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At least 523 records · Page 29Linked to original sources

Geohydrology of the shallow aquifers in the Fort Collins-Loveland area, Colorado

Urban areas commonly rely on ground water for at least part of the municipal water supply, and as population increases, urban areas expand and require larger volumes of water. However, the expansion of an urban area can reduce ground-water availability. This may occur through processes of depletion (withdrawal of most of the available ground water), degradation (chemicals used in the urban area seep into the ground and contaminate the ground water), and preemption (cost or restrictions on pumping ground water from under extensively urbanized areas may be prohibitive). Thus, a vital natural resource needed to support the growth of an urban area and its infrastructure can become less available because of growth itself. The diminished availability of natural resources caused by expansion of urban areas is not unique to water resources. For example, large volumes of aggregate (sand and gravel) are used in concrete and asphalt to build and maintain the infrastructure (buildings, roads, airports, and so forth) of an urban area. Yet, mining of aggregate commonly is preempted by urban expansion; for example, it cannot be mined from under a subdivision. Energy resources such as coal, oil, and natural gas likewise are critical to the growth and existence of an urban area but may become less available as an urban area expands and preempts mining and drilling. In 1996, the U.S. Geological Survey began work on a national initiative designed to provide information on the availability of those natural resources (water, minerals, energy, and biota) that are critical to maintaining the Nation's infrastructure or that may become less available because of urban expansion. The initiative began with a 3-year demonstration project to develop procedures for assessing resources and methods for interpreting and publishing information in digital and traditional paper formats. The Front Range urban corridor of Colorado was chosen as the demonstration area (fig. 1), and the project was titled the Front Range Infrastructure Resources Project (FRIRP). This report and those of Robson (1996), Robson and others (1998), and Robson and others (2000a, 2000b, 2000c) are the results of FRIRP water-resources investigations; reports pertaining to geology, minerals, energy, biota, and cartography of the FRIRP are published separately. The waterresources studies of the FRIRP were undertaken in cooperation with the Colorado Department of Natural Resources, Division of Water Resources, and the Colorado Water Conservation Board.

Hydrologic Atlas↗

User's guide to SAC, a computer program for computing discharge by slope-area method

This user's guide contains information on using the slope-area program, SAC. SAC can be used to compute peak flood discharges from measurements of high-water marks along a stream reach. The Slope-area method used by the program is the U.S. Geological Survey (USGS) procedure presented in Techniques of Water Resources Investigations of the U.S. Geological Survey, beok 3, chapter A2, "Measurement of Peak Discharge by the Slope-Area Method." The program uses input files that have formats compatible with those used by the water-surface profile program (WSPRO) described in the Federal Highways Administration publication FHWA-IP-89-027. The guide briefly describes the slope-area method documents the input requirements and the output produced, and demonstrates use of SAC.

Open-File Report↗

User's guide to the culvert analysis program

This user's guide contains information on using the culvert analysis program (CAP). The procedure used is based on that presented in Techniques of Water- Resources Investigations of the United States Geological Survey, book 3, chapter A3, "Measurement of Peak Discharge at Culverts by Indirect Methods." The program uses input files that have formats compatible with those used by the Water-Surface Profile (WSPRO) program. The program can be used to compute rating surfaces or curves that describe the behavior of flow through a culvert or to compute discharges from measurements of upstream and downstream water-surface elevations.

Open-File Report↗

Index of surface-water stations in Texas, January 1984

The U.S. Geological Survey's investigations of the water resources of Texas are conducted in cooperation with the Texas Department of Water Resources, river authorities, cities, counties, U.S. Army Corps of Engineers, U.S. Bureau of Reclamation, International Boundary and Water Commission, and others. Investigations are under the general direction of C. W. Boning, District Chief, Texas District. The Texas District office is located in the Federal Building, 300 East 8th Street, Austin, Texas 78701. As of January 1, 1984, 399 stream-gaging, 86 reservoir-contents, 19 stage, 2 periodic discharge through range, 42 flood-hydrograph partial-record, 15 floodprofile partial-record, 34 low-flow partial-record, 11 crest-stage partial-record, 11 tide-level , 60 daily chemical-qual ity, 27 continuous-recording water-quality, 187 periodic chemical-qual ity, 175 periodic organic-quality, 60 pesticides, 1 sediment, 43 periodic sediment, 109 periodic biological, 28 continuous-recording water temperature, and 37 national stream-quality accounting network stations were in operation. Plate 1 shows the location of surface-water streamflow or reservoircontent and chemical-qual ity or sediment stations in Texas. Plate 2 shows the location of partial-record surface-water stations. This index shows the station number and name, latitude and longitude, type of data collected, and the office principally responsible for the data collection (table 1). An 8-digit permanent numerical designation for gaging stations has been adopted on a nationwide basis; stations are numbered and listed in downstream order. In the downstream direction along the main stem, all stations on a tributary entering above a main-stem station are listed before that station. A tributary entering between two main-stem stations is listed between them. A similar order is followed in listing stations on first rank, second rank, and other ranks of tributaries. To indicate the rank of any tributary on which a gaging station is situated and the stream to which it is an immediate tributary, each indention in the listing of gaging stations represent one rank. This downstream order and system of indention show which gaging stations are on tributaries between any two stations on a main stem and the rank of the tributary on which each gaging station is situated. On plates 1 and 2 the 8-digit station number is abbreviated because of space limitation.

Texas↗

Activities in Idaho; status of projects, fiscal year 1981

Twenty-three projects were conducted by the Water Resources Division of the U.S. Geological Survey in Idaho during fiscal year 1981. These projects were made in cooperation with 6 State and local and 11 Federal agencies. State and local cooperative funding amounted to $720,670; Federal funding amounted to $2,437,628. Eighty-three persons were employed--40 full time and 43 other than full time. In addition, the Water Resources Division maintains a project office at the Idaho National Engineering Laboratory. Work there is done in cooperation with the U.S. Department of Energy, the sole funding source. Projects other than continuing programs for collection of hydrologic data included flood-characteristics and flood-mapping studies, geothermal-resource investigations, ground-water quality assessments, basin- and region-wide water-resource investigations, river quality-of-water monitoring studies, volcanic-ash related studies, and ground-water-trends and stream-gaging program evaluations.

Idaho↗

1990 National Water Quality Laboratory Services Catalog

PREFACE This catalog provides information about analytical services available from the National Water Quality Laboratory (NWQL) to support programs of the Water Resources Division of the U.S. Geological Survey. To assist personnel in the selection of analytical services, the catalog lists cost, sample volume, applicable concentration range, detection level, precision of analysis, and preservation techniques for samples to be submitted for analysis. Prices for services reflect operationa1 costs, the complexity of each analytical procedure, and the costs to ensure analytical quality control. The catalog consists of five parts. Part 1 is a glossary of terminology; Part 2 lists the bottles, containers, solutions, and other materials that are available through the NWQL; Part 3 describes the field processing of samples to be submitted for analysis; Part 4 describes analytical services that are available; and Part 5 contains indices of analytical methodology and Chemical Abstract Services (CAS) numbers. Nomenclature used in the catalog is consistent with WATSTORE and STORET. The user is provided with laboratory codes and schedules that consist of groupings of parameters which are measured together in the NWQL. In cases where more than one analytical range is offered for a single element or compound, different laboratory codes are given. Book 5 of the series 'Techniques of Water Resources Investigations of the U.S. Geological Survey' should be consulted for more information about the analytical procedures included in the tabulations. This catalog supersedes U.S. Geological Survey Open-File Report 86-232 '1986-87-88 National Water Quality Laboratory Services Catalog', October 1985.

Open-File Report↗

Hydrologic data for wells, springs, and streams in Boulder County, Colorado

Hydrologic data collected in 1975-77 as part of a comprehensive water-resources investigation of Boulder County, Colo., by the U.S. Geological Survey in cooperation with the Boulder County Health Department and the Colorado Geological Survey are presented in this report. The data, in tabular and graphic form, consist of water-quality analyses of selected constituents and geohydrologic-site, water-treatment, and sewage-treatment data for 609 wells and 48 springs; water-quality analyses for 102 of the wells and 9 of the springs; water-quality analyses of streamflow from 34 sites; and specific conductance and water-temperature measurements of streamflow from 3 sites. State and local officials in Boulder County may find these data useful in planning for residential, commercial, and industrial development. (Kosco-USGS)

Open-File Report↗

Raster dataset showing the probability of elevated concentrations of nitrate in ground water in Colorado, hydrogeomorphic regions and fertilizer use estimates included

This dataset is one of eight datasets produced by this study. Four of the datasets predict the probability of detecting atrazine and(or) desethyl-atrazine (a breakdown product of atrazine) in ground water in Colorado; the other four predict the probability of detecting elevated concentrations of nitrate in ground water in Colorado. The four datasets that predict the probability of atrazine and(or) desethyl-atrazine (atrazine/DEA) are differentiated by whether or not they incorporated atrazine use and whether or not they incorporated hydrogeomorphic regions. The four datasets that predict the probability of elevated concentrations of nitrate are differentiated by whether or not they incorporated fertilizer use and whether or not they incorporated hydrogeomorphic regions. Each of the eight datasets has its own unique strengths and weaknesses. The user is cautioned to read Rupert (2003, Probability of detecting atrazine/desethyl-atrazine and elevated concentrations of nitrate in ground water in Colorado: U.S. Geological Survey Water-Resources Investigations Report 02-4269, 35 p., http://water.usgs.gov/pubs/wri/wri02-4269/) to determine if he(she) is using the most appropriate dataset for his(her) particular needs. This dataset specifically predicts the probability of detecting elevated concentrations of nitrate in ground water in Colorado with hydrogeomorphic regions and fertilizer use included. The following text was extracted from Rupert (2003). Draft Federal regulations may require that each State develop a State Pesticide Management Plan for the herbicides atrazine, alachlor, metolachlor, and simazine. Maps were developed that the State of Colorado could use to predict the probability of detecting atrazine/DEA in ground water in Colorado. These maps can be incorporated into the State Pesticide Management Plan and can help provide a sound hydrogeologic basis for atrazine management in Colorado. Maps showing the probability of detecting elevated nitrite plus nitrate as nitrogen (nitrate) concentrations in ground water in Colorado also were developed because nitrate is a contaminant of concern in many areas of Colorado. Maps showing the probability of detecting atrazine/DEA at or greater than concentrations of 0.1 microgram per liter and nitrate concentrations in ground water greater than 5 milligrams per liter were developed as follows: (1) Ground-water quality data were overlaid with anthropogenic and hydrogeologic data by using a geographic information system (GIS) to produce a dataset in which each well had corresponding data on atrazine use, fertilizer use, geology, hydrogeomorphic regions, land cover, precipitation, soils, and well construction. These data then were downloaded to a statistical software package for analysis by logistic regression. (2) Relations were observed between ground-water quality and the percentage of land-cover categories within circular regions (buffers) around wells. Several buffer sizes were evaluated; the buffer size that provided the strongest relation was selected for use in the logistic regression models. (3) Relations between concentrations of atrazine/DEA and nitrate in ground water and atrazine use, fertilizer use, geology, hydrogeomorphic regions, land cover, precipitation, soils, and well-construction data were evaluated, and several preliminary multivariate models with various combinations of independent variables were constructed. (4) The multivariate models that best predicted the presence of atrazine/DEA and elevated concentrations of nitrate in ground water were selected. (5) The accuracy of the multivariate models was confirmed by validating the models with an independent set of ground-water quality data. (6) The multivariate models were entered into a geographic information system and the probability GRIDS were constructed.

Open-File Report↗

Water quality of the Crescent River basin, Lake Clark National Park and Preserve, Alaska, 2003-2004

The U.S. Geological Survey and the National Park Service conducted a water-quality investigation of the Crescent River Basin in Lake Clark National Park and Preserve from May 2003 through September 2004. The Crescent River Basin was studied because it has a productive sockeye salmon run that is important to the Cook Inlet commercial fishing industry. Water-quality, biology, and limnology characteristics were assessed. Glacier-fed streams that flow into Crescent Lake transport suspended sediment that is trapped by the lake. Suspended sediment concentrations from the Lake Fork Crescent River (the outlet stream of Crescent Lake) were less than 10 milligrams per liter, indicating a high trapping efficiency of Crescent Lake. The North Fork Crescent River transports suspended sediment throughout its course and provides most of the suspended sediment to the main stem of the Crescent River downstream from the confluence of the Lake Fork Crescent River. Three locations on Crescent Lake were profiled during the summer of 2004. Turbidity profiles indicate sediment plumes within the water column at various times during the summer. Turbidity values are higher in June, reflecting the glacier-fed runoff into the lake. Lower values of turbidity in August and September indicate a decrease of suspended sediment entering Crescent Lake. The water type throughout the Crescent River Basin is calcium bicarbonate. Concentrations of nutrients, major ions, and dissolved organic carbon are low. Alkalinity concentrations are generally less than 20 milligrams per liter, indicating a low buffering capacity of these waters. Streambed sediments collected from three surface sites analyzed for trace elements indicated that copper concentrations at all sites were above proposed guidelines. However, copper concentrations are due to the local geology, not anthropogenic factors. Zooplankton samples from Crescent Lake indicated the main taxa are Cyclops sp., a Copepod, and within that taxa were a relatively small number of ovigerous (egg-bearing) individuals. Cyclops sp. are one of the primary food sources for rearing sockeye salmon juveniles and were most prevalent in the July sampling. Qualitative-Multi-Habitat algae samples were collected from two surface-water sites. A total of 59 taxa were found and were comprised of 4 phyla: Rhodophyta (red algae), Cyanophyta (blue-green algae), Chlorophyta (green algae), and Chrysophyta (diatoms). Twenty-two algal taxa were collected from the upper site, North Fork Crescent River, whereas twice as many taxa were collected from the downstream site, Crescent River near the mouth.

Scientific Investigations Report↗

Water Quality, Physical Habitat, and Biology of the Kijik River Basin, Lake Clark National Park and Preserve, Alaska, 2004-2005

The U.S. Geological Survey and the National Park Service conducted a water-quality investigation of the Kijik River Basin in Lake Clark National Park and Preserve from June 2004 to March 2005. The Kijik River Basin was studied because it has a productive sockeye salmon run that is important to the larger Kvichak River watershed. Water-quality, physical habitat, and biological characteristics were assessed. Water type throughout the Kijik River Basin is calcium bicarbonate although Little Kijik River above Kijik Lake does have slightly higher concentrations of sulfate and chloride. Alkalinity concentrations are generally less than 28 milligrams per liter, indicating a low buffering capacity of these waters. Lachbuna Lake traps much of the suspended sediment from the glacier streams in the headwaters of the basin as evidenced by low secchi-disc transparency of 1 to 2 meters and low suspended sediment concentrations in the Kijik River downstream from the lake. Kijik Lake is a fed by clearwater streams and has secchi-disc readings ranging from 11 to 15 meters. Streambed sediments collected from four surface sites analyzed for trace elements indicated that arsenic concentrations at all sites were above proposed guidelines. However, arsenic concentrations are due to the local geology, not anthropogenic factors. Benthic macroinvertebrate qualitative multi-habitat samples collected from two sites on the Little Kijik River and two sites on the main stem of the Kijik River indicated a total of 69 taxa present among the four sites. The class Insecta, made up the largest percentage of macroinvertebrates, totaling 70 percent of the families found. The insects were comprised of four orders; Diptera (flies and midges), Ephemeroptera (mayflies), Plecoptera (stoneflies), and Trichoptera (caddisflies). One-hundred twenty-two species of periphytic algae were identified in qualitative multi-habitat samples collected at the four stream sites. Eight species of non-motile, diatoms were collected from all four stream sites suggesting that the areas from which they were collected are relatively stable and unaffected by sedimentation.

Scientific Investigations Report↗

Ecological indicators of water quality in the Spokane River, Idaho and Washington, 1998 and 1999

A water-quality investigation of the Spokane River was completed during summer low-flow conditions in 1998 and 1999 as part of the USGS NAWQA Program, in cooperation with the WDOE. (Abbreviations used in this report are defined on the last page.) Samples for analyses of water chemistry; bed sediment; aquatic communities (fish, macroinvertebrates, and algae); contaminants in tissue (fish and macroinvertebrates); and associated measures of habitat were collected at six sites downstream from Coeur d’Alene Lake between river miles 63 and 100. These data provided baseline information to evaluate the water-quality status of the Spokane River and can be used to determine the ecological risk to aquatic organisms from contaminants.

Washington;Idaho↗

Propagation and composition of the flood wave on the upper Mississippi River, 1993

During spring and summer 1993, record flooding inundated much of the upper Mississippi River Basin. The magnitude of the damages-in terms of property, disrupted business, and personal trauma was unmatched by any other flood disaster in United States history. Property damage alone is expected to exceed $10 billion. Damaged highways and submerged roads disrupted overland transportation throughout the flooded region. The Mississippi and the Missouri Rivers were closed to navigation before, during, and after the flooding. Millions of acres of productive farmland remained under water for weeks during the growing season. Rills and gullies in many tilled fields are the result of the severe erosion that occurred throughout the Midwestern United States farmbelt. The hydrologic effects of extended rainfall throughout the upper Midwestern United States were severe and widespread. The banks and channels of many rivers were severely eroded, and sediment was deposited over large areas of the basin's flood plain. Record flows submerged many areas that had not been affected by previous floods. Industrial and agricultural areas were inundated, which caused concern about the transport and fate of industrial chemicals, sewage effluent, and agricultural chemicals in the floodwaters. The extent and duration of the flooding caused numerous levees to fail. One failed levee on the Raccoon River in Des Moines, Iowa, led to flooding of the city's water treatment plant. As a result, the city was without drinking water for 19 days. As the Nation's principal water-science agency, the U.S. Geological Survey (USGS) is in a unique position to provide an immediate assessment of some of the hydrological effects of the 1993 flood. The USGS maintains a hydrologic data network and conducts extensive water-resources investigations nationwide. Long-term data from this network and information on local and regional hydrology provide the basis for identifying and documenting the effects of the flooding . During the flood, the USGS provided continuous streamflow and related information to the National Weather Service (NWS), the U.S. Army Corps of Engineers, the Federal Emergency Management Agency (FEMA), and many State and local agencies as part of its role to provide basic information on the Nation's surface- and ground-water resources at thousands of locations across the United States. The NWS has used the data in forecasting floods and issuing flood warnings. The data have been used by the Corps of Engineers to operate water diversions, dams, locks, and levees. The FEMA and many State and local emergency management agencies have used USGS hydrologic data and NWS forecasts as part of the basis of their local flood-response activities. In addition, USGS hydrologists are conducting a series of investigations to document the effects of the flooding and to improve understanding of the related processes. The major initial findings from these studies will be reported in this Circular series as results become available. U.S. Geological Survey Circular 1120, Floods in the Upper Mississippi River Basin, 1993, consists of individually published chapters that will document the effects of the 1993 flooding. The series includes data and findings on the magnitude and frequency of peak discharges; precipitation; water-quality characteristics, including nutrients and man-made contaminants; transport of sediment; assessment of sediment deposited on flood plains; effects of inundation on ground-water quality; flood-discharge volume; effects of reservoir storage on flood peaks; stream-channel scour at selected bridges; extent of floodplain inundation; and documentation of geomorphologic changes.

upper Mississippi River basin↗

Numerical simulation of groundwater and surface-water interactions in the Big River Management Area, central Rhode Island

The Rhode Island Water Resources Board is considering use of groundwater resources from the Big River Management Area in central Rhode Island because increasing water demands in Rhode Island may exceed the capacity of current sources. Previous water-resources investigations in this glacially derived, valley-fill aquifer system have focused primarily on the effects of potential groundwater-pumping scenarios on streamflow depletion; however, the effects of groundwater withdrawals on wetlands have not been assessed, and such assessments are a requirement of the State’s permitting process to develop a water supply in this area. A need for an assessment of the potential effects of pumping on wetlands in the Big River Management Area led to a cooperative agreement in 2008 between the Rhode Island Water Resources Board, the U.S. Geological Survey, and the University of Rhode Island. This partnership was formed with the goal of developing methods for characterizing wetland vegetation, soil type, and hydrologic conditions, and monitoring and modeling water levels for pre- and post-water-supply development to assess potential effects of groundwater withdrawals on wetlands. This report describes the hydrogeology of the area and the numerical simulations that were used to analyze the interaction between groundwater and surface water in response to simulated groundwater withdrawals. The results of this analysis suggest that, given the hydrogeologic conditions in the Big River Management Area, a standard 5-day aquifer test may not be sufficient to determine the effects of pumping on water levels in nearby wetlands. Model simulations showed water levels beneath Reynolds Swamp declined by about 0.1 foot after 5 days of continuous pumping, but continued to decline by an additional 4 to 6 feet as pumping times were increased from a 5-day simulation period to a simulation period representative of long-term average monthly conditions. This continued decline in water levels with increased pumping time is related to the shift from the primary source of water to the pumped wells being derived from aquifer storage during the early-time (5 days) simulation to being derived more from induced infiltration from the flooded portion of the Big River (southernmost extent of the Flat River Reservoir) during the months of March through October or from captured groundwater discharge to this portion of the Big River when the downstream Flat River Reservoir is drained for weed control during the months of November through February, as was the case for the long-term monthly conditions.

Rhode Island↗

Transportation and Hydrology Studies of the U.S. Geological Survey in New England

The U.S. Geological Survey (USGS) has a long history of working with the Federal Highway Administration (FHWA) and State transportation agencies to provide data and information to address various issues related to water resources and the Nation’s transportation infrastructure. These issues include the following: • Streamgaging data networks • Flow frequencies and flow statistics • Water-quality investigations • Bridge scour and sediment transport • Hydrologic and hydraulic flood modeling In New England, the USGS is conducting investigations to improve flood flow estimation techniques, to define channel characteristics at bankfull discharge, and to document storm tide as a result of major coastal storms. Current locally focused investigations include examination of flow frequency in rural, urban, and small watersheds; documentation of extreme inland floods along with flood-frequency updates; examination of the effects of roadway blasting on groundwater quality; and determinations of the effects of road salting on the quality of runoff and receiving waters.

New England↗

Selected hydrologic data, Arkansas River basin, Pueblo and southeastern Fremont Counties, Colorado, 1975-80

Selected hydrologic data collected in 1975-80 as part of water-quality investigations by the U.S. Geological Survey in Pueblo and southeastern Fremont Counties, Colo., are presented in this report. The data, in tabular form, consist of streamflow-discharge measurements for 33 sites, channel-geometry measurements for 97 sites, traveltime data for 12 sites, and field and laboratory water-quality analyses for 194 sites. Federal, state, and local officials may find these data useful in making decisions relating to the management of water resources of the area.

Colorado↗

A brief investigation of the surface-water hydrology of Yemen Arab Republic

Yemen, near the southwest tip of the Arabian Peninsula, is a mountainous country bordered by a desert on the east and a coastal plain on the west. Rainfall is low and seasonal; consequently, most streams (wadis) are ephemeral. The natural flow regimens of many of the smaller wadis are modified by terracing for agriculture. The only streamflow data available in Yemen are short records on four large wadis. A brief field investigation and application of reconnaissance techniques are the bases for the largely qualitative description of the hydrology, and for the proposal to collect streamflow data needed for orderly development of the expanding economy. (Woodard-USGS)

Open-File Report↗

A comparison of selected diversity, similarity, and biotic indices for detecting changes in benthic-invertebrate community structure and stream quality

Implementation of advanced wastewater treatment at the two municipal wastewater-treatment plants for Indianapolis, Indiana, resulted in substantial improvement in the quality of the receiving stream and significant changes in the benthic-invertebrate community. Diversity, similarity, and biotic indices were compared to determine which indices best reflected changes in the composition of the biota in the river. None of the indices perfectly reflected the changes in river quality or community structure. Similarity indices, especially percentage similarity, exhibit the most promise of the three classes of indices. Diversity indices were least useful, wrongly indicating that water quality deteriorated after the upgrade of the wastewater-treatment plants. The most descriptive tool in analyzing the data was the percentage of Ephemeroptera, Plecoptera, and Trichoptera (EPT) taxa present. Using a mixture of indices and other analytical tools, such as EPT, in the analysis of biological data will ensure the most effective investigations of water quality.

Archives of Environmental Contamination and Toxico↗

Geochemistry of speleothem records from southern Illinois: Development of (234U)/(238U) as a proxy for paleoprecipitation

Natural waters universally show fractionation of uranium series (U-series) parent-daughter pairs, with the disequilibrium between 234U and 238U (234U)/(238U) commonly used as a tracer of groundwater flow. Because speleothems provide a temporal record of geochemical variations in groundwater precipitating calcite, (234U)/(238U) variations in speleothems provide a unique method of investigating water-rock interaction processes over millennium time scales. We present high precision Thermal Ionization Mass Spectrometric (TIMS) U-series analyses of speleothems and drip waters from Fogelpole Cave in southern Illinois. Data from all speleothems from the cave show an inverse correlation between (234U)/(238U) and U concentration, following the pattern observed in groundwaters globally. Within a 65-cm-long stalagmite, concordant 234U-238 U-230Th and 235U-231Pa ages for 5 samples indicate accurate chronology from 78.5 ka to 30 ka. Notably, (234U)/(238U)o which differs from most speleothems by having (234U)/(238U)o <1, positively correlates with speleothem growth rate. We generalize this to the observation that speleothems globally show (234U)/ (238U)o deviating farther from secular equilibrium at lower growth rates and approaching secular equilibrium at higher grow rates. Based on the Fogelpole observations, we suggest that groundwater (234U)/(238U) is controlled by the U oxidation state, the U concentration of the water and the fluid velocity. A transport model whereby U-series nuclides react and exchange with mineral surfaces can reproduce the observed trend between growth rate and (234U)/(238U)o. Based on this result, we suggest that (234U)/(238U)o in speleothems may record changes in hydrologic flux with time and thus could provide a useful proxy for long term records of paleoprecipitation. ?? 2005 Elsevier B.V. All rights reserved.

Chemical Geology↗