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Inhibition of hydroxyl radical reaction with aromatics by dissolved natural organic matter

Reaction of aromatic compounds with hydroxyl radical is inhibited by dissolved natural organic matter (NOM). The degree of inhibition is significantly greater than that expected based on a simple model in which aromatic compound molecules bound to NOM are considered to be unreactive. In this study, hydroxyl radical was produced at steady-state concentrations using Fenton chemistry (H2O2 + Fe2+ ??? Fe3+ + HO- + HO??). Suwannee River fulvic acid and humic acid were used as NOM. The most likely mechanism for the observed inhibition is that hydroxyl radical formation occurs in microenvironmental sites remote from the aromatic compounds. In addition to changes in kinetics, pyrene hydroxyl radical reaction also exhibited a mechanistic change in the presence of fulvic acid. The mechanism changed from a reaction that was apparently firstorder in pyrene to one that was apparently secondorder in pyrene, indicating that pyrene self-reaction may have become the dominant mechanism in the presence of fulvic acid. Dissolved NOM causes significant changes in the rate and mechanism of hydroxyl radical degradation of aromatic compounds. Consequently, literature rate constants measured in pure water will not be useful for predicting the degradation of pollutants in environmental systems. The kinetic and mechanistic information in this study will be useful for developing improved degradation methods involving Fenton chemistry.Reaction of aromatic compounds with hydroxyl radical is inhibited by dissolved natural organic matter (NOM). The degree of inhibition is significantly greater than that expected based on a simple model in which aromatic compounds molecules bounds to NOM are considered to be unreactive. In this study, hydroxyl radical was produced at steady-state concentrations using Fenton chemistry (H2O2 + Fe2+ ??? Fe3+ + HO- + HO??). Suwannee River fulvic acid and humic acid were used as NOM. The most likely mechanisms for the observed inhibition is that hydroxyl radical formation occurs in microenvironmental sites remote from the aromatic compounds. In addition to changes in kinetics, pyrene hydroxyl radical reaction also exhibited a mechanistic change in the presence of fulvic acid. The mechanism changed from a reaction that was apparently first-order in pyrene to one that was apparently second-order in pyrene, indicating that pyrene self-reaction may have become the dominant mechanism in the presence of fulvic acid. Dissolved NOM causes significant changes in the rate and mechanism of hydroxyl radical degradation of aromatic compounds. Consequently, literature rate constants measured in pure water will not be useful for predicting the degradation of pollutants in environmental systems. The kinetic and mechanistic information in this study will be useful for developing improved degradation methods involving Fenton chemistry.

Environmental Science & Technology

Cape Romain partnership for coastal protection

This final report summarizes activities, outcomes, and lessons learned from a 3-year project titled “Climate Change Adaptation for Coastal National Wildlife Refuges” with the Cape Romain National Wildlife Refuge (NWR) and local partners in the surrounding South Carolina Lowcountry. The Lowcountry is classified as the 10-county area encompassing the coastal plain of South Carolina (this report specifically focuses on Berkeley, Charleston, and Georgetown Counties). The goals of this work, sponsored by the U.S. Geological Survey’s Southeast Climate Adaptation Science Center (SECASC), were to foster active engagement with stakeholders; to develop a comprehensive definition of adaptation problems faced by agencies, organizations, and individuals near the Cape Romain NWR that accounts for global change, local values, knowledge and perceptions; and to encourage social learning and building of effective networks and trust across South Carolina Lowcountry organizations and individuals. Although project scoping began at the scale of the Atlantic seaboard, by engaging with NWRs from Massachusetts to Florida, participating refuge personnel eventually selected the Cape Romain NWR to serve as a case study for testing our goals. The Cape Romain Partnership for Coastal Conservation was established to address global change impacts at a regional level and includes representation from Federal and State resource agencies, local conservation nongovernmental organizations, and organizations representing underserved community interests. Research topics, originating from discussions with Cape Romain Partnership for Coastal Conservation members, focused on quantifying key drivers of change including localized sea-level rise (SLR) predictions, estimates of coastal hurricane inundation as amplified by SLR, and urban growth trends and forecasts. These key drivers provided a foundation to engage stakeholders in planning exercises to begin a process of collective understanding and collaborative decision making. The goal of this process was to develop collective strategies of adaptation to enhance community and ecosystem resilience in the South Carolina Lowcountry. South Carolina’s Lowcountry is experiencing rapid environmental and social transformation because of SLR rates approaching twice the global average, chronic tidal flooding and catastrophic storm surges, erosion and loss of habitats that provide essential services to wildlife and humans, and increasing social polarization fueled by aggressive low-density urban growth and other forms of land conversion. To support characterizations of plausible future scenarios, we used available or, in some cases, developed new models to project future conditions of key environmental and social-economic drivers. Because of the imprecision of mean global SLR projections, the SECASC commissioned a climatological study to account for local conditions and multiple representative concentration pathways to project a tailored distribution of future sea levels. These projections were matched to SLR scenarios provided by existing models to anticipate the range of future coastal habitat changes in the South Carolina Lowcountry. SLR scenarios were also incorporated into existing storm-surge models, which do not account for alternate baseline sea levels, to project the local effects of future hurricanes. To evaluate the extent and effects of population growth and urban expansion, we relied on an existing urban-growth model to map the spatial distribution of land-conversion probabilities, the total area of which is predicted to increase twofold to threefold over the next 60 years. In addition to this simplified model, an econometric model is in development to account for nonlinear feedback dynamics in land value, land use, and ecosystem service production. Although not yet completed, the goals of this model are to produce more-detailed projections of growth dynamics and to allow predictions of development patterns resulting from alternate land-use planning policies and incentives. Collaborative planning for an uncertain future requires more than providing decision makers with information on future physical and ecological conditions; developing effective and consensual strategies must also integrate sociological values, multiple cultural perspectives, and an understanding of human behavior. To support broad stakeholder engagement in integrative approaches to adaptation planning, emphasis was placed on the importance of considering differences in how individuals perceive their environment and create meaning. Because cultural frameworks form the basis for perceptions and, ultimately, the behaviors of individuals and institutions, we describe a model of human behavior and how it can be used to understand the effect of cultural complexity and variation in perception on choices, behavioral change, and long-term maintenance of behaviors. We consider a model commonly used in the field of behavioral health that accommodates variation in human perception when describing stages of behavior and the dynamics of behavioral change. Tailoring communication and engagement activities to targeted stakeholders is likely to benefit from increased understanding of behavioral change processes. The complex nature of this problem limited the usefulness of a traditional decision-analytic approach, we explored alternative methods for engagement, collaborative learning and decision making. Recognizing that project partners and Lowcountry stakeholders may be at different stages of preparedness and interest level for modifying behavior as a function of global change, we facilitated a scenario-planning exercise to familiarize partners with this well-established approach for communicating the opportunities and threats arising under alternative, plausible futures. We developed narratives for four alternative South Carolina Lowcountry scenarios to be used in later strategic planning that focus on quantitative trends for three primary drivers with high impact and high uncertainty: manifestations of climate change, social-political shifts at a global level, and forces of local value and power structures. This scenario-planning exercise underscored the complex relation between the temporospatial scale of the production of ecological goods and services and the institutional scale at which they are managed. We then guided the partners through an assessment of the relevant strengths and weaknesses of the Cape Romain Partnership for Coastal Protection, using the threats and opportunities characterized by each scenario to understand how the partnership might respond when attempting to meet conservation and societal objectives. The partnership identified key strengths including partnership experience, outreach and technical capacities, a substantial conservation land base, and high social cohesion in the South Carolina Lowcountry. Limited communication expertise, institutional inertia, and insufficient staffing and funding were recognized as important weaknesses across the partnership. By examining and scoring combinations of internal strengths and weaknesses and external threats and opportunities, the partnership developed sets of prioritized strategies to consider in the context of a given scenario. Although we had insufficient time to examine all scenarios in detail, the intent was to identify a portfolio of strategic actions to address threats and opportunities represented in multiple plausible futures. Top-ranking strategies encompassed a range of actions that focused on strengthening the conservation community and communicating the benefits of nature (that is, ecosystem services) to leveraging partnerships to expand land protection. This report also details the methods and preliminary results of several models developed or applied in support of this project. Two parcel-selection algorithms were used to evaluate anticipated habitat changes and patterns of urban growth to guide decisions on optimal conservation reserve design to protect habitat communities. One approach used a widely available planning software (MARXAN) to maximize conservation benefits near the Cape Romain NWR, whereas the other approach was a novel application of economic theory to account for uncertainty in future conditions and for the risks of unanticipated habitat loss. This latter model applies modern portfolio theory to estimate the risk of investing in any portfolio of land parcels (that is, candidate “reserves”) under climate-change uncertainty by quantifying the variation and spatial correlation of conservation benefits derived from each portfolio. We expanded the range of actions beyond simply whether or not to invest in a set of land parcels, an approach commonly used in spatial conservation planning, to also include consideration of divestment from currently protected lands. Such refinements allow for better accounting of system dynamics and can evaluate the benefits of flexible conservation tools such as rolling easements. Model results were conditional on a decision maker’s risk tolerance but highlighted general strategies of land conservation to increase future habitat representation beyond what is expected under the current protected land base. We built models that may help inform coastal planning by estimating salinity dynamics and the performance of oyster reef restoration efforts to predict the combined effects of global change and management of freshwater flows on coastal habitats and the processes that contribute to their resilience. These models can support restoration decisions by evaluating the expected benefits of site locations for shoreline protection and fisheries production. Lastly, we developed a spatially explicit economic model that predicts feedback dynamics among land value, land-use change, and effects on ecosystem service provision to explore zoning policies and incentives on urban growth and ecosystem services. We summarize these efforts with insights and considerations for the Cape Romain Partnership for Coastal Protection to continue to engage stakeholders in effective adaptation planning. First, notions of place attachment (referred to as sense of place), and the role of culture in social discourse are increasingly being used to understand the complex interactions between society and the environment and how societies respond and adapt to climate change. Sense of place was a unifying theme whenever the future of the South Carolina Lowcountry was discussed. The contribution of the South Carolina Lowcountry’s environmental wealth, rich cultural heritage, and quality of life to sense of place has important implications for how adaptation planning might best be pursued. More community-based governance of the commons (in other words, natural and cultural resources held in common), in which broad stakeholder participation and power sharing are key elements, is considered important. This devolution of governance is characterized by polycentric institutions and self-organizing social networks that promote a local culture of knowledge sharing, problem solving, and learning. These so-called bridging organizations (or individuals) often provide the leadership necessary to bring together potentially disparate Government agencies and institutions, private organizations, and individuals in a collective process of problem solving. Our observations also suggest that the conservation community in the South Carolina Lowcountry views its activities as integral to the broader governance of social-ecological systems, in which responses to the forces of global change are mediated through culture, economics, and politics. Rather than directly competing with other interests, the South Carolina Lowcountry conservation community seems to embrace an interpretation of conservation in which the fundamental objective is the quality of human life rather than environmental protection. Fundamental to the types of governance reforms described above is the notion of coproduction, in which experts and users collaborate to develop a shared body of knowledge. In this approach, scientists work with stakeholders to help frame questions, design research, and collect and analyze data. Such sustained collaborations are increasingly believed to be an effective way to produce useable (or actionable) science. The emphasis on social learning, leveraging strong social networks, coordinating and deliberating among diverse stakeholders, and applying principles of adaptive management is an essential contribution to adaptive capacity. The diverse and robust set of scientific approaches, methods to help stakeholders collaborate in effective and goal-driven planning processes, and decision tools resulting from this project hopefully will assist Cape Romain NWR and its partners prepare for climatic, ecological, and social changes over the coming decades.

South Carolina

Four-dimensional surface motions of the Slumgullion landslide and quantification of hydrometeorological forcing

Landslides modify the natural landscape and cause fatalities and property damage worldwide. Quantifying landslide dynamics is challenging due to the stochastic nature of the environment. With its large area of ~1 km 2 and perennial motions at ~10–20 mm per day, the Slumgullion landslide in Colorado, USA, represents an ideal natural laboratory to better understand landslide behavior. Here, we use hybrid remote sensing data and methods to recover the four-dimensional surface motions during 2011–2018. We refine the boundaries of an area of ~0.35 km 2 below the crest of the prehistoric landslide. We construct a mechanical framework to quantify the rheology, subsurface channel geometry, mass flow rate, and spatiotemporally dependent pore-water pressure feedback through a joint analysis of displacement and hydrometeorological measurements from ground, air and space. Our study demonstrates the importance of remotely characterizing often inaccessible, dangerous slopes to better understand landslides and other quasi-static mass fluxes in natural and industrial environments, which will ultimately help reduce associated hazards.

Colorado

The centenary of IAVCEI 1919–2019 and beyond: The people, places, and things of volcano geodesy

Over the first century of the International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI), volcano geodesy grew from roots as an accidental and incidental system of measurements to an important method for monitoring volcanic activity and forecasting eruptions. The first practitioners in volcano geodesy were experts in other disciplines, and it was not until the latter half of the twentieth century that specialists in the field emerged—scientists who developed new methods, measured geodetic change at volcanoes, and quantitatively interpreted the results in terms of magmatic processes. Much of the early work in the field was restricted to a few volcanoes and involved techniques that had been adapted from other applications; relatively few methods were developed specifically for use on volcanoes. These volcanoes, however, provided the natural laboratories needed to advance the field. By the start of the twenty-first century, geodetic studies, especially using space-based techniques, contributed to the recognition of deformation and gravity change at hundreds of volcanoes on Earth. In coming years, IAVCEI researchers will focus on comprehensive exploitation of the growing volumes of geodetic data to better model, forecast, and track activity at volcanoes worldwide. Meanwhile, the field needs to become more diverse, better representing people who live in the shadows of volcanoes around the globe.

Bulletin of Volcanology

Stable Isotope Analysis of Water and Aqueous Solutions by Conventional Dual-Inlet Mass Spectrometry

This chapter reviews the recent developments and refinements of analytical methods for preparing waters and other aqueous samples of different origins for the measurement of the oxygen and hydrogen isotopes by conventional dual-inlet, dynamic gas-source isotope-ratio mass spectrometry. The emerging techniques of continuous-flow mass-spectrometry are discussed as they are employed in both dual-inlet and continuous-flow mass-spectrometry. The size, chemical composition, and isotopic abundance of aqueous samples vary widely depending on their type, origin, and history. Automated gas equilibration methods are very suitable and are becoming standard techniques in many isotope hydrology laboratories. The increased analytical precisions are due to the subsequent development of modern gas-source isotope-ratio mass spectrometers with dual-inlets and multi-collectors, have caused the proliferation of new analytical methods and applications for the oxygen and hydrogen isotopic compositions of water. For natural hydrologic samples and new developments of continuous-flow mass spectrometry, it is possible to determine both δD and δ 18 O values, as they can provide two-dimensional information. The most significant progress in analytical techniques for stable isotope analysis of water is witnessed. Hence, overall quality control of isotopic data is becoming an important issue.

Book chapter

Automatic measurements and computations for radiochemical analyses

In natural radioactive sources the most important radioactive daughter products useful for geochemical studies are protactinium-231, the alpha-emitting thorium isotopes, and the radium isotopes. To resolve the abundances of these thorium and radium isotopes by their characteristic decay and growth patterns, a large number of repeated alpha activity measurements on the two chemically separated elements were made over extended periods of time. Alpha scintillation counting with automatic measurements and sample changing is used to obtain the basic count data. Generation of the required theoretical decay and growth functions, varying with time, and the least squares solution of the overdetermined simultaneous count rate equations are done with a digital computer. Examples of the complex count rate equations which may be solved and results of a natural sample containing four alpha-emitting isotopes of thorium are illustrated. These methods facilitate the determination of the radioactive sources on the large scale required for many geochemical investigations.

Analytical Chemistry

Evaluation of a method for comparing phosphorus loads from barnyards and croplands in Otter Creek Watershed, Wisconsin

Control of phosphorus from rural nonpoint sources is a major focus of current efforts to improve and protect water resources in Wisconsin and is recommended in almost every priority watershed plan prepared for the State's Nonpoint Source (NFS) Program. Barnyards and crop- lands usually are identified as the primary rural sources of phosphorus. Numerous questions have arisen about which of these two sources to control and about the method currently being used by the NFS program to compare phosphorus loads from barnyards and croplands. To evaluate the method, the U.S. Geological Survey (USGS). in cooperation with the Wisconsin Department of Natural Resources, used phosphorus-load and sediment-load data from streams and phosphorus concentrations in soils from the Otter Creek Watershed (located in the Sheboygan River Basin: fig. 1) in conjunction with two computer-based models.

Wisconsin

Literature review for Texas Department of Transportation Research Project 0-4695: Guidance for design in areas of extreme bed-load mobility, Edwards Plateau, Texas

A review of the literature addressing sediment transport in gravel-bed river systems and structures designed to control bed-load mobility is provided as part of Texas Department of Transportation research project 0–4695: Guidance for Design in Areas of Extreme Bed-Load Mobility. The study area comprises the western half of the Edwards Plateau in central Texas. Three primary foci of the literature review are journal articles, edited volumes, and government publications. Major themes within the body of literature include deterministic sediment transport theory and equations, development of methods to measure and analyze fluvial sediment, applications and development of theory in natural channels and flume experiments, and recommendations for river management and structural design. The literature review provides an outline and foundation for the research project to characterize extreme bed-load mobility in rivers and streams across the study area. The literature review also provides a basis upon which potential modifications to low-water stream-crossing design in the study area can be made.

Open-File Report

Documentation of computer program (FHB1) for assignment of transient specified-flow and specified-head boundaries in applications of the modular finite-diference ground-water flow model (MODFLOW)

A computer program called the Flow and Head Boundary Package (FHB1) was developed for the U.S. Geological Survey three-dimensional finite-difference modular ground-water flow model, commonly referred to as MODFLOW. FHB1 allows MODFLOW users to specify flow or head boundary conditions that vary at times other than starting and ending times of stress periods and associated time steps. Values of flow and (or) head at each time step are calculated by linear interpolation of user- specified values. The ability to assign variable flow and head conditions defined at times not corresponding with the model stress periods allows greater flexibility in simulating natural geohydrologic systems and, at the same time, improves the efficiency of the methods used to represent these systems. The package also provides a way to apply specified-flow and specified-head boundaries in embedded, or nested, smaller-scale models using flow and (or) head values from larger-scale models. Using FHB1, the two models can have different simulation stress periods and time steps. Specification of variable-flow pumped wells in ground-water models is another example application.

Open-File Report

Wet meadow regeneration through restoration of biophysical feedbacks

Wet meadows are globally significant ecosystems that provide critical hydrological, ecological, and biogeochemical functions, yet their extent has declined dramatically due to land use changes and hydrologic alteration. These sedge-dominated wetlands exist at the drier end of the wetland gradient, maintained by shallow groundwater and periodic inundation. This paper is a global synthesis of the ecological, geomorphic, and hydrological dynamics of wet meadows, with an emphasis on alluvial systems, to inform effective restoration strategies. We compare wet meadows to other wetlands, classify them into palustrine, lacustrine, and alluvial types, then focus on alluvial wet meadows and discuss how their formation and persistence depend on ground and surface water interactions, sediment deposition and flow obstructions, all mediated by biological processes. In particular, we highlight the role of hydric graminoids in resisting erosion and maintaining soil cohesion, how beaver promote meadow persistence, and the significance of wet meadows as carbon sinks. We also present stratigraphic evidence demonstrating that incision, often triggered by anthropogenic activity or changing climate, is the primary mechanism of alluvial wet meadow degradation, resulting in water table decline and shifts in vegetation composition. Restoration requires reversing these incisional processes through techniques that elevate water tables, disperse flow and retain sediment—methods traditionally associated with either soil conservation or stream restoration. These include nature-based solutions that create obstructions such as beaver dams and their analogues, rock and wood-based obstructions and incision trench or gully filling and grading. Given their multifunctional value—including but not limited to flood attenuation, biodiversity support, and carbon sequestration—wet meadows warrant a focused restoration framework. This review advocates for a valley-floor scale restoration paradigm that integrates hydrological reconnection, sediment retention, and biological reinforcement to ensure long-term resilience of these systems in the face of changing climate and land use pressures.

Frontiers in Environmental Science

Data mining for water resource management part 2 - methods and approaches to solving contemporary problems

This is the second of two papers that describe how data mining can aid natural-resource managers with the difficult problem of controlling the interactions between hydrologic and man-made systems. Data mining is a new science that assists scientists in converting large databases into knowledge, and is uniquely able to leverage the large amounts of real-time, multivariate data now being collected for hydrologic systems. Part 1 gives a high-level overview of data mining, and describes several applications that have addressed major water resource issues in South Carolina. This Part 2 paper describes how various data mining methods are integrated to produce predictive models for controlling surface- and groundwater hydraulics and quality. The methods include: - signal processing to remove noise and decompose complex signals into simpler components; - time series clustering that optimally groups hundreds of signals into "classes" that behave similarly for data reduction and (or) divide-and-conquer problem solving; - classification which optimally matches new data to behavioral classes; - artificial neural networks which optimally fit multivariate data to create predictive models; - model response surface visualization that greatly aids in understanding data and physical processes; and, - decision support systems that integrate data, models, and graphics into a single package that is easy to use.

South Carolina

Beyond technical expertise: The role of mindset, interpersonal, and intrapersonal skills in the development of fisheries professionals

Objective Recognized as essential components for success, mindset and inter- and intrapersonal skills (often referred to as soft skills) play a crucial role in the growth and effectiveness of individuals throughout their careers. Individuals with strong inter- and intrapersonal skills and a mindset open to growth can efficiently navigate complex challenges that may involve working with diverse stakeholder groups, managing interdisciplinary teams, or resolving conflicts in ways that allow them to excel beyond their technical skill sets. Although formal education of natural resources professionals (and many other professions) generally prioritizes technical skills, cultivating inter- and intrapersonal skills and a growth mindset is critical to success. Methods Drawing on presentations and discussion from an early-career symposium at the 2023 American Fisheries Society Conference, we summarize skill sets valuable for success in fisheries and natural resources. Results We provide an overview of the roles mindset and inter- and intrapersonal skills have in developing a career, how to use these competencies to navigate natural resources professions, and actions for enhancing personal skills. This paper aims to provide a compendium of information and lessons learned from natural resources professionals with diverse experiences and to emphasize familiar concepts to help formalize their discussion in the fisheries profession. Conclusion Fisheries and other natural resource fields have become increasingly interdisciplinary, necessitating a broad suite of skills to effectively communicate across disciplines, convey multiple data types, and make decisions to address complex problems. Inter- and intrapersonal skill sets are foundational to successfully navigating the fisheries profession. Moreover, personal skills transcend our profession into our everyday lives, thus strengthening personal skills is a worthy endeavor.

Fisheries

Assessment of habitat, fish communities, and streamflow requirements for habitat protection, Ipswich River, Massachusetts, 1998-99

The relations among stream habitat, fish communities, and hydrologic conditions were investigated in the Ipswich River Basin in northeastern Massachusetts. Data were assessed from 27 sites on the mainstem of the Ipswich River from July to September 1998 and from 10 sites on 5 major tributaries in July and August 1999. Habitat assessments made in 1998 determined that in a year with sustained streamflow for most of the summer, the Ipswich River contains diverse, high-quality aquatic habitat. Channel types are predominantly low gradient glides, pools, and impoundments, with a sandy streambed and a forest or shrub riparian zone. Features that provide fish habitat are located mostly along stream margins; these features include overhanging brush, undercut banks, exposed roots, and woody debris. These habitat features decrease in availability to aquatic communities with declining streamflows and generally become unavailable after streamflows drop to the point where the edge of water recedes from the stream banks. The mainstem and tributaries were sampled to determine fish species composition, relative abundance, and length frequency. Fish sampling indicates that the fish community in the Ipswich River is currently a warm-water fish community dominated by pond-type fish. However, historical temperature data, and survival of stocked trout in the mainstem Ipswich into late summer of 1998, indicate that the Ipswich River potentially could support cold-water fish species if adequate flows are maintained. Dominant fish species sampled in the mainstem Ipswich River were redfin pickerel ( Esox americanus ), American eel ( Anguilla rostrata ), and pumpkinseed ( Lepomis gibbosus ), which together represented 41, 22, and 10 percent, respectively, of 4,745 fish sampled. The fish communities of the mainstem and tributaries contained few fluvial-dependent or fluvial-specialist species (requiring flow), and were dominated by macrohabitat generalists (tolerant of low-flow, warm-water, and ponded conditions). In comparison to a nearby river (Lamprey River, N.H.), and a reference fish community developed for inland New England streams, the Ipswich fish community would be expected to have appreciably higher percentages of fluvial-dependent and fluvial-specialist species were streamflows restored. Four riffle sites on the mainstem of the Ipswich River were identified as critical habitat areas because they are among the first sites to exhibit fish-passage problems or to dry during low flows. A watershed-scale precipitation-runoff model previously developed for the Ipswich River was used to simulate streamflows at these four sites for the period 1961­95 under no withdrawals (for water supply) and 1991 land use to evaluate habitat suitability under conditions that approximate the natural flow conditions. These simulated flows were used to calculate streamflow requirements by the Tennant and New England Aquatic-Base-Flow methods. Stream channels were surveyed at the critical riffle sites, and Water Surface Profile models were used to simulate streamflows and hydraulic characteristics needed for determining streamflow requirements by use of the Wetted-Perimeter and R2Cross methods. Normalized by drainage area to units of cubic feet per second per square mile, these methods yielded the following streamflow requirements: 0.50 cubic feet per second per square mile for the Tennant 30-percent Q MA method, 0.42 cubic feet per second per square mile for the wetted-perimeter value necessary to maintain wetted perimeter at three altered riffle sites, 0.42 cubic feet per second per square mile for the R2Cross value required to maintain R2Cross hydraulic criteria at a natural riffle site, and 0.34 cubic feet per second per square mile for the aquatic-base-flow median of monthly mean flows for August for the simulated 1961­95 period under no withdrawals and 1991 land use. The mean streamflow requirement determined from these four methods is 0.42 cubic feet per second per square mile. This flow would represent an average flow-exceedence value for the six study sites of about 77 percent under simulated flows with no withdrawals. For these flows, the 70-, 80-, and 90-percent exceedence flows averaged 0.59, 0.37, and 0.21 cubic feet per second per square mile, respectively, and the 7-day, 10-year low flow statistic at the two gaged sites averaged 0.08 cubic feet per second per square mile. Simulated flows under no withdrawals were used to determine monthly mean flows and other flow statistics used in the Range of Variability Approach to define a flow regime that mimics the river's natural flow regime.

Massachusetts

Broad-scale assessments of ecological landscapes: developing methods and applications

The U.S. Department of the Interior (DOI) Bureau of Land Management (BLM) is developing a Landscape Approach for managing multiple uses of public lands by incorporating multiscale information to quantify the effects of natural and human influences on natural resource conditions and trends. A primary goal of the approach is to identify opportunities for resource conservation, restoration, and development. The BLM Landscape Approach is developing assessment methods that promote consistency in management decisions, identify ecological characteristics that promote ecosystem resilience under rapidly changing environmental conditions, and foster collaboration among land management agencies. The BLM Landscape Approach is closely aligned with the DOI’s “A Strategy for Improving the Mitigation Policies and Practices of The Department of the Interior.” A major component of the BLM Landscape Approach is the Rapid Ecoregional Assessment (REA) program. REAs identify important ecosystems and wildlife habitats at broad spatial scales and determine where these resources are at risk from environmental stressors that can affect the integrity of ecological systems. Building on the lessons learned from completed or current REAs, the BLM, in partnership with the U.S. Geological Survey, will perform systematic comparisons of REA methods to identify the most promising suite of landscape-level analysis tools. In addition, the BLM and USGS will develop practical applications that demonstrate how to incorporate assessment information to address existing management issues, such as cumulative effects of proposed management actions. The outcome of these efforts will be a set of comprehensive technical guidance documents for conducting and applying broad-scale assessments.

Fact Sheet

Changes in the C storage in Las Tablas de Daimiel National Park (PNTD) in the last 1000 years [Cambios en el almacenamiento de C en el Parque Nacional de Las Tablas de Daimiel (PNTD) en los últimos 1000 años]

Las Tablas de Daimiel National Park has suffered too many modifications throughout its history, natural as well as anthropic, which have affected the carbon storage in different ways. The study of those variations has been carried out by the analysis of sedimentary record and historical data. The sedimentary record has been studied from the core Ciguela 4. It was sampled with a systematic high resolution method (0.7 cm thickness average) to analyze geochemistry and pollen. The analysis of all data shows that the natural changes (linked with the climate) have more variation ranges than the anthropic ones, are directly related with the climate and not with the concentration of the atmospheric CO2, showing a natural cyclicity with a fast mitigation (decades) of the variations. In the other hand the anthropogenic impacts depend on the proximity and intensity of the impact. The usage changes produced during the second half of the 19th century were an indirect impact with medium intensity. The environment had the capacity to recover the values of a normal storage in less than 50 years. Nevertheless the dissication and overexploitation of the groundwater (second half of 20th century) were direct and high intensity impacts. These impacts caused a fast loss of the water table and the salinization of the environment. Due to that the ecosystem lost capacity to store C. recovery of the normal values by a natural way is difficult now.

Las Tablas de Daimiel National Park

Change points in annual peak streamflows: Method comparisons and historical change points in the United States

Change-point, or step-trend, detection is an active area of research in statistics and an area of great interest in hydrology because change points may be evidence of natural or anthropogenic changes in climatic, hydrologic, or landscape processes. A common change-point technique is the Pettitt test; however, many change-point methods are now available and testing of methods has been limited. This study investigated eight methods for detecting change points in the location (central tendency, seven methods) and scale (dispersion or spread, one method) of annual peak streamflows, using simulated data with and without change points, and peak-streamflow series from basins with known large additions of reservoir storage. Parametric methods tested, including a Bayesian one, did not perform well, even when transforming peak streamflows to approximate normality by using logarithms. Nonparametric methods other than the Pettitt test allow for more than one change point but have an unacceptable number of false positives. Based on the results of our methods comparisons, we used the Pettitt and the Mood tests to find change points in location and scale, respectively, in thousands of streamgage records in the conterminous United States. Change points in location (median) and scale are abundant, with the changes in median peak streamflow showing regional patterns, as well as a strong increased streamflow signal around 1970. The changes in scale of peak streamflows are dominated more by temporal than spatial patterns; more streamgages had decreases in scale in earlier decades than recent decades and more streamgages had increases in scale occurring in recent decades than earlier decades.

Journal of Hydrology

A method for determining transmissibility‐ and storage‐coefficients by tests of multiple well‐systems

Ground‐water has long been recognized as one of our important natural resources, but only in about the last 20 years has concentrated effort been made to place ground‐water hydrology on a quantitative basis. The quantitative approach to ground‐water work has been brought about largely through the leadership of O. E. MEINZER, Chief of the Ground‐Water Division of the Geological Survey, United States Department of the Interior, who has originated and applied many quantitative methods himself, and who has consistently fostered and encouraged this method of attack by his coworkers. That this effort has been ably directed and especially fruitful Is shown by the vast number of important ground‐water problems relating to the water‐supplies for war activities that have been worked out by means of quantitative methods in the last few years.

Eos, Transactions, American Geophysical Union

Reduced population variance in strontium isotope values informs domesticated turkey use at Chaco Canyon, New Mexico, USA

Traditionally strontium isotopes (87Sr/86Sr) have been used as a sourcing tool in numerous archaeological artifact classes. The research presented here demonstrates that 87Sr/86Srbioapatite ratios also can be used at a population level to investigate the presence of domesticated animals and methods of management. The proposed methodology combines ecology, isotope geochemistry, and behavioral ecology to assess the presence and nature of turkey (Meleagris gallopavo) domestication. This case study utilizes 87Sr/86Srbioapatite ratios from teeth and bones of archaeological turkey, deer (Odocoileus sp.), lagomorph (Lepus sp. and Sylvilagus sp.), and prairie-dog (Cynomys sp.) from Chaco Canyon, New Mexico, U.S.A. (ca. A.D. 800 – 1250). Wild deer and turkey from the southwestern U.S.A. have much larger home ranges and dispersal behaviors (measured in kilometers) when compared to lagomorphs and prairie dogs (measured in meters). Hunted deer and wild turkey from archaeological contexts at Chaco Canyon are expected to have a higher variance in their 87Sr/86Srbioapatite ratios, when compared to small range taxa (lagomorphs and prairie dogs). Contrary to this expectation, 87Sr/86Srbioapatite values of turkey bones from Chacoan assemblages have a much lower variance than deer and are similar to that of smaller mammals. The sampled turkey values show variability most similar to lagomorphs and prairie dogs, suggesting the turkeys from Chaco Canyon were consuming a uniform diet and/or were constrained within a limited home range, indicating at least proto-domestication. The population approach has wide applicability for evaluating the presence and nature of domestication when combined with paleoecology and behavioral ecology in a variety of animals and environments.

New Mexico