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Effects of urbanization on stream water quality in the city of Atlanta, Georgia, USA

A long-term stream water quality monitoring network was established in the city of Atlanta, Georgia during 2003 to assess baseline water quality conditions and the effects of urbanization on stream water quality. Routine hydrologically based manual stream sampling, including several concurrent manual point and equal width increment sampling, was conducted ???12 times annually at 21 stations, with drainage areas ranging from 3.7 to 232 km 2 . Eleven of the stations are real-time (RT) stations having continuous measures of stream stage/ discharge, pH, dissolved oxygen, specific conductance, water temperature and turbidity, and automatic samplers for stormwater collection. Samples were analyzed for field parameters, and a broad suite of water quality and sediment-related constituents. Field parameters and concentrations of major ions, metals, nutrient species and coliform bacteria among stations were evaluated and with respect to watershed characteristics and plausible sources from 2003 through September 2007. Most constituent concentrations are much higher than nearby reference streams. Concentrations are statistically different among stations for several constituents, despite high variability both within and among stations. Routine manual sampling, automatic sampling during stormflows and RT water quality monitoring provided sufficient information about urban stream water quality variability to evaluate causes of water quality differences among streams. Fecal coliform bacteria concentrations of most samples exceeded Georgia's water quality standard for any water-usage class. High chloride concentrations occur at three stations and are hypothesized to be associated with discharges of chlorinated combined sewer overflows, drainage of swimming pool(s) and dissolution and transport during rainstorms of CaCl 2 , a deicing salt applied to roads during winter storms. One stream was affected by dissolution and transport of ammonium alum [NH 4 Al(SO 4 ) 2 ] from an alum-manufacturing plant; streamwater has low pH (<5), low alkalinity and high metals concentrations. Several trace metals exceed acute and chronic water quality standards and high concentrations are attributed to washoff from impervious surfaces.

Hydrological Processes

A comparison of contemporary and historical hydrology and water quality in the foothills and coastal plain of the Arctic National Wildlife Refuge, Arctic Slope, northern Alaska

The Arctic National Wildlife Refuge is a unique landscape in northern Alaska with limited water resources, substantial biodiversity of rare and threatened species, as well as oil and gas resources. The region has unique hydrology related to perennial springs, and the formation of large aufeis fields—sheets of ice that grow in the river channels where water reaches the surface in the winter and freezes. This work aims to update our understanding of water resources and water quality in the springs, streams, rivers, and lakes of this region, returning to sites sampled by the U.S. Geological Survey in the 1970s. We resampled eight streams, four springs, and six lakes for hydrological metrics, water quality, and macroinvertebrates, and recalculated flood-frequency metrics for rivers using updated data and modern techniques. Aufeis field melt rates were also assessed for the past several decades. Although the available data preclude trend determinations in most cases, our analysis and comparison to the historical sampling indicates an increase in dissolved ions for streams and springs, faster and earlier aufeis melt, and similar macroinvertebrate populations.

Alaska

Multi-decadal erosion rates from glacierized watersheds on Mount Baker, Washington, USA, reveal topographic, climatic, and lithologic controls on sediment yields

Understanding land surface change in and sediment export out of proglacial landscapes is critical for understanding geohazard and flood risks over engineering timescales and characterizing landscape evolution over geomorphic timescales. We used automated Structure from Motion software to process historical aerial photographs and, with modern lidar data, generated a high-resolution DEM time series with coverage over 10 glacierized watersheds on Mount Baker, Washington, USA for the time period between 1947 and 2015. We measured basin-wide sediment yields and sediment redistribution on hillslopes and in stream channels. Slopes within most measured erosion sites are above theoretical and observed debris-flow thresholds. We observed significant erosion of hillslopes and limited deposition on hillslopes and in stream channels. Sediment delivery ratios during time periods with net erosion averaged 0.73. We determined, consistent with previous field observations, that debris flows originating from moraines are a primary erosion mechanism in proglacial zones on Mount Baker. Time series measurements indicate that temporal variability in erosion rates is associated with climate oscillations, with higher erosion rates during cooler-wetter periods. Basin-wide sediment yield is positively correlated with lithology (r 2 = 0.54), hillslope angle (r 2 = 0.52), drainage area (r 2 = 0.82), and negatively correlated with stream channel slope (r 2 = 0.67). Topographic differences between high and low yielding basins indicate that spatial variability in erosion on Mount Baker is sensitive to Pleistocene and Holocene glacial and volcanic activity. Specific sediment yields in six basins averaged 4600 ton/km 2 /yr, consistent with global measurements in glacierized catchments. Specific sediment yield decreased with increasing basin area, with total loads in the downstream main stem Nooksack River estimated between 480 and 820 ton/km 2 /yr. Proglacial sediment yields account for between 18 and 32 % of total sediment load in the main stem Nooksack River and exceed contributions by bluff and terrace erosion, which account for between 8 and 13 % of total load. Our findings indicate that erosion in glacierized basins is sensitive to decadal climate oscillations and that high proglacial sediment yields provide an important contribution to river systems downstream, particularly in catchments where upland topography and lithology is favorable.

Washington

Stoichiometric relationship between suspension-feeding caddisfly (Trichoptera: Brachycentridae) and seston

Organisms must acquire adequate amounts of carbon (C) and nutrients [i.e., nitrogen (N) and phosphorus (P)] from their food to support growth. The growth of organisms can be constrained by consumer-resource elemental imbalances in C:nutrient ratios, especially in aquatic ecosystems. Furthermore, the elemental composition of aquatic organisms can change through ontogeny, which can impose additional challenges to growth (the growth rate hypothesis), terminal body size, and reproductive output. In streams, growth in larval aquatic insects is influenced primarily by food quality and quantity, temperature, and population density. We conducted a field study that tracked the growth of a common suspension-feeding caddisfly ( Brachycentrus occidentalis ) through its ontogeny by comparing the elemental composition (C:N:P) of the organism with its available food supply (suspended particulate organic matter or seston). Larvae and seston were sampled from four streams throughout 1 year. Differences in the growth of larvae among the streams were evident, even though the streams possessed similar thermal regimes. Spatial and temporal differences in the nutrient contents of B. occidentalis and seston were observed, suggesting a consumer-resource elemental imbalance. Lower C:P and N:P ratios in food were positively correlated to larval growth rate, suggesting growth was limited by P. The C, N, and P contents in B. occidentalis ’ body tissue did change throughout ontogeny. C:nutrient ratios varied across sites during larval development; however, inter-site variation decreased substantially as the populations approached pupation. Ultimately, consumer-resource elemental imbalances during the larval stage did not lead to differences in pre-emergent standing stocks across sites.

Hydrobiologia

Geohydrologic summary of the Pearl River basin, Mississippi and Louisiana

Fresh water in abundance is contained in large artesian reservoirs in sand and gravel deposits of Tertiary and Quaternary ages in the Pearl River basin, a watershed of 8,760 square miles. Shallow, water-table reservoirs occur in Quarternary deposits (Pleistocene and Holocene) that blanket most of the uplands in .the southern half of the basin and that are present in smaller upland areas and along streams elsewhere. The shallow reservoirs contribute substantially to dry-weather flow of the Strong River and Bogue Chitto and of Holiday, Lower Little, Silver, and Whitesand Creeks, among others. About 3 billion acre-feet of ground water is in storage in the fresh-water section, which extends from the surface to depths ranging from about sea level in the extreme northern part of the basin to more than 3,000 feet below sea level in the southern part of the basin. Variations in low flow for different parts of the river basin are closely related to geologic terrane and occurrence of ground water. The upland terrace belt that crosses the south-central part of the basin is underlain by permeable sand and gravel deposits and yields more than 0.20 cubic feet per second per square mile of drainage area to streamflow, whereas the northern part of the basin, underlain by clay, marl, and fine to medium sand, yields less than 0.05 cubic feet per second per square mile of drainage area (based on 7-day Q2 minimum flow computed from records). Overall, the potential surface-water supplies are large. Because water is available at shallow depths, most of the deeper aquifers have not been developed anywhere in the basin. At many places in the south, seven or more aquifers could be developed either by tapping one sand in each well or by screening two or more sands in a single well. Well fields each capable, of producing several million gallons of water a day are feasible nearly anywhere in the Pearl River basin. Water in nearly all the aquifers is of good to excellent quality and requires little or no treatment for most uses. The water is a soft, sodium bicarbonate type and therefore has a low to moderate dissolved-solids content. Mineral content increases generally downdip in an aquifer. Excessive iron, common in shallow aquifers, is objectionable for some water uses. Water from the streams, except in salty tidal reaches, is less mineralized than ground water; in 10 sites the median dissolved-solids content in streamflow was 50 milligrams per liter or less. Moderately intensive ground-water development has been made in the Bogalusa area, Louisiana; at the Mississippi Test Facility, Hancock County, Miss. ; and in the Jackson area, Mississippi. Wells with pumping rates of 500 to 1,000 gallons per minute each are common throughout the Pearl River basin, and some deep wells flow more than 3,000 gallons per minute in the coastal lowland areas. Probably 20 million gallons per day of artesian water flows uncontrolled from wells in the southern part of the basin. Ground-water levels, except in the higher altitudes, are within 60 feet of the surface, and flowing wells are common in the valleys and in the coastal Pine Meadows. Decline of water level is a problem in only a few small areas. Saline water as a resource is available for development from aquifers and streams near the coast and from aquifers at considerable depth in most of the Pearl River basin. Pollution is a problem in oil fields and in reaches of some streams below sewage and other waste-disposal points. The basin estuary contains water of variable quality but has potential for certain water-use developments that will require special planning and management.

Water Supply Paper

Field manual for the investigation of fish kills

Preface Fish kills are graphic evidence of serious problems in a lake or stream. If the kill is related to the presence of toxic chemicals, there may be human health concerns, in addition to the obvious damage to the ecosystem and the fisheries resources. Depending on the cause of a fish kill, legal and economic ramifications may be involved. If the kill is cause by human or corporate actions, litigation is likely to follow, with possible court-awarded damages and assessed costs for cleanup and restoration. Federal and State agencies have expressed the need for a compendium of known and accepted methods and techniques that should be followed by anyone investigation a fish kill. This manual is an attempt to fill that need. It addresses the many facets involved in a fish kill investigation and provides instruction, guidance, examples, and sample forms that can be used. The U.S. Fish and Wildlife Service is pleased to provide this manual to help fisheries biologists and others prepare for a fish kill investigation. Research and Development (Region 8) has cooperated with the Division of Environmental Contaminants in Fish and Wildlife Enhancement to provide expertise and funds. We hope that the manual proves to be useful for interpreting evidence at the site of a fish kill, and corrective actions, and preparing for appearance as a court witness.

Resource Publication

Modelling streamwater chemistry as a mixture of soilwater end-members - A step towards second-generation acidification models

In present acidification models, soilwater characteristics, though modelled, are seldom checked against field observations. Given that such data are now collected as part of many catchment studies, a technique is developed whereby stream water can be predicted as a mixture of the observed soilwater classes or end-members. Provided that a sufficient set of end-members has been identified, a least-squares technique can be used to estimate the contribution to the stream from each end-member, whenever streamwater samples have been taken. For two catchments, Birkenes in southern Norway and Plynlimon in Mid-Wales, the analysis indicates that the soilwater end-members observed to date are insufficient to explain streamwater chemistry. However, properties of the missing soil waters have been identified, thus facilitating future field work. When an adequate set of soilwater end-members has been established, long-term predictions of changes in streamwater chemistry reduce to the problem of predicting the fate of each end-member. Thus, a separate hydrological submodel is not needed, since the mixing patterns are derived from the end-member analysis.

Journal of Hydrology

An experimental evaluation of the feasibility of inferring concentrations of a visible tracer dye from remotely sensed data in turbid rivers

The movement of contaminants and biota within river channels is influenced by the flow field via various processes of dispersion. Understanding and modeling of these processes thus can facilitate applications ranging from the prediction of travel times for spills of toxic materials to the simulation of larval drift for endangered species of fish. A common means of examining dispersion in rivers involves conducting tracer experiments with a visible tracer dye. Whereas conventional in situ instruments can only measure variations in dye concentration over time at specific, fixed locations, remote sensing could provide more detailed, spatially distributed information for characterizing dispersion patterns and validating two-dimensional numerical models. Although previous studies have demonstrated the potential to infer dye concentrations from remotely sensed data in clear-flowing streams, whether this approach can be applied to more turbid rivers remains an open question. To evaluate the feasibility of mapping spatial patterns of dispersion in streams with greater turbidity, we conducted an experiment that involved manipulating dye concentration and turbidity while acquiring field spectra and hyperspectral and RGB (red, green, blue) images from a small Unoccupied Aircraft System (sUAS). Applying an Optimal Band Ratio Analysis (OBRA) algorithm to these data sets indicated strong relationships between reflectance (i.e., water color) and Rhodamine WT dye concentration across four different turbidity levels from 40-60 NTU. Moreover, we obtained high correlations between spectrally based quantities (i.e., band ratios) and dye concentration for the original, essentially continuous field spectra; field spectra resampled to the bands of a five-band imaging system and an RGB camera; and both hyperspectral and RGB images acquired from a sUAS during the experiment. The results of this study thus confirmed the potential to map dispersion patterns of tracer dye via remote sensing and suggested that this approach can be extended to more turbid rivers than those examined previously.

Missouri

Observations on basaltic lava streams in tubes from Kilauea Volcano, island of Hawai'i

From 1986 to 1997, the Pu'u 'O'o-Kupaianaha eruption of Kilauea produced a vast pahoehoe flow field fed by lava tubes that extended 10–12 km from vents on the volcano's east rift zone to the ocean. Within a kilometer of the vent, tubes were as much as 20 m high and 10–25 m wide. On steep slopes (4–10°) a little farther away from the vent, some tubes formed by roofing over of lava channels. Lava streams were typically 1–2 m deep flowing within a tube that here was typically 5 m high and 3 m wide. On the coastal plain (<1°), tubes within inflated sheet flows were completely filled, typically 1–2 m high, and several tens of meters wide. Tubes develop as a flow's crust grows on the top, bottom, and sides of the tubes, restricting the size of the fluid core. The tubes start out with nearly elliptical cross-sectional shapes, many times wider than high. Broad, flat sheet flows evolve into elongate tumuli with an axial crack as the flanks of the original flow were progressively buried by breakouts. Temperature measurements and the presence of stalactites in active tubes confirmed that the tube walls were above the solidus and subject to melting. Sometimes, the tubes began downcutting. Progressive downcutting was frequently observed through skylights; a rate of 10 cm/d was measured at one skylight for nearly 2 months.

Journal of Geophysical Research B: Solid Earth

Determination of time-of-travel, dispersion characteristics, and oxygen reaeration coefficients during low streamflows--Lower Tacony/Frankford Creek, Philadelphia, Pennsylvania

Time-of-travel, dispersion characteristics, and oxygen reaeration coefficients were determined by use of dye and gas tracing for a 2-mile reach of Tacony/Frankford Creek in Philadelphia, southeastern Pennsylvania. The reach frequently has concentrations of dissolved oxygen (DO) below the water-quality standard of 4 milligrams per liter during warm months. Several large combined sewer overflows (CSOs), including one of the largest in Philadelphia (former Wingohocking Creek), discharge to the study reach in this urbanized watershed, affecting water quality and the timing and magnitude of storm peaks. In addition, a dam that commonly results in backwater conditions and reduced natural reaeration is present a few hundred feet from the end of the study reach. Time-of-travel and reaeration data were collected under base-flow conditions in August and September 2009 for three sub-reaches from Roosevelt Boulevard (U.S. Route 1) to Castor Avenue. Determination of traveltimes to the centroid of the dye cloud were needed for calculation of the reaeration coefficients. Results of the dye study in Tacony/Frankford Creek indicate that traveltimes were affected by the presence of man-made structures, such as the large scour hole and pool developed at the outfall of the T14 CSO and the dam, both of which reduce stream velocities. Mean stream velocities during the dye-tracer tests ranged from a maximum of 0.44 to 0.04 foot per second through a large pool. The dispersion efficiency of the stream was determined from relations between normalized unit concentrations to time to peak for use in water-quality modeling. Oxygen reaeration coefficients determined by a constant rate-injection method using propane as the tracer gas were as low as 0.04 unit per hour in a long pool affected by backwater conditions behind a dam. The highest reaeration coefficient was 2.29 units per hour for a steep-gradient reach with multiple winding channels through gravel deposits, just downstream of a large scour pool developed at the outlet of the T14 CSO. Reaeration coefficients determined from the field tracer-gas method were compared to values calculated by two other methods, one that is based on theoretical equations using physical properties of the stream as variables and the other that is based on equations using the timing of measured daily maximum DO concentrations in the stream. Reaeration coefficients from the two alternate methods were most similar to values determined from the field tracer-gas method for the upstream portion of the study reach, characterized by free-flowing riffle and pools. Values of reaeration coefficients determined by the tracer-gas method were 2 to 10 times higher than values determined by 2 alternate methods for most subreaches hydraulically affected by man-made structures. In addition to the tracer gas, propane, the gas analysis also included methane, ethane, and ethene, of which only methane was measured in concentrations above a few micrograms per liter. Methane, thought to occur naturally or because of ongoing processes in the stream, was measured in concentrations ranging from 6.6 to 78 micrograms per liter; the concentrations were greatest in sub-reaches dominated by pools.

Pennsylvania

Evaluating coexistence of fish species with coastal cutthroat trout in low order streams of western Oregon and Washington, USA

When multiple species of fish coexist there are a host of potential ways through which they may interact, yet there is often a strong focus on studies of single species without considering these interactions. For example, many studies of forestry–stream interactions in the Pacific Northwest have focused solely on the most prevalent species: Coastal cutthroat trout. To examine the potential for interactions of other fishes with coastal cutthroat trout, we conducted an analysis of 281 sites in low order streams located on Washington’s Olympic Peninsula and along the central Oregon coast. Coastal cutthroat trout and juvenile coho salmon were the most commonly found salmonid species within these streams and exhibited positive associations with each other for both presence and density. Steelhead were negatively associated with the presence of coastal cutthroat trout as well as with coho salmon and sculpins (Cottidae). Coastal cutthroat trout most frequently shared streams with juvenile coho salmon. For densities of these co-occurring species, associations between these two species were relatively weak compared to the strong influences of physical stream conditions (size and gradient), suggesting that physical conditions may have more of an influence on density than species interactions. Collectively, our analysis, along with a review of findings from prior field and laboratory studies, suggests that the net effect of interactions between coastal cutthroat trout and coho salmon do not appear to inhibit their presence or densities in small streams along the Pacific Northwest.

Washington

Erosion potential and flood vulnerability of streams and stream crossings at Acadia National Park, Maine

Acadia National Park has had increases in the frequency and magnitude of precipitation in recent years, leading to increased flood flows, stream erosion, and costly infrastructure damage. To improve infrastructure management in a changing climate, the U.S. Geological Survey, in cooperation with the National Park Service, has developed multiple datasets that can help natural resource managers identify stream reaches and stream crossings that have the highest potential for erosion and flood damage within Acadia National Park. To develop these datasets, we first created a lidar-derived hydrography based on a 1-meter digital elevation model and then estimated peak flows at stream crossings and along the stream network using regional regression equations for Maine. We assessed the erosion potential of stream reaches by computing channel morphologic and hydrologic metrics associated with erosive power, such as stream steepness, topographic openness, and percent storage in the contributing watershed. Stream crossing flood vulnerability was assessed by comparing estimated peak flows to stream crossing conveyance capacities. Our results indicate that stream reaches in the headwaters of the Acadia National Park highlands such as Sargent, Penobscot, and Cadillac Mountain, have the highest erosion potential and generally coincide with reaches that have had erosion and infrastructure damage in the past. Stream crossings with the highest flood vulnerability are distributed throughout Mount Desert Island and Acadia National Park, especially south of Jordan Pond, north of Sargent Mountain, and surrounding Eagle Lake. Over a quarter of the total stream crossings have insufficient information to compute flood vulnerability and are often on the parts of the stream with the highest potential for erosion. The datasets allow users to identify stream reaches with the highest erosion potential, stream crossings that are most vulnerable to flood damage, and to highlight areas where supplemental field assessments could most effectively be completed.

Maine

Nutrient and pesticide contamination bias estimated from field blanks collected at surface-water sites in U.S. Geological Survey Water-Quality Networks, 2002–12

Potential contamination bias was estimated for 8 nutrient analytes and 40 pesticides in stream water collected by the U.S. Geological Survey at 147 stream sites from across the United States, and representing a variety of hydrologic conditions and site types, for water years 2002–12. This study updates previous U.S. Geological Survey evaluations of potential contamination bias for nutrients and pesticides. Contamination is potentially introduced to water samples by exposure to airborne gases and particulates, from inadequate cleaning of sampling or analytic equipment, and from inadvertent sources during sample collection, field processing, shipment, and laboratory analysis. Potential contamination bias, based on frequency and magnitude of detections in field blanks, is used to determine whether or under what conditions environmental data might need to be qualified for the interpretation of results in the context of comparisons with background levels, drinking-water standards, aquatic-life criteria or benchmarks, or human-health benchmarks. Environmental samples for which contamination bias as determined in this report applies are those from historical U.S. Geological Survey water-quality networks or programs that were collected during the same time frame and according to the same protocols and that were analyzed in the same laboratory as field blanks described in this report. Results from field blanks for ammonia, nitrite, nitrite plus nitrate, orthophosphate, and total phosphorus were partitioned by analytical method; results from the most commonly used analytical method for total phosphorus were further partitioned by date. Depending on the analytical method, 3.8, 9.2, or 26.9 percent of environmental samples, the last of these percentages pertaining to all results from 2007 through 2012, were potentially affected by ammonia contamination. Nitrite contamination potentially affected up to 2.6 percent of environmental samples collected between 2002 and 2006 and affected about 3.3 percent of samples collected between 2007 and 2012. The percentages of environmental samples collected between 2002 and 2011 that were potentially affected by nitrite plus nitrate contamination were 7.3 for samples analyzed with the low-level method and 0.4 for samples analyzed with the standard-level method. These percentages increased to 14.8 and 2.2 for samples collected in 2012 and analyzed using replacement low- and standard-level methods, respectively. The maximum potentially affected concentrations for nitrite and for nitrite plus nitrate were much less than their respective maximum contamination levels for drinking-water standards. Although contamination from particulate nitrogen can potentially affect up to 21.2 percent and that from total Kjeldahl nitrogen can affect up to 16.5 percent of environmental samples, there are no critical or background levels for these substances. For total nitrogen, orthophosphate, and total phosphorus, contamination in a small percentage of environmental samples might be consequential for comparisons relative to impairment risks or background levels. At the low ends of the respective ranges of impairment risk for these nutrients, contamination in up to 5 percent of stream samples could account for at least 23 percent of measured concentrations of total nitrogen, for at least 40 or 90 percent of concentrations of orthophosphate, depending on the analytical method, and for 31 to 76 percent of concentrations of total phosphorus, depending on the time period. Twenty-six pesticides had no detections in field blanks. Atrazine with 12 and metolachlor with 11 had the highest number of detections, mostly occurring in spring or early summer. At a 99-percent level of confidence, contamination was estimated to be no greater than the detection limit in at least 98 percent of all samples for 38 of 40 pesticides. For metolachlor and atrazine, potential contamination was no greater than 0.0053 and 0.0093 micrograms per liter in 98 percent of samples. For 11 of 14 pesticides with at least one detection, the maximum potentially affected concentration of the environmental sample was less than their respective human-health or aquatic-life benchmarks. Small percentages of environmental samples had concentrations high enough that atrazine contamination potentially could account for the entire aquatic-life benchmark for acute effects on nonvascular plants, that dieldrin contamination could account for up to 100 percent of the cancer health-based screening level, or that chlorpyrifos contamination could account for 13 or 12 percent of the concentrations in the aquatic-life benchmarks for chronic effects on invertebrates or the criterion continuous concentration for chronic effects on aquatic life.

Scientific Investigations Report

A comparison of susceptibility to Myxobolus cerebralis among strains of rainbow trout and steelhead field and laboratory trials

Three strains of rainbow trout and steelhead Oncorhynchus mykiss were evaluated for the presence of whirling disease in field and laboratory trials. In the field exposures, fingerling Salmon River steelhead and Cayuga Lake and Randolph strains of rainbow trout were placed in wire cages in an earthen, stream-fed pond in New York State that was known to harbor Myxobolus cerebralis. Control fish were held at another hatchery that was free of whirling disease. In the controlled trials at the National Fish Health Research Laboratory, fingerling steelhead and Cayuga Lake and Mount Lassen rainbow trout were exposed to triactinomyxons at low (200 triactinomyxons/fish) or high (2,000 triactinomyxons/fish) levels for 2 h. Controls of each group were sham-exposed. Following an incubation period of 154 d for laboratory trials and 180 d for field trials, cranial tissue samples were taken for spore enumeration (field and laboratory trials) and histological analyses (laboratory only). Clinical signs of disease, including whirling behavior, blacktail, and skeletal deformities, were recorded for each fish in the laboratory trial at the terminal sampling. No clinical evidence of disease was noted among fish in the field trials. Clinical signs were noted among all strains in the laboratory trials at both exposure levels, and these signs were consistently greatest for the Mount Lassen strain. Whirling and skeletal deformities were more evident in the steelhead than in the Cayuga Lake rainbow trout; blacktail was more common in the Cayuga Lake fish. In both field and laboratory trials, spore counts were significantly higher for Cayuga Lake rainbow trout than in steelhead. In laboratory trials, moderate to marked cranial tissue lesions predominated in all three strains.

New York

Effects of produced waters at oilfield production sites on the Osage Indian Reservation, northeastern Oklahoma

The authors conducted limited site surveys in the Wildhorse and Burbank oilfields on the Osage Indian Reservation, northeastern Oklahoma. The purpose was to document salt scarring, erosion, and soil and water salinization, to survey for radioactivity in oilfield equipment, and to determine if trace elements and naturally occurring radioactive materials (NORM) were present in soils affected by oilfield solid waste and produced waters. These surveys were also designed to see if field gamma spectrometry and field soil conductivity measurements were useful in screening for NORM contamination and soil salinity at these sites. Visits to oilfield production sites in the Wildhorse field in June of 1995 and 1996 confirmed the presence of substantial salt scarring, soil salinization, and slight to locally severe erosion. Levels of radioactivity on some oil field equipment, soils, and road surfaces exceed proposed state standards. Radium activities in soils affected by tank sludge and produced waters also locally exceed proposed state standards. Laboratory analyses of samples from two sites show moderate levels of copper, lead, and zinc in brine-affected soils and pipe scale. Several sites showed detectable levels of bromine and iodine, suggesting that these trace elements may be present in sufficient quantity to inhibit plant growth. Surface waters in streams at two sampled sites exceed total dissolved solid limits for drinking waters. At one site in the Wildhorse field, an EM survey showed that saline soils in the upper 6m extend from a surface salt scar downvalley about 150 m. (Photo [95k]: Dead oak trees and partly revegetated salt scar at Site OS95-2 in the Wildhorse field, Osage County, Oklahoma.) In the Burbank field, limited salt scarring and slight erosion occurs in soils at some sites and low to moderate levels of radioactivity were observed in oil field equipment at some sites. The levels of radioactivity and radium observed in some soils and equipment at these sites are above levels of concern as defined in regulations proposed by the Conference of Radiation Control Program Directors. The volumes of material involved appear to be relatively small for most sites. The lead levels observed in soils affected by tank sludge wastes are about one half of the US Environmental Protection Agency (USEPA) interim remedial action levels used for Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) and Resource Conservation and Recovery Act (RCRA) sites (400 ppm). Field gamma spectrometry proved useful in delineating areas where radium has been added to the natural soil by oilfield solid waste and produced water, although the technique does not meet standards of assessment used in the state of Louisiana which require core sampling of 15 cm intervals and radiochemical analysis in the laboratory. Further work is needed to develop field gamma spectrometry as a substitute for the more expensive coring and laboratory analysis. The ratio of radium-228 to radium-226 may hold promise in evaluating the relative ages of NORM contamination at a site.

Oklahoma

Relations among sulfate, metals, sediment, and streamflow data for a stream draining a coal-mined watershed in East-Central Pennsylvania

Streamflow and water-quality data for the northern part of Swatara Creek, which drains a 112-km 2 area in the Southern Anthracite Field of east-central Pennsylvania, indicate iron, copper, and lead, and to a lesser extent manganese and zinc, are transported with suspended particles during stormflow conditions. During stormflow conditions, concentrations of these constituents typically peak prior to peak stream stage as a result of scour and transport of streambed deposits. In contrast, sulfate is transported mostly as a dissolved ion. Concentrations of sulfate, specific conductance, and pH are inversely related to streamflow, indicating dilution and acidification during stormflow. This effect is attributed to the mixing of poorly buffered stream water having pH 6.0-6.5 with weakly acidic storm runoff having pH 4.0-4.5 and low dissolved solids.

Pennsylvania

Cotton herbicides in the surface waters of the Mississippi Alluvial Plain (the Delta)

The U.S. Geological Survey is conducting two studies to assess the environmental fate of herbicides used in cotton producing areas of the southeastern United States. The first study is evaluating surface-water quality on a regional basis and relating water quality to land use. The second study is examining the use of Best Management Practices to reduce off-site movement of agricultural chemicals in surface-water runoff. Maximum concentrations of the herbicides fluometuron and norflurazon in samples from surface water in edge-of-field studies were 23 and 7 micrograms per liter, respectively. Also, they were detected in the runoff of nearly every sampled storm for the 1997 water year at concentrations higher than 1.0 microgram per liter. Fluometuron and norflurazon were measured frequently in samples from rivers and streams in cotton producing areas, but the frequency of occurrence and the maximum concentrations were less than those in the edge-of-field studies.

Conference Paper

Soil calcium status and the response of stream chemistry to changing acidic deposition rates

Despite a decreasing trend in acidic deposition rates over the past two to three decades, acidified surface waters in the northeastern United States have shown minimal changes. Depletion of soil Ca pools has been suggested as a cause, although changes in soil Ca pools have not been directly related to long-term records of stream chemistry. To investigate this problem, a comprehensive watershed study was conducted in the Neversink River Basin, in the Catskill Mountains of New York, during 1991–1996. Spatial variations of atmospheric deposition, soil chemistry, and stream chemistry were evaluated over an elevation range of 817–1234 m to determine whether these factors exhibited elevational patterns. An increase in atmospheric deposition of SO 4 with increasing elevation corresponded with upslope decreases of exchangeable soil base concentrations and acid-neutralizing capacity of stream water. Exchangeable base concentrations in homogeneous soil incubated within the soil profile for one year also decreased with increasing elevation. An elevational gradient in precipitation was not observed, and effects of a temperature gradient on soil properties were not detected. Laboratory leaching experiments with soils from this watershed showed that (1) concentrations of Ca in leachate increased as the concentrations of acid anions in added solution increased, and (2) the slope of this relationship was positively correlated with base saturation. Field and laboratory soil analyses are consistent with the interpretation that decreasing trends in acid-neutralizing capacity in stream water in the Neversink Basin, dating back to 1984, are the result of decreases in soil base saturation caused by acidic deposition.

Ecological Applications