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Selenium and other elements in freshwater fishes from the irrigated San Joaquin valley, California

Arsenic (As), chromium (Cr), mercury (Hg), and selenium (Se) were measured in composite whole-body samples of five fishes — bluegill ( Lepomis macrochirus ), common carp ( Cyprinus carpio ), mosquitofish ( Gambusia affinis ), largemouth bass ( Micropterus salmoides ), and Sacramento blackfish ( Orthodon microlepidotus ) — from the San Joaquin River system to determine if concentrations were elevated from exposure to agricultural subsurface (tile) drainage. Except for Cr, the concentrations of these elements in fishes from one or more sites were elevated; however, only Se approached concentrations that may adversely affect survival, growth, or reproduction in warm water fishes. Moreover, only Se among the four measured elements exhibited a geographic (spatial) pattern that coincided with known inflows of tile drainage to the San Joaquin River and its tributaries. Historical data from the Grassland Water District (Grasslands; a region exposed to concentrated tile drainage) suggested that concentrations of Se in fishes were at maximum during or shortly after 1984 and have been slightly lower since then. The recent decline of Se concentrations in fishes from the Grasslands could be temporary if additional acreages of irrigated lands in this portion of the San Joaquin Valley must be tile-drained to protect agricultural crops from rising groundwater tables

California

[Book review] Politics and water resources

Arizona is a state in which development has proceeded sufficiently rapidly relative to the available water supply that its water problems are as acute as those of nearly any other state in the Union. Owing to the fact that, in the past, the principal use of water was for irrigation, and that the areas where the water has been utilized were geographically separated from the mountain zones where the water originated, surface water resources were developed fairly early in the state’s history.

Arizona

Global daily reference evapotranspiration modeling and evaluation

Accurate and reliable evapotranspiration (ET) datasets are crucial in regional water and energy balance studies. Due to the complex instrumentation requirements, actual ET values are generally estimated from reference ET values by adjustment factors using coefficients for water stress and vegetation conditions, commonly referred to as crop coefficients. Until recently, the modeling of reference ET has been solely based on important weather variables collected from weather stations that are generally located in selected agro-climatic locations. Since 2001, the National Oceanic and Atmospheric Administration’s Global Data Assimilation System (GDAS) has been producing six-hourly climate parameter datasets that are used to calculate daily reference ET for the whole globe at 1-degree spatial resolution. The U.S. Geological Survey Center for Earth Resources Observation and Science has been producing daily reference ET (ETo) since 2001, and it has been used on a variety of operational hydrological models for drought and streamflow monitoring all over the world. With the increasing availability of local station-based reference ET estimates, we evaluated the GDAS-based reference ET estimates using data from the California Irrigation Management Information System (CIMIS). Daily CIMIS reference ET estimates from 85 stations were compared with GDAS-based reference ET at different spatial and temporal scales using five-year daily data from 2002 through 2006. Despite the large difference in spatial scale (point vs . ∼100 km grid cell) between the two datasets, the correlations between station-based ET and GDAS-ET were very high, exceeding 0.97 on a daily basis to more than 0.99 on time scales of more than 10 days. Both the temporal and spatial correspondences in trend/pattern and magnitudes between the two datasets were satisfactory, suggesting the reliability of using GDAS parameter-based reference ET for regional water and energy balance studies in many parts of the world. While the study revealed the potential of GDAS ETo for large-scale hydrological applications, site-specific use of GDAS ETo in complex hydro-climatic regions such as coastal areas and rugged terrain may require the application of bias correction and/or disaggregation of the GDAS ETo using downscaling techniques.

Journal of the American Water Resources Associatio

Transport of free and particulate-associated bacteria in karst

Karst aquifers, because of their unique hydrogeologic characteristics, are extremely susceptible to contamination by pathogens. Here we present the results of an investigation of contamination of a karst aquifer by fecal indicator bacteria. Two wells intercepting zones with contrasting effective hydraulic conductivities, as determined by pump test, were monitored both during the dry season and in response to a rain event. Samples were also collected from the adjacent ephemeral surface Stream, which is known to be impacted by an upstream wastewater treatment plant after rainfall. Whole water and suspended sediment samples were analyzed for fecal coliforms and enterococci. During the dry season, pumping over a 2-day period resulted in increases in concentrations of fecal coliforms to greater than 10,000 CFU/100 ml in the high-conductivity well; enterococci and total suspended solids also increased, to a lesser degree. Toward the end of the pumping period, as much as 50% of the fecal coliforms were associated with suspended sediment. Irrigation of an up-gradient pine plantation with primary-treated wastewater is the probable source of the bacterial contamination. Sampling after a rain event revealed the strong influence of water quality of the adjacent Terrieu Creek on the ground water. Bacterial concentrations in the wells showed a rapid response to increased concentrations in the surface water, with fecal coliform concentrations in ground water ultimately reaching 60,000 CFU/100 ml. Up to 100% of the bacteria in the ground water was associated with suspended sediment at various times. The results of this investigation are evidence of the strong influence of surface water on ground water in karst terrain, including that of irrigation water. The large proportion of bacteria associated with particulates in the ground Water has important implications for public health, as bacteria associated with particulates may be more persistent and more difficult to inactivate. The high bacterial concentrations found in both wells, despite the difference in hydraulic conductivity, demonstrates the difficulty of predicting vulnerability of individual wells to bacterial contamination in karst. The extreme temporal variability in bacterial concentrations underscores the importance of event-based monitoring of the bacterial quality of public water supplies in karst. (C) 2000 Elsevier Science B.V.Karst aquifers, because of their unique hydrogeologic characteristics, are extremely susceptible to contamination by pathogens. Here we present the results of an investigation of contamination of a karst aquifer by fecal indicator bacteria. Two wells intercepting zones with contrasting effective hydraulic conductivities, as determined by pump test, were monitored both during the dry season and in response to a rain event. Samples were also collected from the adjacent ephemeral surface stream, which is known to be impacted by an upstream wastewater treatment plant after rainfall. Whole water and suspended sediment samples were analyzed for fecal coliforms and enterococci. During the dry season, pumping over a 2-day period resulted in increases in concentrations of fecal coliforms to greater than 10,000 CFU/100 ml in the high-conductivity well; enterococci and total suspended solids also increased, to a lesser degree. Toward the end of the pumping period, as much as 50% of the fecal coliforms were associated with suspended sediment. Irrigation of an up-gradient pine plantation with primary-treated wastewater is the probable source of the bacterial contamination. Sampling after a rain event revealed the strong influence of water quality of the adjacent Terrieu Creek on the ground water. Bacterial concentrations in the wells showed a rapid response to increased concentrations in the surface water, with fecal coliform concentrations in ground water ultimately reaching 60,000 CFU/100 ml. Up to 100% of the bacteria in the ground water was associated with suspended

Journal of Hydrology

Influence of multi-decadal land use, irrigation practices and climate on riparian corridors across the Upper Missouri River Headwaters Basin, Montana

The Upper Missouri River Headwaters Basin (36,400 km2) depends on its river corridors to support irrigated agriculture and world-class trout fisheries. We evaluated trends (1984-2016) in riparian wetness, an indicator of riparian condition, in peak irrigation months (June, July, August) for 158 km2 of riparian area across the basin using the Landsat Normalized Difference Wetness Index (NDWI). We found that 8 of the 19 riparian reaches across the basin showed a significant drying trend over this period, including all three basin outlet reaches along the Jefferson, Madison and Gallatin Rivers. The influence of upstream climate was quantified using per reach random forest regressions. Much of the interannual variability in the NDWI was explained by climate, especially by drought indices and annual precipitation, but the significant temporal drying trends persisted in the NDWI-climate model residuals, indicating that trends were not entirely attributable to climate. Over the same period we documented a basin-wide shift from 9% of agriculture irrigated with center pivot irrigation to 50% irrigated with center pivot irrigation. Riparian reaches with a drying trend had a greater increase in the total area with center pivot irrigation (within-reach and upstream from the reach) relative to riparian reaches without such a trend (p<0.05). The drying trend, however, did not extend to river discharge. Over the same period, stream gages (n=7) showed a positive correlation with riparian wetness (p<0.05), but no trend in summer river discharge, suggesting that riparian areas may be more sensitive to changes in irrigation return flows, relative to river discharge. Identifying trends in riparian vegetation is a critical precursor to enhancing the resiliency of river systems and associated riparian corridors.

Montana

Examples of deformation-dependent flow simulations of conjunctive use with MF-OWHM

The dependency of surface- and groundwater flows and aquifer hydraulic properties on deformation induced by changes in aquifer head is not accounted for in the standard version of MODFLOW. A new USGS integrated hydrologic model, MODFLOW-OWHM, incorporates this dependency by linking subsidence and mesh deformation with changes in aquifer transmissivity and storage coefficient, and with flows that also depend on aquifer characteristics and land-surface geometry. This new deformation-dependent approach is being used for the further development of the integrated Central Valley hydrologic model (CVHM) in California. Preliminary results from this application and from hypothetical test cases of similar systems show that changes in canal flows, stream seepage, and evapotranspiration from groundwater (ET gw ) are sensitive to deformation. Deformation feedback has been shown to also have an indirect effect on conjunctive surface- and groundwater use components with increased stream seepage and streamflows influencing surface-water deliveries and return flows. In the Central Valley model, land subsidence may significantly degrade the ability of the major canals to deliver surface water from the Delta to the San Joaquin and Tulare basins. Subsidence can also affect irrigation demand and ET gw , which, along with altered surface-water supplies, causes a feedback response resulting in changed estimates of groundwater pumping for irrigation. This modeling feature also may improve the impact assessment of dewatering-induced land subsidence/uplift (following irrigation pumping or coal-seam gas extraction) on surface receptors, inter-basin transfers, and surface infrastructure integrity.

Proceedings of the International Association of Hy

Protecting the wildland-urban interface in California: Greenbelts vs thinning for wildfire threats to homes

This study utilized native chaparral and sage scrub shrubs to evaluate the impact of light summer irrigation on live fuel moisture content (LFMC) and predicted fire behavior. As to be expected LFMC varied markedly throughout the year being over 100% in winter in all species and treatments but differed markedly by treatment in the summer and fall. For most species lightly irrigated plants had the highest LFMC in the summer and fall, followed by thinned treatments and controls. These differences in moisture content coupled with structural differences in the vegetation contributed to expected differences in flame length and rate of spread. Lightly irrigated native shrubs planted around homes can reduce fire hazard and at the same time increase faunal diversity and other desirable features of utilizing native vegetation.

California

Point sources of emerging contaminants along the Colorado River Basin: Source water for the arid Southwestern United States

Emerging contaminants (ECs) (e.g., pharmaceuticals, illicit drugs, personal care products) have been detected in waters across the United States. The objective of this study was to evaluate point sources of ECs along the Colorado River, from the headwaters in Colorado to the Gulf of California. At selected locations in the Colorado River Basin (sites in Colorado, Utah, Nevada, Arizona, and California), waste stream tributaries and receiving surface waters were sampled using either grab sampling or polar organic chemical integrative samplers (POCIS). The grab samples were extracted using solid-phase cartridge extraction (SPE), and the POCIS sorbents were transferred into empty SPEs and eluted with methanol. All extracts were prepared for, and analyzed by, liquid chromatography–electrospray-ion trap mass spectrometry (LC–ESI-ITMS). Log D OW values were calculated for all ECs in the study and compared to the empirical data collected. POCIS extracts were screened for the presence of estrogenic chemicals using the yeast estrogen screen (YES) assay. Extracts from the 2008 POCIS deployment in the Las Vegas Wash showed the second highest estrogenicity response. In the grab samples, azithromycin (an antibiotic) was detected in all but one urban waste stream, with concentrations ranging from 30 ng/L to 2800 ng/L. Concentration levels of azithromycin, methamphetamine and pseudoephedrine showed temporal variation from the Tucson WWTP. Those ECs that were detected in the main surface water channels (those that are diverted for urban use and irrigation along the Colorado River) were in the region of the limit-of-detection (e.g., 10 ng/L), but most were below detection limits.

Arizona;California;Colorado;Nevada;New Mexico;Utah

What is a picture worth? A history of remote sensing

Remote sensing is the use of electromagnetic energy to measure the physical properties of distant objects. It includes photography and geophysical surveying as well as newer techniques that use other parts of the electromagnetic spectrum. The history of remote sensing begins with photography. The origin of other types of remote sensing can be traced to World War II, with the development of radar, sonar, and thermal infrared detection systems. Since the 1960s, sensors have been designed to operate in virtually all of the electromagnetic spectrum. Today a wide variety of remote sensing instruments are available for use in hydrological studies; satellite data, such as Skylab photographs and Landsat images are particularly suitable for regional problems and studies. Planned future satellites will provide a ground resolution of 10–80 m. Remote sensing is currently used for hydrological applications in most countries of the world. The range of applications includes groundwater exploration determination of physical water quality, snowfield mapping, flood-inundation delineation, and making inventories of irrigated land. The use of remote sensing commonly results in considerable hydrological information at minimal cost. This information can be used to speed-up the development of water resources, to improve management practices, and to monitor environmental problems.

Hydrological Sciences Bulletin

Isotopic evaluation of the National Water Model reveals missing agricultural irrigation contributions to streamflow across the western United States

The National Water Model (NWM) provides critical analyses and projections of streamflow that support water management decisions. However, the NWM performs poorly in lower-elevation rivers of the western United States (US). The accuracy of the NWM depends on the fidelity of the model inputs and the representation and calibration of model processes and water sources. To evaluate the NWM performance in the western US, we compared observations of river water isotope ratios ( 18 O / "> 16 O and 2 H / "> 1 H expressed in δ notation) to NWM-flux-estimated (model) river reach isotope ratios. The modeled estimates were calculated from long-term (2000–2019) mean summer (June, July, and August) NWM hydrologic fluxes and gridded isotope ratios using a mass balance approach. The observational dataset comprised 4503 in-stream water isotope observations in 877 reaches across 5 basins. A simple regression between observed and modeled isotope ratios explained 57.9 % ( δ 18 O) and 67.1 % ( δ 2 H) of variance, although observations were 0.5 ‰ ( δ 18 O) and 4.8 ‰ ( δ 2 H) higher, on average, than mass balance estimates. The unexplained variance suggest that the NWM does not include all relevant water fluxes to rivers. To infer possible missing water fluxes, we evaluated patterns in observation–model differences using δ 18 O diff ( δ 18 O obs − δ 18 O mod ) and d diff ( &#x3B4; 2 H diff - 8 &#x22C5; &#x3B4; 18 O diff "> ). We detected evidence of evaporation in observations but not model estimates (negative d diff and positive δ 18 O diff ) at lower-elevation, higher-stream-order, arid sites. The catchment actual-evaporation-to-precipitation ratio, the fraction of streamflow estimated to be derived from agricultural irrigation, and whether a site was reservoir-affected were all significant predictors of d diff in a linear mixed-effects model, with up to 15.2 % of variance explained by fixed effects. This finding is supported by seasonal patterns, groundwater levels, and isotope ratios, and it suggests the importance of including irrigation return flows to rivers, especially in lower-elevation, higher-stream-order, arid rivers of the western US.

Hydrology and Earth Systems Science

Soil nitrogen balance under wastewater management: Field measurements and simulation results

The use of treated wastewater for irrigation of crops could result in high nitrate-nitrogen (NO3-N) concentrations in the vadose zone and ground water. The goal of this 2-yr field-monitoring study in the deep silty clay loam soils south of Dodge City, Kansas, was to assess how and under what circumstances N from the secondary-treated, wastewater-irrigated corn reached the deep (20-45 m) water table of the underlying High Plains aquifer and what could be done to minimize this problem. We collected 15.2-m-deep soil cores for characterization of physical and chemical properties; installed neutron probe access tubes to measure soil-water content and suction lysimeters to sample soil water periodically; sampled monitoring, irrigation, and domestic wells in the area; and obtained climatic, crop, irrigation, and N application rate records for two wastewater-irrigated study sites. These data and additional information were used to run the Root Zone Water Quality Model to identify key parameters and processes that influence N losses in the study area. We demonstrated that NO3-N transport processes result in significant accumulations of N in the vadose zone and that NO3-N in the underlying ground water is increasing with time. Root Zone Water Quality Model simulations for two wastewater-irrigated study sites indicated that reducing levels of corn N fertilization by more than half to 170 kg ha-1 substantially increases N-use efficiency and achieves near-maximum crop yield. Combining such measures with a crop rotation that includes alfalfa should further reduce the accumulation and downward movement of NO3-N in the soil profile. Copyright ?? 2009 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality

A synthesis of aquatic science for management of Lakes Mead and Mohave

Lakes Mead and Mohave, which are the centerpieces of Lake Mead National Recreation Area, provide many significant benefits that have made the modern development of the Southwestern United States possible. Lake Mead is the largest reservoir by volume in the nation and it supplies critical storage of water supplies for more than 25 million people in three Western States (California, Arizona, and Nevada). Storage within Lake Mead supplies drinking water and the hydropower to provide electricity for major cities including Las Vegas, Phoenix, Los Angeles, Tucson, and San Diego, and irrigation of more than 2.5 million acres of croplands. Lake Mead is arguably the most important reservoir in the nation because of its size and the services it delivers to the Western United States. This Circular includes seven chapters. Chapter 1 provides a short summary of the overall findings and management implications for Lakes Mead and Mohave that can be used to guide the reader through the rest of the Circular. Chapter 2 introduces the environmental setting and characteristics of Lakes Mead and Mohave and provides a brief management context of the lakes within the Colorado River system as well as overviews of the geological bedrock and sediment accumulations of the lakes. Chapter 3 contains summaries of the operational and hydrologic characteristics of Lakes Mead and Mohave. Chapter 4 provides information on water quality, including discussion on the monitoring of contaminants and sediments within the reservoirs. Chapter 5 describes aquatic biota and wildlife, including food-web dynamics, plankton, invertebrates, fish, aquatic birds, and aquatic vegetation. Chapter 6 outlines threats and stressors to the health of Lake Mead aquatic ecosystems that include a range of environmental contaminants, invasive species, and climate change. Chapter 7 provides a more detailed summary of overall findings that are presented in Chapter 1; and it contains a more detailed discussion on associated management implications, additional research, and monitoring needs.

Arizona, Nevada

Water-Quality Data for Selected National Park Units within the Southern Colorado Plateau Network, Arizona, Utah, Colorado, and New Mexico, Water Years 2005 and 2006

The National Park Service initiated a Level 1 Water-Quality Inventory program to provide water-quality data to park managers so informed natural resource management decisions could be made. Level 1 water-quality data were collected by the U.S. Geological Survey Arizona Water Science Center at 57 sites in 13 National Park units located in the Southern Colorado Plateau Inventory and Monitoring network in water years 2005 and 2006. These data describe the current water-quality at selected sites within the park units and provide information for monitoring future trends. Water samples were collected three times at each type of site including wells, springs, seeps, tinajas, rivers, a lake, and an irrigation ditch. Field measurements were taken at each site and they included pH, specific conductance, temperature, barometric pressure, dissolved oxygen, alkalinity, turbidity, and discharge rates where applicable. Water samples collected were sent to the U.S. Geological Survey National Water Quality Laboratory and analyzed for major ions, trace elements, and nutrients. The National Water Quality Laboratory also analyzed selected samples for mercury and petroleum hydrocarbons. Additional samples at selected sites were collected and analyzed for cyanide, radiochemistry, and suspended sediment by U.S. Geological Survey contract labs. Fecal-indicator bacteria (Escherichia coli) were sampled for at selected sites as another indicator of water quality. Quality control for this study was achieved through proper training of field personnel, use of standard U.S. Geological Survey field and laboratory protocols, collection of sample blanks and replicates, and a thorough review of the water-quality analyses. Measured field pH ranged from 6.0 to 8.8, within normal range for springs and rivers, at most sites. Concentrations of dissolved solids ranged from 48 to 8,680 mg/L and the majority of samples had concentrations of dissolved solids below 900 mg/L. Trace-element concentrations at most sites were at or near the laboratory reporting levels. The highest overall trace-element concentrations were found at U.S. Highway 160 Spring near Park Entrance to Mesa Verde National Park. Concentrations of uranium in samples at all sites ranged from below the detection limit to 55.7 ?g/L. Water samples from selected sites were analyzed for total petroleum hydrocarbons and concentrations of total petroleum hydrocarbons were at or above the laboratory detection limit in samples at six National Park units. Ten sites were sampled for Escherichia coli and positive counts were found at 9 out of the ten sites, the highest colony counts were found at Chinle Creek at Chinle, AZ in Canyon de Chelly National Monument. Measured concentrations of dissolved ammonia, nitrite, and nitrate were at or near laboratory reporting levels at most sites; nitrate concentrations ranged from below the reporting limit (0.047 mg/L) to 9.77 mg/L. Samples that were analyzed for mercury had concentrations below or at the laboratory reporting level. Concentrations of cyanide were less than the laboratory reporting level for all samples except two, Spruce Tree House Spring in Mesa Verde National Park and Pine Tree Canyon Tinaja in Canyon de Chelly National Monument, which had average concentrations of .042 and .011 ?g/L respectively. Gross alpha/beta radioactivity counts were below the U.S. Environmental Protection Agency maximum contaminant level except for samples from Casa Chiquita Well  Middle at Chaco Culture National Historical Park which averaged 35 pCi/L. Suspended-sediment concentrations were variable and ranged from 10 to 150,000 mg/L.

Open-File Report

Inset groundwater-flow models for the Cache and Grand Prairie Critical Groundwater Areas, northeastern Arkansas

The water resources in the Mississippi alluvial plain, located in parts of Missouri, Kentucky, Tennessee, Mississippi, Louisiana, and Arkansas, supports a multibillion-dollar agricultural industry that relies heavily on pumping of groundwater for irrigation of crops and aquaculture. The primary source of groundwater for agricultural-related pumping is the Mississippi River Valley alluvial aquifer, which has declined in storage for decades; secondary groundwater sources include the middle Claiborne aquifer and Wilcox aquifer system. Two areas in northeastern Arkansas that lie within the Mississippi alluvial plain, part of the Cache and Grand Prairie regions, have been designated as Critical Groundwater Areas owing to decades of groundwater declines that resulted from past and current water use. The multidisciplinary Mississippi Alluvial Plain project, led by the U.S. Geological Survey, and funded by their Water Availability and Use Science Program, included objectives to develop numerical groundwater models in focus regions, including the part of the Cache and Grand Prairie regions of northeastern Arkansas. Two inset models were developed using the child model capabilities of MODFLOW 6, the U.S. Geological Survey’s Modular Hydrologic Model simulation software. Both models, called the Cache model and Grand Prairie model, simulated the groundwater system and surface-water/groundwater interactions for the Mississippi River Valley alluvial aquifer and underlying Tertiary-age aquifers and confining units to the Midway confining unit. Each model was spatially discretized into 500-meter x 500-meter orthogonal cells on a grid with 5-meter constant-thickness vertical layers that represented the Mississippi River Valley alluvial aquifer and increasing thickness layers for the aquifers and confining units below the alluvial aquifer. The Cache and Grand Prairie models were calibrated with the PEST++ iterative ensemble smoother Version 5 and employed high dimensional parameterization schemes of 13,740 and 30,436 parameters, respectively. The Cache mean absolute residual for groundwater-level observations within each model domain for the priority well was 1.58 meters. Grand Prairie mean absolute residuals for the alluvial aquifer and middle Claiborne aquifer groundwater-level observations were 2.71 and 10.78 meters, respectively. The groundwater budgets for the Cache and Grand Prairie models were characterized by substantial outflows to irrigation wells, which constituted about 52 and 54 percent of all outflows, with the primary source of water to those wells being releases from unconfined aquifer storage.

Arkansas

Groundwater availability of the Northern High Plains aquifer in Colorado, Kansas, Nebraska, South Dakota, and Wyoming

Executive Summary The Northern High Plains aquifer underlies about 93,000 square miles of Colorado, Kansas, Nebraska, South Dakota, and Wyoming and is the largest subregion of the nationally important High Plains aquifer. Irrigation, primarily using groundwater, has supported agricultural production since before 1940, resulting in nearly $50 billion in sales in 2012. In 2010, the High Plains aquifer had the largest groundwater withdrawals of any major aquifer system in the United States. Nearly one-half of those withdrawals were from the Northern High Plains aquifer, which has little hydrologic interaction with parts of the aquifer farther south. Land-surface elevation ranges from more than 7,400 feet (ft) near the western edge to less than 1,100 ft near the eastern edge. Major stream primarily flow west to east and include the Big Blue River, Elkhorn River, Loup River, Niobrara River, Republican River and Platte River with its two forks—the North Platte River and South Platte River. Population in the Northern High Plain aquifer area is sparse with only 2 cities having a population greater than 30,000. Droughts across much of the area from 2001 to 2007, combined with recent (2004–18) legislation, have heightened concerns regarding future groundwater availability and highlighted the need for science-based water-resource management. Groundwater models with the capability to provide forecasts of groundwater availability and related stream base flows from the Northern High Plains aquifer were published recently (2016) and were used to analyze groundwater availability. Stream base flows are generally the dominant component of total streamflow in the Northern High Plains aquifer, and total streamflows or shortages thereof define conjunctive management triggers, at least in Nebraska. Groundwater availability was evaluated through comparison of aquifer-scale water budgets compared for periods before and after major groundwater development and across selected future forecasts. Groundwater-level declines and the forecast amount of groundwater in storage in the aquifer also were examined. Major Findings Aquifer losses to irrigation withdrawals increased greatly from 1940 to 2009 and were the largest average 2000–9 outflow (49 percent of total). Basin to basin groundwater flows were not a large part of basin water budgets. Development of irrigated land and associated withdrawals were not uniform across the Northern High Plains aquifer, and different parts of the Northern High Plains aquifer responded differently to agricultural development. For the Northern High Plains aquifer, areas with high recharge and low evapotranspiration had the most streamflow, and most streams only remove water from the aquifer. Results of a baseline future forecast indicated that groundwater levels declined overall, indicating an overdraft of the aquifer when climate was about average and agricultural development was held at the same state as 2009. Results of two human stresses future forecasts indicated that increases of 13 percent or 23 percent in agricultural development, mostly near areas of previous development, caused increases in groundwater pumping of 8 percent or 11 percent, and resulted in continued groundwater-level declines, at rates 0.3 or 0.5 million acre-feet per year larger than the baseline forecast. Results of environmental stresses forecasts (generated from two downscalings of global climate model outputs) compared with the baseline forecast indicated that even though annual precipitation was nearly the same, differences in temperature and a redistribution of precipitation from the spring to the growing season (from about May 1 through September 30), created a large (12–15 percent) decrease in recharge to the aquifer. For the two environmental stresses forecasts, temperature and precipitation were distributed about the same among basins of the Northern High Plains aquifer, but the amounts were different.

Colorado, Kansas, Nebraska, South Dakota, Wyoming

Challenge theme 4: People in the Borderlands: Chapter 6 in United States-Mexican Borderlands: Facing tomorrow's challenges through USGS science

The management of shared resources in the United States–Mexican border region requires cooperation from the people of both countries to assess and understand their relation to the environment. Society is dependent on the long-term healthy functioning of ecosystems and their ability to supply food and raw materials. Likewise, resources and services obtained from nature could be used efficiently within the society. A more equitable distribution of costs and benefits related to goods and services can lead to fewer tensions and a higher quality of life for all the people in the Borderlands. Urban development, background contamination from mineral ore deposits, irrigation, sewage effluent, and even global climate change all have the potential to alter the stability of the fragile systems in the Borderlands (Brady and others, 2001, 2002; Norman, 2007, 2010; Gu and others, 2008; Norman, Gray, and others, 2008; Norman, Hirsch, and Ward, 2008; Norman, Callegary, and others, 2010; Norman, Huth, and others, 2010; Norman, Levick, and others, 2010; Norman, Tallent-Halsell, and others, 2010; Norman, Villarreal, and others 2012). Social efficiency means that because resources should be used where they are needed most, they should be distributed proportionally among human societies and individuals (Azar and others, 1996). Despite the critical role natural resources play in maintaining human and environmental health, current knowledge of the manner in which natural and human-caused forces interact to limit these resources—including their quality and quantity (such as through spatiotemporal changes in precipitation, evapotranspiration, pumping of groundwater, and release of contaminants)—is inadequate. The U.S. Geological Survey (USGS) is trying to understand the relation between changing landscapes, changing demographics, and a changing climate in the Borderlands while the environmental, economic, and societal issues continue to be intertwined between the two nations.

United States-Mexico Borderlands

Yuma Ridgway’s rail selenium exposure and occupancy within managed and unmanaged emergent marshes at the Salton Sea

Yuma Ridgway’s rail ( Rallus obsoletus yumanensis , hereafter, rail) is an endangered species for which patches of emergent marsh within the Salton Sea watershed comprise a substantial part of habitat for the species’ disjointed range in the southwestern United States. These areas of emergent marsh include (1) marshes managed by federal (particularly the U.S. Fish and Wildlife Service’s Sonny Bono Salton Sea National Wildlife Refuge), state (California Department of Fish and Wildlife), and local (Imperial Irrigation District) resource agencies that are sustained by direct deliveries of Colorado River water and (2) unmanaged marshes sustained by agricultural drainage water. Management of rail habitat in this arid environment is complicated by increasingly limited availability of unimpaired freshwater owing to water management decisions associated with the Quantification Settlement Agreement and risks posed by potentially harmful concentrations of selenium found in agricultural drainage water that can readily bioaccumulate in aquatic food webs. To provide timely science for managers, herein we report summary statistics for managed and unmanaged emergent marshes sampled at the Salton Sea during the rail breeding season of 2016 pertaining to (1) selenium concentrations in food webs representing dietary pathways of selenium exposure and (2) patterns of rail occupancy and inter-marsh movements, estimated abundance, and regional population size of rail. For selenium-specific objectives, we sampled unfiltered surface water, midge larvae (Chironomidae), water boatmen (Corixidae), mosquitofish ( Gambusia spp.), and crayfish (Astacidae). Selenium samples were collected from 15 fixed sampling points, each in managed and unmanaged marshes, during late February, April, and June 2016, which corresponded to rail pre-nesting, nesting, and fledgling reproductive life-stages, respectively. Two areas within the two treatment types (managed versus unmanaged marsh) were of particular interest to help assess risks associated with changing sea dynamics and different water-management strategies: (1) a large unmanaged marsh (Morton Bay) unintentionally created in approximately 2008 when it became separated from the Salton Sea as water inflows began to drop and a berm formed from accumulated sediment and (2) a restored marsh (HZ9A) managed by the Sonny Bono Salton Sea National Wildlife Refuge, which is currently supplied with Colorado River water but may be sustained in the future by a blend of clean (that is, low selenium) Colorado River and agricultural drainage water with higher selenium from the Alamo River. Hence, baseline data for these marshes are important for future management decisions. We also report selenium concentrations in rail blood, head feathers, and breast feathers from rails captured as part of the movement study. Results indicated relatively higher risks from dietary selenium exposure for rails occupying unmanaged marshes compared to managed marshes and similar risks among unmanaged marshes. However, risks also were potentially elevated for rails occupying some managed marshes (that is, the Hazard Marshes), where relatively high proportions of Chironomidae and mosquitofish exceeded dietary thresholds for selenium effects on avian reproduction. For rail-specific objectives, we quantified occupancy and spatial distribution using call count data analyzed with imperfect detection models. Imperfect detection models allowed us to jointly estimate detection probability and abundance of detected rails in association with habitats. We then used estimates of detection probability and abundance at the habitat level to extrapolate rail population abundance for the Salton Sea region. Inter- and intra-marsh movements were described from over 5,000 locations obtained from 15 radio-marked rails. Resultant space use patterns indicated that, in general, selenium risk to individuals is not equally shared because of high levels of territoriality and very limited movement throughout the landscape. Moreover, the largest contiguous blocks of habitat are associated with unmanaged marshlands located on the former southeastern shoreline and outside traditional management areas and authorities. Thus, a substantial proportion of the rail population that is using unmanaged marsh on the southeastern shoreline may have disproportionate risk of elevated selenium exposure, yet how that risk translates to population-level effects remains unknown.

California

Characterization of hydraulic fracturing flowback water in Colorado: Implications for water treatment

A suite of analytical tools was applied to thoroughly analyze the chemical composition of an oil/gas well flowback water from the Denver–Julesburg (DJ) basin in Colorado, and the water quality data was translated to propose effective treatment solutions tailored to specific reuse goals. Analysis included bulk quality parameters, trace organic and inorganic constituents, and organic matter characterization. The flowback sample contained salts (TDS = 22,500 mg/L), metals (e.g., iron at 81.4 mg/L) and high concentration of dissolved organic matter (DOC = 590 mgC/L). The organic matter comprised fracturing fluid additives such as surfactants (e.g., linear alkyl ethoxylates) and high levels of acetic acid (an additives' degradation product), indicating the anthropogenic impact on this wastewater. Based on the water quality results and preliminary treatability tests, the removal of suspended solids and iron by aeration/precipitation (and/or filtration) followed by disinfection was identified as appropriate for flowback recycling in future fracturing operations. In addition to these treatments, a biological treatment (to remove dissolved organic matter) followed by reverse osmosis desalination was determined to be necessary to attain water quality standards appropriate for other water reuse options (e.g., crop irrigation). The study provides a framework for evaluating site-specific hydraulic fracturing wastewaters, proposing a suite of analytical methods for characterization, and a process for guiding the choice of a tailored treatment approach.

Colorado