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Water use permits as of July 2024 and reported water use near the North Unit of Theodore Roosevelt National Park, North Dakota, 1980–2023

Starting in the early 2000s, increasing oil and gas development in western North Dakota created a need for additional water resources from surface-water and groundwater sources near the North Unit of Theodore Roosevelt National Park. To summarize the use of water in that area, the U.S. Geological Survey, in cooperation with the National Park Service, developed a map of surface-water and groundwater resources, aquifers, and water-use diversions, and plotted water-use trends from 1980 to 2023. Reported water used from permits in the map area has more than doubled since 2020, increasing from about 750 acre-feet in 2020 to about 2,300 acre-feet in 2022 and 2,000 acre-feet in 2023. Surface water provided the primary source of reported water used for the study period with an average of about 410 acre-feet per year from 1980 through 2017 and about 1,330 acre-feet per year from 2018 through 2023. After 2011, groundwater sourced from the Little Missouri River, Tobacco Garden Creek, Fox Hills, Fort Union, and Dakota aquifers became a larger portion of total annual reported water use from permits in the map area. From 1980 through 2015, water use for irrigation averaged 86 percent of the total annual reported surface-water and groundwater use in the map area. Starting in 2011, however, industrial uses became a proportionally larger total use of water, and in 2015, became the highest reported volume of water use in the map area. From 2011 to 2023, industrial use designated for water depots increased from 50 acre-feet to about 1,370 acre-feet, accounting for about 70 percent of total reported water use in the map area in 2023.

North Dakota

The influence of pre-existing structures on geothermal springs: Inferences from potential field mapping in Surprise Valley, CA and other sites In the northwestern Great Basin

Surprise Valley, located in the northwestern Great Basin, is an asymmetric extensional basin that marks a major tectonic transition between the relatively un-extended volcanic Modoc Plateau to the west, and the Basin and Range to the east that has undergone 10-15% extension. In addition, it sits just north of the Walker Lane which accommodates up to 20% of dextral slip associated with Pacific-North American plate interactions. Thermal springs issue from eight areas within Surprise Valley. Most of these occur within the basin and are not situated on the main basin forming range-front faults. As a result, efforts to resolve the structural setting of the valley’s hydrothermal system have relied on geophysics to characterize basin structure and geology. Extensive efforts to map the basin with ground and airborne magnetics have revealed a >35 km-long linear, intra-basin magnetic high, interpreted as a buried dike swarm. Geothermal springs on the eastern side of the valley, including Seifert hot springs, Leonards hot springs, and Surprise Valley hot springs (SVHS), are all situated along the magnetic high and occur at local breaks and bends in the anomaly, suggesting that fracture permeability is enhanced along the feature and particularly at these discontinuities. Recent studies, including drilling over the anomaly near SVHS that likely intersected dike material, as well as subsequent mapping and sampling of dikes outcropping along the anomaly on the playa surface south of SVHS, confirm (as previously inferred) that mafic intrusives are the principal source of the anomaly. Similar interpretations made in two other valleys (in southern Oregon and northwestern Nevada), where inferred intra-basin dikes appear to be spatially correlated with hot springs or prospective geothermal resource areas, suggest that the impact of pre-existing basement structure on hydrothermal activity may pertain more generally to other hydrothermal settings throughout the Great Basin. If so, efforts to map basement may enhance understanding structural controls on some geothermal systems. Furthermore, similarities across these disparate sites suggest that magmatism may play a much larger role in accommodating extension and influencing basin evolution across the western Great Basin than previously recognized.

Conference Paper

Complex carbonate ore mineralogy in the Mountain Pass carbonatite rare earth element deposit, USA

Economic concentrations of rare earth element (REE) minerals are uncommon in the Earth’s crust, with most occurring in carbonatites. Unlike most igneous rocks composed of silicate minerals, carbonatites are dominated by carbonate minerals, some of which can incorporate significant light REEs (LREEs; La, Ce, Pr, Nd). Technological applications of REEs are numerous and they have been identified as some of the most critical mineral commodities to the global economy. The Mountain Pass carbonatite stock in the Mojave Desert of California is the most economically significant REE deposit in the USA and contains a few to tens of percent (by volume) of the carbonate REE ore mineral bastnäsite. Despite the economic significance of the Mountain Pass deposit, studies of its ore mineralogy are limited. Here we present new carbonate ore mineralogy data for a compositionally diverse suite of carbonatitic rocks from the Mountain Pass stock and related dikes. Whole-rock geochemical data are integrated with mineral-scale textural and chemical data obtained by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and microRaman spectroscopy. Our results document a complex spectrum of REE-bearing carbonate minerals and intermediate mixed-layer structures. Mineral species include bastnäsite [REE(CO 3 )F], hydroxylbastnäsite [REE(CO 3 )OH], parisite [Ca(REE) 2 (CO 3 ) 3 F 2 ], synchysite [Ca(REE)(CO 3 ) 2 F], röntgenite [Ca 2 (Ce,La) 3 (CO 3 ) 5 F 3 ], and sahamalite [(Mg,Fe 2+ )(REE) 2 (CO 3 ) 4 ]. Carbonate ore mineralogy is heterogeneous within and between samples, including at the intracrystal scale. Complexly zoned crystals exhibit as many as five to six different compositional domains and syntaxial intergrowths, commonly with the more Ca-rich varieties (parisite, synchysite) forming crystal rims that surround relict bastnäsite cores. We attribute the phenocryst variability to changes in the chemistry and temperature of primary carbonatite magmas and evolved/exsolved fluids. Cross-cutting vein textures of calcite, celestine and various REE carbonate minerals, interstitial bastnäsite crystallization, breccia blocks lined by fine-grained bastnäsite, and the presence of hydroxylbastnäsite and partially hydroxylated bastnäsite point to the role of secondary hydrothermal processes in REE mineralization. Fluorcarbonate mineral compositions demonstrate that La and Ce are more structurally abundant in bastnäsite, whereas the more Ca-rich species (parisite, synchysite) contain a greater proportion of REE heavier than Pr (Nd, Sm, Eu, Gd) and Y. Atomic ratios of Pr/(Nd + Pr) are likewise variable, with the highest average value for bastnäsite (0.25) compared to parisite (0.22) and sychysite (0.21). This finding has geometallurgical implications, given that current mining operations are focused on recovery of Nd and Pr for high field strength permanent magnets and the Nd/Pr ratios are a critical factor in ore processing and magnet manufacture.

California

Cambrian and Ordovician stratigraphy, conodont biostratigraphy, and microfacies analysis to support 1:24,000-scale geologic mapping of the southern Lake Champlain valley, New York and Vermont

Introduction Geologic mapping in the southern Lake Champlain valley of New York and Vermont (fig. 1) has required evaluation of stratigraphic nomenclature used since the early 1900s. The paleogeography of the Cambrian and Ordovician adjacent to the Adirondack Highlands, the high-relief mountains of Proterozoic igneous and metamorphic rocks of northern New York, has impacted the lithostratigraphic succession, facies changes, and several hiatuses that occur within the package of clastic and carbonate rocks that demonstrates overall deepening consistent from the southern to northern Appalachians. The stratigraphic nomenclature used for the geologic mapping of the Cambrian and Ordovician strata of the study area is derived from evaluation of names put forth by previous workers from areas of northern New York and western Vermont. Descriptions of type localities or type sections and other criteria set forth by the North American Stratigraphic Code (North American Commission on Stratigraphic Nomenclature [NACSN], 2021) were consulted. The North American Stratigraphic Code states that lithostratigraphic units, such as the fundamental unit, the formation, be defined by lithic character and be mappable (NACSN, 2021, Article 24). However, some early workers (Walcott, 1912; Kay, 1937; Fisher and Hanson, 1951; Oxley and Kay, 1959) have defined stratigraphic units based on fossil content, which may or may not be facies dependent, and hence may not be mappable as lithostratigraphic units. Although preservation of older names takes priority in stratigraphic nomenclature (NACSN, 2021, Article 7), some do not have adequately defined stratotypes or are located a distance away with different lithologies than that in the study area. Biostratigraphy can be a helpful tool for understanding correlations and facies changes. Herein, conodont biostratigraphy is utilized to date and correlate separate lithologic units. Further, microfacies analyses of units through inspection of petrographic thin sections provide paleogeographic information that helps in understanding the genesis of geologic units.

New York, Vermont

Near-surface geophysics: Environmental applications

The field of geophysics encompasses a broad and diverse compilation of methodologies that employs principles of physics to characterize properties of earth materials within the subsurface. While geophysical methods have a long history in resource exploration and studies of Earth’s interior, the subdiscipline of “near-surface geophysics” has evolved in recent decades for examination of the shallow, near-surface environment for a range of purposes ranging from archaeological or forensic investigations to assessment of geologic, hydrologic, biologic, and geochemical properties and processes. “Environmental geophysics” are near-surface geophysical studies and methods that focus on understanding natural systems (e.g., watershed hydrology, groundwater–surface water connections, biophysical processes) as well as research pertaining to anthropogenic impacts and land management, (e.g., contamination and remediation, saltwater intrusion, agricultural practices). This field can be further subdivided into subdisciplines focused on specific topics and applications, such as water resources and hydrology (hydrogeophysics) or biologic and microbial processes (biogeophysics). Studies in environmental geophysics span a range of scales, from pore-scale laboratory tests to watershed-scale or regional field experiments. Methods vary by the nature of physics employed, the specific measurement acquired, and how that data is ultimately processed and analyzed to produce interpretable results. There exists further diversity in the acquisition logistics, geometry, and timing of data collection. Geophysical data can be collected in boreholes (one-dimensional, 1-D, vertical profiles), along survey lines (two-dimensional, 2-D, cross-sections), or in dense sensor arrays or gridded profiles (three-dimensional, 3-D, models). Regarding the temporal aspect, studies can conduct one-time geophysical surveys to obtain detailed imaging of subsurface structure or use timelapse and continuous monitoring to investigate variations in subsurface properties over time. The cumulation of all possible permutations of these factors (method, acquisition geometry, survey design, and target application) results in an immense diversity among environmental geophysical studies. Nevertheless, this field remains unified in the pursuit of understanding natural and human-impacted near-surface environments through geophysical investigations. Here we highlight some key references within environmental geophysics. Resources on geophysical theory, acquisition logistics, processing and inversion workflows, and example case studies are categorized into the most common geophysical classes within Geophysical Methods. Lastly, example references for the dominant types of applications in environmental geophysical studies are catalogued in Environmental Applications.

Book chapter

Subsurface vertical connectivity shapes solute transport to montane streams: Insights from watershed-scale geophysics-informed modeling

Headwater catchments provide essential water and nutrients to downstream ecosystems. The timing and evolution of their transport is shaped in part by the “invisible” subsurface structure but have been largely unexplored at the watershed scale. This raises a fundamental question: how and to what extent does subsurface structure influence streamflow and solute transport in montane watersheds? Here, we test controls of three-dimensionally resolved subsurface structure on solute transport, which reflects source waters and water residence time. We integrate the geophysically mapped architecture of Coal Creek, a headwater catchment in the Colorado River Basin, into numerical flow-transport models. Our results reveal greater vertical connectivity elongates flow paths and enhances deep groundwater contributions to streams, therefore substantially influencing the timing and magnitude of solute transport. In contrast, watershed-integrated outlet discharge can be predicted without high-resolution subsurface information. These findings demonstrate incorporating subsurface architecture is critical for predicting ecosystem health and contaminant transport.

Colorado

Cross-fade sampling: Extremely efficient Bayesian inversion for a variety of geophysical problems

This paper introduces cross-fade sampling, a computationally efficient Markov Chain Monte Carlo simulation method that uses a semi-analytical approach to quickly solve Bayesian inverse problems that do not themselves have an analytical solution. Cross-fading is efficient in two ways. First, it requires fewer samples to obtain the same quality simulation of the target probability density function (PDF). Secondly, it is much faster to evaluate the posterior probability of each sample than conventional sampling methods for simulating Bayesian posterior PDFs. Conventional methods require evaluating the prior probability (which describes your a priori constraints) and data likelihood (which describes the fit between the observations and the predictions of the model) for each sample model. However, cross-fading does not require evaluating the data likelihood, meaning that ‘big data’ can be fit with zero additional computational cost. Further, the cross-fading approach can be used to calculate the marginal likelihood associated with a model design, facilitating model comparison and Bayesian model averaging. Topics covered in this paper include derivation of the cross-fade approach and how it can be used to simulate Bayesian posterior PDFs and compute the marginal likelihood, discussion of the class of problems to which cross-fading can be applied (with examples from earthquake statistics, earthquake ground motion modelling, volcanic eruption forecasting, and finite fault slip modelling), demonstration of efficiency relative to existing sampling methods and discussion of how cross-fading can be used to account for prediction errors (i.e. epistemic errors) as part of the geophysical inverse problem.

Geophysical Journal International

Revisiting the utility of regional-scale, high-quality geophysical data in mineral exploration - A case study featuring the Mammoth Magnetic Anomaly, Pinal County, Arizona

Regional aeromagnetic surveys passively measure the total magnetic intensity (TMI) and are a foundational tool used in mineral exploration (Airo, 2015). With the increased global demand and the number of critical mineral resources required for manufacturing high-tech devices, developing high-quality, regional-scale geophysical surveys could aid critical mineral exploration efforts and geologic mapping. In 2019, the U. S. Geological Survey launched the Earth Mapping Resources Initiative (Earth MRI) to modernize the geologic and geophysical mapping of regions that have the potential to contain critical mineral resources within the United States. In support of planning Earth MRI geophysical surveys, Drenth and Grauch (2019) defined five aeromagnetic data quality rankings (rank 1 through rank 5) applying them to the airborne geophysical survey inventory of the United States (Johnson et al., 2021). Rank 1 aeromagnetic surveys are of the highest quality, meeting modern standards and allowing best practices for qualitative and quantitative interpretation; whereas rank 5 aeromagnetic surveys are of the lowest quality, being useful only for qualitative interpretation of broad features. Through the Earth MRI effort, 48 high-quality, regional-scale rank 1 and 2 airborne magnetic and radiometric geophysical surveys have been planned, collected, or publicly release through May 2025 (U. S. Geological Survey, 2025). Here, a portion of a rank 1 Earth MRI aeromagnetic survey in southeast Arizona is presented and compared to a legacy rank 5 aeromagnetic survey over the Mammoth Magnetic Anomaly (MMA), demonstrating how modern, high-quality aeromagnetic data improves our view of crustal geology, aiding mineral exploration.

Arizona

Computational electromagnetic geophysics for groundwater system studies: A review on established practices and recent advances

Identifying effective solutions for locating groundwater resources and ensuring the quality of drinking water is increasingly urgent, given the challenges posed by climate change and population growth. This review investigates electromagnetic geophysical imaging techniques, in both time- and frequency-domain, that can provide valuable insights for groundwater assessment. We explore computational electromagnetic methods used to evaluate electromagnetic data and several recent hydrogeophysical case studies. As open-source frameworks for modeling electromagnetic geophysical problems become available, a broader range of researchers can interpret their data with computationally advanced software. We provide an overview of documented open-source codes for evaluating electromagnetic data and analyze various hydrological targets in relation to their electromagnetic surveying technique and the computational method applied. Furthermore, we evaluate the potential of advanced computational techniques, including three-dimensional modeling, non-deterministic inversion and machine learning, to couple geophysical with numerical groundwater modeling and apply it in groundwater system studies. Despite obstacles such as complexity and resource demands, our findings indicate that the quantification and integration of predictive uncertainties from both electromagnetic and hydrological data and simulations would significantly improve the reliability of hydrogeophysical models. This can lead to a deeper understanding of groundwater systems and improved management practices.

Journal of Hydrology

Multi-scale geophysical mapping of the brine and bedrock surfaces along the Dolores River, Paradox Valley, Colorado, December 2023

Total dissolved solids derived from salt dome–sourced brine in the underlying alluvial aquifer substantially increase with distance in the reach of the Dolores River that passes through Paradox Valley in southwestern Colorado. The area has been the site of salinity control operations since the 1990s to reduce salt loading to the downstream Colorado River. Previous airborne and ground/water-based electromagnetic (EM) geophysical data have successfully mapped the top of the brine surface, albeit with relatively coarse near-surface resolution and limited spatial coverage. This present December 2023 study used ground-based high-resolution EM and passive seismic (horizontal-to-vertical spectral ratio, HVSR) tools to map in detail the depth and thickness of the brine zone in the alluvial aquifer (top of the brine down to bedrock contact) in areas immediately surrounding the Dolores River where previous airborne EM (AEM) results indicated brine within 10 m of land surface. Results indicate the deepest bedrock is generally associated with the shallowest brine and local depressions in the collapse breccia (caprock to the Paradox Formation salt) may facilitate vertical migration of brine into the alluvial aquifer. Additionally, the ground-based EM mapping corroborated general patterns in depth to brine that were observed in previous AEM results while also revealing additional detail, including suspected focused brine discharge zones to the Dolores River. A river-based survey wherein EM data, channel depth and river water–specific conductance information were collected augmented these findings and indicated specific areas on both the western and eastern sides of the river where focused brine discharge may occur. This study comprises a large-scale, ground- and water-based geophysical mapping effort, including hundreds of HVSR soundings and 100s of kilometres of EM data, which were successfully translated into digital brine and bedrock surfaces that could be incorporated into groundwater modelling efforts, future well siting or other decision-making.

Colorado

A multi-channel digital telemetry system for low frequency geophysical data

An inexpensive general purpose digital telemetry system for collection of low frequency geophysical data from U.S. Geological Survey instruments (eg. tilt, strain, gravity, creep, water level, radon, magnetic field, resistivity, telluric current, temperature, etc.) has been designed and built. This system provides data for a more general interactive data acquisition, retrieval and analysis system. The field stations are self-contained, battery operated and housed in weather proof containers. Each accepts up to 15 analog data inputs in the range of -5 to +5 volts. The dynamic range is 70db. The units transmit information as FSK (Frequency Shift Keyed) tones onto either a phone line or radio link with up to 150 transmitters sharing one line. The average power consumption is 0.06 nR watts where n is the 1 number of input channels transmitted and R is the sample rate in minutes -1 . The central receiver-recorder unit accepts and decodes the FSK tones and converts, formats and records the digital data together with time information and station identification on IBM combatible magnetic tape. The digital data are also converted and recorded in analog form for visual monitoring.

Open-File Report

Multi-scale geophysical imaging of a hydrothermal system in Yellowstone National Park, USA

Little is known about the local plumbing systems that fuel Yellowstone’s famous hot springs, geysers and mud pots. A multi-method, multi-scale geophysical investigation was carried out in the Obsidian Pool Thermal Area (OPTA) to: (i) delineate the lateral extent of the hydrothermal area and associated surface features; (ii) estimate the dimensions of the upflow zone and identify its main controlling structures; (iii) assess fluids circulation pathways from depth to surface. Ground and airborne geophysical data were acquired to connect local and regional scales, from shallow to large depths. Maps of surface electrical resistivity show a strong correlation with hydrothermal features. At in-termediate depths, electrical resistivity permits delineating the upper limit of the upflow zone, while Poisson’s ratio highlights differences in subsurface fluid content. Combining these results with surface observations and topographic information, we speculate that differential mixing of hydrothermal and fresh water could explain the wide diversity of features observed at OPTA. Low electrical resistivity observed at large depths also suggest that a vast upflow zone, controlled by rhyolite flows and conjugate faults, underlies the OPTA. We speculate that hydrothermal fluids rise along fractures and reach the surface in topographic lows to form hydrothermal features. Our results show that synoptic, multi-scale geophysical measurements provide a roadmap for understanding where and how geologic heterogeneity, topography, fluid-gas separation, and the mixing of thermal and meteoric waters conspire to produce the wide variety of Yellowstone’s renowned hydrothermal features.

Wyoming

Groundwater spatial variability within an atoll island: Assessing shallow aquifer heterogeneity with geophysical and physicochemical measurements

This study examines the spatial variability of shallow groundwater on Dhigelaabadhoo Island using electromagnetic induction surveys, groundwater monitoring, and sediment analyses. The research reveals how variations in island morphology—such as differences in elevation, reef flat width, and sediment composition—affect the spatial distribution of groundwater lenses and the overall aquifer dynamics. Saltwater intrusion is especially pronounced in low elevated areas, with narrow reef flat plate and areas where higher hydraulic conductivity—driven by the presence of coarser sediments—is observed, whereas regions characterized by finer sediments, higher elevation, and wider reef flat plates tend to support more symmetric and less saline groundwater lenses. The geophysical investigations reveal that tidal oscillations alter groundwater movement by markedly changing water levels and conductivity, thereby underscoring the critical need to account for temporal dynamics in atoll coastal aquifer systems and the importance of integrating tidal dynamics into the aquifer zone. The findings highlight the significant role of intrinsic morphological and external hydrodynamic factors in shaping groundwater distribution on atoll islands, offering critical insights for sustainable freshwater resource management.

Dhigelaabadhoo Island

Geophysical characterization of an alkaline‑carbonatite complex using gravity and magnetic methods at Magnet Cove, Arkansas, USA

The Magnet Cove alkaline‑carbonatite complex (MCC), located in the Ouachita Mountains of south-central Arkansas in the United States, hosts an extensive variety of rare rock types and critical mineral resources with physical properties (density and magnetization) that contrast significantly with the sedimentary rocks into which they have intruded. Newly acquired ground-based gravity and magnetic data were used to develop two-dimensional and three-dimensional geophysical models of the Cretaceous-aged Magnet Cove intrusive complex. The models reveal that the MCC: (1) widens out at middle crustal depths to as much 22 km across, and may reach a depth of 20 km; (2) has a total volume (exposed and subsurface) that may be over 800 km 3 ; (3) is likely connected at depth to other intrusions in the Arkansas alkaline province; and (4) has a geometry that is aligned with pre-existing structures such as the Reelfoot rift and the Ouachita orogenic belt, some of which were likely structurally controlled by the Precambrian crystalline basement and the continent-ocean transition zone buried beneath the Ouachita orogen. For the first time, the magnetic models of the MCC account for the presence of strong remanent magnetization. This results in a geophysical workflow necessary to accurately interpret magnetic anomalies over the much larger Arkansas alkaline province, its geologic and structural framework, and critical mineral potential.

Arkansas

Preliminary ground and airborne-based geophysical mapping and modelling of an active hydrothermal system at Mammoth Lakes, California

Mammoth Lakes, California hosts a productive hydrothermal system within the seismically active south moat of Long Valley Caldera. Surficial evidence of the shallow hydrothermal system includes discrete zones of tree-kill dispersed between Shady Rest Park and the Casa Diablo Geothermal Power Plant (40 MW), as well as east of the power plant. The tree-kill areas are associated with elevated diffuse CO₂ emissions, heated ground, hydrothermal alteration, diffuse soil H₂S emissions, and gas vents. Previous mapping delineates prominent north and northwest trending structures within the south moat along the southwestern edge of the resurgent dome that may accommodate gas and fluid flow at the Shady Rest Park and Basalt Canyon Tree Kill Areas (SRTKA and BCTKA, respectively). Both tree-kill areas are also located along contacts between resurgent rhyolite, mafic lavas, and surficial deposits which may provide additional pathways for gas and fluid migration in the shallow subsurface. Characterizing structure and lithology using geophysical anomalies is critical to determining primary structural controls on the hydrothermal system and the extent of subsurface alteration at these sites. We conducted ground and airborne-based potential field geophysical surveys to map gravity and magnetic anomalies. These anomalies are then used to model subsurface geology, structure, and hydrothermal alteration. Here we present our preliminary geophysical mapping and modelling results at both tree-kill locations. Gravity and magnetic data suggest complex structural intersections are coincident with heated ground and gas emissions at the SRTKA and BCTKA. Hydrothermal systems are often observed or interpreted to exploit fault intersections which can serve as highly permeable pathways for hydrothermal fluid and gas discharge, enabling economic geothermal energy production. Geophysical mapping and modelling are an effective means of investigating such structural complexity at Mammoth Lakes due to the presence of unidentified and concealed structures.

California

Synergy between geology and geophysics in graphite mineral resource assessment

Graphite is designated as a critical mineral by the U.S. Government due to its essential role in modern technology and its vulnerability to supply chain disruption. To evaluate domestic graphite resources, the U.S. Geological Survey (USGS) conducted two airborne electromagnetic (AEM) surveys as part of the Earth Mapping Resources Initiative (Earth MRI) over prospective areas in the southern Appalachians of Alabama and the Seward Peninsula of Alaska. These surveys aimed to refine areas of interest by revealing subsurface electrical resistivity patterns indicative of graphite-bearing rocks. The results of the AEM surveys were integrated with existing geological knowledge and supplemented by field observations to assess the likelihood of undiscovered resources in these regions. This multidisciplinary approach combined geophysical techniques with traditional geological methods, enhancing the understanding of graphite potential in areas that may have been previously overlooked. The findings from this initiative are expected to contribute significantly to the ongoing efforts to secure a reliable domestic supply of graphite, thereby reducing import reliance and supporting national interests in mineral resource management.

Conference Paper

Advancing subsurface investigations beyond the borehole with passive seismic horizontal-to-vertical spectral ratio and electromagnetic geophysical methods at transportation infrastructure sites in New Hampshire

The U.S. Geological Survey (USGS), in cooperation with the New Hampshire Department of Transportation (NHDOT), surveyed transportation infrastructure sites using rapidly deployable geophysical methods to assess benefits added to a comprehensive site characterization with traditional geotechnical techniques. Horizontal-to-vertical spectral-ratio (HVSR) passive-seismic and electromagnetic-induction (EMI) methods were applied at 4 sites including a roadway-stream crossing, roadway-bridge rail-trail crossing, commuter-parking expansion, and a railroad-adjacent river-cutbank slope-failure site. Additionally, ground-penetrating-radar (GPR) was used at the slope-failure site. Typically, subsurface geotechnical properties are determined from boring data; however, borings are often spaced hundreds of feet apart, potentially missing important spatial variability between boreholes. Geotechnical site characterization including geophysical surveys helped provide a more accurate characterization by using continuous or near continuous profiling. Three-component ambient noise measured with HVSR methods were used to determine resonance frequency and estimate sediment thickness. The method works when there is a strong shear-wave acoustic impedance contrast (> 2:1) between sediment and bedrock. Sediment thickness estimates from HVSR measurements were combined with boring data to make detailed maps of the bedrock surface altitude. The bulk electrical conductivity of the subsurface was indirectly measured with EMI methods and was used to identify lithologic variations, shallow bedrock, and conductive groundwater. Ground penetrating radar, which transmits pulses of electromagnetic energy into the subsurface and records the amplitude and timing of reflected signals, was used to identify bedding and changes in lithology or water content. By combining geophysical and boring data analyses, transportation projects produced more spatially comprehensive representations of geotechnical subsurface conditions than would be determined using conventional borings alone.

New Hampshire

Borehole geophysical time-series logging to monitor passive ISCO treatment of residual chlorinated-ethenes in a confining bed, NAS Pensacola, Florida

In-situ chemical oxidation (ISCO) is a common method to remediate chlorinated ethene contaminants in groundwater. Monitoring the effectiveness of ISCO can be hindered because of insufficient observations to assess oxidant delivery. Advantageously, potassium permanganate, one type of oxidant, provides the opportunity to use its strong electrical signal as a surrogate to track oxidant delivery using time-series borehole geophysical methods, like electromagnetic (EM) induction logging. Here we report a passive ISCO (P-ISCO) experiment, using potassium permanganate cylinders emplaced in boreholes, at a chlorinated ethene contamination site, Naval Air Station Pensacola, Florida. The contaminants are found primarily at the base of a shallow sandy aquifer in contact with an underlying silty-clay confining bed. We used results of the time-series borehole logging collected between 2017 and 2022 in 4 monitoring wells to track oxidant delivery. The EM-induction logs from the monitoring wells showed an increase in EM response primarily along the contact, likely from pooling of the oxidant, during P-ISCO treatment in 2021. Interestingly, concurrent natural gamma-ray (NGR) logging showed a decrease in NGR response at 3 of the 4 wells possibly from the formation of manganese precipitates coating sediments. The coupling of time-series logging and well-chemistry data allowed for an improved assessment of passive ISCO treatment effectiveness.

Florida