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USGS1995

Bibliography, indices, and data sources of water-related studies, upper Colorado River basin, Colorado and Utah, 1872-1995

As part of the U.S. Geological Survey's National Water-Quality Assessment Program, current water-quality conditions in the Upper Colorado River Basin in Colorado and Utah are being assessed. This report is an initial effort to identify and compile information on water-related studies previously conducted in the basin and consists of a bibliography, coauthor and subject indices, and sources of available water-related data. Computerized literature searches of scientific data bases were carried out to identify past water-related studies in the basin, and government agencies and private organizations were contacted regarding their knowledge or possession of water-related publications and data. Categories of information in the bibliography include: aquatic biology, climate, energy development, geology, land use, limnology, runoff, salinity, surface- and ground-water hydrology, water chemistry, water quality and quantity, and water use and management. The approximately 1,400 indexed references date from 1872 through February 1995 and include books, journal articles, maps, and reports. In many instances, an abstract has been provided for a given reference. Sources of water-related data in the basin are included in a table.

Colorado, Utah↗

USGS2015

Applied Geochemistry Special Issue on Environmental geochemistry of modern mining

Environmental geochemistry is an integral part of the mine-life cycle, particularly for modern mining. The critical importance of environmental geochemistry begins with pre-mining baseline characterization and the assessment of environmental risks related to mining, continues through active mining especially in water and waste management practices, and culminates in mine closure. The enhanced significance of environmental geochemistry to modern mining has arisen from an increased knowledge of the impacts that historical and active mining can have on the environment, and from new regulations meant to guard against these impacts. New regulations are commonly motivated by advances in the scientific understanding of the environmental impacts of past mining. The impacts can be physical, chemical, and biological in nature. The physical challenges typically fall within the purview of engineers, whereas the chemical and biological challenges typically require a multidisciplinary array of expertise including geologists, geochemists, hydrologists, microbiologists, and biologists. The modern mine-permitting process throughout most of the world now requires that potential risks be assessed prior to the start of mining. The strategies for this risk assessment include a thorough characterization of pre-mining baseline conditions and the identification of risks specifically related to the manner in which the ore will be mined and processed, how water and waste products will be managed, and what the final configuration of the post-mining landscape will be. In the Fall 2010, the Society of Economic Geologists held a short course in conjunction with the annual meeting of the Geological Society of America in Denver, Colorado (USA) to examine the environmental geochemistry of modern mining. The intent was to focus on issues that are pertinent to current and future mines, as opposed to abandoned mines, which have been the focus of numerous previous short courses. The geochemical challenges of current and future mines share similarities with abandoned mines, but differences also exist. Mining and ore processing techniques have changed; the environmental footprint of waste materials has changed; environmental protection has become a more integral part of the mine planning process; and most historical mining was done with limited regard for the environment. The 17 papers in this special issue evolved from the Society of Economic Geologists’ short course. The relevant geochemical processes encompass the source, transport, and fate of contaminants related to the life cycle of a mine. Contaminants include metals and other inorganic species derived from geologic sources such as ore and solid mine waste, and substances brought to the site for ore processing, such as cyanide to leach gold. Factors, such as mine-waste mineralogy, hydrologic setting, mine-drainage chemistry, and microbial activity, that affect the hydrochemical risks from mining are reviewed by Nordstrom et al. In another paper, Nordstrom discusses baseline characterization at mine sites in a regulatory framework, and emphasizes the influence of mineral deposits in producing naturally elevated concentrations of many trace elements in surface water and groundwater. Surface water quality in mineralized watersheds is influenced by a number of processes that act on daily (diel) cycles and can produce dramatic variations in trace element concentrations as described by Gammons et al. Pre-mining baseline characterization studies should strive to capture the magnitude of these diel variations. Desbarats et al., using a case study of mine drainage from a gold mine, illustrate how elements that commonly occur as negatively charged species (anions) in solution, such as arsenic as arsenate, behave in an opposite fashion than most metals, which occur as positively charged species (cations). Significant improvement in the understanding of factors that influence the toxicity of metals to aquatic organisms in surface water has highlighted the importance of aqueous chemistry, particularly dissolved organic carbon, as described by Smith et al. Stream sediment contamination is another important pathway for affecting aquatic organisms, as reviewed by Besser et al. Understanding and predicting environmental consequences from mining begins with knowing the mineralogy and mineral reactivity of the ore, the wastes, and of secondary minerals formed later. Jamieson et al. review the importance of mineralogical studies in mine planning and remediation. A number of types of site-specific studies are needed to identify environmental risks related to individual mines. Lapakko reviews the general framework of mine waste characterization studies that are integral to the mine planning process. Hageman et al. present a comparative study of several static tests commonly used to characterize mine waste. The mining and ore processing practices employed at a specific mine site will vary on the basis of the commodities being targeted, the geology of the deposit, the geometry of the deposit, and the mining and ore processing methods used. Thus, these factors, in addition to the waste management practices used, can result in a variety of end-member mine waste features, each of which has its own set of challenges. Open pit mines and underground mines require waste rock to be removed to access ore. Waste rock presents unique problems because the rock is commonly mineralized at sub-economic grades and has not been processed to remove potentially problematic minerals, such as pyrite. Amos et al. examine the salient aspects of the geochemistry of waste rock. Mill tailings – the waste material after ore minerals have been removed – are a volumetrically important solid waste at many mine sites. Their fine grain size and the options for their management make their behavior in the environment distinct from that of waste rock. Lindsay et al. describe some of these differences through three case-study examples. Subaqueous disposal of tailings is another option described by Moncur et al. Cyanide leaching for gold extraction is a common method throughout the world. Johnson describes environmental aspects of cyanidation. Uranium mining presents unique environmental challenges, particularly since in-situ recovery has seen widespread use. Campbell et al. review the environmental geochemistry of uranium mining and current research on bioremediation. Ore concentrates from many types of metal mining undergo a pyrometallurgical technique known as smelting to extract the metal. Slag is the result of smelting, and it may be an environmental liability or a valuable byproduct, as described by Piatak et al. Finally, the open pits that result from surface mining commonly reach below the water table. At the end of mining, these pits may fill to form lakes that become part of the legacy of the mine. Castendyk et al., in two papers, review theoretical aspects of the environmental limnology of pit lakes. They also describe approaches that have been used to model pit lake water balance, wall-rock contributions to pit lake chemistry, pit lake water quality, and limnological processes, such as vertical mixing, through the use of three case studies.

Applied Geochemistry↗

USGS2023

Toxicity of wildland fire retardants to rainbow trout in short exposures

Long-term wildland fire retardants are one important tool used to control and suppress wildfires. During suppression activities, these retardants may enter waterbodies; thus, there is a need to understand their potential effects to aquatic biota. We investigated the effect of three current-use wildland fire retardants to juvenile rainbow trout ( Oncorhynchus mykiss) survival in short exposures more realistic to actual intrusion scenarios. Lethal effect concentrations decreased with time and varied among chemicals (LC95A-R > 259-Fx > MVP-Fx). The lowest effect concentrations observed were 2 to 10 times above the threshold used by federal agencies to assess potential impacts to aquatic organisms following a retardant intrusion. These data can be used by resource managers to balance wildfire control with potential environmental impacts of retardant use.

Environmental Toxicology and Chemistry↗

USGS2015

Critical loads of atmospheric deposition to Adirondack lake watersheds: A guide for policymakers

Acid deposition is sometimes referred to as “acid rain,” although part of the acid load reaches the surface by means other than rainfall. In the eastern U.S., acid deposition consists of several forms of sulfur and nitrogen that largely originate as emissions to the atmosphere from sources such as electricity-generating facilities (coal, oil, and natural gas), diesel- and gasoline-burning vehicles, some agricultural activities, and smokestack industries. Acid deposition is known to cause deleterious effects to sensitive ecosystems of which the Adirondack region of New York State provides several well-known and well-studied examples. This largely forested region includes abundant lakes, streams, and wetlands and possesses several landscape features that result in high ecosystem sensitivity to acid deposition. These features include bedrock that weathers slowly, steep slopes, and thin, naturally acidic soils. An ecosystem is described as sensitive to, or affected by, acid deposition if prolonged exposure to acid deposition has resulted in detrimental ecosystem effects. Soils, streams, and lakes that are less sensitive are better able to buffer acid deposition. A principal reason that acidification is a concern for resource managers is because of the changes induced in native biota and their habitat on land and in water. As the chemistry of soils and surface waters in sensitive landscapes changes in response to prolonged exposure to acid deposition, organisms that cannot tolerate high acidity, such as sugar maple trees and many species of fish and aquatic insects, may be gradually eliminated from the ecosystem. Other biota such as red spruce may experience increased stress and reduced growth rates as a result of acidification, exposing these species to increased susceptibility to disease and other natural stressors and perhaps increased mortality. The ecological effects of acid deposition have been documented by extensive research that began in the U.S. in the 1970s and continues today. This report does not provide a detailed discussion of these ecological effects, but interested readers can refer to four publications that provide good summaries of current scientific knowledge of these effects, including extensive reference to previous research in the Adirondacks (Driscoll et al. 2001, Jenkins et al. 2007, Burns et al. 2011, Sullivan 2015).

New York↗

USGS2018

Contaminants of emerging concern presence and adverse effects in fish: A case study in the Laurentian Great Lakes

The Laurentian Great Lakes are a valuable natural resource that is affected by contaminants of emerging concern (CECs), including sex steroid hormones, personal care products, pharmaceuticals, industrial chemicals, and new generation pesticides. However, little is known about the fate and biological effects of CECs in tributaries to the Great Lakes. In the current study, 16 sites on three rivers in the Great Lakes basin (Fox, Cuyahoga, and Raquette Rivers) were assessed for CEC presence using polar organic chemical integrative samplers (POCIS) and grab water samplers. Biological activity was assessed through a combination of in vitro bioassays (focused on estrogenic activity) and in vivo assays with larval fathead minnows. In addition, resident sunfish, largemouth bass, and white suckers were assessed for changes in biological endpoints associated with CEC exposure. CECs were present in all water samples and POCIS extracts. A total of 111 and 97 chemicals were detected in at least one water sample and POCIS extract, respectively. Known estrogenic chemicals were detected in water samples at all 16 sites and in POCIS extracts at 13 sites. Most sites elicited estrogenic activity in bioassays. Ranking sites and rivers based on water chemistry, POCIS chemistry, or total in vitro estrogenicity produced comparable patterns with the Cuyahoga River ranking as most and the Raquette River as least affected by CECs. Changes in biological responses grouped according to physiological processes, and differed between species but not sex. The Fox and Cuyahoga Rivers often had significantly different patterns in biological response Our study supports the need for multiple lines of evidence and provides a framework to assess CEC presence and effects in fish in the Laurentian Great Lakes basin.

Environmental Pollution↗

USGS2008

Improvements in the use of aquatic herbicides and establishment of future research directions

Peer-reviewed literature over the past 20 years identifies significant changes and improvements in chemical control strategies used to manage nuisance submersed vegetation. The invasive exotic plants hydrilla (Hydrilla verticillata L.f. Royle) and Eurasian watermilfoil (Myriophyllum spicatum L.) continue to spread and remain the plant species of greatest concern for aquatic resource managers at the national scale. Emerging exotic weeds of regional concern such as egeria (Egeria densa Planch.), curlyleaf pondweed (Potamogeton crispus L.), and hygrophila (Hygrophila polysperma (Roxb.) T. Anders), as well as native plants such as variable watermilfoil (Myriophyllum heterophyllum Michx), and cabomba (Cabomba caroliniana Gray) are invasive outside their home ranges. In addition, there is always the threat of new plant introductions such as African elodea (Lagarosiphon major (Ridley) Moss) or narrow-leaf anacharis (Egeria najas Planchon). The registration of the bleaching herbicide fluridone in the mid 1980s for whole-lake and large-scale management stimulated numerous lines of research involving reduction of use rates, plant selectivity, residue monitoring, and impacts on fisheries. In addition to numerous advances, the specificity of fluridone for a single plant enzyme led to the first documented case of herbicide resistance in aquatic plant management. The resistance of hydrilla to fluridone has stimulated a renewed interest by industry and others in the registration of alternative modes of action for aquatic use. These newer chemistries tend to be enzyme-specific compounds with favorable non-target toxicity profiles. Registration efforts have been facilitated by increased cooperation between key federal government agencies that have aquatic weed control and research responsibilities, and regulators within the U.S. Environmental Protection Agency (USEPA). We reviewed past and current research efforts to identify areas in need of further investigation and to establish priorities for future research directions in chemical management of submersed plants. The priorities we identified include: (A) improving methods for evaluating non-target impacts of herbicides with an emphasis on threatened and endangered species, or species of special concern; (B) improving herbicide performance in flowing-water environments, including irrigation canals; (C) screening and developing new herbicides to supplement fluridone for large-scale or whole-lake management approaches; (D) screening and developing new organic algaecides to supplement the use of copper-based compounds; (E) developing risk assessment tools to educate the public on the risks of invasive species and chemical management options; (F) increasing cooperative research with ecologists and fisheries scientists to evaluate the long-term impacts of invasive species introductions and herbicide programs on native plant assemblages, water quality, and fish populations; and (G) improving the integration of chemical control technology with other aquatic plant management disciplines. While circumstances may dictate setting new priorities or dropping current ones, the list we have generated represents our vision of the needs that will require the greatest focus over the next several years.

Conference Paper↗

USGS2000

Composition and depositional environment of concretionary strata of early Cenomanian (early Late Cretaceous) age, Johnson County, Wyoming

Unusual, concretion-bearing mudrocks of early Late Cretaceous age, which were deposited in an early Cenomanian epeiric sea, have been recognized at outcrops in eastern Wyoming and in adjoining areas of Montana, South Dakota, Nebraska, and Colorado. In Johnson County, Wyo., on the western flank of the Powder River Basin, these strata are in the lower part of the Belle Fourche Member of the Frontier Formation. At a core hole in south-central Johnson County, they are informally named Unit 2. These strata are about 34 m (110 ft) thick and consist mainly of medium- to dark-gray, noncalcareous, silty shale and clayey or sandy siltstone; and light-gray to grayish-red bentonite. The shale and siltstone are either bioturbated or interlaminated; the laminae are discontinuous, parallel, and even or wavy. Several ichnogenera of deposit feeders are common in the unit but filter feeders are sparse. The unit also contains marine and continental palynomorphs and, near the top, a few arenaceous foraminifers. No invertebrate macrofossils have been found in these rocks. Unit 2 conformably overlies lower Cenomanian shale in the lowermost Belle Fourche Member, informally named Unit 3, and is conformably overlain by lower and middle Cenomanian shale, siltstone, and sandstone within the member, which are informally named Unit 1. The mineral and chemical composition of the three Cenomanian units is comparable and similar to that of shale and siltstone in the Upper Cretaceous Pierre Shale, except that these units contain more SiO2 and less CaO, carbonate carbon, and manganese. Silica is generally more abundant and CaO is generally less abundant in river water than in seawater. The composition of Unit 2 contrasts significantly with that of the underlying and overlying units. Unit 2 contains no pyrite and dolomite and much less sulfur than Units 1 and 3. Sulfate is generally less abundant in river water than in seawater. Unit 2 also includes sideritic and calcitic concretions, whereas Units 1 and 3 contain neither concretions nor siderite and only sparse calcite. Carbon-sulfur-iron chemistry for the concretions suggests that sulfate availability was the limiting factor in pyrite formation and sulfide incorporation in Unit 2. Isotopic compositions of the carbon and oxygen in siderite and calcite from several concretions are variable and suggest cementation during early diagenesis in a variety of microenvironments. The isotopic composition of these carbonate minerals differs from that of Upper Cretaceous marine limestones. When considered in conjunction with the proportions of sulfur, organic carbon, and iron in Unit 2, major-element and micropaleontological data suggest that the composition of the original pore waters and of overlying waters in the late early Cenomanian sea was brackish to fresh. The mudrocks of Units 3 and 2, and a lower part of Unit 1, accumulated on a shelf at low to moderate rates of sedimentation in association with variable but generally weak current action. In Unit 2 and laterally equivalent rocks of the region, the sideritic and calcitic concretions probably indicate the extent of a body of brackish to fresh and oxygen-deficient water. Rates of precipitation in this region during the mid-Cretaceous could have been unusually high and the precipitation probably was seasonal. The organic matter in Unit 2 is humic-rich and would have been derived from continental environments. If the epeiric sea was brackish to fresh in the region of eastern Wyoming and contiguous areas, meteoric runoff from the adjoining lowlands must have been periodically large and the seaway north of the region probably was constricted. Seasonal changes in salinity might have been accompanied by changes in water temperature and oxygen content. The lower part of the Frontier Formation (Units 3, 2, and 1) in Wyoming records an intermittently and easterly prograding shoreline during late early and early middle Cenomanian time. Laterally equivalent strata in Nebraska

Bulletin↗

USGS1995

Toxicity and bioaccumulation of sediment-associated contaminants using freshwater invertebrates: A review of methods and applications

This paper reviews recent developments in methods for evaluating the toxicity and bioaccumulation of contaminants associated with freshwater sediments and summarizes example case studies demonstrating the application of these methods. Over the past decade, research has emphasized development of more specific testing procedures for conducting 10-d toxicity tests with the amphipod Hyalella azteca and the midge Chironomus tentans. Toxicity endpoints measured in these tests are survival for H. azteca and survival and growth for C. tentans. Guidance has also been developed for conducting 28-d bioaccumulation tests with the oligochaete Lumbriculus variegatus, including determination of bioaccumulation kinetics for different compound classes. These methods have been applied to a variety of sediments to address issues ranging from site assessments to bioavailability of organic and inorganic contaminants using field-collected and laboratory-spiked samples. Survival and growth of controls routinely meet or exceed test acceptability criteria. Results of laboratory bioaccumulation studies with L. variegatus have been confirmed with comparisons to residues (PCBs, PAHs, DDT) present from synoptically collected field populations of oligochaetes. Additional method development is currently underway to develop chronic toxicity tests and to provide additional data-confirming responses observed in laboratory sediment tests with natural benthic populations.

Environmental Toxicology and Chemistry↗

USGS2016

New organic reference materials for hydrogen, carbon, and nitrogen stable isotope-ratio measurements: caffeines, n-alkanes, fatty acid methyl esters, glycines, L-valines, polyethylenes, and oils

An international project developed, quality-tested, and determined isotope−δ values of 19 new organic reference materials (RMs) for hydrogen, carbon, and nitrogen stable isotope-ratio measurements, in addition to analyzing pre-existing RMs NBS 22 (oil), IAEA-CH-7 (polyethylene foil), and IAEA-600 (caffeine). These new RMs enable users to normalize measurements of samples to isotope−δ scales. The RMs span a range of δ 2 H VSMOW-SLAP values from −210.8 to +397.0 mUr or ‰, for δ 13 C VPDB-LSVEC from −40.81 to +0.49 mUr and for δ 15 N Air from −5.21 to +61.53 mUr. Many of the new RMs are amenable to gas and liquid chromatography. The RMs include triads of isotopically contrasting caffeines, C 16 n -alkanes, n -C 20 -fatty acid methyl esters (FAMEs), glycines, and l -valines, together with polyethylene powder and string, one n -C 17 -FAME, a vacuum oil (NBS 22a) to replace NBS 22 oil, and a 2 H-enriched vacuum oil. A total of 11 laboratories from 7 countries used multiple analytical approaches and instrumentation for 2-point isotopic normalization against international primary measurement standards. The use of reference waters in silver tubes allowed direct normalization of δ 2 H values of organic materials against isotopic reference waters following the principle of identical treatment. Bayesian statistical analysis yielded the mean values reported here. New RMs are numbered from USGS61 through USGS78, in addition to NBS 22a. Because of exchangeable hydrogen, amino acid RMs currently are recommended only for carbon- and nitrogen-isotope measurements. Some amino acids contain 13 C and carbon-bound organic 2 H-enrichments at different molecular sites to provide RMs for potential site-specific isotopic analysis in future studies.

Analytical Chemistry↗

USGS2003

Hydric soils in a southeastern Oregon vernal pool

Vernal pools on the High Lava Plain of the northern Great Basin become ponded in most years, but their soils exhibit weak redoximorphic features indicative of hydric conditions. We studied the hydrology, temperature, redox potentials, soil chemistry, and soil morphology of a vernal pool to determine if the soils are hydric, and to evaluate hydric soil field indicators. We collected data for 3 yr from piezometers, Pt electrodes, and thermocouples. Soil and water samples were analyzed for pH, organic C, and extractable Fe and Mn. Soils were ponded from January through April or May, but subsurface saturation was never detected. Soil temperatures 50 cm below the surface rose above 5°C by March. Clayey Bt horizons perched water and limited saturation to the upper 10 cm. Redox potentials at a 5-cm depth were often between 200 and 300 mV, indicating anaerobic conditions, but producing soluble Fe 2+ concentrations <1 mg L −1 Extractable soil Fe contents indicated Fe depletion from pool surface horizons and accumulation at or near the upper Bt1 horizon. Depletions and concentrations did not satisfy the criteria of any current hydric soil indicators. We recommend development of new indicators based on acceptance of fewer, less distinct redox concentrations for recognition of a depleted A horizon, and on presence of a thin zone containing redox concentrations located in the upper part of the near-surface perching horizon.

Soil Science Society of America Journal↗

USGS2010

Accumulation of current-use and organochlorine pesticides in crab embyros from northern California, USA

Invertebrates have long been used as resident sentinels for assessing ecosystem health and productivity. The shore crabs, Hemigrapsus oregonensis and Pachygrapsus crassipes, are abundant in estuaries and beaches throughout northern California, USA and have been used as indicators of habitat conditions in several salt marshes. The overall objectives of the present study were to conduct a lab-based study to test the accumulation of current-use pesticides, validate the analytical method and to analyze field-collected crabs for a suite of 74 current-use and legacy pesticides. A simple laboratory uptake study was designed to determine if embryos could bioconcentrate the herbicide molinate over a 7-d period. At the end of the experiment, embryos were removed from the crabs and analyzed by gas chromatography/mass spectrometry. Although relatively hydrophilic (log K(OW) of 2.9), molinate did accumulate with an estimated bioconcentration factor (log BCF) of approximately 2.5. Following method validation, embryos were collected from two different Northern California salt marshes and analyzed. In field-collected embryos 18 current-use and eight organochlorine pesticides were detected including synthetic pyrethroids and organophosphate insecticides, as well as DDT and its degradates. Lipid-normalized concentrations of the pesticides detected in the field-collected crab embryos ranged from 0.1 to 4 ppm. Pesticide concentrations and profiles in crab embryos were site specific and could be correlated to differences in land-use practices. These preliminary results indicate that embryos are an effective sink for organic contaminants in the environment and have the potential to be good indicators of ecosystem health, especially when contaminant body burden analyses are paired with reproductive impairment assays.

California↗

USGS2007

Ground-Water Quality of the Northern High Plains Aquifer, 1997, 2002-04

An assessment of ground-water quality in the northern High Plains aquifer was completed during 1997 and 2002-04. Ground-water samples were collected at 192 low-capacity, primarily domestic wells in four major hydrogeologic units of the northern High Plains aquifer-Ogallala Formation, Eastern Nebraska, Sand Hills, and Platte River Valley. Each well was sampled once, and water samples were analyzed for physical properties and concentrations of nitrogen and phosphorus compounds, pesticides and pesticide degradates, dissolved solids, major ions, trace elements, dissolved organic carbon (DOC), radon, and volatile organic compounds (VOCs). Tritium and microbiology were analyzed at selected sites. The results of this assessment were used to determine the current water-quality conditions in this subregion of the High Plains aquifer and to relate ground-water quality to natural and human factors affecting water quality. Water-quality analyses indicated that water samples rarely exceeded established U.S. Environmental Protection Agency public drinking-water standards for those constituents sampled; 13 of the constituents measured or analyzed exceeded their respective standards in at least one sample. The constituents that most often failed to meet drinking-water standards were dissolved solids (13 percent of samples exceeded the U.S. Environmental Protection Agency Secondary Drinking-Water Regulation) and arsenic (8 percent of samples exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level). Nitrate, uranium, iron, and manganese concentrations were larger than drinking-water standards in 6 percent of the samples. Ground-water chemistry varied among hydrogeologic units. Wells sampled in the Platte River Valley and Eastern Nebraska units exceeded water-quality standards more often than the Ogallala Formation and Sand Hills units. Thirty-one percent of the samples collected in the Platte River Valley unit had nitrate concentrations greater than the standard, 22 percent exceeded the manganese standard, 19 percent exceeded the sulfate standard, 26 percent exceeded the uranium standard, and 38 percent exceeded the dissolved-solids standard. In addition, 78 percent of samples had at least one detectable pesticide and 22 percent of samples had at least one detectable VOC. In the Eastern Nebraska unit, 30 percent of the samples collected had dissolved-solids concentrations larger than the standard, 23 percent exceeded the iron standard, 13 percent exceeded the manganese standard, 10 percent exceeded the arsenic standard, 7 percent exceeded the sulfate standard, 7 percent exceeded the uranium standard, and 7 percent exceeded the selenium standard. No samples exceeded the nitrate standard. Thirty percent of samples had at least one detectable pesticide compound and 10 percent of samples had at least one detectable VOC. In contrast, the Sand Hills and Ogallala Formation units had fewer detections of anthropogenic compounds and drinking-water exceedances. In the Sand Hills unit, 15 percent of the samples exceeded the arsenic standard, 4 percent exceeded the nitrate standard, 4 percent exceeded the uranium standard, 4 percent exceeded the iron standard, and 4 percent exceeded the dissolved-solids standard. Fifteen percent of samples had at least one pesticide compound detected and 4 percent had at least one VOC detected. In the Ogallala Formation unit, 6 percent of water samples exceeded the arsenic standard, 4 percent exceeded the dissolved-solids standard, 3 percent exceeded the nitrate standard, 2 percent exceeded the manganese standard, 1 percent exceeded the iron standard, 1 percent exceeded the sulfate standard, and 1 percent exceeded the uranium standard. Eight percent of samples collected in the Ogallala Formation unit had at least one pesticide detected and 6 percent had at least one VOC detected. Differences in ground-water chemistry among the hydrogeologic units were attributed to variable depth to water, depth of the well screen below the water table, reduction-oxidation conditions, ground-water residence time, interactions with surface water, composition of aquifer sediments, extent of cropland, extent of irrigated land, and fertilizer application rates.

Scientific Investigations Report↗

USGS2016

Sensitivity of lake sturgeon ( Acipenser fulvescens ) early life stages to 2,3,7,8-tetrachlorodibenzo- P -dioxin and 3,3′,4,4′,5-pentachlorobiphenyl

The aquatic food web of the Great Lakes has been contaminated with polychlorinated biphenyls (PCBs) since the mid-20th century. Threats of PCB exposures to long-lived species of fish, such as lake sturgeon ( Acipenser fulvescens ), have been uncertain because of a lack of information on the relative sensitivity of the species. The objective of the present study was to evaluate the sensitivity of early–life stage lake sturgeon to 3,3′,4,4′,5-pentachlorobiphenyl (PCB-126) or 2,3,7,8-tetrachlorodibenzo- p -dioxin (TCDD) exposure. Mortality, growth, morphological and tissue pathologies, swimming performance, and activity levels were used as assessment endpoints. Pericardial and yolk sac edema, tubular heart, yolk sac hemorrhaging, and small size were the most commonly observed pathologies in both TCDD and PCB-126 exposures, beginning as early as 4 d postfertilization, with many of these pathologies occurring in a dose-dependent manner. Median lethal doses for PCB-126 and TCDD in lake sturgeon were 5.4 ng/g egg (95% confidence interval, 3.9–7.4 ng/g egg) and 0.61 ng/g egg (0.47–0.82 ng/g egg), respectively. The resulting relative potency factor for PCB-126 (0.11) was greater than the World Health Organization estimate for fish (toxic equivalency factor = 0.005), suggesting that current risk assessments may underestimate PCB toxicity toward lake sturgeon. Swimming activity and endurance were reduced in lake sturgeon survivors from the median lethal doses at 60 d postfertilization. Threshold and median toxicity values indicate that lake sturgeon, like other Acipenser species, are more sensitive to PCB and TCDD than the other genus of sturgeon, Scaphirhynchus , found in North America. Indeed, lake sturgeon populations in the Great Lakes and elsewhere are susceptible to PCB/TCDD-induced developmental toxicity in embryos and reductions in swimming performance.

Environmental Toxicology and Chemistry↗

USGS2004

Water-quality characteristics of quaternary unconsolidated-deposit aquifers and lower tertiary aquifers of the Bighorn Basin, Wyoming and Montana, 1999-2001

As part of the Yellowstone River Basin National Water Quality Assessment study, ground-water samples were collected from Quaternary unconsolidated-deposit and lower Tertiary aquifers in the Bighorn Basin of Wyoming and Montana from 1999 to 2001. Samples from 54 wells were analyzed for physical characteristics, major ions, trace elements, nutrients, dissolved organic carbon, radionuclides, pesticide compounds, and volatile organic compounds (VOCs) to evaluate current water-quality conditions in both aquifers. Water-quality samples indicated that waters generally were suitable for most uses, and that natural conditions, rather than the effects of human activities, were more likely to limit uses of the waters. Waters in both types of aquifers generally were highly mineralized, and total dissolved-solids concentrations frequently exceeded the U.S. Environmental Protection Agency (USEPA) Secondary Maximum Contaminant Level (SMCL) of 500 milligrams per liter (mg/L). Because of generally high mineralization, waters from nearly one-half of the samples from Quaternary aquifers and more than one-half of the samples from lower Tertiary aquifers were not classified as fresh (dissolved-solids concentration were not less than 1,000 mg/L). The anions sulfate, fluoride, and chloride were measured in some ground-water samples at concentrations greater than SMCLs. Most waters from the Quaternary aquifers were classified as very hard (hardness greater than 180 mg/L), but hardness varied much more in waters from the lower Tertiary aquifers and ranged from soft (less than 60 mg/L) to very hard (greater than 180 mg/L). Major-ion chemistry varied with dissolved-solids concentrations. In both types of aquifers, the predominant anion changes from bicarbonate to sulfate with increasing dissolved-solids concentrations. Samples from Quaternary aquifers with fresh waters generally were calcium-bicarbonate, calcium-sodium-bicarbonate, and calcium-sodium-sulfate-bicarbonate type waters, whereas samples with larger concentrations generally were calcium-sodium-sulfate, calcium-sulfate, or sodium-sulfate-type waters. In the lower Tertiary aquifers, samples with fresh waters generally were sodium-bicarbonate or sodium-bicarbonate-sulfate type waters, whereas samples with larger concentrations were sodium-sulfate or calcium-sodium-sulfate types. Concentrations of most trace elements in both types of aquifers generally were small and most were less than applicable USEPA standards. The trace elements that most often did not meet USEPA secondary drinking-water standards were iron and manganese. In fact, the SMCL for manganese was the most frequently exceeded standard; 68 percent of the samples from the Quaternary aquifers and 31 percent of the samples from the lower Tertiary aquifers exceeded the manganese standard. Geochemical conditions may control manganese in both aquifers as concentrations in Quaternary aquifers were negatively correlated with dissolved oxygen concentrations and concentrations in lower Tertiary aquifers decreased with increasing pH. Elevated nitrate concentrations, in addition to detection of pesticides and VOCs in both aquifers, indicated some effects of human activities on ground-water quality. Nitrate concentrations in 36 percent of the wells in Quaternary aquifers and 28 percent of the wells in lower Tertiary aquifers were greater than 1 mg/L, which may indicate ground-water contamination from human sources. The USEPA drinking-water Maximum Contaminant Level (MCL) for nitrate, 10 mg/L, was exceeded in 8 percent of samples collected from Quaternary aquifers and 3 percent from lower Tertiary aquifers. Nitrate concentrations in Quaternary aquifers were positively correlated with the percentage of cropland and other agricultural land (non-cropland), and negatively correlated with rangeland and riparian land. In the lower Tertiary aquifers, nitrate concentrations only were correlated with the percentage of cropland. Concentratio

Scientific Investigations Report↗

USGS2010

Status and understanding of groundwater quality in the northern San Joaquin Basin, 2005: California GAMA Priority Basin Project

Groundwater quality in the 2,079 square mile Northern San Joaquin Basin (Northern San Joaquin) study unit was investigated from December 2004 through February 2005 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001 that was passed by the State of California and is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The Northern San Joaquin study unit was the third study unit to be designed and sampled as part of the Priority Basin Project. Results of the study provide a spatially unbiased assessment of the quality of raw (untreated) groundwater, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 61 wells in parts of Alameda, Amador, Calaveras, Contra Costa, San Joaquin, and Stanislaus Counties; 51 of the wells were selected using a spatially distributed, randomized grid-based approach to provide statistical representation of the study area (grid wells), and 10 of the wells were sampled to increase spatial density and provide additional information for the evaluation of water chemistry in the study unit (understanding/flowpath wells). The primary aquifer systems (hereinafter, primary aquifers) assessed in this study are defined by the depth intervals of the wells in the California Department of Public Health database for each study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to contamination from the surface. Two types of assessments were made: (1) status, assessment of the current quality of the groundwater resource; and (2) understanding, identification of the natural and human factors affecting groundwater quality. Relative-concentrations (sample concentrations divided by benchmark concentrations) were used for evaluating groundwater quality for those constituents that have Federal or California regulatory or non-regulatory benchmarks for drinking-water quality. Benchmarks used in this study were either health-based (regulatory and non-regulatory) or aesthetic based (non-regulatory). For inorganic constituents, relative-concentrations were classified as high (equal to or greater than 1.0), indicating relative-concentrations greater than benchmarks; moderate (equal to or greater than 0.5, and less than 1.0); or, low (less than 0.5). For organic and special- interest constituents [1,2,3-trichloropropane (1,2,3-TCP), N-nitrosodimethylamine (NDMA), and perchlorate], relative- concentrations were classified as high (equal to or greater than 1.0); moderate (equal to or greater than 0.1 and less than 1.0); or, low (less than 0.1). Aquifer-scale proportion was used as the primary metric in the status assessment for groundwater quality. High aquifer- scale proportion is defined as the percentage of the primary aquifer with relative-concentrations greater than 1.0; moderate and low aquifer-scale proportions are defined as the percentage of the primary aquifer with moderate and low relative- concentrations, respectively. The methods used to calculate aquifer-scale proportions are based on an equal-area grid; thus, the proportions are areal rather than volumetric. Two statistical approaches - grid-based, which used one value per grid cell, and spatially weighted, which used the full dataset - were used to calculate aquifer-scale proportions for individual constituents and classes of constituents. The spatially weighted estimates of high aquifer-scale proportions were within the 90-percent confidence intervals of the grid-based estimates in all cases. The understanding assessment used statistical correlations between constituent relative-concentrations and

California↗

USGS2016

Alternative approaches to vertebrate ecotoxicity tests in the 21st century: A review of developments over the last 2 decades and current status

The need for alternative approaches to the use of vertebrate animals for hazard assessment of chemicals and pollutants has become of increasing importance. It is now the first consideration when initiating a vertebrate ecotoxicity test, to ensure that unnecessary use of vertebrate organisms is minimized wherever possible. For some regulatory purposes, the use of vertebrate organisms for environmental risk assessments has been banned; in other situations, the number of organisms tested has been dramatically reduced or the severity of the procedure refined. However, there is still a long way to go to achieve a complete replacement of vertebrate organisms to generate environmental hazard data. The development of animal alternatives is based not just on ethical considerations but also on reducing the cost of performing vertebrate ecotoxicity tests and in some cases on providing better information aimed at improving environmental risk assessments. The present Focus article provides an overview of the considerable advances that have been made toward alternative approaches for ecotoxicity assessments over the last few decades.

Environmental Toxicology and Chemistry↗

USGS2011

An evaluation of the relative quality of dike pools for benthic macroinvertebrates in the Lower Missouri River, USA

A habitat-based aquatic macroinvertebrate study was initiated in the Lower Missouri River to evaluate relative quality and biological condition of dike pool habitats. Water-quality and sediment-quality parameters and macroinvertebrate assemblage structure were measured from depositional substrates at 18 sites. Sediment porewater was analysed for ammonia, sulphide, pH and oxidation-reduction potential. Whole sediments were analysed for particle-size distribution, organic carbon and contaminants. Field water-quality parameters were measured at subsurface and at the sediment-water interface. Pool area adjacent and downstream from each dike was estimated from aerial photography. Macroinvertebrate biotic condition scores were determined by integrating the following indicator response metrics: % of Ephemeroptera (mayflies), % of Oligochaeta worms, Shannon Diversity Index and total taxa richness. Regression models were developed for predicting macroinvertebrate scores based on individual water-quality and sediment-quality variables and a water/sediment-quality score that integrated all variables. Macroinvertebrate scores generated significant determination coefficients with dike pool area ( R 2 =0.56), oxidation–reduction potential ( R 2 =0.81) and water/sediment-quality score ( R 2 =0.71). Dissolved oxygen saturation, oxidation-reduction potential and total ammonia in sediment porewater were most important in explaining variation in macroinvertebrate scores. The best two-variable regression models included dike pool size + the water/sediment-quality score ( R 2 =0.84) and dike pool size + oxidation-reduction potential ( R 2 =0.93). Results indicate that dike pool size and chemistry of sediments and overlying water can be used to evaluate dike pool quality and identify environmental conditions necessary for optimizing diversity and productivity of important aquatic macroinvertebrates. A combination of these variables could be utilized for measuring the success of habitat enhancement activities currently being implemented in this system.

Iowa;Nebraska;Missouri;Kansas↗

USGS2006

Metallogeny of the Great Basin: Crustal evolution, fluid flow, and ore deposits

The Great Basin physiographic province in the Western United States contains a diverse assortment of world-class ore deposits. It currently (2006) is the world’s second leading producer of gold, contains large silver and base metal (Cu, Zn, Pb, Mo, W) deposits, a variety of other important metallic (Fe, Ni, Be, REE’s, Hg, PGE) and industrial mineral (diatomite, barite, perlite, kaolinite, gallium) resources, as well as petroleum and geothermal energy resources. Ore deposits are most numerous and largest in size in linear mineral belts with complex geology. U.S. Geological Survey (USGS) scientists are in the final year of a research project initiated in the fall of 2001 to increase understanding of relations between crustal evolution, fluid flow, and ore deposits in the Great Basin. Because of its substantial past and current mineral production, this region has been the focus of numerous investigations over the past century and is the site of ongoing research by industry, academia, and state agencies. A variety of geoinformatic tools was used to organize, reinterpret, and display, in space and time, the large amounts of geologic, geophysical, geochemical, and hydrologic information deemed pertinent to this problem. This information, in combination with concentrated research on (1) critical aspects of the geologic history, (2) an area in northern Nevada that encompasses the major mineral belts, and (3) important mining districts and deposits, is producing new insights about the interplay between key tectonic events, hydrothermal fluid flow, and ore genesis in mineral belts. The results suggest that the Archean to Holocene history of the Great Basin was punctuated by several tectonic events that caused fluids of different origins (sea water, basinal brine, meteoric water, metamorphic water, magmatic water) to move through the crust. Basement faults reactivated during these events localized deformation, sedimentation, magmatism, and hydrothermal fluid flow in overlying rocks to form mineral belts that contain ore deposits of different types and ages that are locally superimposed (demonstrating inheritance). Fluid flow in these systems also was influenced by the distribution of permeable lithologies and paleotopographic highs and lows. Hydrothermal fluids evolved from their initial chemistries towards compositions that reflect the ƒ O 2 and ƒ S 2 buffering capacity of, and the ligands and metals present in, the rocks (±older mineralization) through which they moved. In northern Nevada, where gold deposits are relatively common, carbonaceous, pyritic strata buffered fluids of diverse origins to H 2 S-rich compositions so they could transport gold repeatedly over Paleozoic-Cenozoic time (convergent evolution). Ore formed where metal-laden fluids encountered effective physicochemical traps. Maps of Neogene basin fill and erosion surfaces identify areas where preexisting ore deposits have been progressively exposed or concealed. Comparisons with analogous terrains and deposit types in other parts of the world provide global context. The initial findings and some of the databases, geologic maps, sections, reconstructions, hydrogeologic models, topical syntheses, regional overviews, short courses, field guides, and deposit comparisons produced by project staff and associated managers, contractors, and collaborators have been presented in numerous abstracts, symposia, USGS publications, and professional journals over the last 5 years (see the extensive bibliography). Notable among these was the 2005 Geological Society of Nevada symposium in Reno, Nevada, and the 2005 Geological Society of America annual meeting in Salt Lake City, Utah, where project results were presented to audiences from around the nation and world. The final results of the project will be submitted for publication in 2007 to appropriate USGS and professional journals. A special issue of GEOSPHERE, scheduled for publication in 2007, will be devoted to the results of this project and related work. This special issue will reach an international audience and be available worldwide on the internet. Much of the research for this project has concentrated on areas that will receive the focused attention of the mining industry in the future. As such, the data and interpretations generated by this project have direct use for land-use managers in Federal, State, and local agencies. Improved hydrogeologic models developed by this project will considerably enhance ongoing and future water resource investigations in the region. The increased understanding of when, where, and how hydrothermal systems produce significant economic deposits has direct uses for mineral exploration and for future USGS mineral resource assessments in the Great Basin and other parts of the world.

Great Basin↗