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Distribution and sources of nitrate, and presence of fluoride and pesticides, in parts of the Pasco Basin, Washington, 1986-88

Ground water was sampled in a 900-square-mile agricultural area in the Pasco Basin, which includes parts of eastern Benton County and western Franklin County, Washington, to determine distributions of nitrate and fluoride. Additional data were obtained to determine if fertilizers, irrigation water, septic systems, and naturally occurring nitrate are sources of nitrate in ground water. Limited sampling also was done to determine if pesticides were present in the ground water. Nitrate concentrations in ground water ranged from less than 0.1 to 100 milligrams per liter as nitrogen, and median concentrations of nitrate nitrogen in ground water were 3.2 and 6.7 milligrams per liter for Benton and Franklin Counties, respectively. In Franklin County, where a large percentage of the land is used for irrigated agriculture, nitrate nitrogen concentrations in water from 31 percent of sampled wells were equal to or greater than the maximum contaminant level for drinking water of 10 milligrams per liter. In Benton County, nitrate concentrations in water from about 10 percent of the sampled wells exceeded the maximum contaminant level. Nitrate concentrations in ground water at some locations in Franklin County have increased by as much as two orders of magnitude since the early 1950's. Historical data generally were not available to evaluate changes of nitrate concentrations in ground water in Benton County, except for the area around the town of Finley. A comparison of data collected during this study with data collected during 1976-77 indicate that nitrate concentrations in ground water of the Finley area probably have not changed over the intervening period. Applied nitrogen fertilizers are a major source of nitrate in ground water at many locations in the study area. Surface water used for irrigation does not contain sufficient nitrate to cause elevated concentrations in ground water. Instead, canal seepage, which makes up about 50 percent of the ground-water recharge in the study area, tends to dilute the nitrate present in ground water. Septic systems in the Finley area of Benton County are a source of nitrate in ground water, but analyses of data and results of a numerical model analysis of nitrate concentrations in the unconfmed ground-water system indicate that they are not the primary source of nitrate in ground water in this area. Naturally occurring nitrate may be a source of nitrate in ground water underlying Badger Coulee in Benton County. Average masses of natural nitrate per unit volume of sediment in two boreholes in Badger Coulee were equivalent to 2,590 and 964 pounds of nitrogen, respectively, in a block of sediments 50 feet thick underlying an acre of land. At most other locations in the study area, the amount of natural nitrate in ground water is probably small compared with nitrate from anthropogenic sources. Fluoride concentrations in ground water in the study area ranged from less than 0.1 to 4.7 milligrams per liter; the median concentration was 0.5 milligram per liter. The concentration of fluoride in water from only two of 143 wells equalled or exceeded 2.0 milligrams per liter, which is the secondary maximum contaminant level for drinking water. Both are deep wells open to the Saddle Mountains Basalt in Franklin County. Large concentrations of fluoride in deep ground waters of the Pasco Basin are apparently the result of natural conditions in the deeper basalt aquifers. One or more pesticide compounds were detected in 10 of 29 ground-water samples, which were analyzed for selected chlorophenoxy acid herbicides, triazine herbicides, carbamate insecticides, organophosphorus insecticides, and a few other types of pesticides. The sampling locations did not represent a random distribution, but instead, most were wells open to unconfined, shallow ground water in irrigated areas. The pesticides found include the herbicides atrazine, dicamba, metribuzin, picloram, and 2,4,5-T. Also present were aldicarb sulfone and aldicarb sulfoxide, which are degradation products of the insecticide aldicarb. Except for metribuzin, pesticide concentrations were at or near the analytical reporting limits. In all instances, the concentrations of pesticides detected were below the health advisory levels that are issued by the U.S. Environmental Protection Agency

Washington

Mercury concentrations in water and mercury and selenium concentrations in fish from Brownlee Reservoir and selected sites in the Boise and Snake Rivers, Idaho and Oregon, 2013-17

Mercury (Hg) analyses were conducted on samples of water and sport fish collected from selected sampling sites in the Boise and Snake Rivers and Brownlee Reservoir, in Idaho and Oregon, to meet National Pollution Discharge and Elimination System permit requirements for the City of Boise, Idaho, from 2013 to 2017. City of Boise personnel collected water samples from six sites in October and November of 2013, 2015 and 2017, and sampled one site in 2014 and 2016. Total Hg concentrations in unfiltered water samples ranged from 0.41 to 8.78 nanograms per liter (ng/L), with the highest value (8.78 ng/L) observed in Brownlee Reservoir in 2013. All samples were less than the U.S. Environmental Protection Agency aquatic life criterion of 12 ng/L. Individual fillets of mountain whitefish ( Prosopium williamsoni ), rainbow trout ( Oncorhynchus mykiss ), smallmouth bass ( Micropterus dolomieu ), and channel catfish ( Ictalurus punctatus ) were collected and analyzed for Hg. The tissue Hg concentrations were compared with regulatory or advisory values for wet-weight methylmercury in fish tissue. In this report, methylmercury concentrations in fish tissue are considered similar to total Hg in fish muscle tissue and are simply referred to as Hg. The 2013 average Hg concentration for smallmouth bass (0.32 mg/kg) collected at Brownlee Reservoir and for channel catfish (0.33 mg/kg) collected at the Boise River mouth, exceeded the Idaho water quality criterion (>0.3 mg/kg). The 2017 Hg concentrations in smallmouth bass from Brownlee Reservoir (geometric mean of 0.22 mg/kg) was at the Idaho Fish Consumption Advisory Program action level. Selenium (Se) interacts with Hg to reduce the health risks of Hg, such that tissues with Se-to-Hg molar ratios greater than 1 are considered to present less potential health risks for a given Hg concentration than are tissues with lower Se-to-Hg ratios. One composite fish tissue sample per site was analyzed for Se. Selenium-to-Hg molar ratios in the fish tissue samples ranged from 0.99 to 24.7.

Idaho, Oregon

Notes on sedimentation activities calendar year 1977

The need for disseminating current information on activities in the field of sedimentation was proposed by the Chairman of the Federal Interagency River Basin Committee's Subcommittee on Sedimentation shortly after the subcommittee was formed in May 1946. At the fifth meeting of the subcommittee on September 17, 1946, the members approved this proposal and agreed to the issuance of a quarterly report as one means of effecting better coordination of the work of various Federal agencies in the field of sedimentation.

Report

Guidelines for determining flood flow frequency: Bulletin #17B of the Hydrology Subcommittee

In December 1967, Bulletin No. 15, "A Uniform Technique for Determining Flood Flow Frequencies," was issued by the Hydrology Committee of the Water Resources Council. The report recommended use of the Pearson Type III distribution with log transformation of the data (log-Pearson Type III distribution) as a base method for flood flow frequency studies. As pointed out in that report, further studies were needed covering various aspects of flow frequency determinations. In March 1976, Bulletin 17, "Guidelines for Determining Flood Flow Frequency" was issued by the Water Resources Council. The guide was an extension and update of Bulletin No. 15. It provided a more complete guide for flood flow frequency analysis incorporating currently accepted technical methods with sufficient detail to promote uniform application. It was limited to defining flood potentials in terms of peak discharge and exceedance probability at locations where a systematic record of peak flood flows is available. The recommended set of procedures was selected from those used or described in the literature prior to 1976, based on studies conducted for this purpose at the Center for Research in Water Resources of the University of Texas at Austin (summarized in Appendix 14) and on studies by the Work Group on Flood Flow Frequency. The "Guidelines" were revised and reissued in June 1977 as Bulletin 17A. Bulletin 17B is the latest effort to improve and expand upon the earlier publications. Bulletin 17B provides revised procedures for weighting a station skew value with the results from a generalized skew study, detecting and treating outliers, making two station comparisons, and computing confidence limits about a frequency curve. The Work Group that prepared this revision did not address the suitability of the original distribution or the generalized skew map. Major problems are encountered when developing guides for flood flow frequency determinations. There is no procedure or set of procedures that can be adopted which, when rigidly applied to the available data, will accurately define the flood potential of any given watershed. Statistical analysis alone will not resolve all flood frequency problems. As discussed in subsequent sections of this guide, elements of risk and uncertainty are inherent in any flood frequency analysis. User decisions must be based on properly applied procedures and proper interpretation of results considering risk and uncertainty. Therefore, the judgment of a professional experienced in hydrologic analysis will enhance the usefulness of a flood frequency analysis and promote appropriate application. It is possible to standarize many elements of flood frequency analysis. This guide describes each major element of the process of defining the flood potential at a specific location in terms of peak discharge and exceedance probability. Use is confined to stations where available records are adequate to warrant statistical analysis of the data. Special situations may require other approaches. In those cases where the procedures of this guide are not followed, deviations must be supported by appropriate study and accompanied by a comparison of results using the recommended procedures. As a further means of achieving consistency and improving results, the Work Group recommends that studies be coordinated when more than one analyst is working currently on data for the same location. This recommendation holds particularly when defining exceedance probabilities for rare events, where this guide allows more latitude. Flood records are limited. As more years of record become available at each location, the determination of flood potential may change. Thus, an estimate may be outdated a few years after it is made. Additional flood data alone may be sufficient reason for a fresh assessment of the flood potential. When making a new assessment, the analyst should incorporate in his study a review of earlier estimates. Where differences appear, they should be acknowledged and explained.

Bulletin

The 3D Elevation Program: summary of program direction

The 3D Elevation Program (3DEP) initiative responds to a growing need for high-quality topographic data and a wide range of other three-dimensional representations of the Nation's natural and constructed features. The National Enhanced Elevation Assessment (NEEA), which was completed in 2011, clearly documented this need within government and industry sectors. The results of the NEEA indicated that enhanced elevation data have the potential to generate $13 billion in new benefits annually. The benefits apply to food risk management, agriculture, water supply, homeland security, renewable energy, aviation safety, and other areas. The 3DEP initiative was recommended by the National Digital Elevation Program and its 12 Federal member agencies and was endorsed by the National States Geographic Information Council (NSGIC) and the National Geospatial Advisory Committee (NGAC).

Fact Sheet

Presentation Showing Results of a Hydrogeochemical Investigation of the Standard Mine Vicinity, Upper Elk Creek Basin, Colorado

PREFACE This Open-File Report consists of a presentation given in Crested Butte, Colorado on December 13, 2007 to the Standard Mine Advisory Group. The presentation was paired with another presentation given by the Colorado Division of Reclamation, Mining, and Safety on the physical features and geology of the Standard Mine. The presentation in this Open-File Report summarizes the results and conclusions of a hydrogeochemical investigation of the Standard Mine performed by the U.S. Geological Survey (Manning and others, in press). The purpose of the investigation was to aid the U.S. Environmental Protection Agency in evaluating remediation options for the Standard Mine site. Additional details and supporting data related to the information in this presentation can be found in Manning and others (in press).

Open-File Report

Monitoring and modeling to predict Escherichia coli at Presque Isle Beach 2, City of Erie, Erie County, Pennsylvania

The Lake Erie shoreline in Pennsylvania spans nearly 40 miles and is a valuable recreational resource for Erie County. Nearly 7 miles of the Lake Erie shoreline lies within Presque Isle State Park in Erie, Pa. Concentrations of Escherichia coli (E. coli) bacteria at permitted Presque Isle beaches occasionally exceed the single-sample bathing-water standard, resulting in unsafe swimming conditions and closure of the beaches. E. coli concentrations and other water-quality and environmental data collected at Presque Isle Beach 2 during the 2004 and 2005 recreational seasons were used to develop models using tobit regression analyses to predict E. coli concentrations. All variables statistically related to E. coli concentrations were included in the initial regression analyses, and after several iterations, only those explanatory variables that made the models significantly better at predicting E. coli concentrations were included in the final models. Regression models were developed using data from 2004, 2005, and the combined 2-year dataset. Variables in the 2004 model and the combined 2004-2005 model were log10 turbidity, rain weight, wave height (calculated), and wind direction. Variables in the 2005 model were log10 turbidity and wind direction. Explanatory variables not included in the final models were water temperature, streamflow, wind speed, and current speed; model results indicated these variables did not meet significance criteria at the 95-percent confidence level (probabilities were greater than 0.05). The predicted E. coli concentrations produced by the models were used to develop probabilities that concentrations would exceed the single-sample bathing-water standard for E. coli of 235 colonies per 100 milliliters. Analysis of the exceedence probabilities helped determine a threshold probability for each model, chosen such that the correct number of exceedences and nonexceedences was maximized and the number of false positives and false negatives was minimized. Future samples with computed exceedence probabilities higher than the selected threshold probability, as determined by the model, will likely exceed the E. coli standard and a beach advisory or closing may need to be issued; computed exceedence probabilities lower than the threshold probability will likely indicate the standard will not be exceeded. Additional data collected each year can be used to test and possibly improve the model. This study will aid beach managers in more rapidly determining when waters are not safe for recreational use and, subsequently, when to issue beach advisories or closings.

Pennsylvania

The U.S. Geological Survey Bird Banding Laboratory: an integrated scientific program supporting research and conservation of North American birds

The U.S. Geological Survey (USGS) Bird Banding Laboratory (BBL) was established in 1920 after ratification of the Migratory Bird Treaty Act with the United Kingdom in 1918. During World War II, the BBL was moved from Washington, D.C., to what is now the USGS Patuxent Wildlife Research Center (PWRC). The BBL issues permits and bands to permittees to band birds, records bird band recoveries or encounters primarily through telephone and Internet reporting, and manages more than 72 million banding records and more than 4.5 million records of encounters using state-of-the-art technologies. Moreover, the BBL also issues bands and manages banding and encounter data for the Canadian Bird Banding Office (BBO). Each year approximately 1 million bands are shipped from the BBL to banders in the United States and Canada, and nearly 100,000 encounter reports are entered into the BBL systems. Banding data are essential for regulatory programs, especially migratory waterfowl harvest regulations. The USGS BBL works closely with the U.S. Fish and Wildlife Service (USFWS) to develop regulations for the capture, handling, banding, and marking of birds. These regulations are published in the Code of Federal Regulations (CFR). In 2006, the BBL and the USFWS Division of Migratory Bird Management (DMBM) began a comprehensive revision of the banding regulations. The bird banding community has three major constituencies: Federal and State agency personnel involved in the management and conservation of bird populations that include the Flyway Councils, ornithological research scientists, and avocational banders. With increased demand for banding activities and relatively constant funding, a Federal Advisory Committee (Committee) was chartered and reviewed the BBL program in 2005. The final report of the Committee included six major goals and 58 specific recommendations, 47 of which have been addressed by the BBL. Specifically, the Committee recommended the BBL continue to support science, conservation, and management of birds through the use of banding and banding data and that the BBL be managed by the USGS and located at the USGS Patuxent Wildlife Research Center (PWRC) in Laurel, Maryland. Recommendations that have not been implemented include those already addressed by other organizations, as well as lower priority, such as developing a BBL business plan. The comprehensive review and recommendations of the Committee, the response of the BBL to address the Committee’s recommendations, and other improvements to its operations have positioned the BBL to provide a high level of service to the banding community. As new technologies are developed and incorporated into BBL operations, further efficiencies are expected to enable the BBL to continue to meet emerging scientific needs.

Open-File Report

Gas shale/oil shale

The production of natural gas from shales continues to increase in North America, and shale gas exploration is on the rise in other parts of the world since the previous report by this committee was published by American Association of Petroleum Geologists, Energy Minerals Division (2009). For the United States, the volume of proved reserves of natural gas increased 11% from 2008 to 2009, the increase driven largely by shale gas development (Energy Information Administration 2010c). Furthermore, shales have increasingly become targets of exploration for oil and condensate as well as gas, which has served to greatly expand their significance as ‘‘unconventional’’ petroleum reservoirs. This report provides information about specific shales across North America and Europe from which gas (biogenic or thermogenic), oil, or natural gas liquids are produced or is actively being explored. The intent is to reflect the recently expanded mission of the Energy Minerals Division (EMD) Gas Shales Committee to serve as a single point of access to technical information on shales regardless of the type of hydrocarbon produced from them. The contents of this report were drawn largely from contributions by numerous members of the EMD Gas Shales Advisory Committee, with much of the data being available from public websites such as state or provincial geological surveys or other public institutions. Shales from which gas or oil is being produced in the United States are listed in alphabetical order by shale name. Information for Canada is presented by province, whereas for Europe, it is presented by country.

Natural Resources Research

A science plan for a comprehensive assessment of water supply in the region underlain by fractured rock in Maryland

The fractured rock region of Maryland, which includes land areas north and west of the Interstate 95 corridor, is the source of water supply for approximately 4.4 million Marylanders, or approximately 76 percent of the State's population. Whereas hundreds of thousands of residents rely on wells (both domestic and community), millions rely on surface-water sources. In this region, land use, geology, topography, water withdrawals, impoundments, and other factors affect water-flow characteristics. The unconfined groundwater systems are closely interconnected with rivers and streams, and are affected by seasonal and climatic variations. During droughts, groundwater levels drop, thereby decreasing well yields, and in some cases, wells have gone dry. Low ground-water levels contribute to reduced streamflows, which in turn, can lead to reduced habitat for aquatic life. Increased demand, over-allocation, population growth, and climate change can affect the future sustainability of water supplies in the region of Maryland underlain by fractured rock. In response to recommendations of the 2008 Advisory Committee on the Management and Protection of the State's Water Resources report, the Maryland Department of the Environment's Water Supply Program, the Maryland Geological Survey, the Maryland Department of Natural Resources, Monitoring and Non-Tidal Assessment (MANTA) Division, and the U.S. Geological Survey have developed a science plan for a comprehensive assessment that will provide new scientific information, new data analysis, and new tools for the State to better manage water resources in the fractured rock region of Maryland. The science plan lays out five goals for the comprehensive assessment: (1) develop tools for the improved management and investigation of groundwater and surface-water resources; (2) characterize factors affecting reliable yields of individual groundwater and surface-water supplies; (3) investigate impacts on nearby water withdrawal users caused by groundwater and surface-water withdrawals; (4) assess the role of streamflow and water withdrawals on the ecological integrity of streams; and (5) improve understanding of the distribution of water-quality conditions in fractured rock aquifers. To accomplish these goals, accurate data collection, review, and analysis are needed, including the study of "Research Watersheds" that can provide detailed information about the potential effects that climate change and water withdrawals may have on groundwater, streamflow, and aquatic life. The assessment planning started in 2009 and is being conducted with close interagency coordination. A Fractured Rock Aquifer Information System is currently (2012) undergoing initial development. Other major tasks that will be performed include the development of work plans for each science goal, the estimation of daily streamflow at ungaged streams, and the design and implementation of Research Watersheds. Finally, scenarios will be modeled to evaluate current water allocation permitting methodologies, investigate effects on nearby water withdrawal users caused by groundwater and surface-water withdrawals, and assess the potential impacts of climate change on water resources. Desktop and Web-based tools will be developed in order to meet the diverse research needs of the assessment. These tools, including the Fractured Rock Aquifer Information System will be continuously improved during the assessment to store relevant groundwater and surface-water data in spatially referenced databases, estimate streamflows, locate higher-yielding wells, estimate the impacts of withdrawals on nearby users, and assess the cumulative impacts of withdrawals on the aquatic resource. Tools will be developed to serve the needs of many audiences, including water resource managers, water suppliers, planners, policymakers, and other scientific investigators.

Maryl

Mercury and methylmercury in reservoirs in Indiana

Mercury (Hg) is an element that occurs naturally, but evidence suggests that human activities have resulted in increased amounts being released to the atmosphere and land surface. When Hg is converted to methylmercury (MeHg) in aquatic ecosystems, MeHg accumulates and increases in the food web so that some fish contain levels which pose a health risk to humans and wildlife that consume these fish. Reservoirs unlike natural lakes, are a part of river systems that are managed for flood control. Data compiled and interpreted for six flood-control reservoirs in Indiana showed a relation between Hg transport, MeHg formation in water, and MeHg in fish that was influenced by physical, chemical, and biological differences among the reservoirs. Existing information precludes a uniform comparison of Hg and MeHg in all reservoirs in the State, but factors and conditions were identified that can indicate where and when Hg and MeHg levels in reservoirs could be highest. As part of a statewide monitoring network for Hg and MeHg in Indiana streams, 66 water samples were collected from four reservoir tailwater sites (downstream near the dams) on a quarterly schedule for 5 years. The reservoirs were Brookville Lake, Cagles Mill Lake, J. Edward Roush Lake, and Mississinewa Lake. Particulate-bound Hg concentrations were significantly lower in tailwater samples than in samples from free-flowing streams in the statewide network. (Free-flowing streams were not affected by dams and were not upstream from these reservoirs.) These data indicated the reduced flow velocity of water upstream from dams was allowing particulate-bound Hg to settle out of the water in the reservoir pools. The concentration ratios of MeHg to Hg were significantly higher in the tailwater samples than in samples from free-flowing streams, and the MeHg to Hg ratios were significantly higher in summer than in other seasons. To evaluate the conditions related to MeHg formation, pools of three reservoirs (Brookville Lake, Monroe Lake, and Patoka Lake) were investigated during summer hydrologic conditions. Water temperature and dissolved oxygen were measured from the water surface to the lake bottom at 10 to 17 transects across each reservoir to identify three thermal strata, defined by water temperature, dissolved oxygen concentration, and depth. Depth-specific water samples were collected from these thermal strata throughout each reservoir, from the headwaters to the dam and from the tailwater. Mercury concentrations higher than 0.04 nanogram per liter (ng/L) were detected in all 53 samples, and MeHg concentrations higher than 0.04 ng/L were detected in 53 percent of the samples. The investigation found a zone of water below 8 or 9 meters, with temperatures less than 18 degrees Celsius and dissolved oxygen less than 3.5 milligrams per liter, extending through nearly half the reservoir area in Monroe Lake and Patoka Lake. This zone had abundant dissolved MeHg and concentration ratios of dissolved MeHg to Hg that ranged from 25 to 82 percent. This zone also had water with pH less than 7 and decreased dissolved sulfate, conditions indicating sulfate reduction by microorganisms that promoted a high potential for the conversion of Hg to MeHg. Reservoir outflow came from this zone at Monroe Lake and contributed to a tailwater concentration ratio for dissolved MeHg to Hg of 56 percent. Reservoir outflow at Patoka Lake was not from this zone, and dissolved MeHg was not detected in the tailwater. In contrast, samples from the summer pool at Brookville Lake had no MeHg detections even though Hg was detected, probably because the water pH higher than 7 inhibited sulfate reduction and did not promote the conversion of Hg to MeHg. Mercury and MeHg concentrations and the concentration ratios of MeHg to Hg in water varied among the six reservoirs in Indiana, and the differences were related to a combination of factors that could apply to other reservoirs. In areas with moderate to high rates of atmospheric Hg wet and dry deposition, Hg runoff and transport to streams and reservoirs was potentially highest for reservoirs with heavily forested watersheds in steep terrains of near-surface bedrock. Methylmercury concentrations and concentration ratios of MeHg to Hg were highest for reservoirs with the longest summer pools and highest inflow-to-outflow retention times, where water-chemistry conditions favoring sulfate reduction promoted conversion of Hg to MeHg. Methylmercury (reported as Hg) in fish-tissue samples collected for the State fish consumption advisory program was used to describe MeHg food-web accumulation and magnification in the reservoirs. The highest percentages of fish-tissue samples with Hg concentrations that exceeded the criterion of 0.30 milligram per kilogram for protection of human health were from Monroe Lake (38 percent) and Patoka Lake (33 percent). A review of the number and size of fish species caught from these two reservoirs resulted in two implications for fish consumption by humans. First, the highest numbers of fish harvested for potential human consumption were species more likely to have MeHg concentrations lower than the human-health criterion (crappie, bluegill, and catfish). Second, although largemouth bass were likely to have MeHg concentrations higher than the human-health criterion, they were caught and released more often than they were harvested. However, the average size largemouth bass (in both reservoirs) and above-average size walleye (in Monroe Lake) that were harvested for potential human consumption were likely to have MeHg concentrations higher than the human-health criterion.

Indiana

Contaminants in fish and shellfish in the Stillaguamish River and Port Susan marine areas, Washington

The greater Port Susan area of Central Puget Sound, Washington, is home to some of the Stillaguamish Tribe’s fishing, hunting, and gathering areas since time immemorial. It is also a popular sport and commercial fishing area for the public. Large shellfish beds lie in the Port Susan and Stillaguamish estuary and several Pacific salmon species return to the Stillaguamish River and Tulalip fishery every year. Clams and salmon are a local and consumable resource for Tribal members and the public. This review largely confirms existing recommendations from the Washington State Department of Health regarding clam and salmon human consumption advisories.

Washington

Ground-water quality in the Red River of the North Basin, Minnesota and North Dakota, 1991-95

Surveys of water quality in surficial, buried glacial, and Cretaceous aquifers in the Red River of the North Basin during 1991-95 showed that some major-ion, nutrient, pesticide, and radioactive-element concentrations differed by physiographic area and differed among these aquifer types. Waters in surficial aquifers in the Drift Prairie (west) and Lake Plain (central) physiographic areas were similar to each other but significantly higher than those in the Moraine (east) area in dissolved solids, sodium, potassium, sulfate, fluoride, silica, and uranium concentrations. Radium, iron, nitrate, and nitrite concentrations were also significantly different among these areas. Pesticides were detected in 12 percent of waters in surficial aquifers in the Drift Prairie area, 20 percent of those in the Lake Plain area, and 52 percent of those in the Moraine area. Triazines and bentazon accounted for 98 percent of summed pesticide concentrations in waters in surficial aquifers. Waters in buried glacial aquifers in the central one-third of the basin had significantly higher concentrations of dissolved solids, sodium, potassium, chloride, fluoride, and iron than did waters in surficial aquifers. No pesticides were detected in five samples from buried glacial aquifers or six samples from Cretaceous aquifers. Waters in all sampled aquifers had a calcium-magnesium ratio of about 1.75 ± 0.75 across the basin regardless of anionic composition. Agricultural land use and soil texture can explain pesticide distributions; soil texture best explains nutrient distributions in waters in surficial aquifers. Confining beds protect waters in buried glacial aquifers from land use effects, resulting in no or low concentrations of nutrients and pesticides. Upward movement of bedrock waters high in dissolved solids concentration can increase concentrations in waters in buried glacial and, to a lesser degree, waters in surficial aquifers in the Lake Plain and Drift Prairie areas. Waters in surficial aquifers exceeded the U.S. Environmental Protection Agency (USEPA) maximum contaminant level in drinking water for nitrate in the Drift Prairie (27 percent) and Moraine (8 percent) areas. Their limited areal extent and susceptibility to contamination restrict the usefulness of surficial aquifers as a drinking water source. Waters in buried glacial aquifers exceeded USEPA health advisories for dissolved solids, sodium, and manganese. Sixty-six percent of waters in surficial aquifers also exceeded the Health Advisory for manganese.

Minnesota, North Dakota, South Dakota

Chester County ground-water atlas, Chester County, Pennsylvania

Chester County encompasses 760 square miles in southeastern Pennsylvania. Groundwater-quality studies have been conducted in the county over several decades to address specific hydrologic issues. This report compiles and describes water-quality data collected during studies conducted mostly after 1990 and summarizes the data in a county-wide perspective. In this report, water-quality constituents are described in regard to what they are, why the constituents are important, and where constituent concentrations vary relative to geology or land use. Water-quality constituents are grouped into logical units to aid presentation: water-quality constituents measured in the field (pH, alkalinity, specific conductance, and dissolved oxygen), common ions, metals, radionuclides, bacteria, nutrients, pesticides, and volatile organic compounds. Water-quality constituents measured in the field, common ions (except chloride), metals, and radionuclides are discussed relative to geology. Bacteria, nutrients, pesticides, and volatile organic compounds are discussed relative to land use. If the U.S. Environmental Protection Agency (USEPA) or Chester County Health Department has drinking water standards for a constituent, the standards are included. Tables and maps are included to assist Chester County residents in understanding the water-quality constituents and their distribution in the county. Ground water in Chester County generally is of good quality and is mostly acidic except in the carbonate rocks and serpentinite, where it is neutral to strongly basic. Calcium carbonate and magnesium carbonate are major constituents of these rocks. Both compounds have high solubility, and, as such, both are major contributors to elevated pH, alkalinity, specific conductance, and the common ions. Elevated pH and alkalinity in carbonate rocks and serpentinite can indicate a potential for scaling in water heaters and household plumbing. Low pH and low alkalinity in the schist, quartzite, and gneiss rocks can indicate a potential for corrosive water. The only constituent measured in the field that has a USEPA Secondary Maximum Contaminant Level (SMCL) is pH. The SMCL for pH is 6.5-8.5; 64 percent of samples analyzed for pH were acidic (below pH 6.5). Only 1 percent of samples were basic (above pH 8.5). Of the common ions, the USEPA has SMCLs for chloride, sulfate, and total dissolved solids. The USEPA has a SMCL and a Primary Maximum Contaminant Level (PMCL) for fluoride. Chloride is more closely related to land use than geology. In Chester County, chloride exceeded the SMCL (250 mg/L) only in 5 percent of the services (commercial services, community services, and military) land-use areas. No samples analyzed for sulfate exceeded the SMCL (250 mg/L). Only 3 percent of samples analyzed for total dissolved solids exceeded the SMCL (500 milligrams per liter) (mg/L). No samples analyzed for fluoride equaled or exceeded the SMCL (2.0 mg/L) or PMCL (4.0 mg/L). Iron concentrations exceeded the USEPA SMCL in 11 percent of samples and were highest in schist (14 percent) and gneiss (13 percent). Manganese concentrations exceeded the SMCL in 19 percent of samples and were highest in quartzite and schist (both 28 percent). Lead and arsenic were present in low concentrations: the highest concentrations of lead occurred in water from quartzite (8 percent exceeded the USEPA Action Level), and arsenic was detected mostly in Triassic sedimentary rocks (9 percent exceeded the USEPA PMCL). The highest concentrations of copper occurred more frequently in quartzite rocks, and to a lesser extent were evenly distributed between ground water in gneiss, schist, and Triassic sedimentary rocks. Elevated concentrations of radon-222 and the combined radium-226/radium-228 radionuclides were common in water from quartzite and schist. Gross alpha and gross beta particle activities were elevated in water from quartzite and carbonate rocks. In contrast, elevated concentrations of uranium primarily were measured in water from Triassic sedimentary and carbonate rocks. Despite a sampling bias towards agricultural land use, only two samples indicated the presence of fecal coliforms. Samples analyzed for nutrients generally exhibited low concentrations, but about 11 percent of samples collected for nitrate exceeded the USEPA PMCL. Only one nitrite sample (less than 1 percent) exceeded the respective USEPA PMCL. Approximately 190 samples were collected for each of the three pesticides in this report: lindane, dieldrin, and diazinon. Sampling was biased towards agricultural, low-medium density residential, and wooded land uses. Approximately 95 percent of samples for each pesticide were below minimum reporting levels (MRL). Only lindane has a USEPA PMCL, and only one sample exceeded the standard. Results for dieldrin and diazinon were similar, except results for two diazinon samples where concentrations were 57.0 and 490 micrograms per liter (μg/L). Volatile organic compounds in this report were analyzed in water from 198 samples. Sampling was biased towards agricultural, low-medium density residential, and wooded land uses. Two percent of samples analyzed for trichloroethylene and less than 1 percent of samples analyzed for tetrachloroethylene exceeded their respective USEPA PMCLs (each 5.0 μg/L). No samples analyzed for 1,1,1-trichloroethane exceeded the USEPA PMCL (200 μg/L). No samples analyzed for methyl tert-butyl ether exceeded the USEPA Drinking Water Advisory (20μg/L).

Open-File Report

Notes on sedimentation activities calendar year 1980

This report is a digest of information furnished by Federal agencies conducting sedimentation investigations on work in progress or planned, important findings, new methods, new publications, laboratory and other research activities, and other pertinent information. The material has been organized by major drainage regions in the conterminous United States, Alaska, Hawaii, Puerto Rico, and foreign. There is also a section on Research and Other Activities.

Report

Notes on sedimentation activities calendar year 1981

This report is a digest of information furnished by those Federal agencies conducting sedimentation investigations. It includes descriptions of work in progress or planned, important findings, new methods, new publications, laboratory and other research activities, and other pertinent information. The material has been organized by major drainage regions in the conterminous United States, Alaska, Hawaii, Puerto Rico, and foreign. There is also a section on Research and Other Activities.

Report

Notes on sedimentation activities calendar year 1983

This report is a digest of information furnished by those Federal agencies conducting sedimentation investigations. It includes descriptions of work in progress or planned, important findings, new methods, new publications, laboratory and other research activities, and other pertinent information. The material has been organized by major drainage regions in the conterminous United States, Alaska, Hawaii, Puerto Rico, and foreign. There is also a section on Research and Other Activities.

Report

Investigation of fish communities in natural channel sections of the Mohawk River, New York

Little is known about the natural resources in the natural channel sections of the Mohawk River between Rome and Frankfort, New York, where the river channel runs separately from and parallel to the Erie Canal. This river section runs through multiple locations that are listed as active remediation sites under New York’s Inactive Hazardous Waste Disposal Site Program and has negligible public or commercial access. As a result, there is minimal recreational usage of this river section, and efforts to conduct biological sampling have been limited. To better understand the composition of fish communities and contaminant concentrations in the natural channel of the Mohawk River, the U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, sampled resident fish in the 34-kilometer section from the mouth of Oriskany Creek downstream to Frankfort. Fish communities were sampled using boat electrofishing during 2021, 2023, and 2024 across multiple reaches within this section. These data were used to estimate species richness (number of species), relative abundance and biomass (catch rates), population size structure (distribution of lengths), and fish condition (a proxy for health). Some gamefish specimens were also analyzed to determine contaminant concentrations in fish tissue. A total of 1,531 individual fish and 38 fish species were captured across all surveys. Seventeen of the 38 (45 percent) species were classified as native to the Mohawk River watershed, whereas 21 of the 38 (55 percent) species were classified as nonnative. Some popular gamefish species such as largemouth bass ( Micropterus salmoides ) and smallmouth bass ( Micropterus dolomieu ) were abundant in most reaches, whereas others such as walleye ( Sander vitreus ) and northern pike ( Esox lucius ) were found sporadically. Only one round goby ( Neogobius melanostomus ) was captured, indicating that this high-profile invasive species remains uncommon in this habitat. A backwater reach had the greatest relative abundance and condition of many species. This indicates connected lentic habitats such as oxbows and backwaters may be important nursery and refuge areas in the aquatic ecosystem. Polychlorinated biphenyl (PCB) concentrations in fish tissue were highly elevated relative to the New York State Department of Health (NYSDOH) fish consumption “don’t eat” advisory guideline. Some specimens exceeded the guideline by an order of magnitude or more, particularly those from a localized area downstream from the Utica Harbor Dam. Concentrations of perfluorooctanesulfonic acid (PFOS) often approached the NYSDOH “don’t eat” consumption guideline but only one sample exceeded the guideline. Concentrations of other contaminants such as mercury and pesticides were consistently measured at less than the “don’t eat” consumption guidelines. These data indicate PCBs remain the primary contaminant of concern in the natural channel of the Mohawk River and are readily bioaccumulating in aquatic organisms despite prior remediation measures. Taken together, the findings in this report are intended to inform future decisions related to fisheries management, public access, recreational usage, and fish consumption advisories.

New York