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207 records · Page 3Linked to original sources
USGS2026

Geochemical disequilibrium at the brittle-ductile transition

We investigate the microtextural, microchemical, and isotopic effects of late-stage ductile deformation in quartzite mylonites and kyanite–muscovite–quartz veins from the Raft River shear zone (Utah). Quartz microstructures record pervasive disequilibrium, expressed by unannealed features including undulatory extinction, deformation lamellae, and poorly defined fabrics, typical of waning deformation in shear zones. Microchemical disequilibrium is best preserved in kyanite quartzites, where CL-zoned kyanite records repeated fractures, overgrowth, and mineral precipitation, and in muscovite from muscovite-poor quartzite mylonites that shows minor-element zoning consistent with syn-deformational overgrowth on detrital cores. In contrast, muscovite from muscovite-rich kyanite quartzites exhibits minimal chemical zoning. These microchemical variations correlate with 40 Ar/ 39 Ar age systematics. Chemically zoned muscovite preserves variable single-step ages, including ∼150 Ma ages, reflecting retention of detrital cores. In contrast, syndeformational muscovite consistently yields Miocene ages, indicating recrystallization and new growth below argon closure temperatures that reset inherited isotopic signatures. Similar trends are observed in quartzite mylonites, where increasing quartz recrystallization and stronger crystallographic preferred orientations occur toward deeper structural levels. Together, these observations indicate increasing retrograde deformation and recrystallization with depth in the Raft River shear zone and demonstrate that strain-driven recrystallization exerts a first-order control on muscovite ages. We suggest that apparent thermochronologic gradients in retrograde shear zones may reflect recrystallization gradients rather than temperature gradients. Where cooling limits the thermal driving force for recrystallization, isotopic relics are preserved, and local deformation and fluid availability control re-equilibration. Consequently, isotopic disequilibrium—particularly in the 40 Ar/ 39 Ar system—may be the rule rather than the exception of retrograde tectonic environments.

Idaho, Utah↗
USGS2025

Using subducting plate motion to constrain Cascadia slab geometry and interface strength

Subduction zones are home to multiple geohazards driven by the evolution of the regional tectonics, including earthquakes, volcanic eruptions and landslides. Past evolution builds the present-day structure of the margin, while the present-day configuration of the system determines the state-of-stress in which individual hazardous events manifest. Regional simulations of subduction zones provide a tool to synthesize the tectonic history of a region and investigate how geologic features lead to variations in the state of stress across the subduction system. However, it is challenging to design regional models that provide a force-balance that is consistent with the large-scale motion of surrounding tectonic plates while also not over-constraining the solution. Here, we present new models for the Cascadia subduction zone that meet these criteria and demonstrate how the motion of the subducting Juan de Fuca plate can be used to determine the along-strike variations in the viscous (long-term) coupling across the plate boundary. All successful models require lower viscous coupling in the northern section of the trench compared to the central and southern sections. However, due to uncertainties in the geometry of the Cascadia slab, we find that there is a trade-off between along-strike variation in viscous coupling and slab shape. Better constraints on the slab shape, and/or use of other observations are needed to resolve this trade-off. The approach presented here provides a framework for further exploring how geologic features in the overriding plate and the properties of the plate boundary region affect the state-of-stress across this and other subduction zones.

Cascadia subduction zone↗
USGS2024

Radiogenic strontium- and uranium-isotope tracers of water-rock interactions and hydrothermal flow in the Upper Geyser Basin, Yellowstone Plateau Volcanic Field, USA

Natural radiogenic isotopes (primarily 87 Sr/ 86 Sr) from hot springs in the Upper Geyser Basin of the Yellowstone Plateau volcanic field and associated rocks were used to evaluate groundwater flow patterns, water-rock reactions, and the extent of mixing between various groundwater sources. Thermal waters have very low uranium concentrations and 234 U/ 238 U activity ratios near 1.0, which limit their utility as tracers in this reducing setting. Thermal waters have higher Sr concentrations (<22 ng/g) and a wide range of 87 Sr/ 86 Sr values that vary both temporally at individual discharge sites and between adjacent springs, indicating that conduits tap different subsurface reservoirs to varying degrees. Sr from local rhyolites have 87 Sr/ 86 Sr compositions that bound the range of values observed in groundwater throughout the basin. Non-boiling springs on the west flank of the basin discharge water with low 87 Sr/ 86 Sr consistent with flow through young volcanic rocks exposed at the surface. Boiling springs in the central basin have higher 87 Sr/ 86 Sr values reflecting interactions with older, more radiogenic volcanic rocks. Variability in upwelling thermal waters requires mixing with a low 87 Sr/ 86 Sr component derived from young lava or glacial sediments, or more likely, from deeper sources of hot groundwater circulating through buried Lava Creek Tuff having intermediate 87 Sr/ 86 Sr. Isotope data constrain basin-wide output of thermal water to 110–140 kg·s −1 . Results underscore the utility of radiogenic Sr isotopes as valuable tracers of hydrothermal flow patterns and improve the understanding of temperature-dependent water-rock reactions in one of the largest continental hydrothermal systems on Earth.

Wyoming↗
USGS2025

The systematics of stable hydrogen (δ2H) and oxygen (δ18O) isotopes and tritium (3H) in the hydrothermal system of the Yellowstone Plateau volcanic field, USA

To improve our understanding of hydrothermal activity on the Yellowstone Plateau volcanic field, we collected and analyzed a large data set of δ 2 H, δ 18 O, and the 3 H concentrations of circum-neutral and alkaline waters. We find that (a) hot springs are fed by recharge throughout the volcanic plateau, likely focused through fractured, permeable tuff units. Previous work had stressed the need for light δ 2 H water recharge restricted to the northern part of the plateau or recharge during past cold periods. However, new data from the Y-7 drill hole suggests that recharge is not restricted to a certain area or a cold period. (b) δ 18 O values of thermal waters in the geyser basins are shifted from the global meteoric water line by temperature-dependent water-rock reactions with higher subsurface temperatures resulting in a greater shift. (c) Large temporal variations in the isotopic composition of meteoric water recharge and small temporal variability in the isotopic composition of hot spring discharge implies that the volume of groundwater in, and around the Yellowstone caldera is substantially larger than the volume of annual water recharge. (d) Hot springs discharged through different rhyolitic units correlate with identifiable differences in δ 2 H and δ 18 O compositions, 3 H concentrations, and water chemistry that imply equilibration at different temperatures and travel along different flow paths. (e) Based on measured 3 H concentrations, we calculate that hot spring waters in the central part of the geyser basins mostly contain <2% post-1950 meteoric water, whereas waters discharged at the basin margins contain larger fractions of post-1950s meteoric water.

Wyoming↗
USGS2026

Mid-Cretaceous porphyritic magmatism in the Beartooth Mountains of the northern Laramide foreland and its connection to Frontier Formation sediment dispersal in Bighorn basin, Montana-Wyoming (USA), and Cordilleran tectonism

Porphyritic intrusions in the southeast Beartooth Mountains and porphyritic cobbles from the Torchlight conglomerate of the Cenomanian Frontier Formation in Bighorn basin (Montana-Wyoming, USA) bear striking resemblance. We utilize geologic mapping, petrography, geochemistry, and geochronology to characterize rocks from both locations and test whether the Beartooth Mountains area was the provenance for Bighorn basin cobbles. Mapping on Line Creek Plateau in the Beartooth Mountains shows three units with porphyritic phenocrysts consisting dominantly of plagioclase, plagioclase + potassium feldspar, and plagioclase + quartz. Petrography shows embayed quartz, opacitic rims, and zoned plagioclase. Geochemistry characterizes the intrusions as trachydacite to trachyte and trace elements exhibit enrichment in light rare earth elements and slight depletion in heavy rare earth elements relative to primitive mantle. Zircon U-Pb dating shows substantial Archean inheritance and ca. 104−92 Ma dates; some samples display multiple mid-Cretaceous date populations. Bighorn basin porphyritic cobbles exhibit similar modal mineralogy, near-identical geochemistry, and Archean inheritance and mid-Cretaceous geochronology. We suggest the porphyritic cobbles were sourced from basement-hosted porphyritic intrusions now exposed in the Beartooth Mountains, given that geochemistry does not agree with coeval volcanic sources along the Frontier Formation depositional fairway (Idaho batholith) or sedimentary-hosted Beartooth Mountains porphyritic sills intruded into Cambrian shale. Stratigraphic evidence does not support kilometer-scale mid-Cretaceous Beartooth Mountains exhumation to expose basement-hosted porphyritic intrusions, and we therefore present a volcanic hypothesis to bring rocks to the surface. This mid-Cretaceous multimillion-year magmatism is unexplained by tectonic models for the north-central Laramide foreland, and thus we further explore the emplacement processes, spatiotemporal significance, and tectonic implications of these rocks.

Montana, Wyoming↗
USGS2024

New U-Pb geochronology and geochemistry of Paleozoic metaigneous rocks from western Yukon and eastern Alaska, cross-border synthesis, and implications for tectonic models

The tectonic evolution of and relation between the Yukon-Tanana terrane and the Lake George assemblage, as well as other associated tectonic assemblages in western Yukon and eastern Alaska, have been debated for decades. The Yukon-Tanana terrane is widely considered to be an allochthonous rifted fragment derived from the Laurentian continental margin, whereas the Lake George assemblage and associated assemblages are currently interpreted to be part of the parautochthonous continental margin of western North America (Laurentia). To address these topics, we present 40 new U-Pb zircon ages and 20 new whole-rock geochemical analyses. We incorporate these data into a new compilation of available geological mapping for a large area that straddles the Alaska-Yukon border, together with 34 previously published U-Pb age determinations and an extensive geochemical database of metaigneous rocks from Late Devonian to Early Mississippian and middle to late Permian assemblages in this area. Magmatism in the Lake George assemblage and related assemblages occurred in two pulses from about 371 to 360 and from about 358 to 347 million years ago (Ma); geochemical discrimination diagrams indicate a large crustal component, possibly indicative of arc magmatism, for felsic metaigneous rocks and a range of tectonic environments for mafic rocks. Magmatism in the Fortymile River and related assemblages, and parts of the Nasina assemblage—all parts of the Yukon-Tanana terrane—are mainly Early Mississippian and span a crystallization age range from about 361 to 343 Ma; geochemical discrimination diagrams for these rocks indicate primarily arc geochemical signatures for both mafic and felsic rocks. Middle to late Permian crystallization ages (about 261–253 Ma) are indicated for felsic metaigneous rocks in the Klondike assemblage and some of the felsic metaigneous rocks in the Nasina assemblage. Based on our mapping, we propose the existence of a possible unconformity between the Mississippian and Permian felsic metavolcanic rocks within the Nasina assemblage that is marked by sporadic occurrences of stretched-pebble conglomerate. Our combined database supports the well-established model of a magmatic arc comprising the Fortymile River and Finlayson assemblages of the rifted Yukon-Tanana terrane continental fragment on which a middle to late Permian arc (Klondike assemblage) was later built. The assemblages of the Yukon-Tanana terrane were subsequently intruded by Late Triassic to Early Jurassic granitoids, presumably during reaccretion of the Yukon-Tanana terrane to the continental margin. Permian and Late Triassic to Early Jurassic intrusions have not been mapped in the now structurally lower plate Lake George assemblage; their absence is one of the lines of evidence that have been used to support the parautochthonous, rather than allochthonous, origin of the Lake George assemblage and related assemblages. Our new data, together with previously published ranges of igneous crystallization ages and geochemical tectonic signatures of the Late Devonian to Early Mississippian magmatic rocks in the Lake George assemblage and associated assemblages and in the Fortymile River, Nasina, and correlated assemblages of the Yukon-Tanana terrane, indicate that the currently accepted interpretation of the Lake George assemblage and associated rocks being part of parauthochthonous North America is not the only possible interpretation of this tectonic entity. Approximately half of the dated intrusive rocks in the Lake George assemblage are contemporaneous with the metaigneous rocks of the Yukon-Tanana terrane arc (<361 Ma). We speculate that our approximately 361 Ma U-Pb age for quartz syenite in part of the North American continental margin in south-central Yukon defines the beginning of rifting of the Laurentian margin. Although the currently favored model of prolonged middle Paleozoic subduction and extension in both the Yukon-Tanana terrane and parautochthonous North America allows for simultaneous middle Paleozoic magmatism on both sides of the Slide Mountain Ocean, we now propose an alternative hypothesis in which the Lake George assemblage represents a deeper part of the rifted Yukon-Tanana terrane arc. If this is the case, the absence of Permian and Late Triassic to Early Jurassic arc rocks in the Lake George assemblage could be explained either by the arcs of these ages not being wide enough to have affected the Lake George assemblage or by tectonic displacement of these arc rocks away from the Lake George assemblage. Our approximately 259 Ma U-Pb zircon age and geochemical analyses of metarhyolite in the Seventymile terrane in Alaska, which comprises remnants of the back-arc basin that separated the Yukon-Tanana terrane from the Laurentian continental margin, confirm the presence of a late middle Permian volcanic arc component to the terrane. Our approximately 319 Ma U-Pb zircon age from the Chicken assemblage (as redefined in this study) in eastern Alaska, combined with previously reported fossil ages and a U-Pb zircon age from this assemblage, indicate that it is a Late Mississippian to Early Pennsylvanian arc assemblage. We propose several other relatively young, locally developed arc assemblages outboard of the ancient continental margin of Laurentia that may correlate with the Chicken assemblage, but we consider its origin to remain an enigma.

Alaska↗
USGS2025

Geochemistry of quartz and fluid inclusions associated with gold, tungsten, and antimony in the Stibnite-Yellow Pine district, Idaho

Deposits in the historic Stibnite-Yellow Pine district in east-central Idaho were mined for Ag, Au, Hg, Sb, and W. Ore is hosted in breccia and fault zones along NE-striking faults that transect the Atlanta lobe of the Late Cretaceous Idaho batholith and metamorphosed Neoproterozoic to lower Paleozoic rocks. Geochronological studies have delineated five superimposed and zoned hydrothermal events in the mining district which range in age from Late Cretaceous to the Eocene. They formed the following consecutive assemblages: (1) vein and disseminated pre-ore milky quartz (± calcite), muscovite, and brassy pyrite with minor molybdenite and base metal sulfides; (2) vein and disseminated quartz, calcite, sericite, auriferous-pyrite, and arsenopyrite; (3) potassium feldspar, quartz, dolomite, and calcite with vein and disseminated scheelite ± pyrite and arsenopyrite; (4) Au-Ag veins that contain adularia; and (5) breccia, vein, and disseminated quartz, calcite, and stibnite with minor Ag sulfosalts and distal zones of cinnabar and realgar at Fern and Hermes mines. In this study, the pressure, temperature, and composition of ore-forming fluids were measured in Au-, W-, and Sb-bearing samples collected from drill core and surface exposures. Using optical petrography, scanning electron microscopy cathodoluminescence (SEM-CL) and electron microprobe cathodoluminescence (EMPA-CL) imaging, as well as electron microprobe (EMP) and laser ablation-inductively coupled plasma-mass spectrometry trace element analyses, four major overprinting generations of hydrothermal quartz are defined. Fluid inclusion assemblages (FIAs) in each generation of quartz were characterized by microthermometry and laser Raman spectroscopy. Quartz and fluid inclusion paragenesis are as follows: (Qi) altered and overprinted Qi with no coeval FIAs that formed before or during event 1; (Q1) early veins as well as disseminated quartz with dull gray SEM-CL and H 2 O-NaCl-CO 2 FIAs that formed at minimum temperatures and pressures of 281° to 358°C and 1346 to 1789 bar during event 2 (Au); (Q2) vein and disseminated quartz, often euhedral, with H 2 O-NaCl ± CO 2 ± CH 4 FIAs that formed at minimum temperatures and pressures of 183° to 213°C and 72 to 602 bar during event 3 (W); and (Q3) euhedral and disseminated quartz with H 2 O-NaCl FIAs that formed at minimum temperature and pressures of 156° to 161°C and 5 to 6 bar during event 5 (Sb). Stibnite hosts H 2 O-NaCl FIAs trapped at minimum temperatures and pressures of 150° to 189°C and 5 to 12 bar that are similar to those of Q3-hosted FIAs. The quartz paragenetic history in the district follows a progressive temporal path from Tienriched quartz deposited by a relatively deep and higher temperature aqueous-carbonic fluid to a Li, Al, and Sb enriched quartz precipitated from a lower temperature aqueous fluid. Gases in fluid inclusion extracts from ore and gangue minerals were analyzed by mass spectrometry. Noble gas isotope analysis of fluid inclusion extracts revealed three signatures. Pre-ore Qi has R/R A (the isotopic ratio of the sample 3 He/ 4 He to atmospheric 3 He/ 4 He (1.384 × 10 −6 )) values that reflect the composition of the crustal melt-derived Atlanta lobe of the Idaho batholith. Quartz (Q1) and auriferous arsenian pyrite of hydrothermal event 2 have 20 Ne/ 4 He and R/R A values that plot along the air-crust mixing line, and these gases were likely introduced by metamorphic fluids derived from metasedimentary rocks. Stibnite with associated quartz (Q3 ± Q2) have 20 Ne/ 4 He and R/R A values that extend from the air-crust mixing line to the air-mantle mixing line, showing a shift from a crustal signature to an overprinting mantle signature. Late calcite has 20 Ne/ 4 He and R/R A values that extend from air toward the mantle end member, which suggests that magmatic volatiles condensed into meteoric groundwater late in the paragenesis. A mantle volatile source is also supported by high 20 Ne/ 22 Ne ratios. The Stibnite-Yellow Pine district is similar to other Au-W-Sb districts around the world in ore fluid chemistries, with late-stage stibnite being a product of cooling. The fluid pressure-temperature-composition (P-T-X) estimates and the crustal source of He during hydrothermal event 2 gold mineralization are characteristic of orogenic Au deposits, and the observed inclusion reequilibration textures indicate that trapped fluid inclusions were deformed during transitions between the brittle-ductile environment. Scheelite was deposited during event 3 with Q2 quartz and is overgrown by Q3 quartz and stibnite. Our interpretation of the quartz texture, chemistry, and fluid inclusion P-T-X data suggest that Au, W, and Sb mineralization occurred as hydrothermal fluids evolved from H 2 O-NaCl-CO 2 at >300°C and depths of ~4 to 6 km near the ductile to brittle transition to H 2 O-NaCl at ~150°C and epithermal depths as the Idaho batholith was exhumed. Geochronology indicates that from the Late Cretaceous to early Eocene, overprinting hydrothermal events formed deep orogenic Au, intermediate W, and shallow epithermal Au-Ag and Sb. Without comprehensive geochronologic constraints, our fluid inclusion data and textural observations could be interpreted as a single evolving hydrothermal system, as has been done in many other mining districts with similar mineralization.

Idaho↗
USGS1997

Water-quality assessment of south-central Texas: Occurrence and distribution of volatile organic compounds in surface water and ground water, 1983-94, and implications for future monitoring

The study area of the South-Central Texas study unit of the National Water-Quality Assessment Program comprises the Edwards aquifer in the San Antonio region and its catchment area. The first phase of the assessment includes evaluation of existing water-quality data for surface water and ground water, including volatile organic compounds, to determine the scope of planned monitoring. Most analyses of volatile organic compounds in surface water are from the National Pollutant Discharge Elimination System sites in San Antonio, Texas. Nine volatile organic compounds were detected at the six sites. The three compounds with the most detections at National Pollutant Discharge Elimination System sites are 1,2,4-trimethylbenzene, toluene, and xylene. Analysis of volatile organic compounds in ground water was limited to Edwards aquifer wells. Twenty-eight volatile organic compounds were detected in samples from 89 wells. The five most commonly detected compounds in samples from wells, in descending order, are tetrachloroethene, trichloroethene, bromoform, chloroform, and dibromochloromethane. Detections of volatile organic compounds in surface water and ground water within the South-Central Texas study area are limited to site-specific sources associated with development; therefore, planned monitoring for possible detections of volatile organic compounds as part of the National Water-Quality Assessment Program will emphasize areas of expanding population and development. Monitoring of volatile organic compounds is planned at National Pollutant Discharge Elimination System sites, at basic fixed surface-water sites, and in the ground-water study-unit surveys.

Texas↗
USGS2025

Petrogenesis and mineralization potential of the Bradley Peak komatiitic basalts, Wyoming Province

The ca. 2.72 Ga Bradley Peak greenstone terrane in the Wyoming Province contains spinifex- and cumulate-textured komatiitic volcanic rocks that may host Ni-Cu-PGE sulfide mineralization. New whole rock geochemistry classifies these rocks as Al-undepleted komatiitic basalts derived from a parental melt with ~17 wt. % MgO. Isotopic data (Sm-Nd, Re-Os) and REE profiles suggest a plume source and possible assimilation of juvenile footwall volcanic rocks. Calculated sulfur concentrations at sulfide saturation and low-detection PGE geochemistry indicate these magmas did not saturate a sulfide liquid resulting in sulfide mineralization. Although the Bradley Peak komatiitic basalt flows are unlikely to host magmatic sulfide mineralization, they are likely the source of Au for regional orogenic gold deposits.

Wyoming↗
USGS2025

Using peak geometry and shifts in the x-ray spectrum of carbon from electron probe microanalysis to determine thermal maturity of organic matter

During the burial of mudstones, the associated organic matter undergoes gradual thermal maturation, a key process that can influence the reactivity of organic matter during catagenesis, the formation of hydrocarbon deposits and the chemical weathering of mudstones. Conventional methods for assessing the thermal maturity of organic matter often fail to reflect the geochemical heterogeneity between individual organic phases in mudstone samples. Here, we report an alternative, non-destructive, surficial and micro-scale (analytical spot size of ~ 300 nm with about 4 μm diffusion depth for micrometre-size organic grains) method to evaluate the thermal maturity of organic matter in mudstones using the carbon K α X-ray spectrum measured by field emission-electron probe microanalyser (FE-EPMA). Using this method, we observed correlations between parameter values derived from FE-EPMA spectra, including the peak position, the peak area and the intra-sample heterogeneity of these measurements, and independently measured vitrinite/solid bitumen reflectance for a suite of mudstones, representing different age, geological context and burial depth. With the increased values in peak area and position, we identified an increase in the carbon mass fraction of organic matter and the mean nominal oxidation state of carbon approaching zero. These trends, which are consistent with aromatisation and graphitisation, provide the rationale for using FE-EPMA to estimate the thermal maturity of organic matter. To explore some of these trends in more detail, we employed time-of-flight secondary ionisation mass spectrometry, X-ray photoelectron spectroscopy and optical reflectance measurements on a subset of samples.

Geostandards and Geoanalytical Research↗
USGS2026

Continuous monitoring and temporal variability of fluorescence of dissolved organic matter in karst groundwater of the Edwards aquifer, south-central Texas, 2019–24

Widespread urbanization on the Edwards aquifer recharge zone in south-central Texas has prompted the development of new approaches and tools for evaluating the current and future status of water quality in the San Antonio and Barton Springs segments of the Edwards aquifer. The U.S. Geological Survey, in cooperation with the San Antonio Water System and the City of Austin, applied continuous monitoring of fluorescence of dissolved organic matter (fDOM) to characterize the sources and transport of dissolved organic matter and associated constituents in the Edwards aquifer. Continuous fDOM time-series data were adjusted using empirically derived temperature, turbidity, and inner-filter-effect correction factors prior to analysis and interpretation. Fully corrected fDOM time-series data from the study sites were evaluated for short- and long-term temporal variability in fDOM in the context of the hydrologic and climatic conditions that occurred during the 5-year study period to understand vulnerability of the aquifer to potential contaminants in recharge. Study results indicate that fDOM is an effective proxy for dissolved organic carbon that, in turn, is indicative of the influx of recent surface water and associated contaminants, and thus, aquifer vulnerability to those contaminants. Although other continuously monitored water-quality parameters provide insights into changes in water quality in response to varying hydrologic conditions, the quantitative relation between fDOM and dissolved organic carbon directly indicates the timing and magnitude of pulses of organic constituents derived from the land surface, whereas other water-quality parameters do not.

Texas↗
USGS2026

Diverging mineral chemistry of iron and nickel throughout Earth’s changing redox conditions reveals foundation for their evolution as protein cofactors

Iron (Fe) and nickel (Ni) were both foundational to early metabolism, yet their biological trajectories diverged as Earth’s surface redox state changed. Here, we integrate mineral chemistry network analysis, protein metal-site coordination-sphere analysis, and curated redox comparisons to test how geochemistry and metalloprotein architecture co-evolved. Mineral network analyses show broader electronegativity variation and network diversity for Fe-bearing minerals through time relative to Ni-bearing minerals. In structural analyses of protein metal centers in a combined Fe/Ni protein structure set, it is shown that Fe- and Ni-associated environments differ in amino-acid composition, hydropathy structure, and cysteine representation. The greater chemical diversity and electronegativity variation in Fe minerals mirror the higher redox and structural versatility of Fe-binding proteins. The presence of Fe in a broader range of mineral and protein environments demonstrates the chemical adaptability of the metal, from the anoxic Archean to oxidative Earth surface conditions following the Great Oxidation Event. Iron, with its broad redox potential range in Fe-oxidoreductases, has a central role in both anaerobic and aerobic metabolisms. Nickel, by contrast, is less widespread in biology. Today, Ni is predominantly employed in deeply branching anaerobic pathways and by proteins with narrower redox potential ranges. Our results show that evolutionary processes, constrained by metal chemistry, habitually utilize Fe as a redox generalist while retaining Ni in specialized roles. The divergent paths of Ni and Fe, from rocks to proteins, demonstrate the intimate relationship between planetary geochemistry and metabolic origins on Earth and suggest that Fe/Ni geochemistry may inform habitability assessments in extraterrestrial environments when interpreted within specific planetary environmental contexts.

Life↗
USGS2025

Integrated stratigraphic and geochemical analysis of organic-rich intervals of the Lewis Shale in the eastern Washakie Basin, Wyoming

Geological studies in the Cretaceous Western Interior Seaway (KWIS) in North America reveal highly variable sedimentological conditions on its western shore caused by rapidly changing sea level and detrital input during the seaway’s closure. Here we examine a 601-foot (183 meters) continuous core through the lower part of the Maastrichtian Lewis Shale in the eastern Washakie Basin, Wyoming, through integrating stratigraphic and geochemical analyses to better understand organic matter deposition and preservation during the final marine transgression within the seaway. The core penetrates eight organic-rich flooding intervals (F1-F8) and a regional condensed section, informally known as the Asquith marker. The lower portions of the core record sediment input from a southern source, likely the Sierra Madre/Park Ranges, while the upper part records sediment input from a northern source, likely the Granite Mountains. This provenance transition is supported by regional stratigraphic analysis and changes in bulk mineral and trace metal composition. The Asquith marker and early flooding surfaces are enriched in oil-prone, marine organic matter deposited under dysoxic to euxinic conditions, whereas younger flooding surfaces show increased terrigenous input and poorer preservation conditions. The Asquith marker is identified as a prime oil-prone source rock. Although younger flooding surfaces also exhibit favorable source-rock properties, their generative potential is reduced due to increased clastic and terrigenous organic matter deposition caused by regression. These results emphasize the importance of sediment source variability, organic matter preservation, and changing redox conditions to provide insight into the sediment provenance and petroleum potential of the Lewis Shale in the context of the final transgression within the KWIS.

Colorado, Wyoming↗
USGS2025

Metaproteomics and metagenomics reveal microbial pathways of organic matter degradation and methanogenesis in a marginally producing natural gas well

The expansion of natural gas production and utilization worldwide has led to the decline of many once-productive wells, eventually resulting in costly well-plugging and unused infrastructure. However, in areas like the Michigan basin, MI, where the majority of natural gas is biogenically produced, microbial communities could potentially be stimulated to generate additional methane, increasing gas supply and reducing the need to drill new wells. In this study, we performed metaproteomic, metagenomic, and geochemical analyses of Antrim Shale formation water from a marginally producing natural gas well to evaluate resident microbial community functions in the context of potential bioenergy production. Functional proteins involved in methanogenesis, degradation/catabolism (including organic matter degradation), biosynthesis, energy utilization, transmembrane transport, and stress response were among the most commonly identified groups. Three metagenome-assembled genomes (MAGs) were characterized, including Methanomicrobiaceae, Methanothrix , and Smithella . For each, the identified proteins involved in methanogenesis and the degradation of diverse organic compounds, strongly suggest their role in utilizing shale-derived organic matter. These findings provide an increased understanding of the microorganisms and their metabolisms generating natural gas in the Antrim Shale and establish a foundation for future stimulation efforts aimed at enhancing biogenic methane production in marginal gas wells.

Michigan↗
USGS2025

Time-varying rates of organic and inorganic mass accumulation in southeast Louisiana marshes: Relationships to sea-level anomalies and tropical storms

Louisiana's coastal wetlands are complex systems that require a continuous input of organic and inorganic material to keep pace with relative sea-level rise. Coastal restoration projects such as sediment diversions are being implemented to mitigate land loss and increase availability of inorganic sediment to coastal wetlands, and marshes specifically rely on organic material to build soil volume and maintain surface elevation. Interannual-to-decadal sea-level anomalies such as hurricanes can affect marsh accretion, mineral deposition, and plant productivity. In this light, complex ecogeomorphic feedback controls whether a marsh surface is sustainable or eroded/drowns. This study performs some of the first differential vertical accretion rates (VARs) and organic and inorganic mass accumulation rates (MARs) over time in SE Louisiana marshes determined from the 210 Pb Constant Rate of Supply model, coupled with standard 137 Cs VARs. These accumulation rates over the past ∼100 years were measured from a total of six brackish and salt marsh locations in Barataria Basin near the proposed Mid-Barataria Sediment Diversion. They were then related to interannual sea-surface elevations at Grand Isle, Louisiana, over the last ∼60 years and recorded hurricane activity in the delta. Results show VARs range from 0.63 cm/y to 1.69 cm/y and total MARs range from 0.11 to 0.43 g/cm 2 /y. Temporally, VARs and MARs (total, inorganic, and organic) are characterized by gradual increases in rates with decreasing age along with episodic peaks in VARs and MARs. The findings of this study indicate that no relationship occurs between sea-level anomalies and VARs or organic and inorganic MARs; however, a strong relationship appears to occur between major hurricanes to VAR and MAR contributions. Furthermore, high water content (81 ± 8%) and organic-rich soils in the sediment cores highlight the significance of belowground biomass and associated pore volume in maintaining marsh elevation in the study area.

Louisiana↗
USGS2025

Emerging investigator series: Post-wildfire sediment geochemical characterization reveals manganese reactivity and a potential link to water quality impairment in the Gallinas Creek watershed, New Mexico

Water quality post-wildfire is often impaired by increased turbidity and elevated concentrations of elements such as manganese (Mn) and iron (Fe). Precipitation events exacerbate these issues, due in part to increased erosion and transport of sediment from hillslopes to surface water. Both Mn and Fe are major redox-active elements in sediments that drive a variety of biogeochemical cycles, precipitate adsorptive phases, and can themselves be drinking water contaminants. By investigating Mn and Fe sediment geochemistry in post-wildfire sediment deposits, related water quality hazards can be assessed. To establish and strengthen this connection, we analyzed the geochemistry of sediment deposits and surface water in the Gallinas Creek watershed, New Mexico over 1.5 years post-wildfire. Analyses included particle size analysis, water extractions, sequential extractions and aqua regia extractions to determine metal partitioning in sediment deposits. Data demonstrate Mn concentrations were distributed across labile and reactive fractions, such as the exchangeable and oxyhydroxide fractions, while Fe concentrations were mainly associated with the residual fraction. Manganese concentrations in aqua regia extractions and several fractions of sequential extractions were also strongly and significantly correlated with fine-grained sediment while the same pools of Fe concentrations were not. Dissolved Mn concentrations in surface water were elevated (>50 μg L −1 ) multiple times over the 1.5 years post-wildfire, highlighting a relationship between sediment geochemistry and water quality. This work shows Mn in sediments mobilized post-wildfire has an influence on water quality and highlights how further investigation into Mn sediment redox processes and mineralogy post-wildfire can inform risk assessments and resource management.

New Mexico↗
USGS2026

Deep subsurface organic-rich shale supports abundant, diverse, and novel fungi

As Earth’s principal reservoir of organic carbon and microbial biomass, the deep subsurface hosts microorganisms capable of mobilizing this once-sequestered carbon. Contrary to standard assumptions of eukaryotic scarcity, this study documents abundant fungal communities, ranging from 4.2 × 10 3 to 6.8 × 10 3 fungal cells mL −1 , across a methane-producing organic-rich shale 247–556 meters below the surface. Although fungal:bacterial cell ratios ranged from 1:7028 to 1:713, application of biomass conversion factors developed for oceanic systems yielded a median fungal:bacterial biomass ratio of 1:4.7. 16S rRNA gene amplicons revealed bacterial and archaeal communities mirroring those found in well-characterized extremophilic, carbon-degrading environments, while sequencing of 18S rRNA gene and ITS rRNA spacer amplicons collectively identified a eukaryotic hotspot with 689 fungal OTUs across six phyla. The dominant fungal classes, Agaricomycetes and Dothideomycetes, are well-established degraders of recalcitrant carbon compounds at the surface, suggesting they may similarly contribute to organic matter degradation and ecosystem maintenance in the subsurface. Cultivation and isolation efforts yielded 205 fungal strains, including 13 candidate novel taxa, underscoring the deep subsurface as an underexplored eukaryotic habitat. Stable carbon isotopes indicate methane is predominantly generated via microbial conversion of the fossil carbon, while water isotopes suggest in situ geochemical conditions have been relatively stable since the Late Pleistocene, with subglacial recharge as a plausible mechanism for microbial introduction. Collectively, these findings suggest that fungi are underrecognized contributors to organic matter transformation and functional diversity in the deep biosphere, revealing a critical gap in our understanding of deep subsurface ecosystem processes.

Indiana, Michigan, Ohio↗