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Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

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At least 523 records · Page 29Linked to original sources
USGS1988

Linear solvation energy relationships for toxicity of selected organic chemicals to Daphnia pulex and Daphnia magna

In the Laurentian Great Lakes, more than 300 contaminants have been identified in fish, other biota, water, and sediment. Current hazard assessment of these chemicals by the National Fisheries Research Center-Great Lakes is based on their toxicity, occurrence in the environment, and source. Although scientists at the Center have tested over 70 chemicals with the crustacean Daphnia pulex , the number of experimental data needed to screen the huge array of chemicals in the Great Lakes exceeds the practical capabilities of conducting bioassays. This limitation can be partly circumvented, however, by using mathematical models based on quantitative structure-activity relationships (QSAR) to provide rapid, inexpensive estimates of toxicity. Many properties of chemicals, including toxicity, bioaccumulation and water solubility are well correlated and can be predicted by equations of the generalized linear solvation energy relationships (LSER). The equation we used to model solute toxicity is Toxicity = constant + m VI/100 + s (π* + dδ) + b βm + a αm where VI = intrinsic (Van der Waals) molar volume; π* = molecular dipolarity/polarizability; δ = polarizability 'correction term'; βm = solute hydrogen bond acceptor basicity; and αm = solute hydrogen bond donor acidity. The subscript m designates solute monomer values for α and β. We applied the LSER model to 48-h acute toxicity data (measured as immobilization) for six classes of chemicals detected in Great Lakes fish. The following regression was obtained for Daphnia pulex (concentration = μM): log EC50 = 4.86 - 4.35 VI/100; N = 38, r2 = 0.867, sd = 0.403 We also used the LSER modeling approach to analyze to a large published data set of 24-h acute toxicity for Daphnia magna ; the following regression resulted, for eight classes of compounds (concentration = mM): log EC50 = 3.88 - 4.52 VI/100 - 1.62 π* + 1.66 βm - 0.916 αm; N = 62, r2 = 0.859, sd = 0.375 In addition we developed computer software that identifies chemical structures, estimates the LSER parameters, and predicts toxicity. The LSER models promise to be effective in differentiating between reactive and nonreactive toxicity behavior where other models have failed. Contaminants with reactive behavior are generally the most toxic and rank highest in hazard assessment of environmental chemicals.

Proceedings of the QSAR↗
USGS1993

Holocene sedimentation and coastal wetlands response to rising sea level at the Aucilla river mouth, a low energy coast in the Big Bend area of Florida

The shallow dip of the Florida carbonate platform results in low wave energy on Florida ???Big Bend??? coasts. Therefore sedimentation is dominated by river-and tidal-hydrodynamics near the Aucilla River mouth. Where present, Holocene sediments are thin and unconformably overlie Oligocene-aged Suwannee Limestone. The oldest unlithified sediments include reworked carbonate rubble with clay and wood fragments (seven thousand years old or less, based on wood radio-carbon dating). Although this basal sequence is observed in most areas, the sediments that overlie it vary. Sediment sequences from the outer littoral to submarine environments include organic-rich sands, oyster biotherm remains, and cleaner sands with organic-filled burrows. Inner littoral (salt-marsh) sequences generally consist of sandy, fining-upwards sequences in which dry weights of fine-grained clastics and organic components increase up-sequence at similar rates. Offshore sediments preserve greatly attenuated fluvial and salt-marsh facies, if these facies are preserved at all. With sea-level rise, erosion can result from insufficient sediment supply and down-cutting by tidal currents (Dolotov, 1992; and Dalrymple et al., 1992). Dolotov (1992) attributes displacement of original coastal stratigraphy to insufficient sediments for beach profile maintenance, while Dalrymple et al. (1992) attribute erosional truncation (ravinement) or complete removal of portions of typical estuarine sequences to headward migration of tidal channels.

Conference Paper↗
USGS2003

Linking Proxy-Based and Datum-Based Shorelines on a High-Energy Coastline: Implications for Shoreline Change Analyses

A primary purpose of this paper is to quantitatively link variously defined and derived shoreline estimates commonly used for shoreline change analysis. Estimates of shoreline mapping and derivation error, natural shoreline variability, and the relationships between horizontally-derived (proxy-based) shorelines to vertical datums (e.g. MHW) are presented. A series of shoreline repeatability and variability experiments as well as data from a beach monitoring program along the high-energy US Pacific Northwest coast, indicate total uncertainty estimates of the horizontal position of proxy-based shorelines to be approximately ?? 50-150 m for T-sheets and aerial photography and approximately ?? 15 m for datum-based shorelines derived from ground- or air-based topographic surveys. The ability to obtain reliable shoreline change results depends upon both the selected shoreline definition (e.g. horizontal- or feature-based proxy, or datum-based intercept) and the accuracy of the technique used in mapping or interpreting its position. The position of the selected shoreline on the beach profile determines its inherent temporal and spatial variability, an important consideration that has often been overlooked in the scientific literature on shoreline change, Historical shorelines mapped on NOS T-sheets and aerial photos have commonly identified high water line (HWL)-type shorelines, which are shown to be higher on the beach surface than the MHW-datum intercept along coasts subject to wave runup. Analyses of 4.5 years of beach profile data from the southwest Washington coast suggest that both the MHW and HWL-type shorelines have greater natural short-term variability than expected, significantly greater than the variability of shoreline proxies defined farther landward and higher on the beach profile. A model for determining the natural variability of HWL-type shorelines reveals that this short-term variability is the dominant factor in the large total uncertainty values associated with shorelines derived from T-sheets and aerial photographs. The results of these analyses and quantitative comparisons are relevant to determining the significance of historical shoreline changes, as well as to defining the appropriate shoreline proxy or datum and time scale for future shoreline change analysis.

Conference Paper↗
USGS2009

Coalbed methane: Clean energy for the world

Coalbed methane (CBM) has the potential to emerge as a significant clean energy resource. It also has the potential to replace other diminishing hydrocarbon reserves. The latest developments in technologies and methodologies are playing a key role in harnessing this unconventional resource. Some of these developments include adaptations of existing technologies used in conventional oil and gas generations, while others include new applications designed specifically to address coal's unique properties. Completion techniques have been developed that cause less damage to the production mechanisms of coal seams, such as those occurring during cementing operations. Stimulation fluids have also been engineered specifically to enhance CBM production. Deep coal deposits that remain inaccessible by conventional mining operations offer CBM development opportunities.

Oilfield Review↗
USGS2009

Monitoring and modeling shoreline response due to shoreface nourishment on a high-energy coast

Shoreface nourishment can be an efficient technique to feed sediment into the littoral zone without the order of magnitude cost increase incurred by directly nourishing the beach. An erosion hot spot at Ocean Beach in San Francisco, California, USA, threatens valuable public infrastructure as well as safe recreational use of the beach. In an effort to reduce the erosion at this location, a new beneficial reuse plan was implemented in May 2005 for the sediment dredged annually from the main shipping channel at the mouth of San Francisco Bay. From 2005 to 2007, approximately 230,000 m of sand was placed annually at depths between 9 and 14 m, in a location where strong tidal currents and open-ocean waves could potentially feed sediment onto the section of beach experiencing critical erosion. The evolution of the disposal mound and adjacent beach were monitored with 12 multibeam bathymetric surveys, and over 40 high-resolution beach topographic surveys. In addition, sediment transport processes were investigated using sediment grab samples, acoustic Doppler profilers, and two separate models: a cross-shore profile model (UNIBEST-TC) and a coastal area model (Delft3D). The results of the monitoring and modeling demonstrate that the disposal mound may be effective in dissipating wave energy striking this vulnerable stretch of coast with negligible shadowing effects, but a positive shoreline response can only be achieved by placing the sediment in water depths less than 5 m.

California↗
USGS2014

Nest site characteristics, nesting movements, and lack of long-term nest site fidelity in Agassiz's desert tortoises at a wind energy facility in southern California

Nest site selection has important consequences for maternal and offspring survival and fitness. Females of some species return to the same nesting areas year after year. We studied nest site characteristics, fidelity, and daily pre-nesting movements in a population of Agassiz’s desert tortoises (Gopherus agassizii) at a wind energy facility in southern California during two field seasons separated by over a decade. No females returned to the same exact nest site within or between years but several nested in the same general area. However, distances between first and second clutches within a year (2000) were not significantly different from distances between nests among years (2000 and 2011) for a small sample of females, suggesting some degree of fidelity within their normal activity areas. Environmental attributes of nest sites did not differ significantly among females but did among years due largely to changes in perennial plant structure as a result of multiple fires. Daily pre-nesting distances moved by females decreased consistently from the time shelled eggs were first visible in X-radiographs until oviposition, again suggesting some degree of nest site selection. Tortoises appear to select nest sites that are within their long-term activity areas, inside the climate-moderated confines of one of their self-constructed burrows, and specifically, at a depth in the burrow that minimizes exposure of eggs and embryos to lethal incubation temperatures. Nesting in “climate-controlled” burrows and nest guarding by females relaxes some of the constraints that drive nest site selection in other oviparous species.

California↗
USGS2011

Energy and conservation benefits from managed prairie biomass

Marginally productive land, such as that enrolled in the Conservation Reserve Program (CRP), may provide acreage and economic incentives for cellulosic energy production. Improving the yields from these lands will help establish a biomass producer's position in the marketplace. The effects of water and nitrogen on biomass yields were investigated in both a plot-scale experiment and a broad-scale survey of CRP lands. The plot-scale experiment demonstrated that irrigation improved mixed-species prairie biomass yields more than nitrogen fertilizer on coarse-textured, marginally productive soils. Experimental plots amended with both irrigation and moderate (but not high) nitrogen produced more biomass than other treatment combinations, but this trend was not statistically significant. The survey of biomass yields on CRP lands across four Midwestern States indicates that yields are better correlated with June rainfall than any other individual month. Applying nutrient-enriched water such as agricultural runoff could benefit prairie yields if applied at appropriate times.

Conference Paper↗
USGS2010

Supply of and demand for selected energy related mineral commodities

In this report, subjects discussed include components of mineral supply, production, and consumption data, and information on selected mineral commodities in which the Energy Critical Elements Study Group has an interest, and U.S. Geological Survey (USGS) recycling studies, with some results of these studies.

Conference Paper↗
USGS1996

Linear solvation energy relationships (LSER): 'rules of thumb' for V i /100, π * , Β m , and α m estimation and use in aquatic toxicology

This chapter provides a listing of the increasing variety of organic moieties and heteroatom group for which Linear Solvation Energy Relationship (LSER) values are available, and the LSER variable estimation rules. The listings include values for typical nitrogen-, sulfur- and phosphorus-containing moieties, and general organosilicon and organotin groups. The contributions by an ion pair situation to the LSER values are also offered in Table 1, allowing estimation of parameters for salts and zwitterions. The guidelines permit quick estimation of values for the four primary LSER variables V i /100, π * , Β m , and α m by summing the contribtuions from its components. The use of guidelines and Table 1 significantly simplifies computation of values for the LSER variables for most possible organic comppounds in the environment, including the larger compounds of environmental and biological interest.

Book chapter↗
USGS2006

An overview of the global variability in radiated energy and apparent stress

a global study of radiated seismic energies ER and apparent stresses τ a reveals systematic patterns. earthquakes with the highest apparent stress occur in regions of intense deformation and rupture strong lithosphere. in oceanic settings, these are strike-slip earthquakes (τ a up to 27 Mpa) occurring intraplate or at evolving ends of transform faults. at subduction zones and intracontinental settings, these are strike slip earthquakes with τ a up to 7 Mpa. normal-fault earthquakes exhibit a more complex pattern. higher τ a ’s (up to5Mpa) are found for intraslab events at depths from 35 to 70 km that occur near zones of intense deformation such as a sharp slab bend or the juncture of colliding slabs. lower τ a ’s (< 1 Mpa) are found for normal-fault earthquakes at the outer rise and outer trench wall or deep in flat warm slabs. the lowest average τ a (0.3 Mpa) is found for thrust-fault earthquakes at subduction zones. the variation of average apparent stress with tectonics suggests a relationship with lithospheric strength and fault maturity. Mature faults, such as plate boundaries that have experienced large cumulative slip, appear to have low strength and tend to yield earthquakes with low apparent stresses. immature faults, in contrast, are stronger and yield high apparent stresses because either they are the result of fresh-rock fracture or at least their cumulative fault slip is quite small. these results have implications of use to the seismic engineering community because ER and its magnitude counterpart Me are reliable indicators of the potential for damaging ground motion.

Book chapter↗
USGS2007

Reducing energy-related CO 2 emissions using accelerated weathering of limestone

The use and impacts of accelerated weathering of limestone (AWL; reaction: CO 2 +H 2 O+CaCO 3 →Ca 2+ +2(HCO 3 - ) is explored as a CO 2 capture and sequestration method. It is shown that significant limestone resources are relatively close to a majority of CO 2 -emitting power plants along the coastal US, a favored siting location for AWL. Waste fines, representing more than 20% of current US crushed limestone production (>10 9 tonnes/yr), could provide an inexpensive or free source of AWL carbonate. With limestone transportation then as the dominant cost variable, CO 2 mitigation costs of $3-$4/tonne appear to be possible in certain locations. Perhaps 10–20% of US point–source CO 2 emissions could be mitigated in this fashion. It is experimentally shown that CO 2 sequestration rates of 10 -6 to 10 -5 moles/sec per m 2 of limestone surface area are achievable, with reaction densities on the order of 10 -2 tonnes CO 2 m -3 day -1 , highly dependent on limestone particle size, solution turbulence and flow, and CO 2 concentration. Modeling shows that AWL would allow carbon storage in the ocean with significantly reduced impacts to seawater pH relative to direct CO 2 disposal into the atmosphere or sea. The addition of AWL-derived alkalinity to the ocean may itself be beneficial for marine biota.

Energy↗
USGS2022

Assessing vegetation recovery from energy development using a dynamic reference approach

Ecologically relevant references are useful for evaluating ecosystem recovery, but references that are temporally static may be less useful when environmental conditions and disturbances are spatially and temporally heterogeneous. This challenge is particularly acute for ecosystems dominated by sagebrush ( Artemisia spp.), where communities may require decades to recover from disturbance. We demonstrated application of a dynamic reference approach to studying sagebrush recovery using three decades of sagebrush cover estimates from remote sensing (1985–2018). We modelled recovery on former oil and gas well pads ( n = 1200) across southwestern Wyoming, USA, relative to paired references identified by the Disturbance Automated Reference Toolset. We also used quantile regression to account for unmodelled heterogeneity in recovery, and projected recovery from similar disturbance across the landscape. Responses to weather and site-level factors often differed among quantiles, and sagebrush recovery on former well pads increased more when paired reference sites had greater sagebrush cover. Little (<5%) of the landscape was projected to recover within 100 years for low to mid quantiles, and recovery often occurred at higher elevations with cool and moist annual conditions. Conversely, 48%–78% of the landscape recovered quickly (within 25 years) for high quantiles of sagebrush cover. Our study demonstrates advantages of using dynamic reference sites when studying vegetation recovery, as well as how additional inferences obtained from quantile regression can inform management.

Wyoming↗
USGS2026

Beach nourishment morphodynamics in a high-energy U.S. West Coast environment

Dredged sediment from engineered inlets can be used to nourish coastlines adjacent to these inlets, serving as a beneficial alternative to offshore disposal. Effective strategies for beneficial use of dredged sediment, however, rely on understanding of local sediment transport. A beach nourishment project utilizing dredged sand was carried out at a highly energetic beach north of the Columbia River mouth (Washington, USA). Within two weeks of placement, during a moderately energetic period, a large part of the beach nourishment had eroded. To predict local hydro- and morphodynamics there, a XBeach model was used, validated with field observations of nearshore hydrodynamics and morphology. It showed that while the subaerial nourishment eroded rapidly, it is likely that the sediment is deposited around the inner bar and is still available to the morphological system of Benson Beach. Additionally, model simulations suggest the nourishment provided a buffer against erosion of the local dune system during its presence.

Washington↗