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Effects of water use and land use on streamflow and aquatic habitat in the Sudbury and Assabet River Basins, Massachusetts

Water withdrawals from surface-water reservoirs and groundwater have affected streamflow in the Sudbury and Assabet River Basins. These effects are particularly evident in the upper Sudbury River Basin, which prompted the need to improve the understanding of water resources and aquatic habitat in these basins. In 2004, the U.S. Geological Survey, in cooperation with the Massachusetts Department of Conservation and Recreation, developed a precipitation-runoff model that uses Hydrologic Simulation Program-FORTRAN (HSPF) to evaluate the effects of water use and projected future water-use and land-use change on streamflow. As part of this study, the aquatic habitat in the basins and the effects of streamflow alteration also were evaluated. Chapter 1 of the report covers the development of the HSPF model that focuses on the upper Sudbury River Basin (106 square miles) but covers the entire Sudbury and Assabet River Basins (339 square miles). The model was calibrated to an 11-year period (1993-2003) using observed or estimated streamflow at four streamgages. The model was then used to simulate long-term (1960-2004) streamflows to evaluate the effects of average 1993-2003 water use and projected 2030 water-use and land-use change over long-term climatic conditions. Simulations indicate that the average 1993-2003 withdrawals most altered streamflow relative to no withdrawals in small headwater subbasins where the ratios of mean annual withdrawals to mean annual streamflow are the highest. The effects of withdrawals are also appreciable in other parts of the upper Sudbury River Basin as a result of the perpetuation of the effects of large withdrawals in upstream reaches or in subbasins that also have a high ratio of withdrawal to streamflow. The simulated effects of potential 2030 water-use and land-use change indicate small decreases in flows as a result of increased water demands, but these flow alterations were offset as a result of decreased evapotranspiration associated with the loss of deep-rooted vegetation. Simulations of reactivating production wells near the north end of Lake Cochituate indicate pumping could substantially affect lake levels and flows at the lake outlet or in nearby reaches in the Sudbury River during periods of low flow, but the effects vary depending on the source of the water to the wells, which is largely unknown. Chapter 2 of the report covers the fish-community assessment and comparison of streamflow-setting standards for protecting aquatic habitat. The fish-community assessment indicates the main stems of the Sudbury and Assabet Rivers are dominated by macrohabitat generalists. Water temperatures recorded in seven free-flowing reaches in the upper Sudbury River Basin at three sites unaffected by withdrawals or impoundments are generally suitable for cold-water fish; however, summer temperatures often rose to a level considered critical to long-term survival of brook trout. At four sites downstream from withdrawals or reservoirs, or both, summer water temperatures were often in the upper critical range for brook trout survival. Physically and statistically based methods for determining streamflows for protecting aquatic habitat were applied at 10 selected riffle sites in the Sudbury and Assabet River Basins. Physically based methods, R2Cross and Wetted-Perimeter, use site-specific physical and hydraulic information and a one-dimensional hydraulics model, HEC-RAS, to determine flows that meet the criteria set forth by the method. The median flow that meets 2-of-3 of the R2Cross hydraulic criteria (percentage of bankfull wetted perimeter, average velocity, and mean depth) ranged from about 0.07 to 0.72 cubic feet per second per square mile (ft3/s/mi2) with an overall median of about 0.24 ft3/s/mi2; the median Wetted-Perimeter target flow ranged from about 0.10 to 0.51 ft3/s/mi2 with an overall median of about 0.25 ft3/s/mi2. Statistically based methods?Tennant, New England Aquatic Base Flow (ABF)

Scientific Investigations Report

Effects of open marsh water management on numbers of larval salt marsh mosquitoes

Open marsh water management (OMWM) is a commonly used approach to manage salt marsh mosquitoes than can obviate the need for pesticide application and at the same time, partially restore natural functions of grid-ditched marshes. OMWM includes a variety of hydrologic manipulations, often tailored to the specific conditions on individual marshes, so the overall effectiveness of this approach is difficult to assess. Here, we report the results of controlled field trials to assess the effects of two approaches to OMWM on larval mosquito production at National Wildlife Refuges (NWR). A traditional OMWM approach, using pond construction and radial ditches was used at Edwin B. Forsythe NWR in New Jersey, and a ditch-plugging approach was used at Parker River NWR in Massachusetts. Mosquito larvae were sampled from randomly placed stations on paired treatment and control marshes at each refuge. The proportion of sampling stations that were wet declined after OMWM at the Forsythe site, but not at the Parker River site. The proportion of samples with larvae present and mean larval densities, declined significantly at the treatment sites on both refuges relative to the control marshes. Percentage of control for the 2 yr posttreatment, compared with the 2 yr pretreatment, was >90% at both treatment sites.

New Jersey;Massachusetts

An automated geographic information system-based hydraulic modeling tool for developing preliminary culvert designs for stream crossings in Massachusetts

Introduction Currently (2026), many of the about 25,000 roadway crossing structures over rivers and streams in Massachusetts are undersized. Undersized culverts and bridges can be detrimental to fish and wildlife movement, habitat continuity, and the health of aquatic organisms. Undersized culverts also can lack the resiliency needed to withstand large floods, which could be worsened by potential increases in flood magnitude and frequency due to climate change. Improving culvert and bridge designs for stream crossing projects may improve aquatic organism passage, stream continuity, and resiliency during future floods by decreasing upstream overbank flooding, road flooding and erosion, and degradation of aquatic habitat. The U.S. Geological Survey (USGS), Massachusetts Department of Environmental Protection (MassDEP), and University of Massachusetts Amherst began a series of cooperative studies in July 2019 to develop an automated geographic information system (GIS) hydraulic modeling tool for preliminary culvert designs for stream crossings. The USGS plans to provide preliminary culvert designs in the web-based StreamStats application, which enables municipalities and engineers to view potential designs and related information for stream crossing replacement projects in Massachusetts. This application can (a) provide information on hydrology, hydraulics, and ecological conditions at stream crossing sites, (b) provide users with potential culvert designs to improve aquatic organism passage and flood resiliency, and (c) assist MassDEP in implementing the Massachusetts Wetlands Protection Act regulations for stream crossing projects.

Massachusetts

Ground Water Atlas of the United States: Segment 12, Connecticut, Maine, Massachusetts, New Hampshire, New York, Rhode Island, Vermont

The State of New York and the six New England States of Maine, Vermont, New Hampshire, Massachusetts, Connecticut, and Rhode Island compose Segment 12 of this Atlas (fig. 1). The seven States have a total land area of about 116,000 square miles (table 1); all but a small area in southwestern New York has been glaciated. Population in the States of Segment 12 totals about 30,408,000 (table 1) and is concentrated in southern and eastern Massachusetts, Connecticut, Rhode Island, and especially New York (fig. 1). The northern part of the segment and the mountainous areas of New York and much of New Hampshire, Vermont, and Maine are sparsely populated. The percentage of population supplied from ground-water sources during 1980 was 54 to 60 percent in Maine, New Hampshire, and Vermont (table 1). Nearly all rural, domestic, and small-community water systems obtain water from wells that are, in comparison with other sources, the safest and the least expensive to install and maintain. Where water demand is great-in the urban areas of New York, Connecticut, Massachusetts, and Rhode Island-sophisticated reservoir, pipeline, and purification systems are economically feasible and are needed to meet demands. Surface water is the principal source of supply in these four States, and ground water was used to supply only 24 to 35 percent of their population during 1980 (table 1).

Connecticut, Maine, Massachusetts, New Hampshire,

Geochemical and hydrologic controls on phosphorus transport in a sewage-contaminated sand and gravel aquifer near Ashumet Pond, Cape Cod, Massachusetts

Currently (1993), about 170 kg/yr of phosphorus discharges into Ashumet Pond on Cape Cod from a plume of sewage-contaminated ground water. Phosphorus in the plume is mobile in two distinct geochemical environments--an anoxic zone containing dissolved iron and a suboxic zone containing dissolved oxygen. Phosphorus mobility in the suboxic zone is due to saturation of available sorption sites. Phosphorus loading to Ashumet Pond may increase significantly after sewage disposal is stopped due to phosphorus desorption from sediment surfaces.

Massachusetts

Water-quality assessment of the New England coastal basins in Maine, Massachusetts, New Hampshire, and Rhode Island: Environmental settings and implications for water quality and aquatic biota

The New England Coastal Basins in Maine, Massachusetts, New Hampshire, and Rhode Island constitute one of 59 study units selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. England Coastal Basins study unit encompasses the fresh surface waters and ground waters in a 23,000 square-mile area that drains to the Atlantic Ocean. Major basins include those of the Kennebec, Androscoggin, Saco, Merrimack, Charles, Blackstone, Taunton, and Pawcatuck Rivers. Defining the environmental setting of the study unit is the first step in designing and conducting a multi-disciplinary regional water-quality assessment. The report describes the natural and human factors that affect water quality in the basins and includes descriptions of the physiography, climate, geology, soils, surface- and ground-water hydrology, land use, and the aquatic ecosystem. Although surface-water quality has greatly improved over the past 30 years as a result of improved wastewater treatment at municipal and industrial wastewater facilities, a number of water-quality problems remain. Industrial and municipal wastewater discharges, combined sewer overflows, hydrologic modifications from dams and water diversions, and runoff from urban land use are the major causes of water-quality degradation in 1998. The most frequently detected contaminants in ground water in the study area are volatile organic compounds, petroleum-related products, nitrates, and chloride and sodium. Sources of these contaminants include leaking storage tanks, accidental spills, landfills, road salting, and septic systems and lagoons. Elevated concentrations of mercury are found in fish tissue from streams and lakes throughout the study area.

Maine, Massachusetts, New Hampshire, Rhode Island

Bottom sediments on the continental shelf off the northeastern United States -- Cape Cod to Cape Ann, Massachusetts

These reconnaissance maps have been constructed to show the areal distribution of major types of bottom sediment and some of their constituents on the sea floor off Massachusetts between Cape Ann and Cape Cod (41°45'N and 42°50'N and west of 70°-00W). They are intended to serve as a guide to future detailed mapping of gravel, sand, silt clay, and organic carbon. Because sediment texture is in part a reflection of long-term hydrologic conditions, the maps will also help to infer the important sediment transport mechanisms in the area and thus they should be useful in problems relating to disposal of solid and liquid waste offshore.

Massachusetts

Use of particle tracking to improve numerical model calibration and to analyze ground-water flow and contaminant migration, Massachusetts Military Reservation, western Cape Cod, Massachusetts

A steady-state, three-dimensional flow model coupled with a particle-tracking algorithm was developed to assess the complex interaction of hydrogeologic conditions affecting ground-water flow and contaminant transport--including aquifer heterogeneities, hydrologic boundaries such as ponds and streams, ground-water withdrawals, and aquifer recharge to characterize the migration of contaminants emanating from beneath the Massachusetts Military Reservation, Cape Cod, Massachusetts. The known extent of contaminant plumes were used to assess the effects of changes in model input parameters on model-calculated water-table and pond altitudes, streamflow, and water-particle pathlines. Although changes in selected simulated hydrogeologic conditions resulted in minor changes in model-calculated water-table altitudes, pond altitudes, and streamflow, these changes had significant effects on the projection of model-calculated water-particle pathlines.

Water Supply Paper

2020 drought in New England

Below average and infrequent rainfall from May through September 2020 led to an extreme hydrologic drought across much of New England, with some areas experiencing a flash drought, reflecting its quick onset. The U.S. Geological Survey (USGS) recorded record-low streamflow and groundwater levels throughout the region. In September, the U.S. Department of Agriculture (2020) declared Aroostook County in Maine and Hillsborough and Merrimack Counties in New Hampshire as crop disaster areas. By the beginning of October, 166 community water systems and 5 municipalities in New Hampshire, more than 100 municipalities in Massachusetts, and several community water supplies in Connecticut, Maine, and Rhode Island had mandatory water restrictions in place.

Connecticut, Maine, Massachusetts, New Hampshire,

Methods for estimating selected low-flow statistics at gaged and ungaged stream sites in Massachusetts

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Conservation and Recreation, Office of Water Resources, computed selected at-site streamflow statistics at U.S. Geological Survey streamgages in and near Massachusetts and developed regional regression equations for estimating selected streamflows at ungaged stream sites in Massachusetts. Two sets of regional regression equations were developed: (1) the “mainland” equations, for mainland Massachusetts excluding the area covered by the second set, and (2) the “southeastern” equations, for the Plymouth-Carver-Kingston-Duxbury aquifer area in southeastern Massachusetts and for Cape Cod. The regression equations and at-site statistics may be used by Federal, State, and local water managers in addressing water-resources issues relevant in Massachusetts. Regional regression analyses for the mainland equations were developed to estimate the following 27 streamflow statistics: 99-, 98-, 95-, 90-, 85-, 80-, 75-, 70-, 60-, and 50-percent flow durations; monthly June, July, August, and September 90- and 50-percent flow durations; February, June, and August median of the monthly means; harmonic mean; and medians of the following annual low-flow frequency statistics: 7-day; 7-day, 2-year; 7-day, 10-year; 30-day, 2-year; and 30-day, 10-year. The analyses used 81 streamgages with minimal to no regulations in and near Massachusetts. The regression analyses determined that four basin characteristics—drainage area, combined hydrologic soils A and B, streamflow variability index, and annual mean temperature—were the only significant explanatory variables for the different mainland equations. Regional regression equations were developed for the Plymouth-Carver-Kingston-Duxbury aquifer area in southeastern Massachusetts and Cape Cod, because surface-water drainage areas and groundwater contributing areas do not always coincide in this area of the State. The regression analyses to estimate 10 flow durations from the 99th to 50th percentiles used 18 streamflow sites with some occasional minor regulations—because there are few unregulated streams in southeastern Massachusetts. The analyses determined that groundwater contributing area and storage (combined water bodies and wetlands) were the only significant explanatory variables in the southeastern equations.

Massachusetts

Effects of carbon dioxide variations in the unsaturated zone on water chemistry in a glacial-outwash aquifer

The research site at Otis Air Base, Cape Cod, Massachusetts, has been developed for hydrogeological and geochemical studies of sewage-effluent contaminated groundwater since 1982. Research of hydrologic properties, transport, and chemical and biological processes is ongoing, but the origin of background water chemistry has not been determined. The principal geochemical process giving rise to the observed background water chemistry is CO2-controlled hydrolysis of Na feldspar. Geochemical modeling demonstrated that CO2 sources could vary over the project area. Analyses of unsaturated zone gases showed variations in CO2 which were dependent on land use and vegetative cover in the area of groundwater recharge. Measurements of CO2 in unsaturated-zone gases showed that concentrations of total inorganic C in recharge water should range from about 0.035 to 1.0 mmoles/L in the vicinity of Otis Air Base. Flux of CO2 from the unsaturated zone varied for a principal land uses, ranging from 86 gC/m2/yr for low vegetated areas to 1630 gC/m2/yr for a golf course. Carbon dioxide flux from woodlands was 220 gC/m2/yr, lower than reported fluxes of 500 to 600 gC/m2/yr for woodlands in a similar climate. Carbon dioxide flux from grassy areas was 540 gC/m2/yr, higher than reported fluxes of 230 to 490 gC/m2/yr for grasslands in a similar climate.

Applied Geochemistry

Hydrogeologic framework of western Cape Cod, Massachusetts

The aquifer of western Cape Cod consists of several hydrogeologic units composed of sand, gravel, silt, and clay (fig. 1) that were deposited during the late Wisconsinan glaciation of New England. The aquifer is a shallow, unconfined hydrologic system in which ground-water flows radially outward from the apex of the ground-water mound near the center of the peninsula toward the coast (fig.2). The aquifer is the sole source of water supply for the towns of Bourne, Sandwich, Falmouth, and Mashpee, and the Massachusetts Military Reservation (MMR). Previous geologic studies summarized the characteristics and relative ages of the glacial moraines and meltwater deposits and the relation of these sediments to the extent of the ice-sheet lobes during the last glaciation of southern New England (Oldale and Barlow, 1986; Hartshorn and others, 1991). Hydrogeologic studies in western Cape Cod characterized the shallow regional ground-water-flow system (LeBlanc and others, 1986) and analyzed simulated responses of the aquifer to changes in hydrologic stresses (Guswa and LeBlanc, 1985; Barlow and Hess, 1993; Masterson and Barlow, 1994; and Masterson and others, 1996). Recent concerns about widespread ground-water contamination, especially from sources on the MMR, have resulted in extensive investigations to characterize the local hydrogeology of the aquifer near the MMR (ABB Environmental Services, 1992). Masterson and others (1996) illustrated the strong influence of geology on ground-water flow and the importance of characterizing the hydrogeology to predict the migration of the contaminant plumes beneath the MMR. This report, a product of a cooperative study between the National Guard Bureau and the U.S. Geological Survey (USGS), characterizes the regional hydrogeology of the western Cape Cod aquifer on the basis of surficial glacial geology previously described by Mather and others (1940) and Oldale and Barlow (1986), and presents a new analysis of the subsurface hydrogeology. The characterization of the regional hydrogeologic framework includes a detailed analysis of the glacial sediments, including deltaic and lacustrine deposits and their sedimentary facies; a structure-contour analysis of the transition between the shallow sand and gravel deposits and the underlying fine sand, silt, and clay deposits; and a summary of the relation between lithologic characteristics (grain size and stratigraphy) and empirically determined hydraulic-conductivity values.

Massachusetts

People and water in the Assabet River basin, eastern Massachusetts

An accounting of the inflows, outflows, and uses of water in the rapidly developing Assabet River Basin, along Interstate 495 in eastern Massachusetts, was done to quantify how people's activities alter the hydrologic system. The study identified subbasins and seasons in which outflows resulting from people's activities were relatively large percentages of total flows, and quantified the fraction of streamflow in the Assabet River that is treated wastewater. Computer models of ground-water flow were also used to test how the components of the hydrologic system, particularly streamflow, would change with future development and increased water use. Computer simulations showed that, when water use was increased to currently permitted levels, streamflows in tributaries would decrease, particularly during the low-flow period. In the Assabet River, increased wastewater discharges resulted in a slight increase in total streamflow and an increase in the fraction of streamflow in the river that is wastewater, relative to existing conditions.

Fact Sheet

Soil-vegetation correlations in the Connecticut River floodplain of Western Massachusetts

As part of a national study analyzing the relation between hydric soils and wetland vegetation, the vegetation associated with a series of known soils was sampled along the Connecticut River floodplain in Massachusetts. Weighted average and index average (presence/absence) values were calculated for vegetation using wetland ecological index values from the National List of Plant Species that Occur in Wetlands developed by the U.S. Fish and Wildlife Service and procedures developed by T. R. Wentworth and G. P. Johnson at North Carolina State University. Good correspondence between soils and vegetation was recorded with two exceptions. Two typically nonhydric soils were determined to be hydric based on vegetation analyses. Examination of the groundwater hydrology of these two soils confirmed their hydric nature. The authors suggested that one of these soils may need to be redefined and they also suggested that the assigned index values for a few species of vegetation should be reexamined. However, in general the index average values of vegetation based on published wetland index values corresponded with the hydric and nonhydric nature of soils.

Massachusetts

Simulated hydrologic responses of the Quashnet River stream-aquifer system to proposed ground-water withdrawals, Cape Cod, Massachusetts

An investigation of the Quashnet River stream- aquifer system on Cape Cod was initiated in response to concern over possible streamflow reduction and degradation of the sea-run brown trout habitat of the river resulting from proposed ground-water withdrawals. A two-layer finite-difference ground-water-flow model was developed to simulate the stream-aquifer system. Steady-state pumping rates of 0.5, 1.0, and 2.0 million gallons per day were simulated at three well sites 1,500 to 2,500 feet west of the river. No infiltration of water from the river to the aquifer was induced in any of the simulations. Maximum streamflow depletion along the river for the scenarios tested ranged from 3 to 15 percent of calculated steady-state prepumping streamflow. Mean monthly streamflow depletions determined by use of the transient model, for a constant withdrawal of 1.0 million gallons per day from a site 1,500 feet west of the river, range from 6 to 8 percent of the mean monthly streamflows measured at a gage located 0.3 miles from the mouth of the river. A particle-tracking postprocessor to the steady-state model was used to delineate contributing areas of the river and the proposed withdrawal sites. Although the simulated cone of depression produced by pumping extends beyond the river, the contributing area of the well does not include the river under any of the withdrawal schemes simulated.

Water-Resources Investigations Report

Estimated hydrologic budgets of kettle-hole ponds in coastal aquifers of southeastern Massachusetts

Kettle-hole ponds in southeastern Massachusetts are in good hydraulic connection to an extensive coastal aquifer system that includes the Plymouth-Carver aquifer system on the mainland and aquifers underlying Cape Cod. The ponds receive water from, and contribute water to, the underlying glacial aquifer; ponds also receive water from precipitation and lose water to evaporation from the pond surface. Some ponds are connected to surface-water drainage systems and receive water from or contribute water to streams or adjacent wetlands. The Massachusetts Department of Environmental Protection currently (2011) is developing Total Maximum Daily Loads of phosphorus for the freshwater ponds in the region to maintain the health of pond ecosystems; the amounts and sources of water fluxes into and out of the ponds are important factors in determining the amount of phosphorus that can be assimilated into a pond. To assist in this effort, the U.S. Geological Survey used groundwater-flow models of the coastal aquifer system to estimate hydrologic budgets-including inflows and outflows from the aquifer system and adjacent streams and wetlands, and recharge from precipitation-for 425 ponds in southeastern Massachusetts. Water fluxes through the ponds are a function of several factors, including the size, shape, and bathymetry of the pond, orientation of the pond relative to the regional hydraulic gradient, and hydrologic setting relative to the proximity of groundwater divides and discharge boundaries. Total steady-state fluxes through the ponds range from more than 3,300,000 to less than 2,000 cubic feet per day. For ponds without surface-water inlets or outlets, groundwater inflow accounts for 98 to 3 percent of total inflow; conversely, recharge onto the pond surface accounts for the remainder of inflow (between 2 and 97 percent). All natural flows from these ponds are through recharge from the pond into the aquifer. In one pond, about 94 percent of the total outflow is removed for water supply. For ponds that are connected to surface-water drainages, most inflow and outflow are through streams. Ponds that receive water from streams receive most (58 to 89 percent) of their water from those streams. Ponds that are drained by streams lose between 5 and 100 percent of their water to those streams.

Scientific Investigations Report

Simulation of the effects of ground-water withdrawals and recharge on ground-water flow in Cape Cod, Martha's Vineyard, and Nantucket Island basins, Massachusetts

The effects of changing patterns of ground-water pumping and aquifer recharge on the surface-water and ground-water hydrologic systems were determined for the Cape Cod, Martha's Vineyard, and Nantucket Island Basins. Three-dimensional, transient, ground-water-flow modelS that simulate both freshwater and saltwater flow were developed for the f1ow cells of Cape Cod which currently have large-capacity public-supply wells. Only the freshwater-flow system was simulated for the Cape Cod flow cells where public-water supply demands are satisfied by small-capacity domestic wells. Two- dimensional, finite-difference, change models were developed for Martha's Vineyard and Nantucket Island to determine the projected drawdowns in response to projected in-season pumping rates for 180 days of no aquifer recharge. Results of the simulations indicate very little change in the position of the freshwater-saltwater interface from predevelopment flow conditions to projected ground-water pumping and recharge rates for Cape Cod in the year 2020. Results of change model simulations for Martha's Vineyard and Nantucket Island indicate that the greatest impact in response to projected in-season ground-water pumping occurs at the pumping centers and the magnitude of the drawdowns are minimal with respect to the total thickness of the aquifers.

Massachusetts

Pharmaceutical compounds in Merrimack River water used for public supply, Lowell, Massachusetts, 2008-09

This report presents results of a study conducted by the U.S. Geological Survey (USGS), in cooperation with the Massachusetts Department of Environmental Protection, to determine the occurrence of 14 commonly used human-health pharmaceutical compounds and fecal-indicator bacteria in Merrimack River water used as a drinking-water source by 135,000 residents in eastern Massachusetts. The study was designed to complement the USGS National Water-Quality Assessment Program's Source Water-Quality Assessment, which identifies patterns of occurrence of 280 primarily unregulated organic wastewater contaminants in source water used by community water systems and determines whether these patterns also occur in treated drinking water prior to distribution. The study involved periodic collection and analysis of raw Merrimack River water and treated drinking water over the course of 1 year. Water samples were collected periodically without regard to flow regime or antecedent weather conditions at the Lowell Regional Water Utility's Merrimack River intake upstream from Lowell, Mass. The same parcel of water was then sampled as finished water following treatment. Despite the presence of many potential sources of contamination in the drinking-water source area, only 2 of the 14 pharmaceutical analytes were detected at reportable concentrations in the source-water samples, and these occurred in only one set of periodic samples. Acetaminophen, a nonprescription analgesic, and caffeine were detected in the September source-water samples at concentrations of 0.084 and 0.068 micrograms per liter, respectively. Three other compounds-carbamazepine, an antiepileptic; cotinine, a metabolite of nicotine; and diphenhydramine, a nonprescription antihistamine-were detected in source-water samples, but at concentrations too low to be reliably quantified. None of the 14 pharmaceuticals was found in the finished water at a reportable concentration, defined as two times the long-term detection limit used by the analytical laboratory. In addition to the pharmaceutical analyses, measurements of fecal-indicator bacteria (Escherichia coli) concentrations and several physical characteristics were made on all source-water samples. Values for these constituents were consistently within State standards. It is possible that the monthly sampling schedule missed hydrologic events that would have transported greater concentrations of sewage contaminants to the sampling site, or that the large flow volume of the river at the study site effectively diluted the contaminant signal, but it is also likely that recent efforts to separate stormwater- and wastewater-discharge systems in the reaches upstream from the Lowell Regional Water Utility have greatly reduced the potential for sewage contamination at the intake.

Scientific Investigations Report