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Characterization of the partial oxidation products of crude oil contaminating groundwater at the U.S. Geological Survey Bemidji research site in Minnesota by elemental analysis, radiocarbon dating, nuclear magnetic resonance spectroscopy, and Fourier transform ion cyclotron resonance mass spectrometry
In oil spill research, a topic of increasing attention during the last decade has been the environmental impact of the partial oxidation products that result from transformation of the petroleum in freshwater, marine, and terrestrial ecosystems. This report describes the isolation and characterization of the partial oxidation products from crude oil contaminating groundwater at the long-term U.S. Geological Survey Bemidji research site in Minnesota. As the result of a pipeline burst in August 1979, a body of light aliphatic crude oil is present from the land surface to 2 meters below the water table in a shallow sand and gravel aquifer in a remote area outside Bemidji, Minnesota, United States. Biodegradation has resulted in the formation of a plume of dissolved organic carbon (DOC) downgradient from the oil body. Groundwater has also been contaminated in an area known as the spray zone, from vertical infiltration of DOC resulting from biodegradation of oil in the soil column, and possibly from photooxidation of oil at the soil surface. The majority of DOC in the contaminated groundwater is in the form of nonvolatile organic acids (NVOAs) which represent the partial oxidation products of the crude oil constituents. The NVOAs have been classified into three fractions according to their isolation on XAD resins: hydrophobic neutrals (HPON), hydrophobic acids (HPOA), and hydrophilic acids (HPIA). These fractions of NVOAs were isolated from wells downgradient from the oil body (sampling well numbers 533, 532, 530, 515), in the spray zone (603), and from an uncontaminated well upgradient of the oil body (310) between the years 1986 and 1989, and again from wells 530 and 603 in 1998. The samples have been characterized by elemental analysis, radiocarbon dating, carbon-13 nuclear magnetic resonance spectroscopy ( 13 C NMR), and negative-mode (-) electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FTICR-MS), with a particular focus on fractions from wells 310, 530, and 603. All the characterization data indicate that the NVOAs from contaminated wells are distinguishable from the background DOC. Carbon-14 ( 14 C) ages of NVOAs from contaminated wells ranged from 3,615 to 18,985 years before the present, whereas the background DOC from the aquifer was post-bomb (post 1950). By elemental analysis, NVOAs from contaminated wells had higher sulfur but lower nitrogen contents than the background. By electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry, number average molecular weights determined from assigned molecular formulas ranged from 416 to 486 daltons for the HPOA and HPIA fractions from both background and contaminant wells. NVOAs from contaminated wells had significantly greater numbers of assigned molecular formulas containing sulfur, with elevated concentrations of the S 1 O 4-10 species in particular. Compared to the background, HPOA and HPIA fractions from contaminant wells had a broader range of double bond equivalents (DBEs) within O n compound classes (n is number of atoms). Additionally, within O n compound classes, contaminant well HPOA fractions had a greater abundance of lower n (less than eight) than the background. Contaminant well double bond equivalents versus carbon number (C # ) plots of oxygen compound classes suggest oil-derived aliphatic compounds in the range from C 12 to C 22 in HPOA and HPIA fractions and oil-derived compounds containing aromatic or saturated rings in the approximate range from C 20 to C 30 are present in HPOA fractions. The data suggest the NVOAs originate from biodegradation of several classes of C 12 and greater crude oil constituents: sulfur-containing constituents, including possibly the resins and asphaltenes; constituents containing aromatic rings substituted with methyl groups, including alkylaromatic and naph- thenoaromatic compounds, and C 12 to C 22 alkyl constituents. The overall similarities of the carbon-13 nuclear magnetic resonance spectra for the well 603 and 530 samples from the two sampling dates suggest that a steady state in the composition of the partial oxidation products in each of the two wells had been reached between 1986–1989 and 1998.
Integrating science and resource management in Tampa Bay, Florida
Tampa Bay is recognized internationally for its remarkable progress towards recovery since it was pronounced "dead" in the late 1970s. Due to significant efforts by local governments, industries and private citizens throughout the watershed, water clarity in Tampa Bay is now equal to what it was in 1950, when population in the watershed was less than one-quarter of what it is today. Seagrass extent has increased by more than 8,000 acres since the mid-1980s, and fish and wildlife populations are increasing. Central to this successful turn-around has been the Tampa Bay resource management community's long-term commitment to development and implementation of strong science-based management strategies. Research institutions and agencies, including Eckerd College, the Florida Wildlife Commission Fish and Wildlife Research Institute, Mote Marine Laboratory, National Oceanic and Atmospheric Administration, the Southwest Florida Water Management District, University of South Florida, U.S. Environmental Protection Agency, U.S. Geological Survey, local and State governments, and private companies contribute significantly to the scientific basis of our understanding of Tampa Bay's structure and ecological function. Resource management agencies, including the Tampa Bay Regional Planning Council's Agency on Bay Management, the Southwest Florida Water Management District's Surface Water Improvement and Management Program, and the Tampa Bay Estuary Program, depend upon this scientific basis to develop and implement regional adaptive management programs. The importance of integrating science with management has become fully recognized by scientists and managers throughout the region, State and Nation. Scientific studies conducted in Tampa Bay over the past 10–15 years are increasingly diverse and complex, and resource management programs reflect our increased knowledge of geology, hydrology and hydrodynamics, ecology and restoration techniques. However, a synthesis of this research and its integration into resource management has not been prepared for Tampa Bay since the mid-1980s. The need for an up-to-date synthesis of Tampa Bay science and management has resulted in the production of this document. The U.S. Geological Survey recently completed a 5-year Tampa Bay Integrated Science Study, and the Tampa Bay Estuary Program updated the Comprehensive Conservation and Management Plan for Tampa Bay in 2006. These efforts build upon results of the many research and management studies and programs summarized here.
How and why is the timing and occurrence of seasonal migrants in the Gulf of Maine changing due to climate?
Plants and animals undergo certain recurring life-cycle events, such as migrations between summer and winter habitats or the annual blooming of plants. Known as phenology, the timing of these events is very sensitive to changes in climate (and changes in one species’ phenology can impact entire food webs and ecosystems). Shifts in phenology have been described as a “fingerprint” of the temporal and spatial responses of wildlife to climate change impacts. Thus, phenology provides one of the strongest indicators of the adaptive capacity of organisms (or the ability of organisms to cope with future environmental conditions). In this study, researchers are exploring how the timing and occurrence of a number of highly migratory marine animals is changing due to a series of climatic and ecological shifts. First, using existing long-term historical data series, they will determine the direction and magnitude of how migration, abundance, or other phenological factors have changed for marine mammals, sea turtles, and fishes that migrate into the Gulf of Maine on a seasonal basis. Because marine animals are inherently difficult to detect, the team will apply dynamic occupancy models to evaluate seasonal migration patterns and habitat use across multiple habitats in the Gulf of Maine region. The project team will also synthesize regional information on a key, ecologically-important prey fish, sandlance, whose timing and abundance is a strong predictor of the occurrence and behavior of predator species targeted in this study as well as a range of other regional fish and wildlife of conservation and management concern. Results from this component of the project will identify coastal fish and wildlife species that are relatively more or less able to adapt and thus potentially vulnerable to climate change; determine the likely primary drivers of those changes; and identify data gaps and future monitoring needs. Ultimately, this information will be available and useful for regional coastal management and adaptation decisions that will allow managers to effectively plan for the future. In a second component of the project, researchers will focus specifically on changes in migration patterns of the endangered North Atlantic right whale. While shifts in the distribution and time of recurring life events are adaptive responses that may help species cope with climate impacts, they can also lead to changes in how species interact with humans. The North Atlantic right whale is one of the most endangered whale species on the planet. In the North Atlantic Ocean, ship strikes and entanglements with commercial fishing gear represent fatal threats to right whales. Recent reports suggest that North Atlantic right whale migration patterns have changed. Many researchers posit that shifts in migration are responsible for recent increases in the overlap between right whales and human activities, especially fishing. To help understand how changes in right whale movements and behaviors may overlap with ship traffic, and thus put the animals at risk of encountering vessels, we will combine right whale habitat models with ship traffic maps. The end result will be a set of maps identifying risk levels.
Surficial sediment character of the New York-New Jersey offshore continental shelf region: A GIS compilation
Broad continental shelf regions such as the New York Bight are the product of a complex geologic history and dynamic oceanographic processes, dominated by the Holocene marine transgression (>100 m sea-level rise) following the end of the last Pleistocene ice advance ~ 20,000 years ago. The area of the U.S. Exclusive Economic Zone (U.S. EEZ) territory, extending 200 nautical miles seaward from the coast, is larger than the continental U.S. and contains submerged landforms that provide a variety of natural functions and societal benefits, such as: critical habitats for fisheries, ship navigation and homeland security, and engineering activities (i.e. oil and gas platforms, pipeline and cable routes, potential wind-energy-generation sites). Some parts of the continental margins, particularly inner-continental shelf regions, also contain unconsolidated hard-mineral deposits such as sand and gravel that are regarded as potential aggregate resources to meet or augment needs not met by onshore deposits (Williams, 1992). The present distribution of surficial sediment off the northeastern United States is shaped from the deposits left by the last glaciation and reflects the cumulative effects of sediment erosion, transport, sorting, and deposition by storm and tidal processes during the Holocene rise in sea level. As a result, the sediments on the sea floor represent both an historical record of former conditions and a guide to possible future sedimentary environments. The U.S. Geological Survey (USGS) through the Coastal and Marine Geology Program, in cooperation with the University of Colorado and other partners, has compiled extant sediment character and textural data as well as other geologic information on the sea floor from all regions around the U.S. into the usSEABED data system (Reid and others, 2005; Buczkowski and others, 2006; Reid and others, 2006). The usSEABED system, which contains information on sediment grain size and lithology for more than 340,500 stations within the U.S. EEZ. has been developed and populated with data as part of the USGS Marine Aggregate Resources and Processes and the National Benthic Habitats projects in order to provide the base-line data needed to update the current maps of offshore surficial geologic character and sediment distribution. The maps are also used to characterize benthic sea floor environments important for marine ecosystems. U.S. Geological Survey, Data Series 118 (Reid and others, 2005), of the usSEABED data release series, represents the combined efforts of the USGS and several other government agencies to provide a unified resource for accessing and preserving records of U.S. east coast sea floor geologic information and sediment texture data. For this present report, we have chosen to focus on the New York-New Jersey region, an area that has been intensely studied by the USGS for many years to address many complex issues. This report illustrates the uses of the usSEABED database for GIS applications, while offering additional insight into the resources and data available from the USGS and its collaborative institutions. This report is based on data contained in U.S. Geological Survey Data Series 118 (Reid and others, 2005) and shows an assortment of example GIS products that are possible using usSEABED. All data are intended to be GIS-ready and should not require any additional cleanup, formatting, or renaming of fields in order to use the data in a Geographic Information System. This project employs the Environmental Systems Research Institute's (ESRI) ArcView™ software. Many of these maps were made as part of the ongoing USGS study to assess marine aggregate resources offshore New York and New Jersey, but these maps can serve many other purposes. The marine science community, educators, students and others are encouraged to use these data to generate GIS products for their own purposes. The objectives of the Marine Aggregate Resources and Processes project are to produce a series of new geologic maps and reports of the sea floor that will provide scientific insights into the character and geologic development of U.S. continental margins and to use these maps and information to assess the potential availability of offshore sand and gravel resources. The mapping and aggregate resource assessments are being conducted on a national scale using the usSEABED data base as described in Williams and others (2003). Potential uses for these data include: (1) defining the geological variability of the sea floor in relation to benthic habitat diversity; (2) improving our understanding of the processes that control the distribution and transport of bottom sediments and benthic habitats; (3) locating aggregate resources for beach nourishment and industrial applications; and (4) providing a detailed geospatial framework for future marine science research, monitoring, and management activities. The initial assessments are in progress for the New York Bight and Louisiana offshore areas.
Geological framework data from Long Island Sound, 1981-1990: A digital data release
Introduction Since 1980 the Coastal and Marine Geology Program of the U.S. Geological Survey and Connecticut Department of Environmental Protection have conducted a joint program of cooperative geologic research in Long Island Sound and its vicinity. As part of this program, a highly successful regional-scale study of the geologic framework was completed. Reconnaissance high-resolution seismic reflection data were collected and used to establish the basic stratigraphy within the Sound and to map the major geologic units; field verification of the geologic interpretations of the seismic profiles was primarily accomplished with vibratory cores. These interpretations were in turn used to produce basin-wide syntheses of the late Quaternary depositional history. Unfortunately, the original seismic records and core logs were generated only in analog form. These unique paper documents, which are still under demand for industrial applications and academic research, are fragile and have become ragged from frequent use. The purpose of this report is to preserve these data by converting the seismic profiles, core descriptions, and ancillary reports into digital form, and to organize these files into a product that can be more readily accessed and disseminated. Not all of the existing high-resolution seismic-reflection surveys, collected in Long Island Sound through cooperatives with the U.S. Geological Survey and the Connecticut Department of Environmental Protection, have been incorporated into this report. These surveys, whose records are still in need of preprocessing and annotation, generally cover smaller areas along the Connecticut coast and were originally intended to provide additional detail to the larger, more regional data sets presented herein. The digital release of the omitted data sets is planned as part of a future product.
Isothermal recombinant polymerase amplification and CRIPSR (CAS12A) assay detection of Renibacterium salmoninarum as an example for wildlife pathogen detection in environmental DNA samples
Improving rapid detection methods for pathogens is important for research as we collectively aim to improve the health of ecosystems globally. In the northern hemisphere, the success of salmon ( Oncorhynchus spp.) populations is vitally important to the larger marine, aquatic, and terrestrial ecosystems they inhabit. This has led to managers cultivating salmon in hatcheries and aquaculture to bolster their populations, but young salmon face many challenges, including diseases such as bacterial kidney disease (BKD). Early detection of the BKD causative agent, Renibacterium salmoninarum , is useful for managers to avoid outbreaks in hatcheries and aquaculture stocks to enable rapid treatment with targeted antibiotics. Isothermal amplification and CRIPSR-Cas12a systems may enable sensitive, relatively rapid, detection of target DNA molecules from environmental samples compared to quantitative PCR (qPCR) and culture methods. We used these technologies to develop a sensitive and specific rapid assay to detect R. salmoninarum from water samples using isothermal recombinase polymerase amplification (RPA) and an AsCas12a RNA-guided nuclease detection. The assay was specific to R. salmoninarum (0/10 co-occurring or closely related bacteria detected) and sensitive to 0.0128 pg/µL of DNA (approximately 20–40 copies/µL) within 10 min of Cas activity. This assay successfully detected R. salmoninarum environmental DNA in 14/20 water samples from hatcheries with known quantification for the pathogen via previous qPCR (70% of qPCR-positive samples). The RPA-CRISPR/AsCas12a assay had a limit of detection (LOD) of >10 copies/µL in the hatchery water samples and stochastic detection below 10 copies/µL, similar to but slightly higher than the qPCR assay. This LOD enables 37 C isothermal detection, potentially in the field, of biologically relevant levels of R. salmoninarum in water. Further research is needed to develop easy-to-use, cost-effective, sensitive RPA/CRISPR-AsCas12a assays for rapidly detecting low concentrations of wildlife pathogens in environmental samples.
USGS Alaska Tissue Archival Projects: An update on FY02 activities
The banking of environmental specimens under cryogenic conditions for future retrospective analysis has been recognized for many years as an important part of environmental monitoring programs. Since 1987, the Alaska Marine Mammal Tissue Archival Project (AMMTAP) has been collecting tissue samples from marine mammals for archival in the National Biomonitoring Specimen Bank (NBSB) at the National Institute of Standards and Technology (NIST) in Gaithersburg, Maryland, USA. The USGS, Alaska Biological Science Center (ABSC), the NOAA Fisheries, Office of Protected Resources (NMFS), and the NIST conduct this partnership project, which began under the Mineral Management Service (MMS) Outer Continental Shelf Environmental Assessment Program. MMS remains the primary client agency for the AMMTAP providing programmatic guidance and review. The purpose of the project is to collect tissue samples from Alaska marine mammals and to store these specimens under the best conditions so that they can be analyzed for environmental contaminants and other constituents. A substantial part of the sample collection is from Arctic species and, since most of the animals sampled are from Alaska Native subsistence harvests, the project relies on cooperation and collaboration with several Alaska Native organizations and local governmental agencies. Although a substantial amount of recent research has been conducted on contaminants in Alaskan marine mammals, few data exists on colonial seabirds nesting in Alaska. Like marine mammals, seabirds are an important group of upper trophic level marine organisms with a potential for accumulating lipophilic contaminants and are identified by MMS as species of interest for monitoring activities. More than 95% of the seabirds breeding in the continental United States nest at colonies in the Bering and Chukchi seas and Gulf of Alaska (see USFWS 1992). Realizing the value of colonial seabirds in environmental monitoring and the lack of recent data from Alaskan seabird colonies, the U.S. Fish and Wildlife Service Alaska Maritime National Wildlife Refuge (USFWS-AMNWR), the U.S. Geological Survey Biological Resources Division (USGS-BRD), and the National Institute of Standards and Technology (NIST) initiated the Seabird Tissue Archival and Monitoring Project (STAMP) in 1998. The project was designed as a 100-year-long program to monitor long-term trends in environmental quality by collecting eggs at nesting colonies using standardized protocols, banking the egg contents under conditions that ensure chemical stability during long-term (decadal) storage, and analyzing subsamples of the stored material to establish baseline levels for persistent bioaccumulative contaminants (e.g., chlorinated pesticides, PCBs, mercury).
Marine fog: a review
The objective of this review is to discuss physical processes over a wide range of spatial scales that govern the formation, evolution, and dissipation of marine fog. We consider marine fog as the collective combination of fog over the open sea along with coastal sea fog and coastal land fog. The review includes a history of sea fog research, field programs, forecasting methods, and detection of sea fog via satellite observations where similarity in radiative properties of fog top and the underlying sea induce further complexity. The main thrust of the study is to provide insight into causality of fog including its initiation, maintenance, and destruction. The interplay between the various physical processes behind the several stages of marine fog is among the most challenging aspects of the problem. An effort is made to identify this interplay between processes that include the microphysics of fog formation and maintenance, the influence of large-scale circulation and precipitation/clouds, radiation, turbulence (air-sea interaction), and advection. The environmental impact of marine fog is also addressed. The study concludes with an assessment of our current knowledge of the phenomenon, our principal areas of ignorance, and future lines of research that hold promise for advances in our understanding.
Marine geophysical data collected in a shallow back-barrier estuary, Barnegat Bay, New Jersey
In 2011, the U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection, began a multidisciplinary research project to better understand the water quality in Barnegat Bay, New Jersey. This back-barrier estuary is experiencing degraded water quality, algal blooms, loss of seagrass, and increases in oxygen stress, macroalgae, stinging nettles, and brown tide. The spatial scale of the estuary and the scope of challenges within it necessitate a multidisciplinary approach that includes establishing the regional geology and the estuary’s physical characteristics and modeling how the estuary’s morphology interacts to affect its water quality. This report presents the data collected during this project for use in understanding the morphology and the distribution of sea-floor and sub-sea-floor sediments within Barnegat Bay, describes the methods used to collect and process those data, and includes links to the final processed datasets. These data can be used by scientists to understand the links between geomorphology, geologic framework, sediment transport, and estuarine water quality and circulation.
Mapping the seafloor geology offshore of Massachusetts
Geologic and bathymetric maps help us understand the evolutionary history of the Massachusetts coast and the processes that have shaped it. The maps show the distribution of bottom types (for example, bedrock, gravel, sand, mud) and water depths over large areas of the seafloor. In turn, these two fundamental parameters largely determine the species of flora and fauna that inhabit a particular area. Knowledge of bottom types and water depths provides a framework for mapping benthic habitats and managing marine resources. The need for coastal–zone mapping to inform policy and management is widely recognized as critical for mitigating hazards, creating resource inventories, and tracking environmental changes (National Research Council, 2004; U.S. Commission on Ocean Policy, 2004).
Growth rates for immature Kemp’s ridley sea turtles from a foraging area in the northern Gulf of Mexico
Examining vital rates helps clarify how environmental characteristics, biological resources and human activities affect population growth. Carapace lengths were gathered for 241 Kemp’s ridley Lepidochelys kempii sea turtles that were marked and recaptured (n = 23) between 2011 and 2019 at a foraging location in northwest Florida, USA. There was a strong correlation between length, width and weight of captured turtles. Mean ± SD size of all captured turtles was 36.6 ± 7.6 cm. Mean recapture interval was 499 ± 475.4 d. Straight-line carapace lengths at initial capture ranged from 20.6 to 53.3 cm. Growth rates from 0.21 to 12.44 cm yr -1 (mean 3.15 ± 2.64 cm) were documented and were greatest for turtles in the 20.0-29.9 cm size class. Growth rates from northwest Florida were slower than those reported from other sites in the Gulf of Mexico. These results indicate that Kemp’s ridleys recruit from oceanic habitat into coastal bays in northwest Florida, where they remain until they reach adulthood. However, some adult-sized turtles may continue to use the nearshore habitat. A gradient in growth rates in the Gulf of Mexico may occur from faster growth in the south to slower growth in the north. Fine-scale variations in resources and environmental conditions may drive regional differences in growth rates, and research on what drives these differences is needed.
Assessing the population consequences of disturbance and climate change for the Pacific walrus
Climate change and anthropogenic disturbance are increasingly affecting wildlife at a global scale. Predicting how varying types and degrees of disturbance may interact to influence population dynamics is a key management challenge. Population consequences of disturbance (PCoD) models provide a framework to link effects of anthropogenic disturbance on an individual’s behavior and physiology to population-level changes. In the present study, we develop a Pacific walrus ( Odobenus rosmarus divergens ) PCoD model to encompass the population-level effects of both anthropogenic disturbance and climate change. As the Arctic becomes increasingly ice-free, walruses spend more time at coastal (vs. ice-based) haulouts, from which they must expend more energy to reach foraging areas and where they have an elevated risk of mortality. Concurrently, sea ice loss is increasing the anthropogenic footprint in the Arctic (e.g. fisheries, shipping, energy exploration), which creates additional disturbance. We applied the PCoD model to 4 scenarios (ranging from optimistic to pessimistic) which incorporate different global sea ice model projections along with varying degrees of anthropogenic disturbance. All scenarios indicated a decline in Pacific walrus vital rates by the end of the 21st century, but our results demonstrated that the intensity of that decline could be mitigated by global efforts to reduce carbon emissions, along with local management and conservation efforts to protect important coastal haulouts and foraging grounds. In summary, we introduce a flexible PCoD modeling framework in a novel context which will prove useful to researchers studying species threatened by rapid environmental change.
Core descriptions, core photographs, physical property logs and surface textural data of sediment cores recovered from the continental shelf of the Monterey Bay National Marine Sanctuary during the research cruises M-1-95-MB, P-2-95-MB, and P-1-97-MB
In response to the 1992 creation of the Monterey Bay National Marine Sanctuary (MBNMS), the United States Geological Survey (USGS) initiated a multiyear investigation of the Sanctuary continental margin. As part of the investigative effort, this report summarizes the shipboard procedures, subsequent laboratory analyses, and data results from three seafloor sampling cruises conducted on the continental shelf between Monterey peninsula, CA and San Francisco, CA. The cruises were conducted in 1995 aboard the NOAA Ship McArthur (M-1-95-MB) and in 1995 and 1997 aboard the R/V Point Sur (P-2-95-MB and P-1-97-MB). Scientists and representatives from the Environmental Protection Agency (EPA), the National Oceanic and Atmospheric Administration (NOAA), the California Department of Fish and Game (CDFG), the University of California Santa Cruz (UCSC), and the San Jose State University Moss Landing Marine Laboratory (SJSU-MLML) supported the research effort. In this report we present sediment descriptions, sediment textural data, physical property logs, station metadata, and photographs of subcores from a total of three hundred and eighty four sample stations. At these sites either a box corer, MultiCore™r, grab sampler or a combination of these sampling devices were used to collect the sea floor sediments. The report is presented in an interactive web-based format with each mapped core station linked to the corresponding description and photo, and to a spreadsheet of surface texture and other sampling data.
Ocean carbon and biogeochemistry scoping workshop on terrestrial and coastal carbon fluxes in the Gulf of Mexico, St. Petersburg, FL, May 6-8, 2008
Despite their relatively small surface area, ocean margins may have a significant impact on global biogeochemical cycles and, potentially, the global air-sea fluxes of carbon dioxide. Margins are characterized by intense geochemical and biological processing of carbon and other elements and exchange large amounts of matter and energy with the open ocean. The area-specific rates of productivity, biogeochemical cycling, and organic/inorganic matter sequestration are high in coastal margins, with as much as half of the global integrated new production occurring over the continental shelves and slopes (Walsh, 1991; Doney and Hood, 2002; Jahnke, in press). However, the current lack of knowledge and understanding of biogeochemical processes occurring at the ocean margins has left them largely ignored in most of the previous global assessments of the oceanic carbon cycle (Doney and Hood, 2002). A major source of North American and global uncertainty is the Gulf of Mexico, a large semi-enclosed subtropical basin bordered by the United States, Mexico, and Cuba. Like many of the marginal oceans worldwide, the Gulf of Mexico remains largely unsampled and poorly characterized in terms of its air-sea exchange of carbon dioxide and other carbon fluxes. In May 2008, the Ocean Carbon and Biogeochemistry Scoping Workshop on Terrestrial and Coastal Carbon Fluxes in the Gulf of Mexico was held in St. Petersburg, FL, to address the information gaps of carbon fluxes associated with the Gulf of Mexico and to offer recommendations to guide future research. The meeting was attended by over 90 participants from over 50 U.S. and Mexican institutions and agencies. The Ocean Carbon and Biogeochemistry program (OCB; http://www.us-ocb.org/) sponsored this workshop with support from the National Science Foundation, the National Oceanic and Atmospheric Administration, the National Aeronautics and Space Administration, the U.S. Geological Survey, and the University of South Florida. The goal of the workshop was to bring together researchers from multiple disciplines studying terrestrial, aquatic, and marine ecosystems to discuss the state of knowledge in carbon fluxes in the Gulf of Mexico, data gaps, and overarching questions in the Gulf of Mexico system. The discussions at the workshop were intended to stimulate integrated studies of marine and terrestrial biogeochemical cycles and associated ecosystems that will help to establish the role of the Gulf of Mexico in the carbon cycle and how it might evolve in the face of environmental change. The information derived from the plenary sessions, questions, and recommendations formulated by the participants will drive future research projects. Further discussion of carbon dynamics is needed to address scales of variability, the infrastructure required for study, and the modeling framework for cross-system integration. During the workshop, participants discussed and provided a number of priorities and recommendations, which are listed on p. 2 of the report. Participants recognized that the key to understanding the Gulf of Mexico system requires international collaboration with scientists from countries adjacent to the Gulf of Mexico. Improved collaboration across existing research community boundaries will be critical and should be encouraged by the funding agencies.
Nearshore single-beam bathymetry data collected in 2015, Dauphin Island, Alabama
Dauphin Island, Alabama, is a barrier island located in the northern Gulf of Mexico that supports local residences, tourism, commercial infrastructure, and historic Fort Gaines. During the past decade, Dauphin Island was affected by several major hurricanes—Hurricanes Ivan (2004), Katrina (2005), and Isaac (2012)—and storms, along with sea-level rise, continue to present a threat to island stability. State and Federal managers are using a scientific approach to identify, formulate, and implement a long-term plan to provide restoration options for Dauphin Island, thereby helping increase its resilience against future storms and sea-level rise. Island morphology, including current bathymetry and shoreline data, is one scientific domain being investigated in an effort to produce a comprehensive restoration plan funded by an interagency grant from the National Fish and Wildlife Foundation Gulf Environmental Benefit Fund . In August 2015, the U.S. Geological Survey ( USGS ) St. Petersburg Coastal and Marine Science Center ( SPCMSC ), in cooperation with the U.S. Army Corps of Engineers at the U.S. Army Engineer Research and Development Center, Mobile District, and the State of Alabama, conducted bathymetric surveys of the nearshore waters surrounding Dauphin Island. This report provides a detailed methodology for the data acquisition and post-processing of 1,165-line kilometers (km) of single-beam bathymetry data collected under the USGS–SPCMSC Alabama Barrier Island Restoration Study . These data were acquired and processed under USGS field activity number 2015–326–FA . Data are provided in three datums: (1) the International Terrestrial Reference Frame of 2000, ellipsoid height (from –47.04 meters (m) to –29.36 m); (2) the North American Datum of 1983, CORS96 realization (NAD83 (CORS96)) horizontal, and the North American Vertical Datum 1988 GEOID12A vertical (from –0.24 m to –17.33 m); and (3) NAD83 (CORS96) horizontal, and mean lower low water vertical (from –0.12 m to –17.93 m). The x,y,z point datasets, trackline shapefiles, digital and handwritten Field Activity Collection Systems logs, one 50-m digital elevation model, and formal Federal Geographic Data Committee metadata are obtainable from the Data Downloads page or the associated USGS data release .
Assessing environmental change associated with early Eocene hyperthermals in the Atlantic Coastal Plain, USA
Eocene transient global warming events (hyperthermals) can provide insight into a future warmer world. While much research has focused on the Paleocene–Eocene Thermal Maximum (PETM), hyperthermals of a smaller magnitude can be used to characterize climatic responses over different magnitudes of forcing. This study identifies two events, namely the Eocene Thermal Maximum 2 (ETM2 and H2), in shallow marine sediments of the Eocene-aged Salisbury Embayment of Maryland, based on magnetostratigraphy, calcareous nannofossil, and dinocyst biostratigraphy, as well as the recognition of negative stable carbon isotope excursions (CIEs) in biogenic calcite. We assess local environmental change in the Salisbury Embayment, utilizing clay mineralogy, marine palynology, δ 18 O of biogenic calcite, and biomarker paleothermometry (TEX 86 ). Paleotemperature proxies show broad agreement between surface water and bottom water temperature changes. However, the timing of the warming does not correspond to the CIE of the ETM2 as expected from other records, and the highest values are observed during H2, suggesting factors in addition to p CO 2 forcing have influenced temperature changes in the region. The ETM2 interval exhibits a shift in clay mineralogy from smectite-dominated facies to illite-rich facies, suggesting hydroclimatic changes but with a rather dampened weathering response relative to that of the PETM in the same region. Organic walled dinoflagellate cyst assemblages show large fluctuations throughout the studied section, none of which seem systematically related to CIE warming. These observations are contrary to the typical tight correspondence between climate change and assemblages across the PETM, regionally and globally, and ETM2 in the Arctic Ocean. The data do indicate very warm and (seasonally) stratified conditions, likely salinity-driven, across H2. The absence of evidence for strong perturbations in local hydrology and nutrient supply during ETM2 and H2, compared to the PETM, is consistent with the less extreme forcing and the warmer pre-event baseline, as well as the non-linear response in hydroclimates to greenhouse forcing.
Moderate-resolution sea surface temperature data for the nearshore North Pacific
Coastal sea surface temperature (SST) is an important environmental characteristic in determining the suitability of habitat for nearshore marine and estuarine organisms. This publication describes and provides access to an easy-to-use coastal SST dataset for ecologists, biogeographers, oceanographers, and other scientists conducting research on nearshore marine habitats or processes. The data cover the Temperate Northern Pacific Ocean as defined by the 'Marine Ecosystems of the World' (MEOW) biogeographic schema developed by The Nature Conservancy. The spatial resolution of the SST data is 4-km grid cells within 20 km of the shore. The data span a 29-year period - from September 1981 to December 2009. These SST data were derived from Advanced Very High Resolution Radiometer (AVHRR) instrument measurements compiled into monthly means as part of the Pathfinder versions 5.0 and 5.1 (PFSST V50 and V51) Project. The processing methods used to transform the data from their native Hierarchical Data Format Scientific Data Set (HDF SDS) to georeferenced, spatial datasets capable of being read into geographic information systems (GIS) software are explained. In addition, links are provided to examples of scripts involved in the data processing steps. The scripts were written in the Python programming language, which is supported by ESRI's ArcGIS version 9 or later. The processed data files are also provided in text (.csv) and Access 2003 Database (.mdb) formats. All data except the raster files include attributes identifying realm, province, and ecoregion as defined by the MEOW classification schema.