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At least 523 records · Page 29Linked to original sources
USGS1970

Emission spectrographic determination of trace elements in lunar samples

Eighteen minor or trace elements were detected and determined by emission spectroscopy. Direct d-c arc excitation of powdered samples was used with three variations in the procedure. Thirteen lunar samples consisting of four fine-grained igneous rocks, one medium-grained igneous rock, seven breccias, and one sample of fines were analyzed. The zinc and nickel concentrations in the breccias were approximately one order of magnitude greater than the concentrations of these elements in igneous rocks.

Science↗
USGS2020

Estimating the contribution of tributary sand inputs to controlled flood deposits for sandbar restoration using elemental tracers, Colorado River, Grand Canyon National Park, Arizona

Completion of Glen Canyon Dam in 1963 resulted in complete elimination of sediment delivery from the upstream Colorado River basin to Grand Canyon and nearly complete control of spring snowmelt floods responsible for creating channel and bar morphology. Management of the river ecosystem in Grand Canyon National Park now relies on dam-release floods to redistribute tributary-derived sediment accumulated on the channel bed to higher-elevation sandbars. Here, we used multivariate mixing analysis of sediment elemental compositions to evaluate the extent to which flood deposits derive from tributary-supplied sand compared to reworked, relict predam sediment. The concentrations of seven major and trace elements (Fe, Ca, K, Ti, Rb, Sr, and Zr) were measured in very fine−, fine-, and medium-grained sand from flood deposits using X-ray fluorescence and interpreted using a Bayesian mixing model to characterize the proportion of sand originating from the Paria River, the only major tributary within the study reach. Flood deposits from the 2013 and 2014 controlled floods contained 69% ± 16% and 84% ± 20% Paria River−derived material, respectively, with substantial variation among sites. Based on a sand mass balance, we calculated that under decreasing storage conditions since 1963, ∼77%−83% of the annual Paria River sand flux needs to be retained within the mass of active sand stored in Marble Canyon each year to reach the observed concentration of Paria River sand at sample locations. This finding suggests that the use of controlled floods may continue to be effective for sandbar maintenance, provided sand inputs from the Paria River do not decline.

Arizona↗
USGS2007

Trace element chemistry of zircons from oceanic crust: A method for distinguishing detrital zircon provenance

We present newly acquired trace element compositions for more than 300 zircon grains in 36 gabbros formed at the slow-spreading Mid-Atlantic and Southwest Indian Ridges. Rare earth element patterns for zircon from modern oceanic crust completely overlap with those for zircon crystallized in continental granitoids. However, plots of U versus Yb and U/Yb versus Hf or Y discriminate zircons crystallized in oceanic crust from continental zircon, and provide a relatively robust method for distinguishing zircons from these environments. Approximately 80% of the modern ocean crust zircons are distinct from the field defined by more than 1700 continental zircons from Archean and Phanerozoic samples. These discrimination diagrams provide a new tool for fingerprinting ocean crust zircons derived from reservoirs like that of modern mid-ocean ridge basalt (MORB) in both modern and ancient detrital zircon populations. Hadean detrital zircons previously reported from the Acasta Gneiss, Canada, and the Narryer Gneiss terrane, Western Australia, plot in the continental granitoid field, supporting hypotheses that at least some Hadean detrital zircons crystallized in continental crust forming magmas and not from a reservoir like modern MORB. ?? 2007 The Geological Society of America.

Geology↗
USGS2008

Trace elements in hydrothermal quartz: Relationships to cathodoluminescent textures and insights into vein formation

High-resolution electron microprobe maps show the distribution of Ti, Al, Ca, K, and Fe among quartz growth zones revealed by scanning electron microscope-cathodoluminescence (SEM-CL) from 12 hydrothermal ore deposits formed between ???100 and e1750 ??C. The maps clearly show the relationships between trace elements and CL intensity in quartz. Among all samples, no single trace element consistently correlates with variations in CL intensity. However in vein quartz from five porphyry-Cu (Mo-Au) deposits, CL intensity always correlates positively with Ti concentrations, suggesting that Ti is a CL activator in quartz formed at >400 ??C. Ti concentrations in most rutile-bearing vein quartz from porphyry copper deposits indicate reasonable formation temperatures of <750 ??C using the TitaniQ geothermometer. Titanium concentrations of <10 ppm in all veins that formed at temperatures <350 ??C suggest broad correlation between Ti concentrations and temperature of quartz precipitation. In quartz from most deposits formed at <350 ??C, bimodal Al concentrations exist wherein some growth bands contain <50 ppm and others contain >2000 ppm, but in high-temperature quartz, Al concentrations are consistently in the range of several hundred ppm. Aluminum concentrations in quartz refl ect the Al solubility in hydrothermal fluids, which is strongly dependent on pH. Aluminum concentrations in quartz therefore reflect fluctuations in pH that may drive metal-sulfide precipitation in hydrothermal systems. ?? 2008 The Geological Society of America.

Geology↗
USGS2026

Zircon petrochronology fingerprints mantle sources of magmatic rare earth element deposits

The mantle sources of carbonatite and alkaline magmatic systems that host rare earth element (REE) deposits are difficult to constrain because whole-rock compositions are commonly altered. Alteration-resistant zircon trace-element compositions are used to fingerprint mantle sources at Mountain Pass, California, the largest REE deposit in the United States, and extend this approach to a global carbonatite−alkaline rock dataset. Autocrystic zircon samples from the Mountain Pass intrusive suite record subduction-like U-Sc-Nb-Yb compositions, oxidized fO2 (0.8−2.4 relative to fayalite-magnetite-quartz buffer [ΔFMQ]), and Ti-in-zircon temperatures up to ∼970 °C, indicating a lithospheric mantle source enriched and oxidized by Paleoproterozoic subduction and subsequently tapped during Mesoproterozoic postcollisional lithospheric thinning. This contrasts with the ocean island basalt−like enriched mantle recorded by Mesoproterozoic zircon from the Bayan Obo carbonatite complex, China, demonstrating that world-class REE deposits of comparable age can reflect fundamentally different mantle sources. New classifiers separate subduction-metasomatized from non-subduction-enriched mantle domains with ∼90% accuracy, providing a zircon-based tool for fingerprinting the mantle source regions of magmatic REE deposits.

Geology↗
USGS1955

Estimates of the abundances of some chemical elements and their reliability

During the past thirty years the development of improved methods of analysis, especially optical spectrography, x-ray spectrography, and colorimetric methods, has resulted in a wealth of new data on the abundances of many elements. Nevertheless, present estimates differ greatly in reliability; some, such as the estimate for bismuth, are based on very few actual determinations, whereas others, such as that for gallium, are based on analyses of many samples. This paper reviews the estimates of abundance for the elements bismuth, germanium, gallium, and yttrium, taken as examples to illustrate the wide variation in reliability. For gallium and yttrium, a study has been made of spectrographic analyses by four laboratories of more than 600 chemically analyzed rocks from many areas of the world. Comparison shows that these furnish valuable data on abundance, although attention must be directed to regional variation. The comparison also shows the need for continued interlaboratory standardization. The estimate for bismuth is based on so few determinations that no appraisal of its accuracy can be made. The estimate for germanium is based on very few determinations but is almost certainly of the right order of magnitude, though perhaps slightly too high. The estimates for gallium and yttrium, based on many determinations, are almost certainly of the right order of magnitude, though that for gallium may be slightly low and that for yttrium may be substantially low.

GSA Special Papers↗
USGS1999

Trace-element geochemistry of metabasaltic rocks from the Yukon-Tanana Upland and implications for the origin of tectonic assemblages in east-central Alaska

We present major- and trace- element geochemical data for 27 amphibolites and six greenstones from three structural packages in the Yukon-Tanana Upland of east-central Alaska: the Lake George assemblage (LG) of Devono-Mississippian augen gneiss, quartz-mica schist, quartzite, and amphibolite; the Taylor Mountain assemblage (TM) of mafic schist and gneiss, marble, quartzite, and metachert; and the Seventymile terrane of greenstone, serpentinized peridotite, and Mississippian to Late Triassic metasedimentary rocks. Most LG amphibolites have relatively high Nb, TiO2, Zr, and light rare earth element contents, indicative of an alkalic to tholeiitic, within-plate basalt origin. The within-plate affinities of the LG amphibolites suggest that their basaltic parent magmas developed in an extensional setting and support a correlation of these metamorphosed continental-margin rocks with less metamorphosed counterparts across the Tintina fault in the Selwyn Basin of the Canadian Cordillera. TM amphibolites have a tholeiitic or calc-alkalic composition, low normalized abundances of Nb and Ta relative to Th and La, and Ti/V values of <20, all indicative of a volcanic-arc origin. Limited results from Seventymile greenstones indicate a tholeiitic or calc-alkalic composition and intermediate to high Ti/V values (27-48), consistent with either a within-plate or an ocean-floor basalt origin. Y-La-Nb proportions in both TM and Seventymile metabasalts indicate the proximity of the arc and marginal basin to continental crust. The arc geochemistry of TM amphibolites is consistent with a model in which the TM assemblage includes arc rocks generated above a west-dipping subduction zone outboard of the North American continental margin in mid-Paleozoic through Triassic time. The ocean-floor or within-plate basalt geochemistry of the Seventymile greenstones supports the correlation of the Seventymile terrane with the Slide Mountain terrane in Canada and the hypothesis that these oceanic rocks originated in a basin between the continental margin and an arc to the west.

Alaska↗
USGS2013

Atomic weights of the elements 2011 (IUPAC Technical Report)

The biennial review of atomic-weight determinations and other cognate data has resulted in changes for the standard atomic weights of five elements. The atomic weight of bromine has changed from 79.904(1) to the interval [79.901, 79.907], germanium from 72.63(1) to 72.630(8), indium from 114.818(3) to 114.818(1), magnesium from 24.3050(6) to the interval [24.304, 24.307], and mercury from 200.59(2) to 200.592(3). For bromine and magnesium, assignment of intervals for the new standard atomic weights reflects the common occurrence of variations in the atomic weights of those elements in normal terrestrial materials.

Pure and Applied Chemistry↗
USGS2009

Atomic weights of the elements 1999

The biennial review of atomic-weight, Ar(E), determinations and other cognate data have resulted in changes for the standard atomic weights of the following elements: Presented are updated tables of the standard atomic weights and their uncertainties estimated by combining experimental uncertainties and terrestrial variabilities. In addition, this report again contains an updated table of relative atomic-mass values and half-lives of selected radioisotopes. Changes in the evaluated isotopic abundance values from those published in 1997 are so minor that an updated list will not be published for the year 1999. Many elements have a different isotopic composition in some nonterrestrial materials. Some recent data on parent nuclides that might affect isotopic abundances or atomic-weight values are included in this report for the information of the interested scientific community.

Pure and Applied Chemistry↗
USGS1996

Discrimination among spawning concentrations of Lake Superior lake herring based on trace element profiles in sagittae

Little is known about the stock structure of lake herring Coregonus artedi in Lake Superior, and recent increases in harvestable stock sizes has led to expanded exploitation in some areas. Research on marine teleosts has demonstrated that chemical differences in sagittal otoliths can be used for identification of fish stocks. We used plasma emission spectrophotometry to measure the concentrations of 10 trace elements in the sagittal otoliths from lake herring captured at eight spawning sites in Lake Superior and from Little Star Lake. an inland lake outside the Lake Superior basin. Discriminant function analysis indicated that elemental concentrations provided site‐specific information but that considerable overlap existed among some locations, especially those in western Lake Superior. Correct classification rates varied from 12.0% to 86.1% and were generally higher for spawning locations from embayments in eastern Lake Superior and for the outgroup population from Little Star Lake. The results presented here demonstrate the potential usefulness of this technique for strictly freshwater species, especially those that live in highly oligotrophic waters such as Lake Superior.

Lake Superior, Little Star Lake↗
USGS2000

Invertebrate assemblages and trace element bioaccumulation associated with constructed wetlands

Invertebrate assemblages were studied in eight monoculture wetland mesocosms constructed for wastewater treatment. Low concentrations of dissolved oxygen (D.O.) were measured in bulrush mesocosms while higher concentrations of D.O. were measured in open water mesocosms containing submerged pondweeds. Invertebrate taxa richness was positively related to D.O. concentrations that were, in turn, related to vegetation communities. Reference wetland sites contained a variety of plant species along with extensive open water areas. Invertebrate taxa richness was greater at reference sites than in any wastewater mesocosm. Invertebrate samples from the wastewater mesocosms and reference sites were analyzed for five trace elements. While the concentrations of aluminum, arsenic, mercury, and silver were below values harmful to wildlife, the concentrations of selenium reached levels of moderate concern on one occasion. Data from this study suggest that selenium bioaccumulation by invertebrates may be related to the type of vegetation community or detrital habitat type. Wetlands designed for invertebrate production for waterfowl should take into account the potential for low D.O. concentrations and trace element bioaccumulation associated with vegetation community types.

Wetlands↗
USGS2007

Effects of mother lode-type gold mineralization on 187Os/188Os and platinum group element concentrations in peridotite: Alleghany District, California

Osmium isotope compositions and concentrations of Re, platinum group elements (PGE), and Au were determined for host peridotites (serpentinites and barzburgites) and hydrothermally altered ultramafic wall rocks associated with Mother Lode-type hydrothermal gold-quartz vein mineralization in the Alleghany district, California. The host peridotites have Os isotope compositions and Re, PGE, and Au abundances typical of the upper mantle at their presumed formation age during the late Proterozoic or early Paleozoic. The hydrothermally altered rocks have highly variable initial Os isotope compositions with ??os, values (% deviation of 187OS/188OS from the chondritic average calculated for the approx. 120 Ma time of mineralization) ranging from -1.4 to -8.3. The lowest Os isotope compositions are consistent with Re depletion of a chondritic source (e.g., the upper mantle) at ca. 1.6 Ga. Most of the altered samples are enriched in Au and have depleted and fractionated abundances of Re and PGE relative to their precursor peridotites. Geoehemical characteristics of the altered samples suggest that Re and some PGE were variably removed from the ultramafic rocks during the mineralization event. In addition to Re, the Pt and Pd abundances of the most intensely altered rocks appear to have been most affected by mineralization. The 187Os-depleted isotopic compositions of some altered rocks are interpreted to be a result of preferential 187Os loss via destruction of Re-rich phases during the event. For these rocks, Os evidently is not a useful tracer of the mineralizing fluids. The results do, however, provide evidence for differential mobility of these elements, and mobility of 187Os relative to the initial bulk Os isotope composition during hydrothermal metasomatic alteration of ultramafic rocks. ?? 2007 Society of Economic Geologists, Inc.

Economic Geology↗
USGS2009

Gold and trace element zonation in pyrite using a laser imaging technique: Implications for the timing of gold in orogenic and carlin-style sediment-hosted deposits

Laser ablation ICP-MS imaging of gold and other trace elements in pyrite from four different sediment- hosted gold-arsenic deposits has revealed two distinct episodes of gold enrichment in each deposit: an early synsedimentary stage where invisible gold is concentrated in arsenian diagenetic pyrite along with other trace elements, in particular, As, Ni, Pb, Zn, Ag, Mo, Te, V, and Se; and a later hydrothermal stage where gold forms as either free gold grains in cracks in overgrowth metamorphic and/or hydrothermal pyrite or as narrow gold- arsenic rims on the outermost parts of the overgrowth hydrothermal pyrite. Compared to the diagenetic pyrites, the hydrothermal pyrites are commonly depleted in Ni, V, Zn, Pb, and Ag with cyclic zones of Co, Ni, and As concentration. The outermost hydrothermal pyrite rims are either As-Au rich, as in moderate- to high- grade deposits such as Carlin and Bendigo, or Co-Ni rich and As-Au poor as in moderate- to low-grade deposits such as Sukhoi Log and Spanish Mountain. The early enrichment of gold in arsenic-bearing syngenetic to diagenetic pyrite, within black shale facies of sedimentary basins, is proposed as a critical requirement for the later development of Carlin-style and orogenic gold deposits in sedimentary environments. The best grade sediment-hosted deposits appear to have the gold climax event, toward the final stages of deformation-related hydrothermal pyrite growth and fluid flow. ?? 2009 Society of Economic Geologists, Inc.

Economic Geology↗
USGS1952

Minor elements in Arkansas bauxite

A study of the minor elements in Arkansas bauxite has revealed some striking relationships between their concentration in the parent nepheline syenite rocks as compared with their concentration in the bauxite . The ratios of concentration, in general, follow a pattern predicted by Gold-schmidt (3),2 based upon the ionic radius and ionic charge of each element present. In the Arkansas deposits, Mg, Ca, Ba, La, and Sr were depleted during the change from nepheline syenite to bauxite . The average concentration of Pb remained the same in the samples tested. Y, Mn, Be, V, Sc, Ti, and Zr were concentrated, but not as much as Al; while Mo, Nb (Cb), Ga, Cu, and Cr were concentrated more than Al.' Niobium (columbium) apparently is found in sufficient quantities to warrant search for methods to extract it commercially as a by-product of alumina plants.

Arkansas↗
USGS1955

Comments on minor elements in pyrrhotite [Idaho]

The cobalt and nickel content of pyrrhotite from the Highland-Surprise mine, Coeur d'Alene district, Idaho, was determined by spectrographic methods. The Co and Ni values fall within the ranges of values found by other investigators. Comparison of the distribution of Co and Ni in the Highland-Surprise ore shoot with the distribution of these elements in the Silberberges, Germany, and Noranda, Canada, ore shoots suggests that caution must be used in the determination of relative temperature conditions in ore shoots by means of studies of minor elements, principally because it seems likely that equilibrium concentrations are commonly absent.

Idaho↗
USGS1997

Element distribution patterns in the ordovician Galena group, Southeastern Minnesota: Indicators of fluid flow and provenance of terrigenous material

As part of a regional geochemical investigation of lower Paleozoic strata in the Hollandale embayment of southeastern Minnesota, elemental concentrations in acid-insoluble residues were determined for carbonate rock in the Middle Ordovician Galena Group. Elemental distribution patterns within the insoluble residues, particularly those of Ti, Al, and Zr, show that the Wisconsin dome and the Wisconsin arch, which contributed sediment to the embayment prior to Galena time, continued as weak sources of sediment during this period. In contrast, trace metals commonly associated with Mississippi Valley-type lead-zinc mineralization, including Pb, Zn, Cu, Ag, Ni, Co, As, and Mo, show dispersal patterns that are independent of those associated with primary depositional phenomena. These trace metals are concentrated in southern Minnesota in carbonate rocks near the interface between limestone- and dolostone-dominated strata. Dispersal patterns imply that the metals were carried by a north-flowing regional ground-water system. The results show that the geochemical attributes of insoluble residues can be used to distinguish provenance and transport directions of primary sediments within a depositional basin from effects of subsequent regional ground-water flow systems.

Economic Geology↗
USGS2019

Rare earth element mineral deposits in the United States

Because of their unique special chemical properties, many of the metals in the group of rare earth elements (REEs) have essential applications in 21st century technologies. Examples of products that use REEs are cell phones, computers, fluorescent and light-emitting-diode lights, flat-screen television and computer monitors, and in high-strength magnets used by clean energy technologies such as the generators of wind turbines and batteries of hybrid and electric vehicles. REEs are used in many defense applications, such as in components of jet engines, missile guidance systems, antimissile defense systems, satellites, and communication systems. The rare earth elements have become vital to manufacturing numerous high-tech products, which has been accompanied by a large increase in their demand. At the same time, there has been concern by the United States and many other Nations about the near-monopoly of mining, processing, and supply of REEs from one Nation, China. Between 2011 and 2017, China produced approximately 84 percent of the world’s REEs, and during this time the United States only produced REEs between 2012 and 2015. The U.S. production came entirely from the Mountain Pass mine in California, providing only about 4 percent of the world REE supply. Because REEs are essential for technological applications and are primarily supplied by one Nation, there has been an increased concern in identifying new sources of REEs, including economic REE deposits. In response to these concerns, since 2009, the U.S. Geological Survey (USGS) has conducted numerous studies focused on the distribution, geology, and potential resources for the REE-bearing mineral deposits in the United States. The basic characteristics of mineral deposit types that host REE enrichments in the United Sates are summarized in this report, with selected examples. Several types of REE-enriched mineral deposits are reviewed, including deposits in carbonatites, alkaline igneous rocks, sedimentary phosphate-rich rocks (phosphorite), regions containing REE-rich veins, iron oxide deposits containing REE-bearing apatite, monazite-xenotime-bearing placer deposits (heavy-mineral sands), and ion-adsorption clay deposits (REE in granite-derived regolith). A better understanding of these mineral deposits will assist in identifying domestic resources to help alleviate the dependence on imported REEs. The economic development of REE mineral deposits is affected by many factors beyond mining, such as commodity prices and mineral processing costs. Most of the REEs are hosted by minerals that have complex chemical formulas; this presents more challenges to process and extract the REEs. Continued advancements and refinements in mineral processing techniques may allow REE deposits with complex mineralogy to be economically developed in the future.

Circular↗
USGS1971

Reconnaissance of selected minor elements in surface waters of the United States, October 1970

A nationwide reconnaissance of selected minor elements in water resources of the 50 States and Puerto Rico was made by the U.S. Geological Survey in cooperation with the U.S. Bureau of Sport Fisheries and Wildlife during autumn, 1970. Initiated in response to the growing need for data on minor elements in water, including toxic metals, the synoptic survey provides an up-to-date baseline of such data largely for dry-weather flows of streams that are sources of municipal and industrial water for the Nation's metropolitan areas.

Circular↗