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At least 487 records · Page 27Linked to original sources
USGS2018

Evolution of sulfur speciation in bitumen through hydrous pyrolysis induced thermal maturation of Jordanian Ghareb Formation oil shale

Previous studies on the distribution of bulk sulfur species in bitumen before and after artificial thermal maturation using various pyrolysis methods have indicated that the quantities of reactive (sulfide, sulfoxide) and thermally stable (thiophene) sulfur moieties change following consistent trends under increasing thermal stress. These trends show that sulfur distributions change during maturation in ways that are similar to those of carbon, most clearly illustrated by the increase in aromatic sulfur (thiophenic) as a function of thermal maturity. In this study, we have examined the sulfur moiety distributions of retained bitumen from a set of pre- and post-pyrolysis rock samples in an organic sulfur-rich, calcareous oil shale from the Upper Cretaceous Ghareb Formation. Samples collected from outcrop in Jordan were subjected to hydrous pyrolysis (HP). Sulfur speciation in extracted bitumens was examined using K-edge X-ray absorption near-edge structure (XANES) spectroscopy. The most substantial changes in sulfur distribution occurred at temperatures up to the point of maximum bitumen generation (∼300 °C) as determined from comparison of the total organic carbon content for samples before and after extraction. Organic sulfide in bitumen decreased with increasing temperature at relativ ely low thermal stress (200–300 °C) and was not detected in extracts from rocks subjected to HP at temperatures above around 300 °C. Sulfoxide content increased between 200 and 280 °C, but decreased at higher temperatures. The concentration of thiophenic sulfur increased up to 300 °C, and remained essentially stable under increasing thermal stress (mg-S/g-bitumen basis). The ratio of stable-to-reactive+stable sulfur moieties ([thiophene/(sulfide+sulfoxide+thiophene)], T/SST) followed a sigmoidal trend with HP temperature, increasing slightly up to 240 °C, followed by a substantial increase between 240 and 320 °C, and approaching a constant value (∼0.95) at temperatures above 320 °C. This sulfur moiety ratio appears to provide complementary thermal maturity information to geochemical parameters derived from other analyses of extracted source rocks.

Fuel↗
USGS2005

The ubiquitous nature of accessory calcite in granitoid rocks: Implications for weathering, solute evolution, and petrogenesis

Calcite is frequently cited as a source of excess Ca, Sr and alkalinity in solutes discharging from silicate terrains yet, no previous effort has been made to assess systematically the overall abundance, composition and petrogenesis of accessory calcite in granitoid rocks. This study addresses this issue by analyzing a worldwide distribution of more than 100 granitoid rocks. Calcite is found to be universally present in a concentration range between 0.028 to 18.8 g kg −1 (mean = 2.52 g kg −1 ). Calcite occurrences include small to large isolated anhedral grains, fracture and cavity infillings, and sericitized cores of plagioclase. No correlation exists between the amount of calcite present and major rock oxide compositions, including CaO. Ion microprobe analyses of in situ calcite grains indicate relatively low Sr (120 to 660 ppm), negligible Rb and 87 Sr/ 86 Sr ratios equal to or higher than those of coexisting plagioclase. Solutes, including Ca and alkalinity produced by batch leaching of the granitoid rocks (5% CO 2 in DI water for 75 d at 25°C), are dominated by the dissolution of calcite relative to silicate minerals. The correlation of these parameters with higher calcite concentrations decreases as leachates approach thermodynamic saturation. In longer term column experiments (1.5 yr), reactive calcite becomes exhausted, solute Ca and Sr become controlled by feldspar dissolution and 87 Sr/ 86 Sr by biotite oxidation. Some accessory calcite in granitoid rocks is related to intrusion into carbonate wall rock or produced by later hydrothermal alteration. However, the ubiquitous occurrence of calcite also suggests formation during late stage (subsolidus) magmatic processes. This conclusion is supported by petrographic observations and 87 Sr/ 86 Sr analyses. A review of thermodynamic data indicates that at moderate pressures and reasonable CO 2 fugacities, calcite is a stable phase at temperatures of 400 to 700°C.

Geochimica et Cosmochimica Acta↗
USGS2013

Ca, Sr, O and D isotope approach to defining the chemical evolution of hydrothermal fluids: example from Long Valley, CA, USA

We present chemical and isotopic data for fluids, minerals and rocks from the Long Valley meteoric-hydrothermal system. The samples encompass the presumed hydrothermal upwelling zone in the west moat of the caldera, the Casa Diablo geothermal field, and a series of wells defining a nearly linear, ∼16 km long, west-to-east trend along the likely fluid flow path. Fluid samples were analyzed for the isotopes of water, Sr, and Ca, the concentrations of major cations and anions, alkalinity, and total CO 2 . Water isotope data conform to trends documented in earlier studies, interpreted as indicating a single hydrothermal fluid mixing with local groundwater. Sr isotopes show subtle changes along the flow path, which requires rapid fluid flow and minimal reaction between the channelized fluids and the wallrocks. Sr and O isotopes are used to calculate fracture spacing using a dual porosity model. Calculated fracture spacing and temperature data for hydrothermal fluids indicate the system is (approximately) at steady-state. Correlated variations among total CO 2 , and the concentration and isotopic composition of Ca suggest progressive fluid degassing (loss of CO 2 ), which drives calcite precipitation as the fluid flows west-to-east and cools. The shifts in Ca isotopes require that calcite precipitated at temperatures of 150–180 °C is fractionated by ca. −0.3‰ to −0.5‰ relative to aqueous species. Our data are the first evidence that Ca isotopes undergo kinetic fractionation at high temperatures (>100 °C) and can be used to trace calcite precipitation along hydrothermal fluid flow paths.

California↗
USGS2016

Isotopic constraints on the genesis and evolution of basanitic lavas at Haleakala, Island of Maui, Hawaii

To understand the dynamics of solid mantle upwelling and melting in the Hawaiian plume, we present new major and trace element data, Nd, Sr, Hf, and Pb isotopic compositions, and 238 U– 230 Th– 226 Ra and 235 U– 231 Pa– 227 Ac activities for 13 Haleakala Crater nepheline normative basanites with ages ranging from ∼900 to 4100 yr B.P. These basanites of the Hana Volcanics exhibit an enrichment in incompatible trace elements and a more depleted isotopic signature than similarly aged Hawaiian shield lavas from Kilauea and Mauna Loa. Here we posit that as the Pacific lithosphere beneath the active shield volcanoes moves away from the center of the Hawaiian plume, increased incorporation of an intrinsic depleted component with relatively low 206 Pb/ 204 Pb produces the source of the basanites of the Hana Volcanics. Haleakala Crater basanites have average ( 230 Th/ 238 U) of 1.23 ( n = 13), average age-corrected ( 226 Ra/ 230 Th) of 1.25 ( n = 13), and average ( 231 Pa/ 235 U) of 1.67 ( n = 4), significantly higher than Kilauea and Mauna Loa tholeiites. U-series modeling shows that solid mantle upwelling velocity for Haleakala Crater basanites ranges from ∼0.7 to 1.0 cm/yr, compared to ∼10 to 20 cm/yr for tholeiites and ∼1 to 2 cm/yr for alkali basalts. These modeling results indicate that solid mantle upwelling rates and porosity of the melting zone are lower for Hana Volcanics basanites than for shield-stage tholeiites from Kilauea and Mauna Loa and alkali basalts from Hualalai. The melting rate, which is directly proportional to both the solid mantle upwelling rate and the degree of melting, is therefore greatest in the center of the Hawaiian plume and lower on its periphery. Our results indicate that solid mantle upwelling velocity is at least 10 times higher at the center of the plume than at its periphery under Haleakala.

Hawaii↗
USGS2022

Juvenile continental crust evolution in a modern oceanic arc setting: Petrogenesis of Cenozoic felsic plutons in Fiji, SW Pacific

Viti Levu, Fiji, provides one of the best exposed Phanerozoic analogues for the formation of juvenile continental crust in an intra-oceanic setting. Tonalites and trondhjemites are present in several large (75–150 km 2 ) adjacent, mid-Cenozoic plutons. We report major and trace element data including rare earth element (REE) and high-precision high field strength element (HFSE) compositions, new Hf-Nd-Sr-Pb isotope data, and zircon U/Pb-ages, O-Hf isotopes, and trace elements, from five different plutons. The Eocene Yavuna pluton and the Miocene Colo plutons are mainly composed of tonalites and trondhjemites and represent the exposed middle crust of the former Vitiaz island arc. The plutons can be divided into three suites. One suite is light REE (LREE) depleted with some trace element ratios lower than average normal mid-ocean ridge basalts (N-MORB). A second suite has flat REE patterns similar to local island arc basalts. Both suites occur near the coast of Viti Levu, include a wide compositional spectrum from gabbro to tonalite, and can be produced mostly by fractional crystallization of mafic precursor melts. The third suite is characterized by LREE enrichments with higher La N /Yb N (2.3–4.9), higher Zr/Y (4.3–7.1), and lower Nb/Ta (9.6–12.4). They occur closer to the center of the island and are bimodal trondhjemite-gabbro intrusions. These characteristics are consistent with formation mostly by partial melting of mafic crust. Trace element modeling shows that the trace element ratios of the third suite can be produced by 10–20 % melting of the mafic crust in the presence of residual amphibole, resulting in the retention of the medium REE (MREE) and diagnostic trace element ratios including low Nb/Ta and high Zr/Y. Geochemical similarities of the LREE enriched suite to typical “low”-pressure Archean tonalites-trondhjemites-granodiorites (TTGs) imply a common petrogenetic origin and similar mechanisms for the generation of juvenile Archean and modern differentiated crust by partial melting of mafic crust with residual amphibole. In modern oceanic arcs, genetically unrelated felsic plutonic as well as volcanic rocks co-exist, and in this regard, the Fijian plutons accompany major tectonic disruptions to arc processes.

Geochimica et Cosmochimica Acta↗
USGS2010

Evolution of earthquake-triggered landslides in the Kashmir Himalaya, northern Pakistan

The influence of the 08 October 2005 Kashmir earthquake and subsequent snow melt and monsoon rainfall on slope stability was evaluated using repeat photography in the Kashmir Himalaya of northern Pakistan. Sixty-eight landslide-affected locations were selected and photographed in November 2005, May/June 2006, June 2007, and August 2007 to evaluate all potential geomorphic changes. Eighty percent of the locations showed no or very little change, 11% of the locations showed a partial vegetation recovery on the slopes, while 9% showed an increase in the landslide area. All those locations that showed an increase in landsliding were located along rivers and/or roads. The small change in landslide extent is remarkable given that the region experienced one of the heaviest monsoon seasons in the last decade and is counter to earlier predictions of accelerated slope erosion by landsliding in the immediate years following the earthquake. Extensive fissures and ground cracks at many localities, however, still present a potential of future landsliding under wetter conditions. ?? 2009 Elsevier B.V. All rights reserved.

Geomorphology↗
USGS2011

Channel evolution on the dammed Elwha River, Washington, USA

Like many rivers in the western U.S., the Elwha River, Washington, has changed substantially over the past century in response to natural and human forcing. The lower river is affected by two upstream dams that are slated for removal as part of a major river restoration effort. In preparation for studying the effects of dam removal, we present a comprehensive field and aerial photographic analysis of dam influence on an anabranching, gravel-bed river. Over the past century with the dams in place, loss of the upstream sediment supply has caused spatial variations in the sedimentary and geomorphic character of the lower Elwha River channel. Bed sediment is armored and better sorted than on the naturally evolving bed upstream of the dams. On time scales of flood seasons, the channel immediately below the lower dam is fairly stable, but progresses toward greater mobility downstream such that the lowermost portion of the river responded to a recent 40-year flood with bank erosion and bed-elevation changes on a scale approaching that of the natural channel above the dams. In general, channel mobility in the lowest 4 km of the Elwha River has not decreased substantially with time. Enough fine sediment remains in the floodplain that – given sufficient flood forcing – the channel position, sinuosity, and braiding index change substantially. The processes by which this river accesses new fine sediment below the dams (rapid migration into noncohesive banks and avulsion of new channels) allow it to compensate for loss of upstream sediment supply more readily than would a dammed river with cohesive banks or a more limited supply of alluvium. The planned dam removal will provide a valuable opportunity to evaluate channel response to the future restoration of natural upstream sediment supply.

Washington↗
USGS2018

The evolution of a colluvial hollow to a fluvial channel with periodic steps following two transformational disturbances: A wildfire and a historic flood

The transition of a colluvial hollow to a fluvial channel with discrete steps was observed after two landscape-scale disturbances. The first disturbance, a high-severity wildfire, changed the catchment hydrology to favor overland flow, which incised a colluvial hollow, creating a channel in the same location. This incised channel became armored with cobbles and boulders following repeated post-wildfire overland flow events. Three years after the fire, a record rainstorm produced regional flooding and generated sufficient fluvial erosion and sorting to produce a fluvial channel with periodically spaced steps. An analysis of the step spacing shows that after the flood, newly formed steps retained a similar spacing to the topographic roughness spacing in the original colluvial hollow (prior to channelization). This suggests that despite a distinct change in channel form roughness and bedform morphology, the endogenous roughness periodicity was conserved. Variations in sediment erodibility helped to create the emergent steps as the largest particles ( >D84) remained immobile, becoming step features, and downstream soil was easily winnowed away.

Geomorphology↗
USGS2021

Geomorphic history of Lake Manix, Mojave Desert, California: Evolution of a complex terminal lake basin

The US Environmental Protection Agency's short-term freshwater effluent test methods include a fish ( Pimephales promelas ), a cladoceran ( Ceriodaphnia dubia ), and a green alga ( Raphidocelis subcapitata ). There is a recognized need for additional taxa to accompany the three standard species for effluent testing. An appropriate additional taxon is unionid mussels because mussels are widely distributed, live burrowed in sediment and filter particles from the water column for food, and exhibit high sensitivity to a variety of contaminants. Multiple studies were conducted to develop a relevant and robust short-term test method for mussels. We first evaluated the comparative sensitivity of two mussel species ( Villosa constricta and Lampsilis siliquoidea ) and two standard species ( P. promelas and C. dubia ) using two mock effluents prepared by mixing ammonia and five metals (cadmium, copper, nickel, lead, and zinc) or a field-collected effluent in 7-day exposures. Both mussel species were equally or more sensitive (more than two-fold) to effluents compared with the standard species. Next, we refined the mussel test method by first determining the best feeding rate of a commercial algal mixture for three age groups (1, 2, and 3 weeks old) of L. siliquoidea in a 7-day feeding experiment, and then used the derived optimal feeding rates to assess the sensitivity of the three ages of juveniles in a 7-day reference toxicant (sodium chloride [NaCl]) test. Juvenile mussels grew substantially (30%–52% length increase) when the 1- or 2-week-old mussels were fed 2 ml twice daily and the 3-week-old mussels were fed 3 ml twice daily. The 25% inhibition concentrations (IC25s) for NaCl were similar (314–520 mg Cl/L) among the three age groups, indicating that an age range of 1- to 3-week-old mussels can be used for a 7-day test. Finally, using the refined test method, we conducted an interlaboratory study among 13 laboratories to evaluate the performance of a 7-day NaCl test with L. siliquoidea . Eleven laboratories successfully completed the test, with more than 80% control survival and reliable growth data. The IC25s ranged from 296 to 1076 mg Cl/L, with a low (34%) coefficient of variation, indicating that the proposed method for L. siliquoidea has acceptable precision. Environ Toxicol Chem 2021;40:3392–3409. © 2021 SETAC

California↗
USGS2011

U-Pb (zircon) and geochemical constraints on the age, origin, and evolution of Paleozoic arc magmas in the Oyu Tolgoi porphyry Cu-Au district, southern Mongolia

Uranium–Pb (zircon) ages are linked with geochemical data for porphyry intrusions associated with giant porphyry Cu–Au systems at Oyu Tolgoi to place those rocks within the petrochemical framework of Devonian and Carboniferous rocks of southern Mongolia. In this part of the Gurvansayhan terrane within the Central Asian Orogenic Belt , the transition from Devonian tholeiitic marine rocks to unconformably overlying Carboniferous calc-alkaline subaerial to shallow marine volcanic rocks reflects volcanic arc thickening and maturation. Radiogenic Nd and Pb isotopic compositions ( ε Nd(t) range from + 3.1 to + 7.5 and 206 Pb/ 204 Pb values for feldspars range from 17.97 to 18.72), as well as low high-field strength element (HFSE) contents of most rocks (mafic rocks typically have < 1.5% TiO 2 ) are consistent with magma derivation from depleted mantle in an intra-oceanic volcanic arc. The Late Devonian and Carboniferous felsic rocks are dominantly medium- to high-K calc-alkaline and characterized by a decrease in Sr/Y ratios through time, with the Carboniferous rocks being more felsic than those of Devonian age. Porphyry Cu–Au related intrusions were emplaced in the Late Devonian during the transition from tholeiitic to calc-alkaline arc magmatism . Uranium–Pb (zircon) geochronology indicates that the Late Devonian pre- to syn-mineral quartz monzodiorite intrusions associated with the porphyry Cu–Au deposits are ~ 372 Ma, whereas granodiorite intrusions that post-date major shortening and are associated with less well-developed porphyry Cu–Au mineralization are ~ 366 Ma. Trace element geochemistry of zircons in the Late Devonian intrusions associated with the porphyry Cu–Au systems contain distinct Th/U and Yb/Gd ratios, as well as Hf and Y concentrations that reflect mixing of magma of distinct compositions. These characteristics are missing in the unmineralized Carboniferous intrusions. High Sr/Y and evidence for magma mixing in syn- to late-mineral intrusions distinguish the Late Devonian rocks associated with giant Cu–Au deposits from younger magmatic suites in the district.

Southern Mongolia↗
USGS2013

Crater topography on Titan: implications for landscape evolution

We present a comprehensive review of available crater topography measurements for Saturn’s moon Titan. In general, the depths of Titan’s craters are within the range of depths observed for similarly sized fresh craters on Ganymede, but several hundreds of meters shallower than Ganymede’s average depth vs. diameter trend. Depth-to-diameter ratios are between 0.0012 ± 0.0003 (for the largest crater studied, Menrva, D ~ 425 km) and 0.017 ± 0.004 (for the smallest crater studied, Ksa, D ~ 39 km). When we evaluate the Anderson–Darling goodness-of-fit parameter, we find that there is less than a 10% probability that Titan’s craters have a current depth distribution that is consistent with the depth distribution of fresh craters on Ganymede. There is, however, a much higher probability that the relative depths are uniformly distributed between 0 (fresh) and 1 (completely infilled). This distribution is consistent with an infilling process that is relatively constant with time, such as aeolian deposition. Assuming that Ganymede represents a close ‘airless’ analogue to Titan, the difference in depths represents the first quantitative measure of the amount of modification that has shaped Titan’s surface, the only body in the outer Solar System with extensive surface–atmosphere exchange.

Icarus↗
USGS2007

High-resolution U-series dates from the Sima de los Huesos hominids yields 600 +∞ -66 : implications for the evolution of the early Neanderthal lineage

The Sima de los Huesos site of the Atapuerca complex near Burgos, Spain contains the skeletal remains of at least 28 individuals in a mud-breccia underlying an accumulation of the Middle Pleistocene cave bear (Ursus deningeri). We report here on new high-precision dates on the recently discovered speleothem SRA-3 overlaying human bones within the Sima de los Huesos. Earlier analyses of this speleothem by TIMS (thermal-ionization mass-spectrometry) showed the lower part to be indistinguishable from internal isotopic equilibrium at the precision of the TIMS instrumentation used, yielding minimum age of 350 kyr (kyr = 103 yr before present). Reanalysis of six samples of SRA-3 by inductively-coupled plasma-multicollector mass-spectrometry (ICP-MS) produced high-precision analytical results allowing calculation of finite dates. The new dates cluster around 600 kyr. A conservative conclusion takes the lower error limit ages as the minimum age of the speleothem, or 530 kyr. This places the SH hominids at the very beginnings of the Neandertal evolutionary lineage.

Atapuerca↗
USGS2020

Temporal evolution of measured and simulated infiltration following wildfire in the Colorado Front Range, USA: Shifting thresholds of runoff generation and hydrologic hazards

Destructive flash floods and debris flows are a common menace following wildfire. The restoration of protection provided by forests from post-fire floods and debris flows depends on the recovery of infiltration and attendant reduction of infiltration-excess surface runoff generation. This work examines seven years of post-fire infiltration measurements and temporal relations fit to soil-hydraulic properties from the Colorado Front Range, USA to assess infiltration recovery with increasing time since fire. Point-scale Green-Ampt simulations of infiltration across a full spectrum of rainfall events are used to evaluate infiltration changes and shifts in surface runoff generation thresholds with post-fire temporal recovery. Measured and simulated infiltration generally recovered monotonically with increasing time since fire. This indicates a reduced vulnerability to infiltration-excess runoff generation as time elapses, with the greatest risk in the first two years after the fire. The threshold for infiltration-excess runoff advances with increasing time to rainfall events with higher intensity and greater return intervals; by the third year after wildfire only extreme events (30-100 year recurrence) generate surface runoff and by the fifth and seventh year even extreme rainfall events typically fail to generate surface runoff. Remotely-sensed vegetation indices suggest linked, or at least contemporaneous, recovery of understory vegetation and field-saturated hydraulic conductivity at this field site, suggesting coincident recovery of multiple hillslope properties impacting surface runoff generation. This work indicates that the closing of the window of disturbance after wildfire, relative to infiltration-excess runoff generation and corresponding flash flood and debris flow hazards, relies on coupled assessments of hillslope property recovery and stochasticity of high-intensity rainfall. Post-fire hazard assessments using static hillslope properties could fail to predict flash floods and debris flows associated with infrequent extreme rainfall events that strike during the post-fire recovery period when hillslope properties are partially recovered.

Colorado↗
USGS2018

Structural evolution of a gold-bearing transtensional zone within the Archean Porcupine-Destor deformation zone, southern Abitibi greenstone belt, eastern Ontario, Canada

The Garrison camp comprises four structurally distinct orogenic gold deposits that formed in different host lithologies during progressive deformation. Detailed field mapping, drill core logging, and geochronological constraints suggest that the 2678 ± 2 Ma Garrison granitic stock played a fundamental rheological role in the location of the four deposits. Initial local shear movement occurred along the southwestern margin of the stock leading to the development of the NW-trending sinistral NE-side-up Buffonta shear zone, which hosts the Buffonta deposit. Subsequently, a transtensional zone formed between the NE-trending sinistral Porcupine-Destor and Munro deformation zones, which host the 903 and Jonpol deposits, respectively. Finally, a local change in shortening orientation from NE to NNW caused westerly directed extension resulting in the formation of the younger gold-bearing veins composing the Garrcon deposit. In situ U-Pb laser ablation-inductively coupled plasma-mass spectrometry performed on monazite grains formed within the shear fabric of the Munro deformation zone indicates that transtension occurred at 2657 ± 15 Ma. Therefore, at least three of the four deposits formed subsequent to crystallization of the Garrison granitic stock. The reported U-Pb dates represent the first direct age constraints on the movement along a gold-bearing deformation zone in the southern Abitibi greenstone belt.

Ontario↗
USGS2019

The Miocene Atastra Creek sinter (Bodie Hills volcanic field, California and Nevada): 4D evolution of a geomorphically intact siliceous hot spring deposit

The Atastra Creek siliceous hot spring deposit, or sinter, occurs in the Paramount-Bald Peak alteration zone, due north of the Bodie precious metals mining district in the Miocene Bodie Hills volcanic field, California and Nevada, U.S.A. Distinctive features include its geomorphically intact geyser vent mounds, the presence of growth-fault-stepped sinter terraces that developed westward along a NNW trending fault, and atypical Hg, Sb and As concentrations. High-temperature (>75 °C), subaerial, proximal apron sinter occurs in two settings – (1) radiating botryoidal geyserite in vent mounds and (2) bedded geyserite (columnar, nodular, size-sorted geyser eggs) intercalated with mid- to low-temperature (<60 °C), middle to distal apron terrace sinter. The active geyser vent mounds migrated from south to north across the apron terrace through time. A newly recognized, visually striking type of sinter – termed silica infiltrate herein – formed directly beneath the subaerial geyserite deposits. It is characterized by mainly parallel, thin, irregular beds of white silica with narrow borders of dark blue-gray silica, as well as swirly to globular white silica, all chaotically linked together by silica ‘necks’ and ‘bridges’. The silica infiltrate permeates the pre-existing sinter, and is interpreted to represent super-heated fluid injections into the immediately overlying geyser vent mounds and pools. The adjacent sinter sheets preserve fluid-flow directions of warm-water channels that traversed the discharge apron, including microbial streamer fabric and wavy laminated sinter with flattened bubbles. More distal sinter textures are recorded by rimmed terracettes with mammillated and palisade microbial fabrics and rare, warm pool-related stromatolites. However, plants are absent, probably due to the high metalloids, in particular As. Post-depositional events include an inferred hydrothermal eruption breccia and an interpreted drop in the water table accompanied by incursion of steam acid condensate, as evidenced by pervasive hydrothermal alteration of the Atastra Creek deposits. Hence, the well-exposed sedimentary facies distributions, well-preserved geomorphology, and stratigraphic and structural relationships together allow an unusually complete, paleoenvironmental reconstruction of the Atastra Creek paleohydrothermal deposit.

Journal of Volcanology and Geothermal Research↗
USGS2004

Late Quaternary evolution of channel and lobe complexes of Monterey Fan

The modern Monterey submarine fan, one of the largest deep-water deposits off the western US, is composed of two major turbidite systems: the Neogene Lower Turbidite System (LTS) and the late Quarternary Upper Turbidite System (UTS). The areally extensive LTS is a distal deposit with low-relief, poorly defined channels, overbank, and lower-fan elements. The younger UTS comprises almost half of the total fan volume and was initiated in the late Pleistocene from canyons in the Monterey Bay area. Rapidly prograding high-relief, channel-levee complexes dominated deposition early in the UTS with periodic avulsion events. In the last few 100 ka, much of the sediment bypassed the northern fan as a result of allocyclic controls, and deposition is simultaneously occuring on a sandy lobe with low-relief channels and on an adjacent detached muddier lobe built from reconfinement of overbank flow from the northern high-relief channels. During the relatively short-lived UTS deposition, at least seven different channel types and two lobe types were formed. This study provides a significant reinterpretation of the depositional history of Monterey Fan by incorporating all available unpublished geophysical data.

California↗
USGS2025

Terrebonne Basin, Gulf of Mexico gas hydrate resource evaluation and 3-D modeling of basin-scale sedimentation, salt tectonics, and hydrate system evolution since the early Miocene

In assessing methane hydrate as a potential transitional energy source, quantification of in-place volumes of gas is a first step—and yet, global, regional, and even local estimates of gas volumes contained within hydrate are highly variable, including within the extensively-studied Gulf of Mexico (GoM) gas hydrate province. Here, we construct the first 3-D basin and hydrocarbon system model of the Terrebonne Basin (Walker Ridge protraction area, northern GoM) to estimate in-place resources contained as gas within hydrate, as well as to provide the first estimate of in-place resources contained within free gas accumulations in the basin. The resultant model-predicted 3-D distributions (and saturations) of hydrate are consistent with independent seismic interpretation and borehole observations. This study reveals both sedimentation-driven and salt diapir-driven gas hydrate recycling produce elevated hydrate saturations in the basin (“recycling” occurs when relative upward shifts of the gas hydrate stability zone (GHSZ) cause hydrate dissociation, generating buoyant free gas that may reaccumulate as higher-saturation hydrate at the new base of GHSZ). An important finding of this study (particularly given that, globally, the source of methane in marine hydrate systems tends to be poorly understood) is that microbial sources can explain most or all hydrate occurrences in Terrebonne Basin. We calculate that ∼32 × 10 9 m 3 (∼1.1 10 12 ft 3 ) of methane gas is trapped within hydrate accumulations throughout Terrebonne Basin, while nearly 2 × 10 9 m 3 (∼67 × 10 9 ft 3 ) of methane occurs as free gas at high saturations within sandy reservoirs beneath the GHSZ and ∼35 × 10 9 m 3 (∼1.2 × 10 12 ft 3 ) occurs as free gas at low saturations within muddy units beneath the GHSZ. In total, our calibrated 3-D model predicts that nearly 70 × 10 9 m 3 (∼2.5 × 10 12 ft 3 ) of microbial methane is trapped as gas hydrate and free gas in the Terrebonne Basin.

Marine and Petroleum Geology↗
USGS2017

Origin and evolution of mineralizing fluids and exploration of the Cerro Quema Au-Cu deposit (Azuero Peninsula, Panama) from a fluid inclusion and stable isotope perspective

Cerro Quema is a high sulfidation epithermal Au-Cu deposit with a measured, indicated and inferred resource of 35.98 Mt. @ 0.77 g/t Au containing 893,600 oz. Au (including 183,930 oz. Au equiv. of Cu ore). It is characterized by a large hydrothermal alteration zone which is interpreted to represent the lithocap of a porphyry system. The innermost zone of the lithocap is constituted by vuggy quartz with advanced argillic alteration locally developed on its margin, enclosed by a well-developed zone of argillic alteration, grading to an external halo of propylitic alteration. The mineralization occurs in the form of disseminations and microveinlets of pyrite, chalcopyrite, enargite, tennantite, and trace sphalerite, crosscut by quartz, barite, pyrite, chalcopyrite, sphalerite and galena veins. Microthermometric analyses of two phase (L + V) secondary fluid inclusions in igneous quartz phenocrysts in vuggy quartz and advanced argillically altered samples indicate low temperature (140–216 °C) and low salinity (0.5–4.8 wt% NaCl eq.) fluids, with hotter and more saline fluids identified in the east half of the deposit (Cerro Quema area). Stable isotope analyses (S, O, H) were performed on mineralization and alteration minerals, including pyrite, chalcopyrite, enargite, alunite, barite, kaolinite, dickite and vuggy quartz. The range of δ 34 S of sulfides is from − 4.8 to − 12.7‰, whereas δ 34 S of sulfates range from 14.1 to 17.4‰. The estimated δ 34 S ΣS of the hydrothermal fluid is − 0.5‰. Within the advanced argillic altered zone the δ 34 S values of sulfides and sulfates are interpreted to reflect isotopic equilibrium at temperatures of ~ 240 °C. The δ 18 O values of vuggy quartz range from 9.0 to 17.5‰, and the δ 18 O values estimated for the vuggy quartz-forming fluid range from − 2.3 to 3.0‰, indicating that it precipitated from mixing of magmatic fluids with surficial fluids. The δ 18 O of kaolinite ranges from 12.7 to 18.1‰ and δD from − 103.3 to − 35.2‰, whereas the δ 18 O of dickite varies between 12.7 and 16.3‰ and δD from − 44 to − 30. Based on δ 18 O and δD, two types of kaolinite/dickite can be distinguished, a supergene type and a hypogene type. Combined, the analytical data indicate that the Cerro Quema deposit formed from magmatic-hydrothermal fluids derived from a porphyry copper-like intrusion located at depth likely towards the east of the deposit. The combination of stable isotope geochemistry and fluid inclusion analysis may provide useful exploration vectors for porphyry copper targets in the high sulfidation/lithocap environment.

Azuero Peninsula↗