from native forests to croplands in 1870. Erosion reduced the SOC storage at the eroding sites and deposition increased the SOC storage at the depositional areas compared with the site without erosion or deposition. Results indicated that soils were consistently carbon sources to the atmosphere at all landscape positions from 1870 to 1950, with lowest source strength at the eroding sites (13 to 24 gC m-2 yr-1), intermediate at the ridge top (34 gC m-2 yr-1), and highest at the depositional sites (42 to 49 gC m-2 yr-1). During this period, erosion reduced carbon emissions via dynamically replacing surface soil with subsurface soil that had lower SOC contents (quantity change) and higher passive SOC fractions (quality change). Soils at all landscape positions became carbon sinks from 1950 to 1997 due to changes in management practices (e.g., intensification of fertilization and crop genetic improvement). The sink strengths were highest at the eroding sites (42 to 44 gC m-2 yr-1 , intermediate at the ridge top (35 gC m-2 yr-1), and lowest at the depositional sites (26 to 29 gC m-2 yr-1). During this period, erosion enhanced carbon uptake at the eroding sites by continuously taking away a fraction of SOC that can be replenished with enhanced plant residue input. Overall, soil erosion and deposition reduced CO2 emissions from the soil into the atmosphere by exposing low carbon-bearing soil at eroding sites and by burying SOC at depositional sites. The results suggest that failing to account for the impact of soil erosion and deposition may potentially contribute to an overestimation of both the total historical carbon released from soils owing to land use change and the contemporary carbon sequestration rates at the eroding sites.

Global Biogeochemical Cycles↗

Hydrologic characterization of desert soils with varying degrees of pedogenesis: 1. field experiments evaluating plant-relevant soil water behavior

To assess the eff ect of pedogenesis on the soil moisture dynamics infl uencing the character and quality of ecological habitat, we conducted infi ltration and redistribution experiments on three alluvial deposits in the Mojave National Preserve: (i) recently deposited active wash sediments, (ii) a soil of early Holocene age, and (iii) a highly developed soil of late Pleistocene age. At each, we ponded water in a 1-m-diameter infi ltration ring for 2.3 h and monitored soil water content and matric pressure during and atier infi ltration, using probes and electrical resistivity imaging (ERI). Infi ltration and downward fl ow rates were greater in younger material, favoring deep-rooted species. Deep-rooted species tend to colonize the margins of washes, where they are unaff ected by sediment transport that inhibits colonization. The ERI results support important generalizations, for example that shallower than 0.5 m, infi ltrated water persists longer in highly developed soil, favoring shallow-rooted species. Soil moisture data for the two youngest soils suggested that saturation overshoot, which may have signifi cant but unexplored hydroecologic and pedogenic eff ects, occurred at the horizontally advancing weting front. Spatial heterogeneity of soil properties generally increased with pedogenic development. Evidence suggested that some early-stage developmental processes may promote uniformity; the intermediate- age soil appeared to have the least heterogeneity in terms of textural variation with depth, and also the least anisotropy. Lateral heterogeneity was pronounced in older soil, having a multitude of eff ects on the distribution and retention of soil water, and may facilitate certain water-conserving strategies of plants over what would be possible in a laterally homogeneous soil. ?? Soil Science Society of America.

California↗

Assessment of hyporheic zone, flood-plain, soil-gas, soil, and surface-water contamination at the Old Incinerator Area, Fort Gordon, Georgia, 2009-2010

The U.S. Geological Survey, in cooperation with the U.S. Department of the Army Environmental and Natural Resources Management Office of the U.S. Army Signal Center and Fort Gordon, Georgia, assessed the hyporheic zone, flood plain, soil gas, soil, and surface-water for contaminants at the Old Incinerator Area at Fort Gordon, from October 2009 to September 2010. The assessment included the detection of organic contaminants in the hyporheic zone, flood plain, soil gas, and surface water. In addition, the organic contaminant assessment included the analysis of explosives and chemical agents in selected areas. Inorganic contaminants were assessed in soil and surface-water samples. The assessment was conducted to provide environmental contamination data to the U.S. Army at Fort Gordon pursuant to requirements of the Resource Conservation and Recovery Act Part B Hazardous Waste Permit process. Total petroleum hydrocarbons were detected above the method detection level in all 13 samplers deployed in the hyporheic zone and flood plain of an unnamed tributary to Spirit Creek. The combined concentrations of benzene, toluene, ethylbenzene, and total xylene were detected at 3 of the 13 samplers. Other organic compounds detected in one sampler included octane and trichloroethylene. In the passive soil-gas survey, 28 of the 60 samplers detected total petroleum hydrocarbons above the method detection level. Additionally, 11 of the 60 samplers detected the combined masses of benzene, toluene, ethylbenzene, and total xylene above the method detection level. Other compounds detected above the method detection level in the passive soil-gas survey included octane, trimethylbenzene, perchlorethylene, and chloroform. Subsequent to the passive soil-gas survey, six areas determined to have relatively high contaminant mass were selected, and soil-gas samplers were deployed, collected, and analyzed for explosives and chemical agents. No explosives or chemical agents were detected above their method detection levels, but those that were detected were above the nondetection level. The same six locations that were sampled for explosives and chemical agents were selected for the collection of soil samples. No metals that exceeded the Regional Screening Levels for Industrial Soils as classified by the U.S. Environmental Protection Agency were detected at any of the six Old Incinerator Area locations. The soil samples also were compared to values from the ambient, uncontaminated (background) levels for soils in South Carolina. Because South Carolina is adjacent to Georgia and the soils in the coastal plain are similar, these comparisons are valid. No similar values are available for Georgia to use for comparison purposes. The only metal detected above the ambient background levels for South Carolina was barium. A surface-water sample collected from a tributary west and north of the Old Incinerator Area was analyzed for volatile organic compounds, semivolatile organic compounds, and inorganic compounds (metals). The only volatile organic and (or) semivolatile organic compound that was detected above the laboratory reporting level was toluene. The compounds 4-isopropyl-1-methylbenzene and isophorone were detected above the nondetection level but below the laboratory reporting level and were estimated. These compounds were detected at levels below the maximum contaminant levels set by the U.S. Environmental Protection Agency National Primary Drinking Water Standard. Iron was the only inorganic compound detected in the surface-water sample that exceeded the maximum contaminant level set by the U.S. Environmental Protection Agency National Secondary Drinking Water Standard. No other inorganic compounds exceeded the maximum contaminant levels for the U.S. Environmental Protection Agency National Primary Drinking Water Standard, National Secondary Drinking Water Standard, or the Georgia In-Stream Water Quality Standard.

Georgia↗

Geochemical variability of natural soils and reclaimed mine-spoil soils in the San Juan Basin, New Mexico

An inventory of total-and extractable-element concentrations in soils was made for three areas of the San Juan Basin in New Mexico: (1) the broad area likely to be affected by energy-related development. (2) an area of soils considered to have potential for use as topsoil in mined-land reclamation. and (3) an area of the San Juan coal mine that has been regraded. topsoiled, and revegetated. Maps made of concentrations of 16 elements in area 1 soils show no gradational pattern across the region. Further. these maps do not correspond to those showing geology or soil types. Sodic or saline problems, and a possible but unproven deficiency of zinc available to plants. may make some of the soils in this area undesirable for use as topsoil in mined-land reclamation. Taxonomic great groups of soil in this area cannot be distinguished because each great group tends to have a large within-group variability if compared to the between-group variability. In area 2 the major soils sampled were of the Sheppard. Shiprock. and Doak association. These soils are quite uniform in chemical composition and are not greatly saline or sodic. As in area 1 soils. zinc deficiency may cause a problem in revegetating most of these soils. It is difficult to distinguish soil taxonomic families by using their respective chemical compositions. because of small between-family variability. Topsoil from a reclaimed area of the San Juan mine (area 3) most closely resembles the chemical composition of natural C horizons of soil from area 1. Spoil material that has not been topsoiled is likely to cause sodic-and saline-related problems in revegetation and may cause boron toxicity in plants. Topsoiling has apparently ameliorated these potential problems for plant growth on mine spoil. Total and extractable concentrations for elements and other parameters for each area of the San Juan Basin provide background information for the evaluation of the chemical quality of soils in each area.

New Mexico↗

Water-balance techniques for determining available soil-water storage for selected sandy and clay soil study sites in Cass County, North Dakota, 2016–17

The U.S. Geological Survey, in cooperation with the U.S. Department of Agriculture Natural Resources Conservation Service, collected field and remotely sensed data on precipitation, evapotranspiration (ET), and soil-water content to determine available soil-water storage (AWS) at six study sites on sandy and clay soils in Cass County, North Dakota. Data were collected at all the study sites from May 1–October 31, 2016, and from May 1–October 24, 2017. Estimated daily AWS was determined using daily meteorological and potential evapotranspiration (PET) data obtained from various climate stations, and estimated monthly AWS was determined using monthly meteorological and PET data and monthly ET data determined using the Operational Simplified Surface Energy Balance model. AWS during 2016 and 2017 was determined at daily and monthly time steps because of data availability and to assess results using varying time steps. Comparisons of measured and estimated daily values of AWS at the Brewer Lake site indicated poor agreement during May–October 2016 and May–October 2017. Comparisons of measured and estimated daily values of AWS at the Embden East and Embden West sites indicated poor and fair agreement respectively. At the Lynchburg Crop and Lynchburg Grass sites, comparisons of measured and estimated daily values of AWS indicated fair and good relations, respectively, even with the possible effects of soil cracks. Mean estimated values of daily runoff plus soil percolation for the four sandy soil sites indicated that a maximum of about 19 percent of the estimated runoff plus soil percolation could be considered runoff and that the remaining 81 percent could be considered soil percolation, and for the two clay soil sites about 13 percent of the runoff plus soil percolation could have been considered runoff and about 87 percent could have been considered soil percolation. Results indicated little difference between using monthly PET or monthly ET in water-balance equations to estimate monthly AWS for the grouped sandy soil sites, and only slightly better results were obtained using monthly PET than monthly ET to estimate monthly AWS for the grouped clay soil study sites. Overall, the monthly water-balance models did not perform as well as the daily water-balance models for determining AWS at the six study sites. Additional data collection from a longer-period study and adjustments to the models may improve results from the monthly water-balance techniques.

North Dakota↗

Simulation of branched serial first-order decay of atrazine and metabolites in adapted and nonadapted soils

In the present study a branched serial first-order decay (BSFOD) model is presented and used to derive transformation rates describing the decay of a common herbicide, atrazine, and its metabolites observed in unsaturated soils adapted to previous atrazine applications and in soils with no history of atrazine applications. Calibration of BSFOD models for soils throughout the country can reduce the uncertainty, relative to that of traditional models, in predicting the fate and transport of pesticides and their metabolites and thus support improved agricultural management schemes for reducing threats to the environment. Results from application of the BSFOD model to better understand the degradation of atrazine supports two previously reported conclusions: atrazine (6-chloro- N -ethyl- N ′-(1-methylethyl)-1,3,5-triazine-2,4-diamine) and its primary metabolites are less persistent in adapted soils than in nonadapted soils; and hydroxyatrazine was the dominant primary metabolite in most of the soils tested. In addition, a method to simulate BSFOD in a one-dimensional solute-transport unsaturated zone model is also presented.

Environmental Toxicology and Chemistry↗

Soil mechanics and soil physics symbols and nomenclature useful in hydrologic studies

The study of hydrology requires an interdisciplinary approach, incorporating knowledge from fields such as engineering, geology, chemistry, and agriculture. With increasing frequency, the hydrologist finds it necessary to study the literature of the soil mechanics and soil physics disciplines for assistance in the solution of hydrologic problems. Because of the inter-relation between hydrology and soil mechanics and soil physics, hydrologists also are preparing an increasing number of technical papers ·for use by these two disciplines. To permit the hydrologist to better understand specialized literature, as well as to assist him in preparing papers for these disciplines, this glossary of soil mechanics and soil physics nomenclature was prepared. It is a compilation from standards, dictionaries, and glossaries published by technical societies, and from reports by selected authorities in the fields of soil mechanics and soil physics. The variety of symbols and definitions presented for many of the terms demonstrates the difficulty that has been encountered over the years in reaching agreement on such a subject as nomenclature. Both old and new definitions and symbols are presented to assist the hydrologist in reading literature. Whenever possible the more recent symbols and nomenclature should be used by the hydrologist in writing papers for soil mechanics or soil physics audiences. When the hydrologist finds it necessary to use symbols or terms not included in the present list, he should try to select those not in conflict with the recent systems presented in this report. Symbols are listed in alphabetical order to assist readers in finding the term represented by a given symbol. Terms also are listed alphabetically, usually followed by recommended symbols and brief definitions. Where two or more symbols or definitions are listed following a term, no significance should be placed on the order of presentation. The source is indicated for each symbol, term, or definition, and the sources are listed in the cited references. It is emphasized that this report is only a compilation of nomenclature generally accepted in the soil mechanics apd soil physics disciplines. It does not necessarily represent the recommendations or usage of such nomenclature by the Geological Survey or any part of its organization.

Open-File Report↗

Assessment of groundwater, soil-gas, and soil contamination at the Vietnam Armor Training Facility, Fort Gordon, Georgia, 2009-2010

The U.S. Geological Survey, in cooperation with the U.S. Department of the Army Environmental and Natural Resources Management Office of the U.S. Army Signal Center and Fort Gordon, Georgia, assessed the groundwater, soil gas, and soil for contaminants at the Vietnam Armor Training Facility (VATF) at Fort Gordon, from October 2009 to September 2010. The assessment included the detection of organic compounds in the groundwater and soil gas, and inorganic compounds in the soil. In addition, organic contaminant assessment included organic compounds classified as explosives and chemical agents in selected areas. The assessment was conducted to provide environmental contamination data to the U.S. Army at Fort Gordon pursuant to requirements of the Resource Conservation and Recovery Act Part B Hazardous Waste Permit process. Four passive samplers were deployed in groundwater wells at the VATF in Fort Gordon. Total petroleum hydrocarbons were detected above the method detection level at all four wells. The only other volatile organic compounds detected above their method detection level were undecane and pentadecane, which were detected in two of the four wells sampled. Soil-gas samplers were deployed at 72 locations in a grid pattern across the VATF. Total petroleum hydrocarbons were detected in 71 of the 72 samplers (one sampler was destroyed in the field and not analyzed) at levels above the method detection level, and the combined mass of benzene, toluene, ethylbenzene, and total xylene was detected above the detection level in 31 of the 71 samplers that were analyzed. Other volatile organic compounds detected above their respective method detection levels were naphthalene, 2-methyl-naphthalene, tridecane, 1,2,4-trimethylbenzene, and perchloroethene. Subsequent to the soil-gas survey, four areas determined to have elevated contaminant mass were selected and sampled for explosives and chemical agents. No detections of explosives or chemical agents above their respective method detection levels were found at any of the sampling locations. The same four locations that were sampled for explosives and chemical agents were selected for the collection of soil samples. A fifth location also was selected on the basis of the elevated contaminant mass of the soil-gas survey. No metals that exceeded the Regional Screening Levels for Industrial Soils as classified by the U.S. Environmental Protection Agency were detected at any of the five VATF locations. The soil samples also were compared to values from the ambient, uncontaminated (background) levels for soils in South Carolina, as classified by the South Carolina Department of Health and Environmental Control. Because South Carolina is adjacent to Georgia and the soils in the coastal plain are similar, these comparisons are valid. No similar values are available for Georgia to use for comparison purposes. The metals that were detected above the ambient background levels for South Carolina, as classified by the South Carolina Department of Health and Environmental Control, include aluminum, arsenic, barium, beryllium, calcium, chromium, copper, iron, lead, magnesium, manganese, nickel, potassium, sodium, and zinc.

Georgia↗

Soil bacterial and fungal community responses to nitrogen addition across soil depth and microhabitat in an arid shrubland

Arid shrublands are stressful environments, typified by alkaline soils low in organic matter, with biologically-limiting extremes in water availability, temperature, and UV radiation. The widely-spaced plants and interspace biological soil crusts in these regions provide soil nutrients in a localized fashion, creating a mosaic pattern of plant- or crust-associated microhabitats with distinct nutrient composition. With sporadic and limited rainfall, nutrients are primarily retained in the shallow surface soil, patterning biological activity. We examined soil bacterial and fungal community responses to simulated nitrogen (N) deposition in an arid Larrea tridentata - Ambrosia dumosa field experiment in southern Nevada, USA, using high-throughput sequencing of ribosomal RNA genes. To examine potential interactions among the N application, microhabitat and soil depth, we sampled soils associated with shrub canopies and interspace biological crusts at two soil depths (0–0.5 or 0–10 cm) across the N-amendment gradient (0, 7, and 15 kg ha −1 yr −1 ). We hypothesized that localized compositional differences in soil microbiota would constrain the impacts of N addition to a microhabitat distribution that would reflect highly localized geochemical conditions and microbial community composition. The richness and community composition of both bacterial and fungal communities differed significantly by microhabitat and with soil depth in each microhabitat. Only bacterial communities exhibited significant responses to the N addition. Community composition correlated with microhabitat and depth differences in soil geochemical features. Given the distinct roles of soil bacteria and fungi in major nutrient cycles, the resilience of fungi and sensitivity of bacteria to N amendments suggests that increased N input predicted for many arid ecosystems could shift nutrient cycling toward pathways driven primarily by fungal communities.

Frontiers in Microbiology↗

Use of soil leachates to define the extent of brine-contaminated soils at the USGS petroleum environmental research site "B", Osage County, northeastern Oklahoma

Soils at an active oil production site with a history of surface releases of produced water were investigated to determine the chemical signature of salt contamination and the spatial distribution of soil salinity in relation to areas of obvious salt scarring. Grab samples of shallow soil (0-15 cm) and selected soil profiles to depths of 0.6 to 1.7 m were collected onsite and offsite using a 5-cm diameter stainless steel soil auger. Air dried and disaggregated soil from 15 cm intervals (100 g) was mixed with 100 ml of distilled-deionized water to dissolve readily soluble salts. After 24 hours the water was separated by centrifugation followed by filtration through a 0.45 micrometer membrane. Specific conductance was measured immediately. Dissolved chloride (Cl) and sulfate (SO4) were initially estimated with Cl titration strips and turbidimetric measurements respectively. More accurate measurements of dissolved Cl, SO4, and bromide (Br) were later performed by ion chromatography. Brine-contaminated soil was indicated by (1) unusually elevated Cl concentrations or relatively low ratios of conductance/Cl in aqueous leachates compared to leachates of uncontaminated soils, and (2) ratios of Cl/Br in leachates (250± 30) that fall within the range of Cl/Br ratios measured in local produced waters (220-320). Leachates of background soils from the area were characterized by low conductance (sandy soils) or dissolved solids dominated by sulfates (shaley soils). At the study site, the surface (0-15 cm) distribution of elevated soil salinity was largely confined to areas of obvious salt scarring. Within the area of salt scars, elevated salinity persisted to depths of refusal by manual augering. The technique will be applied to deeper samples obtained by mechanical augering or direct push techniques.

Oklahoma↗

Performance of Bromus tectorum L. in relation to soil properties, water additions, and chemical amendments in calcareous soils of southeastern Utah, USA

In drylands of southeastern Utah, USA, the invasive exotic grass Bromus tectorum L. occurs in distinct spatial patterns suggesting soil control of ecosystem susceptibility to invasion. To improve our understanding of these patterns, we examined performance of B. tectorum in relation to additions of water, KCl, MgO, and CaO at seventeen 1600 m 2 sites distributed across a calcareous soil gradient in Canyonlands National Park. Water additions resulted in a 57% increase in B. tectorum establishment. Fall establishment was significantly correlated with silt and clay content in wet plots but not in dry plots, suggesting that texture effects on B. tectorum establishment patterns may be greater in wet years than in dry years. Applications of MgO resulted in a 49% decrease in B. tectorum establishment, although MgO had no effect on whole-plot biomass at the end of the growing season. B. tectorum –soil relations were strongest during winter (December–March) when relative growth rates were negatively related to soil acid-neutralizing potential, sand and CaCO 3 content, and a measure of bioavailable Mg; and positively related to silt and clay content, total N, measures of bioavailable Mn, P, and K, and a measure of magnetite indicating distributional patterns of eolian dust. As soils were persistently moist during this period, we attribute strong B. tectorum –soil patterns in winter to effects of low temperature on diffusion, microbial activity, and/or production of root exudates important for nutrient mobilization and uptake. In spring, there was a reversal in B. tectorum –soil relations such that loamy soils with higher B. tectorum densities were unfavorable for growth relative to sandy soils with higher warm-season water potentials. We conclude that resource limitations for B. tectorum in this study area shift seasonally, from water limitation of fall establishment, to nutrient limitation of winter growth, and back to water limitation of spring growth. Because study sites generally were arrayed along a hillslope gradient with downslope trends in soil vtexture and nutrient content, close B. tectorum –soil relations documented in this study indicate that a geomorphic framework is useful for understanding and predicting B. tectorum invasion patterns in dryland ecosystems of this region.

Utah↗

Influence of management history and landscape variables on soil organic carbon and soil redistribution

Controlled studies to investigate the interaction between crop growth, soil properties, hydrology, and management practices are common in agronomy. These sites (much as with real world farmland) often have complex management histories and topographic variability that must be considered. In 1993 an interdisiplinary study was started for a 20-ha site in Beltsville, MD. Soil cores (271) were collected in 1999 in a 30-m grid (with 5-m nesting) and analyzed as part of the site characterization. Soil organic carbon (SOC) and 137Cesium (137Cs) were measured. Analysis of aerial photography from 1992 and of farm management records revealed that part of the site had been maintained as a swine pasture and the other portion as cropped land. Soil properties, particularly soil redistribution and SOC, show large differences in mean values between the two areas. Mass C is 0.8 kg m -2 greater in the pasture area than in the cropped portion. The pasture area is primarily a deposition site, whereas the crop area is dominated by erosion. Management influence is suggested, but topographic variability confounds interpretation. Soil organic carbon is spatially structured, with a regionalized variable of 120 m. 137Cs activity lacks spatial structure, suggesting disturbance of the profile by animal activity and past structures such as swine shelters and roads. Neither SOC nor 137Cs were strongly correlated to terrain parameters, crop yields, or a seasonal soil moisture index predicted from crop yields. SOC and 137Cs were weakly correlated (r2 ???0.2, F-test P-value 0.001), suggesting that soil transport controls, in part, SOC distribution. The study illustrates the importance of past site history when interpreting the landscape distribution of soil properties, especially those strongly influenced by human activity. Confounding variables, complex soil hydrology, and incomplete documentation of land use history make definitive interpretations of the processes behind the spatial distributions difficult. Such complexity may limit the accuracy of scaling approaches to mapping SOC and soil redistribution.

Soil Science↗

Some statistical relationships between stream sediment and soil geochemistry in northwestern Wisconsin - can stream sediment compositions be used to predict compositions of soils in glaciated terranes?

Mean stream sediment chemical compositions from northwestern Wisconsin in the north central United States, based on more than 800 samples, differ significantly from mean A-horizon and C-horizon soil compositions, based on about 380 samples of each horizon. Differences by a factor greater than 1.5 exist for some elements (Ca, Mn, Mg, P, Ti, Ni, Pb, Se, Zn). A very large database of stream sediment geochemistry exists for the region (more than 2200 samples) and for the U.S. (roughly 400,000 samples), whereas data on the chemistry of soils is much sparser both regionally and nationally. Therefore, we have attempted to quantify trends in compositional differences between stream sediments and nearby soils to test whether the abundant stream sediment data can be used to predict soil compositions. A simple computational technique of adjusting the stream sediment compositions according to the ratio of means of soils and stream sediments was conducted. A variety of techniques of correction and interpolation of data were tested and indicate that repetitive testing of results allows an optimum correction to be achieved. Predicted soil compositions compared to analytically determined soil compositions show a range of results from relatively good correspondence for some elements to rather poor correspondence for others. In general, predictions are best at midranges of compositions. The technique does not predict well more extreme or anomalous values. Thus, this technique appears to be useful for estimating background soil compositions and delineating regional compositional trends in soils in situations where large amounts of stream sediment analyses and smaller amounts of soil analyses are available. The technique also provides probabilistic qualifications on the expected error between predicted and actual soil compositions so that individual users can judge if the technique provides data of sufficient accuracy for specific needs. ?? 2003 Elsevier B.V. All rights reserved.

Journal of Geochemical Exploration↗

The relationship between soil heterotrophic activity, soil dissolved organic carbon (DOC) leachate, and catchment-scale DOC export in headwater catchments

Dissolved organic carbon (DOC) from terrestrial sources forms the major component of the annual carbon budget in many headwater streams. In high-elevation catchments in the Rocky Mountains, DOC originates in the upper soil horizons and is flushed to the stream primarily during spring snowmelt. To identify controls on the size of the mobile soil DOC pool available to be transported during the annual melt event, we measured soil DOC production across a range of vegetation communities and soil types together with catchment DOC export in paired watersheds in Summit County, Colorado. Both surface water DOC concentrations and watershed DOC export were lower in areas where pyrite weathering resulted in lower soil p H. Similarly, the amount of DOC leached from organic soils was significantly smaller ( p < 0.01) at sites having low soil p H. Scaling point source measurements of DOC production and leaching to the two basins and assuming only vegetated areas contribute to DOC production, we calculated that the amount of mobile DOC available to be leached to surface water during melt was 20.3 g C m −2 in the circumneutral basin and 17.8 g C m −2 in the catchment characterized by pyrite weathering. The significant ( r 2 =0.91 and p < 0.05), linear relationship between over-winter CO 2 flux and the amount of DOC leached from upper soil horizons during snowmelt suggests that the mechanism for the difference in production of mobile DOC was heterotrophic processing of soil carbon in snow-covered soil. Furthermore, this strong relationship between over-winter heterotrophic activity and the size of the mobile DOC pool present in a range of soil and vegetation types provides a likely mechanism for explaining the interannual variability of DOC export observed in high-elevation catchments.

Water Resources Research↗