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Evaluation of simple geochemical indicators of aeolian sand provenance: Late Quaternary dune fields of North America revisited

Dune fields of Quaternary age occupy large areas of the world's arid and semiarid regions. Despite this, there has been surprisingly little work done on understanding dune sediment provenance, in part because many techniques are time-consuming, prone to operator error, experimental, highly specialized, expensive, or require sophisticated instrumentation. Provenance of dune sand using K/Rb and K/Ba values in K-feldspar in aeolian sands of the arid and semiarid regions of North America is tested here. Results indicate that K/Rb and K/Ba can distinguish different river sands that are sediment sources for dunes and dune fields themselves have distinctive K/Rb and K/Ba compositions. Over the Basin and Range and Great Plains regions of North America, the hypothesized sediment sources of dune fields are reviewed and assessed using K/Rb and K/Ba values in dune sands and in hypothesized source sediments. In some cases, the origins of dunes assessed in this manner are consistent with previous studies and in others, dune fields are found to have a more complex origin than previously thought. Use of K/Rb and K/Ba for provenance studies is a robust method that is inexpensive, rapid, and highly reproducible. It exploits one of the most common minerals found in dune sand, K-feldspar. The method avoids the problem of using simple concentrations of key elements that may be subject to interpretative bias due to changes in mineralogical maturity of Quaternary dune fields that occur over time.

Quaternary Science Reviews

Recommended nomenclature for zeolite minerals: Report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names

This report embodies recommendations on zeolite nomenclature approved by the International Mineralogical Association Commission on New Minerals and Mineral Names. In a working definition of a zeolite mineral used for this review, structures containing an interrupted containing an interrupted framework of tetrahedra are accepted where other zeolitic properties prevail, and complete substitution by elements other than Si and Al is alloowed. Separate species are recognized in topologically distinctive compositional series in which different extra-framework cations are the most abundant in atomic proportions. To name these, the appropriate chemical symbol is attached by a hyphen to the series name as a suffix, except for the names harmotome, pollucite and wairakite in the phillipsite and analcime series. Differences in space-group symmetry and in order-disorder relationships in zeolites having the same topologically distinctive framework do not in general provide adequate grounds for recognition of separate species. Zeolite species are not to be distinguished solely in Si:Al ratio except for heulandite (Si:Al < 4.0) and clinoptilolite (Si:Al ??? 4.0). Dehydration, partial hydration and over-hydration are not sufficient grounds for the recognition of separate species of zeolites. Use of the term 'ideal formula' should be avoided in referring to a simplified or averaged formula of zeolite. Newly recognized species in compositional series are as follows: brewsterite-Sr, -Ba; chabazite-Ca, -Na, -K; clinoptilolite-K, -Na, -Ca; dechiardite-Ca, -Na; erionite-Na, -K, -Ca,; faujasite-Na, -Ca, -Mg; ferrierite-Mg, -K, -Na; gmelinite-Na, -Ca, -K; heulandite-Ca, -Na, -K, -Sr; levyne-Ca, -Na; paulingite-K, -Ca; phillipsite-Na, -Ca, -K stilbite-Ca, -Na. Key references, type locality, origin of name, chemical data, IZA structure-type symbols, space-group symmetry, unit-cell dimensions, and comments on structure are listed for 13 compositional series, 82 accepted zeolite mineral species, and three of doubtful status. Herschelite, leonhardite, svetlozarite and wellsite are discredited as mineral species names. Obsolete and discredited names are listed.

European Journal of Mineralogy

Recommended nomenclature for zeolite minerals: report of the subcommittee on zeolites of the International Mineralogical Association, Commission on new Minerals and Mineral names

This report embodies recommendations on zeolite nomenclature approved by the International Mineralogical Association, Commission on New Minerals and Mineral Names. In a working definition of a zeolite mineral used for this review, structures containing an interrupted framework of tetrahedra are accepted where other zeolitic properties prevail, and complete substitution by elements other than Si and Al is allowed. Separate species are recognized in topologically distinctive compositional series in which different extra-framework cations are the most abundant in atomic proportions. To name these, the appropriate chemicalsymbol is attached by a hyphen to the series name as a suffix, except for the names harmotome, pollucite and wairakite in the phillipsite and analcime series. Differences in space-group symmetry and in order-disorder relationships in zeolites having the same topologically distinctive framework do not in general provide adequate grounds for recognition of separate species. Zeolite species are not to be distinguished solely on the ratio Si:Al except for heulandite (Si:Al < 4.0) and clinoptilolite (Si:Al ??? 4.0). Dehydration, partial hydration, and overhydration are not sufficient grounds for the recognition of separate species of zeolites. Use of the term 'ideal formula' should be avoided in referring to a simplified or averaged formula of a zeolite. newly recognized species in compositional series are as follows: brewsterite-Sr, -Ba, chabazite-Ca, -Na, -K, clinoptilolite-K, -Na, -Ca, dachiardite-Ca, -Na, erionite-Na, erionite-Na, -K, -Ca, faujasite-Na, -Ca, -Mg, ferrierite-Mg, -K, -Na, gmelinite-Na, -Ca, -K, heulandite-Ca, -Na, -K, -Sr, levyne-Ca, -Na, paulingite-K, -Ca, phillipsite-Na, -Ca, -K, and stilbite-Ca, -Na. Key references, type locality, origin of name, chemical data, IZA structure-type symbols, space-group symmetry, unit-cell dimensions, and comments on structure are listed for 13 compositional series, 82 accepted zeolite mineral species, and three of doubtful status. Herschelite, leonhardite, dvetlozarite, and wellsite are discredited as mineral species names. Obsolete and discredited names are listed.

Canadian Mineralogist

The next decade in geochemistry

The purpose, associations, functions; and activities of the Geochmical Society are reviewed briefly. Work on the Colorado Plateau uranium deposits is described as an example of what geochemical research, in conjunction with detailed field work, mineralogical studies, and related techniques can contribute to the understanding of a type of deposit. It is pointed out that not only have these studies given a great deal of information about the origin of the ores, but they have brought about directly a manifold increase in production and reserves of uranium in the United States. Indirectly, they aided the discovery of the tremendous deposits of the Blind River area in Ontario. It is suggested that similar broad cooperative attacks could not only yield comparable results with other types of mineral deposits, such as laterites and Mississippi Valley type lead-zinc deposits, but could also advance our knowledge and understanding of such diverse problems of geology and cosmology as the origin of granites, origin and geologic implications of meteorites (including tektites), origin and search for petroleum, and geochemical relations and interpretations of natural waters. For each of these problems methods of approach are outlined and for some of them, specific projects and correlative problems are mentioned. It is further suggested that the broad cooperative attack needed for most of these problems might be fostered most effectively by a programme comparable to that of the I.G.Y., even though for most types of geochemical research synoptic sampling and observations are not as important as they are for many projects in geophysics.

Geochimica et Cosmochimica Acta

Arsenic and mercury contamination related to historical goldmining in the Sierra Nevada, California

Arsenic (As) is a naturally occurring constituent in low-sulphide gold-quartz vein deposits, the dominant deposit type for lode mines in the Sierra Nevada Foothills (SNFH) gold (Au) province of California. Concentrations of naturally occurring mercury (Hg) in the SNFH Au province are low, but extensive use and loss of elemental Hg during amalgamation processing of ore from lode and placer Au deposits led to widespread contamination of Hg in the Sierra Nevada foothills and downstream areas, such as the Sacramento–San Joaquin Delta and San Francisco Bay. This review paper provides an overview of As and Hg contamination related to historical Au mining in the Sierra Nevada of California. It summarizes the geology, mineralogy, and geochemistry of the Au deposits, and provides information on specific areas where detailed studies have been done in association with past, ongoing, and planned remediation activities related to the environmental As and Hg contamination. Arsenic is a naturally occurring constituent in low-sulphide Au-quartz vein deposits, the dominant deposit type for lode mines in the Sierra Nevada Foothills (SNFH) Au province ( Ashley 2002 ). Because of elevated concentrations of As in accessory iron-sulphide minerals including arsenopyrite (FeAsS) and arsenian pyrite (Fe(S,As) 2 ), As is commonly a contaminant of concern in lode Au mine waste, including waste rock and mill tailings. The principal pathways of human As exposure from mine waste include ingestion of soil or drinking water, and inhalation of dust in contaminated areas ( Mitchell 2014 ). Concentrations of naturally occurring Hg in the SNFH Au province are low, but extensive use and loss of elemental Hg during amalgamation processing of ore from lode and placer Au deposits ( Churchill 2000 ) led to widespread contamination of Hg in the Sierra Nevada foothills and downstream areas, such as the Sacramento–San Joaquin Delta and San Francisco Bay ( Alpers et al. 2005 a ). Conversion of Hg to monomethylmercury (MeHg) by sulphate-reducing and iron-reducing microbes facilitates its bioaccumulation ( Wiener et al. 2003 ). The human Hg exposure pathway of main concern is ingestion of MeHg from sport (non-commercial) fish, especially higher trophic levels such as bass species ( Davis et al. 2008 ). Wildlife exposure to MeHg is also a concern because of chronic and reproductive effects, for example in fish-eating and invertebrate-foraging birds (e.g. Wiener et al. 2003 ; Eagles-Smith et al. 2009 ; Ackerman et al. 2016 ).

California

Uranium in pegmatites

Uranium and rare-earth minerals are common accessory minerals in pegmatite deposits. No domestic pegmatites have been found that are rich enough to support an economic mining operation for uranium alone; however, small quantities of uranium minerals may be recovered as by-products of feldspar or mica mining. Madagascar is the only country that has produced appreciable tonnages of uranium minerals from pegmatites.A review of the literature and observations in the domestic pegmatite districts show that the uranium and rare earth minerals generally occur in pegmatites or pegmatite units rich in potash feldspar. Recent mineralogical and structural studies of pegmatites by the U. S. Geological Survey indicate that, on the basis of geologic mapping, these units can be projected laterally and in depth with reasonable accuracy. In most places the mineral content of these units can be estimated with sufficient accuracy for development purposes.

New Mexico

Rheology of the lithosphere

During the quadrennial term 1979–1982, major advances have been made in our knowledge of the rheology of the oceanic lithosphere by the skillful combination of experimental and theoretical rock mechanics, seismology and marine geophysics in increasingly sophisticated models for the flexure of the oceanic lithosphere at seamounts and island chains, along transform faults, and at subduction zones. The relative simplicity of plate bending geometry, thermal history, and mineralogical and chemical compositions of the oceanic plates in these settings make the geophysical observations very powerful constraints on the in situ rheology of the oceanic lithosphere. In the first part of this paper, I review the laboratory work on materials appropriate to the oceanic lithosphere with emphasis on contributions during the quadrennial period and the need for future work. The important results of flexure models incorporating realistic material properties are then summarized.

Reviews of Geophysics and Space Physics

III.-The Work of Prof. Henry Carvill Lewis in Glacial Geology

The recent notice of the life and work of Prof. Henry Carvill Lewis, whose lamented death occurred in Manchester, July 21st, 1888, in his thirty-fifth year, well indicates the wide range of his scientific labours. He published valuable results of investigations in astronomy, mineralogy and petrology, and especially in glacial geology, the last being based on his exploration of the drift and its terminal moraines in the United States, and later in Ireland, Wales and England. The present article reviews his contributions to our knowledge of these drift formations and of the history of the Ice Age, bringing into comparison and correlation the glacial records of America and Europe. Comprehensive as were Professor Lewis' observations and studies in this field, he was planning yet more thorough and extensive exploration of the drift in Britain, Germany and Scandinavia, when he was taken from us.

Geological Magazine

The Novarupta-Katmai eruption of 1912 - largest eruption of the twentieth century; centennial perspectives

The explosive outburst at Novarupta (Alaska) in June 1912 was the 20th century's most voluminous volcanic eruption. Marking its centennial, we illustrate and document the complex eruptive sequence, which was long misattributed to nearby Mount Katmai, and how its deposits have provided key insights about volcanic and magmatic processes. It was one of the few historical eruptions to produce a collapsed caldera, voluminous high-silica rhyolite, wide compositional zonation (51-78 percent SiO 2 ), banded pumice, welded tuff, and an aerosol/dust veil that depressed global temperature measurably. It emplaced a series of ash flows that filled what became the Valley of Ten Thousand Smokes, sustaining high-temperature metal-transporting fumaroles for a decade. Three explosive episodes spanned ~60 hours, depositing ~17 km 3 of fallout and 11&plusmn;2 km 3 of ignimbrite, together representing ~13.5 km 3 of zoned magma. No observers were nearby and no aircraft were in Alaska, and so the eruption narrative was assembled from scattered villages and ship reports. Because volcanology was in its infancy and the early investigations (1915-23) were conducted under arduous expeditionary conditions, many provocative misapprehensions attended reports based on those studies. Fieldwork at Katmai was not resumed until 1953, but, since then, global advances in physical volcanology and chemical petrology have gone hand in hand with studies of the 1912 deposits, clarifying the sequence of events and processes and turning the eruption into one of the best studied in the world. To provide perspective on this century-long evolution, we describe the geologic and geographic setting of the eruption - in a remote, sparsely inhabited wilderness; we review the cultural and scientific contexts at the time of the eruption and early expeditions; and we compile a chronology of the many Katmai investigations since 1912. Products of the eruption are described in detail, including eight layers of regionwide fallout, nine packages of ash flows, and three lava domes that followed the explosive pyroclastic episodes. Changes in the proportions of coerupting rhyolite, dacite, and andesite pumice documented for the fallout and ash-flow successions, which are locally interbedded, permit close correlation of those synchronously emplaced sequences and their varied facies. Petrological correlation of the sequence of deposits near Novarupta with ash layers at Kodiak village, 170 km downwind, where three episodes of ashfall were recorded (to the hour), provides key constraints on timing of the eruptive events. Syneruptive collapse of a kilometer-deep caldera took place atop Mount Katmai, a stratovolcano centered 10 km east of the eruption site at Novarupta, owing to drainage of magma from beneath the Katmai edifice. Correlation of ~50 earthquakes recorded at distant seismic stations (including 14 shocks of magnitude 6.0 to 7.0) to fitful caldera collapse provides further constraints on eruption timing, because layers of nonjuvenile breccia and mud ejected from Mount Katmai during collapse pulses are intercalated with the pumice-fall layers from Novarupta. Structure of the Novarupta vent, a 2-km-wide depression backfilled by welded tuff and inferred to be funnel-shaped at depth, is described in detail, as is the 4-km-wide caldera at Mount Katmai. Discussions are also provided concerning: (1) the impact on global climate of the great mass of sulfur-poor but halogen-rich aerosol ejected into the atmosphere by the rhyolite-dominated eruption; (2) chemical and mineralogical effects of the fumarolic acid gases; and (3) the timing of several syneruptive landslide deposits sandwiched within the pumice-fall sequence. Secondary posteruption phenomena characterized include impounded lakes, ash-rich debris flows, phreatic craters on the ignimbrite sheet, responses of glaciers to the fallout blanket and to beheading by caldera collapse, growth of new glaciers inside the caldera, and gradual filling of the caldera lake. Structure, composition, and ages of the several andesite-dacite stratovolcanoes, closely clustered near Novarupta, all of which remain fumarolically and seismically active, are summarized. But among them only Mount Katmai extends compositionally to include basalt and rhyolite. The petrological affinities of 1912 magmas erupted at Novarupta with pre-1912 Katmai lavas are outlined, and various chemical, mineralogical, isotopic, and experimental data are assembled to construct a model of preeruptive magma storage beneath Mount Katmai. The monograph concludes by comparing the 1912 eruption with several other well-studied large explosive eruptions, 14 of them historical and 9 prehistoric. Finally, we retrospectively review the historical difficulties in understanding what had actually taken place at Katmai in 1912 and the century of progress in volcano science that has allowed most of it to be figured out.

Alaska;British Columbia;Washington;Yukon

Selected plant microfossil records of the terminal Cretaceous event in terrestrial rocks, western North America

Terrestrial or nonmarine rocks of western North America preserve a record of major disruption and permanent alteration of plant communities precisely at the K-T boundary - in the same rocks that preserve geochemical and mineralogical evidence of the terminal Cretaceous impact event. Plant microfossil records from many localities show abrupt disappearance of pollen species (= plant extinctions) closely associated with impact ejecta deposits containing iridium and shocked quartz. Localities discussed in detail in this review are Starkville South, Clear Creek North, Old Raton Pass, and Sugarite in the Raton Basin of Colorado and New Mexico; West Bijou in the Denver Basin, Colorado; Sussex in the Powder River Basin, Wyoming; and Pyramid Butte and Mud Buttes in the Williston Basin, North Dakota. ?? 2007 Elsevier B.V. All rights reserved.

Palaeogeography, Palaeoclimatology, Palaeoecology

Geoenvironmental model for roll-type uranium deposits in the Texas Gulf Coast

Geoenvironmental models were formulated by the U.S. Geological Survey in the 1990s to describe potential environmental effects of extracting different types of ore deposits in different geologic and climatic regions. This paper presents a geoenvironmental model for roll-front (roll-type) uranium deposits in the Texas Coastal Plain. The model reviews descriptive and quantitative information derived from environmental studies and existing databases to depict existing conditions and potential environmental concerns associated with mining this deposit type. This geoenvironmental model describes how features of the deposits including host rock; ore and gangue mineralogy; geologic, hydrologic, and climatic settings; and mining methods (legacy open-pit and in situ recovery [ISR]) influence potential environmental effects from mining. Element concentrations in soil and water are compared to regulatory thresholds to depict ambient surface water and groundwater conditions. Although most open-pit operations in this region have been reclaimed, concerns remain about groundwater quality at three of the four former mills that supported former open-pit mines and are undergoing closure activities. The primary environmental concerns with ISR mining are (1) radon gas at active ISR operations, (2) radiation or contaminant leakage during production and transport of ISR resin or yellowcake, (3) uranium excursions into groundwater surrounding active ISR operations, and (4) contamination of groundwater after ISR mining. Although existing regulations attempt to address these concerns, some problems remain. Researchers suggest that reactive transport modeling and a better understanding of geology, stratigraphy, and geochemistry of ISR production areas could minimize excursions into surrounding aquifers and improve results of groundwater restoration.

Texas

Epigenetic, diplogenetic, syngenetic, and lithogene deposits

Much of the disagreement over " epigenetic " And " Syngenetic " Deposits Is Semantic; Some Ores And altered rocks are in part syngenetic and in part epigenetic and for them the term " diplogenetic " is proposed. All these terms are primarily time terms related to the contemporaneity of the deposit and the enclosing rock, but in a secondary sense they are space terms; they do not, however, imply process of formation or source of the chemical constituents. Process or source terms such as "magmatic," "hydro-thermal," "sedimentary" are generally satisfactory, but the process term "lateral secretion" is now vague in meaning. A more precise term is needed for the process of mobilization of elements from a solid rock and their transportation and redeposition elsewhere; for this process I propose the term " lithogene " ("stone-born"), to stress the source and process as do "magmatic" and "sedimentary." Such deposits could be derived from syngenetic , diplogenetic , or epigenetic deposits through the action of metamorphic, hydrothermal, supergene or other solutions. If one wishes, however, to emphasize the distance the mobilized elements have moved from the source rock, the resulting deposit can be described best as a locally derived lithogene deposit ("lateral secretion"), or as a regionally derived lithogene deposit ("product of regional metamorphism"). The classification of many deposits such as epigenetic replacement bodies of magnetite in limestone, and syngenetic gold in recent placers is not controversial; however, where large parts of the mineral deposit are made up both of syngenetic elements and introduced elements, the term " diplogenetic " is appropriate. Examples include mineral deposits in which syngenetic cations are united with epigenetic anions, as in fluorite replacements in limestones, or where the reverse relationship holds and epigenetic cations are united to syngenetic sulfur or other anions-as may be true of certain black cupriferous shales of the Mansfeld type. Guides for distinguishing the various types of mineral deposits are discussed at length and include: mineralogy; texture; isotopic composition of hydrogen, carbon, oxygen, sulfur, and perhaps other elements; form; age relations; alteration; zoning; position and quantitative adequacy of supposed source rocks; lithology; structural geology; paleogeography; and regional geologic relations. The criteria developed are used in a critical review of several examples of controversial deposits -including the African Copper-belt deposits and those of the graphitic schists of Fenno-Scandia.

Economic Geology

A review of the phyllosilicates in Gale Crater as detected by the CheMin Instrument on the Mars Science Laboratory, Curiosity Rover

Curiosity , the Mars Science Laboratory (MSL) rover, landed on Mars in August 2012 to investigate the ~3.5-billion-year-old (Ga) fluvio-lacustrine sedimentary deposits of Aeolis Mons (informally known as Mount Sharp) and the surrounding plains (Aeolis Palus) in Gale crater. After nearly nine years, Curiosity has traversed over 25 km, and the Chemistry and Mineralogy (CheMin) X-ray diffraction instrument on-board Curiosity has analyzed 30 drilled rock and three scooped soil samples to date. The principal strategic goal of the mission is to assess the habitability of Mars in its ancient past. Phyllosilicates are common in ancient Martian terrains dating to ~3.5–4 Ga and were detected from orbit in some of the lower strata of Mount Sharp. Phyllosilicates on Earth are important for harboring and preserving organics. On Mars, phyllosilicates are significant for exploration as they are hypothesized to be a marker for potential habitable environments. CheMin data demonstrate that ancient fluvio-lacustrine rocks in Gale crater contain up to ~35 wt. % phyllosilicates. Phyllosilicates are key indicators of past fluid–rock interactions, and variation in the structure and composition of phyllosilicates in Gale crater suggest changes in past aqueous environments that may have been habitable to microbial life with a variety of possible energy sources.

Minerals

Geologic and environmental characteristics of porphyry copper deposits with emphasis on potential future development in the Bristol Bay Watershed, Alaska (Appendix H)

This report is prepared in cooperation with the Bristol Bay Watershed Assessment being conducted by the U.S. Environmental Protection Agency. The goal of the assessment is to help understand how future large-scale development in this watershed may affect water quality and the salmon fishery. Mining has been identified as a potential source of future large scale development in the region, especially because of the advanced stage of activity at the Pebble prospect. The goal of this report is to summarize the geologic and environmental characteristics of porphyry copper deposits in general, largely on the basis of literature review. Data reported in the Pebble Project Environmental Baseline Document, released by the Pebble Limited Partnership in 2011, are used to enhance the relevance of this report to the Bristol Bay watershed. The geologic characteristics of mineral deposits are paramount to determining their geochemical signatures in the environment. The geologic characteristics of mineral deposits are reflected in the mineralogy of the mineralization and alteration assemblages; geochemical associations of elements, including the commodities being sought; the grade and tonnage of the deposit; the likely mining and ore-processing methods used; the environmental attributes of the deposit, such as acid-generating and acid-neutralizing potentials of geologic materials; and the susceptibility of the surrounding ecosystem to various stressors related to the deposit and its mining, among other features (Seal and Hammarstrom, 2003). Within the Bristol Bay watershed, or more specifically the Nushagak and Kvichak watersheds, the geologic setting is permissive for the occurrence of several mineral deposit types that are amenable for large-scale development. Of these deposit types, porphyry copper deposits (e.g., Pebble) and intrusion-related gold deposits (e.g., Shotgun) are the most important on the basis of the current maturity of exploration activities by the mining industry. The Pebble deposit sits astride the drainage divide between the Nushagak and Kvichak watersheds, whereas the Humble, Big Chunk, and Shotgun deposits are within the Nushagak watershed. The Humble and Big Chunk prospects are geophysical anomalies that exhibit some characteristics similar to those found at Pebble. Humble was drilled previously in 1958 and 1959 as an iron prospect on the basis of an airborne magnetic anomaly. Humble is approximately 85 miles (137 km) west of Pebble; Big Chunk is approximately 30 miles (48 km) north-northwest of Pebble; and Shotgun is approximately 110 miles (177 km) northwest of Pebble. The H and D Block prospects, west of Pebble, represent additional porphyry copper exploration targets in the watershed.

Alaska

Demonstration of a novel quantitative microscopy technique for automated characterization of in situ particulate matter in coal miners with progressive massive fibrosis

Rationale: Increasing exposure to respirable crystalline silica (RCS) linked to changes in mining production processes has been implicated in the resurgence of severe lung disease in U.S. coal miners. Lung mineralogy can provide insight into particle pathogenesis. However, standard approaches to characterizing in situ particulate matter (PM) by pulmonary pathologists have poor inter-rater comparability, and consensus agreement is time consuming. Scanning electron microscopy/energy-dispersive spectroscopy (SEM/EDX) is technically complex and labor intensive. We developed a method for quantitative in situ PM characterization using conventional polarized light microscopy (PLM) and explored PM features in lung tissue of coal miners with progressive massive fibrosis (PMF). Methods: With institutional review board approval, PLM images were obtained from 30 miners with PMF, classified by pathologists consensus based on PM profusion; 10 from each profusion group (mild/moderate/severe) were selected. Automated PM counting and characterization (including dimensions and grayscale intensity of PM > 0.3 m diameter) was performed on image samples using PLM with modified cell-counting software (BZ-X800 light microscope, Keyence Corporation, Osaka, Japan) (Figure 1). Quantitative PM density loge(PM count)/mm3 tissue was calculated for each sample and compared to pathologist PM profusion groups. PMF lesion type using consensus pathologist classification (13 coal-type, 9 mixed-type, and 8 silicotic-type) was compared to automated PM birefringence level (% particles with mean grayscale intensity <65, range 0-255). RCS particles are expected to be weakly birefringent (lower intensity) relative to other common minerals (e.g., silicates) contained in coal mine dust. PM features were analyzed in R 4.0.3 using one-way ANOVA for between-group comparisons. Results: Measured PM log-density increased significantly with higher qualitative profusion group (mild=10.480.98/mm3, moderate=11.460.81/mm3, severe=12.520.86/mm3, p<0.0001). Prevalence of weakly birefringent particles was significantly higher among silicotic-type PMF samples (31.57.9%) compared to either coal-type (21.510.1%, p=0.022) or mixed-type lesions (21.510.5%, p=0.025). Conclusion: This pilot study demonstrates the feasibility of a novel quantitative microscopy technique for counting and characterizing in situ lung PM in coal miners with PMF. Quantitative PM burden was comparable to pulmonary pathologists consensus profusion classification, but this method was substantially less time consuming and labor intensive and provided additional information about relevant PM features. The higher prevalence of weakly birefringent particles seen in silicotic-type PMF lesions may help inform mineralogic pathogenesis of RCS. Future efforts will expand the number of PMF cases analyzed, further validate our mineralogic findings using data from SEM/EDX and lung tissue digestate methods, and compare findings in historical versus contemporary coal miners with PMF.

Conference Paper

Mineralogical applications of electron diffraction. 1. Theory and techniques

The small wavelengths used in electron-diffraction experiments and the thinness of the crystals necessary for the transmission of the electron beam combine to require a somewhat different diffraction geometry for the interpretation of electron-diffraction patterns than is used in the interpretation of X-ray diffraction patterns. This geometry, based on the reciprocal lattice concept and geometrical construction of Ewald, needed for the interpretation. of transmission electron-diffraction single-crystal patterns is here reviewed. Transmission electron-diffraction single-crystal patterns of two monoclinic substances, colemanite [CaB 3 O 3 (OH) 3 •H 2 O] and potassium chlorate (KC10 3 ), are examined and the .theory necessary for their interpretation is given in detail. The study of these patterns furnishes a basis for the interpretation of single-crystal patterns of materials belonging to any crystal system. It is shown that useful unit-cell data, accurate to a few tenths of a percent, can be obtained from the patterns of colemanite and KClO 3 . A method of evaluating unit-cell data from measurements of such single-crystal patterns is given. The transmission electron-diffraction powder pattern obtained from an oriented aggregate of thin crystals gives the same unit-cell data as are given by the electron-diffraction single-crystal pattern obtained from one crystal of the aggregate., A graphical method is given for precisely evaluating unit-cell constants from measurements of such a powder pattern.

Trace Elements Investigations

Decomposition techniques

Sample decomposition is a fundamental and integral step in the procedure of geochemical analysis. It is often the limiting factor to sample throughput, especially with the recent application of the fast and modern multi-element measurement instrumentation. The complexity of geological materials makes it necessary to choose the sample decomposition technique that is compatible with the specific objective of the analysis. When selecting a decomposition technique, consideration should be given to the chemical and mineralogical characteristics of the sample, elements to be determined, precision and accuracy requirements, sample throughput, technical capability of personnel, and time constraints. This paper addresses these concerns and discusses the attributes and limitations of many techniques of sample decomposition along with examples of their application to geochemical analysis. The chemical properties of reagents as to their function as decomposition agents are also reviewed. The section on acid dissolution techniques addresses the various inorganic acids that are used individually or in combination in both open and closed systems. Fluxes used in sample fusion are discussed. The promising microwave-oven technology and the emerging field of automation are also examined. A section on applications highlights the use of decomposition techniques for the determination of Au, platinum group elements (PGEs), Hg, U, hydride-forming elements, rare earth elements (REEs), and multi-elements in geological materials. Partial dissolution techniques used for geochemical exploration which have been treated in detail elsewhere are not discussed here; nor are fire-assaying for noble metals and decomposition techniques for X-ray fluorescence or nuclear methods be discussed.

Journal of Geochemical Exploration

Hydrogeochemical processes governing the origin, transport and fate of major and trace elements from mine wastes and mineralized rock to surface waters

The formation of acid mine drainage from metals extraction or natural acid rock drainage and its mixing with surface waters is a complex process that depends on petrology and mineralogy, structural geology, geomorphology, surface-water hydrology, hydrogeology, climatology, microbiology, chemistry, and mining and mineral processing history. The concentrations of metals, metalloids, acidity, alkalinity, Cl - , F - and SO 4 2- found in receiving streams, rivers, and lakes are affected by all of these factors and their interactions. Remediation of mine sites is an engineering concern but to design a remediation plan without understanding the hydrogeochemical processes of contaminant mobilization can lead to ineffective and excessively costly remediation. Furthermore, remediation needs a goal commensurate with natural background conditions rather than water-quality standards that might bear little relation to conditions of a highly mineralized terrain. This paper reviews hydrogeochemical generalizations, primarily from US Geological Survey research, that enhance our understanding of the origin, transport, and fate of contaminants released from mined and mineralized areas. Mobility of potential or actual contaminants from mining and mineral processing activities depends on (1) occurrence : is the mineral source of the contaminant actually present? (2) abundance : is the mineral present in sufficient quantity to make a difference? (3) reactivity : what are the energetics, rates, and mechanisms of sorption and mineral dissolution and precipitation relative to the flow rate of the water? and (4) hydrology : what are the main flow paths for contaminated water? Estimates of relative proportions of minerals dissolved and precipitated can be made with mass-balance calculations if minerals and water compositions along a flow path are known. Combined with discharge, these mass-balance estimates quantify the actual weathering rate of pyrite mineralization in the environment and compare reasonably well with laboratory rates of pyrite oxidation except when large quantities of soluble salts and evaporated mine waters have accumulated underground. Quantitative mineralogy with trace-element compositions can substantially improve the identification of source minerals for specific trace elements through mass balances. Post-dissolution sorption and precipitation (attenuation) reactions depend on the chemical behavior of each element, solution composition and pH, aqueous speciation, temperature, and contact-time with mineral surfaces. For example, little metal attenuation occurs in waters of low pH (<3.5) and metals tend to maintain element ratios indicative of the main mineral or group of minerals from which they dissolved, except Fe, SiO 2 , and redox-sensitive oxyanions (As, Sb, Se, Mo, Cr, V). Once dissolved, metal and metalloid concentrations are strongly affected by redox conditions and pH. Iron is the most reactive because it is rapidly oxidized by bacteria and archaea and Fe(III) hydrolyzes and precipitates at low pH (1&ndash;3) which is related directly to its first hydrolysis constant, pK 1 = 2.2. Several insoluble sulfate minerals precipitate at low pH including anglesite, barite, jarosite, alunite and basaluminite. Aluminum hydrolyzes near pH 5 (pK 1 = 5.0) and provides buffering and removal of Al by mineral precipitation from pH 4&ndash;5.5. Dissolved sulfate behaves conservatively because the amount removed from solution by precipitation is usually too small relative to the high concentrations in the water column and relative to the flow rate of the water.

Applied Geochemistry