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Geochemistry of oceanic igneous rocks - Ridges, islands, and arcs - With emphasis on manganese, scandium, and vanadium

A database on a number of elements in oceanic volcanic rocks is presented, including the principal major-element oxides-SiO 2 , TiO 2 , Al 2 O 3 , Fe 2 O 3 (T), MnO, MgO, CaO, Na 2 O, K 2 O, and P 2 O 5 (where T refers to total iron)–and the trace elements–Ba, Ce, Cr, Cu, Ni, Sc, Sr, V, Pb (mainly by isotope dilution), Yb, Zn, and Zr. Interpretations are given for transition metals, with emphasis on Mn, Sc, and V, in order to determine the concentration of the elements in primitive melts and assess their trends in magmatic differentiation. Transition metals are not enriched in plagioclase, so all are incompatible with pure plagioclase removal–that is, they become enriched in the melt. Both Cr and Ni are known to be highly compatible with olivine separation-i.e., they are depleted in the melt early in differentiation. Also, Sc is compatible with clinopyroxene (Cpx) removal from the melt and is depleted by separation of Cpx. Copper does not fit well in any of the principal silicates, but Cu, like Ni, is greatly enriched in sulfides that may remain in the source or separate from the magma. Decreasing Ni abundances and increasing Cu contents during differentiation are a sign of olivine separation. In the analysis presented herein, V–in the absence of Cpx separation–is found to behave remarkably like the moderately incompatible element Zn, and these two elements add to the list of element pairs of similar incompatibility whose ratios are insensitive to differentiation and to submarine weathering as well. Both are enhanced in titanomagnetite, so both would be compatible during titanomagnetite separation. When Cpx separates, however, V becomes compatible like Sc, but Zn remains incompatible. Thus, decreasing V (and Sc) contents and increasing Zn contents during differentiation are a sign of Cpx separation. Manganese often behaves much like Zn and therefore is moderately incompatible, but Mn is less compatible than Zn and V in titanomagnetite. Thus, decreasing Zn and V with increasing Mn is an indication of titanomagnetite removal. Dual compatible and incompatible trends with differentiation are found chiefly for Cu, Sc, and Sr. Distinguishing mid-ocean ridge basalts (MORB), oceanic-island volcanic rocks (OIV), and island-arc volcanic rocks (IAV) may be accomplished by plots of Ce/Yb versus Ba/Ce, where OIV plot to higher values of Ce/Yb than do MORB, and IAV data plot to higher values of Ba/Ce than do those of MORB. These ratios do not seem to be significantly affected by submarine weathering.

International Geology Review↗

The eruptive history, magmatic evolution, and influence of glacial ice at long-lived Akutan volcano, eastern Aleutian Islands, Alaska, USA

New 40 Ar/ 39 Ar and whole-rock geochemical data are used to develop a detailed eruptive chronology for Akutan volcano, Akutan Island, Alaska, USA, in the eastern Aleutian island arc. Akutan Island (166°W, 54.1°N) is the site of long-lived volcanism and the entire island comprises volcanic rocks as old as 3.3 Ma. Our current study is on the 225 km 2 western half of the island, where our results show that the focus of volcanism has shifted over the last ∼700 k.y., and that on occasion, multiple volcanic centers have been active over the same period, including within the Holocene. Incremental heating experiments resulted in 56 40 Ar/ 39 Ar plateau ages and span 2.3 Ma to 9.2 ka. Eruptive products of all units are primarily tholeiitic and medium-K, and range from basalt to dacite. Rare calc-alkaline lavas show evidence suggesting their formation via mixing of mafic and evolved magmas, not via crystallization-derived differentiation through the calc-alkaline trend. Earliest lavas are broadly dispersed and are almost exclusively mafic with high and variable La/Yb ratios that are likely the result of low degrees of partial mantle melting. Holocene lavas all fall along a single tholeiitic, basalt-to-dacite evolutionary trend and have among the lowest La/Yb ratios, which favors higher degrees of mantle melting and is consistent with the increased magma flux during this time. A suite of xenoliths, spanning a wide range of compositions, are found in the deposits of the 1.6 ka caldera-forming eruption. They are interpreted to represent completely crystallized liquids or the crystal residuum from tholeiitic fractional crystallization of the active Akutan magma system. The new geochronologic and geochemical data are used along with existing geodetic and seismic interpretations from the island to develop a conceptual model of the active Akutan magma system. Collectively, these data are consistent with hot, dry magmas that are likely stored at 5−10 km depth prior to eruption. The prolonged eruptive activity at Akutan has also allowed us to evaluate patterns in lava-ice interactions through time as our new data and observations suggest that the influence of glaciation on eruptive activity, and possible magma composition, is more pronounced at Akutan than has been observed for other well-studied Aleutian volcanoes to the west.

Alaska↗

A lithologic-tectonic framework for the metallogenic provinces of California

The lithologic-tectonic framework of California developed principally during Mesozoic time when various terranes of oceanic crust and island-arc crust were accreted to older sialic crust, resulting in westward growth of the continent. Emplacement of great batholithic masses of granitoid rocks cutting all these crustal types also took place during the Mesozoic period. The discrete tectonostratigraphic terranes that resulted from these events and subsequent Tertiary and Quaternary volcanic events are characterized by specific types of metallic mineral deposits or, in some terranes, by the virtual absence of deposits. Lead-silver-zinc replacement-type deposits are common in the Paleozoic carbonate terrane in the eastern part of the state and occur sporadically elsewhere in the miogeoclinal and cratonal terranes but are absent from the oceanic and island-arc terranes. The vast majority of contact metasomatic tungsten deposits, including all the large ones, are in pendants of miogeoclinal rocks in the Sierra Nevada batholith, but the important Atolia deposits reside in granitoid rocks that invade oceanic terrane. Molybdenum distribution closely follows that of tungsten. All the large contact metasomatic iron deposits in California are in craton and miogeoclinal terranes, but sparse small deposits of this type also occur in island-arc terranes of the northern Sierra Nevada and eastern Klamath Mountains. Lode gold deposits, although widely scattered, show a marked preference for oceanic and island-arc terranes that have been invaded by granitoid plutons. All the major deposits, including late Tertiary bonanza deposits such as Bodie, are in such terranes. It appears that magmatic processes were responsible for mobilizing and transporting the gold, but the metal was perhaps derived from the eugeosynclinal rocks, notably the mafic volcanics. Most mercury deposits are found in the Coast Ranges, where they commonly occur in silica-carbonate rock, an alteration product of serpentinite. The deposits appear to be spatially related to the Coast Range thrust, and the source of the mercury may have been sedimentary rocks of the underlying Franciscan assemblage. Epigenetic mineralization occurred at several different times during the Mesozoic, and again during Miocene and Pliocene time. The timing of mineralization events and the distribution of various deposit types indicate that no broad-scale zoning of epigenetic deposits exists around the Sierra Nevada batholith.Syngenetic deposits are represented mainly by massive sulfides, chert-associated manganese, and chromite. The massive sulfide deposits, with one exception, are restricted to island-arc terranes, and nearly all of these deposits are in silicic volcanic rocks. They are interpreted to be syngenetic with the enclosing rocks, although some redistribution of metals may have occurred after the original deposition. The deposits occur in volcanic sequences of at least five different ages ranging from Early Devonian to Late Jurassic or Early Cretaceous and, along with their enclosing rocks, were probably formed at some distance from their present sites. Chert-associated manganese deposits occur mainly in exotic blocks of oceanic crust in melange and probably formed in fairly deep ocean environments. Chromite is confined to ultramafic rock, much of which occupies suture zones separating various accreted terranes.

Economic Geology↗

Uranium-Lead Zircon Ages and Sr, Nd, and Pb Isotope Geochemistry of Selected Plutonic Rocks from Western Idaho

Across the Salmon River suture in western Idaho, where allochthonous Permian to Cretaceous oceanic rocks are juxtaposed against Proterozoic North American rocks, a wide variety of plutonic rocks are exposed. Available data indicate much variation in composition, source, and structural state of these plutons. The plutonic rocks were long described as the western border zone of the Cretaceous Idaho batholith but limited pre-existing age data indicate more complicated origins. Because the affinity and age of the plutonic rocks cannot be reliably determined from field relations, TIMS U-Pb dating in conjunction with Sr, Nd, and Pb isotopic studies of selected plutons across the suture in western Idaho were undertaken. The data indicate three general groups of plutons including (1) those that intruded the island arc terranes during the Triassic and Jurassic, those that intruded near the western edge of oceanic rocks along the suture in the Early Cretaceous, and the plutons of the Idaho batholith that intruded Proterozoic North American rocks in the Late Cretaceous. Plutons that intruded Proterozoic North American rocks commonly include xenocrystic zircons and in several cases, ages could not be determined. The least radiogenic Sr and most radiogenic Nd are found among the Blue Mountains superterrane island arc samples. Suture-zone plutons have isotopic characteristics that span the range between Idaho batholith and island arc samples but mostly follow island arc signatures. Plutons of the Idaho batholith have the most radiogenic initial Pb and Sr ratios and the least radiogenic Nd of the samples analyzed.

Open-File Report↗

Forearc structure beneath southwestern British Columbia: A three-dimensional tomographic velocity model

This paper presents a three-dimensional compressional wave velocity model of the forearc crust and upper mantle and the subducting Juan de Fuca plate beneath southwestern British Columbia and the adjoining straits of Georgia and Juan de Fuca. The velocity model was constructed through joint tomographic inversion of 50,000 first-arrival times from earthquakes and active seismic sources. Wrangellia rocks of the accreted Paleozoic and Mesozoic island arc assemblage underlying southern Vancouver Island in the Cascadia forearc are imaged at some locations with higher than average lower crustal velocities of 6.5-7.2 km/s, similar to observations at other island arc terranes. The mafic Eocene Crescent terrane, thrust landward beneath southern Vancouver Island, exhibits crustal velocities in the range of 6.0-6.7 km/s and is inferred to extend to a depth of more than 20 km. The Cenozoic Olympic Subduction Complex, an accretionary prism thrust beneath the Crescent terrane in the Olympic Peninsula, is imaged as a low-velocity wedge to depths of at least 20 km. Three zones with velocities of 7.0-7.5 km/s, inferred to be mafic and/or ultramafic units, lie above the subducting Juan de Fuca plate at depths of 25-35 km. The forearc upper mantle wedge beneath southeastern Vancouver Island and the Strait of Georgia exhibits low velocities of 7.2-7.5 km/s, inferred to correspond to ???20% serpentinization of mantle peridotites, and consistent with similar observations in other warm subduction zones. Estimated dip of the Juan de Fuca plate beneath southern Vancouver Island is ???11??, 16??, and 27?? at depths of 30, 40, and 50 km, respectively. Copyright 2005 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

Geophysical modeling of the northern Appalachian Brompton-Cameron, Central Maine, and Avalon terranes under the New Jersey Coastal Plain

A regional terrane map of the New Jersey Coastal Plain basement was constructed using seismic, drilling, gravity and magnetic data. The Brompton-Cameron and Central Maine terranes were coalesced as one volcanic island arc terrane before obducting onto Laurentian, Grenville age, continental crust in the Taconian orogeny [Rankin, D.W., 1994. Continental margin of the eastern United States: past and present. In: Speed, R.C., (Ed.), Phanerozoic Evolution of North American Continent-Ocean Transitions. DNAG Continent-Ocean Transect Volume. Geological Society of America, Boulder, Colorado, pp. 129-218]. Volcanic island-arc rocks of the Avalon terrane are in contact with Central Maine terrane rocks in southern Connecticut where the latter are overthrust onto the Brompton-Cameron terrane, which is thrust over Laurentian basement. Similarities of these allochthonous island arc terranes (Brompton-Cameron, Central Maine, Avalon) in lithology, fauna and age suggest that they are faulted segments of the margin of one major late Precambrian to early Paleozoic, high latitude peri-Gondwana island arc designated as "Avalonia", which collided with Laurentia in the early to middle Paleozoic. The Brompton Cameron, Central Maine, and Avalon terranes are projected as the basement under the eastern New Jersey Coastal Plain based on drill core samples of metamorphic rocks of active margin/magmatic arc origin. A seismic reflection profile across the New York Bight traces the gentle dipping (approximately 20 degrees) Cameron's Line Taconian suture southeast beneath allochthonous Avalon and other terranes to a 4 sec TWTT depth (approximately 9 km) where the Avalonian rocks are over Laurentian crust. Gentle up-plunge (approximately 5 degrees) projections to the southwest bring the Laurentian Grenville age basement and the drift-stage early Paleozoic cover rocks to windows in Burlington Co. at approximately 1 km depth and Cape May Co. at approximately 2 km depths. The antiformal Shellburne Falls and Chester domes and Chain Lakes-Pelham dome-Bronson Hill structural trends, and the synformal Connecticut Valley-Gaspe structural trend can be traced southwest into the New Jersey Coastal Plain basement. A Mesozoic rift basin, the "Sandy Hook basin", and associated eastern boundary fault is identified, based upon gravity modeling, in the vicinity of Sandy Hook, New Jersey. The thickness of the rift-basin sedimentary rocks contained within the "Sandy Hook basin" is approximately 4.7 km, with the basin extending offshore to the east of the New Jersey coast. Gravity modeling indicates a deep rift basin and the magnetic data indicates a shallow magnetic basement caused by magnetic diabase sills and/or basalt flows contained within the rift-basin sedimentary rocks. The igneous sills and/or flows may be the eastward continuation of the Watchung and Palisades bodies. ?? 2004 Elsevier Ltd. All rights reserved.

Journal of Geodynamics↗

Geodynamic interpretation of the 40Ar/39Ar dating of ophiolitic and arc-related mafics and metamafics of the northern part of the Anadyr-Koryak region

Isotope datings of amphibole-bearing mafics and metamafics in the northern part of the Anadyr-Koryak region allow clarification of the time of magmatic and metamorphic processes, which are synchronous with certain stages of the geodynamic development of the northwest segment of the Pacific mobile belt in the Phanerozoic. To define the 40 Ar/ 39 Ar age of amphiboles, eight samples of amphibole gabbroids and metamafics were selected during field work from five massifs representing ophiolites and mafic plutons of the island arc. Rocks from terranes of three foldbelts: 1) Pekulnei (Chukotka region), 2) Ust-Belaya (West Koryak region), and 3) the Tamvatnei and El’gevayam subterranes of the Mainits terrane (Koryak-Kamchatka region), were studied. The isotope investigations enabled us to divide the studied amphiboles into two groups varying in rock petrographic features. The first was represented by gabbroids of the Svetlorechensk massif of the Pekulnei Range and by ophiolites of the Tamvatnei Mts.; their magmatic amphiboles show the distribution of argon isotopes in the form of clearly distinguished plateau with an age ranging within 120–129 Ma. The second group includes metamorphic amphiboles of metagabbroids and apogabbro amphibolites of the Ust-Belaya Mts., Pekulnei and Kenkeren ranges (El’gevayam subterranes). Their age spectra show loss of argon and do not provide well defined plateaus the datings obtained for them are interpreted as minimum ages. Dates of amphiboles from the metagabbro of the upper tectonic plate of the Ust-Belaya allochthon points to metamorphism in the suprasubduction environment in the fragment of Late Neoproterozoic oceanic lithosphere in Middle-Late Devonian time, long before the Uda-Murgal island arc system was formed. The amphibolite metamorphism in the dunite-clinopyroxenite-metagabbro Pekulnei sequence was dated to occur at the Permian-Triassic boundary. The age of amphiboles from gabbrodiorites of the Kenkeren Range was dated to be Early Jurassic that confirmed their assignment to the El’gevayam volcanic-plutonic assemblage. These data are consistent with geological concepts and make more precise the available age dates. Neocomian-Aptian 40 Ar/ 39 Ar age of amphibolites from the Pekulnei and Tamvatnei gabbroids make evident that mafics of these terranes (varying in geodynamic formation settings and in petrogenesis) were generated in later stages of the development of the West Pekulnei and Mainits-Algan Middle-Late Jurassic-Early Cretaceous island arc systems, presumably due to breakup of island arcs in the Neocomian.

Geotectonics↗

Mesozoic and Cenozoic tectonics of the eastern and central Alaska Range: Progressive basin development and deformation in a suture zone

Analysis of late Mesozoic and Cenozoic sedimentary basins, metamorphic rocks, and major faults in the eastern and central Alaska Range documents the progressive development of a suture zone that formed as a result of collision of an island-arc assemblage (the Wrangellia composite terrane) with the former North American continental margin. New basin-analysis, structural, and geochronologic data indicate the following stages in the development of the suture zone: (1) Deposition of 3-5 km of Upper Jurassic-Upper Cretaceous marine strata (the Kahiltna assemblage) recorded the initial collision of the island-arc assemblage with the continental margin. The Kahiltna assemblage exposed in the northern Talkeetna Mountains represents a Kimmeridgian-Valanginian backarc basin that was filled by northwestward-flowing submarine-fan systems that were transporting sediment derived from Mesozoic strata of the island-arc assemblage. The Kahiltna assemblage exposed in the southern Alaska Range represents a Valanginian-Cenomanian remnant ocean basin filled by west-southwestward-flowing submarine-fan systems that were transporting sediment derived from Paleozoic continental-margin strata uplifted in the along-strike suture zone. A belt of retrograde metamorphism and a regional anticlinorium developed along the continental margin from 115 to 106 Ma, roughly coeval with the end of widespread deposition in the Kahiltna sedimentary basins. (2) Metamorphism of submarine-fan deposits of the Kahiltna basin, located near the leading edge of the island-arc assemblage, occurred at ca. 74 Ma, as determined from a new U-Pb zircon age for a synkinematic sill. Coeval with metamorphism of deposits of the Kahiltna basin in the southern part of the suture zone was development of a thrust-top basin, the Cantwell basin, in the northern part of the suture zone. Geologic mapping and compositional data suggest that the 4 km of Upper Cretaceous nonmarine and marginal marine sedimentary strata in this basin record regional subaerial uplift of the suture zone. (3) Shortening and exhumation of the suture zone peaked from 65 to 60 Ma on the basis of metamorphic and geochronologic data. In the southern part of the suture zone, submarine-fan deposits of the Kahiltna basin, which had been metamorphosed to kyanite schists at ???25 km depth and ???650 ??C, were exhumed and cooled through the biotite closure temperature (???300 ??C) by ca. 62 Ma. In the northern part of the suture zone, this time period was marked by shortening, uplift, and erosion of sedimentary strata of the Cantwell basin. (4) From 60 to 54 Ma, ???3 km of volcanic strata were deposited over deformed sedimentary strata of the Cantwell basin, and several granitic plutons (the McKinley sequence) were emplaced along the suture zone. (5) Following igneous activity, strikeslip displacement occurred from ca. 54 to 24 Ma along the Denali fault system, which had developed in the existing suture zone. Late Eocene-Oligocene strike-slip displacement resulted in the formation of several small sedimentary basins along the Denali fault system. (6) Regional transpressive shortening characterized the suture zone from ca. 24 Ma to the present. Flexural subsidence, related to regional shortening, is represented by late Eocene to Holocene nonmarine deposits of the Tanana foreland basin. Regional subsidence resulted in Miocene coal seams up to 20 m thick and well-developed lacustrine deposits. Overlying the Miocene deposits are ???1.2 km of Pliocene and Holocene conglomeratic deposits. Compositional and paleocurrent data from these younger deposits record regional Neogene uplift of the suture zone and recycling of detritus from older basins to the south that had become incorporated into the uplifted suture zone. Geologic mapping of major thrust faults along the northern and southern margins of the suture zone documents Paleozoic strata thrust over both Pliocene fluvial deposits and Quaternary glacial deposits of the Tanana basin.

Geological Society of America Bulletin↗

Massive sulfide deposits of the Southern Appalachians central Virginia volcanic-plutonic belt as a host for massive sulfide deposits

Strata-bound massive sulfide deposits of the central Virginia Piedmont occur in a volcanic- plutonic belt composed of Lower Cambrian(?) metamorphosed volcanic rocks and locally of pre-Upper Ordovician, low potassium granitoid rocks. The belt, interpreted as an ancient island arc, begins about 50 km south of Washington, D. C, and extends some 175 km south- westward. The volcanic rocks within the belt are located along the flanks of the Quantico- Columbia synclinorium and the Arvonia syncline. The Chopawamsic Formation, a western facies of the belt, consists of volcanic rocks that have the geochemical features (rare earth and immobile elements) of a tholeiitic island-arc suite; it also contains calc-alkaline components. Tholeiitic amphibolites of the Ta River Metamorphic Suite on the eastern side of the belt form an oceanward facies of the island arc, coeval with the Chopawamsic. This distribution suggests an underlying westward-dipping Cambrian(?) subduction zone. Contrasts in stratigraphy, geochemistry, and magnetic and gravity features indicate that the central Virginia volcanic- plutonic belt is not related to the Carolina slate belt as has been proposed in the past. Known sulfide bodies in the Chopawamsic and its coeval units total about 13.5 million tons. The Mineral district on the northwest flank of the Quantico-Columbia synclinorium has the largest deposits and contains about 10 million tons. Sulfide bodies in the belt consist largely of pyrite with minor sphalerite and chalcopyrite; Zn and Pb are important in a few of the smaller deposits. There are local concentrations of sphalerite and other base metal minerals within the major pyritic deposits (Zn = 1-12.5%; Cu - 1-2%; Pb as much as 5%). The dom- inantly sphaleritic deposits are found in and northward for about 15 km from the Mineral district. Sulfide mineralization is found in all types of volcanic rock, but the large sulfide bodies on the northwest flank of the Quantico-Columbia synclinorium are in felsite. Am- phibolite, containing local beds of iron-formation, is abundant on the southeast flank of the Arvonia syncline; however, most sulfide mineralization there took place in felsitic to intermediate layers. Mineralization, attributed to submarine volcanic exhalation, took place during formation of the island arc.

Economic Geology↗

The Uralides and the motion of the Russian and Siberian Platforms

The Uralides—the late Precambrian and Paleozoic orogenic terrane between the Russian and Siberian Platforms—in part are exposed in the Ural Mountains, in the central Soviet Arctic, along the west edge of the Siberian Platform, and in southern Siberia and Kazakhstan, and in part are buried beneath the fill of the West Siberian Lowlands and other basins. Paleomagnetic orientations suggest that the Russian and Siberian Platforms were far apart during the early Paleozoic, converged during the middle Paleozoic, and collided in the Permian or Triassic. The geology of the Uralides accords with the concept that the two subcontinents approached and collided as the intervening oceanic plate slid beneath them along subduction (Benioff) zones. The medial eugeosyncline of the Uralides consists largely of what may be oceanic material scraped off against the edges of the opposed subcontinents. Basalt-and-spilite belts may represent ocean-floor abyssal tholeiite, and the manganiferous cherts and other sediments upon them may be pelagic oozes. Andesite belts may have formed as island arcs within the ocean, swept subsequently against the continents. Fossil subduction zones are recorded by great faults soled by, or containing tectonic injections of, mafic and ultramafic rocks from the lower oceanic crust and upper mantle, and containing high-pressure metamorphic rocks. Granitic and silicic-volcanic rocks may have formed above the subduction zones in the accreted parts of the continental plates. Both these continental-margin magmatic rocks and the island-arc complexes display ratios of potassium to silicon that vary across strike and so indicate the directions of dip of the subduction zones. From the distribution of such indicators of various ages, a history of the continental margins can be deduced. An active subduction zone dipped beneath the Siberian Platform during at least parts of late Precambrian and early, middle, and late Paleozoic time. The late Precambrian and Cambrian history of the Russian side is unclear, but in the Ordovician and Silurian the Russian continental margin was stable, while somewhere offshore an island arc was present whose trench was on the Russian side; the last of the intervening oceanic plate vanished down the subduction zone in about the Early Devonian, and the island arc became part of the continental margin. During the remainder of the Devonian and during the Carboniferous and Early Permian, a subduction zone was present along the margin of the enlarged Russian continent and dipped beneath it. Each subcontinent grew oceanward as oceanic material was accreted against it, and the subduction zones stepped oceanward correspondingly. The continental magmatic zones migrated oceanward behind the accreting edges of the continental plates, so the tectonic and magmatic progression with time at any one place is analogous to the variations present across the entire orogenic belt at any one time. Severe right-lateral deformation of the Uralides, the Russian side having moved northward relative to the Siberian side during Mesozoic and early Cenozoic time, is inferred from structural and magnetic-anomaly patterns. The deformation was accomplished by oroclinal folding, strike-slip faulting, and tensional thinning of the crust. The Uralides may have been continuous in early Mesozoic time with the Ellesmerides of North Greenland and the Canadian Arctic islands. The Cenozoic (and late Mesozoic?) opening of the Arctic Ocean was accomplished by spreading of the Eurasia Basin, and by opening of the Canada Basin behind a counterclockwise-rotating Alaska.

Siberia, Ural Mountains↗

The plumbotectonics of the West Shasta mining district, eastern Klamath Mountains, California

The tectonic setting comprising the West Shasta mining district has often been compared with that of primitive island arcs. Concentrations of uranium, thorium, and lead and lead isotope compositions were determined for Devonian ores and rocks of the West Shasta district, eastern Klamath Mountains, California, to help evaluate the tectonic classification. The lead isotope pattern is found to be complex. From comparison of the data with those on younger ores and rocks in the region and with those isotopic patterns found in modern tectonic terranes, however, a number of conclusions are possible. A lead isotope point for the Devonian oceanic mantle is now well established from this study on the West Shasta district. This isotopic composition is in agreement with that suggested by Slawson in 1983--i.e., from a sample of massive sulfide ore from the Golinsky deposit--with a 206 Pb/ 204 Pb of 17.830, a 207 Pb/ 204 Pb of 15.450, and a 208 Pb/ 204 Pb of 37.313. If the Devonian mantle is analogous to the modern mantle, the determined value is probably at the more radiogenic end of the Devonian oceanic mantle array.Some samples of volcanic rocks and ores that have elevated values of 207 Pb/ 204 Pb and 208 Pb/ 204 Pb indicate that subducted pelagic sediments or interaction of the magmas with other sediments downsection have been involved to varying degrees in the generation of magmas. The high ratios were not attained by addition of lead to the volcanic rocks or ores during subsequent magmatic events, such as intrusion of the Permian Pit River stock to the east or of the Cretaceous Shasta Bally batholith that crops out to the south and west and may underlie part of the district. Some values of 207 Pb/ 204 Pb are sufficiently high as to suggest that West Shasta may have developed nearer a continent than was previously supposed. Lead isotope data for Quaternary volcanic rocks are somewhat more radiogenic than for Cretaceous ores and plutonic rocks. Permo-Triassic ores are again a bit less radiogenic. The isotopic differences between the Permo-Triassic and Quaternary data could be accounted for by a value for 238 U/ 204 Pb of 10.42 in common source material. Using this value of 238 U/ 204 Pb to calculate even further back to 400 m.y., the resulting ratios are found to fall very close to the "best value" for the lead isotope mixing line between the Devonian mantle and pelagic sediments. We interpret this intersection to be the "mean value" for the assimilated Devonian sediment lead--18.250 for 206 Pb/ 204 Pb and 15.582 for 207 Pb/ 204 Pb. As deduced for the lead isotope composition for the Devonian mantle at this location, the pelagic sediment, lead isotope composition also is toward the more radiogenic end of the values expected for pelagic sediments in the Devonian. Lack of sediments in the observed volcanic section of the West Shasta district suggests a submerged volcanic-arc setting (as interpreted by others for the Troodos and Samail ophiolites) rather than an island-arc situation (such as the Green Tuff area of Japan) or an incipient spreading ridge setting (that might have grown to be a subaerial Iceland). The elevated values of 207 Pb/ 204 Pb for some samples suggest a submerged volcanic are whereas the exceedingly low values of thorium--which is not easily mobilized during alteration events--for both basaltic andesites and plagiorhyolites is suggestive of depleted source material such as is found for most oceanic spreading centers. Elevated values of 207 Pb/ 204 Pb are exceedingly rare in midocean ridge basalts and low contents of thorium are known in island arcs, so a submerged volcanic arc is the preferred interpretation. Some similarity exists between the 206 Pb/ 204 Pb values of Devonian ores having elevated values of 207 Pb/ 204 Pb and those of the Permo-Triassic ores of the East Shasta district, as mentioned by Slawson in 1983. This similarity is now confirmed to be a coincidence. We find it due first of all to some incorporation of sediment lead in the magmas, followed later by some migration of radiogenic lead--probably locally derived--into the ores during subsequent events. Because there was some postdepositional lead migration into the ores, some migration of copper also into the ores cannot be excluded. Lead, especially radiogenic lead, however, is more mobile than copper. As the migrating lead is deduced to have been locally derived from the observed section rather than exotically derived, any copper added was probably locally derived also.

Economic Geology↗

Gravity modeling of the Muertos Trough and tectonic implications (north-eastern Caribbean)

The Muertos Trough in the northeast Caribbean has been interpreted as a subduction zone from seismicity, leading to infer a possible reversal subduction polarity. However, the distribution of the seismicity is very diffuse and makes definition of the plate geometry difficult. In addition, the compressive deformational features observed in the upper crust and sandbox kinematic modeling do not necessarily suggest a subduction process. We tested the hypothesized subduction of the Caribbean plate's interior beneath the eastern Greater Antilles island arc using gravity modeling. Gravity models simulating a subduction process yield a regional mass deficit beneath the island arc independently of the geometry and depth of the subducted slab used in the models. This mass deficit results from sinking of the less dense Caribbean slab beneath the lithospheric mantle replacing denser mantle materials and suggests that there is not a subducted Caribbean plateau beneath the island arc. The geologically more realistic gravity model which would explain the N-S shortening observed in the upper crust requires an overthrusted Caribbean slab extending at least 60 km northward from the deformation front, a progressive increase in the thrusting angle from 8?? to 30?? reaching a maximum depth of 22 km beneath the insular slope. This new tectonic model for the Muertos Margin, defined as a retroarc thrusting, will help to assess the seismic and tsunami hazard in the region. The use of gravity modeling has provided targets for future wide-angle seismic surveys in the Muertos Margin. ?? 2010 Springer Science+Business Media B.V.

Marine Geophysical Research↗

Metallogenesis and tectonics of the Russian Far East, Alaska, and the Canadian Cordillera

The Proterozoic and Phanerozoic metallogenic and tectonic evolution of the Russian Far East, Alaska, and the Canadian Cordillera is recorded in the cratons, craton margins, and orogenic collages of the Circum-North Pacific mountain belts that separate the North Pacific from the eastern North Asian and western North American Cratons. The collages consist of tectonostratigraphic terranes and contained metallogenic belts, which are composed of fragments of igneous arcs, accretionary-wedge and subduction-zone complexes, passive continental margins, and cratons. The terranes are overlapped by continental-margin-arc and sedimentary-basin assemblages and contained metallogenic belts. The metallogenic and geologic history of terranes, overlap assemblages, cratons, and craton margins has been complicated by postaccretion dismemberment and translation during strike-slip faulting that occurred subparallel to continental margins. Seven processes overlapping in time were responsible for most of metallogenic and geologic complexities of the region (1) In the Early and Middle Proterozoic, marine sedimentary basins developed on major cratons and were the loci for ironstone (Superior Fe) deposits and sediment-hosted Cu deposits that occur along both the North Asia Craton and North American Craton Margin. (2) In the Late Proterozoic, Late Devonian, and Early Carboniferous, major periods of rifting occurred along the ancestral margins of present-day Northeast Asia and northwestern North America. The rifting resulted in fragmentation of each continent, and formation of cratonal and passive continental-margin terranes that eventually migrated and accreted to other sites along the evolving margins of the original or adjacent continents. The rifting also resulted in formation of various massive-sulfide metallogenic belts. (3) From about the late Paleozoic through the mid-Cretaceous, a succession of island arcs and contained igneous-arc-related metallogenic belts and tectonically paired subduction zones formed near continental margins. (4) From about mainly the mid-Cretaceous through the present, a succession of continental-margin igneous arcs (some extending offshore into island arcs) and contained metallogenic belts, and tectonically paired subduction zones formed along the continental margins. (5) From about the Jurassic to the present, oblique convergence and rotations caused orogen-parallel sinistral, and then dextral displacements within the plate margins of the Northeast Asian and North American Cratons. The oblique convergences and rotations resulted in the fragmentation, displacement, and duplication of formerly more continuous arcs, subduction zones, passive continental margins, and contained metallogenic belts. These fragments were subsequently accreted along the margins of the expanding continental margins. (6) From the Early Jurassic through Tertiary, movement of the upper continental plates toward subduction zones resulted in strong plate coupling and accretion of the former island arcs, subduction zones, and contained metallogenic belts to continental margins. In this region, the multiple arc accretions were accompanied and followed by crustal thickening, anatexis, metamorphism, formation of collision-related metallogenic belts, and uplift; this resulted in the substantial growth of the North Asian and North American continents. (7) In the middle and late Cenozoic, oblique to orthogonal convergence of the Pacific Plate with present-day Alaska and Northeast Asia resulted in formation of the present ring of volcanoes and contained metallogenic belts around the Circum-North Pacific. Oblique convergence between the Pacific Plate and Alaska also resulted in major dextral-slip faulting in interior and southern Alaska and along the western part of the Aleutian- Wrangell arc. Associated with dextral-slip faulting was crustal extrusion of terranes from western Alaska into the Bering Sea.

Professional Paper↗

Thermochronology and tectonics of the Leeward Antilles: Evolution of the southern Caribbean Plate boundary zone

Tectonic reconstructions of the Caribbean Plate are severely hampered by a paucity of geochronologic and exhumation constraints from anastomosed basement blocks along its southern margin. New U/Pb, 40 Ar/ 39 Ar, apatite fission track, and apatite (U-Th)/He data constrain quantitative thermal and exhumation histories, which have been used to propose a model for the tectonic evolution of the emergent parts of the Bonaire Block and the southern Caribbean Plate boundary zone. An east facing arc system intruded through an oceanic plateau during ~90 to ~87 Ma and crops out on Aruba. Subsequent structural displacements resulted in >80°C of cooling on Aruba during 70–60 Ma. In contrast, exhumation of the island arc sequence exposed on Bonaire occurred at 85–80 Ma and 55–45 Ma. Santonian exhumation on Bonaire occurred immediately subsequent to burial metamorphism and may have been driven by the collision of a west facing island arc with the Caribbean Plate. Island arc rocks intruded oceanic plateau rocks on Gran Roque at ~65 Ma and exhumed rapidly at 55–45 Ma. We attribute Maastrichtian-Danian exhumation on Aruba and early Eocene exhumation on Bonaire and Gran Roque to sequential diachronous accretion of their basement units to the South American Plate. Widespread unconformities indicate late Eocene subaerial exposure. Late Oligocene–early Miocene dextral transtension within the Bonaire Block drove subsidence and burial of crystalline basement rocks of the Leeward Antilles to ≤1 km. Late Miocene–recent transpression caused inversion and ≤1 km of exhumation, possibly as a result of the northward escape of the Maracaibo Block.

Tectonics↗

The Precambrian terranes of Yemen and their correlation with those of Saudi Arabia and Somalia: Implications for the accretion of Gondwana

Most of the basement of Yemen consists of early Precambrian continental high-grade terranes and Neoproterozoic low-grade island arcs that were accreted together to form an arc-continent collage during the Pan-African orogeny (Windley et al., 1996; Whitehouse et al., 1998; Whitehouse et al., in press). The suture zones between the arc and gneiss terranes are major crustal- scale tectonic boundaries. The terranes are situated east of the Nabitah suture and of the collage of low-grade, mainly island arc terranes of the Arabian Shield, but they have been reworked by a Neoproterozoic event associated with island arc accretion. Further east in Yemen are mostly unconformable, very weakly deformed and very low-grade or unmetamorphosed sediments. Thus Yemen provides key information on the broad zone of Neoproterozoic reworking associated with the collisional boundary between western and eastern Gondwana.

Gondwana Research↗

Back-arc with frontal-arc component origin of Triassic Karmutsen basalt, British Columbia, Canada

The largely basaltic, ???4.5-6.2-km-thick, Middle to Upper Triassic Karmutsen Formation is a prominent part of the Wrangellian sequence. Twelve analyses of major and minor elements of representative samples of pillowed and massive basalt flows and sills from Queen Charlotte and Vancouver Islands are ferrotholeiites that show a range of 10.2-3.8% MgO (as normalized, H2O- and CO2-free) and related increases in TiO2 (1.0-2.5%), Zr (43-147 ppm) and Nb (5-16 ppm). Other elemental abundances are not related simply to MgO: distinct groupings are evident in Al2O3, Na2O and Cr, but considerable scatter is present in FeO* (FeO + 0.9Fe2O3) and CaO. Some of the variation is attributed to alteration during low-rank metamorphism or by seawater - including variation of Ba, Rb, Sr and Cu, but high-field-strength elements (Sc, Ti, Y, Zr and Nb) as well as Cr, Ni, Cu and rare-earth elements (REE's) were relatively immobile. REE's show chondrite-normalized patterns ranging from light-REE depleted to moderately light-REE enriched. On eleven discriminant plots these analyses fall largely into or across fields of within-plate basalt (WIP), normal or enriched mid-ocean-ridge tholeiite (MORB) and island-arc tholeiite (IAT). Karmutsen basalts are chemically identical to the stratigraphically equivalent Nikolai Greenstone of southern Alaska and Yukon Territory. These data and the fact that the Karmutsen rests on Sicker Group island-arc rocks of Paleozoic age suggest to us that: 1. (1) the basal arc, after minor carbonate-shale deposition, underwent near-axial back-arc rifting (as, e.g., the Mariana arc rifted at different times); 2. (2) the Karmutsen basalts were erupted along this rift or basin as "arc-rift" tholeiitite; and 3. (3) after subsequent deposition of carbonates and other rocks, and Jurassic magmatism, a large fragment of this basalt-sediment-covered island arc was accreted to North America as Wrangellia. The major- and minor-elemental abundances of Karmutsen basalt is modeled by first mixing primitive arc magma with enriched basaltic liquid derived either from garnet peridotite or metasomatized mantle, followed by fractionation of olivine, pyroxenes, plagioclase and spinel. ?? 1989.

Chemical Geology↗

Ore-forming adakitic porphyry produced by fractional crystallization of oxidized basaltic magmas in a subcrustal chamber (Jiamate, East Junggar, NW China)

Adakitic intrusions are supposed to have a close genetic and spatial relationship to porphyry Cu deposits. However, the genesis of adakitic intrusions is still under dispute. Here, we describe newly discovered intrusive complex rocks, which are composed of ore-bearing, layered magnetite-bearing gabbroic and adakitic rocks in Jiamate, East Junggar, NW China. These Jiamate Complex intrusions have diagnostic petrologic, geochronologic and geochemical signatures that indicate they were all generated from the same oxidized precursor magma source. Additionally, these layered rocks underwent the same fractional crystallization process as the ore-bearing adakitic rocks in the adjacent Kalaxiangar Porphyry Cu Belt (KPCB) in an oceanic island arc (OIA) setting. The rocks studied for this paper include layered magnetite-bearing gabbroic intrusive rocks that contain: (1) gradual contact changes between lithological units of mafic and intermediate rocks, (2) geochemical signatures that are the same as those found in oceanic island arc (OIA) rocks, (3) typical adakitic geochemistry, and (4) similar characteristics and apparent fractional crystallization relationships of ultra-basic to basic rocks to those in the nearby Beitashan Formation and to ore-bearing adakitic rocks in the KPCB. They also display similar zircon U-Pb and zircon Hf model ages. The Jiamate Complex intrusions contain intergrowths of magnetite and layered gabbro, and the intermediate-acidic intrusions of the Complex display typical adakitic affinities. Moreover, in conjunction with previously published geochronological and geochemistry data of the mafic rocks in the Beitashan Formation and in the KPCB area, additional data generated for the Jiamate Complex intrusions rocks indicate that they were formed from fractional crystallization processes. The Jiamate Complex intrusions most likely were derived from a metasomatized mantle wedge that was underplated at the root of the Saur oceanic island arc (Saur OIA). The ore-bearing adakitic intrusions in the KPCB and the adakitic Jiamate Complex intrusions were both probably generated from the same basaltic parental magmas through fractional crystallization. In addition, characteristics of the layered, magnetite-bearing, oxidized, basaltic Jiamate Complex intrusive rocks indicate that they are likely to be the parental arc magmas for the nearby porphyry Cu deposits. This conclusion is based on new interpretations of the regional and local geology, on interpretation of new geochemical analysis, new stable isotope analysis, new geothermobarometry, and new zircon age dating as well as other techniques and interpretations.

LITHOS↗

Paleozoic ophiolitic assemblages within the southern New England orogen of eastern Australia: Implications for growth of the Gondwana margin

Several ophiolitic assemblages occur in the southern New England orogen. The development of these rocks and their relations to the rest of the orogen have major implications for the tectonic evolution of eastern Gondwana. A major, narrow but elongate belt of Early Cambrian suprasubduction zone ophiolite crops out along and near the PeelManning Fault System and is juxtaposed against younger arc and subduction complex terranes. No pre-Permian links with the rest of the New England orogen have been established for this terrane. It may represent portions of Lachlan Fold Belt basement which underlies younger, westward overthrust New England terranes, and has been diapirically emplaced at higher crustal levels as serpentinite-matrix melange. Middle to Late Devonian ophiolitic rocks in the Yarras Complex comprise basement to the Birpai subterrane and represent a crustal cross section through a rifted island arc. Correlatives of this terrane also occur within the more extensive Gamilaroi terrane to the west of which deeper crustal levels are not exposed. The various components of serpentinite-matrix melange in the Ngamba terrane at Port Macquarie superficially appear to represent a dismembered ophiolite association. However, the various components of the melange exhibit a wide range of ages, metamorphism, and tectonic affinities, rendering a genetically related origin unlikely. This terrane includes fragments of ocean floor accreted into a Late Devonian subduction complex, which was later affected by Early Carboniferous forearc serpentinite diapirism and high Mg series magmatism. Zircon inheritance in Triassic dikes, which intrude the melange attest to the development or later emplacement of this forearc region over an older Lachlan Fold Belt basement. Ultramafic rocks of the Bundjalung terrane in the east of the New England region probably formed at deep levels in an intraoceanic island arc and are intruded by boninitic dikes. The tectonic development of the NEO was significantly more complicated than has been suggested in earlier published models. Periodic accretion of island arc systems, some of which are now represented by suprasubduction zone ophiolites, to the eastern margin of Gondwana suggests multiple phases of subduction with the possibility of polarity reversals throughout the history of accretion. Lateral accretion was not the only means by which Gondwana continental crust grew, and there was considerable postaccretion continentward overthrusting of younger terranes.

New South Wales↗