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USGS1869

Preliminary Field Report of the United States Geological Survey of Colorado and New Mexico

SIR : In accordance with your instructions dated Washington, April 1, 1869, I have the honor to transmit my preliminary field report of the United States geological survey of Colorado and New Mexico, conducted by me, under your direction, during the past season. A portion of your instructions is as follows : “You will proceed to the field of your labors as soon as the necessary arrangements can be made and the season will permit, and your attention will be especially directed to the geological, mineralogical and agricultural resources of the Territories herein designated; you will be required to ascertain the age, order of succession, relative position, dip, and comparative thickness of the different strata and geological formations, and examine with care all the beds, veins, and other deposits, of ores, coals, clays, marls, peat, and other mineral substances, as well as the fossil remains of the different formations; and you will also make full collections in geology, mineralogy, and paleontology, to illustrate your notes taken in the field.”

Colorado, New Mexico↗
USGS1993

Understanding our fragile environment; Lessons from geochemical studies

An understanding of our fragile environment can begin with a recognition of the importance of certain elements, commonly called "minerals substances" (such as iron and zinc), in the lives of humans and animals and in the soils that support plants. This recognition is well deserved because these elements are essential for the life or optimum health of an organism. Some elements such as carbon, hydrogen, oxygen, magnesium, potassium, and phosphorus are required in relatively large amounts by organisms. However, others are required in smaller quantities; these are referred to as trace elements. Diseases have been related to the deficiency of about 20 elements in animals and humans and to the deficiency of approximately 13 elements in plants. At the same time, if these and other elements occur in quantities great enough, toxicity can result. An element, or any substance, that occurs in the environment and contains concentrations above what are considered to be background levels may be considered a contaminant. When contaminants occur at levels that are potentially harmful to organisms, they are labeled as hazards. Often the quantitative difference between essential amounts and toxic concentrations of these elements is very small. For example, the trace element selenium is required at a level of no less than 0.4 ppm in the diet of cattle but can be toxic at levels greater than approximately 4ppm. Elements that are required for survival by animals and plants are termed essential, while those not required are nonessential. Trace essential elements such as fluorine, copper, selenium, molybdenum, and others listed in the table on page 1 can be hazardous to life forms if present at high levels. Nonessential heavy metals such as arsenic, lead, mercury, cadmium, and chromium are usually toxic to organisms at much lower levels than trace essential elements. Depending on the association that these nonessential elements may form with natural geologic materials such as organic matter, other elements or minerals, and adsorbers (such as clays), these elements can range from being safe to being extremely toxic. The elemental composition of plants, animals, and humans correlates with the geologic makeup of the Earth, and life has evolved reflecting these natural occurrences. The science of environmental geochemistry examines the interrelationship of life with the physical and chemical Earth.

Circular↗
USGS2013

Local-area-enhanced, 2.5-meter resolution natural-color and color-infrared satellite-image mosaics of the Baghlan mineral district in Afghanistan: Chapter P in Local-area-enhanced, high-resolution natural-color and color-infrared satellite-image mosaics of mineral districts in Afghanistan

The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Defense Task Force for Business and Stability Operations, prepared databases for mineral-resource target areas in Afghanistan. The purpose of the databases is to (1) provide useful data to ground-survey crews for use in performing detailed assessments of the areas and (2) provide useful information to private investors who are considering investment in a particular area for development of its natural resources. The set of satellite-image mosaics provided in this Data Series (DS) is one such database. Although airborne digital color-infrared imagery was acquired for parts of Afghanistan in 2006, the image data have radiometric variations that preclude their use in creating a consistent image mosaic for geologic analysis. Consequently, image mosaics were created using ALOS (Advanced Land Observation Satellite; renamed Daichi) satellite images, whose radiometry has been well determined (Saunier, 2007a,b). This part of the DS consists of the locally enhanced ALOS image mosaics for the Baghlan mineral district, which has industrial clay and gypsum deposits. ALOS was launched on January 24, 2006, and provides multispectral images from the AVNIR (Advanced Visible and Near-Infrared Radiometer) sensor in blue (420–500 nanometer, nm), green (520–600 nm), red (610–690 nm), and near-infrared (760–890 nm) wavelength bands with an 8-bit dynamic range and a 10-meter (m) ground resolution. The satellite also provides a panchromatic band image from the PRISM (Panchromatic Remote-sensing Instrument for Stereo Mapping) sensor (520–770 nm) with the same dynamic range but a 2.5-m ground resolution. The image products in this DS incorporate copyrighted data provided by the Japan Aerospace Exploration Agency (©JAXA, 2006, 2007, 2008), but the image processing has altered the original pixel structure and all image values of the JAXA ALOS data, such that original image values cannot be recreated from this DS. As such, the DS products match JAXA criteria for value added products, which are not copyrighted, according to the ALOS end-user license agreement. The selection criteria for the satellite imagery used in our mosaics were images having (1) the highest solar-elevation angles (near summer solstice) and (2) the least cloud, cloud-shadow, and snow cover. The multispectral and panchromatic data were orthorectified with ALOS satellite ephemeris data, a process which is not as accurate as orthorectification using digital elevation models (DEMs); however, the ALOS processing center did not have a precise DEM. As a result, the multispectral and panchromatic image pairs were generally not well registered to the surface and not coregistered well enough to perform resolution enhancement on the multispectral data. Therefore, it was necessary to (1) register the 10-m AVNIR multispectral imagery to a well-controlled Landsat image base, (2) mosaic the individual multispectral images into a single image of the entire area of interest, (3) register each panchromatic image to the registered multispectral image base, and (4) mosaic the individual panchromatic images into a single image of the entire area of interest. The two image-registration steps were facilitated using an automated control-point algorithm developed by the USGS that allows image coregistration to within one picture element. Before rectification, the multispectral and panchromatic images were converted to radiance values and then to relative-reflectance values using the methods described in Davis (2006). Mosaicking the multispectral or panchromatic images started with the image with the highest sun-elevation angle and the least atmospheric scattering, which was treated as the standard image. The band-reflectance values of all other multispectral or panchromatic images within the area were sequentially adjusted to that of the standard image by determining band-reflectance correspondence between overlapping images using linear least-squares analysis. The resolution of the multispectral image mosaic was then increased to that of the panchromatic image mosaic using the SPARKLE logic, which is described in Davis (2006). Each of the four-band images within the resolution-enhanced image mosaic was individually subjected to a local-area histogram stretch algorithm (described in Davis, 2007), which stretches each band’s picture element based on the digital values of all picture elements within a 315-m radius. The final databases, which are provided in this DS, are three-band, color-composite images of the local-area-enhanced, natural-color data (the blue, green, and red wavelength bands) and color-infrared data (the green, red, and near-infrared wavelength bands). All image data were initially projected and maintained in Universal Transverse Mercator (UTM) map projection using the target area’s local zone (42 for Baghlan) and the WGS84 datum. The final image mosaics were subdivided into two overlapping tiles or quadrants because of the large size of the target area. The two image tiles (or quadrants) for the Baghlan area are provided as embedded geotiff images, which can be read and used by most geographic information system (GIS) and image-processing software. The tiff world files (tfw) are provided, even though they are generally not needed for most software to read an embedded geotiff image.

Baghlan Mineral District↗
USGS2012

Mapping argillic and advanced argillic alteration in volcanic rocks, quartzites, and quartz arenites in the western Richfield 1° x 2 ° quadrangle, southwestern Utah, using ASTER satellite data

The Richfield quadrangle in southwestern Utah is known to contain a variety of porphyry Mo, skarn, polymetallic replacement and vein, alunite, and kaolin resources associated with 27-32 Ma calc-alkaline or 12-23 Ma bimodal volcano-plutonic centers in Neoproterozoic to Mesozoic carbonate and siliciclastic rocks. Four scenes of visible to shortwave-infrared image data acquired by the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor were analyzed to generate maps of exposed clay, sulfate, mica, and carbonate minerals, and ASTER thermal infrared data were analyzed to identify quartz and carbonate minerals. Argillic and advanced argillic alteration minerals including alunite, pyrophyllite, dickite, and kaolinite were identified in both undocumented (U) and known (K) areas, including in the southern Paradise Mtns. (U); in calc-alkaline volcanic rocks in the Wah Wah Mtns. between Broken Ridge and the NG area (U/K); at Wah Wah Summit in a small zone adjacent to 33.1 Ma diorite and marble (U); in fractures cutting quartzites surrounding the 20-22 Ma Pine Grove Mo deposit (U); in volcanic rocks in the Shauntie Hills (U/K); in quartzites in the west-central San Francisco Mtns. (U); in volcanic rocks in the Black Mtns. (K); and in mainly 12-13 Ma rhyolitic rocks along a 20 km E-W belt that includes the Bible Spring fault zone west of Broken Ridge, with several small centers in the Escalante Desert to the south (U/K). Argillized Navajo Sandstone with kaolinite and (or) dickite ± alunite was mapped adjacent to calc-alkaline intrusions in the Star Range (U). Intense quartz-sericite alteration (K) with local kaolinite was identified in andesite adjacent to calc-alkaline intrusions in the Beaver Lake Mountains. Mo-bearing phyllic alteration was identified in 22.2 Ma rhyolite plugs at the center of the NG alunite area. Limestones, dolomites, and marbles were differentiated, and quartz and sericite were identified in most unaltered quartzites. Halos of argillically-altered rock ≈12 km in diameter surround the Pine Grove deposit, the central rhyolites at NG, and the North Peaks just south of the Bible Spring fault zone. A southward shift from 22-23 Ma alunite at NG in the northeast to the 12-13 Ma alunite near Broken Ridge in the southwest mirrors a shift in the locus of bimodal magmatism and is similar to the southward shift of activity from the Antelope Range to Alunite Ridge (porphyry Mo potential) in the Marysvale volcanic field farther east. The poster provided in this report compares mineral maps generated from analysis of combined visible-near infrared (VNIR) and shortwave-infrared (SWIR) data and thermal infrared (TIR) ASTER data to a previously published regional geologic map. Such comparisons are used to identify and differentiate rock-forming and hydrothermal alteration-related minerals, which aids in lithologic mapping and alteration characterization over an 11,245 square kilometer area.

Utah↗
USGS2022

Preliminary geologic map of the Cherry Hill quadrangle, Dinwiddie, Sussex, and Greensville Counties, Virginia

The Cherry Hill 7.5-minute quadrangle straddles the Coastal Plain and Piedmont Provinces along the Tidewater Fall Line. Rocks of the eastern Piedmont Roanoke Rapids terrane crop out in the western part of the quadrangle and consist of greenschist- to amphibolite-facies Neoproterozoic felsic to intermediate metavolcanic rocks, some of which contain flattened quartz phenocrysts and are locally isoclinally folded; greenstone that locally preserves primary layering; and intrusive metadiorite and metagabbro, much of which has been altered to amphibolite. Most of these rocks are strongly foliated and jointed. Greenschist-facies metasiltstone that preserves primary bedding also occurs locally in the Roanoke Rapids terrane. Neoproterozoic mica schist, middle Paleozoic foliated metagranite, and late Paleozoic massive and porphyritic granite crop out in the eastern part of the quadrangle and are part of the Dinwiddie terrane and the late Paleozoic De Witt pluton. Upper greenschist- to lower amphibolite-facies mica schist consists of stringers and boudins of vein quartz and contains porphyroclasts of staurolite that preserve an earlier foliation as inclusion trails. Porphyroblasts of garnet, staurolite, and kyanite also occur locally. Foliation in granites of the De Witt pluton may be magmatic. Separating the Dinwiddie terrane from the Roanoke Rapids terrane are greenschist-facies, highly strained granitic mylonite and bodies of less deformed granite within the Nottoway River fault zone, which is a strand of the eastern Piedmont fault system. Paleozoic pegmatite dikes and quartz veins cross-cut rocks of the Dinwiddie terrane, and quartz veins and Jurassic diabase dikes cross-cut rocks of the Roanoke Rapids terrane. Sand and gravel deposits of the Atlantic Coastal Plain overlie Piedmont rocks. Two units assigned to the upper part of the Neogene Chesapeake Group occur at elevations up to 295 feet (90 meters) above sea level atop the Richmond plain in the central part of the quadrangle. Two units of the Quaternary Bacons Castle Formation occupy the Essex plain and Norge uplands at elevations up to 180 feet (55 meters) above sea level in the eastern part of the quadrangle. In the western part of the quadrangle, multiple levels of terrace deposits are the fluvial equivalent of estuarine to marine units of the Atlantic Coastal Plain to the east. Holocene alluvium occurs along creeks and the Nottoway River. Quaternary colluvial deposits occur locally. Numerous Carolina bays pock the landscape of the Richmond and Essex plains, and three abandoned channelways represent former locations of Sappony Creek, one of the major drainages of the quadrangle. Brittle faults juxtapose Piedmont basement rocks against Neogene sediments of the upper part of the Chesapeake Group. These Cenozoic faults were first uncovered in mine excavations in the late 1990s; new mapping indicates that many of these faults are reactivated silicified cataclasite zones that occur throughout the Piedmont basement rocks. Silicified cataclasites and associated quartz veins are typically mineralized with iron and iron sulfide minerals. The quadrangle was the focus of extensive mining for heavy minerals, including ilmenite and zircon, in upland Atlantic Coastal Plain deposits beginning in the mid-1990s. Other mineral resources, including precious metals, clay for structural brick, crushed stone, and building stone for millstones, have also been prospected or quarried in the quadrangle.

Virginia↗
USGS1994

Ground-water flow and quality, and geochemical processes, in Indian Wells Valley, Kern, Inyo, and San Bernardino counties, California, 1987-88

An existing water-quality data base for the 300- square-mile Indian Wells Valley was updated by means of chemical and isotopic analysis of ground water. The wide range in measured concentrations of major ions and of minor constituents such as fluoride, borate, nitrate, manganese, and iron is attributed to geochemical reactions within lacustrine deposits of the valley floor. These reactions include sulfate reduction accompanied by generation of alkalinity, precipitation of carbonates, exchange of aqueous alkaline-earth ions for sodium on clays, and dissolution of evaporite minerals. Differences in timing and location of recharge, which originates primarily in the Sierra Nevada to the west, and evapotranspiration from a shallow water table on the valley floor result in a wide range in ratios of stable hydrogen and oxygen isotopes. As ground water moves from alluvium into lustrine deposits of the ancestral China Lake, dissolved-solids concen- trations increase from about 200 to more than 1,000 milligrams per liter; further large increases to several thousand milligrams per liter occur beneath the China Lake playa. Historical data show an increase during the past 20 years in dissolved- solids concentration in several wells in the principal pumping areas at Ridgecrest and between Ridgecrest and Inyokern. The increase apparently is caused by induced flow of saline ground water from nearby China, Mirror, and Satellite Lakes. A simplified advective-transport model calculates ground-water travel times between parts of the valley of at least several thousand years, indi- cating the presence of old ground water. A local ground-water line and an evaporation line estimated using isotopic data from the China Lake area inter- sect at a delta-deuterium value of about -125 permil. This indicates that late Pleistocene recharge was 15 to 35 permil more negative than current recharge.

Water-Resources Investigations Report↗
USGS2016

Rare earth element ore geology of carbonatites

For nearly 50 years, carbonatites have been the primary source of niobium and rare earth elements (REEs), in particular the light REEs, including La, Ce, Pr, and Nd. Carbonatites are a relatively rare type of igneous rock composed of greater than 50 vol % primary carbonate minerals, primarily calcite and/or dolomite, and contain the highest concentrations of REEs of any igneous rocks. Although there are more than 500 known carbonatites in the world, currently only four are being mined for REEs: the Bayan Obo, Maoniuping, and Dalucao deposits in China, and the Mountain Pass deposit in California, United States. The carbonatite-derived laterite deposit at Mount Weld in Western Australia is also a REE producer. In addition to REEs, carbonatite-related deposits are the primary source of Nb, with the Araxá deposit, a carbonatite-derived laterite in Minas Gerais state, Brazil, being the dominant producer. Other commodities produced from carbonatite-related deposits include phosphates, iron, fluorite, copper, vanadium, titanium, uranium, and calcite. Types of ores include those formed as primary magmatic minerals, from late magmatic hydrothermal fluids, and by supergene enrichment in weathered horizons. Although the principal REE-bearing mineral phases include fluorocarbonates (bastnäsite, parisite, and synchysite), hydrated carbonates (ancylite), and phosphates (monazite and apatite), the dominant mineral exploited at most mines is bastnäsite. Bastnäsite typically is coarse grained and contains approximately 75 wt % RE 2 O 3 (rare earth oxides; REOs). Processes responsible for REE enrichment include fractional crystallization of the carbonatitic magma, enrichment of REEs in orthomagmatic or hydrothermal fluids and subsequent precipitation or subsolidus metasomatic redistribution of REEs, and breakdown of primary carbonatitic mineral phases by chemical weathering and sequestration of REEs in secondary minerals or in association with clays. Carbonatites are primarily associated with continental rifting, but some carbonatites are associated with orogenic activity. Although there is debate on how carbonatite magmas are generated, the parental magma and REEs are clearly derived from mantle sources.

Book chapter↗
USGS1994

The Pennsylvanian Fire Clay tonstein of the Appalachian basin—Its distribution, biostratigraphy, and mineralogy

The Middle Pennsylvanian Fire Clay tonstein, mostly kaolinite and minor accessory minerals, is an altered and lithified volcanic ash preserved as a thin, isochronous layer associated with the Fire Clay coal bed. Seven samples of the tonstein, taken along a 300-km traverse of the central Appalachian basin, contain cogenetic phenocrysts and trapped silicate-melt inclusions of a rhyolitic magma. The phenocrysts include beta-form quartz, apatite, zircon, sanidine, pyroxene, amphibole, monazite, garnet, biotite, and various sulfides. An inherited component of the zircons (determined from U-Pb isotope analyses) provides evidence that the source of the Fire Clay ash was Middle Proterozoic (Grenvillian) continental crust inboard of the active North American margin. 40 Ar/ 39 Ar plateau ages of seven sanidine samples from the tonstein have a mean age of 310.9 ± 0.8 Ma, which suggests that it is the product of a single, large-volume, high-silica, rhyolitic eruption possibly associated with one of the Hercynian granitic plutons in the Piedmont. Biostratigraphic analyses correlate the Fire Clay coal bed with a position just below the top of the Trace Creek Member of the Atoka Formation in the North American Midcontinent and near the Westphalian B-C boundary in western Europe.

Kentucky, Tennessee, Virginia, West Virginia↗
USGS2009

Geological controls on soil parent material geochemistry along a northern Manitoba-North Dakota transect

As a pilot study for mapping the geochemistry of North American soils, samples were collected along two continental transects extending east–west from Virginia to California, and north–south from northern Manitoba to the US–Mexican border and subjected to geochemical and mineralogical analyses. For the northern Manitoba–North Dakota segment of the north–south transect, X-ray diffraction analysis and bivariate relations indicate that geochemical properties of soil parent materials may be interpreted in terms of minerals derived from Shield and clastic sedimentary bedrock, and carbonate sedimentary bedrock terranes. The elements Cu, Zn, Ni, Cr and Ti occur primarily in silicate minerals decomposed by aqua regia, likely phyllosilicates, that preferentially concentrate in clay-sized fractions; Cr and Ti also occur in minerals decomposed only by stronger acid. Physical glacial processes affecting the distribution and concentration of carbonate minerals are significant controls on the variation of trace metal background concentrations.

Applied Geochemistry↗
USGS2015

Convergence of soil nitrogen isotopes across global climate gradients

Quantifying global patterns of terrestrial nitrogen (N) cycling is central to predicting future patterns of primary productivity, carbon sequestration, nutrient fluxes to aquatic systems, and climate forcing. With limited direct measures of soil N cycling at the global scale, syntheses of the 15 N: 14 N ratio of soil organic matter across climate gradients provide key insights into understanding global patterns of N cycling. In synthesizing data from over 6000 soil samples, we show strong global relationships among soil N isotopes, mean annual temperature (MAT), mean annual precipitation (MAP), and the concentrations of organic carbon and clay in soil. In both hot ecosystems and dry ecosystems, soil organic matter was more enriched in 15 N than in corresponding cold ecosystems or wet ecosystems. Below a MAT of 9.8°C, soil δ 15 N was invariant with MAT. At the global scale, soil organic C concentrations also declined with increasing MAT and decreasing MAP. After standardizing for variation among mineral soils in soil C and clay concentrations, soil δ 15 N showed no consistent trends across global climate and latitudinal gradients. Our analyses could place new constraints on interpretations of patterns of ecosystem N cycling and global budgets of gaseous N loss.

Scientific Reports↗
USGS2008

Geochemical evidence for airborne dust additions to soils in Channel Islands National Park, California

There is an increasing awareness that dust plays important roles in climate change, biogeochemical cycles, nutrient supply to ecosystems, and soil formation. In Channel Islands National Park, California, soils are clay-rich Vertisols or Alfisols and Mollisols with vertic properties. The soils are overlain by silt-rich mantles that contrast sharply with the underlying clay-rich horizons. Silt mantles contain minerals that are rare or absent in the volcanic rocks that dominate these islands. Immobile trace elements (Sc-Th-La and Ta-Nd-Cr) and rare-earth elements show that the basalt and andesite on the islands have a composition intermediate between upper-continental crust and oceanic crust. In contrast, the silt fractions and, to a lesser extent, clay fractions of the silt mantle have compositions closer to average upper-continental crust and very similar to Mojave Desert dust. Island shelves, exposed during the last glacial period, could have provided a source of eolian sediment for the silt mantles, but this is not supported by mineralogical data. We hypothesize that a more likely source for the silt-rich mantles is airborne dust from mainland California and Baja California, either from the Mojave Desert or from the continental shelf during glacial low stands of sea. Although average winds are from the northwest in coastal California, easterly winds occur numerous times of the year when "Santa Ana" conditions prevail, caused by a high-pressure cell centered over the Great Basin. The eolian silt mantles constitute an important medium of plant growth and provide evidence that abundant eolian silt and clay may be delivered to the eastern Pacific Ocean from inland desert sources. ?? 2007 Geological Society of America.

Geological Society of America Bulletin↗
USGS2012

The origins of Late Quaternary debris avalanche and debris flow deposits from Cofre de Perote volcano, México

Cofre de Perote volcano is a compound, shield-like volcano located in the northeastern Trans-Mexican volcanic belt. Large debris avalanche and lahar deposits are associated with the evolution of Cofre. The two best preserved of these debris-avalanche and debris-flow deposits are the ∼42 ka “Los Pescados debris flow” deposit and the ∼11–13 ka “Xico avalanche” deposit, both of which display contrasting morphological and textural characteristics, source materials, origins and emplacement environments. Laboratory X-ray diffraction and visible-infrared reflectance spectroscopy were used to identify the most abundant clay, sulfate, ferric-iron, and silica minerals in the deposits, which were either related to hydrothermal alteration or chemical weathering processes. Cloud-free Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) remote sensing imagery, supporting EO-1 Hyperion image spectra, and field ground truth samples were used to map the mineralogy and distribution of hydrothermally altered rocks on the modern summit of Cofre de Perote. The results were then compared to minerals identified in the two debris-avalanche and debris-flow deposits in order to assess possible source materials and origins for the two deposits. The older Los Pescados debris-flow deposit contains mostly halloysite and hydrous silica minerals, which match the dominant mineralogy of soils and weathered volcanic deposit in the surrounding flanks of Cofre de Perote. Its source materials were most likely derived from initially noncohesive or clay-poor flows, which subsequently bulked with clay-rich valley soils and alluvium in a manner similar to lahars from Nevado del Ruiz in 1985, but on a larger scale. The younger Xico avalanche deposit contains abundant smectite, jarosite, kaolinite, gypsum, and mixed-layered illite/smectite, which are either definitely or most likely of hydrothermal alteration origin. Smectite in particular appears to be the most abundant and spectrally dominant mineral in summit ground truth samples, ASTER mapping results, Xico avalanche deposit, and an older (pre-Xico avalanche) deposit derived from collapse(s) of ancestral Cofre de Perote edifice. However, both Xico avalanche and Los Pescados debris flow deposits show some evidence of secondary, postemplacement weathering and induration, which is evident by the presence of gibbsite, and hydroxyl interlayered minerals, in addition to recently formed halloysite and hydrous silica (i.e., indurating) cements. Field-based, visible infrared image spectroscopy (VIS/IR) spectral measurements offer the possibility of distinguishing primary minerals of hydrothermal alteration origin in debris-avalanche and debris-flow deposits from those produced either by in situ chemical weathering or bulked from weathered source materials.

Cofre de Perote volcano↗
USGS2024

Adsorption of benzene, toluene, and xylene by two tetramethylammonium-smectites having different charge densities

A high-charge smectite from Arizona [cation-exchange capacity (CEC) = 120 meq/100 g] and a low-charge smectite from Wyoming (CEC = 90 meq/100 g) were used to prepare homoionic tetramethylammonium (TMA)-clay complexes. The adsorption of benzene, toluene, and o-xylene as vapors by the dry TMA-clays and as solutes from water by the wet TMA-clays was studied. The adsorption of the organic vapors by the dry TMA-smectite samples was strong and apparently consisted of interactions with both the aluminosilicate mineral surfaces and the TMA exchange ions in the interlayers. In the adsorption of organic vapors, the closer packing of TMA ions in the dry high-charge TMA-smectite, compared with the dry low-charge TMA-smectite, resulted in a somewhat higher degree of shape-selective adsorption of benzene, toluene, and xylene. In the presence of water, the adsorption capacities of both samples for the aromatic compounds were significantly reduced, although the uptake of benzene from water by the low-charge TMA-smectite was still substantial. This lower sorption capacity was accompanied by increased shape-selectivity for the aromatic compounds. The reduction in uptake and increased selectivity was much more pronounced for the water-saturated, high-charge TMA-smectite than for the low-charge TMA-smectite. Hydration of the TMA exchange ions and/or the mineral surfaces apparently reduced the accessibility of the aromatic molecules to interlamellar regions. The resulting water-induced sieving effect was greater for the high-charge TMA-smectite due to the higher density of exchanged TMA-ions. The low-charge Wyoming TMA-smectite was a highly effective adsorbent for removing benzene from water and may be useful for purifying benzene-contaminated water.

Clays and Clay Minerals↗
USGS1991

The use of mineralogic techniques as relative age indicators for weathering profiles on the Atlantic Coastal Plain, USA

Textural, geochemical, and mineralogic study of soils and weathering profiles has led to the practice of applying varioys weathering parameters as relative age indicators. In our studies examined the entire thickness of weathered sediment (i.e., the weathering profile) for evidence of weathering-induced changes in both sand- and clay-sized mineralogy, and used two techniques for relative age determinations. These techniques were developed as tools to support geologic mapping. One of our techniques for determining relative ages is based on the depth of weathering as recorded by progressive loss of denrital sand-sized minerals upward in the weathering profile. This is our preferred tool, especially in areas where weathering profiles have been truncated. We have found a gradual trend of increasing loss of labile sand-sized minerals (e.g., hornblendes, feldspars) and increasing depth of weathering with increasing age of the deposit. Of significance to many research programs, this technique does not require expensive instruments such as an X-ray diffractometer. Our other technique depends on accumulation of stable, secondary clay-sized minerals in the upper part of the weathering profile. In our study area on the Atlantic Coastal Plain of the United States, the stable assemblage consists of vermiculite, kaolinite, gibbsite, and iron oxides and hydroxides. This technique can be effective for relative age determinations where profiles have not been truncated, and can provide useful information on depositional and erosional history. However, in areas of widespread erosion and profile truncation, such as the Carolinas, the utility of this technique for relative age determinations is limited. There, soils were partially or completely removed in many localities in relatively recent times.

Delaware, Maryland, New Jersey, North Carolina, So↗
USGS1993

Summary of the mineral- and energy-resource endowment, BLM roswell resource area, east-central New Mexico

In this summary of two comprehensive resource reports produced by the U.S. Bureau of Mines and the U.S. Geological Survey for the U.S. Bureau of Land Management, we discuss the mineral- and energyresource endowment of the 14-millon-acre Roswell Resource Area, New Mexico, managed by the Bureau of Land Management. The Bureau and Survey reports result from separate studies that are compilations of published and unpublished data and integrate new findings on the geology, geochemistry, geophysics, mineral, industrial, and energy commodities, and resources for the seven-county area. The reports have been used by the Bureau of Land Management in preparation of the Roswell Resource Area Resource Management Plan, and will have future use in nationwide mineral- and energy-resource inventories and assessments, as reference and training documents, and as public-information tools. In the Roswell Resource Area, many metals, industrial mineral commodities, and energy resources are being, or have been, produced or prospected. These include metals and high-technology materials, such as copper, gold, silver, thorium, uranium and/or vanadium, rare-earth element minerals, iron, manganese, tungsten, lead, zinc, and molybdenum; industrial mineral resources, including barite, limestone/dolomite, caliche, clay, fluorspar, gypsum, scoria, aggregate, and sand and gravel; and fuels and associated resources, such as oil, gas, tar sand and heavy oil, coal, and gases associated with hydrocarbons. Other commodities that have yet to be identified in economic concentrations include potash, halite, polyhalite, anhydrite, sulfur, feldspar, building stone and decorative rock, brines, various gases associated with oil and gas exploration, and carbon dioxide. ?? 1993 Oxford University Press.

Nonrenewable Resources↗
USGS2021

Hydrous pyrolysis of New Albany Shale: A study examining maturation changes and porosity development

The characterization of nanoscale organic structures has improved our understanding of porosity development within source-rock reservoirs, but research linking organic porosity evolution to thermal maturity has generated conflicting results. To better understand this connection, an immature (0.25% solid bitumen reflectance; BR o ) sample of the New Albany Shale was used in four isothermal hydrous pyrolysis (HP) experiment sequences at 300°, 320°, 340°, and 370°C, with residues collected periodically for a maximum of 103 days. The HP residues, along with the original immature sample and two naturally matured (1.49 and 1.56% BR o ) New Albany Shale samples were analyzed for organic petrology, total organic carbon (TOC) content, and organic porosity evaluation using correlative light and electron microscopy (CLEM). All of the HP series increased in thermal maturity with increasing duration of pyrolysis, though reflectance for each series plateaued within 25 days of maturation. Initially, TOC in the HP residues decreases (from 14.24 wt. %) with increasing thermal maturity until ∼1.0% BR o where TOC remains at ∼9–10 wt. % for all remaining residues. Qualitative CLEM observations within the 50–100 day 300° and 340°C HP sequences (0.95–1.70% BR o ), and the naturally matured samples, develop organic porosity in smaller (<5 μm in diameter), void-filling solid bitumen that occurs in spaces between clays and other fine-grained minerals. The 370°C HP residues developed significant organic porosity, relative to the other HP temperature series in all solid bitumen accumulations regardless of size. Overall, the study indicates that temperature and duration of artificial maturation play an important role in the abundance of pores in the HP residues. This work expands on our understanding of the conditions needed for the generation and development of organic porosity in the New Albany Shale and potentially in other marine source-rock petroleum systems.

Illinois, Indiana↗
USGS1986

Hydrothermal minerals and alteration rates at Surtsey volcano, Iceland

The volcanic island Surtsey, off the south coast of Iceland, was created by volcanic activity in 1963–1967. Core from a 181-m-deep hole extending 123 m below sea level shows the results of 12 yr of hydrothermal alteration of basaltic tephra. The primary cause of heating of the tephra and of development of the hydrothermal system was the intrusion of dikes below sea level. At present, the hottest part of the hole, at a maximum temperature of 150 °C, is cooling at ∼0.9 °C per year. Palagonitization of sideromelane glass, a dominant constituent of the tephra, is an important alteration process that is strongly temperature dependent, the rate doubling for every 12 °C increase. At 60 °C, <40% of the glass is palagonitized, but above 100 °C, >90% is palagonitized. Above 120 °C, olivine crystals are replaced on their edges by nontronite; the thickness of clay doubles for each 8 °C increase. Ten hydrothermal minerals have crystallized in the tephra at 25 to 150 °C; the dominant species are smectite (nontronite), analcite, phillipsite, and tobermorite. The primary clay species of palagonite is probably nontronite. Other minerals are halite, opal, calcite, chabazite, xonotlite, anhydrite, and gypsum. No major differences in mineral occurrence are noted above and below sea level, but phillipsite and tobermorite tend to grow larger below sea level, even at the same temperature. Analcite appears at lower temperature (55 °C) above sea level than below sea level (75 °C). Anhydrite is most abundant deep in the hole, where inflowing, cool sea water precipitated sulfate due to reduced sulfate solubility at higher temperatures.

Surtsey↗