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USGS2018

Spatial decision‐support tools to guide restoration and seed‐sourcing in the Desert Southwest

Altered disturbance regimes and shifting climates have increased the need for large‐scale restoration treatments across the western United States. Seed‐sourcing remains a considerable challenge for revegetation efforts, particularly on public lands where policy favors the use of native, locally sourced plant material to avoid maladaptation. An important area of emphasis for public agencies has been the development of spatial tools to guide selection of genetically appropriate seed. When genetic information is not available, current seed transfer guidelines stipulate use of climate‐based or provisional seed transfer zones, which serve as a proxy for local adaptation by representing climate gradients to which plants are commonly adapted. Despite this guidance, little emphasis has been placed on identifying best practices for deriving provisional seed zones or on incorporating predictions from future climate. We describe a flexible, multivariate procedure for deriving such zones that incorporates a broad range of climatic characteristics while accounting for covariation among climate variables. With this approach, we derive provisional seed zones for four regions in the Desert Southwest (the Mojave Desert, Sonoran Desert, Colorado Plateau, and Southern Great Basin). To facilitate future‐resilient restoration designs, we project each zone into its relative position in the future climate based on near‐term, RCP4.5 and RCP8.5 emissions scenarios. Although provisional seed zones are useful in a variety of contexts, there are also situations in which site‐specific guidance is preferable. To meet this need, we implement Climate Distance Mapper, an interactive decision‐support tool designed to help practitioners match seed sources with restoration sites through an accessible online interface. The application allows users to rank the suitability of seed sources anywhere on the landscape based on multivariate climate distances. Users can perform calculations for either the current or future climates. Additionally, tools are available to guide sample effort in regional‐scale seed collections or to partition the landscape into climate clusters representing suitable planting sites for different seed sources. Our tools and analytic procedures represent a flexible and reproducible framework for advancing native plant development programs in the Desert Southwest and beyond.

Ecosphere↗

USGS2014

Seismicity and seismic structure at Okmok Volcano, Alaska

Okmok volcano is an active volcanic caldera located on the northeastern portion of Umnak Island in the Aleutian arc, with recent eruptions in 1997 and 2008. The Okmok area had ~900 locatable earthquakes between 2003 and June 2008, and an additional ~600 earthquakes from the beginning of the 2008 eruption to mid 2009, providing an adequate dataset for seismic tomography. To image the seismic velocity structure of Okmok, we apply waveform cross-correlation using bispectrum verification and double-difference tomography to a subset of these earthquakes. We also perform P-wave attenuation tomography using a spectral decay technique. We examine the spatio-temporal characteristics of seismicity in the opening sequence of the 2008 eruption to investigate the path of magma migration during the establishment of a new eruptive vent. We also incorporate the new earthquake relocations and three-dimensional (3D) velocity model with first-motion polarities to compute focal mechanisms for selected events in the 2008 pre-eruptive and eruptive periods. Through these techniques we obtain precise relocations, a well-constrained 3D P-wave velocity model, and a marginally resolved S-wave velocity model. We image a main low Vp and Vs anomaly directly under the caldera consisting of a shallow zone at 0–2 km depth connected to a larger deeper zone that extends to about 6 km depth. We find that areas of low Qp are concentrated in the central to southwestern portion of the caldera and correspond fairly well with areas of low Vp. We interpret the deeper part of the low velocity anomaly (4–6 km depth) beneath the caldera as a magma body. This is consistent with results from ambient noise tomography and suggests that previous estimates of depth to Okmok's magma chamber based only on geodetic data may be too shallow. The distribution of events preceding the 2008 eruption suggest that a combination of overpressure in the zone surrounding the magma chamber and the introduction of new material from below were jointly responsible for the explosive eruption. Magma escaping from the top of the main magma chamber likely reacted with both a smaller shallow pod of magma and groundwater on its way up below the Cone D area. The earthquakes in the 2008 pre-eruptive and eruptive periods are found to have a mixture of strike-slip, oblique normal, and oblique thrust mechanisms, with a dominant P-axis orientation that is nearly perpendicular to the regional tectonic stress. This may indicate that the stresses related to magmatic activity locally dominated regional tectonic forces during this time period.

Alaska↗

USGS2015

Normalization of stable isotope data for carbonate minerals: implementation of IUPAC guideline

Carbonate minerals provide a rich source of geochemical information because their δ 13 C and δ 18 O values provide information about surface and subsurface Earth processes. However, a significant problem is that the same δ 18 O value is not reported for the identical carbonate sample when analyzed in different isotope laboratories in spite of the fact that the International Union of Pure and Applied Chemistry (IUPAC) has provided reporting guidelines for two decades. This issue arises because (1) the δ 18 O measurements are performed on CO 2 evolved by reaction of carbonates with phosphoric acid, (2) the acid-liberated CO 2 is isotopically fractionated (enriched in 18 O) because it contains only two-thirds of the oxygen from the solid carbonate, (3) this oxygen isotopic fractionation factor is a function of mineralogy, temperature, concentration of the phosphoric acid, and δ 18 O value of water in the phosphoric acid, (4) researchers may use any one of an assortment of oxygen isotopic fractionation factors that have been published for various minerals at various reaction temperatures, and (5) it sometimes is not clear how one should calculate δ 18 O VPDB values on a scale normalized such that the δ 18 O value of SLAP reference water is −55.5 &permil; relative to VSMOW reference water. To enable researchers worldwide to publish the same δ 18 O value (within experimental uncertainty) for the same carbonate sample, we have re-evaluated reported acid fractionation factors for calcite at 25, 50, and 75 °C and propose a revised relation for the temperature dependence of oxygen isotopic acid fractionation factor, α CO 2 ( ACID ) -calcite αCO2(ACID)-calcite , of 1000ln α CO 2 ( ACID ) -calcite=3.48(10 3 /T)-1.47 1000lnαCO2(ACID)-calcite=3.48(103/T)-1.47 Turn MathJax on where T is temperature in kelvin. At 25 °C, α CO 2 ( ACID ) -calcite=1.01025 αCO2(ACID)-calcite=1.01025 , the most commonly accepted value for this quantity. We propose a normalization protocol in which (1) the internationally distributed carbonate isotopic reference materials NBS 18 and NBS 19 are interspersed among carbonate samples analyzed by treatment with phosphoric acid, (2) the δ 18 O values of the calcite reference materials and the carbonate samples are calculated, respectively, by using the α CO 2 ( ACID ) -calcite αCO2(ACID)-calcite relation above and oxygen-isotope acid fractionation factors appropriate for the sample mineralogy and reaction temperature, (3) the δ 18 O values of solid carbonate samples are determined on the VPDB scale ( δ 18 O VPDB ) with IUPAC-recommended scale expansion such that the δ 18 O of SLAP reference water is −55.5 &permil; relative to VSMOW reference water by normalizing δ 18 O values of carbonate samples with 2014-IUPAC-recommended δ 18 O values of NBS 18 and NBS 19, and (4) δ 18 O values on the VPDB scale are converted to δ 18 O values on the VSMOW-SLAP scale by using IUPAC recommendations. To ease calculations in the protocol, a software application titled “Carbon and Oxygen Isotopic Normalization Tool for Carbonates” is available that relies upon IUPAC-recommended δ 13 C and δ 18 O values of carbonate isotopic reference materials ( http://isotopes.usgs.gov/research/topics/carbonatesnormalizationtool.html ).

Geochimica et Cosmochimica Acta↗

USGS2009

The performance of nearshore dredge disposal at Ocean Beach, San Francisco, California, 2005-2007

Ocean Beach, California, contains an erosion hot spot in the shadow of the San Francisco ebb tidal delta that threatens valuable public infrastructure as well as the safe recreational use of the beach. In an effort to reduce the erosion at this location a new plan for the management of sediment dredged annually from the main shipping channel at the mouth of San Francisco Bay was implemented in May 2005 by the United States Army Corps of Engineers, San Francisco District (USACE). The USACE designated a temporary nearshore dredge disposal site for the annual disposal of about 230,000 m3 (300,000 yd3) of sand about 750 m offshore and slightly south of the erosion hot spot, in depths between approximately 9 and 14 m. The site has now been used three times for a total sediment disposal of about 690,000 m3 (about 900,000 yds3). The disposal site was chosen because it is in a location where strong tidal currents and open-ocean waves can potentially feed sediment toward the littoral zone in the reach of the beach that is experiencing critical erosion, as well as prevent further scour on an exposed outfall pipe. The onshore migration of sediment from the target disposal location might feed the primary longshore bar or the nearshore zone, and provide a buffer to erosion that peaks during winter months when large waves impact the region. The United States Geological Survey (USGS) has been monitoring and modeling the bathymetric evolution of the test dredge disposal site and the adjacent coastal region since inception in May 2005. This paper reports on the first 2.5 years of this monitoring program effort (May 2005 to December 2007) and assesses the short-term coastal response. Here are the key findings of this report: *Approximately half of the sediment that has been placed in the nearshore dredge-disposal site during the 2.5 years of this study remains within the dredge focus area. *In the winter of 2006-7, large waves transported the dredge-mound material onshore. *High rates of seasonal cross-shore sediment transport mask any potential profile change in the Coastal Profiling System data due to dredge placement. *Pockets of accretion have been recorded by topographic surveying adjacent to the dredge site, but it is unclear if the accretion is linked to the nourishment. *Cross-shore profile modeling suggests that dredge material must be placed in water depths no greater than 5 m to drive a positive shoreline response. *Area modeling demonstrates that the new dredge site increases wave dissipation and modifies local sediment-transport patterns, although the effect on the nearshore morphology is largely negligible. *Any increase in beach width or wave energy-dissipation related to the nourishment is likely to be realized only in the vicinity directly onshore of the nourishment site, which is several hundred meters south of the area of critical erosion. *Larger waves from the northwest and smaller waves from the west or southwest contribute most to the sediment transport from the dredge mound onshore.

California↗

USGS1987

Results of a workshop concerning impacts of various activities on the functions of bottomland hardwoods

Under Section 404 of the Clean Water Act, the U.S. Environmental Protection Agency (EPA) has regulatory responsibilities related to the discharge of dredged or fill material into the Nation’s waters. In addition to its advisory role in the U.S. Army Corps of Engineers' permit program, EPA has a number of specific authorities, including formulation of the Section 404(b)(1) guidelines, use of Section 404(c) to prohibit disposal at particular sites, and enforcement actions for unauthorized discharges. A number of recent court cases focus on the geographic scope of Section 404 jurisdiction in potential bottomland hardwood (BLH) wetlands and the nature of landclearing activities in these areas that require a permit under Section 404. Accordingly, EPA needs to establish the scientific basis for implementing its responsibilities under Section 404 in bottomland hardwoods. EPA is approaching this task through a series of workshops designed to provide current scientific information on bottomland hardwoods and to organize that information in a manner pertinent to key policy questions. The first two workshops in the series were originally conceived as technically oriented meetings that would provide the information necessary to develop policy options at the third workshop. More specifically, the first workshop was designed to examine a zonation concept as a means of characterizing different BLH communities and describing variations in their functions along a soil moisture gradient. The second workshop was perceived as an attempt to evaluate the impacts of various activities on those functions. However, one conclusion of the first workshop, which was held in December 1984 in St. Francisville, Louisiana, was that the zonation approach does not describe the variability in the functions performed by BLH ecosystems sufficiently well to allow its use as the sole basis for developing a regulatory framework. That is, factors other than zone were considered critical for an effective characterization of the structure and functions of bottomland hardwoods. The approach to the second workshop, the results of which are described in this report, was therefore modified in response to the conclusions from the first workshop. The focus of the second workshop remained an analysis of the impacts of various activities or the functions of BLH ecosystems. However, as a prerequisite to this analysis, participants were also asked to develop a list of characteristics that determine the extent to which BLH sites perform the important functions. The workshop was organized such that alternating plenary and workgroup sessions allowed ample time for communication while still maintaining a focus on the overall goal. In the initial session, various individuals gave presentations concerning methodologies for evaluating the functions performed by wetlands, factors influencing the conversion of BLH forests to other uses, and the impacts of conversion activities. These were followed by a series of case study presentations designed to familiarize participants with the kinds of issues that are dealt with in the Section 404 program. These presentations are cited in this report as (author, workshop presentation). At the conclusion of these presentations, participants were divided into six workgroups to examine the functions of BLH ecosystems in the areas of hydrology, water quality, fisheries, wildlife, ecosystem processes, and culture/recreation/economics. Each workgroup was asked to undertake the following tasks. 1. Developed a list of functions performed by BLH ecosystems from the perspective of the workgroup's expertise and area of responsibility. 2. Identify those activities (e.g., impoundment construction, conversion to soybean farming) that impact the major functions (e.g., sediment retention, detrital export) performed by BLH ecosystems. 3. Develop a list of characteristics that determine the extent to which a BLH site performs each function and describe the relationship of each characteristic to the function. Develop, with supporting evidence where possible, an analysis of the impact of each activity (Task 2) on each characteristic (Task 3) and on each function as a whole. Upon completion of Task 2, in an effort to provide some uniformity in the analysis by the various workgroups, EPA personnel and several participants met and compiled a complete list of all the activities identified as having significant impacts in bottomland hardwoods (Table 1). From this list the group derived a set of seven activities, and a number of specific actions associated with each, for analysis by the workgroups (Table 2). These activities were selected on the basis of their perceived importance in BLH ecosystems and their interest from the perspective of EPA. Each workgroup was also encourage to ass any activities of particular important from its perspective. The workgroup reports that follow document the results of discussion concerning the above tasks. The WORKSHOP SUMMARY attempts to summarize these workgroup results, discuss availability of information, and identify some problems that must be addressed prior to the third workshop in this series.

Report↗

USGS2021

Techniques to improve ecological interpretability of black box machine learning models

Statistical modeling of ecological data is often faced with a large number of variables as well as possible nonlinear relationships and higher-order interaction effects. Gradient boosted trees (GBT) have been successful in addressing these issues and have shown a good predictive performance in modeling nonlinear relationships, in particular in classification settings with a categorical response variable. They also tend to be robust against outliers. However, their black-box nature makes it difficult to interpret these models. We introduce several recently developed statistical tools to the environmental research community in order to advance interpretation of these black-box models. To analyze the properties of the tools, we applied gradient boosted trees to investigate biological health of streams within the contiguous USA, as measured by a benthic macroinvertebrate biotic index. Based on these data and a simulation study, we demonstrate the advantages and limitations of partial dependence plots (PDP), individual conditional expectation (ICE) curves and accumulated local effects (ALE) in their ability to identify covariate–response relationships. Additionally, interaction effects were quantified according to interaction strength (IAS) and Friedman’s H 2 "> H 2 statistic. Interpretable machine learning techniques are useful tools to open the black-box of gradient boosted trees in the environmental sciences. This finding is supported by our case study on the effect of impervious surface on the benthic condition, which agrees with previous results in the literature. Overall, the most important variables were ecoregion, bed stability, watershed area, riparian vegetation and catchment slope. These variables were also present in most identified interaction effects. In conclusion, graphical tools (PDP, ICE, ALE) enable visualization and easier interpretation of GBT but should be supported by analytical statistical measures. Future methodological research is needed to investigate the properties of interaction tests. Supplementary materials accompanying this paper appear on-line.

Journal of Agricultural, Biological, and Environme↗

USGS2010

In-situ arsenic remediation in Carson Valley, Douglas County, west-central Nevada

Conventional arsenic remediation strategies primarily involve above-ground treatment that include costs involved in the disposal of sludge material. The primary advantages of in-situ remediation are that building and maintaining a large treatment facility are not necessary and that costs associated with the disposal of sludge are eliminated. A two-phase study was implemented to address the feasibility of in-situ arsenic remediation in Douglas County, Nevada. Arsenic concentrations in groundwater within Douglas County range from 1 to 85 micrograms per liter. The primary arsenic species in groundwater at greater than 250 ft from land surface is arsenite; however, in the upper 150 ft of the aquifer arsenate predominates. Where arsenite is the primary form of arsenic, the oxidation of arsenite to arsenate is necessary. The results of the first phase of this investigation indicated that arsenic concentrations can be remediated to below the drinking-water standard using aeration, chlorination, iron, and pH adjustment. Arsenic concentrations were remediated to less than 10 micrograms per liter in groundwater from the shallow and deep aquifer when iron concentrations of 3-6 milligrams per liter and pH adjustments to less than 6 were used. Because of the rapid depletion of dissolved oxygen, the secondary drinking-water standards for iron (300 micrograms per liter) and manganese (100 micrograms per liter) were exceeded during treatment. Treatment was more effective in the shallow well as indicated by a greater recovery of water meeting the arsenic standard. Laboratory and field tests were included in the second phase of this study. Laboratory column experiments using aquifer material indicated the treatment process followed during the first phase of this study will continue to work, without exceeding secondary drinking-water standards, provided that groundwater was pre-aerated and an adequate number of pore volumes treated. During the 147-day laboratory experiment, no decrease in flow through the column was observed. The primary mechanism of arsenic removal is through coprecipitation with iron oxide. Calculations based on the results of the column experiments and assuming 10 and 30 percent porosity indicated that treatment of approximately 237,000-714,000 gallons of water would be required in order to remediate arsenic concentrations to less than 10 micrograms per liter. During the first second-phase field experiment, effective injection of treated groundwater back into the aquifer was prevented due to clogging likely caused by entrained gases and the fine texture (sand, clay, and gravel) of the aquifer sediments. Because of the overflow of treated water from the injection wells, only 3,760 gallons of treated water were injected. Immediately upon terminating this first experiment, no arsenic remediation was apparent. However, approximately 24 hours after terminating the experiment arsenic concentrations in groundwater collected from one of the injection wells showed a decrease from about 30 to 15 micrograms per liter, indicating that some remediation had taken place. In agreement with the laboratory-column experiments, pre-aeration prevented the exceedence of the secondary drinking-water standards for iron and manganese. Because of complications associated with system hydraulics, no additional experiments were performed.

Scientific Investigations Report↗

USGS2017

Use of swabs for sampling epithelial cells for molecular genetics analyses in Enteroctopus

We evaluated the efficacy of using swabs to collect cells from the epidermis of octopus as a non-invasive DNA source for classical genetic studies, and demonstrated value of the technique by incorporating it into an effort to determine, within a day, the lineage of captured, live Enteroctopus ( E. dofleini or a cryptic lineage). The cryptic lineage was targeted for captive behavioral and morphological studies, while once genetically identified, the non-target lineage could be more rapidly released back to the wild. We used commercially available sterile foamtipped swabs and a high-salt preservation buffer to collect and store paired swab and muscle (arm tip) tissue sampled from live Enteroctopus collected from Prince William Sound, Alaska. We performed a one-day extraction of DNA from epithelial swab samples and amplification of two diagnostic microsatellite loci to determine the lineage of each of the 21 individuals. Following this rapid lineage assessment, which allowed us to release non-target individuals within a day of laboratory work, we compared paired swab and muscle tissue samples from each individual to assess quantity of DNA yields and consistency of genotyping results, followed by assessment of locus-by-locus reliability of DNA extracts from swabs. Epithelial swabs yielded, on average, lower quantities of DNA (170.32 ± 74.72 (SD) ng/μL) relative to DNA obtained from tissues collected using invasive or destructive techniques (310.95 ± 147.37 (SD) ng/μL. We observed some decrease in yields of DNA from extractions of swab samples conducted 19 and 31 months after initial extractions when samples were stored at room temperature in lysis buffer. All extractions yielded quantities of DNA sufficient to amplify and score all loci, which included fragment data from 10 microsatellite loci (nine polymorphic loci and monomorphic locus EdoμA106), and nucleotide sequence data from a 528 base pair portion of the nuclear octopine dehydrogenase gene. All results from genotyping and sequencing using paired swab and muscle tissue extracts were concordant, and experimental reliability levels for multilocus genotypes generated from swab samples exceeded 97%. This technique is useful for studies in which invasive sampling is not optimal, and in remote field situations since samples can be stored at ambient temperatures for at least 31 months. The use of epithelial swabs is thus a noninvasive technique appropriate for sampling genetic material from live octopuses for use in classical genetic studies as well as supporting experimental and behavioral studies.

American Malacological Bulletin↗

USGS2017

A geochemical examination of humidity cell tests

Humidity cell tests (HCTs) are long-term (20 to >300 weeks) leach tests that are considered by some to be the among the most reliable geochemical characterization methods for estimating the leachate quality of mined materials. A number of modifications have been added to the original HCT method, but the interpretation of test results varies widely. We suggest that the HCTs represent an underutilized source of geochemical data, with a year-long test generating approximately 2500 individual chemical data points. The HCT concentration peaks and valleys can be thought of as a “chromatogram” of reactions that may occur in the field, whereby peaks in concentrations are associated with different geochemical processes, including sulfate salt dissolution, sulfide oxidation, and dissolution of rock-forming minerals, some of which can neutralize acid. Some of these reactions occur simultaneously, some do not, and geochemical modeling can be used to help distinguish the dominant processes. Our detailed examination, including speciation and inverse modeling, of HCTs from three projects with different geology and mineralization shows that rapid sulfide oxidation dominates over a limited period of time that starts between 40 and 200 weeks of testing. The applicability of laboratory tests results to predicting field leachate concentrations, loads, or rates of reaction has not been adequately demonstrated, although early flush releases and rapid sulfide oxidation rates in HCTs should have some relevance to field conditions. Knowledge of possible maximum solute concentrations is needed to design effective treatment and mitigation approaches. Early flush and maximum sulfide oxidation results from HCTs should be retained and used in environmental models. Factors that complicate the use of HCTs include: sample representation, time for microbial oxidizers to grow, sample storage before testing, geochemical reactions that add or remove constituents, and the HCT results chosen for use in modeling the environmental performance at mine sites. Improved guidance is needed for more consistent interpretation and use of HCT results that rely on identifying: the geochemical processes; the mineralogy, including secondary mineralogy; the available surface area for reactions; and the influence of hydrologic processes on leachate concentrations in runoff, streams, and groundwater.

Applied Geochemistry↗

USGS2023

Comparison of δ13C analyses of individual foraminifer (Orbulina universa) shells by secondary ion mass spectrometry and gas source mass spectrometry

Rationale: The use of secondary ion mass spectrometry (SIMS) to perform micrometer-scale in situ carbon isotope (δ 13 C) analyses of shells of marine microfossils called planktic foraminifers holds promise to explore calcification and ecological processes. The potential of this technique, however, cannot be realized without comparison to traditional whole-shell δ 13 C values measured by gas source mass spectrometry (GSMS). Methods: Paired SIMS and GSMS δ 13 C values measured from final chamber fragments of the same shell of the planktic foraminifer Orbulina universa are compared. The SIMS–GSMS δ 13 C differences (Δ 13 C SIMS-GSMS ) were determined via paired analysis of hydrogen peroxide-cleaned fragments of modern cultured specimens and of fossil specimens from deep-sea sediments that were either untreated, sonicated, and cleaned with hydrogen peroxide or vacuum roasted. After treatment, fragments were analyzed by a CAMECA IMS 1280 SIMS instrument and either a ThermoScientific MAT-253 or a Fisons Optima isotope ratio mass spectrometer (GSMS). Results: Paired analyses of cleaned fragments of cultured specimens ( n = 7) yield no SIMS–GSMS δ 13 C difference. However, paired analyses of untreated ( n = 18) and cleaned ( n = 12) fragments of fossil shells yield average Δ 13 C SIMS-GSMS values of 0.8‰ and 0.6‰ (±0.2‰, 2 SE), respectively, while vacuum roasting of fossil shell fragments ( n = 11) removes the SIMS–GSMS δ 13 C difference. Conclusions: The noted Δ 13 C SIMS-GSMS values are most likely due to matrix effects causing sample–standard mismatch for SIMS analyses but may also be a combination of other factors such as SIMS measurement of chemically bound water. The volume of material analyzed via SIMS is ~10 5 times smaller than that analyzed by GSMS; hence, the extent to which these Δ 13 C SIMS-GSMS values represent differences in analyte or instrument factors remains unclear.

Rapid Communications in Mass Spectrometry↗

USGS2003

Use of an intact core and stable-metal isotopes to examine leaching characteristics of a fluvial tailings deposit

The upper Arkansas River south of Leadville, Colorado, USA, contains deposits of fluvial tailings from historical mining operations in the Leadville area. These deposits are possible non-point sources of acid and metal contamination to surface- and ground-water systems. We used stable-metal isotopes to help ascertain metal retention and release mechanisms that influence metal transport from the deposits to shallow ground-water systems. To accomplish this, we excavated an intact core from a small fluvial tailings deposit and performed laboratory column experiments to examine the amount of metals leaching through the core. Deionised water was continuously applied to the top of the core, and effluent was collected from the bottom of the core for a period of about two months. Three saturation conditions were used, including unsaturated, partially saturated, and fully saturated. Reducing conditions developed upon partial and complete saturation of the core. During the unsaturated leaching phase, core effluents were acidic (pH 2.8 - 3.5) and contained elevated metal concentrations. During a portion of the unsaturated leaching phase, stable-metal isotope spikes and conservative tracers were simultaneously applied to the top of the core. The isotopes provide a means to delineate metal behaviour within the core. During the unsaturated leaching phase, the isotope spikes did not exhibit breakthrough with simultaneously added conservative tracers. However, some of the stable-metal isotope spikes did break through when reducing conditions occurred in the core (during the partial- and completesaturation conditions). In this paper, we use Cd as an example of the utility of stable-metal isotopes in geochemical studies. In the case of Cd, after the core was partially saturated, the 111 Cd spike was released as evidenced by a change in the Cd isotope ratios in the effluent. This release continued during the fully saturated leaching phase, however, the total Cd concentration did not increase. These results suggest that the 111 Cd spike was retained inside the core during the unsaturated leaching phase, and only partially released as reducing conditions developed. Results from this core-leaching experiment indicate there is a large reservoir of water-soluble material within the fluvial tailings deposit, which yields elevated metal concentrations and high acidity, and which may degrade adjacent ground- and surface-water quality. Use of stable metal isotopes in this study facilitated the determination of different metal-retention processes, metal-release processes, and metal sources in the fluvial tailings deposit in response to changing geochemical conditions.

Conference Paper↗

USGS2011

Assessing the natural performance of felsic tuffs using the Rb-Sr and Sm-Nd systems-A study of the altered zone in the Topopah Spring Member, Paintbrush Tuff, Yucca Mountain, Nevada

Core samples of the Topopah Spring Member of the Paintbrush Tuff from drill hole UE25A#1 were analyzed for Sr and Nd isotopes and selected minor and trace elements to constrain the origin of a zcolitized zone associated with the lower vitrophyre. The Sm-Nd radiogenic isotope system was unperturbed by the alteration, but the Rb-Sr system was severely disturbed in the altered zone. The thick, densely welded high-silica rhyolite is remarkably uniform in composition with only a slight decrease in initial 87 Sr/ 86 Sr ratios with depth (0.7129–0.7125). Quartz latite in the upper part of the Topopah Spring has significantly lower initial Sr isotope ratios (0.7095–0.7114). Locally in the altered zone, Sr and Ca were gained in substantial amounts, and K, Rb, and Y were removed. Ti, Zr, Nb, Ba, La, Ce, Sm, and Nd were relatively immobile during the alteration. Sr added to the altered zone had an isotopic composition of 0.7119 ± 0.0002 and was probably derived from dissolution of glass in the bulk Topopah Spring (high silica rhyolite + quartz latite) and transported downward by infiltration.

Nevada↗

USGS2011

The Moon Mineralogy Mapper (M3) imaging spectrometer for lunar science: Instrument description, calibration, on‐orbit measurements, science data calibration and on‐orbit validation

The NASA Discovery Moon Mineralogy Mapper imaging spectrometer was selected to pursue a wide range of science objectives requiring measurement of composition at fine spatial scales over the full lunar surface. To pursue these objectives, a broad spectral range imaging spectrometer with high uniformity and high signal-to-noise ratio capable of measuring compositionally diagnostic spectral absorption features from a wide variety of known and possible lunar materials was required. For this purpose the Moon Mineralogy Mapper imaging spectrometer was designed and developed that measures the spectral range from 430 to 3000 nm with 10 nm spectral sampling through a 24 degree field of view with 0.7 milliradian spatial sampling. The instrument has a signal-to-noise ratio of greater than 400 for the specified equatorial reference radiance and greater than 100 for the polar reference radiance. The spectral cross-track uniformity is >90% and spectral instantaneous field-of-view uniformity is >90%. The Moon Mineralogy Mapper was launched on Chandrayaan-1 on the 22nd of October. On the 18th of November 2008 the Moon Mineralogy Mapper was turned on and collected a first light data set within 24 h. During this early checkout period and throughout the mission the spacecraft thermal environment and orbital parameters varied more than expected and placed operational and data quality constraints on the measurements. On the 29th of August 2009, spacecraft communication was lost. Over the course of the flight mission 1542 downlinked data sets were acquired that provide coverage of more than 95% of the lunar surface. An end-to-end science data calibration system was developed and all measurements have been passed through this system and delivered to the Planetary Data System (PDS.NASA.GOV). An extensive effort has been undertaken by the science team to validate the Moon Mineralogy Mapper science measurements in the context of the mission objectives. A focused spectral, radiometric, spatial, and uniformity validation effort has been pursued with selected data sets including an Earth-view data set. With this effort an initial validation of the on-orbit performance of the imaging spectrometer has been achieved, including validation of the cross-track spectral uniformity and spectral instantaneous field of view uniformity. The Moon Mineralogy Mapper is the first imaging spectrometer to measure a data set of this kind at the Moon. These calibrated science measurements are being used to address the full set of science goals and objectives for this mission.

Journal of Geophysical Research E: Planets↗

USGS2001

Seismic tomography shows that upwelling beneath Iceland is confined to the upper mantle

We report the results of the highest-resolution teleseismic tomography study yet performed of the upper mantle beneath Iceland. The experiment used data gathered by the Iceland Hotspot Project, which operated a 35-station network of continuously recording, digital, broad-band seismometers over all of Iceland 1996-1998. The structure of the upper mantle was determined using the ACH damped least-squares method and involved 42 stations, 3159 P-wave, and 1338 S-wave arrival times, including the phases P, pP, sP, PP, SP, PcP, PKIKP, pPKIKP, S, sS, SS, SKS and Sdiff. Artefacts, both perceptual and parametric, were minimized by well-tested smoothing techniques involving layer thinning and offset-and-averaging. Resolution is good beneath most of Iceland from ??? 60 km depth to a maximum of ??? 450 km depth and beneath the Tjornes Fracture Zone and near-shore parts of the Reykjanes ridge. The results reveal a coherent, negative wave-speed anomaly with a diameter of 200-250 km and anomalies in P-wave speed, Vp, as strong as -2.7 per cent and in S-wave speed, Vs, as strong as -4.9 per cent. The anomaly extends from the surface to the limit of good resolution at ??? 450 km depth. In the upper ??? 250 km it is centred beneath the eastern part of the Middle Volcanic Zone, coincident with the centre of the ??? 100 mGal Bouguer gravity low over Iceland, and a lower crustal low-velocity zone identified by receiver functions. This is probably the true centre of the Iceland hotspot. In the upper ??? 200 km, the low-wave-speed body extends along the Reykjanes ridge but is sharply truncated beneath the Tjornes Fracture Zone. This suggests that material may flow unimpeded along the Reykjanes ridge from beneath Iceland but is blocked beneath the Tjornes Fracture Zone. The magnitudes of the Vp, Vs and Vp/Vs anomalies cannot be explained by elevated temperature alone, but favour a model of maximum temperature anomalies <200 K, along with up to ??? 2 per cent of partial melt in the depth range ??? 100-300 km beneath east-central Iceland. The anomalous body is approximately cylindrical in the top 250 km but tabular in shape at greater depth, elongated north-south and generally underlying the spreading plate boundary. Such a morphological change and its relationship to surface rift zones are predicted to occur in convective upwellings driven by basal heating, passive upwelling in response to plate separation and lateral temperature gradients. Although we cannot resolve structure deeper than ??? 450 km, and do not detect a bottom to the anomaly, these models suggest that it extends no deeper than the mantle transition zone. Such models thus suggest a shallow origin for the Iceland hotspot rather than a deep mantle plume, and imply that the hotspot has been located on the spreading ridge in the centre of the north Atlantic for its entire history, and is not fixed relative to other Atlantic hotspots. The results are consistent with recent, regional full-thickness mantle tomography and whole-mantle tomography images that show a strong, low-wave-speed anomaly beneath the Iceland region that is confined to the upper mantle and thus do not require a plume in the lower mantle. Seismic and geochemical observations that are interpreted as indicating a lower mantle, or core-mantle boundary origin for the North Atlantic Igneous Province and the Iceland hotspot should be re-examined to consider whether they are consistent with upper mantle processes.

Geophysical Journal International↗

USGS2013

Natural-color and color-infrared image mosaics of the Colorado River corridor in Arizona derived from the May 2009 airborne image collection

The Grand Canyon Monitoring and Research Center (GCMRC) of the U.S. Geological Survey (USGS) periodically collects airborne image data for the Colorado River corridor within Arizona (fig. 1) to allow scientists to study the impacts of Glen Canyon Dam water release on the corridor’s natural and cultural resources. These data are collected from just above Glen Canyon Dam (in Lake Powell) down to the entrance of Lake Mead, for a total distance of 450 kilometers (km) and within a 500-meter (m) swath centered on the river’s mainstem and its seven main tributaries (fig. 1). The most recent airborne data collection in 2009 acquired image data in four wavelength bands (blue, green, red, and near infrared) at a spatial resolution of 20 centimeters (cm). The image collection used the latest model of the Leica ADS40 airborne digital sensor (the SH52), which uses a single optic for all four bands and collects and stores band radiance in 12-bits. Davis (2012) reported on the performance of the SH52 sensor and on the processing steps required to produce the nearly flawless four-band image mosaic (sectioned into map tiles) for the river corridor. The final image mosaic has a total of only 3 km of surface defects in addition to some areas of cloud shadow because of persistent inclement weather during data collection. The 2009 four-band image mosaic is perhaps the best image dataset that exists for the entire Arizona part of the Colorado River. Some analyses of these image mosaics do not require the full 12-bit dynamic range or all four bands of the calibrated image database, in which atmospheric scattering (or haze) had not been removed from the four bands. To provide scientists and the general public with image products that are more useful for visual interpretation, the 12-bit image data were converted to 8-bit natural-color and color-infrared images, which also removed atmospheric scattering within each wavelength-band image. The conversion required an evaluation of the histograms of each band’s digital-number population within each map tile throughout the corridor and the determination of the digital numbers corresponding to the lower and upper one percent of the picture-element population within each map tile. Visual examination of the image tiles that were given a 1-percent stretch (whereby the lower 1- percent 12-bit digital number is assigned an 8-bit value of zero and the upper 1-percent 12-bit digital number is assigned an 8-bit value of 255) indicated that this stretch sufficiently removed atmospheric scattering, which provided improved image clarity and true natural colors for all surface materials. The lower and upper 1-percent, 12-bit digital numbers for each wavelength-band image in the image tiles exhibit erratic variations along the river corridor; the variations exhibited similar trends in both the lower and upper 1-percent digital numbers for all four wavelength-band images (figs. 2–5). The erratic variations are attributed to (1) daily variations in atmospheric water-vapor content due to monsoonal storms, (2) variations in channel water color due to variable sediment input from tributaries, and (3) variations in the amount of topographic shadows within each image tile, in which reflectance is dominated by atmospheric scattering. To make the surface colors of the stretched, 8-bit images consistent among adjacent image tiles, it was necessary to average both the lower and upper 1-percent digital values for each wavelength-band image over 20 river miles to subdue the erratic variations. The average lower and upper 1-percent digital numbers for each image tile (figs. 2–5) were used to convert the 12-bit image values to 8-bit values and the resulting 8-bit four-band images were stored as natural-color (red, green, and blue wavelength bands) and color-infrared (near-infrared, red, and green wavelength bands) images in embedded geotiff format, which can be read and used by most geographic information system (GIS) and image-processing software. The tiff world files (tfw) are provided, even though they are generally not needed for most software to read an embedded geotiff image. All image data are projected in the State Plane (SP) map projection using the central Arizona zone (202) and the North American Datum of 1983 (NAD83). The map-tile scheme used to segment the corridor image mosaic followed the standard USGS quarter-quadrangle (QQ) map borders, but the high resolution (20 cm) of the images required further quarter segmentation (QQQ) of the standard QQ tiles, where the image mosaic covered a large fraction of a QQ map tile (segmentation shown in (figure 6), where QQ_1 to QQ_4 shows the number convention used to designate a quarter of a QQ tile). To minimize the size of each image tile, each image or map tile was subset to only include that part of the tile that had image data. In addition, some QQQ image tiles within a QQ tile were combined when adjacent QQQ map tiles were small. Thus, some image tiles consist of combinations of QQQ map tiles, some consist of an entire QQ map tile, and some consist of two adjoining QQ map tiles. The final image tiles number 143, which is a large number of files to list on the Internet for both the natural-color and color-infrared images. Thus, the image tiles were placed in seven file folders based on the one-half-degree geographic boundaries within the study area (fig. 7). The map tiles in each file folder were compressed to minimize folder size for more efficient downloading. The file folders are sequentially referred to as zone 1 through zone 7, proceeding down river (fig. 7). The QQ designations of the image tiles contained within each folder or zone are shown on the index map for each respective zone (figs. 8–14).

Arizona↗

USGS2012

Geophysical investigation of sentinel lakes in Lake, Seminole, Orange, and Volusia Counties, Florida

This study was initiated in cooperation with the St. Johns River Water Management District (SJRWMD) to investigate groundwater and surface-water interaction in designated sentinel lakes in central Florida. Sentinel lakes are a SJRWMD established set of priority water bodies (lakes) for which minimum flows and levels (MFLs) are determined. Understanding both the structure and lithology beneath these lakes can ultimately lead to a better understanding of the MFLs and why water levels fluctuate in certain lakes more so than in other lakes. These sentinel lakes have become important water bodies to use as water-fluctuation indicators in the SJRWMD Minimum Flows and Levels program and will be used to define long-term hydrologic and ecologic performance measures. Geologic control on lake hydrology remains poorly understood in this study area. Therefore, the U.S. Geological Survey investigated 16 of the 21 water bodies on the SJRWMD priority list. Geologic information was obtained by the tandem use of high-resolution seismic profiling (HRSP) and direct-current (DC) resistivity profiling to isolate both the geologic framework (structure) and composition (lithology). Previous HRSP surveys from various lakes in the study area have been successful in identifying karst features, such as subsidence sinkholes. However, by using this method only, it is difficult to image highly irregular or chaotic surfaces, such as collapse sinkholes. Resistivity profiling was used to complement HRSP by detecting porosity change within fractured or collapsed structures and increase the ability to fully characterize the subsurface. Lake Saunders (Lake County) is an example of a lake composed of a series of north-south-trending sinkholes that have joined to form one lake body. HRSP shows surface depressions and deformation in the substrate. Resistivity data likewise show areas in the southern part of the lake where resistivity shifts abruptly from approximately 400 ohm meters (ohm-m) along the edges to approximately 12 ohm-m in the center. These well-defined areas may indicate a "ravel" zone of increased porosity or clay content. Within Lake Helen (Volusia County), a parallel set of seismic reflectors within a host of chaotic reflectors may represent fill within a large sinkhole. The feature extends to more than 50 meters (m) deep and contains very steep pinnacles within the center. Seismic data in Lake Helen are supported by high resistivity values from adjacent continuous resistivity profiles that show possible center collapse within the lake and infilling of sandy material. When used together, HRSP and DC resistivity techniques provide a composite image of structure and lithology to detect potential conduits for fluid flow.

Florida↗

USGS1968

Water resources inventory of Connecticut Part 3: lower Thames and southeastern coastal river basins

The lower Thames and southeastern coastal river basins have a relatively abundant supply of water of generally good quality which is derived from streams entering the area and precipitation that has fallen on the area. Annual precipitation has ranged from about 32 inches to 65 inches and has averaged about 48 inches over a 30-year period. Approximately 22 inches of water are returned to the atmosphere each year by evaporation and transpiration; the remainder of the annual precipitation either flows overland to streams or percolates downward to the water table and ultimately flows out of the report area through estuaries and coastal streams or as underflow through the deposits beneath. During the autumn and winter months precipitation normally is sufficient to cause a substantial increase in the amount of water stored underground and in surface reservoirs within the report area, whereas in the summer most of the precipitation is lost through evaporation and transpiration, resulting in sharply reduced stream-flow and lowered ground-water levels. The mean monthly storage of water on an average is about 3.8 inches higher in November than it is in June. The amount of water that flows through and out of the report area represents the total amount of water potentially available for use by man. For the 30-year period 1931 through 1960, the annual runoff from the report area has averaged nearly 26 inches (200 billion gallons), from the entire Thames River basin above Norwich about 24 inches (530 billion gallons), and from the Pawcatuck River basin about 26 inches (130 billion gallons). A total average annual runoff of 860 billion gallons is therefore available. Although runoff indicates the total amount of water potentially available, it is usually not economically feasible for man to use all of it. On the other hand, with increased development, it is possible that some water will be reused several times. The water available may be tapped as it flows through the area or is temporarily stored in streams, lakes, and aquifers. The amounts that can be developed vary from place to place and time to time, depending on the amount of precipitation, on the size of drainage area, on the thickness, permeability, and areal extent of aquifers, and on the variations in chemical and physical quality of the water. Differences in streamflow from point to point are due primarily to differences in the proportion of stratified drift in the drainage basin above each point, which affect the timing of streamflow, and to differences in precipitation, which affect the amount of streamflow. Ground water can be obtained from wells almost anywhere in the area, but the amount obtainable at any particular point depends upon the type and water-bearing properties of the aquifers. For practical purposes, the earth materials in the report area comprise three aquifers--stratified drift, bedrock, and till. Stratified drift is the only aquifer generally capable of yielding more than 100 gpm (gallons per minute) to individual wells. It covers about 20 percent of the area and occurs chiefly in lowlands where it overlies till and bedrock. The coefficient of permeability of the coarse-grained unit of stratified drift averages about 1,500 gbd (gallons per day) per sq ft. Drilled, screened wells tapping this unit are known to yield from 4 to 88o gpm and average 146 gpm. Dug wells in coarse-grained stratified drift supply about 2 gpm per foot of drawdown over a period of a few hours. Fine-grained stratified drift has an average coefficient of permeability of about 300 gpd per sq ft and can usually yield supplies sufficient for household use to dug wells. Bedrock and till are widespread in extent but generally provide only small water supplies. Bedrock is tapped chiefly by drilled wells, about 90 percent of which will supply at least 3 gpm. Very few, however, will supply more than 50 gpm. Till is tapped in a few places by dug wells which can yield small supplies of only a few hundred gpd throughout all or most of the year. The coefficient of permeability of till ranges from about 0.2 gpd per sq ft to 120 gpd per sq ft. The amount of ground water potentially available in the report area depends upon the amount of ground-water outflow, the amount of ground water in storage, and the quantity of water available by induced infiltration from streams and lakes. From data on permeability, saturated thickness, recharge, yield from aquifer storage, well performance, and streamflow, preliminary estimates of ground-water availability can be made for any point in the report area. Long-term yields estimated for 18 areas of stratified drift especially favorable for development of large ground-water supplies ranged from 1.3 to 66 mgd. Detailed site studies to determine optimum yields, drawdowns, and spacing of individual wells are needed before major ground-water development is undertaken in these or other areas. The chemical quality of water in the report area is generally good to excellent. Samples of naturally occurring surface water collected at 24 sites contained less than 151 ppm (parts per million) of dissolved solids and less than 63 ppm of hardness. Water from wells is more highly mineralized than naturally occurring water from streams. Even so only 12 percent of the wells sampled yielded water with more than 200 ppm of dissolved solids and only 8 percent yielded water with more than 120 ppm of hardness. Even in major streams, which are used to transport industrial waste, hardness rarely exceeds 60 ppm and the dissolved mineral content is generally less than 200 ppm. At a few places in the town of Montville however, waters may contain dissolved mineral concentrations of 2,000 to 4,000 ppm. Iron and manganese in both ground water and surface water are the only constituents whose concentrations commonly exceed recommended limits for domestic and industrial use. Most wells in the report area yield clear water with little or no iron or manganese, but distributed among them are wells yielding ground water that contains enough of these dissolved constituents to be troublesome for most uses. Iron concentrations in naturally occurring stream water exceed 0.3 ppm under low-flow conditions at 33 percent of the sites sampled. Large concentrations of iron in stream water result from discharge of iron-bearing water from aquifers or from swamps where it is released largely from decaying vegetation. Ground water more than 30 feet below the land surface has a relatively constant temperature, usually between 48°F and 52°F. Water temperature in very shallow wells may fluctuate from about 38°F in February or March to about 55°F in late summer. Water temperature in the larger streams fluctuates much more widely, ranging from 32°F at least for brief periods in winter, to about 85°F occasionally during summer. The quality of suspended sediment transported by streams in the area is negligible. Turbidity in streams is generally not a problem although amounts large enough to be troublesome may occur locally at times. The total amount of water used in the report area for all purposes during 1964 was about 118,260 million gallons, of which 105,600 million gallons was estuarine water used for cooling by industry. The average per capita water use, excluding estuarine, temporary summer residence, and institutional water was equivalent to 186 gpd. Public water systems supplied the domestic needs of nearly tw0-thirds the population of the report area. All of the 19 systems, which were sampled, provided water of better quality than the U.S. Public Health Service suggests for drinking water standards.

Connecticut↗

USGS2013

Assessment of mercury and methylmercury in water, sediment, and biota in Sulphur Creek in the vicinity of the Clyde Gold Mine and the Elgin Mercury Mine, Colusa County, California

At the request of the U.S. Bureau of Land Management, we performed a study during April–July 2010 to characterize mercury (Hg), monomethyl mercury (MMeHg), and other geochemical constituents in sediment, water, and biota at the Clyde Gold Mine and the Elgin Mercury Mine, located in neighboring subwatersheds of Sulphur Creek, Colusa County, California. This study was in support of a Comprehensive Environmental Response, Compensation, and Liability Act - Removal Site Investigation. The investigation was in response to an abatement notification from the California Central Valley Regional Water Quality Control Board to evaluate the release of Hg from the Clyde and Elgin mines. Samples of water, sediment, and biota (aquatic macroinvertebrates) were collected from sites upstream and downstream from the two mine sites to evaluate the level of Hg contamination contributed by each mine to the aquatic ecosystem. Physical parameters, as well as dissolved organic carbon, total Hg (Hg T ), and MMeHg were analyzed in water and sediment. Other relevant geochemical constituents were analyzed in sediment, filtered water, and unfiltered water. Samples of aquatic macroinvertebrates from each mine were analyzed for Hg T and MMeHg. The presence of low to moderate concentrations of Hg T and MMeHg in water, sediment, and biota from the Freshwater Branch of Sulphur Creek, and the lack of significant increases in these concentrations downstream from the Clyde Mine indicated that this mine is not a significant source of Hg to the watershed during low flow conditions. Although concentrations of Hg T and MMeHg were generally higher in samples of sediment and water from the Elgin Mine compared to the Clyde Mine, concentrations in comparable biota from the two mine areas were similar. It is likely that highly saline effluent from nearby hot springs contribute more Hg to the West Fork of Sulphur Creek than the mine waste material at the Elgin Mine.

California↗