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At least 523 records · Page 29Linked to original sources

USGS2002

Seismicity, gas emission and deformation from 18 July to 25 September 1995 during the initial phreatic phase of the eruption of Soufrière Hills Volcano, Montserrat

On 18 July 1995, after more than three years of irregularly increasing seismicity, phreatic explosions opened a new vent on Soufrière Hills Volcano, about 4 km east of the capital city of Plymouth, Montserrat. By early August 1995, the volcano was monitored by a nine-station seismic network, three telemetered electronic tiltmeters, and daily correlation spectroscopy (COSPEC) flights to measure SO 2 emission rates and to observe vent areas. Seismicity and SO 2 emission rates implicated magma intrusion as the cause of the seismic unrest. Strong evidence of magma ascent to shallow levels, however, did not appear until late September 1995, when increasing numbers of hybrid events heralded the formation of a small dome and spine. We infer from the data that intrusion of a small volume of magma occurred in July, but stalled on ascent. Degassing of the stalled magma formed a carapace that thickened with time. We suggest that either volatile build-up beneath the degassed carapace, or aseismic intrusion of fresh material, finally forced the stalled magma to the surface in late September 1995. A similar cycle of activity appears to have occurred during the second phreatic phase between late September and mid-November 1995.

Soufrière Hills Volcano↗

USGS2003

Distinguishing palagonitized from pedogenically-altered basaltic Hawaiian tephra: Mineralogical and geochemical criteria

Palagonitization is a common, but imperfectly defined process that greatly modifies the physical and chemical properties of glassy basaltic tephra deposited in subaquatic/subglacial environments on Earth and perhaps Mars. It also results in textures and mineralogies that are distinct from other forms of (mainly pedogenic) low temperature alteration. Specifically, the process of palagonitization (1) initially results in the formation of 'palaginitized glass', a quasi- or nano-crystalline, rind-like material that contains smectite, as well as lesser amounts of other clays (e.g. serpentine), and (2) eventually results in consolidation of tephra, mediated through the accretion of palagonitized glass and later- formed authigenic cements. Conversely, pedogenic weathering of glassy basaltic tephra is characterized by disaggregation of tephra, and formation of a wide range of pedogenic products, including layer silicates (although not primarily smectite), short-range-order aluminosilicates and oxyhydroxides, whose composition reflects the intensity of the weathering environment. These mineralogical and textural properties can be readily recognized through a variety of techniques including electron microscopy/microprobe analysis, reflectance spectroscopy, X-ray diffraction and soil chemistry. Analyses of samples collected from the summit regions of Kilauea and Mauna Kea volcanoes on the island of Hawaii are presented here in order to illustrate differences between palagonitization and pedogenic weathering of glassy basaltic tephra. In the young Hawaiian tephras studied, palagonitization has occurred in response to hydrothermal activity shortly after deposition. Although some, non-hydrothermally affected tephras may eventually become palagonitized, those that have been strongly desilicated by intense pedogenic weathering will probably never become palagonitized.

Geological Society Special Publication↗

USGS2022

Demonstration of a novel quantitative microscopy technique for automated characterization of in situ particulate matter in coal miners with progressive massive fibrosis

Rationale: Increasing exposure to respirable crystalline silica (RCS) linked to changes in mining production processes has been implicated in the resurgence of severe lung disease in U.S. coal miners. Lung mineralogy can provide insight into particle pathogenesis. However, standard approaches to characterizing in situ particulate matter (PM) by pulmonary pathologists have poor inter-rater comparability, and consensus agreement is time consuming. Scanning electron microscopy/energy-dispersive spectroscopy (SEM/EDX) is technically complex and labor intensive. We developed a method for quantitative in situ PM characterization using conventional polarized light microscopy (PLM) and explored PM features in lung tissue of coal miners with progressive massive fibrosis (PMF). Methods: With institutional review board approval, PLM images were obtained from 30 miners with PMF, classified by pathologists consensus based on PM profusion; 10 from each profusion group (mild/moderate/severe) were selected. Automated PM counting and characterization (including dimensions and grayscale intensity of PM > 0.3 m diameter) was performed on image samples using PLM with modified cell-counting software (BZ-X800 light microscope, Keyence Corporation, Osaka, Japan) (Figure 1). Quantitative PM density loge(PM count)/mm3 tissue was calculated for each sample and compared to pathologist PM profusion groups. PMF lesion type using consensus pathologist classification (13 coal-type, 9 mixed-type, and 8 silicotic-type) was compared to automated PM birefringence level (% particles with mean grayscale intensity <65, range 0-255). RCS particles are expected to be weakly birefringent (lower intensity) relative to other common minerals (e.g., silicates) contained in coal mine dust. PM features were analyzed in R 4.0.3 using one-way ANOVA for between-group comparisons. Results: Measured PM log-density increased significantly with higher qualitative profusion group (mild=10.480.98/mm3, moderate=11.460.81/mm3, severe=12.520.86/mm3, p<0.0001). Prevalence of weakly birefringent particles was significantly higher among silicotic-type PMF samples (31.57.9%) compared to either coal-type (21.510.1%, p=0.022) or mixed-type lesions (21.510.5%, p=0.025). Conclusion: This pilot study demonstrates the feasibility of a novel quantitative microscopy technique for counting and characterizing in situ lung PM in coal miners with PMF. Quantitative PM burden was comparable to pulmonary pathologists consensus profusion classification, but this method was substantially less time consuming and labor intensive and provided additional information about relevant PM features. The higher prevalence of weakly birefringent particles seen in silicotic-type PMF lesions may help inform mineralogic pathogenesis of RCS. Future efforts will expand the number of PMF cases analyzed, further validate our mineralogic findings using data from SEM/EDX and lung tissue digestate methods, and compare findings in historical versus contemporary coal miners with PMF.

Conference Paper↗

USGS2021

Multimineral petrophysics of thermally immature Eagle Ford Group and Cretaceous mudstones, U.S. Geological Survey Gulf Coast 1 research wellbore in central Texas

Traditional petrophysical methods to evaluate organic richness and mineralogy using gamma-ray and resistivity log responses are not diagnostic in source rocks. We have developed a deterministic, nonproprietary method to quantify formation variability in total organic carbon (TOC) and three key mudrock mineralogical components of nonhydrocarbon-bearing source rock strata of the Eagle Ford Group by developing a set of log-derived multimineral models calibrated with Fourier transform infrared spectroscopy core data from the research borehole U.S. Geological Survey Gulf Coast 1 West Woodway. We determined that bulk density response is a reliable indicator of organic content in these thermally immature, water-bearing source rocks. Multimineral findings indicate that a high degree of laminae-scale mineralogical heterogeneity exists due to thinly interbedded carbonate cements amid clay-rich mudstone layers. The lower part of the Eagle Ford Group contains the highest average TOC content (4.7 wt%) and the highest average carbonate volume (64.1 vol%), making it the optimal target in thermally mature areas for source-rock potential and hydraulic-fracture placement. In contrast, the uppermost portion of the Eagle Ford Group contains the highest average volume of clay minerals (42.6 vol%), which increases the potential for wellbore stability issues. Petrophysical characterization reveals that porosity is approximately 30% in this relatively uncompacted formation. In this thermally immature source rock, water saturation is nearly 100% and no free hydrocarbons were observed on the resistivity logs. No evidence of borehole ellipticity was observed on the three-arm caliper log, and horizontal stresses are presumed to be directionally uniform in the vicinity of this near-surface wellbore. This shallow wellbore has a temperature gradient of 1.87°F/100 ft (16.3°C/km) and is likely influenced by earth surface heating.

Texas↗

USGS2011

Hyperspectral remote sensing of vegetation

Hyperspectral narrow-band (or imaging spectroscopy) spectral data are fast emerging as practical solutions in modeling and mapping vegetation. Recent research has demonstrated the advances in and merit of hyperspectral data in a range of applications including quantifying agricultural crops, modeling forest canopy biochemical properties, detecting crop stress and disease, mapping leaf chlorophyll content as it influences crop production, identifying plants affected by contaminants such as arsenic, demonstrating sensitivity to plant nitrogen content, classifying vegetation species and type, characterizing wetlands, and mapping invasive species. The need for significant improvements in quantifying, modeling, and mapping plant chemical, physical, and water properties is more critical than ever before to reduce uncertainties in our understanding of the Earth and to better sustain it. There is also a need for a synthesis of the vast knowledge spread throughout the literature from more than 40 years of research.

Book↗

USGS2024

Reassessment of the volkonskoite-chromian smectite nomenclature problem.

The name volkonskoite was first used in 1830 to describe a bright blue-green, chromium-bearing clay material from the Okhansk region, west of the Ural Mountains, U.S.S.R. Since that time, the name has been applied to numerous members of the smectite group of clay minerals, although the reported chromium content has ranged from 1% to about 30% Cr 2 O 3 . The name has also been applied to some chromian chlorites. Because volkonskoite has been used for materials that differ not only in their chromium content but also in their basic structure, the species status of the mineral has been unclear. To resolve this uncertainty, two specimens of volkonskoite from (1) Mount Efimiatsk, the type locality in the Soviet Union (USNM 16308) and (2) the Okhansk region in the Perm Basin, U.S.S.R. (USNM R4820), were examined by several mineralogical techniques. Neotype sample 16308 has the following structural formula: (Ca 0.11 Mg 0.11 Fe 2+ 0.03 K 0.02 )(Cr 1.18 Mg 0.78 Fe 3+ 0.29 Ca 0.02 )(Si 3.50 Al 0.51 )O 10 (OH) 2 ⋅3.64H 2 O. Sample R4820 has the following structural formula: (Ca 0.25 Mg 0.05 Fe 2+ 0.01 K 0.03 Mn 0.01 )(Cr 1.07 Mg 0.75 Fe 3+ 0.35 (Si 3.59 Al 0.43 )O 10 (OH) 2 ⋅4.22H 2 O. Mössbauer spectroscopy indicates that 91% and 98% of the iron is present as Fe 3+ in samples 16308 and R4820, respectively. X-ray powder diffraction patterns of both samples have broad lines corresponding to minerals of the smectite group. On the basis of these data, volkonskoite appears to be a dioctahedral member of the smectite group that contains chromium as the dominant cation in the octahedral layer. Smectites containing less than this amount of octahedral chromium should not be called volkonskoite, but should be named by chemical element adjectives, e.g., chromian montmorillonite, chromian nontronite.

Clays and Clay Minerals↗

USGS2011

A natural experiment on the condition-dependence of achromatic plumage reflectance in black-capped chickadees

Honest advertisement models posit that only individuals in good health can produce and/or maintain ornamental traits. Even though disease has profound effects on condition, few studies have experimentally tested its effects on trait expression and even fewer have identified a mechanistic basis for these effects. Recent evidence suggests that black and white, but not grey, plumage colors of black-capped chickadees (Poecile atricapillus) are sexually selected. We therefore hypothesized that birds afflicted with avian keratin disorder, a condition that affects the beak and other keratinized tissues, would show reduced expression of black and white, but not grey, color. UV-vis spectrometry of black-capped chickadees affected and unaffected by avian keratin disorder revealed spectral differences between them consistent with this hypothesis. To elucidate the mechanistic bases of these differences, we used scanning electron microscopy (SEM), electron-dispersive x-ray spectroscopy (EDX) and a feather cleaning experiment. SEM showed extreme feather soiling in affected birds, and EDX revealed that this was most likely from external sources. Experimentally cleaning the feathers increased color expression of ornamental feathers of affected, but not unaffected, birds. These data provide strong evidence that black and white color is an honest indicator in chickadees, and that variation in feather dirtiness, likely due to differences in preening behavior is a mechanism for this association.

PLoS ONE↗

USGS2013

Detection of salt marsh vegetation stress and recovery after the Deepwater Horizon Oil Spill in Barataria Bay, Gulf of Mexico using AVIRIS data

The British Petroleum Deepwater Horizon Oil Spill in the Gulf of Mexico was the biggest oil spill in US history. To assess the impact of the oil spill on the saltmarsh plant community, we examined Advanced Visible Infrared Imaging Spectrometer (AVIRIS) data flown over Barataria Bay, Louisiana in September 2010 and August 2011. Oil contamination was mapped using oil absorption features in pixel spectra and used to examine impact of oil along the oiled shorelines. Results showed that vegetation stress was restricted to the tidal zone extending 14 m inland from the shoreline in September 2010. Four indexes of plant stress and three indexes of canopy water content all consistently showed that stress was highest in pixels next to the shoreline and decreased with increasing distance from the shoreline. Index values along the oiled shoreline were significantly lower than those along the oil-free shoreline. Regression of index values with respect to distance from oil showed that in 2011, index values were no longer correlated with proximity to oil suggesting that the marsh was on its way to recovery. Change detection between the two dates showed that areas denuded of vegetation after the oil impact experienced varying degrees of re-vegetation in the following year. This recovery was poorest in the first three pixels adjacent to the shoreline. This study illustrates the usefulness of high spatial resolution airborne imaging spectroscopy to map actual locations where oil from the spill reached the shore and then to assess its impacts on the plant community. We demonstrate that post-oiling trends in terms of plant health and mortality could be detected and monitored, including recovery of these saltmarsh meadows one year after the oil spill.

Louisiana↗

USGS2014

An integrated approach to the Taxonomic identification of prehistoric shell ornaments

Shell beads appear to have been one of the earliest examples of personal adornments. Marine shells identified far from the shore evidence long-distance transport and imply networks of exchange and negotiation. However, worked beads lose taxonomic clues to identification, and this may be compounded by taphonomic alteration. Consequently, the significance of this key early artefact may be underestimated. We report the use of bulk amino acid composition of the stable intra-crystalline proteins preserved in shell biominerals and the application of pattern recognition methods to a large dataset (777 samples) to demonstrate that taxonomic identification can be achieved at genus level. Amino acid analyses are fast (<2 hours per sample) and micro-destructive (sample size <2 mg). Their integration with non-destructive techniques provides a valuable and affordable tool, which can be used by archaeologists and museum curators to gain insight into early exploitation of natural resources by humans. Here we combine amino acid analyses, macro- and microstructural observations (by light microscopy and scanning electron microscopy) and Raman spectroscopy to try to identify the raw material used for beads discovered at the Early Bronze Age site of Great Cornard (UK). Our results show that at least two shell taxa were used and we hypothesise that these were sourced locally.

PLoS ONE↗

USGS2015

Fluid inclusion chemistry of adularia-sericite epithermal Au-Ag deposits of the southern Hauraki Goldfield, New Zealand

Microthermometry, laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), and Raman spectroscopy have been used to determine the temperature, apparent salinity, and composition of individual fluid inclusions in adularia-sericite Au-Ag epithermal veins from the Karangahake, Martha, Favona, and Waitekauri deposits, southern Hauraki goldfield, New Zealand. Quartz veins contain colloform to crustiform bands that alternate with coarse-grained quartz and amethyst. The ore mineralization occurs only in colloform to crustiform bands. Analyses of individual fluid inclusions by LA-ICP-MS identify Na as the most abundant cation, together with variable concentrations of K, Ca, Rb, Sr, Sb, and As. Rare inclusions have detectable Li, Al, and Ba concentrations, although recorded Al concentrations with values up to 231 ppm in Al-free quartz may reflect an accidentally captured mineral phase rather than fluid itself. The Na content ranges from ~260 to 10,200 ppm for inclusions in quartz and ~9,700 to 13,700 ppm for inclusions in amethyst. Antimony is the second most commonly detected element in both quartz- and amethyst-hosted inclusions; this element is also detected in the host mineral. Concentrations of Sb and As range from 0.3 to 988 ppm and from 3.33 to 418 ppm, respectively, and are most commonly detected in inclusions from the Karangahake and Martha deposits. The poor correlation between the Na content with either Sb or As suggests that Sb and As were transported as neutral hydroxyl complexes of Sb(OH)3 and As(OH)3. Both Au and Ag occur at concentrations that are less than their respective detection limits (ppm). Geochemical modeling of the microthermometric and LA-ICP-MS data obtained from individual fluid inclusions suggests that fluids responsible for the quartz deposition were neutral to alkaline and that adiabatic boiling is the most effective mechanism for both gold and silica precipitation. The presence of single-phase vapor-only fluid inclusions in some mineralized samples indicates that local flashing may have contributed to deposition of Au and Ag. Assuming adiabatic boiling under hydrostatic pressure, samples from the Karangahake deposit (Maria vein) were deposited from low-salinity fluids (<3.9 wt % NaCl equiv) at temperatures between 225° and 262°C and at depths of 270 to 575 m below the former water table. The average deep reservoir fluid temperature estimated from the Na/K geothermometer is 287°C, and the steam loss during boiling ranges between 8 and 17%. Fluid inclusions in quartz from the Martha deposit trapped dilute fluids with salinity less than 1.7 wt % NaCl equiv. The coexisting liquid-rich (homogenization temperature, Th = 189°–225°C) and vapor-rich inclusions (Th = 205°–243°C) suggest formation at depths of 200 to 400 m below the water table. According to the Na/K geothermometer, the deep reservoir fluid temperature was near 295°C, and the steam loss during boiling ranged between 15 and 23%. Pseudosecondary inclusions in amethyst display salinity around 4.0 wt % NaCl equiv and homogenization temperatures between 218° and 241°C. Secondary inclusions are slightly more dilute (3.2–4.2 wt % NaCl equiv), with homogenization temperatures between 213° and 242°C. Fluid inclusions in quartz from the Waitekauri deposit homogenize from 210° to 265°C and contain less than 1.2 wt % NaCl equiv. A thin quartz vein that occurs between the Jubilee and Scotia deposits contains coexisting liquid- and vapor-rich inclusions; their homogenization temperatures indicate a formation depth of 300 m below the former water table. The calculated deep reservoir fluid temperature is around 283°C and the steam loss is estimated to be between 13 and 18%. LA-ICP-MS analyses show that in some cases different fluid inclusion assemblages (FIAs) within a single sample trapped fluids with variable chemistries. These differences likely reflect modification of a single parent fluid through mineral dissolution and precipitation, water/rock interactions, boiling and vapor loss, conductive cooling, and mixing.

Economic Geology↗

USGS1969

Chemical composition of the hydrothermal fluids responsible for the lead-zinc deposits at Providencia, Zacatecas, Mexico

The chemical composition of 22 samples of primary fluid inclusions in quartz, calcite, and sphalerite from Providencia, Mexico, has been determined. Samples were prepared, crushed, and leached as described by Roedder et al. (1963). Cation analyses of leachates were made by atomic absorption spectroscopy, and the anions were analyzed by a special X-ray fluorescence technique. The Na, K, Ca, and C1 concentrations show a considerable range that reflects the widespread salinity variations in the hydrothermal fluids observed by Sawkins (1964). The K/Na atomic ratios of most samples range from 0.18 to 0.43 and the ratios tend to increase with the salinity of the inclusions. The temperatures indicated by the K/Na ratios from the published curves of K/Na ratios vs. temperature are mostly at least 100 ø C greater than corresponding filling temperatures. The Ca/Na atomic ratios of inclusions in sphalerite range from 0.12 to 0.61. The K/Na and Ca/Na data agree well with previous δO¹⁸ data (Rye, 1966; Rye and O'Neil. 1968) which indicate that the hydrothermal fluids were derived from the magma related to the Providencia granodiorite stock and that the fluids reacted only slightly with the crystalline stock during the late phases of ore deposition. The data also indicate that the salinity variations in the hydrothermal fluids probably occurred at the source of the fluids and may have resulted from boiling in the magma chamber. Mg concentrations are generally no more than a few hundred parts per million. Most of the Mg in the hydrothermal fluids was evidently removed during the formation of calcium-magnesium silicates in the lower levels of the ore pipes. Mg/Ca atomic ratios are generally less than 0.08 and are consistent with the paucity of dolomite in the area. Zn and Cu concentrations in water leaches of inclusions in calcite are generally less than 50 ppm. Maximum base-metal concentrations from water leaches of two samples of inclusions in quartz are 890 ppm Zn and 530 ppm Cu. Chloride is the major anion in the fluids, and C1 concentrations vary with corresponding cation concentrations. With two exceptions, sulfur concentrations of the inclusions in calcite and quartz, analyzed as SO₄, are below the level of detection

Zacatecas↗

USGS1986

Spectral reflectance of carbonatites and related alkalic igneous rocks: Selected samples from four North American localities

Laboratory spectral reflectance measurements were made in the 0.4- to 2.5-mu m wavelength range for samples collected from four North American carbonatite-alkalic igneous rock complexes. Alkalic rock spectra produced few absorption features; however, the carbonatites typically showed conspicuous carbonate, ferric and ferrous iron, and in some cases rare earth element absorption bands. Trivalent neodymium was the most abundant rare earth element producing absorption features and could be detected in amounts as low as 300 ppm. Ferrous iron was present in most dolomitic carbonatite samples and caused more intense ferrous absorption bands than commonly is seen in carbonate rocks of sedimentary origin. High carbonatite iron content also resulted in pervasive limonitic staining and related ferric iron absorption features. These absorption features sometimes masked other absorption bands.Because reflectance measurements can be carried out rapidly, with minimal sample preparation, reflectance spectroscopy may provide a useful field and laboratory tool for analyzing economic rare earth concentrations. In addition, the distinctive spectral characteristics of carbonatite material, in conjunction with the discordant spatial relationships between associated alkalic and carbonatite rocks, may provide a basis for remote-sensing detection of these complexes.

Economic Geology↗

USGS2003

Utility of high-altitude infrared spectral data in mineral exploration: Application to Northern Patagonia Mountains, Arizona

Synoptic views of hydrothermal alteration assemblages are of considerable utility in regional-scale minerals exploration . Recent advances in data acquisition and analysis technologies have greatly enhanced the usefulness of remotely sensed imaging spectroscopy for reliable alteration mineral assemblages mapping. Using NASA's Airborne Visible Infrared Imaging Spectrometer (AVIRIS) sensor, this study mapped large areas of advanced argillic and phyllic-argillic alteration assemblages in the southeastern Santa Rita and northern Patagonia mountains , Arizona . Two concealed porphyry copper deposits have been identified during past exploration , the Red Mountain and Sunnyside deposits, and related published hydrothermal alteration zoning studies allow the comparison of the results obtained from AVIRIS data to the more traditional field mapping approaches. The AVIRIS mapping compares favorably with field-based studies. An analysis of iron-bearing oxide minerals above a concealed supergene chalcocite deposit at Red Mountain also indicates that remotely sensed data can be of value in the interpretation of leached caps above porphyry copper deposits. In conjunction with other types of geophysical data , AVIRIS mineral maps can be used to discriminate different exploration targets within a region.

Economic Geology↗

USGS2010

Biologic origin of iron nodules in a marine terrace chronosequence, Santa Cruz, California

The distribution, chemistry, and morphology of Fe nodules were studied in a marine terrace soil chronosequence northwest of Santa Cruz, California. The Fe nodules are found at depths <1 m on all terraces. The nodules consisted of soil mineral grains cemented by Fe oxides. The nodules varied in size from 0.5 to 25 mm in diameter. Nodules did not occur in the underlying regolith. The Fe-oxide mineralogy of the nodules was typically goethite; however, a subset of nodules consisted of maghemite. There was a slight transformation to hematite with time. The abundance of soil Fe nodules increased with terrace age on the five terraces studied (aged 65,000-226,000 yr). Scanning electron microscopy (SEM) revealed Fe-oxide-containing fungal hyphae throughout the nodules, including organic structures incorporating fine-grained Fe oxides. The fine-grained nature of the Fe oxides was substantiated by M??ssbauer spectroscopy. Our microscopic observations led to the hypothesis that the nodules in the Santa Cruz terrace soils are precipitated by fungi, perhaps as a strategy to sequester primary mineral grains for nutrient extraction. The fungal structures are fixed by the seasonal wetting and dry cycles and rounded through bioturbation. The organic structures are compacted by the degradation of fungal C with time. ?? Soil Science Society of America. All rights reserved.

Soil Science Society of America Journal↗

USGS2026

Complex carbonate ore mineralogy in the Mountain Pass carbonatite rare earth element deposit, USA

Economic concentrations of rare earth element (REE) minerals are uncommon in the Earth’s crust, with most occurring in carbonatites. Unlike most igneous rocks composed of silicate minerals, carbonatites are dominated by carbonate minerals, some of which can incorporate significant light REEs (LREEs; La, Ce, Pr, Nd). Technological applications of REEs are numerous and they have been identified as some of the most critical mineral commodities to the global economy. The Mountain Pass carbonatite stock in the Mojave Desert of California is the most economically significant REE deposit in the USA and contains a few to tens of percent (by volume) of the carbonate REE ore mineral bastnäsite. Despite the economic significance of the Mountain Pass deposit, studies of its ore mineralogy are limited. Here we present new carbonate ore mineralogy data for a compositionally diverse suite of carbonatitic rocks from the Mountain Pass stock and related dikes. Whole-rock geochemical data are integrated with mineral-scale textural and chemical data obtained by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and microRaman spectroscopy. Our results document a complex spectrum of REE-bearing carbonate minerals and intermediate mixed-layer structures. Mineral species include bastnäsite [REE(CO 3 )F], hydroxylbastnäsite [REE(CO 3 )OH], parisite [Ca(REE) 2 (CO 3 ) 3 F 2 ], synchysite [Ca(REE)(CO 3 ) 2 F], röntgenite [Ca 2 (Ce,La) 3 (CO 3 ) 5 F 3 ], and sahamalite [(Mg,Fe 2+ )(REE) 2 (CO 3 ) 4 ]. Carbonate ore mineralogy is heterogeneous within and between samples, including at the intracrystal scale. Complexly zoned crystals exhibit as many as five to six different compositional domains and syntaxial intergrowths, commonly with the more Ca-rich varieties (parisite, synchysite) forming crystal rims that surround relict bastnäsite cores. We attribute the phenocryst variability to changes in the chemistry and temperature of primary carbonatite magmas and evolved/exsolved fluids. Cross-cutting vein textures of calcite, celestine and various REE carbonate minerals, interstitial bastnäsite crystallization, breccia blocks lined by fine-grained bastnäsite, and the presence of hydroxylbastnäsite and partially hydroxylated bastnäsite point to the role of secondary hydrothermal processes in REE mineralization. Fluorcarbonate mineral compositions demonstrate that La and Ce are more structurally abundant in bastnäsite, whereas the more Ca-rich species (parisite, synchysite) contain a greater proportion of REE heavier than Pr (Nd, Sm, Eu, Gd) and Y. Atomic ratios of Pr/(Nd + Pr) are likewise variable, with the highest average value for bastnäsite (0.25) compared to parisite (0.22) and sychysite (0.21). This finding has geometallurgical implications, given that current mining operations are focused on recovery of Nd and Pr for high field strength permanent magnets and the Nd/Pr ratios are a critical factor in ore processing and magnet manufacture.

California↗

USGS2010

Monoclinic tridymite in clast-rich impact melt rock from the Chesapeake Bay impact structure

X-ray diffraction and Raman spectroscopy confirm a rare terrestrial occurrence of monoclinic tridymite in clast-rich impact melt rock from the Eyreville B drill core in the Chesapeake Bay impact structure. The monoclinic tridymite occurs with quartz paramorphs after tridymite and K-feldspar in a microcrystalline groundmass of devitrified glass and Fe-rich smectite. Electron-microprobe analyses revealed that the tridymite and quartz paramorphs after tridymite contain different amounts of chemical impurities. Inspection by SEM showed that the tridymite crystal surfaces are smooth, whereas the quartz paramorphs contain irregular tabular voids. These voids may represent microporosity formed by volume decrease in the presence of fluid during transformation from tridymite to quartz, or skeletal growth in the original tridymite. Cristobalite locally rims spherulites within the same drill core interval. The occurrences of tridymite and cristobalite appear to be restricted to the thickest clast-rich impact melt body in the core at 1402.02–1407.49 m depth. Their formation and preservation in an alkali-rich, high-silica melt rock suggest initially high temperatures followed by rapid cooling.

American Mineralogist↗

USGS2015

Asteroid photometry

Asteroid photometry has three major applications: providing clues about asteroid surface physical properties and compositions, facilitating photometric corrections, and helping design and plan ground-based and spacecraft observations. The most significant advances in asteroid photometry in the past decade were driven by spacecraft observations that collected spatially resolved imaging and spectroscopy data. In the mean time, laboratory measurements and theoretical developments are revealing controversies regarding the physical interpretations of models and model parameter values. We will review the new developments in asteroid photometry that have occurred over the past decade in the three complementary areas of observations, laboratory work, and theory. Finally we will summarize and discuss the implications of recent findings.

Book chapter↗

USGS2005

Acute toxicity of resmethrin, malathion and methoprene to larval and juvenile American lobsters ( Homarus amemcanus ) and analysis of pesticide levels in surface waters after Scourge™, Anvil™ and Altsoid™ application

Acute toxicity and immune response, combined with temperature stress effects, were evaluated in larval and juvenile American lobsters ( Homarus americanus ) exposed to malathion, resmethrin and methoprene. These pesticides were used to control West Nile virus in New York in 1999, the same year the American lobster population collapsed in western Long Island Sound (LIS). Whereas the suite of pesticides used for mosquito control changed in subsequent years, a field study was also conducted to determine pesticide concentrations in surface waters on Long Island and in LIS after operational applications. The commercial formulations used in 2002 and 2003—Scourge, Anvil and Altosid—contain the active ingredients resmethrin, sumithrin and methoprene, respectively. Concentrations of the synergist piperonyl butoxide (PBO) were also measured as a proxy for pesticide exposure. Acute mortality in Stage I-II larval lobsters demonstrated that they are extremely sensitive to continuous resmethrin exposure. Resmethrin LC50s for larval lobsters determined under flow-through conditions varied from 0.26–0.95 μg L −1 in 48- and 96-h experiments at 16°C, respectively. Increased temperature (24°C) did not significantly alter resmethrin toxicity. Malathion and methoprene were less toxic than resmethrin. The 48-h LC50 for malathion was 3.7 μg L −1 and methoprene showed no toxicity at the highest (10 μg L −1 ) concentration tested. Phenoloxidase activity was used as a measure of immune response for juvenile lobsters exposed to sublethal pesticide concentrations. In continuous exposures to sublethal doses of resmethrin (0.03 μg L −1 ) or malathion (1 μg L −1 ) for 7 d at 16 or 22°C, temperature had a significant effect on phenoloxidase activity ( P ≤ 0.006) whereas pesticide exposure did not ( P = 0.880). The analytical methods developed using high performance liquid chromatography coupled to time-of-flight mass spectroscopy (LC-TOF-MS) provided high sensitivity with mass detection limits of 0.1–0.3 ng L −1 . Pesticide levels were often detected in the ng L −1 range in Long Island surface waters and western LIS (except in open waters), but rarely at concentrations found to be toxic in flow-through laboratory exposures, even immediately after spray events.

Journal of Shellfish Research↗