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USGS2011

Sulfate threshold target to control methylmercury levels in wetland ecosystems

Sulfate contamination has a significant environmental implication through the stimulation of toxic hydrogen sulfide and methylmercury (MeHg) production. High levels of MeHg are a serious problem in many wetland ecosystems worldwide. In the Florida Everglades, it has been demonstrated that increasing MeHg occurrence is due to a sulfate contamination problem. A promising strategy of lowering the MeHg occurrence is to reduce the amount of sulfate entering the ecosystem. High surface water sulfate concentrations in the Everglades are mainly due to discharges from the Everglades Agricultural Area (EAA) canals. Water and total sulfur mass balances indicated that total sulfur released by soil oxidation, Lake Okeechobee and agricultural application were the major sources contributing 49,169, 35,217 and 11,775mtonsyear-1, respectively. Total sulfur loads from groundwater, levees, and atmospheric deposition contributed to a lesser extent: 4055; 5858 and 4229mtonsyear-1, respectively. Total sulfur leaving the EAA into Water Conservation Areas (WCAs) through canal discharge was estimated at 116,360mtonsyear-1, and total sulfur removed by sugarcane harvest accounted for 23,182mtonsyear-1. Furthermore, a rise in the mineral content and pH of the EAA soil over time, suggested that the current rates of sulfur application would increase as the buffer capacity of the soil increases. Therefore, a site specific numeric criterion for sulfate of 1mgL-1 was recommended for the protection of the Everglades; above this level, mercury methylation is enhanced. In parallel, sulfide concentrations in the EAA exceeded the 2??gL-1 criterion for surface water already established by the U.S. Environmental Protection Agency (EPA). ?? 2011 Elsevier B.V.

Science of the Total Environment↗

USGS2025

Landsliding follows signatures of wildfire history and vegetative regrowth in a steep coastal shrubland

Five years after the deadly and destructive 9 January 2018 Montecito debris flows (Santa Barbara County, California, USA), an atmospheric river storm on 9 January 2023 triggered widespread landsliding that affected many of the same drainages in the Santa Ynez Mountains. Using high-resolution aerial imagery, we identified >10,000 landslides over an ∼160 km 2 area. Most of the landslides were shallow (<1 m in depth) translational debris slides that initiated on steep (∼40°), south-facing hillslopes, with the highest incidence of landsliding in a sandstone-dominated bedrock unit. The landslides mobilized into debris flows and delivered substantial quantities of sediment downstream, which contributed to costly infrastructure impairments. We detected order-of-magnitude differences in landslide density across the study area that could not be attributed to variations in geomorphology (topographic aspect and slope), geology (bedrock type), or hydrology (seasonal antecedent rainfall, peak hourly storm rainfall intensity, total storm rainfall), which are usually considered relevant factors for shallow landsliding. Rather, we found that vegetation regrowth following wildfire was likely a relevant factor associated with the highly variable landslide densities. Hillslopes with less and different types of vegetation regrowth after fire appear to have been more susceptible to shallow landslides. We identify a possible vegetation control on postfire landsliding, which highlights an opportunity for hypothesis testing using more advanced techniques to track the evolution of vegetation cover and vegetation type in steep shrubland environments following wildfire.

California↗

USGS2019

Physical mechanisms influencing localized patterns of temperature variability and coral bleaching within a system of reef atolls

Interactions between oceanic and atmospheric processes within coral reefs can significantly alter local-scale (< km) water temperatures, and consequently drive variations in heat stress and bleaching severity. The Scott Reef atoll system was one of many reefs affected by the 2015–2016 mass coral bleaching event across tropical Australia, and specifically experienced sea surface temperature anomalies of 2 °C that caused severe mass bleaching (> 60%) over most of this system; however, the bleaching patterns were not uniform. Little is known about the processes governing thermodynamic variability within atolls, particularly those that are dominated by large amplitude tides. Here, we identify three mechanisms at Scott Reef that alleviated heat stress during the marine heatwave in 2016: (1) the cool wake of a tropical cyclone that induced temperature drops of 1.3 °C over a period of 8 days; (2) air–sea heat fluxes that interacted with the reef morphology during neap tides at one of the atolls to reduce water temperatures by up to 2.9 °C; (3) internal tidal processes that forced deeper and cooler water (up to 2.7 °C) into some sections of the shallow reefs. The latter two processes created localized areas of reduced temperatures that led to lower incidences of coral bleaching for parts of the reef. We predict these processes are likely to occur in other similar tide-dominated reef environments worldwide. Identifying locations where physical processes reduce heat stress will likely be critical for coral reefs in the future, by maintaining communities that can help facilitate local recovery of reefs following bleaching events that are expected to increase in frequency and severity in the coming decades.

Coral Reefs↗

USGS2023

Gulf Islands National Seashore regional sediment budget research and data needs—Workshop series summary

Executive Summary The National Park Service (NPS), in collaboration with the U.S. Geological Survey (USGS), recognizes the need to quantify the sediment budget of the barrier islands within the Gulf Islands National Seashore (GINS) to understand the coastal processes affecting island resiliency. To achieve this goal, identifying and quantifying the physical parameters that drive long-term change is necessary to model the processes that are both generative and terminal in island evolution and capture island response to long-term human alteration and climatic patterns. For example, measuring change across periods of storminess is more effective at assessing island resiliency than measuring change resulting from a single storm impact. Understanding changes to the physical environment over time is key to successfully predicting island responses to future storm impacts, human alteration, and sea-level rise and is necessary for effective decision making and management response. Yet, the diversity of factors affecting natural and cultural resources necessitates a strategic approach to data collection priorities that can inform sediment budget quantification and integrated resource management. This study sought to advance sediment budget modeling efforts by conducting a “Needs Assessment Workshop” at the GINS. The purpose of the workshop was to identify and prioritize the specific research and data needs regarding the sediment budget at the GINS that can enhance the NPS efforts to conserve the islands’ natural resources, cultural resources, and the facilities and infrastructure that support both conservation and visitor use of those resources. This effort explored two research questions: (1) “what research and data needs exist for the sediment budget at Gulf Islands National Seashore” (research question 1) and (2) “how can research to address these needs capitalize on regional partnerships to advance natural and cultural resource conservation at Gulf Islands National Seashore” (research question 2)? The workshop was conducted virtually in a two-part, two-day series. The workshop series was organized by researchers from North Carolina State University in collaboration with NPS and USGS staff and was facilitated by National Oceanographic and Atmospheric Administration staff. The workshop series (two paired, sequential, partial-day workshops) addressed two target audiences: (1) NPS and USGS staff (April workshop) and (2) regional Federal, State, county, and nongovernmental organization staff, including NPS and USGS staff (May workshop). A total of four workshop sessions were held, comprising two sessions with each target audience. The workshop series intended to identify sediment management research and data needs that could enhance natural and cultural resource stewardship at the GINS. One objective was to share information about regional sediment transport and management, available sediment management plans, and predictive modeling capabilities, including geomorphologic and hydrodynamic predictive models. This information was shared through a series of presentations by park managers and NPS and USGS researchers that identified park issues and available capabilities and data. The second objective was to elicit research and data needs, with a primary goal of assessing the importance and urgency of the identified needs. This assessment was partly determined by requesting that the workshop participants identify and prioritize research themes through polls, comments, and discussion. The polls explicitly asked participants to qualitatively evaluate the importance (not at all, slightly, somewhat, very, or extremely) and urgency (not at all, slightly, somewhat, very, or extremely) of the thematically grouped research and data needs. These evaluations were plotted and shared during the workshop to visualize how the relative importance ( x -axis) and relative urgency ( y -axis) of each “need,” relative to other needs, to identify the most necessary (importance) and time-sensitive (urgent) items, thereby allowing an enhanced, holistic understanding of the sediment budget at GINS. Results of the poll are published as a USGS data release. The assessment results revealed that the most important and urgent research and data needs included mapping (for example, elevation, habitat, and cultural resources), a regional sediment budget and management plan, and the dynamic modeling of sediment processes. During the workshop, these issues were visualized using scatter plots to demonstrate the relative importance and urgency of each theme, provide descriptive statistics, and elicit discussion. This format of iterative presentation, discussion, and prioritization allowed the project team to effectively accomplish their objective of identifying important and urgent research needs for natural and cultural resource stewardship at the GINS. Through the workshop, it was determined that expanded communication with the broader research community was needed to coordinate research activities and streamline potential funding opportunities and that research and policy should be integrated through a structured decision-making process. At the conclusion of the workshop, an administered poll showed that the presentations effectively identified data and research needs and that the goals of the workshop were achieved. The results suggest that this type of needs-assessment workshop can effectively identify existing research capabilities and data, determine and prioritize research and data needs, and address how these efforts can use regional partnerships to aid natural and cultural resource conservation and management at National Parks.

Florida, Mississippi↗

USGS1998

Water-quality and algal conditions in the North Umpqua River Basin, Oregon, 1992-95, and implications for resource management

This report describes the results of a synoptic water-quality and algal investigation during July 1995 at 36 stream sites in a 1,350 square-mile area of the North Umpqua River Basin, Oregon. The study area includes a headwaters hydroelectric project area, a Wild and Scenic reach in the main stem immediately downstream, and the watersheds of several major tributaries. Additional data from previous investigations are reviewed, and impacts on water quality in the Wild and Scenic reach from resource management, including forestry and reservoir operations, are inferred where sufficient data exist. Water-quality standards were occasionally exceeded for dissolved oxygen and pH, and daily maximum stream temperatures in the Wild and Scenic reach were higher than both the 1996 standard for the State of Oregon and the optimal temperature ranges for many anadromous fish. Dissolved oxygen in the basin was controlled more by stream temperature and reaeration than by primary production. Arsenic concentrations in the river during low flow (1 µg/L [microgram per liter]) indicate a potential cancer risk of between 1:5,000 and 1:20,000 for people using the river as a source of drinking water and fish for consumption. Streambed-sediment concentrations of arsenic, chromium, copper, manganese, and nickel were approximately double the sediment-quality criteria values adopted by New York State and by the Ontario Ministry of the Environment. High concentrations of phosphorus in bed sediments indicated that much of the phosphorus observed in the water column throughout the basin (medians: 32, 9, and 50 µg/L in the main stem, tributaries, and hydroelectric project areas, respectively) could have been geologically derived. Inorganic and organic nitrogen concentrations in water were mostly below minimum reporting limits (5 and 200 µg/L, respectively), indicating severe nitrogen limitation at most locations. Benthic algal biomass, biovolume, and chlorophyll a concentrations were highest at the sites directly below impoundments and at one headwater tributary (medians: 46 grams per square meter, 821 million cubic micrometers per square centimeter, and 126 milligrams per square meter, respectively), and were also somewhat elevated downstream in the Wild and Scenic reach compared with those in similar streams in the Pacific Northwest. Classification of the algal taxa indicated that, among all sites sampled, alkaliphilic taxa, nitrogen fixing taxa, and eutrophic taxa were the most abundant on the basis of biovolume and density. Cold-water taxa, facultative nitrogen heterotrophs, and oligotrophic taxa constituted the remainder of the taxa. Multivariate analyses indicated that algal communities at the hydroelectric-project-affected sites were distinct from communities at sites on the main stem and Steamboat Creek. At many locations, the river’s algal community might be compensating for the low nitrogen concentrations by fixation of atmospheric nitrogen or through heterotrophic assimilation of organic nitrogen. Water quality in the Wild and Scenic reach is dominated by water released from the hydroelectric project area during summer. Effects of the hydroelectric project include seasonal control of streamflow, water temperature, and phosphorus concentrations, and the possible release of low but ecologically important concentrations of organic nitrogen. A review of available data and literature suggests that the reservoirs can increase the interception of sediments and large organic debris, and promote their conversion into fine-grained particulate and dissolved organic matter for downstream transport. These effects could be compounded by the effects of forestry in the basin, including alteration of hydrologic cycles, changes in sediment and nutrient runoff, reductions of the transport of large woody debris, and degradation of habitat quality. It is hypothesized that, in the North Umpqua River, these processes have induced a fundamental shift in the river’s food web, from a detritus-based system to a system with a 2 higher emphasis on algal production. Confirmation of these changes and their effects on higher trophic levels are needed to properly manage the aquatic resources for all designated beneficial uses in the basin.

Oregon↗

USGS2006

Polar Bear Population Status in the Southern Beaufort Sea

Polar bears depend entirely on sea ice for survival. In recent years, a warming climate has caused major changes in the Arctic sea ice environment, leading to concerns regarding the status of polar bear populations. Here we present findings from long-term studies of polar bears in the southern Beaufort Sea (SBS) region of the U.S. and Canada, which are relevant to these concerns. We applied open population capture-recapture models to data collected from 2001 to 2006, and estimated there were 1,526 (95% CI = 1,211; 1,841) polar bears in the SBS region in 2006. The number of polar bears in this region was previously estimated to be approximately 1,800. Because precision of earlier estimates was low, our current estimate of population size and the earlier ones cannot be statistically differentiated. For the 2001-06 period, the best fitting capture-recapture model provided estimates of total apparent survival of 0.43 for cubs of the year (COYs), and 0.92 for all polar bears older than COYs. Because the survival rates for older polar bears included multiple sex and age strata, they could not be compared to previous estimates. Survival rates for COYs, however, were significantly lower than estimates derived in earlier studies (P = 0.03). The lower survival of COYs was corroborated by a comparison of the number of COYs per adult female for periods before (1967-89) and after (1990-2006) the winter of 1989-90, when warming temperatures and altered atmospheric circulation caused an abrupt change in sea ice conditions in the Arctic basin. In the latter period, there were significantly more COYs per adult female in the spring (P = 0.02), and significantly fewer COYs per adult female in the autumn (P < 0.001). Apparently, cub production was higher in the latter period, but fewer cubs survived beyond the first 6 months of life. Parallel with declining survival, skull measurements suggested that COYs captured from 1990 to 2006 were smaller than those captured before 1990. Similarly, both skull measurements and body weights suggested that adult males captured from 1990 to 2006 were smaller than those captured before 1990. The smaller stature of males was especially notable because it corresponded with a higher mean age of adult males. Male polar bears continue to grow into their teens, and if adequately nourished, the older males captured in the latter period should have been larger than those captured earlier. In western Hudson Bay, Canada, a significant decline in population size was preceded by observed declines in cub survival and physical stature. The evidence of declining recruitment and body size reported here, therefore, suggests vigilance regarding the future of polar bears in the SBS region.

Open-File Report↗

USGS2010

Modeling amphibian energetics, habitat suitability, and movements of western toads, Anaxyrus (=Bufo) boreas, across present and future landscapes

Effective conservation of amphibian populations requires the prediction of how amphibians use and move through a landscape. Amphibians are closely coupled to their physical environment. Thus an approach that uses the physiological attributes of amphibians, together with knowledge of their natural history, should be helpful. We used Niche Mapper™ to model the known movements and habitat use patterns of a population of Western toads ( Anaxyrus (= Bufo ) boreas ) occupying forested habitats in southeastern Idaho. Niche Mapper uses first principles of environmental biophysics to combine features of topography, climate, land cover, and animal features to model microclimates and animal physiology and behavior across landscapes. Niche Mapper reproduced core body temperatures ( T c ) and evaporation rates of live toads with average errors of 1.6 ± 0.4 °C and 0.8 ± 0.2 g/h, respectively. For four different habitat types, it reproduced similar mid-summer daily temperature patterns as those measured in the field and calculated evaporation rates (g/h) with an average error rate of 7.2 ± 5.5%. Sensitivity analyses indicate these errors do not significantly affect estimates of food consumption or activity. Using Niche Mapper we predicted the daily habitats used by free-ranging toads; our accuracy for female toads was greater than for male toads (74.2 ± 6.8% and 53.6 ± 15.8%, respectively), reflecting the stronger patterns of habitat selection among females. Using these changing to construct a cost surface, we also reconstructed movement paths that were consistent with field observations. The effect of climate warming on toads depends on the interaction of temperature and atmospheric moisture. If climate change occurs as predicted, results from Niche Mapper suggests that climate warming will increase the physiological cost of landscapes thereby limiting the activity for toads in different habitats.

Idaho↗

USGS2011

Applying monitoring, verification, and accounting techniques to a real-world, enhanced oil recovery operational CO2 leak

The use of carbon dioxide (CO 2 ) for enhanced oil recovery (EOR) is being tested for oil fields in the Illinois Basin, USA. While this technology has shown promise for improving oil production, it has raised some issues about the safety of CO 2 injection and storage. The Midwest Geological Sequestration Consortium (MGSC) organized a Monitoring, Verification, and Accounting (MVA) team to develop and deploy monitoring programs at three EOR sites in Illinois, Indiana, and Kentucky, USA. MVA goals include establishing baseline conditions to evaluate potential impacts from CO 2 injection, demonstrating that project activities are protective of human health and the environment, and providing an accurate accounting of stored CO 2 . This paper focuses on the use of MVA techniques in monitoring a small CO 2 leak from a supply line at an EOR facility under real-world conditions. The ability of shallow monitoring techniques to detect and quantify a CO 2 leak under real-world conditions has been largely unproven. In July of 2009, a leak in the pipe supplying pressurized CO 2 to an injection well was observed at an MGSC EOR site located in west-central Kentucky. Carbon dioxide was escaping from the supply pipe located approximately 1 m underground. The leak was discovered visually by site personnel and injection was halted immediately. At its largest extent, the hole created by the leak was approximately 1.9 m long by 1.7 m wide and 0.7 m deep in the land surface. This circumstance provided an excellent opportunity to evaluate the performance of several monitoring techniques including soil CO 2 flux measurements, portable infrared gas analysis, thermal infrared imagery, and aerial hyperspectral imagery. Valuable experience was gained during this effort. Lessons learned included determining (1) hyperspectral imagery was not effective in detecting this relatively small, short-term CO 2 leak, (2) even though injection was halted, the leak remained dynamic and presented a safety risk concern during monitoring activities and, (3) the atmospheric and soil monitoring techniques used were relatively cost-effective, easily and rapidly deployable, and required minimal manpower to set up and maintain for short-term assessments. However, characterization of CO 2 distribution near the land surface resulting from a dynamic leak with widely variable concentrations and fluxes was challenging.

Illinois, Indiana, and Kentucky↗

USGS2020

Sediment dynamics of a divergent bay–marsh complex

Bay–marsh systems, composed of an embayment surrounded by fringing marsh incised by tidal channels, are widely distributed coastal environments. External sediment availability, marsh-edge erosion, and sea-level rise acting on such bay–marsh complexes may drive diverse sediment-flux regimes. These factors reinforce the ephemeral and dynamic nature of fringing marshes: material released by marsh-edge erosion becomes part of a bay–marsh exchange that fuels the geomorphic evolution of the coupled system. The dynamics of this sediment exchange determine the balance among seaward export, deposition on the embayment seabed, flux into tidal channels, and import to the marsh platform. In this work, we investigate the sediment dynamics of a transgressive bay–marsh complex and link them to larger-scale considerations of its geomorphic trajectory. Grand Bay, Alabama/Mississippi, is a shallow microtidal embayment surrounded by salt marshes with lateral erosion rates of up to 5 m year −1 . We collected 6 months of oceanographic data at four moorings within Grand Bay and its tidal channels to assess hydrographic conditions and net sediment-flux patterns and augmented the observations with numerical modeling. The observations imply a divergent sedimentary system in which a majority of the suspended sediment is exported seaward, while a smaller fraction is imported landward via tidal channels, assisting in vertical marsh-plain accumulation, maintenance of channel and intertidal-flat morphologies, and landward transgression. These results describe a dynamic system that is responsive to episodic atmospheric forcing in the absence of a strong tidal signal and the presence of severe lateral marsh loss.

Alabama, Mississippi↗

USGS2020

Degradation of RDX (Hexahydro-1,3,5-trinitro-1,3,5-triazine) in contrasting coastal marine habitats: Subtidal non-vegetated (sand), subtidal vegetated (silt/eel grass), and intertidal marsh

Hundreds of explosive-contaminated marine sites exist globally, many of which contain the common munitions constituent hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX). Quantitative information about RDX transformation in coastal ecosystems is essential for management of many of these sites. Isotopically labelled RDX containing 15 N in all 3 nitro groups was used to track the fate of RDX in three coastal ecosystem types. Flow-through mesocosms representing subtidal vegetated (silt/eel grass), subtidal non-vegetated (sand) and intertidal marsh ecosystems were continuously loaded with isotopically labelled RDX for 16–17 days. Sediment, pore-water and overlying surface water were analyzed to determine the distribution of RDX, nitroso-triazine transformation products (NXs) and nitrogen containing complete mineralization products, including ammonium, nitrate+nitrite, nitrous oxide and nitrogen gas. The marsh, silt, and sand ecotypes transformed 94%, 90% and 76% of supplied RDX, respectively. Total dissolved NXs accounted for 2%–4% of the transformed 15 N-RDX. The majority of RDX transformation in the water column was by mineralization to inorganic N (dissolved and evaded; 64%–78% of transformed 15 N-RDX). RDX was mineralized primarily to N 2 O (62–74% of transformed 15 N-RDX) and secondarily to N 2 (1–2% of transformed 15 N-RDX) which exchanged with the atmosphere. Transformation of RDX was favored in carbon-rich lower redox potential sediments of the silt and marsh mesocosms where anaerobic processes of iron and sulfate reduction were most prevalent. RDX was most persistent in the carbon-poor sand mesocosm. Partitioning of 15 N derived from RDX onto sediment and suspended particulates was negligible in the overall mass balance of RDX transformation (2%–3% of transformed 15 N-RDX). The fraction of 15 N derived from RDX that was sorbed or assimilated in sediment was largest in the marsh mesocosm (most organic carbon), and smallest in the sand mesocosm (largest grain size and least organic carbon). Sediment redox conditions and available organic carbon stores affect the fate of RDX in different coastal marine habitats.

Connecticut, New York↗

USGS2010

Secular variation in economic geology

The temporal pattern of ore deposits on a constantly evolving Earth reflects the complex interplay between the evolving global tectonic regime, episodic mantle plume events, overall changes in global heat flow, atmospheric and oceanic redox states, and even singular impact and glaciation events. Within this framework, a particular ore deposit type will tend to have a time-bound nature. In other words, there are times in Earth history when particular deposit types are absent, times when these deposits are present but scarce, times when they are abundant, and still other times for which we lack sufficient data. Understanding of such secular variation provides a critical first-order tool for exploration targeting, because rocks that have formed or were deformed during a certain time slice may be very permissive for a given deposit type, whereas identification of rocks of less favorable ages would help eliminate large areas during exploration programs. Secular analysis, therefore, is potentially a powerful tool for mineral resource assessment in poorly known terranes, providing a quick filter for favorability of a given deposit type using age of host rocks. Factors bearing on the known age distribution of a particular type of deposit include the following: (1) uneven preservation, (2) data gaps, (3) contingencies of plate motions, and (4) long-term secular changes in the Earth System. The present special issue of Economic Geology is focused on the latter factor, although all of these are interrelated. The selective preservation of certain mineral deposit types and the greater susceptibility for shallowly formed ores in tectonically active environments to be lost to erosion define a pattern that is superimposed on the secular formational trends (e.g., Groves et al., 2005a , b ; Kerrich et al., 2005 ). With improved geochronological methods and the availability of information on important mineral deposits from most parts of the world, data gaps for defining broad temporal distributions of ore types are becoming smaller. It has been increasingly recognized that ore deposit formation is also correlated with plate tectonic setting. Nevertheless, a complex Earth history of supercontinent assembly and breakup has led to the fragmentation of many Paleozoic and Precambrian mineral provinces. The use of plate reconstructions in economic geology, although extremely controversial and conjectural before the late Paleozoic, is critical for defining these provinces prior to the added complications resulting from post-ore plate motions. It is now well established that the temporal patterns of many types of mineral deposits (Fig. 1 1 ) reflect the formation or break-up of supercontinents and the preservation potential of deposits formed during these periods ( Barley and Groves, 1992 ; Titley, 1993 ; Kerrich et al., 2005 ; Goldfarb et al., 2009 ). Approximate time periods for such formation and break-up, respectively, include 2800–2500 and 2450–2100 Ma for Kenorland, 2100–1800 and 1600–1300 Ma for Nuna/Columbia, 1300–1100 and 850–600 Ma for Rodinia, and 600–300 Ma and 200–60 Ma for Gondwanaland-Pangea. A new supercontinent, Amasia, has begun to form during the past 250 m.y., thus overlapping Pangea break-up. Many of the formation-preservation patterns are themselves controlled by progressive cooling of Earth, the change from a mantle-plume buoyancy style to subduction-dominated tectonics, a decreasing buoyancy of the subcontinental lithospheric mantle, and depth of ore formation. In general, orogenic Au, volcanogenic massive sulfide (VMS), epithermal Au-Ag, and porphyry Cu±Au and Mo porphyry deposits form in active margins during periods of supercontinent assembly. Numerous other ore deposit types show an association with supercontinent formation, but develop inland of the active margin. These include many of the MVT Pb-Zn deposits and unconformity-type U deposits. The Tertiary Carlin-type deposits within the deformed shelf sequences along the North American craton margin also appear to have formed during the ongoing growth of Amasia. Those ores associated with periods of supercontinent breakup or attempted breakup are more difficult to define. They probably include diamond, Bushveld-type Ni-Cu-PGE, IOCG, and clastic-dominated Pb-Zn (or SEDEX) deposits in intracontinental areas of failed rifting, and other clastic-dominated Pb-Zn deposits in areas of actual breakup. In all cases, however, these temporal/spatial distributions are ultimately controlled by the secular character of Earth history.

Economic Geology↗

USGS2005

Ground water to surface water: Chemistry of thermal outflows in Yellowstone National Park

Geothermal waters in the earth’s subsurface boil with steam separation and may mix with dilute ground waters (that may or may not contain sulfuric acid from sulfur oxidation), resulting in a wide range of compositions when they discharge and emerge at the surface. As they discharge onto the ground surface they undergo evaporative cooling, degassing, oxidation, and mineral precipitation. Within this aquatic environment of rapidly changing physical and chemical parameters, numerous microbial communities develop—some of which affect oxidation and mineral precipitation. Microbes are responsible for rapid oxidation of iron and arsenic in thermal outflows, and for catalyzing the production of sulfuric acid from the oxidation of elemental sulfur. The attractive visual display of colors observed in Yellowstone’s geothermal waters reflects this interplay of physical, chemical, and biological phenomena. Oxidation of dissolved sulfide to thiosulfate occurs abiotically, and thiosulfate can be found in many of Yellowstone’s thermal waters—at any pH, temperature, and composition. Polythionates, on the other hand, are rarely found in Yellowstone waters but are associated with sulfur hydrolysis in Cinder Pool. Oxidation rates of iron and arsenic in overflows have been estimated at 1-3 mM/h and 0.04-0.1 mM/h, respectively—orders of magnitude faster than the abiotic rate. The abiotic production of thiosulfate from oxidation of dissolved sulfi de at Angel Terrace and Ojo Caliente is about 3-30 µM/min, faster by 2-3 orders of magnitude than the laboratory rate at 25°C. The partitioning of dissolved sulfide between that volatilized to the air and that oxidized to thiosulfate has been estimated at Angel Terrace and at Ojo Caliente. For the pH range of 6-8 and the temperature range of 50-93°C, 67-86% of the dissolved sulfide is lost to the atmosphere and 10-33% is oxidized to thiosulfate. Only a very small percentage, if any, forms elemental sulfur under these conditions.

Wyoming↗

USGS2007

Factors to consider for trace element deposition biomonitoring surveys with lichen transplants

A trace element deposition biomonitoring experiment with transplants of the fruticose lichen Evernia prunastri was developed, aimed at monitoring the effects of different exposure parameters (exposure orientation and direct rain) and to the elements Ti, V, Cr, Co, Cu, Zn, Rb, Cd, Sb and Pb. Accumulations were observed for most of the elements, confirming the ability of Evernia transplants for atmospheric metal deposition monitoring. The accumulation trends were mainly affected by the exposure orientation and slightly less so by the protection from rain. The zonation of the trace elements inside the thallus was also studied. It was concluded that trace element concentrations were not homogeneous in Evernia, thus imposing some cautions on the sampling approach. A nuclear microprobe analysis of an E. prunastri transplanted thallus in thin cross-sections concluded that the trace elements were mainly concentrated on the cortex of the thallus, except Zn, Ca and K which were also present in the internal layers. The size of the particles deposited or entrapped on the cortex surface averaged 7????m. A list of key parameters to ensure the comparability of surveys aiming at observing temporal or spatial deposition variation is presented. ?? 2006 Elsevier B.V. All rights reserved.

Tête Ronde, Gif-sur-Yvette↗

USGS2023

Panarctic lakes exerted a small positive feedback on early Holocene warming due to deglacial release of methane

Climate-driven permafrost thaw can release ancient carbon to the atmosphere, begetting further warming in a positive feedback loop. Polar ice core data and young radiocarbon ages of dissolved methane in thermokarst lakes have challenged the importance of this feedback, but field studies did not adequately account for older methane released from permafrost through bubbling. We synthesized panarctic isotope and emissions datasets to derive integrated ages of panarctic lake methane fluxes. Methane age in modern thermokarst lakes (3132 ± 731 years before present) reflects remobilization of ancient carbon. Thermokarst-lake methane emissions fit within the constraints imposed by polar ice core data. Younger, albeit ultimately larger sources of methane from glacial lakes, estimated here, lagged those from thermokarst lakes. Our results imply that panarctic lake methane release was a small positive feedback to climate warming, comprising up to 17% of total northern hemisphere sources during the deglacial period.

Communications Earth and Environment↗

USGS2025

Geochemistry of quartz and fluid inclusions associated with gold, tungsten, and antimony in the Stibnite-Yellow Pine district, Idaho

Deposits in the historic Stibnite-Yellow Pine district in east-central Idaho were mined for Ag, Au, Hg, Sb, and W. Ore is hosted in breccia and fault zones along NE-striking faults that transect the Atlanta lobe of the Late Cretaceous Idaho batholith and metamorphosed Neoproterozoic to lower Paleozoic rocks. Geochronological studies have delineated five superimposed and zoned hydrothermal events in the mining district which range in age from Late Cretaceous to the Eocene. They formed the following consecutive assemblages: (1) vein and disseminated pre-ore milky quartz (± calcite), muscovite, and brassy pyrite with minor molybdenite and base metal sulfides; (2) vein and disseminated quartz, calcite, sericite, auriferous-pyrite, and arsenopyrite; (3) potassium feldspar, quartz, dolomite, and calcite with vein and disseminated scheelite ± pyrite and arsenopyrite; (4) Au-Ag veins that contain adularia; and (5) breccia, vein, and disseminated quartz, calcite, and stibnite with minor Ag sulfosalts and distal zones of cinnabar and realgar at Fern and Hermes mines. In this study, the pressure, temperature, and composition of ore-forming fluids were measured in Au-, W-, and Sb-bearing samples collected from drill core and surface exposures. Using optical petrography, scanning electron microscopy cathodoluminescence (SEM-CL) and electron microprobe cathodoluminescence (EMPA-CL) imaging, as well as electron microprobe (EMP) and laser ablation-inductively coupled plasma-mass spectrometry trace element analyses, four major overprinting generations of hydrothermal quartz are defined. Fluid inclusion assemblages (FIAs) in each generation of quartz were characterized by microthermometry and laser Raman spectroscopy. Quartz and fluid inclusion paragenesis are as follows: (Qi) altered and overprinted Qi with no coeval FIAs that formed before or during event 1; (Q1) early veins as well as disseminated quartz with dull gray SEM-CL and H 2 O-NaCl-CO 2 FIAs that formed at minimum temperatures and pressures of 281° to 358°C and 1346 to 1789 bar during event 2 (Au); (Q2) vein and disseminated quartz, often euhedral, with H 2 O-NaCl ± CO 2 ± CH 4 FIAs that formed at minimum temperatures and pressures of 183° to 213°C and 72 to 602 bar during event 3 (W); and (Q3) euhedral and disseminated quartz with H 2 O-NaCl FIAs that formed at minimum temperature and pressures of 156° to 161°C and 5 to 6 bar during event 5 (Sb). Stibnite hosts H 2 O-NaCl FIAs trapped at minimum temperatures and pressures of 150° to 189°C and 5 to 12 bar that are similar to those of Q3-hosted FIAs. The quartz paragenetic history in the district follows a progressive temporal path from Tienriched quartz deposited by a relatively deep and higher temperature aqueous-carbonic fluid to a Li, Al, and Sb enriched quartz precipitated from a lower temperature aqueous fluid. Gases in fluid inclusion extracts from ore and gangue minerals were analyzed by mass spectrometry. Noble gas isotope analysis of fluid inclusion extracts revealed three signatures. Pre-ore Qi has R/R A (the isotopic ratio of the sample 3 He/ 4 He to atmospheric 3 He/ 4 He (1.384 × 10 −6 )) values that reflect the composition of the crustal melt-derived Atlanta lobe of the Idaho batholith. Quartz (Q1) and auriferous arsenian pyrite of hydrothermal event 2 have 20 Ne/ 4 He and R/R A values that plot along the air-crust mixing line, and these gases were likely introduced by metamorphic fluids derived from metasedimentary rocks. Stibnite with associated quartz (Q3 ± Q2) have 20 Ne/ 4 He and R/R A values that extend from the air-crust mixing line to the air-mantle mixing line, showing a shift from a crustal signature to an overprinting mantle signature. Late calcite has 20 Ne/ 4 He and R/R A values that extend from air toward the mantle end member, which suggests that magmatic volatiles condensed into meteoric groundwater late in the paragenesis. A mantle volatile source is also supported by high 20 Ne/ 22 Ne ratios. The Stibnite-Yellow Pine district is similar to other Au-W-Sb districts around the world in ore fluid chemistries, with late-stage stibnite being a product of cooling. The fluid pressure-temperature-composition (P-T-X) estimates and the crustal source of He during hydrothermal event 2 gold mineralization are characteristic of orogenic Au deposits, and the observed inclusion reequilibration textures indicate that trapped fluid inclusions were deformed during transitions between the brittle-ductile environment. Scheelite was deposited during event 3 with Q2 quartz and is overgrown by Q3 quartz and stibnite. Our interpretation of the quartz texture, chemistry, and fluid inclusion P-T-X data suggest that Au, W, and Sb mineralization occurred as hydrothermal fluids evolved from H 2 O-NaCl-CO 2 at >300°C and depths of ~4 to 6 km near the ductile to brittle transition to H 2 O-NaCl at ~150°C and epithermal depths as the Idaho batholith was exhumed. Geochronology indicates that from the Late Cretaceous to early Eocene, overprinting hydrothermal events formed deep orogenic Au, intermediate W, and shallow epithermal Au-Ag and Sb. Without comprehensive geochronologic constraints, our fluid inclusion data and textural observations could be interpreted as a single evolving hydrothermal system, as has been done in many other mining districts with similar mineralization.

Idaho↗

USGS2024

The EnMAP spaceborne imaging spectroscopy mission: Initial scientific results two years after launch

Imaging spectroscopy has been a recognized and established remote sensing technology since the 1980s, mainly using airborne and field-based platforms to identify and quantify key bio- and geo-chemical surface and atmospheric compounds, based on characteristic spectral reflectance features in the visible-near infrared (VNIR) and short-wave infrared (SWIR). Spaceborne missions, a leap in technology, were sparse, starting with the CHRIS/PROBA and EO1/Hyperion missions in the early 2000s, and providing spectroscopy data with limited spectral coverage and/or low data quality in the SWIR. Since 2019, several countries and agencies have successfully launched a number of spaceborne imaging spectroscopy systems into orbit or deployed them on the International Space Station (ISS) such as DESIS, PRISMA, HISUI, GF-5, EnMAP and EMIT. Among these recent missions, the German Environmental Mapping and Analysis Program (EnMAP) stands for its long-term development, sophisticated design with on-board calibration, high data quality requirements, and extensive accompanying science program. EnMAP was launched in April 2022 and, following a successful commissioning phase, started its operational activities in November 2022. The EnMAP mission encompasses global coverage from 80° N to 80° S through on-demand data acquisitions. Data are free and open access with 30 m spatial resolution, a high spectral resolution with a spectral sampling distance of 6.5 nm and 10 nm in the VNIR and SWIR regions respectively, and a high signal-to-noise ratio. In this paper, we aim to present the mission's current status, coverage, science capabilities and performance two years after launch. We show the potential of EnMAP for space-based imaging spectroscopy to operate in various environments, including high and low light levels, dense forests, Antarctic glaciers, and arid agricultural areas. EnMAP enables various applications in fields such as agriculture and forestry, soil compositional, raw materials, and methane mapping, as well as water quality assessment, and snow and ice properties. The results show that EnMAP's performance exceeds the mission requirements, and highlights the significant potential for contribution to scientific exploitation in various geo- and biochemical sciences. EnMAP is also expected to serve as a key tool for the development and testing of data processing algorithms for upcoming global operational missions.

Remote Sensing of Environment↗

USGS2018

Methane in groundwater from a leaking gas well, Piceance Basin, Colorado, USA

Site-specific and regional analysis of time-series hydrologic and geochemical data collected from 15 monitoring wells in the Piceance Basin indicated that a leaking gas well contaminated shallow groundwater with thermogenic methane. The gas well was drilled in 1956 and plugged and abandoned in 1990. Chemical and isotopic data showed the thermogenic methane was not from mixing of gas-rich formation water with shallow groundwater or natural migration of a free-gas phase. Water-level and methane-isotopic data, and video logs from a deep monitoring well, indicated that a shale confining layer ~125 m below the zone of contamination was an effective barrier to upward migration of water and gas. The gas well, located 27 m from the contaminated monitoring well, had ~1000 m of uncemented annular space behind production casing that was the likely pathway through which deep gas migrated into the shallow aquifer. Measurements of soil gas near the gas well showed no evidence of methane emissions from the soil to the atmosphere even though methane concentrations in shallow groundwater (16 to 20 mg/L) were above air-saturation levels. Methane degassing from the water table was likely oxidized in the relatively thick unsaturated zone (~18 m), thus rendering the leak undetectable at land surface. Drilling and plugging records for oil and gas wells in Colorado and proxies for depth to groundwater indicated thousands of oil and gas wells were drilled and plugged in the same timeframe as the implicated gas well, and the majority of those wells were in areas with relatively large depths to groundwater. This study represents one of the few detailed subsurface investigations of methane leakage from a plugged and abandoned gas well. As such, it could provide a useful template for prioritizing and assessing potentially leaking wells, particularly in cases where the leakage does not manifest itself at land surface.

Colorado↗

USGS2019

It is raining plastic

Atmospheric deposition samples were collected using the National Atmospheric Deposition Program / National Trends Network (NADP/NTN) at 6 sites in the Denver-Boulder urban corridor and 2 adjacent sites in the Colorado Front Range. Weekly wet-only atmospheric deposition samples collected at these sites during winter-summer of 2017 were filtered (0.45 micrometers, polyethersulfone) to obtain particulates washed from the atmosphere (washout). Plastics were identified on over 90 percent of the filters. The plastic materials are mostly fibers that are only visible with magnification (~40X). Fibers were present in a variety of colors; the most frequently observed color was blue followed by red > silver > purple > green > yellow > other colors. Plastic particles such as beads and shards were also observed with magnification. More plastic fibers were observed in samples from urban sites than from isolated, montane sites. However, frequent observation of plastic fibers in washout samples from the isolated Loch Vale site in Rocky Mountain National Park (elevation 3,159 meters) suggests that wet-deposition of plastic is ubiquitous and not just an urban condition. The mass of plastic in even the most concentrated samples was not large enough to weigh or reliably estimate. Developing a routine capability to calculate plastic wet-deposition loads is not possible with current technology. Counting plastic fibers under a microscope and multiplying the counts by a mean mass per fiber might be possible, but it is tedious, expensive, and has large inherent error. A means to estimate the recovery of the plastic materials from the NADP samples is needed. However, saving the NADP filters for subsequent analysis would make a washout deposition network possible with very little added expense, and methods could be developed to more accurately estimate plastic loads using the NTN. It is unclear how these plastic materials are accumulating and being assimilated in the environment and biota. Moreover, the potential effects of these materials on biota is not understood.

Colorado↗