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At least 55 records · Page 3Linked to original sources
USGS2000

Wildlife in a chemical world

Snapping turtles were collected by the Ohio State EPA from six locations in Ohio believed to have different contaminant concentrations. Previously we reported significant correlations among four hepatic microsomal dealkylases and CYP1A in these turtles. Herein we compare ethoxyresorufin-O-dealkylase (EROD) and methoxyROD (MROD) to tissue contaminant concentrations. For Fifty-four of these turtles, muscle, fat body and liver tissues were assessed for PCBs and 20 organochlorine analytes and hepatic microsomal dealkylases. Of the contaminants analyzed, only DDE, dieldrin, oxychlordane, trans-nonachlor and PCB 1260 were detected in >25% of each sample type. When EROD and MROD activities were compared to tissue values for these contaminants, they were found to correlate significantly only to DDE, dieldrin and trans-nonachlor. For an 18 female subset of these turtles, serum PCBs and organochlorine pesticides, egg, fat body and liver dioxins and furans, and hepatic microsomal dealkylases were assessed. EROD and MROD both correlated significantly to serum PCB 105, PCB 138 and DDE, and to egg total PCBs. EROD and MROD did not correlate significantly with liver dioxins and furans, but there were significant correlations between EROD and egg and fat body dioxins and furans, and MROD and fat body dioxins and furans. It is expected that CYP1A-type inducers such as certain PCBs, and halogenated dioxins and furans, but not organochlorine pesticides, would be inducers in turtles. Presumably the correlation of monooxygenase with organochlorine pesticides is fortuitous, and toxic equivalencies are being calculated using a number of systems.

Ohio↗
USGS1993

Geologic radon potential of the United States

The Indoor Radon Abatement Act of 1988 (Public Law 100-551) directed the U.S. Environmental Protection Agency (EPA) to identify areas of the United States that have the potential to produce harmful levels of indoor radon, based on both geological data and on indoor radon levels in homes and other structures. As part of an Interagency Agreement between the EPA and the U.S. Geological Survey (USGS), the USGS prepared radon potential estimates for the United States. The purpose and intended use of these reports is to help identify areas where states can target their radon program resources, to provide guidance in selecting the most appropriate building code options for areas, and to provide general information on radon and geology for each state for federal, state, and municipal officials dealing with radon issues. The booklets are organized by EPA Federal boundaries (Regions) with chapters for each state. Each state chapter discusses the state's specific geographic setting, soils, geologic setting, geologic radon potential, indoor radon data, and a summary outlining the radon potential rankings of geologic areas in the state.

Open-File Report↗
USGS1995

Occurrence of the gasoline additive MTBE in shallow ground water in urban and agricultural areas

Methyl tert -butyl ether (MTBE) is a volatile organic compound (VOC) derived from natural gas that is added to gasoline either seasonally or year round in many parts of the United States to increase the octane level and to reduce carbon monoxide and ozone levels in the air. In 1993, production of MTBE ranked second among all organic chemicals manufactured in the United States. Currently, the U.S. Environmental Protection Agency (EPA) tentatively classifies MTBE as a possible human carcinogen. Health complaints related to MTBE in the air were first reported in Fairbanks, Alaska in November 1992 when about 200 residents reported problems such as headaches, dizziness, eye irritation, burning of the nose and throat, disorientation, and nausea. Similar health complaints have been registered in Anchorage, Alaska; Missoula, Montana; Milwaukee, Wisconsin; and New Jersey. As part of the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Program, concentrations of 60 VOCs were measured in samples from 211 shallow wells in 8 urban areas and 524 shallow wells in 20 agricultural areas. Chloroform and MTBE were the two most frequently detected VOCs. MTBE was detected in 27 percent of the urban wells and 1.3 percent of the agricultural wells. Concentrations ranged from less than the detection level of 0.2 μg/L (micrograms per liter) to as high as 23,000 μg/L. When detected, the median concentration of MTBE was 0.6 μg/L. MTBE was most frequently detected in shallow ground water in Denver, Colorado and urban areas in New England. In Denver, 79 percent of the samples from shallow urban wells had detectable concentrations of MTBE and in New England, 37 percent of the samples from urban wells had detectable concentrations. Only 3 percent of the wells sampled in urban areas had concentrations of MTBE that exceeded 20 μg/L, which is the estimated lower limit of the EPA draft drinking water health advisory level. Contaminant concentrations below the health advisory are not expected to cause any adverse effects over a lifetime of exposure. MTBE is on the EPA’s Drinking Water Priority List, which means it is a possible candidate for future regulation.

Fact Sheet↗
USGS2000

Analytical results for total-digestions, EPA-1312 leach, and net acid production for twenty-three abandoned metal-mining related wastes in the Boulder River watershed, northern Jefferson County, Montana

Introduction Metal-mining related wastes in the Boulder River basin study area in northern Jefferson County, Montana, have been implicated in their detrimental effects on water quality with regard to acid generation and toxic-metal solubilization during snow melt and storm water runoff events. This degradation of water quality is defined chiefly by the “Class 1 Aquatic Life Standards” that give limits for certain dissolved metal concentrations according to water alkalinity. Veins enriched in base- and precious metals were explored and mined in the Basin, Cataract Creek, and High Ore Creek drainages over a period of more than 70 years. Extracted minerals included galena, sphalerite, pyrite, chalcopyrite, tetrahedrite and arsenopyrite. Most of the metal-mining wastes in the study area were identified and described by the Montana Bureau of Mines and Geology. In 1997, the U.S. Geological Survey collected 20 composite samples of mine-dump or tailings waste from ten sites in the Basin and Cataract Creek drainages, and two samples from one site in the High Ore Creek drainage. Desborough and Fey presented data concerning acid generation potential, mineralogy, concentrations of certain metals by energy-dispersive X-ray fluorescence (EDXRF), and trace-element leachability of mine and exploration wastes from the ten sites of the Basin and Cataract Creek drainages. The present report presents total-digestion major- and trace-element analyses, net acid production (NAP), and results from the EPA-1312 synthetic precipitation leach procedure (SPLP) performed on the same composite samples from the ten sites from the Basin and Cataract Creek drainages, and two composite samples from the site in the High Ore Creek drainage.

Montana↗
USGS2020

Arsenic and uranium occurrence in private wells in Connecticut, 2013–18—A spatially weighted and bedrock geology assessment

The U.S. Geological Survey, in cooperation with the Connecticut Department of Public Health, conducted a study to determine the presence of arsenic and uranium in private drinking water wells in Connecticut. Samples were collected during 2013–18 from wells completed in 115 geologic units, with 2,433 samples analyzed for arsenic and 2,191 samples analyzed for uranium. The study concluded four major findings. In a spatially weighted analysis of groundwater samples collected from more than 2,000 private wells in bedrock aquifers in Connecticut, 3.9 percent of collected samples contained arsenic concentrations greater than the U.S. Environmental Protection Agency’s (EPA) maximum contaminant level (MCL) of 10 micrograms per liter (µg/L), and 4.7 percent of collected samples contained uranium concentrations greater than the EPA MCL of 30 µg/L. Of the 2,433 water samples collected and analyzed from bedrock aquifers in Connecticut, 4.2 percent (102) contained arsenic concentrations at greater than 10 µg/L, and of the 2,191 water samples collected and analyzed from bedrock aquifers in Connecticut, 5.4 percent (118) contained uranium concentrations greater than 30 µg/L. Uranium concentrations greater than or equal to 1 µg/L are relatively ubiquitous across the State of Connecticut, with these concentrations present in 44.9 percent of the State, according to spatially weighted statewide-scale proportion analysis. Of the 115 geologic units studied, 44 had at least one sample with arsenic or uranium concentrations that exceeded the respective constituent’s EPA MCL.

Connecticut↗
USGS2011

An evaluation of traditional and emerging remote sensing technologies for the detection of fugitive contamination at selected Superfund hazardous waste sites

This report represents a remote sensing research effort conducted by the U.S. Geological Survey in cooperation with the U.S. Environmental Protection Agency (EPA) for the EPA Office of Inspector General. The objective of this investigation was to explore the efficacy of remote sensing as a technology for postclosure monitoring of hazardous waste sites as defined under the Comprehensive Environmental Response Compensation and Liability Act of 1980 (Public Law 96-510, 42 U.S.C. §9601 et seq.), also known as \"Superfund.\" Five delisted Superfund sites in Maryland and Virginia were imaged with a hyperspectral sensor and visited for collection of soil, water, and spectral samples and inspection of general site conditions. This report evaluates traditional and hyperspectral imagery and field spectroscopic measurement techniques in the characterization and analysis of fugitive (anthropogenic, uncontrolled) contamination at previously remediated hazardous waste disposal sites.

Open-File Report↗
USGS1997

A new database on contaminant exposure and effects in terrestrial vertebrates for natural resource managers

The Biomonitoring of Environmental Status and Trends (BEST) program of the Department of the Interior is focused to identify and understand effects of contaminant stressors on biological resources under their stewardship. Despite the desire of many to continuously monitor the environmental health of our estuaries, much can be learned by summarizing existing temporal, geographic, and phylogenetic contaminant information. To this end, retrospective contaminant exposure and effects data for amphibians, reptiles, birds, and mammals residing within 30 km of Atlantic coast estuaries are being assembled through searches of published literature (e.g., Fisheries Review, Wildlife Review, BIOSIS Previews) and databases (e.g., US EPA Ecological Incident Information System; USGS Diagnostic and Epizootic Databases), and compilation of summary data from unpublished reports of government natural resource agencies, private conservation groups, and universities. These contaminant exposure and effect data for terrestrial vertebrates (CEE-TV) are being summarized using Borland dBASE in a 96- field format, including species, collection time and site coordinates, sample matrix, contaminant concentration, biomarker and bioindicator responses, and source of information (N>1500 records). This CEE-TV database has been imported into the ARC/INFO geographic information system (GIS), for purposes of examining geographic coverage and trends, and to identify critical data gaps. A preliminary risk assessment will be conducted to identify and characterize contaminants and other stressors potentially affecting terrestrial vertebrates that reside, migrate through or reproduce in these estuaries. Evaluations are underway, using specific measurement and assessment endpoints, to rank and prioritize estuarine ecosystems in which terrestrial vertebrates are potentially at risk for purposes of prediction and focusing future biomonitoring efforts.

Book chapter↗
USGS2020

Technical memorandum: Compound specific isotope analysis, Oak Grove Village well site OU1, Franklin County, Missouri

A study involving Compound Specific Isotope Analysis (CSIA) of trichloroethene (TCE) in groundwater at the Oak Grove Village (OGV) Well Site was conducted by the U.S. Environmental Protection Agency (EPA) in 2014 in an effort to fingerprint the source(s). This technical memorandum, written as a joint effort between HydroGeoLogic, Inc. (HGL) and the U.S. Geological Survey (USGS) Central Midwest Water Science Center (Schumacher, 2019), documents the procedures and analysis of the CSIA investigation. CSIA is an analytical method that measures the isotopic ratios of naturally occurring stable isotopes in specific chemical compounds in environmental samples. CSIA using primarily the ratio of carbon 13 C/ 12 C (δ 13 C), known as 1-D CSIA, has been used for decades in evaluating degradation pathways of organic compounds, including chlorinated solvents such as TCE. Ratios of stable chlorine isotopes 37 Cl/ 35 Cl (δ 37 Cl) also have been used with carbon isotopes, collectively known as 2-D CSIA, and most recently isotopes of hydrogen 2 H/ 1 H (δ 2 H) have been added, collectively known as 3-D CSIA, in attempts to further determine source, transport, and fate of compounds such as TCE (Ertl et al., 1998; Hunkeler et al., 2011; Kuder et al., 2013; McHugh et al., 2011; Shouakar-Stash et al., 2003; EPA, 2008; and van Warmerdam et al., 1995.

Missouri↗
USGS2021

Borehole analysis, single-well aquifer testing, and water quality for the Burnpit well, Mount Rushmore National Memorial, South Dakota

Mount Rushmore National Memorial (hereafter referred to as “the memorial”), in western South Dakota, is maintained by the National Park Service (NPS) and includes 1,278 acres of land in the east-central part of the Black Hills. An ongoing challenge for NPS managers at the memorial is providing water from sustainable and reliable sources for operations, staff, and the increasing number of visitors. In 2020, the U.S. Geological Survey (USGS) and NPS completed a hydrological study of the Burnpit well (well 5), a 580-foot-deep open hole groundwater well completed in metamorphic (crystalline) rock at the memorial. The purpose of this study was to estimate the geological and hydraulic properties of the aquifer supplying the well and to determine the water quality of the groundwater from the well. The study provides NPS staff and managers background information for assessing future uses for the well. Methods for data collection and analysis for the study included borehole and video camera analysis in 2020, aquifer testing by the NPS in 2009 and the USGS in 2020, and water-quality sampling in 2020. Borehole camera video generally matched the lithology recorded in the well log. Fractures recorded in the well log and observed with the borehole camera, including more than 20 less prominent fractures and rough sidewall areas, indicated a fractured aquifer. The fractures are the primary conduits for groundwater flow through the rock and into the well. Transmissivity was estimated for the upper and lower water-level drawdown zones at the Burnpit well with data from the NPS and USGS using the Theis and Cooper-Jacob methods. Transmissivity for the NPS test using the Theis method was 9.0 and 11 feet squared per day (ft 2 /d) for the upper and lower drawdown zones, respectively. Using the Cooper-Jacob method, the transmissivity was 22 and 14 ft 2 /d for the upper and lower drawdown zones of the aquifer, respectively. Transmissivity estimates from data from the USGS test were similar. The Theis method, applied to the upper and lower drawdown zones of the aquifer, produced transmissivity estimates of 7.7 and 10 ft 2 /d, and the Cooper-Jacob method produced estimates of 9.7 and 12 ft 2 /d, respectively. Storativity (specific yield) estimated using the Theis method for the NPS aquifer-test data was 0.85 and 0.92 for the upper and lower drawdown zones of the aquifer, respectively. The Cooper-Jacob method applied to the NPS aquifer-test data produced storativity estimates of 0.11 and 0.50 for the upper and lower drawdown zones, respectively. The Theis method applied to the USGS aquifer-test data estimated storativity values of 0.77 and 1.0 for the upper and lower drawdown zones, respectively. The Cooper-Jacob method estimated storativity of 0.50 and 0.60 for the upper and lower drawdown zones of the USGS aquifer test, respectively. The estimated storativity values from the NPS and USGS aquifer tests for the upper and lower drawdown zones were higher than expected for limestones and schists. The hypothetical equilibrium drawdown for the Burnpit well was estimated after the NPS test in 2009 at no more, and possibly less, than 35 gallons per minute. The NPS noted that the sustainable yield likely was overestimated because the water level did not stabilize during the NPS aquifer test. The specific capacity for the NPS aquifer test in 2009 was 0.16 gallon per minute per foot ([gal/min]/ft) of drawdown at 3 hours, and the specific capacity for the USGS aquifer test in 2020 was 0.13 (gal/min)/ft of drawdown at 3 hours. The rate of water-level recovery after pumping ceased was 0.017 and 0.013 (gal/min)/ft for the NPS and USGS aquifer tests, respectively. The water-level recovery rate was nearly an order of magnitude less than the specific capacity estimated during pumping, indicating that water levels in the Burnpit well may not recover quickly enough during pumping to provide for a continuous source of water. Water-quality samples were collected at the Burnpit well on June 24 and July 23, 2020, and analyzed for field-measured properties, major ions, metals, nutrients, and perchlorate. Iron, zinc, and lithium concentrations for unfiltered samples in the well were at least three times greater than the mean filtered sample concentrations reported for crystalline aquifers in the Black Hills. Manganese concentrations were less than the mean concentration for crystalline aquifers but exceeded the U.S. Environmental Protection Agency (EPA) secondary drinking-water standards. The iron concentration from the June 24 sample was about 11 times greater than the EPA secondary drinking-water standards and mean concentrations from crystalline aquifers in the Black Hills. Arsenic concentrations in Burnpit well samples collected in 2020 were greater than the EPA primary drinking-water standard and the mean concentration for crystalline aquifers in the Black Hills. Arsenic occurs naturally in the rock of crystalline aquifers, and concentrations from samples in the Black Hills commonly exceed the EPA primary drinking-water standard of 10 micrograms per liter. High concentrations of arsenic, iron, and manganese metals in the Burnpit well make groundwater from the well in its natural state unusable as a drinking-water source, and water treatment would be necessary to reduce the trace element concentrations to less than the EPA primary and secondary drinking-water standards. However, if the memorial has immediate nonpotable water requirements, such as for construction and fire suppression, groundwater from the Burnpit well could provide water without causing additional stress to current (2021) drinking-water sources.

South Dakota↗
USGS2012

Reformatted data sets used in the Cooperative LACSD/USGS Palos Verdes Flow Study, 2000--2008

Beginning in 1997, the Environmental Protection Agency (EPA) defined a contaminated section of the Palos Verdes shelf in southern California as a Superfund site, initiating a continuing investigation of this area. A number of agencies, including the EPA, U.S. Geological Survey (USGS), and Science Applications International Corporation (SAIC), conducted two oceanographic measurement programs in 2004 and 2007-2008 (SAIC, 2004, 2005; Rosenberger and others, 2010; Sherwood and others, unpublished data) to improve our understanding of the natural processes that resuspend and transport sediment in the area, especially in the region southeast of the Whites Point ocean outfall where earlier measurements were thought to be deficient. Los Angeles County Sanitation Districts (LACSD) deployed a simpler but much broader array of instruments on the Palos Verdes shelf and within the northern reaches of San Pedro Bay from 2000 to 2008 in order to characterize the current and temperature patterns within these regions. This program overlapped the two programs run by USGS and other agencies in 2004 and 2007. The LACSD data were made available to the USGS and the EPA in order to support their joint efforts to model the transport of the contaminated sediments in the region. This report describes the LACSD data sets, the instruments and data-processing procedures used, and the archive that contains the data sets that have passed our quality-assurance procedures.

California↗
USGS2018

Assessment of dissolved-selenium concentrations and loads in the lower Gunnison River Basin, Colorado, as part of the Selenium Management Program, from 2011 to 2016

The Gunnison Basin Selenium Management Program implemented a water-quality monitoring network in 2011 in the lower Gunnison River Basin in Colorado. Selenium is a trace element that bioaccumulates in aquatic food chains and can cause reproductive failure, deformities, and other harmful effects. This report presents the percentile values of selenium because regulatory agencies in Colorado make decisions based on the U.S. Environmental Protection Agency (EPA) Clean Water Act Section 303(d) that uses percentile values of concentration. Also presented are dissolved-selenium loads at 18 sites in the lower Gunnison River Basin for water years (WYs) 2011–2016 (October 1, 2010, through September 30, 2016). Annual dissolved-selenium loads were calculated for five sites with continuous U.S. Geological Survey (USGS) streamflow-gaging stations. Annual dissolved-selenium loads for WY 2011 through WY 2016 ranged from 179 and 391 pounds (lb) at Uncompahgre River at Colona to 11,100 and 17,300 lb at Gunnison River near Grand Junction (herein called Whitewater), respectively. Instantaneous loads were calculated for five sites with continuous U.S. Geological Survey (USGS) streamflow-gaging stations and 13 ancillary sites where discrete water-quality sampling also took place, using discrete water-quality samples and the associated discharge measurements collected during the period. Median instantaneous loads ranged from 0.01 pound per day (lb/d) at Smith Fork near Lazear to 33.0 lb/d at Whitewater. Mean instantaneous loads ranged from 0.06 lb/d at Smith Fork near Lazear to 36.2 lb/d at Whitewater. Most tributary sites in the basin had a median instantaneous dissolved-selenium load of less than 20.0 lb/day. In general, dissolved-selenium loads at Gunnison River main-stem sites showed an increase from upstream to downstream. The State of Colorado water-quality standard for dissolved selenium of 4.6 micrograms per liter (µg/L) was compared to the 85th percentiles for dissolved selenium at selected sites. Annual 85th percentiles for dissolved selenium were calculated for the five core sites having USGS streamflow-gaging stations using estimated dissolved-selenium concentrations from linear regression models. The 85th-percentile concentrations for WYs 2011–2016 based on this method ranged from 0.62 µg/L and 1.1µg/L at Uncompahgre River at Colona to 12.1 µg/L and 18.7 µg/L at Uncompahgre River at Delta. The 85th percentiles for dissolved selenium also were calculated for sites with sufficient data using water-quality samples collected during WYs 2011–2016. The annual 85th-percentile concentrations based on the discrete samples ranged from 0.16 µg/L and 0.17 µg/L at Gunnison River below Gunnison Tunnel to 62.2 µg/L and 170 µg/L at Loutzenhizer Arroyo at North River Road. A trend analysis was completed for Whitewater to determine if dissolved-selenium loads are increasing or decreasing. The trend analysis indicates a decrease of 9,100 lb from WY 1986 to WY 2016, a 40.8 percent reduction during the time period. The trend analysis for the annual dissolved-selenium load for WY 1994 to WY 2016 indicates a decrease of 6,300 lb per year, or 33.3 percent.

Colorado↗
USGS2012

Socio-environmental health analysis in Nogales, Sonora, Mexico

In Nogales, Sonora, Mexico, some neighborhoods, or colonias, have intermittent delivery of water through pipes from the city of Nogales’s municipal water-delivery system while other areas lack piped water and rely on water delivered by truck or pipas. This research examined how lifestyles, water quality, and potential disease response, such as diarrhea, differs seasonally from a colonia with access to piped water as opposed to one using alternative water-delivery systems. Water samples were collected from taps or spigots at homes in two Nogales colonias. One colonia reflected high socio-environmental conditions where residents are supplied with municipal piped water (Colonia Lomas de Fatima); the second colonia reflected low socio-environmental conditions, lacking access to piped water and served by pipas (Colonia Luis Donaldo Colosio). A survey was developed and implemented to characterize perceptions of water quality, health impacts, and quality of life. Water samples were analyzed for microbial and inorganic water-quality parameters known to impact human health including, Escherichia coli (E. coli), total coliform bacteria, arsenic, and lead. A total of 21 households agreed to participate in the study (14 in Colosio and 7 in Fatima). In both colonias metal concentrations from water samples were all well below the United States Environmental Protection Agency’s (US EPA’s) maximum contaminant levels. E. coli concentrations exceeded the US EPA’s drinking-water standard in Colosio but not Fatima. Total coliform bacteria were present in over 50 % of households in both colonias. Microbial contamination was significantly higher in the summer than in the winter in both colonias. Resulting analysis suggests that residents in colonias without piped water are at a greater risk of gastrointestinal illness from consumption of compromised drinking water. Our survey corroborated reports of gastrointestinal illness in the summer months but not in the winter. Chloride was found to be significantly greater in Colosio (median 29.2 mg/L) although still below the US EPA’s maximum contaminant levels of 250 mg/L. Ongoing binational collaboration can promote mechanisms to improve water quality in cities located in the US–Mexico border.

Water Quality, Exposure, and Health↗